CN104789391A - Fully-biodegradable detergent containing orange oil and preparation method thereof - Google Patents
Fully-biodegradable detergent containing orange oil and preparation method thereof Download PDFInfo
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- CN104789391A CN104789391A CN201510131356.3A CN201510131356A CN104789391A CN 104789391 A CN104789391 A CN 104789391A CN 201510131356 A CN201510131356 A CN 201510131356A CN 104789391 A CN104789391 A CN 104789391A
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Abstract
The invention relates to a fully-biodegradable detergent containing orange oil and a preparation method thereof. The detergent comprises the following raw materials in parts by weight: 10-25 parts of orange oil, 10-25 parts of lauryl sodium sulfate, 4-15 parts of fatty alcohol-polyoxyethylene ether, 10-20 parts of lauryl/myristyl polyoxyethylene ether sodium (AES-Na(EO=3)), 10-20 parts of ethyl alcohol and 100 parts of softened water, wherein the content of limonene in the orange oil is higher than 80%. The detergent is prepared by taking the orange oil with an 80% or higher concentration of limonene as the main component and compounding the orange oil with a plurality of surfactants; the detergent is relatively low in surface tension, so that the detergent can be used for effectively removing organic oil stain, and the corrosion to the surfaces of washed objects is avoided.
Description
Technical field
the invention belongs to technical field of fine, be specifically related to a kind of using natural phant as main raw material containing the degradable type sanitising agent of biology of mandarin oil and preparation method.
Background technology
in the process that the environment of human survival contacts with the medium, raw materials for production, dust, mechanical greasy dirt etc. that are discharged into air in commercial process, due to occur physics, chemistry and electrochemistry or biological effect, remain, deposit and generate the various dirt harmful to production run, quality product or health of human body in the environmental surfaces of its attachment, become dirt.These dirts must be removed in time, and its method removed can adopt physics, chemistry or biological method, no matter which kind of method, environmental requirement must not have secondary pollution, accomplishes nontoxic and safety.Vegetalitas solvent can the purification agent prepared of degradable emulsifying agent as main component complex biological, meets eco-friendly condition.
mandarin oil is as one of vegetalitas solvent, belong to oil-soluble substance, the most outstanding feature is the excellent organic fouling performance of removal, to human body and environment without any pollution, biodegradable, can substitute the current chemical solvents generally used, reduce environmental pollution, people are devoted to research and development and the improvement of this series products always nearly ten years.
the patent No. is 200610015634X, name is called in the patent of invention of a kind of airstrip greasy dirt detergent and preparation method thereof that disclosing clean-out system is made up of the following raw material with parts by weight: 70 ~ 80 parts of mandarin oils, 10 ~ 15 parts of Sodium dodecylbenzene sulfonatees, 12 ~ 20 parts of potassium pyrophosphates, 1 ~ 3 part of trolamine and 100 parts of deionized waters form, in mandarin oil, limonene content is more than 80%, but composition potassium pyrophosphate wherein and trolamine have a certain impact to environment.
the patent No. is 201210288167.3, name is called that disclosing sanitising agent in a kind of patent of invention of the environment-friendly type sanitising agent containing mandarin oil is made up of the following raw material with parts by weight: 20 ~ 30 parts of mandarin oils, 30 ~ 50 parts of sodium lauryl sulphate, 10 ~ 20 parts of fatty alcohol-polyoxyethylene ether, 10 ~ 20 parts of alkyl glycoside, 10 ~ 20 parts of ethanol and 100 parts of deionized water compositions, fatty alcohol-polyoxyethylene ether is selected from AE03, AE04, AE05, AE06, AE07, any one in AE08 and AE09, in mandarin oil, limonene content is more than 80%, but there is the unsatisfactory part of cost value in composition alkyl glycoside wherein.
Summary of the invention
technical problem to be solved by this invention overcomes the deficiencies in the prior art, a kind of fully biodegradable is provided, surface tension is low, and detersive power is good, and pH value belongs to neutral and surface to be cleaned do not had to the degradable type sanitising agent of biology containing mandarin oil and the preparation method of secondary damage and pollution.
for solving above technical problem, a kind of technical scheme that the present invention takes is:
containing the degradable type sanitising agent of biology of mandarin oil, be made up of the following raw material with parts by weight:
mandarin oil 10 ~ 25
sodium lauryl sulphate 10 ~ 25
fatty alcohol-polyoxyethylene ether 4 ~ 15
lauryl/myristyl polyethenoxy ether sodium sulfate (AES-Na (EO=3)) 10 ~ 20
ethanol 10 ~ 20
softening water 100
in mandarin oil, limonene content is more than 80%.
preferably, the pH value containing the degradable type sanitising agent of biology of mandarin oil is 5 ~ 6.
preferably, fatty alcohol-polyoxyethylene ether is selected from any one in AE03, AE04, AE05, AE06, AE07, AE08 and AE09.
preferably, the surface tension of the degradable type sanitising agent of the biology containing mandarin oil is 22.23 ± 0.01 ~ 20.00 mN/m when room temperature, and solvent viscosity is 2.000 ~ 1.550 mm
2
/ s, flash-point (remaining silent) is 100 DEG C.
the another kind of technical scheme that the present invention takes is:
containing a preparation method for the degradable type sanitising agent of biology of mandarin oil, comprise the following steps:
(1) mixing adding in container successively according to the fatty alcohol-polyoxyethylene ether of above-mentioned parts by weight, lauryl/myristyl polyethenoxy ether sodium sulfate (AES-Na (EO=3)) and mandarin oil, stirring 50 ~ 70 minutes under the rotating speed of the temperature of 30 DEG C ~ 60 DEG C and 1000 ~ 6000rpm;
(2) sodium lauryl sulphate according to above-mentioned parts by weight is joined in container, stir 30 ~ 50 minutes under the rotating speed of 1000 ~ 6000rpm;
(3) finally the softening water according to above-mentioned parts by weight is added in container with the speed of 20ml/10mins at the temperature of 40 DEG C ~ 50 DEG C, then the ethanol according to above-mentioned parts by weight is added, stir 20 ~ 40 minutes under the rotating speed of 1000 ~ 6000rpm, mixing terminates to be cooled to by solution the temperature of 20 ~ 25 DEG C namely to obtain the described degradable type sanitising agent of biology containing mandarin oil.
due to the employing of above technical scheme, the present invention compared with prior art tool has the following advantages:
1, sanitising agent of the present invention utilizes the mandarin oil containing more than 80% limonene as main component, and it is composite and make with kinds of surface promoting agent, it has lower surface tension, thus can effectively remove organic greasy dirt, and not corrode the surface of cleaned material;
2, because mandarin oil refines in the orange skin being subordinated to natural phant to form, thus its to environment and HUMAN HEALTH harmless, and complete biodegradable and do not burn, do not explode, thus uses fool proof;
3, sanitising agent rate of volatilization of the present invention is relatively low, so can be reclaimed after clean-out operation, and through distillation after Reusability, therefore, it is possible to reduce costs.
Embodiment
below in conjunction with specific embodiment, the invention will be further described.
embodiment 1
(1) 10 parts of fatty alcohol-polyoxyethylene ether (AEO3), 10 parts of lauryl/myristyl polyethenoxy ether sodium sulfates (AES-Na (EO=3)) and 20 parts of mandarin oils are added in container successively mix, stir 50 minutes under the rotating speed of the temperature of 30 DEG C and 6000rpm;
(2) 10 parts of sodium lauryl sulphate are joined in container, stir 50 minutes under the rotating speed of 1000rpm;
(3) finally 100 parts of softening waters are added in container with the speed of 20ml/10mins at the temperature of 40 DEG C, then 10 parts of ethanol are added, stir 20 minutes under the rotating speed of 6000rpm, mixing terminates to be cooled to by solution the temperature of 20 ~ 25 DEG C namely to obtain the described degradable type sanitising agent of biology containing mandarin oil.
embodiment 2
(1) 8 parts of fatty alcohol-polyoxyethylene ether (AEO4), 12 parts of lauryl/myristyl polyethenoxy ether sodium sulfates (AES-Na (EO=3)) and 25 parts of mandarin oils are added in container successively mix, stir 60 minutes under the rotating speed of the temperature of 40 DEG C and 2000rpm;
(2) 15 parts of sodium lauryl sulphate are joined in container, stir 30 minutes under the rotating speed of 4000rpm;
(3) finally 100 parts of softening waters are added in container with the speed of 20ml/10mins at the temperature of 50 DEG C, then 10 parts of ethanol are added, stir 30 minutes under the rotating speed of 3000rpm, mixing terminates to be cooled to by solution the temperature of 20 ~ 25 DEG C namely to obtain the described degradable type sanitising agent of biology containing mandarin oil.
embodiment 3
(1) 15 parts of fatty alcohol-polyoxyethylene ether (AEO5), 15 parts of lauryl/myristyl polyethenoxy ether sodium sulfates (AES-Na (EO=3)) and 15 parts of mandarin oils are added in container successively mix, stir 60 minutes under the rotating speed of the temperature of 50 DEG C and 2000rpm;
(2) 18 parts of sodium lauryl sulphate are joined in container, stir 40 minutes under the rotating speed of 3000rpm;
(3) finally 100 parts of softening waters are added in container with the speed of 20ml/10mins at the temperature of 50 DEG C, then 20 parts of ethanol are added, stir 30 minutes under the rotating speed of 3000rpm, mixing terminates to be cooled to by solution the temperature of 20 ~ 25 DEG C namely to obtain the described degradable type sanitising agent of biology containing mandarin oil.
embodiment 4
(1) 12 parts of fatty alcohol-polyoxyethylene ether (AEO6), 20 parts of lauryl/myristyl polyethenoxy ether sodium sulfates (AES-Na (EO=3)) and 10 parts of mandarin oils are added in container successively mix, stir 60 minutes under the rotating speed of the temperature of 40 DEG C and 2000rpm;
(2) 12 parts of sodium lauryl sulphate are joined in container, stir 30 minutes under the rotating speed of 4000rpm;
(3) finally 100 parts of softening waters are added in container with the speed of 20ml/10mins at the temperature of 40 DEG C, then 15 parts of ethanol are added, stir 40 minutes under the rotating speed of 1000rpm, mixing terminates to be cooled to by solution the temperature of 20 ~ 25 DEG C namely to obtain the described degradable type sanitising agent of biology containing mandarin oil.
embodiment 5
(1) 10 parts of fatty alcohol-polyoxyethylene ether (AEO7), 11 parts of lauryl/myristyl polyethenoxy ether sodium sulfates (AES-Na (EO=3)) and 22 parts of mandarin oils are added in container successively mix, stir 60 minutes under the rotating speed of the temperature of 40 DEG C and 2000rpm;
(2) 8 parts of sodium lauryl sulphate are joined in container, stir 30 minutes under the rotating speed of 4000rpm;
(3) finally 100 parts of softening waters are added in container with the speed of 20ml/10mins at the temperature of 50 DEG C, then 10 parts of ethanol are added, stir 30 minutes under the rotating speed of 3000rpm, mixing terminates to be cooled to by solution the temperature of 20 ~ 25 DEG C namely to obtain the described degradable type sanitising agent of biology containing mandarin oil.
embodiment 6
(1) 13 parts of fatty alcohol-polyoxyethylene ether (AEO8), 18 parts of lauryl/myristyl polyethenoxy ether sodium sulfates (AES-Na (EO=3)) and 18 parts of mandarin oils are added in container successively mix, stir 60 minutes under the rotating speed of the temperature of 40 DEG C and 2000rpm;
(2) 10 parts of sodium lauryl sulphate are joined in container, stir 30 minutes under the rotating speed of 4000rpm;
(3) finally 100 parts of softening waters are added in container with the speed of 20ml/10mins at the temperature of 50 DEG C, then 10 parts of ethanol are added, stir 30 minutes under the rotating speed of 3000rpm, mixing terminates to be cooled to by solution the temperature of 20 ~ 25 DEG C namely to obtain the described degradable type sanitising agent of biology containing mandarin oil.
embodiment 7
(1) 4 parts of fatty alcohol-polyoxyethylene ether (AEO9), 10 parts of lauryl/myristyl polyethenoxy ether sodium sulfates (AES-Na (EO=3)) and 10 parts of mandarin oils are added in container successively mix, stir 40 minutes under the rotating speed of the temperature of 30 DEG C and 6000rpm;
(2) 10 parts of sodium lauryl sulphate are joined in container, stir 40 minutes under the rotating speed of 3000rpm;
(3) finally 100 parts of softening waters are added in container with the speed of 20ml/10mins at the temperature of 50 DEG C, then 10 parts of ethanol are added, stir 30 minutes under the rotating speed of 3000rpm, mixing terminates to be cooled to by solution the temperature of 20 ~ 25 DEG C namely to obtain the described degradable type sanitising agent of biology containing mandarin oil.
embodiment 8
(1) 15 parts of fatty alcohol-polyoxyethylene ether (AEO6), 20 parts of lauryl/myristyl polyethenoxy ether sodium sulfates (AES-Na (EO=3)) and 25 parts of mandarin oils are added in container successively mix, stir 60 minutes under the rotating speed of the temperature of 60 DEG C and 1000rpm;
(2) 25 parts of sodium lauryl sulphate are joined in container, stir 50 minutes under the rotating speed of 2000rpm;
(3) finally 100 parts of softening waters are added in container with the speed of 20ml/10mins at the temperature of 40 DEG C, then 20 parts of ethanol are added, stir 20 minutes under the rotating speed of 6000rpm, mixing terminates to be cooled to by solution the temperature of 20 ~ 25 DEG C namely to obtain the described degradable type sanitising agent of biology containing mandarin oil.
in the present invention, in mandarin oil, limonene content is more than 80%, and the pH value of the degradable type sanitising agent of the biology containing mandarin oil is 5 ~ 6.
in the present invention, the present invention is 22.23 ± 0.01 ~ 20.00 mN/m when room temperature containing the surface tension of the degradable type sanitising agent of biology of mandarin oil, and solvent viscosity is 2.000 ~ 1.550 mm
2
/ s, flash-point (remaining silent) is 100 DEG C.
sanitising agent of the present invention utilizes the mandarin oil containing more than 80% limonene as main component, and it is composite and make with kinds of surface promoting agent, it has lower surface tension, thus can effectively remove organic greasy dirt, and not corrode the surface of cleaned material.
when utilizing sanitising agent wipe oil provided by the invention, use after adopting dilute with water suitable proportion according to the contaminated degree difference of greasy dirt to solvent, after general dilution, detergent contents is 5% ~ 70%.Concrete using method: when such as cleaning the greasy dirt on airstrip, adopt airport combined machine, poured into by sanitising agent in work car tank, sprays clean-out system-polish-brush-absorption and reclaims-rinse recovery-wiped clean, fulfil assignment in 5 ~ 10 minutes.If other industry and domestic pollutant sanitising agent can be sprayed directly on dirt soaked for 5 seconds after direct friction remove.
above to invention has been detailed description; the explanation of embodiment just understands method of the present invention and core concept thereof for helping; its object is to allow the personage being familiar with this art can understand content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalences done according to spirit of the present invention change or modify, and all should be encompassed within protection scope of the present invention.
Claims (5)
1., containing the degradable type sanitising agent of biology of mandarin oil, it is characterized in that: be made up of the following raw material with parts by weight:
Mandarin oil 10 ~ 25
Sodium lauryl sulphate 10 ~ 25
Fatty alcohol-polyoxyethylene ether 4 ~ 15
Lauryl/myristyl polyethenoxy ether sodium sulfate (AES-Na (EO=3)) 10 ~ 20
Ethanol 10 ~ 20
Softening water 100
In described mandarin oil, limonene content is more than 80%.
2. the degradable type sanitising agent of biology containing mandarin oil according to claim 1, is characterized in that: the pH value of the described degradable type sanitising agent of biology containing mandarin oil is 5 ~ 6.
3. the degradable type sanitising agent of biology containing mandarin oil according to claim 1, is characterized in that: described fatty alcohol-polyoxyethylene ether is selected from any one in AE03, AE04, AE05, AE06, AE07, AE08 and AE09.
4. the degradable type sanitising agent of biology containing mandarin oil according to claim 1, it is characterized in that: the surface tension of the described degradable type sanitising agent of biology containing mandarin oil is 22.23 ± 0.01 ~ 20.00 mN/m when room temperature, and solvent viscosity is 2.000 ~ 1.550 mm
2/ s, flash-point (remaining silent) is 100 DEG C.
5. a preparation method for the degradable type sanitising agent of biology containing mandarin oil as claimed in claim 1, is characterized in that: comprise the following steps:
(1) mixing adding in container successively according to the fatty alcohol-polyoxyethylene ether of above-mentioned parts by weight, lauryl/myristyl polyethenoxy ether sodium sulfate (AES-Na (EO=3)) and mandarin oil, stirring 50 ~ 70 minutes under the rotating speed of the temperature of 30 DEG C ~ 60 DEG C and 1000 ~ 6000rpm;
(2) sodium lauryl sulphate according to above-mentioned parts by weight is joined in container, stir 30 ~ 50 minutes under the rotating speed of 1000 ~ 6000rpm;
(3) finally the softening water according to above-mentioned parts by weight is added in container with the speed of 20ml/10mins at the temperature of 40 DEG C ~ 50 DEG C, then the ethanol according to above-mentioned parts by weight is added, stir 20 ~ 40 minutes under the rotating speed of 1000 ~ 6000rpm, mixing terminates to be cooled to by solution the temperature of 20 ~ 25 DEG C namely to obtain the described degradable type sanitising agent of biology containing mandarin oil.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510131356.3A CN104789391B (en) | 2015-03-25 | 2015-03-25 | A kind of biological degradable type cleaning agent and preparation method containing citrus seed oil |
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| CN201510131356.3A CN104789391B (en) | 2015-03-25 | 2015-03-25 | A kind of biological degradable type cleaning agent and preparation method containing citrus seed oil |
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| CN115044422A (en) * | 2022-07-18 | 2022-09-13 | 长兴净安环保科技有限公司 | High-activity multipurpose universal cleaning agent |
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| CN104789391B (en) | 2018-02-16 |
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