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CN104858959A - 一种木材防腐阻燃增强改性的生产方法 - Google Patents

一种木材防腐阻燃增强改性的生产方法 Download PDF

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CN104858959A
CN104858959A CN201410818869.7A CN201410818869A CN104858959A CN 104858959 A CN104858959 A CN 104858959A CN 201410818869 A CN201410818869 A CN 201410818869A CN 104858959 A CN104858959 A CN 104858959A
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/18Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/14Boron; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16Heavy metals; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/26Phosphorus; Compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/0207Pretreatment of wood before impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/0207Pretreatment of wood before impregnation
    • B27K3/0214Drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/08Impregnating by pressure, e.g. vacuum impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/52Impregnating agents containing mixtures of inorganic and organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/04Combined bleaching or impregnating and drying of wood

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

本发明公开了一种木材防腐阻燃增强改性的生产方法,包括木材预处理、配制木材改性剂、配制木材改性液、浸渍处理和后干燥处理五个步骤,其中所述木材改性剂是由正硅酸乙酯、聚乙二醇、磷酸、水、八硼酸钠、多菌灵、硼酸锌、钼酸铵和十二烷基苯磺酸钠配制而成。本发明的有益效果是,本发明具有处理工艺简单、高效、成本低、渗透性强等优点,而且以正硅酸乙酯为前驱体形成二氧化硅具有增韧补强、协效阻燃等作用,经过处理后的木材在防腐、阻燃、表面硬度、耐磨性、抗弯强度、抗弯弹性模量、加工良好特性、尺寸稳定性等方面均得到大幅提高。

Description

一种木材防腐阻燃增强改性的生产方法
技术领域
本发明涉及木材生产技术领域,具体地说是一种木材防腐阻燃增强改性的生产方法。
背景技术
木材作为一种天然可再生的资源,并具有纹理美观、色泽天然、质感舒适、可塑性好、易于加工等优点,因而被作为建筑装修和家具制造的理想材料。但木材由于长期与氧、光、湿气接触,容易干缩湿胀、尺寸稳定性差,而且易变色、开裂、磨损和挫伤,还容易燃烧和易被虫菌蛀蚀等。所以,对木材的改性处理长期以来一直受到广泛关注。传统对木材的改性方法主要有热处理和化学处理两种。热处理的方式安全无毒,但会使木材的组分发生不同程度的降解和结构变化,降低木材的力学强度,同时加深木材的材色,影响木材的美观感。化学处理采用处理药剂的方法,其成本低、工艺简单,但大多数药剂中所含的铜、铬、砷等重金属离子和氯、酚醛等化合物对环境和人畜都有潜在的危害。因此,研制一种无毒安全、并兼具防腐阻燃增强改性的木材生产方法,将具有重要的现实意义和推广前景。
发明内容
本发明的目的在于提供一种工艺简单、处理高效、环保的木材防腐阻燃增强改性的生产方法。
本发明解决其技术问题所采用的技术方案是:一种木材防腐阻燃增强改性的生产方法,包括以下步骤:
(1)、木材预处理:将原木去皮、切锯剖成所需尺寸的规格后,在50℃~80℃的条件下干燥8~24h,控制木材的含水率达8%~25%,然后微波处理10~30min;
(2)、配制木材改性剂:向反应容器依次加入正硅酸乙酯20~30质量份、聚乙二醇50~80质量份、磷酸1~2质量份,搅拌均匀,然后加入水300~450质量份,再加入八硼酸钠10~15质量份、多菌灵8~12质量份、硼酸锌6~10质量份、钼酸铵1~4质量份、十二烷基苯磺酸钠1~2质量份,使一起搅拌20~40min,待均匀分散后,即制得所用的木材改性剂;
(3)、配制木材改性液:将步骤(2)制得的木材改性剂用水稀释至质量百分比浓度为15%~30%的悬浮溶液,即得所需的木材改性液;
(4)、浸渍处理:将步骤(1)得到的木材放入密闭的浸渍处理罐中,抽真空使罐内真空度在-0.08~-0.1MPa,保持30~60min,再将步骤(3)配制的木材改性液注入浸渍处理罐中,并使完全淹没木材,然后解除真空,向处理罐内施加0.6~1.5MPa气压,保持1~4h;
(5)、后干燥处理:解除压力,排出剩余的改性液,取出木材水洗,风干至表面无明显水迹残留,再移至干燥窑进行烘干,干燥温度90℃~115℃,干燥时间12~36h,然后冷却至室温,即得到含水率为5%~15%的改性木材。
本发明的有益效果是,本发明具有处理工艺简单、高效、成本低、渗透性强等优点,而且以正硅酸乙酯为前驱体形成二氧化硅具有增韧补强、协效阻燃等作用,经过处理后的木材在防腐、阻燃、表面硬度、耐磨性、抗弯强度、抗弯弹性模量、加工良好特性、尺寸稳定性等方面均得到大幅提高。
具体实施方式
下面结合具体的优选实施例来进一步说明本发明的技术方案。
一种木材防腐阻燃增强改性的生产方法,包括以下步骤:
(1)、木材预处理:将原木去皮、切锯剖成所需尺寸的规格后,在50℃~80℃的条件下干燥8~24h,控制木材的含水率达8%~25%,然后微波处理10~30min;
(2)、配制木材改性剂:向反应容器依次加入正硅酸乙酯20~30质量份、聚乙二醇50~80质量份、磷酸1~2质量份,搅拌均匀,然后加入水300~450质量份,再加入八硼酸钠10~15质量份、多菌灵8~12质量份、硼酸锌6~10质量份、钼酸铵1~4质量份、十二烷基苯磺酸钠1~2质量份,使一起搅拌20~40min,待均匀分散后,即制得所用的木材改性剂;
(3)、配制木材改性液:将步骤(2)制得的木材改性剂用水稀释至质量百分比浓度为15%~30%的悬浮溶液,即得所需的木材改性液;
(4)、浸渍处理:将步骤(1)得到的木材放入密闭的浸渍处理罐中,抽真空使罐内真空度在-0.08~-0.1MPa,保持30~60min,再将步骤(3)配制的木材改性液注入浸渍处理罐中,并使完全淹没木材,然后解除真空,向处理罐内施加0.6~1.5MPa气压,保持1~4h;
(5)、后干燥处理:解除压力,排出剩余的改性液,取出木材水洗,风干至表面无明显水迹残留,再移至干燥窑进行烘干,干燥温度90℃~115℃,干燥时间12~36h,然后冷却至室温,即得到含水率为5%~15%的改性木材。

Claims (1)

1.一种木材防腐阻燃增强改性的生产方法,其特征在于,包括以下步骤:
(1)、木材预处理:将原木去皮、切锯剖成所需尺寸的规格后,在50℃~80℃的条件下干燥8~24h,控制木材的含水率达8%~25%,然后微波处理10~30min;
(2)、配制木材改性剂:向反应容器依次加入正硅酸乙酯20~30质量份、聚乙二醇50~80质量份、磷酸1~2质量份,搅拌均匀,然后加入水300~450质量份,再加入八硼酸钠10~15质量份、多菌灵8~12质量份、硼酸锌6~10质量份、钼酸铵1~4质量份、十二烷基苯磺酸钠1~2质量份,使一起搅拌20~40min,待均匀分散后,即制得所用的木材改性剂;
(3)、配制木材改性液:将步骤(2)制得的木材改性剂用水稀释至质量百分比浓度为15%~30%的悬浮溶液,即得所需的木材改性液;
(4)、浸渍处理:将步骤(1)得到的木材放入密闭的浸渍处理罐中,抽真空使罐内真空度在-0.08~-0.1MPa,保持30~60min,再将步骤(3)配制的木材改性液注入浸渍处理罐中,并使完全淹没木材,然后解除真空,向处理罐内施加0.6~1.5MPa气压,保持1~4h;
(5)、后干燥处理:解除压力,排出剩余的改性液,取出木材水洗,风干至表面无明显水迹残留,再移至干燥窑进行烘干,干燥温度90℃~115℃,干燥时间12~36h,然后冷却至室温,即得到含水率为5%~15%的改性木材。
CN201410818869.7A 2014-12-25 2014-12-25 一种木材防腐阻燃增强改性的生产方法 Pending CN104858959A (zh)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106042118A (zh) * 2016-07-14 2016-10-26 阜南县宏泰工艺品有限公司 一种增强增韧柳编用柳条溶胶‑凝胶表面处理剂及其制备方法
CN107718205A (zh) * 2017-09-12 2018-02-23 海宁恒森家具有限公司 一种保健木材的制作方法
CN112248162A (zh) * 2020-10-20 2021-01-22 海南博展实业有限公司 一种木材防腐改性液及其制备方法
CN115256578A (zh) * 2022-07-27 2022-11-01 李开天 一种木材防腐阻燃剂及其制备方法和应用方法

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106042118A (zh) * 2016-07-14 2016-10-26 阜南县宏泰工艺品有限公司 一种增强增韧柳编用柳条溶胶‑凝胶表面处理剂及其制备方法
CN107718205A (zh) * 2017-09-12 2018-02-23 海宁恒森家具有限公司 一种保健木材的制作方法
CN107718205B (zh) * 2017-09-12 2019-02-22 海宁恒森家具有限公司 一种保健木材的制作方法
CN112248162A (zh) * 2020-10-20 2021-01-22 海南博展实业有限公司 一种木材防腐改性液及其制备方法
CN115256578A (zh) * 2022-07-27 2022-11-01 李开天 一种木材防腐阻燃剂及其制备方法和应用方法

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