CN104877496A - Important component of crack-resistant insulated flame-retardant building material coating - Google Patents
Important component of crack-resistant insulated flame-retardant building material coating Download PDFInfo
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- CN104877496A CN104877496A CN201510198142.8A CN201510198142A CN104877496A CN 104877496 A CN104877496 A CN 104877496A CN 201510198142 A CN201510198142 A CN 201510198142A CN 104877496 A CN104877496 A CN 104877496A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
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- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
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Abstract
The invention discloses an important component of a crack-resistant insulated flame-retardant building material coating. The important component is characterized in that nanosilicon dioxide and a graphene microchip are added to an insulated flame-retardant coating, wherein the nanosilicon dioxide accounts for 1%-5% of the weight of basic components of the insulated flame-retardant coating; the graphene microchip accounts for 0.5%-5% of the weight of the basic components; the crack resistance of the coating is improved by adding two inorganic non-metallic materials, namely the nanosilicon dioxide and the graphene microchip; crystal is grown and generated from the graphene microchip in a three-dimensional cellular way (same as a diamond mine); four valence electrons of each carbon atom form covalent bonds to be bound, cannot form electron flow in directional movement, and cannot conduct electricity; generated graphite carbon crystal is ground in a single direction in a wet nano-grinding manner, so as to generate the graphene microchip of which the thickness is in a nanometer scale and the area is in a micron scale; due to the addition of the graphene microchip into the coating, the fusion performance of the coating can be greatly improved; and the coating has good crack resistance.
Description
Technical field
The present invention relates to technical field of inorganic nonmetallic materials, be specifically related to a kind of anti-cracking resistance heat-insulating and fire-proof building materials coating important composition composition.
Background technology
After 20 century 70s, world climate warms, and earth energy is increasingly exhausted.In AND ENERGY RESOURCES CONSUMPTION IN CHINA, building energy consumption accounts for the 30-40% of mankind's energy consumption, and improving building heat preserving heat-proof quality is save energy, the important channel of improving buildings using function.Thermal insulating coating is applied over the temperature that building surface can effectively reduce building surface and inside.In recent years, along with the popularization of building energy conservation, thermal insulating coating more and more receives the concern of people because of advantages such as economic, convenient and good heat-insulation effect.Therefore, research and develop the daily life of novel, compound insulating mold coating to the mankind to be of great immediate significance.
Existing insulating mold coating mainly adopts organic polymeric emulsions, cenosphere, the heat insulation color stuffing such as porous filler and heat-reflecting material reaches heat insulating, the object of water proof anti-soil, a kind of counter radiation thermal insulating coating disclosed in Chinese patent ZL99114454.6, a kind of aquosity elastic heat preserving insulating paint and preparation method thereof disclosed in ZL200710075800.X, insulating mold coating disclosed in ZL200910061883.6, a kind of thermal insulating coating and uses thereof disclosed in ZL200510000149.0, a kind of thermal insulating coating etc. reflecting solar heat ray disclosed in ZL200710035834.6.Disclosed in its Patent ZL200710035834.6, a kind of thermal insulating coating reflecting solar heat ray is made up of bottom-coating and painting coating, and primary coat adopts hollow beads lagging material, heat-reflecting material and macromolecule resin to make; Face is coated with and adopts Surface coating reverberation ray matrix material, heat-reflecting material and macromolecule resin to make, owing to containing the extinction groups such as a large amount of-C=0 ,-C-0-C ,-0H in organic polymer, inorganic color stuffing is higher than to the degree of absorption of sunlight, so when the addition of organic polymeric emulsions is larger, film is also larger to the absorbed dose of sunlight, the thermal conductivity of film also can correspondingly improve, and can reduce the effect of heat insulation of coating.In order to reach the basic process based prediction model requirement of common exterior coating, this kind of existing traditional thermal insulating coating must ensure the higher addition of organic polymeric emulsions in coating, causes its effect of heat insulation undesirable.And not there is resistance to cleavage, in use receive many restrictions.
Summary of the invention
It is simple that technical problem to be solved by this invention is to improve a kind of preparation, the anti-cracking resistance heat-insulating and fire-proof building materials coating important composition composition that cost is low.
Technical problem to be solved by this invention realizes by the following technical solutions:
A kind of anti-cracking resistance heat-insulating and fire-proof building materials coating important composition composition, is characterized in that: in heat-insulating and fire-proof coating, add accounting for the basic nano silicon of Ingredients Weight 1-5% of heat-insulating and fire-proof coating and the graphene microchip of 0.5-5%; The resistance to cleavage of coating is improved by adding nano silicon and these two kinds of ceramic of graphene microchip.
The concrete moiety of heat-insulating and fire-proof building materials coating of the present invention is, percentage meter by weight:
Above-mentioned graphene microchip is with the long brilliant generation (as Diamond Deposit class) of the cellular fashion of solid, and four of each carbon atom valence electrons formed covalent linkage in bond live, the stream of electrons of displacement can not be formed, so just can not conduct electricity, after generating, graphite carbon crystal utilizes the nano-milled mode of wet type, with single direction grinding, generation thickness is nanometer, and area is micronized graphene microchip; In coating, add the fusion performance that graphene microchip can promote coating greatly, there is extraordinary resistance to cleavage.
The preparation method of above-mentioned nano silicon is as follows:
1) ratio of 1-3:1-5 takes SiO 2 powder and Neon SiC powder in mass ratio;
2) be dispersion medium to the silicon-dioxide taken and sic powder with dehydrated alcohol, wherein the mass ratio of powder and alcohol is 1:30, in model be ZB220-T supersonic cleaning machine on ultrasonic disperse 1 hour;
3) compound through ultrasonic disperse being put into nylon ball grinder, take agate ball as abrading-ball, and ball material mass ratio is 7:1, is under the condition of 150 revs/min at rotating speed, is continuous ball milling 2 hours in the planetary ball mill of QM-1SP in model;
4) pour in powder dish by powder complete for ball milling together with agate abrading-ball, dry at 80 DEG C, the model of baking oven is 202-2 type;
5) powder of drying is sieved, take out agate abrading-ball, then powder mix is ground, until without till larger reunion, so far, obtain nano silicon.
Described oxidation inhibitor is made up of the component of following parts by weight: DMKO 20 parts, peanut oil 25 parts, soybean protein isolate 4 parts, nonane diacid 2 parts, Isoamyl Acetate FCC 4 parts, Graphene 2 parts, silicone oil 10 parts, plam oil 4 parts, whiteruss 3 parts, the trimethyl carbinol 4 parts.
Described defoamer is made up of the component of following parts by weight: aerosil 12 parts, 55 parts, mineral oil, nonane diacid 2 parts, Rizinsan K2 A2 2 parts, albutin 2 parts, 8 parts, Vaseline, Microcrystalline Wax 5 parts, nanometer silicon carbide 2 parts, modified corn starch 5 parts.
The invention has the beneficial effects as follows: (1) elasticity and splitting resistance good; (2) preparation technology is simple, and finished product is nonpoisonous and tasteless, environmental protection; (3) can save and not degenerate for a long time; (4) good leveling property, strong adhesion when spreading; (5) do not chap after long-time use, do not come off.
Embodiment
The technique means realized to make the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with specific embodiment, setting forth the present invention further.
Embodiment 1
A kind of anti-cracking resistance heat-insulating and fire-proof building materials coating important composition composition, percentage meter by weight, be made up of following component:
Non-metallic material improve the resistance to cleavage of coating.
Above-mentioned graphene microchip is with the long brilliant generation (as Diamond Deposit class) of the cellular fashion of solid, and four of each carbon atom valence electrons formed covalent linkage in bond live, the stream of electrons of displacement can not be formed, so just can not conduct electricity, after generating, graphite carbon crystal utilizes the nano-milled mode of wet type, with single direction grinding, generation thickness is nanometer, and area is micronized graphene microchip; In coating, add the fusion performance that graphene microchip can promote coating greatly, there is extraordinary resistance to cleavage.
The preparation method of above-mentioned nano silicon is as follows:
1) SiO 2 powder and Neon SiC powder is taken in the ratio of 1-3:1-5;
2) be dispersion medium to the silicon-dioxide taken and sic powder with dehydrated alcohol, wherein the mass ratio of powder and alcohol is 1:30, in model be ZB220-T supersonic cleaning machine on ultrasonic disperse 1 hour;
3) compound through ultrasonic disperse being put into nylon ball grinder, take agate ball as abrading-ball, and ball material mass ratio is 7:1, is under the condition of 150 revs/min at rotating speed, is continuous ball milling 2 hours in the planetary ball mill of QM-1SP in model;
4) pour in powder dish by powder complete for ball milling together with agate abrading-ball, dry at 80 DEG C, the model of baking oven is 202-2 type;
5) powder of drying is sieved, take out agate abrading-ball, then powder mix is ground, until without till larger reunion, so far, obtain nano silicon.
Described oxidation inhibitor is made up of the component of following parts by weight: DMKO 20 parts, peanut oil 25 parts, soybean protein isolate 4 parts, nonane diacid 2 parts, Isoamyl Acetate FCC 4 parts, Graphene 2 parts, silicone oil 10 parts, plam oil 4 parts, whiteruss 3 parts, the trimethyl carbinol 4 parts.
During production, whether first monitoring device can run well, the various raw-material proportioning weight of accurate measurement is also ready to by production sequence, then, the agitator motor starting mixing machine keeps spiral to be in whipped state, drop into previously prepared mixture again by mixing machine, dispersion is stirred, grind, stirring is finished product again; Discharging, product quality inspection, metering packing.
The performance index that table 2 is coating of the present invention:
Table 1
More than show and describe ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.
Claims (3)
1. an anti-cracking resistance heat-insulating and fire-proof building materials coating important composition composition, it is characterized in that, percentage meter is made up of following composition by weight:
2. one according to claim 1 anti-cracking resistance heat-insulating and fire-proof building materials coating important composition composition, it is characterized in that, above-mentioned graphene microchip is with the long brilliant generation of the cellular fashion of solid, after generating, graphite carbon crystal utilizes the nano-milled mode of wet type, grind with single direction, generation thickness is nanometer, and area is micronized graphene microchip.
3. one according to claim 1 anti-cracking resistance heat-insulating and fire-proof building materials coating important composition composition, it is characterized in that, the preparation method of above-mentioned nano silicon is as follows:
1) ratio of 1-3:1-5 takes SiO 2 powder and Neon SiC powder in mass ratio;
2) be dispersion medium to the silicon-dioxide taken and sic powder with dehydrated alcohol, wherein the mass ratio of powder and alcohol is 1:30, ultrasonic disperse 1 hour on supersonic cleaning machine;
3) compound through ultrasonic disperse being put into nylon ball grinder, take agate ball as abrading-ball, and ball material mass ratio is 7:1, is under the condition of 150 revs/min at rotating speed, continuous ball milling 2 hours;
4) pour in powder dish by powder complete for ball milling together with agate abrading-ball, dry at 80 DEG C, the model of baking oven is 202-2 type;
5) powder of drying is sieved, take out agate abrading-ball, then powder mix is ground, until without till larger reunion, so far, obtain nano silicon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510198142.8A CN104877496B (en) | 2015-04-24 | 2015-04-24 | Crack-resistant insulated flame-retardant building material coating |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510198142.8A CN104877496B (en) | 2015-04-24 | 2015-04-24 | Crack-resistant insulated flame-retardant building material coating |
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| CN104877496A true CN104877496A (en) | 2015-09-02 |
| CN104877496B CN104877496B (en) | 2017-01-25 |
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| CN201510198142.8A Expired - Fee Related CN104877496B (en) | 2015-04-24 | 2015-04-24 | Crack-resistant insulated flame-retardant building material coating |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105400387A (en) * | 2015-12-17 | 2016-03-16 | 滁州市友邦涂装有限公司 | Bending-resistant powder coating |
| CN105505142A (en) * | 2015-12-17 | 2016-04-20 | 滁州市友邦涂装有限公司 | Super-weatherability powder coating for electrostatic spraying |
| CN105602413A (en) * | 2015-12-17 | 2016-05-25 | 滁州市友邦涂装有限公司 | Metallic powder for powder electrostatic spraying |
| CN107151113A (en) * | 2017-07-05 | 2017-09-12 | 合肥片美环保科技有限公司 | Preparation method of novel energy-saving environment-friendly building material |
| CN107382371A (en) * | 2017-08-23 | 2017-11-24 | 北京奥克森节能环保科技有限公司 | A kind of modifying agent and preparation method thereof |
| CN107987650A (en) * | 2017-12-25 | 2018-05-04 | 张龙 | A kind of anti-cracking resistance thermal insulation coatings important composition component |
| CN107987649A (en) * | 2017-12-25 | 2018-05-04 | 韩昕冉 | A kind of anti-cracking resistance heat-insulating and fire-proof coating important composition component |
| CN108017968A (en) * | 2017-12-25 | 2018-05-11 | 韩昕冉 | A kind of anti-cracking resistance high temperature insulating thermal insulation coatings important composition component |
| CN108250894A (en) * | 2017-12-13 | 2018-07-06 | 颍上永红建材有限公司 | A kind of flame-proof environmental protection building materials paint |
| CN108976923A (en) * | 2018-06-11 | 2018-12-11 | 成都兰腾科技有限公司 | A kind of hydrophobe hybrid cellular shape heat-conductive coating |
| CN109097155A (en) * | 2018-09-13 | 2018-12-28 | 吴文林 | A kind of preparation method lubricating nanometer additive |
| CN109135472A (en) * | 2018-08-01 | 2019-01-04 | 浙江埃普瑞纳米材料有限公司 | The formula and preparation method thereof of Neon SiC powder coating |
| CN109233522A (en) * | 2018-09-28 | 2019-01-18 | 佛山齐安建筑科技有限公司 | A kind of building material surface fireproof coating |
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| CN104293086A (en) * | 2014-09-22 | 2015-01-21 | 铜陵市新泰电容电器有限责任公司 | Coating taking graphene microchip as main agent and applied on aluminum foil for radiating |
| CN104449159A (en) * | 2013-09-23 | 2015-03-25 | 青岛兴国涂料有限公司 | Environment-friendly nanometre ultraviolet-proof wall paint |
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2015
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Patent Citations (6)
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| JP2008303263A (en) * | 2007-06-06 | 2008-12-18 | Teijin Ltd | Thermally conductive coating material |
| CN102827522A (en) * | 2012-09-03 | 2012-12-19 | 黑龙江省林城涂料有限公司 | Natural stone paint and preparation method thereof |
| CN104449159A (en) * | 2013-09-23 | 2015-03-25 | 青岛兴国涂料有限公司 | Environment-friendly nanometre ultraviolet-proof wall paint |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105400387A (en) * | 2015-12-17 | 2016-03-16 | 滁州市友邦涂装有限公司 | Bending-resistant powder coating |
| CN105505142A (en) * | 2015-12-17 | 2016-04-20 | 滁州市友邦涂装有限公司 | Super-weatherability powder coating for electrostatic spraying |
| CN105602413A (en) * | 2015-12-17 | 2016-05-25 | 滁州市友邦涂装有限公司 | Metallic powder for powder electrostatic spraying |
| CN107151113A (en) * | 2017-07-05 | 2017-09-12 | 合肥片美环保科技有限公司 | Preparation method of novel energy-saving environment-friendly building material |
| CN107382371A (en) * | 2017-08-23 | 2017-11-24 | 北京奥克森节能环保科技有限公司 | A kind of modifying agent and preparation method thereof |
| CN108250894A (en) * | 2017-12-13 | 2018-07-06 | 颍上永红建材有限公司 | A kind of flame-proof environmental protection building materials paint |
| CN107987649A (en) * | 2017-12-25 | 2018-05-04 | 韩昕冉 | A kind of anti-cracking resistance heat-insulating and fire-proof coating important composition component |
| CN108017968A (en) * | 2017-12-25 | 2018-05-11 | 韩昕冉 | A kind of anti-cracking resistance high temperature insulating thermal insulation coatings important composition component |
| CN107987650A (en) * | 2017-12-25 | 2018-05-04 | 张龙 | A kind of anti-cracking resistance thermal insulation coatings important composition component |
| CN108976923A (en) * | 2018-06-11 | 2018-12-11 | 成都兰腾科技有限公司 | A kind of hydrophobe hybrid cellular shape heat-conductive coating |
| CN109135472A (en) * | 2018-08-01 | 2019-01-04 | 浙江埃普瑞纳米材料有限公司 | The formula and preparation method thereof of Neon SiC powder coating |
| CN109097155A (en) * | 2018-09-13 | 2018-12-28 | 吴文林 | A kind of preparation method lubricating nanometer additive |
| CN109233522A (en) * | 2018-09-28 | 2019-01-18 | 佛山齐安建筑科技有限公司 | A kind of building material surface fireproof coating |
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| CN104877496B (en) | 2017-01-25 |
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