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CN104874941A - 一种耐蚀药芯焊丝 - Google Patents

一种耐蚀药芯焊丝 Download PDF

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Publication number
CN104874941A
CN104874941A CN201510227463.6A CN201510227463A CN104874941A CN 104874941 A CN104874941 A CN 104874941A CN 201510227463 A CN201510227463 A CN 201510227463A CN 104874941 A CN104874941 A CN 104874941A
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Prior art keywords
cored wire
flux
powder
corrosion
content
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Inventor
付伟
安毕军
张德远
刘小军
郭寅斌
李强
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Space Flight Kaihong Science & Technology Co Ltd Guizhou
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Space Flight Kaihong Science & Technology Co Ltd Guizhou
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3601Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0255Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
    • B23K35/0261Rods, electrodes, wires
    • B23K35/0266Rods, electrodes, wires flux-cored
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3601Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
    • B23K35/3603Halide salts
    • B23K35/3605Fluorides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3601Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
    • B23K35/3607Silica or silicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3601Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
    • B23K35/3608Titania or titanates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/368Selection of non-metallic compositions of core materials either alone or conjoint with selection of soldering or welding materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/40Making wire or rods for soldering or welding
    • B23K35/406Filled tubular wire or rods

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Nonmetallic Welding Materials (AREA)

Abstract

本发明公开了一种耐蚀药芯焊丝,包括钢皮和药粉,所述药粉由以下重量百分比的各组分混合而成:铁粉8-10%、硅锰合金25-30%、金红石18-20%、硅灰石3-5%、铬铁15-17%、石英8-9%、萤石0.3-1.5%、钛铁1-2%。通过加大金红石、石英的比例,有效的改善了焊接工艺性能,加入的硅灰石可以调整熔渣的粘度、熔点和表面张力,加入硅锰合金可以有效改善焊缝成型,铁粉的加入有助于提高熔敷效率,减少凹坑和气孔的数量,铬铁的加入主要是向焊缝金属过渡合金元素,萤石中的氟化钙可以改善熔渣的物化性能,加入的钛铁其含有的钛可以细化晶粒,有利于焊缝金属韧性的改善,通过本药粉制备出的药芯焊丝具有脱渣容易、电弧稳定、焊缝金属韧性高且耐腐蚀性强的特点。

Description

一种耐蚀药芯焊丝
技术领域
本发明涉及金属焊接材料技术领域,具体涉及一种耐蚀药芯焊丝。
背景技术
药芯焊丝也称为管状焊丝或粉芯焊丝,是20世纪50年代发展起来的高效率焊接材料,可以通过调整药芯添加物的种类和比例,很方便地设计各种不同用途的焊接材料,以适于不同工矿、不同条件设备部件的要求,用来焊接各种类型钢材。药芯焊丝既具有药皮焊条的配方可调性,同时又具有实芯焊丝连续焊接的特点。药芯焊丝正以其无可比拟的技术和经济性,受到国内外焊接界的极大关注。
随着焊接生产向高效率、低成本、高质量方向发展,药芯焊丝作为一种极有发展前途的焊接材料及高技术产品,在焊接材料中所占的比例越来越大,现有的药芯焊丝普遍存在、电弧不稳定、焊缝金属韧性低、耐腐蚀性差、不容易脱渣等问题。
发明内容
为解决上述技术问题,本发明提供了一种脱渣容易、电弧稳定、焊缝金属韧性高且耐腐蚀性较强的药芯焊丝。
本发明是通过以下技术方案予以实现的:
一种耐蚀药芯焊丝,包括钢皮和药粉,所述药粉由以下重量百分比的各组分混合而成:铁粉8-10%、硅锰合金25-30%、金红石18-20%、硅灰石3-5%、铬铁15-17%、石英8-9%、萤石0.3-1.5%、钛铁1-2%。
所述铁粉中Fe的含量≥98%。
所述硅锰合金中Si的含量为30-35%。
所述金红石中TiO2的含量≥96%。
所述硅灰石中CaSiO3的含量≥72%。
所述铬铁中铬的含量为70-74%。
所述石英中二氧化硅的含量≥98%。
所述萤石中氟化钙的含量≥97%。
所述钛铁中钛的含量为25-30%。
本发明的有益效果在于:通过加大金红石、石英的比例,有效的改善了焊接工艺性能,使得其电弧稳定性更好,加入的硅灰石可以调整熔渣的粘度、熔点和表面张力,加入硅锰合金可以有效改善焊缝成型,铁粉的加入有助于提高熔敷效率,减少凹坑和气孔的数量,铬铁的加入主要是向焊缝金属过渡合金元素,萤石中的氟化钙可以改善熔渣的物化性能,加入的钛铁其含有的钛可以细化晶粒,有利于焊缝金属韧性的改善,通过本药粉制备出的药芯焊丝具有脱渣容易、电弧稳定、焊缝金属韧性高且耐腐蚀性强的特点。
具体实施方式
以下结合具体实施例对本发明的技术方案作进一步描述,但要求保护的范围并不局限于所述。
实施例一
取500g混合物为例:铁粉40g、硅锰合金125g、金红石90g、硅灰石15g、铬铁75g、石英40g、萤石1.5g、钛铁5g。将各种粉末放入混粉机中混合45min,让后将粉末加入到钢皮中,填充率为18%,使药粉包裹在其中,然后通过拉丝机处理即得到本发明耐蚀药芯焊丝。
实施例二
取500g混合物为例:铁粉45g、硅锰合金140g、金红石95g、硅灰石20g、铬铁80g、石英42.5g、萤石4.5g、钛铁7.5g。将各种粉末放入混粉机中混合45min,让后将粉末加入到钢皮中,填充率为18%,使药粉包裹在其中,然后通过拉丝机处理即得到本发明耐蚀药芯焊丝。
实施例三
取500g混合物为例:铁粉50g、硅锰合金150g、金红石100g、硅灰石25g、铬铁85g、石英45g、萤石7.5g、钛铁10g。将各种粉末放入混粉机中混合45min,让后将粉末加入到钢皮中,填充率为18%,使药粉包裹在其中,然后通过拉丝机处理即得到本发明耐蚀药芯焊丝。
实施例四
取1000g混合物为例:铁粉80g、硅锰合金250g、金红石180g、硅灰石30g、铬铁150g、石英80g、萤石3g、钛铁10g。将各种粉末放入混粉机中混合45min,让后将粉末加入到钢皮中,填充率为19%,使药粉包裹在其中,然后通过拉丝机处理即得到本发明耐蚀药芯焊丝。
实施例五
取1000g混合物为例:铁粉90g、硅锰合金280g、金红石190g、硅灰石40g、铬铁160g、石英85g、萤石9g、钛铁15g。将各种粉末放入混粉机中混合45min,让后将粉末加入到钢皮中,填充率为19%,使药粉包裹在其中,然后通过拉丝机处理即得到本发明耐蚀药芯焊丝。
实施例六
取1000g混合物为例:铁粉100g、硅锰合金300g、金红石200g、硅灰石50g、铬铁170g、石英90g、萤石15g、钛铁20g。将各种粉末放入混粉机中混合45min,让后将粉末加入到钢皮中,填充率为19%,使药粉包裹在其中,然后通过拉丝机处理即得到本发明耐蚀药芯焊丝。

Claims (9)

1.一种耐蚀药芯焊丝,包括钢皮和药粉,其特征在于:所述药粉由以下重量百分比的各组分混合而成:铁粉8-10%、硅锰合金25-30%、金红石18-20%、硅灰石3-5%、铬铁15-17%、石英8-9%、萤石0.3-1.5%、钛铁1-2%。
2.根据权利要求1所述的耐蚀药芯焊丝,其特征在于:所述铁粉中Fe的含量≥98%。
3.根据权利要求1所述的耐蚀药芯焊丝,其特征在于:所述硅锰合金中Si的含量为30-35%。
4.根据权利要求1所述的耐蚀药芯焊丝,其特征在于:所述金红石中TiO2的含量≥96%。
5.根据权利要求1所述的耐蚀药芯焊丝,其特征在于:所述硅灰石中CaSiO3的含量≥72%。
6.根据权利要求1所述的耐蚀药芯焊丝,其特征在于:所述铬铁中铬的含量为70-74%。
7.根据权利要求1所述的耐蚀药芯焊丝,其特征在于:所述石英中二氧化硅的含量≥98%。
8.根据权利要求1所述的耐蚀药芯焊丝,其特征在于:所述萤石中氟化钙的含量≥97%。
9.根据权利要求1所述的耐蚀药芯焊丝,其特征在于:所述钛铁中钛的含量为25-30%。
CN201510227463.6A 2015-05-06 2015-05-06 一种耐蚀药芯焊丝 Pending CN104874941A (zh)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107498212A (zh) * 2017-10-18 2017-12-22 镇江市锶达合金材料有限公司 一种药性焊丝材料配方及其制造方法
CN111037153A (zh) * 2019-12-27 2020-04-21 中国第一重型机械集团大连加氢反应器制造有限公司 快中子反应堆设备制造用e316h型焊条

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Publication number Priority date Publication date Assignee Title
CN1603055A (zh) * 2004-11-15 2005-04-06 攀钢集团攀枝花钢铁研究院 一种支撑辊堆焊用药芯焊丝
CN101450425A (zh) * 2008-12-31 2009-06-10 宁波隆兴焊割科技股份有限公司 耐热钢药芯焊丝
EP2105243A1 (en) * 2008-03-26 2009-09-30 Nippon Steel & Sumikin Welding Co., Ltd. Metal-based flux cored wire for Ar-CO 2 mixed gas shielded arc welding
JP5153421B2 (ja) * 2008-04-07 2013-02-27 日鐵住金溶接工業株式会社 ガスシールドアーク溶接用フラックス入りワイヤ
CN103495817A (zh) * 2013-10-16 2014-01-08 宁波隆兴焊割科技股份有限公司 C02或80Ar+C02气体保护碱性焊药芯焊丝
CN103659039A (zh) * 2013-12-04 2014-03-26 宁波隆兴焊割科技股份有限公司 一种超音速火焰喷涂型药芯焊丝及其制备方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1603055A (zh) * 2004-11-15 2005-04-06 攀钢集团攀枝花钢铁研究院 一种支撑辊堆焊用药芯焊丝
EP2105243A1 (en) * 2008-03-26 2009-09-30 Nippon Steel & Sumikin Welding Co., Ltd. Metal-based flux cored wire for Ar-CO 2 mixed gas shielded arc welding
JP5153421B2 (ja) * 2008-04-07 2013-02-27 日鐵住金溶接工業株式会社 ガスシールドアーク溶接用フラックス入りワイヤ
CN101450425A (zh) * 2008-12-31 2009-06-10 宁波隆兴焊割科技股份有限公司 耐热钢药芯焊丝
CN103495817A (zh) * 2013-10-16 2014-01-08 宁波隆兴焊割科技股份有限公司 C02或80Ar+C02气体保护碱性焊药芯焊丝
CN103659039A (zh) * 2013-12-04 2014-03-26 宁波隆兴焊割科技股份有限公司 一种超音速火焰喷涂型药芯焊丝及其制备方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107498212A (zh) * 2017-10-18 2017-12-22 镇江市锶达合金材料有限公司 一种药性焊丝材料配方及其制造方法
CN111037153A (zh) * 2019-12-27 2020-04-21 中国第一重型机械集团大连加氢反应器制造有限公司 快中子反应堆设备制造用e316h型焊条

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Application publication date: 20150902