CN104553176B - Matrix material of electrodepositable and preparation method thereof - Google Patents
Matrix material of electrodepositable and preparation method thereof Download PDFInfo
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- CN104553176B CN104553176B CN201310470495.XA CN201310470495A CN104553176B CN 104553176 B CN104553176 B CN 104553176B CN 201310470495 A CN201310470495 A CN 201310470495A CN 104553176 B CN104553176 B CN 104553176B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
- B32B9/007—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/08—Impregnating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/16—Drying; Softening; Cleaning
- B32B38/164—Drying
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/047—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of fibres or filaments
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/106—Carbon fibres, e.g. graphite fibres
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- Chemical & Material Sciences (AREA)
- Laminated Bodies (AREA)
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Abstract
The invention discloses a kind of matrix material of electrodepositable and preparation method thereof.The matrix material includes composite layer and is coated on the layer of carbon fiber material of composite layer surface.By coating conductive carbon fibre material in composite material surface, the matrix material that can be directly entered plating bath plates is finally given, and the coat of metal and the adhesive force of composite that are obtained after electroplating are preferable.Coat of metal adhesive force is poor after scheme provided by the present invention solves the problems, such as composite material surface plating difficulty and electroplated, the fields such as Aeronautics and Astronautics, electronic device and metal screen layer are applied to after electroplated has preferable effect, and the present invention does not need large-scale instrument and equipment, simple process is easy.
Description
Technical field
The present invention relates to composite material surface processing technology field, in particular to a kind of matrix material of electrodepositable
And preparation method thereof.
Background technology
In recent years, composite has been applied in production and daily necessities more and more widely by its peculiar advantage.It
Traditional metal material can not only be substituted in performance, additionally it is possible to save machining time, improve work production
Rate, mitigate product weight and reduce product cost.
But above-mentioned composite is there is also some defects, as composite is non-conductive, not heat conduction, wears no resistance, easily
Deformation, not anti-pollution and shortage metallic luster etc., so as to define the use range of composite to a certain extent, especially
When composite is used to electroplate, because composite is in itself and non-conductive, it is impossible to plating bath plates are directly entered, even if electric
Obtaining the composite with a small amount of electrodeposition of metals after plating, the adhesion of the electrodeposition of metals and composite is also very poor,
Peel strength is very low, easily comes off, it is difficult to apply it to the fields such as Aeronautics and Astronautics, electronic device and metal screen layer.
Therefore, there is an urgent need to a kind of surface treatment method of composite occur at present so that be obtained after surface treatment
Composite can obtain preferable electroplating effect when for electroplating, and formed in its surface after composite and plating
Electrodeposition of metals tool is well bonded.
The content of the invention
The present invention is intended to provide a kind of matrix material of electrodepositable and preparation method thereof, of the prior art compound to solve
The difficult technical problem of electroplating material.
To achieve these goals, according to an aspect of the invention, there is provided a kind of matrix material of electrodepositable, including
Composite layer and the layer of carbon fiber material for being arranged on composite layer surface.
Further, layer of carbon fiber material is arranged on the one or both sides of composite layer.
Further, composite layer is that the one or more in glass fabric, aramid fabric and quartz fabric pass through dipping
Formed.
Further, layer of carbon fiber material is that carbon cloth and/or carbon fibre segment are formed by impregnating.
According to another aspect of the present invention, there is provided a kind of preparation method of the matrix material of electrodepositable, using maceration extract
Composite and carbon fibre material are impregnated, lamination, solidified, obtaining surface has the matrix material of layer of carbon fiber material.
Further, comprise the following steps：S1, composite and carbon fibre material are provided, by composite and carbon fiber
Material, which is respectively placed in maceration extract, to be impregnated, and primary solidification, obtains the composite layer of semi-solid preparation and the carbon fibre material of semi-solid preparation
Layer；And S2, the layer of carbon fiber material of semi-solid preparation is arranged in the composite layer surface of semi-solid preparation, through further solidification,
Obtain the matrix material that layer of carbon fiber material is bonded to one with composite layer.
Further, the solidification temperature of primary solidification is 80 DEG C~100 DEG C.
Further, the solidifying pressure of primary solidification is 0~0.1Mpa.
Further, the hardening time of primary solidification is 0.2~3 hour.
Further, the solidification temperature further solidified is 100 DEG C~300 DEG C.
Further, the solidifying pressure further solidified is 0~3Mpa.
Further, the hardening time further solidified is 1~12 hour.
Further, one or more of the composite in glass fabric, aramid fabric and quartz fabric；Carbon fiber material
Expect for carbon cloth and/or carbon fibre segment.
Further, maceration extract includes matrix liquid, curing agent and accelerator.
Further, curing agent is amine curing agent, and amine curing agent is selected from aliphatic diamine, aromatic polyamine and dicyandiamide
In one or more；Accelerator is stated selected from acrylic amine, ferric trichloride, ferrocene and to one kind in Chlorobenzoic Acid or more
Kind.
Further, one or more of the matrix liquid in epoxy resin, cyanate and double maleic anhydrides.
Apply the technical scheme of the present invention, by setting conductive carbon fibre material in composite material surface, most
The matrix material of plating bath plates is obtained being directly entered eventually, and the coat of metal that is obtained after electroplating and composite is attached
Put forth effort preferably.Scheme provided by the present invention solve composite material surface plating it is difficult and after electroplating coat of metal adhesive force compared with
The problem of poor, the fields such as Aeronautics and Astronautics, electronic device and metal screen layer are applied to after electroplated has preferable effect,
And the present invention does not need large-scale instrument and equipment, simple process is easy.
Brief description of the drawings
The Figure of description for forming the part of the application is used for providing a further understanding of the present invention, and of the invention shows
Meaning property embodiment and its illustrate be used for explain the present invention, do not form inappropriate limitation of the present invention.In the accompanying drawings：
Fig. 1 shows that a kind of section structure of the matrix material of the electrodepositable of exemplary embodiments according to the present invention is illustrated
Figure.
Embodiment
It should be noted that in the case where not conflicting, the feature in embodiment and embodiment in the application can phase
Mutually combination.Describe the present invention in detail below with reference to the accompanying drawings and in conjunction with the embodiments.
In order to solve the problems, such as that the plating of composite material surface present in prior art is difficult, can not metallize, the present invention
A kind of matrix material of electrodepositable is provided, as shown in figure 1, the matrix material includes composite layer 10 and is arranged on compound
The layer of carbon fiber material 20 on the surface of material layer 10.
By setting conductive carbon fibre material in composite material surface, electricity can be directly entered by having finally given
The matrix material of coating bath plating, and the coat of metal and the adhesive force of composite that are obtained after electroplating are preferable.It is provided by the present invention
Scheme solve the problems, such as that composite material surface plating is difficult and electroplate after coat of metal adhesive force it is poor, applied after electroplated
There is preferable effect to fields such as Aeronautics and Astronautics, electronic device and metal screen layers, and the present invention does not need large-scale instrument
Equipment, simple process are easy
A preferred embodiment of the invention, layer of carbon fiber material 20 be arranged on composite layer 10 side or
Both sides.It can be configured according to being actually needed, wherein layer of carbon fiber material 20 can not only be provided at composite layer 10
One or both sides, the surface of composite layer 10 can also all be coated or part coats.Composite layer 10 is glass
It is one or more by impregnating formation in fiber cloth, aramid fabric and quartz fabric.Layer of carbon fiber material 20 be carbon cloth and/or
Carbon fibre segment is formed by impregnating.Wherein carbon fibre segment refers to some chopped carbon fibers or carbon fiber whisker.
It is of the invention preferably but to be not limited to above-mentioned composite layer 10 and layer of carbon fiber material 20, using above-mentioned compound
Material layer 10 and layer of carbon fiber material 20 can cause the metal level on the surface of matrix material to have more after follow-up electroplating processes
Good adhesion.
Composite and carbon fibre material of the present invention are commercially available prod, and every itself is non-conductive and can be with
Impregnated carbon fiber liquid bonding, need the composite that is metallized on surface to use, it is every conductive and can with it is multiple
The compound carbon fiber of condensation material or the carbon fiber paper that can be conductive obtained after carbon fiber is handled, braid etc. can be used
To be arranged on the surface of composite.
According to another aspect of the present invention, there is provided a kind of preparation method of matrix material, using maceration extract to composite wood
Material and carbon fibre material are impregnated, lamination, and solidification, obtaining surface has the matrix material of layer of carbon fiber material 20.Preferably,
The preparation method of matrix material comprises the following steps：S1, composite and carbon fibre material are provided, by composite and carbon fiber
Material, which is respectively placed in maceration extract, to be impregnated, primary solidification, obtains the composite layer 10 of semi-solid preparation and the carbon fiber material of semi-solid preparation
The bed of material 20；And S2, the layer of carbon fiber material 20 of semi-solid preparation is arranged on semi-solid preparation composite layer 10 surface laggard one
Step solidification, obtain the matrix material that layer of carbon fiber material 20 is bonded to one with composite layer 10.
The present invention has obtained having one by primary solidification after impregnating composite and carbon fibre material in maceration extract
Determine the composite layer 10 and carbon fiber layer 20 of caking property, carbon fiber layer 20 be now stacked in the surface of composite layer 10,
By further solidification, the polar group of impregnated carbon fiber liquid institute band can be combined into the polar group of composite institute band
Key, therefore composite layer 10 and carbon fiber layer 20 can be bonded to one, thus in the Surface coating of composite layer 10
One layer of layer of carbon fiber material 20.
Preferably, one or more of the composite in glass fabric, aramid fabric and quartz fabric；Carbon fibre material
For carbon cloth and/or carbon fibre segment.Maceration extract of the present invention includes matrix liquid, curing agent and accelerator, is promoting
Matrix liquid energy enough more fast and effeciently solidifies in the presence of entering agent.Wherein matrix liquid is selected from epoxy resin, cyanate and span
The one or more come in acid anhydrides, the present invention preferably but are not limited to above-mentioned matrix liquid, if can by carbon fibre material and
Composite bonding is simultaneously solidified togather.Maceration extract in the present invention for infused composite is with being used for impregnation of carbon fibers
The maceration extract of material can it is identical can also be different, it is either still equal using different maceration extracts using identical maceration extract
The purpose of adhesive solidification of the present invention can be reached.
Preferably, curing agent is amine curing agent, and amine curing agent is in aliphatic diamine, aromatic polyamine and dicyandiamide
One or more；Accelerator is selected from acrylic amine, ferric trichloride, ferrocene and to the one or more in Chlorobenzoic Acid.
In addition, accelerator can also select amine type accelerator, anhydrides accelerator and tin class accelerator.From the curing agent of mentioned kind
Composite layer 10 and the time of the solidification of layer of carbon fiber material 20 can be shortened with accelerator so that composite layer 10 and carbon fiber
The bonding on the surface of material layer 20 is more firm, contributes to follow-up plating step.
A preferred embodiment of the invention, the solidification temperature of primary solidification is 80 DEG C~100 DEG C.Primary solidification
Solidifying pressure be 0~0.1Mpa.The hardening time of primary solidification is 0.2~3 hour.Preferably, the solidification temperature of primary solidification
Spend for 85 DEG C~95 DEG C, the solidifying pressure of primary solidification is 0.05~0.08Mpa, and the hardening time of primary solidification is small for 0.2~1
When.Consider the temperature, pressure and time of primary solidification, controlled within the above range, primary solidification can either be ensured
Effect, while be also convenient for operating process.If the temperature of primary solidification is higher, can cause maceration extract shift to an earlier date it is partially cured or
Person is fully cured, and is difficult to when carbon fiber layer 20 is carried out lamination by next step with composite layer 10；If on the contrary, temperature
Less than 80 DEG C, then because of temperature is too low maceration extract can be caused to be difficult to be impregnated into fiber system.
The solidification temperature further solidified is 100 °C~300 DEG C, and the solidifying pressure further solidified is 0~3Mpa, enters one
The hardening time of step solidification is 1~12 hour.Preferably, the solidification temperature further solidified is 150 DEG C~250 DEG C, further
The solidifying pressure of solidification is 0.1~1Mpa, and the hardening time further solidified is 2~5 hours.After primary solidification, synthesis is examined
Consider temperature, pressure and the time factor further solidified, these factor controllings both ensure that to resin impregnates within the above range
Liquid is fully cured, while by controlling solidifying pressure curing time control in suitable scope, accelerates solidification speed
Rate.If solidification temperature is higher than 300 DEG C, it can cause maceration extract is rotten to decompose；If solidification temperature is less than 100 DEG C, can lead
Cause the intensity after maceration extract solidification too low, influence the performance of final matrix material.
Beneficial effects of the present invention are further illustrated with reference to specific embodiment.
Embodiment 1
The quartz fiber cloth and carbon cloth provided using Wuhan Xin Youtai Optoelectronics Technology company.By quartz fiber cloth and carbon
Fiber cloth is respectively placed in maceration extract（Maceration extract is by 140 parts of matrix liquid bisphenol A epoxide resins, 7 parts of curing agent dicyandiamides and 7 parts
Accelerator acrylic amine forms）Impregnate 3 hours, in the baking oven after taking-up at 95 DEG C, primary solidification 0.5 hour.
By the carbon cloth of the semi-cured state obtained after primary solidification and the quartz fiber cloth lamination of semi-cured state, make
Carbon cloth is arranged on the two sides of the quartz fiber cloth of semi-cured state, is put into afterwards after bag vacuum and is put into baking oven and consolidates
Change, condition of cure is warming up to 130 DEG C and continues solidification 2 hours, be continuously heating to 150 afterwards first to solidify 2 hours at 100 DEG C
DEG C continue solidification 1 hour, obtain matrix material.
Embodiment 2：
Glass fabric and carbon cloth are respectively placed in maceration extract（Maceration extract is by 140 parts of matrix liquid bisphenol-A epoxy trees
Fat, 7 parts of curing agent dicyandiamides and 7 parts of accelerator acrylic amine compositions）Dipping 5 hours, it is placed in after taking-up under 80 DEG C and 0.1MPa
Primary solidification 0.2 hour.
By the carbon cloth of the semi-cured state obtained after primary solidification and the glass fabric lamination of semi-cured state, make
Carbon cloth is coated on the surface of the glass fabric of semi-cured state, is put into bag vacuum afterwards, then at 300 DEG C
Further solidify 12 hours in baking oven, obtain matrix material.
Embodiment 3
The carbon fibre segment that the aramid fabric provided using E.I.Du Pont Company and Yixing City Hua Wei Science and Technology Ltd.s are provided, by virtue
Synthetic fibre cloth and carbon fibre segment are respectively placed in maceration extract（Maceration extract is by 90 parts of matrix liquid cyanates, 10 parts of phenol aldehyde type epoxy resins
Formed with 2 parts of acrylic amines）Dipping 4 hours, primary solidification 3 hours under 100 DEG C and 0.05MPa are placed in after taking-up.
By the carbon fibre segment of the semi-cured state obtained after primary solidification and the aramid fabric lamination of semi-cured state, make carbon
Fiber cloth is coated on the aramid fabric surface of semi-cured state, is put into bag vacuum afterwards, is put into afterwards under 200 DEG C and 3MPa
Baking oven in further solidification 1 hour, obtain matrix material.
Comparative example 1
Carbon cloth is not used, is only to solidify and electroplate using quartz fiber cloth dipping, concrete technology is as follows：
The quartz fiber cloth provided using Wuhan Xin Youtai Optoelectronics Technology company, quartz fibre is arranged in maceration extract
（Maceration extract is made up of 140 parts of matrix liquid bisphenol A epoxide resins, 7 parts of curing agent dicyandiamides and 7 parts of accelerator acrylic amines）Dipping
3 hours, in the baking oven after taking-up at 95 DEG C, primary solidification 0.5 hour.
By the quartz fiber cloth lamination of the semi-cured state obtained after primary solidification, put after being put into bag vacuum afterwards
Enter curing oven, condition of cure is warming up to 130 DEG C and continues solidification 2 hours, continue to rise afterwards first to solidify 2 hours at 100 DEG C
Temperature continues to solidify 1 hour to 150 DEG C, obtains matrix material.
The matrix material prepared in embodiment 1~3 and comparative example 1 is carried out into surface treatment to make it suitable for electroplating, it
After be respectively put into electroplating bath and electroplate, at a temperature of 20 DEG C~25 DEG C with every liter in containing 180~240g copper sulphate, 20~25ml
Bright sulfur acid, 80~100mg chlorions, 0.5~1.0mg 2-mercaptobenzimidazole, 0.3~0.8mg ethylene thioureas and 10~
Surface after the mixed liquor of 20mg sodium polydithio-dipropyl sulfonates cleans to above-mentioned acetone soln carries out electro-coppering reserves, and electric current is close
Spend for 0.5~1.5A/dm2, until reaching predetermined thickness.Surface after cleaning above-mentioned plating Copper treatment with acetone soln, by
This, which obtains electroplating surface, the matrix material of metal level.
The matrix material with metal level obtained after being electroplated in embodiment 1~3 and comparative example 1 is tested, adopted
Peel strength is tested with peeling strength test machine between composite film, test result is shown in Table 1.
Table 1
" * " is more, represents that uniformity is better.
It can be seen that from the data in table 1 and technical scheme used in embodiment 1~3, i.e., in composite
Surface sets conductive layer of carbon fiber material, and the matrix material obtained after configured can be directly entered electroplating bath electricity
Plating, is tested under the same conditions in the thickness of electroplated metal layer, the metal electricity of the substrate material surface in embodiment 1~3
The adhesive force of coating and composite is preferable, and its peel strength is up to 15kgf/cm2, it is difficult to come off, and from matrix material
Electroplated metal layer is seen on surface than more uniform, better performances.
And layer of carbon fiber material is not arranged on to the surface of composite layer in comparative example 1, due to composite in itself
And it is non-conductive, it is difficult to form metal on the surface of composite when the composite after by solidification is sent directly into plating bath plates
Electrodeposited coating, the electrodeposition of metals of less area is formd even in the surface of composite, the electrodeposition of metals and composite
Adhesive force it is poor, its peel strength only has 10kgf/cm2, so the electrodeposition of metals of composite material surface easily comes off,
It is difficult to the composite is applied directly to the fields such as Aeronautics and Astronautics, electronic device and metal screen layer.
As fully visible, using the technical side that conductive carbon fibre material is set in composite material surface of the present invention
Electrodeposition of metals adhesive force is poor after case solves composite material surface plating difficulty and electroplated, and peel strength is relatively low to ask
Topic, the fields such as Aeronautics and Astronautics, electronic device and metal screen layer are applied to after electroplated has preferable effect, the present invention
Large-scale instrument and equipment is not needed, simple process is easy.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, for the skill of this area
For art personnel, the present invention can have various modifications and variations.Within the spirit and principles of the invention, that is made any repaiies
Change, equivalent substitution, improvement etc., should be included in the scope of the protection.
Claims (11)
1. a kind of matrix material of electrodepositable, it is characterised in that including composite layer (10) and be arranged on the composite wood
The layer of carbon fiber material (20) on the bed of material (10) surface, the layer of carbon fiber material (20) are carbon cloth and/or carbon fibre segment
Formed by impregnating, the maceration extract that the dipping uses includes matrix liquid, curing agent and accelerator, and described matrix liquid is selected from epoxy
One or more in resin, cyanate and double maleic anhydrides, the composite layer (10) be glass fabric, aramid fabric and
It is one or more by impregnating formation in quartz fabric.
2. matrix material according to claim 1, it is characterised in that the layer of carbon fiber material (20) is arranged on described multiple
The one or both sides of condensation material layer (10).
3. a kind of preparation method of the matrix material of electrodepositable, it is characterised in that using maceration extract to composite and carbon fiber
Material is impregnated, lamination, and solidification, obtaining surface has the matrix material of layer of carbon fiber material (20), the carbon fibre material
For carbon cloth and/or carbon fibre segment, the maceration extract includes matrix liquid, curing agent and accelerator, and described matrix liquid is selected from
One or more in epoxy resin, cyanate and double maleic anhydrides, the composite be selected from glass fabric, aramid fabric and
One or more in quartz fabric.
4. preparation method according to claim 3, it is characterised in that comprise the following steps：
S1, composite and carbon fibre material are provided, the composite and the carbon fibre material are respectively placed in maceration extract
Middle dipping, primary solidification, obtain the composite layer (10) of semi-solid preparation and the layer of carbon fiber material (20) of semi-solid preparation；And
S2, the layer of carbon fiber material (20) of the semi-solid preparation is arranged on composite layer (10) surface of the semi-solid preparation,
Through further solidification, the matrix material that the layer of carbon fiber material (20) is bonded to one with the composite layer (10) is obtained
Material.
5. preparation method according to claim 4, it is characterised in that the solidification temperature of the primary solidification be 80 DEG C~
100℃。
6. preparation method according to claim 4, it is characterised in that the solidifying pressure of the primary solidification be 0~
0.1Mpa。
7. preparation method according to claim 4, it is characterised in that the hardening time of the primary solidification is 0.2~3 small
When.
8. preparation method according to claim 4, it is characterised in that the solidification temperature further solidified is 100 DEG C
~300 DEG C.
9. preparation method according to claim 4, it is characterised in that the solidifying pressure further solidified be 0~
3Mpa。
10. preparation method according to claim 4, it is characterised in that the hardening time further solidified is 1~12
Hour.
11. preparation method according to claim 3, it is characterised in that
The curing agent is amine curing agent, and the amine curing agent is in aliphatic diamine, aromatic polyamine and dicyandiamide
It is one or more；
The accelerator is selected from acrylic amine, ferric trichloride, ferrocene and to the one or more in Chlorobenzoic Acid.
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| CN105034532A (en) * | 2015-06-30 | 2015-11-11 | 苏州华日金菱机械有限公司 | Preparation method of base material for electroplating |
| CN109554916B (en) * | 2017-09-26 | 2021-03-30 | 中蓝晨光化工研究设计院有限公司 | Preparation method of surface-metallized aramid fiber |
| CN109878149A (en) * | 2019-03-20 | 2019-06-14 | 海添琪 | A kind of composite structure and its production method |
| CN110029382B (en) * | 2019-05-22 | 2021-09-24 | 电子科技大学 | Surface treatment process for direct electroplating and related direct electroplating process |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101944404A (en) * | 2009-02-24 | 2011-01-12 | 英特利赛沃有限责任公司 | Use the cable of impregnation of fibers intensity layer and/or the structure of optical cable |
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| GB2444710B (en) * | 2006-12-14 | 2011-04-13 | Advanced Composites Group Ltd | Metallic coating of composite materials |
| CN101255585B (en) * | 2007-12-05 | 2010-06-09 | 天津大学 | Novel surface metallization method for carbon-fibre reinforced epoxy resin composite material |
| CN102031547A (en) * | 2010-11-05 | 2011-04-27 | 天津市飞荣达科技有限公司 | Device and method for continuously compounding plating metal and nano-particles on surface of carbon fiber |
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| CN101944404A (en) * | 2009-02-24 | 2011-01-12 | 英特利赛沃有限责任公司 | Use the cable of impregnation of fibers intensity layer and/or the structure of optical cable |
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