CN104558726A - Neoprene material for air conditioner motor damping rings - Google Patents
Neoprene material for air conditioner motor damping rings Download PDFInfo
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- CN104558726A CN104558726A CN201510068729.7A CN201510068729A CN104558726A CN 104558726 A CN104558726 A CN 104558726A CN 201510068729 A CN201510068729 A CN 201510068729A CN 104558726 A CN104558726 A CN 104558726A
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- air conditioner
- accelerator
- shock absorbing
- conditioner motor
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Abstract
The invention discloses a neoprene material for air conditioner motor damping rings, which is prepared from the following raw materials in parts by weight: 40-90 parts of neoprene, 10-60 parts of natural rubber, 5-15 parts of rubber composite vulcanizing agent and 1-5 parts of rubber anti-aging agent. The rubber composite vulcanizing agent is composed of sulfur and one or more of zinc oxide, magnesium oxide, rubber accelerator M, rubber accelerator DM, rubber accelerator TT and rubber accelerator CZ. The neoprene material has the advantages of low cost, favorable high-temperature resistance, small variation in hardness after aging, and favorable damping effect.
Description
Technical field
The present invention relates to chloroprene rubber technical field, particularly relate to a kind of air conditioner motor shock absorbing ring chloroprene rubber material.
Background technology
Rubber has excellent damping shock absorption characteristic, is widely used in manufacture to prevent vibration, the transmission impacted, absorption from impacting or playing the anti-vibration article of shock absorption.The elastomeric material that anti-vibration article is selected, mainly according to application target and working conditions, mainly considers its Young's modulus, physical strength and dynamic fatigue, creep, stress relaxation, processing characteristics and cost factor.Elastomeric material at present as damping can be divided into six classes:
1. natural rubber, styrene-butadiene rubber(SBR), cis-1,4-polybutadiene rubber are main General Purpose Rubber material;
2. the oil-resistant rubber material based on paracril;
3. the elastomeric material of resistance to weather based on chloroprene rubber;
4. the high-damping rubber material can be used for buffering or shock isolation based on isoprene-isobutylene rubber;
5. the heat resistant rubber material based on terpolymer EP rubber;
6. the high-temperature resistant rubber material based on silicon rubber.
The working temperature of air conditioner motor shock absorbing ring is near room temperature, and contact environment is the ozone that air, air-conditioning and motor produce, the vibrations etc. that equipment produces.According to requirements, sizing material hardness generally 40 degree of levels, after 120 DEG C × 72h is aging, the requirement of changes in hardness within ± 4 degree.Main elastomeric material at present for air conditioner motor shock absorbing ring has: chloroprene rubber, silicon rubber etc.
The most significant advantage of silastic material is its resistance to elevated temperatures, but because its tensile strength generally can only reach a few MPa, cause it resistance toly to subdue, the performance such as antifatigue far below chloroprene rubber material, silastic material is generally only applied to the high temperature resistant occasion not high to mechanical property requirements.The use temperature of air conditioner motor shock absorbing ring, near room temperature, does not need its resistance to elevated temperatures.
Chloroprene rubber material mainly has the following advantages compared with silastic material:
1, have very high mechanical property, because chloroprene rubber belongs to from reinforced rubber, its tensile strength is close with natural rubber, reaches as high as 25.7MPa.The tensile strength of general silastic material only has a few MPa.The mechanics reliability of neoprene neoprene is far above silastic material.
2, excellent fatigue performance, because physical strength is high, the flexing fatigue of chloroprene rubber material can reach more than 40,000 times, and under the same terms, the flexing fatigue performance of silastic material only has about 1/4 of chloroprene rubber.
3, excellent flame resistivity, the flame resistivity of chloroprene rubber is best in conventional rubber, and it has non-hypergolic feature, can from fire from putting out.And silicon rubber itself does not have anti-flaming function.
4, excellent oil resistant, solvent resistance, use range is wide, can be used for general oil resistant operating mode.Silastic material then can not be used for oil resistant operating mode.
Owing to being that to be cross-linked be main oxidising process in chloroprene rubber weathering process, the Young's modulus of aging rear material rises, and cause the Static stiffness of shock absorbing ring to become large, deviation resonance region, makes the cushioning effect of shock absorbing ring reduce, air-conditioning noise raising.Patent of invention CN 102464811A discloses a kind of natural rubber composition of resistance to ozone type for automobile absorber, due in this formula based on natural rubber, chloroprene rubber only accounts for the 2-3% of weight percent, can not meet air conditioning shock-proof circle 120 DEG C × 72h aging after, the requirement of changes in hardness within ± 4 degree.Though silicon rubber can meet the heat resistance of shock absorbing ring, it is all not as chloroprene rubber material in strength and extension property, fatigue performance, flame resistivity and medium-resistance etc., and cost is again higher than chloroprene rubber material simultaneously.
Summary of the invention
The present invention proposes a kind of air conditioner motor shock absorbing ring chloroprene rubber material, cost is low, and resistance to elevated temperatures is good, and aging rear changes in hardness is little, and cushioning effect is good.
A kind of air conditioner motor shock absorbing ring chloroprene rubber material that the present invention proposes, its raw material comprises by weight: chloroprene rubber 40-90 part, natural rubber 10-60 part, rubber combined vulcanizing agent is 5-15 part, rubber antioxidant 1-5 part, described rubber combined vulcanizing agent is for be made up of one or more and sulphur in zinc oxide, magnesium oxide, rubber accelerator M, rubber accelerator DM, rubber accelerator TT, rubber accelerator CZ.
Preferably, rubber combined vulcanizing agent is for be made up of zinc oxide, magnesium oxide, rubber accelerator M, rubber accelerator DM, rubber accelerator TT, rubber accelerator CZ and sulphur.
Preferably, the weight ratio of chloroprene rubber and natural rubber is 50-90:10-50.
Preferably, the weight ratio of chloroprene rubber and rubber combined vulcanizing agent is 50-90:8-12.
Preferably, its raw material comprises by weight: chloroprene rubber 50-90 part, natural rubber 10-50 part, cis-1,4-polybutadiene rubber 5-8 part, and rubber combined vulcanizing agent is 8-12 part, rubber antioxidant 1-4 part.
Preferably, the weight ratio of chloroprene rubber, natural rubber and cis-1,4-polybutadiene rubber is 76-78:34-36:6-8.
Preferably, its raw material also comprises strengthening agent, weighting agent, softening agent by weight.
Preferably, described strengthening agent is a kind of or wherein several combination in N550-N990 series carbon black.
Preferably, described weighting agent is a kind of or wherein several combination in light calcium carbonate, potter's clay, water-ground limestone, diatomite.
Preferably, described softening agent is a kind of or wherein several combination in naphthenic oil, aromatic hydrocarbon oil, paraffin oil.
The present invention by adding appropriate natural rubber in Chloroprene rubber formula, the characteristic of natural degradation of rubber deliquescing after utilizing high temperature ageing, compensate the shortcoming that chloroprene rubber age hardening causes material hardness to improve, and with above-mentioned materials, the aging rear hardness of goods remains unchanged substantially, the hardening problem causing shock absorbing ring rigidity to increase after not only can effectively improving chloroprene rubber material high temperature ageing, there is intensity simultaneously high, ageing-resistant, the performances such as resistance to ozone, with cis-1,4-polybutadiene rubber mating reaction, cis-1,4-polybutadiene rubber elasticity is excellent, goods are when hardness remains unchanged, cushioning effect strengthens further, wherein sulphur, zinc oxide, magnesium oxide, rubber accelerator M, rubber accelerator DM, rubber accelerator TT, the rubber combined vulcanizing agent that rubber accelerator CZ forms, degree of crosslinking can be improved, the Heat-resistant stable performance of cross-linked rubber is good, wherein rubber accelerator M, rubber accelerator DM, rubber accelerator TT, rubber accelerator CZ acts synergistically, goods cross-linking properties is good, Article Stiffness Determination is good, heat-resistant stability strengthens further, the present invention is applicable to shock absorber part article processing techniques field, be specially adapted to the anti-vibration article processing technique field requiring constant rigidity.
Embodiment
Embodiment 1
A kind of air conditioner motor shock absorbing ring chloroprene rubber material, its raw material comprises by weight: chloroprene rubber 40 parts, natural rubber 60 parts, rubber combined vulcanizing agent is 5 parts, rubber antioxidant 5 parts, described rubber combined vulcanizing agent is for be made up of zinc oxide, rubber accelerator M, rubber accelerator DM and sulphur.
Embodiment 2
A kind of air conditioner motor shock absorbing ring chloroprene rubber material, its raw material comprises by weight: chloroprene rubber 90 parts, natural rubber 10 parts, rubber combined vulcanizing agent is 15 parts, rubber antioxidant 1 part, described rubber combined vulcanizing agent is for be made up of zinc oxide, magnesium oxide, rubber accelerator M, rubber accelerator DM, rubber accelerator TT, rubber accelerator CZ and sulphur.
Embodiment 3
A kind of air conditioner motor shock absorbing ring chloroprene rubber material, its raw material comprises by weight: chloroprene rubber 50 parts, natural rubber 50 parts, and rubber combined vulcanizing agent is 8 parts, cis-1,4-polybutadiene rubber 5 parts, rubber antioxidant 4 parts, strengthening agent, weighting agent, softening agent; Described rubber combined vulcanizing agent is made up of zinc oxide, magnesium oxide, rubber accelerator M, rubber accelerator DM, rubber accelerator TT, rubber accelerator CZ and sulphur, described strengthening agent N990 carbon black.Described weighting agent is diatomite, and described softening agent is made up of naphthenic oil, aromatic hydrocarbon oil.
Embodiment 4
A kind of air conditioner motor shock absorbing ring chloroprene rubber material, its raw material comprises by weight: chloroprene rubber 85 parts, natural rubber 16 parts, cis-1,4-polybutadiene rubber 8 parts, rubber combined vulcanizing agent is 12 parts, rubber antioxidant 2 parts, strengthening agent, weighting agent, softening agent; Described rubber combined vulcanizing agent is made up of zinc oxide, magnesium oxide, rubber accelerator M, rubber accelerator DM, rubber accelerator TT, rubber accelerator CZ and sulphur, described strengthening agent is made up of N220, N330, N550, described weighting agent is made up of light calcium carbonate, potter's clay, and described softening agent is made up of naphthenic oil, aromatic hydrocarbon oil, paraffin oil.
Embodiment 5
A kind of air conditioner motor shock absorbing ring chloroprene rubber material, its raw material comprises by weight: chloroprene rubber 77 parts, natural rubber 35 parts, cis-1,4-polybutadiene rubber 7 parts, and rubber combined vulcanizing agent is 10 parts, rubber antioxidant 2 parts, strengthening agent, weighting agent, softening agent; Described rubber combined vulcanizing agent is made up of zinc oxide, magnesium oxide, rubber accelerator M, rubber accelerator DM, rubber accelerator TT, rubber accelerator CZ and sulphur, described strengthening agent is made up of N220, N330, N550, N660, N774, N990, described weighting agent is made up of light calcium carbonate, potter's clay, water-ground limestone, diatomite, and described softening agent is paraffin oil.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (10)
1. an air conditioner motor shock absorbing ring chloroprene rubber material, it is characterized in that, its raw material comprises by weight: chloroprene rubber 40-90 part, natural rubber 10-60 part, rubber combined vulcanizing agent is 5-15 part, rubber antioxidant 1-5 part, described rubber combined vulcanizing agent is for be made up of one or more and sulphur in zinc oxide, magnesium oxide, rubber accelerator M, rubber accelerator DM, rubber accelerator TT, rubber accelerator CZ.
2. air conditioner motor shock absorbing ring chloroprene rubber material according to claim 1, it is characterized in that, rubber combined vulcanizing agent is for be made up of zinc oxide, magnesium oxide, rubber accelerator M, rubber accelerator DM, rubber accelerator TT, rubber accelerator CZ and sulphur.
3. air conditioner motor shock absorbing ring chloroprene rubber material according to claim 1, it is characterized in that, the weight ratio of chloroprene rubber and natural rubber is 50-90:10-50.
4. air conditioner motor shock absorbing ring chloroprene rubber material according to claim 1, it is characterized in that, the weight ratio of chloroprene rubber and rubber combined vulcanizing agent is 50-90:8-12.
5. air conditioner motor shock absorbing ring chloroprene rubber material according to any one of claim 1-4, it is characterized in that, its raw material comprises by weight: chloroprene rubber 50-90 part, natural rubber 10-50 part, cis-1,4-polybutadiene rubber 5-8 part, rubber combined vulcanizing agent is 8-12 part, rubber antioxidant 1-4 part.
6. air conditioner motor shock absorbing ring chloroprene rubber material according to claim 5, it is characterized in that, the weight ratio of chloroprene rubber, natural rubber and cis-1,4-polybutadiene rubber is 76-78:34-36:6-8.
7. air conditioner motor shock absorbing ring chloroprene rubber material according to claim 1, it is characterized in that, its raw material also comprises strengthening agent, weighting agent, softening agent by weight.
8. air conditioner motor shock absorbing ring chloroprene rubber material according to claim 7, is characterized in that, described strengthening agent is a kind of or wherein several combination in N550-N990 series carbon black.
9. air conditioner motor shock absorbing ring chloroprene rubber material according to claim 8, it is characterized in that, described weighting agent is a kind of or wherein several combination in light calcium carbonate, potter's clay, water-ground limestone, diatomite.
10. air conditioner motor shock absorbing ring chloroprene rubber material according to claim 9, it is characterized in that, described softening agent is a kind of or wherein several combination in naphthenic oil, aromatic hydrocarbon oil, paraffin oil.
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104893043A (en) * | 2015-05-28 | 2015-09-09 | 安徽同丰橡塑工业有限公司 | Shock-reducing rubber |
CN106317526A (en) * | 2016-08-29 | 2017-01-11 | 宁波美亚达汽车部件制造有限公司 | Fatigue-resistant deflection-resistant rubber material |
CN107189123A (en) * | 2017-06-29 | 2017-09-22 | 苏州广能电子科技有限公司 | A kind of console rubber corner fittings |
CN109021315A (en) * | 2018-06-29 | 2018-12-18 | 宁国中信零部件有限公司 | A kind of compressor of air conditioner rubber pad glue stuff compounding and preparation method thereof |
CN109776890A (en) * | 2019-02-26 | 2019-05-21 | 江苏骆氏减震件有限公司 | A kind of yielding rubber of high-elastic wear-resistant |
CN110922647A (en) * | 2018-09-20 | 2020-03-27 | 南通鸿图橡塑有限公司 | High-elasticity rubber and composition thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103992533A (en) * | 2014-04-17 | 2014-08-20 | 宁国中奕橡塑有限公司 | Air conditioner motor damping ring rubber assembly material and assembly making method |
CN104231339A (en) * | 2014-08-30 | 2014-12-24 | 保隆(安徽)汽车配件有限公司 | Outer glue material of rubber pneumatic bag for automobile air suspensions and preparation method thereof |
-
2015
- 2015-02-10 CN CN201510068729.7A patent/CN104558726A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103992533A (en) * | 2014-04-17 | 2014-08-20 | 宁国中奕橡塑有限公司 | Air conditioner motor damping ring rubber assembly material and assembly making method |
CN104231339A (en) * | 2014-08-30 | 2014-12-24 | 保隆(安徽)汽车配件有限公司 | Outer glue material of rubber pneumatic bag for automobile air suspensions and preparation method thereof |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104893043A (en) * | 2015-05-28 | 2015-09-09 | 安徽同丰橡塑工业有限公司 | Shock-reducing rubber |
CN106317526A (en) * | 2016-08-29 | 2017-01-11 | 宁波美亚达汽车部件制造有限公司 | Fatigue-resistant deflection-resistant rubber material |
CN107189123A (en) * | 2017-06-29 | 2017-09-22 | 苏州广能电子科技有限公司 | A kind of console rubber corner fittings |
CN109021315A (en) * | 2018-06-29 | 2018-12-18 | 宁国中信零部件有限公司 | A kind of compressor of air conditioner rubber pad glue stuff compounding and preparation method thereof |
CN110922647A (en) * | 2018-09-20 | 2020-03-27 | 南通鸿图橡塑有限公司 | High-elasticity rubber and composition thereof |
CN109776890A (en) * | 2019-02-26 | 2019-05-21 | 江苏骆氏减震件有限公司 | A kind of yielding rubber of high-elastic wear-resistant |
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Application publication date: 20150429 |