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CN104909451B - A kind of flat plate microporous membrane bioreactor of ceramic hollow - Google Patents

A kind of flat plate microporous membrane bioreactor of ceramic hollow Download PDF

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Publication number
CN104909451B
CN104909451B CN201510332512.2A CN201510332512A CN104909451B CN 104909451 B CN104909451 B CN 104909451B CN 201510332512 A CN201510332512 A CN 201510332512A CN 104909451 B CN104909451 B CN 104909451B
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membrane
layer
ceramic hollow
flat plate
groove
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CN104909451A (en
Inventor
陆涛
朱宣
何佳
丁恺
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Nanjing Fiberglass Research and Design Institute Co Ltd
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Nanjing Sinoma Water Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Separation Using Semi-Permeable Membranes (AREA)
  • Biological Treatment Of Waste Water (AREA)

Abstract

The invention discloses a kind of flat plate microporous membrane bioreactor of ceramic hollow, including membrane support, membrane layer and aeration layer, membrane support is frame structure, aeration layer and membrane layer is each provided in the framework of membrane support and membrane layer is located at the top of aeration layer;Membrane layer includes ceramic hollow flat plate porous film, guide plate, draw-in groove and collector pipe, and guide plate is located on membrane support, and draw-in groove is located on guide plate, and ceramic hollow flat plate porous film is fastened on membrane support by draw-in groove;The top of ceramic hollow flat plate porous film is provided with faucet, and tube side of catchmenting wall is provided with inlet opening, and faucet is corresponded with inlet opening, and passes through soft pipe connection.The core parts of the flat plate microporous membrane bioreactor of ceramic hollow of the present invention adopt ceramic hollow flat plate porous film, there is high mechanical strength, chemical stability is good, water flux is big, resistance tocrocking good, the features such as be readily cleaned regeneration, solve during organic membrane component runs the difficulty that cleaning is frequent, maintenance is loaded down with trivial details, effectively increase the service life of membrane bioreactor.

Description

A kind of flat plate microporous membrane bioreactor of ceramic hollow
Technical field
The present invention relates to a kind of flat plate microporous membrane bioreactor of ceramic hollow, belong to water treatment field.
Background technology
Membrane bioreactor is as a kind of new and effective sewage disposal technology, it has also become town sewage, industrial wastewater or even Indispensable treatment technology in highly difficult wastewater treatment.
Membrane bioreactor is wide variety of at present is hollow-fiber membrane bioreactor, is acted on by aeration and increases flco Sludge concentration, improves the effect degraded organic matter of sewage of specially good effect bacterium in mud.But, exist serious in actual moving process Pollution problem, hollow-fibre membrane bad mechanical strength, easily fracture of wire in filter membrane, and assembly is dirty stifled frequent, and service life is short, and occurs Diaphragm must be changed after damaging, non-renewable, and operating cost is high.
Content of the invention
In order to solve the filter membrane bad mechanical strength of membrane bioreactor presence in prior art, fracture of wire, assembly easily occur Dirty stifled frequently service life is short, and occurs diaphragm must change after damaging, non-renewable, the problems such as operating cost is high, the present invention There is provided a kind of ceramic hollow flat plate microporous membrane bioreactor.
For solving above-mentioned technical problem, the technical solution adopted in the present invention is as follows:
A kind of flat plate microporous membrane bioreactor of ceramic hollow, including membrane support, membrane layer and aeration layer, membrane support is frame Frame structure, aeration layer and membrane layer are each provided in the framework of membrane support and membrane layer is located at the top of aeration layer;Membrane layer includes Ceramic hollow flat plate porous film, guide plate, draw-in groove and collector pipe, guide plate is located on membrane support, and draw-in groove is located on guide plate, ceramic hollow Flat plate porous film is fastened on membrane support by draw-in groove;Collector pipe is located on the membrane support above ceramic hollow flat plate porous film; The top of ceramic hollow flat plate porous film is provided with faucet, and tube side of catchmenting wall is provided with inlet opening, and faucet is with inlet opening one by one Corresponding, and pass through soft pipe connection.
The application with ceramic hollow flat plate porous film as membrane bioreactor core component, have resistance tocrocking good, Be readily cleaned regeneration, the advantages of long service life, chemical stability are good, high mechanical strength, water flux are big, can effectively solving existing Hollow-fibre membrane, organic Flat Membrane service life present in engineer applied process are short, the problems such as be easily subject to acid and alkali corrosion, and Used ceramic membrane can reclaim for other ceramics, reduces garbage.In actual applications, can be according to need Being operated in parallel or in series of assembly to be carried out.
The positive and negative of ceramic hollow flat plate porous film is equipped with micropore, and inside is provided with aquaporin, enters ceramic hollow flat board Water in microporous membrane, is flowed out by faucet.
Preferably, the inlet opening on the side wall of collector pipe is divided two rows, and the upper inlet opening of two rows is crisscross arranged, the upper phase of same row The spacing of adjacent two inlet openings is the twice of adjacent two ceramic hollow flat plate porous film spacing.
During use, flat plate microporous for ceramic hollow membrane bioreactor is immersed in cesspool, the sewage after aeration enters pottery In porcelain hollow flat plate porous film, flowed out from faucet after the flat plate microporous film process of ceramic hollow, and collection is entered by flexible pipe Water pipe.
The application top, bottom, the phase referring both to when the flat plate microporous membrane bioreactor of ceramic hollow normally uses such as upper and lower To position.The quantity of ceramic hollow flat plate porous film can determine according to aeration rate, the top of every ceramic hollow flat plate porous film All there is a faucet in portion, and the quantity of the inlet opening on collector pipe is equal with water outlet unrounded number, and corresponds.
Preferably, membrane support is cuboid framework structure, and membrane support includes being vertically arranged and four contour root posts, four The top of column is connected as a single entity by connecting rod;Aeration layer support and membrane layer support are sequentially provided with from top to bottom on membrane support, Membrane layer support includes upper and lower two-layer guide plate and the two-layer draw-in groove being separately positioned on two-layer guide plate, ceramic hollow flat plate porous film It is fastened between two-layer draw-in groove;Collector pipe is located between upper strata guide plate and the connecting rod at column top.So can carry further The stability of high membrane support.So it is not only simple in structure, convenient installation, and stability is strong.
In order to improve the stability of membrane support further, the bottom of every root post is additionally provided with bearing.The purpose of bearing setting It is to increase lifting surface area.
Every layer of guide plate has two, and two guide plates of same layer are located on the length direction of support and highly equal relatively, lead The two ends of plate are connected with two root posts respectively;It is equipped with draw-in groove, upper and lower two-layer draw-in groove is oppositely arranged on every guide plate.So pottery All there is corresponding draw-in groove engaging at four angles of hollow flat plate porous film, further increase the stability of device.
Draw-in groove is shaped as strip, and draw-in groove length direction is wherein provided with groove, the groove of upper and lower two-layer draw-in groove It is oppositely arranged, the shape of upper and lower two-layer groove is corresponding with the shape of ceramic hollow flat plate porous film upper and lower ends respectively.So Further increase convenience and the stability of the installation of ceramic hollow flat plate porous film.
Draw-in groove can move up and down with respect to guide plate.So when installing, the position of draw-in groove can adjust, further up and down Improve the convenience of installation and removal, and be easily installed the adjustment of rear stability.
Guide plate is provided with mounting hole, and draw-in groove is provided with bolt hole, and draw-in groove is solid by the bolt through bolt hole and mounting hole It is scheduled on guide plate.As another kind of scheme of the application, mounting hole is also used in the plural spiral shell of setting on same vertical curve Keyhole substitutes.Purpose is the upper-lower position facilitating draw-in groove relative to guide plate, and then is easy for installation and removal.
Membrane support be formed around enclosing.Gas so can be prevented to membrane support external diffusion it is ensured that air water is sufficiently mixed, Improve ceramic hollow flat plate microporous Membrane Bioreactor for Wastewater Treatment effect.
Spacing between the top of ceramic hollow flat plate porous film and collector pipe is 0.1-0.2m;Collector pipe clip is fixed On membrane support;The quantity of ceramic hollow flat plate porous film is determined according to the aeration rate of aeration layer, and the tolerance of 11-13L/min needs Will a piece of ceramic hollow flat plate porous film.The selection of the spacing between the top of ceramic hollow flat plate porous film and collector pipe helps In raising water collection efficiency;The selection of the mounting means of collector pipe, not only facilitates and installs, dismantles, and Stability Analysis of Structures;Ceramic hollow is put down The selection of plate microporous membrane quantity can be further ensured that the efficiency of sewage purification.
On ceramic hollow flat plate porous film, the aperture of micropore is 0.1-0.3 μm, and membrane flux is 0.2~1.5m3/ (d).This Sample can improve the efficiency of sewage disposal further.The implication of d is sky.
The height of membrane layer is 1-1.1m;Ceramic hollow flat plate porous film is arranged in parallel, and adjacent two ceramic hollow flat boards are micro- The spacing of pore membrane is 15-20mm;The height of aeration layer is 0.15-0.25m, the distance of the distance from bottom membrane support bottom of aeration layer For 0.25-0.35m, aeration layer is furnished with U-shaped aeration tube, and aeration tube is provided with solarization air cap, and solarization air cap aperture is 4-5mm, solarization air cap Quantity be 40-70, solarization air cap flow velocity is 25-35m/s.The setting of above-mentioned each structure, can further improve sewage disposal Efficiency.
Above-mentioned membrane support is preferably steel membrane support.So can extension reactor service life.
The top of membrane support is preferably provided with two handles being oppositely arranged.So further facilitate the carrying of reactor.
Ceramic hollow flat plate porous film includes diaphragm block, is fastened on the U-shaped rustless steel card of diaphragm block top and bottom Groove and be located at sealing ring between diaphragm block and U-shaped rustless steel draw-in groove, faucet is located at the U-shaped rustless steel at diaphragm block top On draw-in groove.In the above-mentioned manufacture in diaphragm, change the form that original diaphragm goes out chewing gum envelope, be processed into U-type groove with stainless steel material, close Sealer piece two ends, port sealing ring seals.This diaphragm fixed form have dismounting flexible feature, be easy to diaphragm cleaning with Dismounting, it is only necessary to pull down two ends rustless steel U-type groove when ceramic diaphragm needs to be regenerated, will after the completion of regeneration again Frid is reinstalled up, saves the process of the sealer piece that removes photoresist.
The NM technology of the present invention is all with reference to prior art.
The core parts of the flat plate microporous membrane bioreactor of ceramic hollow of the present invention adopt ceramic hollow flat plate porous film, tool The features such as have that high mechanical strength, chemical stability are good, water flux is big, resistance tocrocking good, be readily cleaned regeneration, solves organic membrane Element cleans frequently in running, safeguards loaded down with trivial details difficulty, effectively increases the service life of membrane bioreactor;Can be according to reality Requirement of engineering flexible configuration reactor size, simply it is operated in parallel or in series, is realized real exclusive customization, efficiently saved Energy;Ceramic hollow flat plate porous film bioreactor construction is simple, easy accessibility.
Brief description
Fig. 1 is the structural representation of the flat plate microporous membrane bioreactor of ceramic hollow of the present invention.
Fig. 2 is the arrangement schematic diagram of inlet opening on collector pipe in embodiment 1;
Fig. 3 is ceramic hollow flat plate porous film front view;
Fig. 4 is the left view of Fig. 3;
Fig. 5 is the amplification view that in Fig. 4, A goes out;
In figure, 1 is connecting rod, and 2 is guide plate, and 3 is draw-in groove, and 4 is collector pipe, and 5 is ceramic hollow flat plate porous film, and 6 is film Support, 7 is U-shaped aeration tube, and 8 is flexible pipe, and 9 is faucet, and 10 is inlet opening, and 11 is aeration layer, and 12 is membrane layer, and 13 is to prop up Seat, 14 is inlet opening, and 15 is diaphragm block, and 16 is U-shaped rustless steel draw-in groove, and 17 is sealing ring;In figure only depicts a piece of pottery Hollow flat plate porous film, other omissions.
Specific embodiment
For a better understanding of the present invention, it is further elucidated with present disclosure with reference to embodiment, but the present invention Content is not limited solely to the following examples.
Embodiment 1
A kind of flat plate microporous membrane bioreactor of ceramic hollow, including membrane support, membrane layer and aeration layer, membrane support is frame Frame structure, aeration layer and membrane layer are each provided in the framework of membrane support and membrane layer is located at the top of aeration layer;Membrane layer includes 75 pieces of ceramic hollow flat plate porous film, guide plate, draw-in groove and collector pipe, guide plate is located on membrane support, and draw-in groove is located on guide plate, pottery Hollow flat plate porous film is fastened on membrane support by draw-in groove;Collector pipe is located at the membrane support above ceramic hollow flat plate porous film On;The top of every piece of ceramic hollow flat plate porous film is equipped with faucet, angle looping perforate in level ± 30 ° on tube side of catchmenting wall Totally 75 radius is 3mm as inlet opening, each faucet corresponds to an inlet opening, and corresponding faucet and inlet opening lead to Cross snap joint and soft pipe connection, connect snap joint and flexible pipe one by one and ceramic membrane is produced water introducing in parallel collector pipe.Pottery The micropore size of porcelain hollow flat plate porous film is 0.15 μm, and membrane component length × width x thickness=1000 × 250 × 6mm, in this pottery The membrane flux of empty flat plate microporous membrane bioreactor is 1.5m3/ (d), working pressure range 0~0.6MPa.The side of collector pipe Inlet opening on wall is divided two rows, and the upper inlet opening of two rows is crisscross arranged, and the spacing of upper adjacent two inlet openings of same row is adjacent The twice of two ceramic hollow flat plate porous film spacing.
Membrane support is cuboid framework structure, and membrane support includes being vertically arranged and four contour root posts, four root posts Top is connected as a single entity by connecting rod, and the bottom of every root post is additionally provided with bearing, and membrane support is welded by rustless steel angle steel, film The long 1.37m of support, wide 0.32m, high 1.8m;Aeration layer support and membrane layer support are sequentially provided with from top to bottom on membrane support, Membrane layer support includes upper and lower two-layer guide plate and the two-layer draw-in groove being separately positioned on two-layer guide plate, ceramic hollow flat plate porous film It is fastened between two-layer draw-in groove;Collector pipe is located between upper strata guide plate and the connecting rod at column top;Every layer of guide plate has two, with One layer of two guide plates are located on the length direction of support and highly equal relatively, and the two ends of guide plate are respectively with two root posts even Connect;Draw-in groove is equipped with every guide plate, draw-in groove length direction is wherein provided with groove, the groove phase of upper and lower two-layer draw-in groove To setting, the shape of upper and lower two-layer groove is corresponding with the shape of ceramic hollow flat plate porous film upper and lower ends respectively.
Guide plate is provided with mounting hole, and draw-in groove is provided with bolt hole, and draw-in groove is solid by the bolt through bolt hole and mounting hole It is scheduled on guide plate, draw-in groove can move up and down with respect to guide plate.
Membrane support be formed around 3mm thickness corrosion resistant plate enclosing;Ceramic hollow flat plate porous film includes diaphragm block, engaging U-shaped rustless steel draw-in groove in diaphragm block top and bottom and be located at sealing ring between diaphragm block and U-shaped rustless steel draw-in groove, Faucet is located on the U-shaped rustless steel draw-in groove at diaphragm block top;
Spacing between the top of ceramic hollow flat plate porous film and collector pipe is 0.15m;Collector pipe is stainless by DN40
Steel pipe is manufactured, and collector pipe clip is fixed on membrane support.
On ceramic hollow flat plate porous film, the aperture of micropore is 0.15 μm, and membrane flux is 1.0m3/(㎡d).
The height of membrane layer is 1.06m;Ceramic hollow flat plate porous film is arranged in parallel, and adjacent two ceramic hollows are flat plate microporous The spacing of film is 18mm;The height of aeration layer is 0.2m, and the distance of the distance from bottom membrane support bottom of aeration layer is 0.3m, aeration Layer is furnished with the U-shaped aeration tube of DN32 stainless steel tube making, and aeration tube is provided with solarization air cap, and solarization air cap aperture is 4mm, solarization air cap Quantity is 54, and solarization air cap flow velocity is 25-35m/s.
The mounting means of 75 pieces of ceramic hollow flat plate porous films is, by a piece of ceramic hollow flat plate porous film from support front After insertion, lower floor's draw-in groove is moved up 20mm, bolt is fixed;Upper strata both sides draw-in groove is moved downward to and blocks diaphragm position Put, bolt is fixed, then be sequentially inserted into 74 films, finally move up lower floor's another side draw-in groove further by ceramic hollow flat board Microporous membrane clamping.
Used by embodiment, ceramic hollow flat plate porous film is prepared as:Raw material consists of:Particle diameter is 2 μm of α-al2o3powder bodies, Starch, carboxymethyl cellulose are with 80wt%:10wt%:The ratio of 10wt%, solid material gross mass is 100kg;Water, glycerol, Nano silicon dioxide dispersion is with 60wt%:5wt%:The part by weight of 35wt%, total mass of liquid raw material is 25kg.
Above two raw material solid, liquid are according to 4:1 part by weight mixing.
Preparation method:The powder body that gets togather of premix and liquid charging stock are mixed be incorporated in kneader mediate, mud refining system in pug mill One-tenth porous ceramic shaping mud, old 24 hours.Old good pug is loaded descaling extrusion press extrusion molding, extrusion pressure is 6MPa, extruded velocity is 3m/min, and extrusion temperature is 25 DEG C, and the duct in connector units outside extrusion die with extrusion direction is in 45 ° of angles.The plasticity green compact of extrusion are placed on the porous flat plate of upper berth fiber felt, enter microwave drier and 1h is dried.It is dried The semi-finished product completing stack 5 layers and enter kiln sintering, 1250 DEG C of sintering temperature, are incubated 4h, make large size thin-walled flat membrane.
Prepared by separation membrane layer:α-Al2O3Diameter of particle D50 is 500nm, α-Al2O3, water is with 40%:51.8% ratio mixing Then add 0.2% sodium polyacrylate disperant, using ball milling method mixing 2h, subsequently add Nano silica sol 8%, ball milling 2h The good membrane layer pulp of processability afterwards, is then entered in the flat support body surface face processing with regard to effect surface in advance using spraying coating process Row coating.Spray gas pressure is adjusted to 0.3MPa, after spraying weightening quality control in 100-400g, film layer after drying 1200 Burn till at a temperature of DEG C, be incubated 2h, prepared flat film product.
The core parts of the flat plate microporous membrane bioreactor of ceramic hollow of above-described embodiment gained adopt ceramic hollow to put down Plate microporous membrane, have high mechanical strength, chemical stability is good, water flux is big, resistance tocrocking good, the features such as be readily cleaned regeneration, Solve during organic membrane component runs the difficulty that cleaning is frequent, maintenance is loaded down with trivial details, effectively increase the use longevity of membrane bioreactor Life;Can realize real special according to actual requirement of engineering flexible configuration reactor size, be simply operated in parallel or in series Belong to customization, energy-efficient;Ceramic hollow flat plate porous film bioreactor construction is simple, easy accessibility.

Claims (6)

1. a kind of flat plate microporous membrane bioreactor of ceramic hollow it is characterised in that:Including membrane support, membrane layer and aeration layer, Membrane support is cuboid framework structure, and membrane support includes being vertically arranged and four contour root posts, and the top of four root posts is passed through Connecting rod is connected as a single entity;Membrane support is sequentially provided with aeration layer support and membrane layer support from top to bottom, and aeration layer and membrane layer divide It is not located in aeration layer support and in membrane layer support;Membrane layer includes ceramic hollow flat plate porous film and collector pipe, membrane layer Support includes the guide plate of two-layer up and down being located on membrane support and the two-layer draw-in groove being separately positioned on two-layer guide plate, and ceramic hollow is put down Plate microporous membrane is fastened between two-layer draw-in groove;Collector pipe is located between upper strata guide plate and the connecting rod at column top;Ceramic hollow The top of flat plate porous film is provided with faucet, and tube side of catchmenting wall is provided with inlet opening, and faucet is corresponded with inlet opening, and leads to Cross soft pipe connection;
Inlet opening on the side wall of collector pipe is divided two rows, and the upper inlet opening of two rows is crisscross arranged, and same row upper adjacent two is intake The spacing in hole is the twice of adjacent two ceramic hollow flat plate porous film spacing;
Every layer of guide plate has two, and two guide plates of same layer are located on the length direction of support and highly equal relatively, guide plate Two ends are connected with two root posts respectively;It is equipped with draw-in groove, upper and lower two-layer draw-in groove is oppositely arranged on every guide plate;
On draw-in groove length direction wherein while being provided with groove, the groove of upper and lower two-layer draw-in groove is oppositely arranged, upper and lower two-layer groove Shape corresponding with the shape of ceramic hollow flat plate porous film upper and lower ends respectively;
Draw-in groove can move up and down with respect to guide plate.
2. the flat plate microporous membrane bioreactor of ceramic hollow as claimed in claim 1 it is characterised in that:Guide plate is provided with kidney-shaped Hole, draw-in groove is provided with bolt hole, and draw-in groove is by being bolted on guide plate through bolt hole and mounting hole.
3. the flat plate microporous membrane bioreactor of ceramic hollow as claimed in claim 1 or 2 it is characterised in that:The four of membrane support Week is provided with enclosing;Ceramic hollow flat plate porous film includes diaphragm block, is fastened on the U-shaped rustless steel of diaphragm block top and bottom Draw-in groove and be located at sealing ring between diaphragm block and U-shaped rustless steel draw-in groove, the U-shaped that faucet is located at diaphragm block top is stainless On steel draw-in groove.
4. the flat plate microporous membrane bioreactor of ceramic hollow as claimed in claim 1 or 2 it is characterised in that:Ceramic hollow is put down Spacing between the top of plate microporous membrane and collector pipe is 0.1-0.2m;Collector pipe clip is fixed on membrane support;In pottery The quantity of empty flat plate porous film is determined according to the aeration rate of aeration layer, and the tolerance of 11-13L/min needs a piece of ceramic hollow flat board Microporous membrane.
5. the flat plate microporous membrane bioreactor of ceramic hollow as claimed in claim 1 or 2 it is characterised in that:Ceramic hollow is put down On plate microporous membrane, the aperture of micropore is 0.1-0.3 μm, and membrane flux is 0.2~1.5m3/(㎡d).
6. the flat plate microporous membrane bioreactor of ceramic hollow as claimed in claim 1 or 2 it is characterised in that:The height of membrane layer Spend for 1-1.1m;Ceramic hollow flat plate porous film is arranged in parallel, and the spacing of adjacent two ceramic hollow flat plate porous films is 15- 20mm;The height of aeration layer is 0.15-0.25m, and the distance of the distance from bottom membrane support bottom of aeration layer is 0.25-0.35m, exposes Gas-bearing formation is furnished with U-shaped aeration tube, and aeration tube is provided with solarization air cap, and solarization air cap aperture is 4-5mm, and the quantity of solarization air cap is 40-70, Solarization air cap flow velocity is 25-35m/s.
CN201510332512.2A 2015-06-16 2015-06-16 A kind of flat plate microporous membrane bioreactor of ceramic hollow Active CN104909451B (en)

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CN105692883B (en) * 2016-02-05 2018-12-14 新疆碧水源环境资源股份有限公司 A kind of mobile cross-flow aerator for capableing of on-line cleaning
CN112473385A (en) * 2020-12-03 2021-03-12 张家港市华远环境科技有限公司 Corrugated plate ceramic filtering membrane

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US9278317B2 (en) * 2011-12-09 2016-03-08 Lotte Chemical Corporation Hollow fiber membrane module with miniskeins in miniheaders having a zig-zag configuration
CN203959884U (en) * 2014-06-21 2014-11-26 吴然然 A kind of membrane module
CN204111408U (en) * 2014-10-20 2015-01-21 胡奠新 Ceramic membrane bioreactor
CN204824328U (en) * 2015-06-16 2015-12-02 南京中材水务股份有限公司 Dull and stereotyped micropore membrane bioreactor of pottery cavity

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