CN104830180A - Waterborne anticorrosive coating - Google Patents
Waterborne anticorrosive coating Download PDFInfo
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- CN104830180A CN104830180A CN201510277593.0A CN201510277593A CN104830180A CN 104830180 A CN104830180 A CN 104830180A CN 201510277593 A CN201510277593 A CN 201510277593A CN 104830180 A CN104830180 A CN 104830180A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0881—Titanium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/329—Phosphorus containing acids
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- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a waterborne anticorrosive coating. The waterborne anticorrosive coating comprises, by weight, 15-35 parts of water, 15-30 parts of acrylic emulsion, 0.3-0.7 part of dispersant, 0.1-0.5 part of wetting agent, 0.2-0.4 part of defoamer, 5-10 parts of high-titanium powder, 5-10 parts of feldspar powder, 5-15 parts of talcum powder, 0.1-0.3 part of sodium pyrophosphate, 0.1-0.4 part of nanosilicon dioxide, 0.1-0.2 part of aseptic and 0.1-0.2 part of antibacterial agent. The waterborne anticorrosive coating is reasonable in composition and low in cost, various components are good in compatibility, and the waterborne anticorrosive coating is environment friendly, mildewproof and anti-bacteria and has excellent application value. Natural antibacterial agent and inorganic antibacterial agent are mixed, and mildewproof effect is long lasting. The waterborne anticorrosive coating is short in film drying time and good in firmness and has excellent extending performance and heat-resistant performance.
Description
Technical field
The invention belongs to technical field of coatings, be specifically related to a kind of water-based anticorrosive paint.
Background technology
Water-borne coatings is the technology grown up in the sixties in last century, with the coating of water as dispersion medium and thinner, compared with the coating of organic solvent type, a large amount of organic materials resources saved by water-borne coatings, greatly reduces the volatilization of organic solvent in coating to the fire hazard in the pollution of air and construction process, and water is extremely rich in natural resources on the earth, it takes conveniently, with low cost, use as the solvent in coating, destruction or less can not be produced to water resources.Therefore water-borne coatings had both decreased the discharge of volatile organic solvent, again can saving resource, the energy, simultaneously convenient transport and storage.Along with the enhancing of people's environmental consciousness, the usage quantity of water-borne coatings increases year by year, will become the main flow direction of modern coatings industrial development gradually.
The water-borne coatings used in the market; when mostly there is film forming, time of drying is long; be coated with film elasticity easily aging; flintiness is bad, and water soluble paint subjects to biological damage, and the generation due to bacterium depends on the environment of water; therefore; existing water soluble paint is easy to occur going mouldy mostly, and its anticorrosion and uniform ideal of wear resisting property, effectively can not protect relevant device.
Summary of the invention
For the defect existed in prior art, the object of this invention is to provide a kind of water-based anticorrosive paint.
Described a kind of water-based anticorrosive paint, is characterized in that this water-based anticorrosive paint is made up of the component of following weight part: water 15-35 part, ACRYLIC EMULSION 15-30 part, dispersion agent 0.3-0.7 part, wetting agent 0.1-0.5 part, defoamer 0.2-0.4 part, high titanium valve 5-10 part, Feldspar Powder 5-10 part, talcum powder 5-15 part, trisodium phosphate 0.1-0.3 part, nano silicon 0.1-0.4 part, sanitas 0.1-0.2 part, antiseptic-germicide 0.1-0.2 part.
Described described a kind of water-based anticorrosive paint, is characterized in that this water-based anticorrosive paint is made up of the component of following weight part: water 20-30 part, ACRYLIC EMULSION 20-25 part, dispersion agent 0.4-0.6 part, wetting agent 0.2-0.4 part, defoamer 0.2-0.3 part, high titanium valve 6-8 part, Feldspar Powder 6-8 part, talcum powder 8-12 part, trisodium phosphate 0.2-0.3 part, nano silicon 0.2-0.3 part, sanitas 0.1-0.2 part, antiseptic-germicide 0.1-0.2 part.
Described a kind of water-based anticorrosive paint, is characterized in that described water-based anticorrosive paint is made up of the component of following weight part: 25 parts, water, ACRYLIC EMULSION 22 parts, dispersion agent 0.5 part, wetting agent 0.3 part, defoamer 0.2 part, high titanium valve 7 parts, Feldspar Powder 7 parts, talcum powder 10 parts, trisodium phosphate 0.3 part, nano silicon 0.3 part, sanitas 0.2 part, antiseptic-germicide 0.2 part.
Described a kind of water-based anticorrosive paint, is characterized in that described antiseptic-germicide is that natural antibacterial agent and inorganic antiseptic mix with the weight of 1:1.
Described a kind of water-based anticorrosive paint, is characterized in that described natural antibacterial agent is Folium Bambosae extract, tea leaf extract, Pericarpium Granati extract, Aloe extract mix with the weight of 0.5:0.5:1:1.
Described a kind of water-based anticorrosive paint, is characterized in that described inorganic antiseptic is the mixture of bentonite bactericidal agent and montmorillonite germicide, and the weight ratio of described bentonite bactericidal agent and montmorillonite germicide is 1:1.
Wetting agent of the present invention adopts the wetting agent D-504 of low bubble performance, transparent yellow liquid, uses in formula with other components matching, has certain froth breaking and presses down bubble effect, can improve the flow leveling of product simultaneously; Defoamer adopts mineral oil antifoam agent, and defoaming capacity is strong, is easy to other batching mixing, can not causes side reaction, with wetting agent with the use of reaching better wetting effect in film process.
The use of antiseptic-germicide of the present invention, can the generation of effective mould fungus inhibition, and fungistatic effect is lasting, and this antiseptic-germicide environmental protection, can not to environment.
Compared with prior art, the present invention has following beneficial effect:
1, coating disclosed by the invention composition rationally, and cost is low, and between each component, consistency is good, environmental protection, mildew-resistant, antibacterial, has excellent using value;
2, natural antibacterial agent of the present invention and inorganic antiseptic is used in combination, namely avoids and uses merely the problem of the poor stability existing for natural antibacterial agent or be used alone the pollution that organic antibacterial agent brings and the high cost problem being used alone inorganic antiseptic; Combinationally use its anti-mold effect more lasting;
3, water-borne coatings film forming of the present invention is short for time of drying, and flintiness is good, also has good extension property and resistance toheat simultaneously.
Embodiment
The present invention is described in further detail below in conjunction with embodiment.
Embodiment 1
A kind of water-based anticorrosive paint, is made up of the component of following weight part: 25 parts, water, ACRYLIC EMULSION 22 parts, dispersion agent 0.5 part, wetting agent 0.3 part, defoamer 0.2 part, high titanium valve 7 parts, Feldspar Powder 7 parts, talcum powder 10 parts, trisodium phosphate 0.3 part, nano silicon 0.3 part, sanitas 0.2 part, antiseptic-germicide 0.2 part.Wherein, antiseptic-germicide is that natural antibacterial agent and inorganic antiseptic mix with the weight of 1:1, and natural antibacterial agent is Folium Bambosae extract, tea leaf extract, Pericarpium Granati extract, Aloe extract mix with the weight of 0.5:0.5:1:1; Inorganic antiseptic is the mixture of bentonite bactericidal agent and montmorillonite germicide, and the weight ratio of bentonite bactericidal agent and montmorillonite germicide is 1:1.The each composition of natural antibacterial agent and each composition of inorganic antiseptic all can be bought by market and obtain.
Embodiment 2
A kind of water-based anticorrosive paint, is made up of the component of following weight part: 35 parts, water, ACRYLIC EMULSION 15 parts, dispersion agent 0.7 part, wetting agent 0.1 part, defoamer 0.4 part, high titanium valve 5 parts, Feldspar Powder 10 parts, talcum powder 5 parts, trisodium phosphate 0.3 part, nano silicon 0.1 part, sanitas 0.2 part, antiseptic-germicide 0.1 part.Wherein, antiseptic-germicide is that natural antibacterial agent and inorganic antiseptic mix with the weight of 1:1, and natural antibacterial agent is Folium Bambosae extract, tea leaf extract, Pericarpium Granati extract, Aloe extract mix with the weight of 0.5:0.5:1:1; Inorganic antiseptic is the mixture of bentonite bactericidal agent and montmorillonite germicide, and the weight ratio of bentonite bactericidal agent and montmorillonite germicide is 1:1.The each composition of natural antibacterial agent and each composition of inorganic antiseptic all can be bought by market and obtain.
Embodiment 3
A kind of water-based anticorrosive paint, is made up of the component of following weight part: 20 parts, water, ACRYLIC EMULSION 25 parts, dispersion agent 0.6 part, wetting agent 0.2 part, defoamer 0.3 part, high titanium valve 6 parts, Feldspar Powder 8 parts, talcum powder 8 parts, trisodium phosphate 0.2 part, nano silicon 0.2 part, sanitas 0.1 part, antiseptic-germicide 0.1 part.Wherein, antiseptic-germicide is that natural antibacterial agent and inorganic antiseptic mix with the weight of 1:1, and natural antibacterial agent is Folium Bambosae extract, tea leaf extract, Pericarpium Granati extract, Aloe extract mix with the weight of 0.5:0.5:1:1; Inorganic antiseptic is the mixture of bentonite bactericidal agent and montmorillonite germicide, and the weight ratio of bentonite bactericidal agent and montmorillonite germicide is 1:1.The each composition of natural antibacterial agent and each composition of inorganic antiseptic all can be bought by market and obtain.
Performance test
Test the VOC content of above-mentioned coating according to GB18582-2008, test the sticking power of above-mentioned coating, time of drying and impact resistance according to GB1720, GB1728, GB1732, the results are shown in Table 1.
Table 1 performance test
Sterilant is tested: intestinal bacteria, black-koji mould are spread evenly across and scribble on the slide glass of above-mentioned coating, after 0,5,15,30,60,120 hour, be gently stained with bacterium liquid by swab stick is placed in physiological saline, vibration, get 0.5ml in culture dish, add substratum, cultivate 48 hours in incubator, take out number colony number, according to formulae discovery sterilizing rate: sterilizing rate=(after initial colony number-sterilization colony number)/initial colony number × 100%, the results are shown in Table 2.
Table 2 sterilization is tested
As can be seen from table 1 and table 2, coating antibiosis fungicidal properties of the present invention is good, environmental protection, solidification are quick, has excellent flame retardant properties, is applicable to applying.
To adopting the water-based anticorrosive paint of embodiment 1 formula preparation to carry out antiseptic property detection, detected result is in table 3.
Table 3: antiseptic property detected result of the present invention
As shown in Table 3: adopt the present invention fill a prescription preparation water-based anticorrosive paint there is higher resisting salt fog corrosion ability, favorable anti-corrosion effect.
Claims (6)
1. a water-based anticorrosive paint, is characterized in that this water-based anticorrosive paint is made up of the component of following weight part: water 15-35 part, ACRYLIC EMULSION 15-30 part, dispersion agent 0.3-0.7 part, wetting agent 0.1-0.5 part, defoamer 0.2-0.4 part, high titanium valve 5-10 part, Feldspar Powder 5-10 part, talcum powder 5-15 part, trisodium phosphate 0.1-0.3 part, nano silicon 0.1-0.4 part, sanitas 0.1-0.2 part, antiseptic-germicide 0.1-0.2 part.
2. a kind of water-based anticorrosive paint according to claim 1, is characterized in that this water-based anticorrosive paint is made up of the component of following weight part: water 20-30 part, ACRYLIC EMULSION 20-25 part, dispersion agent 0.4-0.6 part, wetting agent 0.2-0.4 part, defoamer 0.2-0.3 part, high titanium valve 6-8 part, Feldspar Powder 6-8 part, talcum powder 8-12 part, trisodium phosphate 0.2-0.3 part, nano silicon 0.2-0.3 part, sanitas 0.1-0.2 part, antiseptic-germicide 0.1-0.2 part.
3. a kind of water-based anticorrosive paint according to claim 1 and 2, is characterized in that described water-based anticorrosive paint is made up of the component of following weight part: 25 parts, water, ACRYLIC EMULSION 22 parts, dispersion agent 0.5 part, wetting agent 0.3 part, defoamer 0.2 part, high titanium valve 7 parts, Feldspar Powder 7 parts, talcum powder 10 parts, trisodium phosphate 0.3 part, nano silicon 0.3 part, sanitas 0.2 part, antiseptic-germicide 0.2 part.
4. a kind of water-based anticorrosive paint according to claim 1 or 2 or 3, is characterized in that described antiseptic-germicide is that natural antibacterial agent and inorganic antiseptic mix with the weight of 1:1.
5. a kind of water-based anticorrosive paint according to claim 4, is characterized in that described natural antibacterial agent is Folium Bambosae extract, tea leaf extract, Pericarpium Granati extract, Aloe extract mix with the weight of 0.5:0.5:1:1.
6. a kind of water-based anticorrosive paint according to claim 4, is characterized in that described inorganic antiseptic is the mixture of bentonite bactericidal agent and montmorillonite germicide, and the weight ratio of described bentonite bactericidal agent and montmorillonite germicide is 1:1.
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CN201510277593.0A CN104830180A (en) | 2015-05-27 | 2015-05-27 | Waterborne anticorrosive coating |
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CN201510277593.0A CN104830180A (en) | 2015-05-27 | 2015-05-27 | Waterborne anticorrosive coating |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105017876A (en) * | 2015-08-26 | 2015-11-04 | 湖州大周高分子材料有限公司 | Antibacterial and flame-retardant coating |
CN108610820A (en) * | 2018-05-23 | 2018-10-02 | 扬州工业职业技术学院 | A kind of water-based paint compositions |
CN111087870A (en) * | 2019-12-23 | 2020-05-01 | 普施耐(苏州)工业技术有限公司 | High-adhesion high-titanium-base bottom coating and preparation method thereof |
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CN104017445A (en) * | 2014-06-06 | 2014-09-03 | 湖州百胜涂料有限公司 | Water-based coating |
CN104017446A (en) * | 2014-06-06 | 2014-09-03 | 湖州百胜涂料有限公司 | Environment-friendly coating |
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CN104017445A (en) * | 2014-06-06 | 2014-09-03 | 湖州百胜涂料有限公司 | Water-based coating |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105017876A (en) * | 2015-08-26 | 2015-11-04 | 湖州大周高分子材料有限公司 | Antibacterial and flame-retardant coating |
CN108610820A (en) * | 2018-05-23 | 2018-10-02 | 扬州工业职业技术学院 | A kind of water-based paint compositions |
CN111087870A (en) * | 2019-12-23 | 2020-05-01 | 普施耐(苏州)工业技术有限公司 | High-adhesion high-titanium-base bottom coating and preparation method thereof |
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Application publication date: 20150812 |