CN104523453B - A kind of wire drawing stabilizer, with composition for stablizing wire-drawing effect and preparation method thereof - Google Patents
A kind of wire drawing stabilizer, with composition for stablizing wire-drawing effect and preparation method thereof Download PDFInfo
- Publication number
- CN104523453B CN104523453B CN201410788253.XA CN201410788253A CN104523453B CN 104523453 B CN104523453 B CN 104523453B CN 201410788253 A CN201410788253 A CN 201410788253A CN 104523453 B CN104523453 B CN 104523453B
- Authority
- CN
- China
- Prior art keywords
- wire drawing
- wire
- composition
- product
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Cosmetics (AREA)
Abstract
The invention discloses it is a kind of can as skin-protection product wire drawing stabilizer material --- containing manganese compound.Invention also discloses a kind of composition for having and stablizing wire-drawing effect, contains manganous compound and wire drawing agent；The wire drawing agent is polyethylene glycol or polyoxyethylene vinyl polymerization thing.Preferably, said composition is made up of the compound containing manganese element, polyoxyethylene vinyl polymerization thing, polyalcohol, deionized water, and stable available for preparation has wire drawing shape toner, emulsion, cream, mask and other products.Sample is tested through 48 DEG C heat-resisting 15 DEG C cold-resistant tests and sunlight according to shining 3 months, wire drawing efficiently solves the product containing wire drawing without degraded, wire-drawing effect degradation problem occurs in storage and using process, there is more preferable replenishing water and preserving moisture effect than mill run after tested, with good development prospect.
Description
Technical field
The invention belongs to cosmetic field, be related to it is a kind of have stablize composition of wire-drawing effect and preparation method thereof.
Background technology
With the improvement of people ' s living standards, and living environment influence, the requirement demand to cosmetics is more and more thinner,
Effect that cosmetics have not only is only focused on, the outward appearance to product is also increasingly paid close attention to.
Consumer has double requirements to the outward appearance of product, and one kind is spiritual, and a kind of is on material.Product sheet
Body should have three kinds of functions：Utility function, aesthetic function, Symbol Function.One good product should be the coordination of these three functions
And synthesis.
The aesthetic process of consumer is the object by product, includes vision, the sense of hearing by the sense organ of consumer, touches
Feel, smell, sense of taste etc., receive the various information of product, aesthetic experience are then produced to product, so as to obtain aesthetic enjoy
By.Certainly the outward appearance to product is aesthetic mainly by vision and tactile.
The higher appearance design of technology content is always welcome.In order that product quickly becomes commodity, manufacturer also gets over
To be more concerned about the aesthetic needs and aesthetical interest of masses, as the formulator of cosmetics first it is to be understood that the aesthetic need of consumer
Ask, can just design the product for meeting consumer.
In today of scientific and technical fast development, people advocate knowledge, it is known that scientific and technical application can improve ours
Quality of life.Today's society is the epoch that new material, new technology emerge in an endless stream, and to meet the esthetic requirement that consumer looks for novelty,
Designer must can carry out deisgn product with new material, new technology, found brand image, attract consumer, excellent product, together
When be also the art work, consumer can also obtain artistic treat while using product.In line with consumer to cosmetic product
In effect and outward appearance demand, the cosmetics with wire drawing shape are taken advantage of a situation and life, and it not only has long-acting moisture retention, even more caters to
The consumer demand aesthetic to product appearance.Investigate according to the study：Wire drawing cosmetics are favored by consumer very much, but with drawing
Thread cosmetic art is not still very ripe, so commercially successful drawn wire product is actually rare.
CN 102482495 discloses a kind of personal care composition with mucus property.Mucilaginous substance liquid can be formed
Filament or line, with " wire drawing " property.In order to provide suitable viscosity, thickener can be used, suitable thickener example is
Sodium alginate, gum arabic, polyoxyethylene, guar gum, HPG, ethoxylated alcohol, such as laureth -4 or
Polyethylene glycol 400, example are methylcellulose, methylhydroxypropylcellulose, hydroxypropyl cellulose, poly- hydroxypropyl hydroxyethyl cellulose
Cellulose derivative, starch and example be the starch derivatives of hydroxyethyl amylose and starch amylose, locust bean gum,
Example is the electrolyte and sugar of sodium chloride and ammonium chloride, e.g., fructose and glucose, and sugared derivative, such as PEG-120 methyl
Glucose dioleate or the mixture of two or more in these.
However, the cosmetics with wire drawing property easily occur certainly under the effect of ultraviolet, strong acid and transition metal ions
Dynamic oxidation is degraded so that wire drawing character fades away.Wire drawing degradation speed is is alleviated in the enterprise of production drawn wire product at present, generally
Using the consumption for increasing antioxidant, the cost not only increased, while the excitant of product is also increased, but effect is not
It is preferable.
The content of the invention
An object of the present invention is the additive for providing a kind of stable wire drawing character of energy.
It is a further object of the present invention to provide a kind of composition of the stable wire drawing character of energy.
It is a further object of the present invention to provide a kind of skin care compositions for having and stablizing wire-drawing effect.
It is a further object of the present invention to provide a kind of moisture-keeping composition of the stable wire drawing character of energy.
It is a further object of the present invention to provide the preparation method of above-mentioned composition.
There is provided the functional component of wire-drawing performance it is mainly wire drawing agent therein in the skin care item with wire drawing character,
It make it that product has certain viscosity, can produce wire drawing behavior.One of which wire drawing agent is polyethylene glycol or polyoxyethylene
Vinyl polymer.
The molecular weight (number is equal) of these polymer can be 20000-8000000, or preferably 4000000-8000000.
However, the wire drawing cosmetic product of polyethylene glycol/polyoxyethylene vinyl polymerization thing, in ultraviolet, strong acid and transition gold
Belong in the presence of ion etc., easily occur autoxidation degraded.Therefore with the increase of standing time, under the wire-drawing performance of product
Drop.
Inventor is found that a kind of additive --- compound containing manganese element of energy stable prod wire drawing character first.More
Say, it is applied to the drawn wire product containing polyethylene glycol/polyoxyethylene vinyl polymerization thing body.
Further, described compound containing manganese element manganous compound.It is highly preferred that being soluble bivalent manganese chemical combination
Thing.
As optional embodiment, described contains manganese compound in manganese sulfate, manganese carbonate, manganese chloride, manganese stearate
One or more.
In one exemplary embodiment of the present invention, the manganous compound is manganese chloride.
Inventor is confirmed by degradations such as high temperature, sunlight irradiations, contains polyethylene glycol/polyoxyethylene relative to common
The preserving moisture and protecting skin product of vinyl polymer, with the addition of the product tool of polyethylene glycol/polyoxyethylene vinyl polymerization thing of manganese compound
There is more stable wire-drawing performance.In high-temperature circulation test, common drawn wire product is after placing 60 days, and its wire drawing is scored from starting
5 points drop to 1 point, and the product that with the addition of manganese compound still maintains 4-5 points of score；In sunlit aging examination
In testing, the wire drawing stability of common drawn wire product is very poor, places i.e. only 2 points two days later of score；And with the addition of manganese compound
Product 3-4 point score is still maintained after placing 90 days.
Compound containing manganese element is effective stabilizer of wire drawing agent polyethylene glycol or polyoxyethylene vinyl polymerization thing.It can be with
Alleviate oxidative degradation of the drawn wire product under ultraviolet, strong acid, transition metal ions effect.
Further experiment finds, add manganese element compound drawn wire product can not only wire-drawing performance it is stable, and with
In the presence of polyethylene glycol or polyoxyethylene vinyl polymerization thing are common, the moisture-retaining capacity of the latter can be strengthened.Polyethylene glycol is used as change
Cosmetic raw material, in addition to as thickener/wire drawing agent, also plays many effects, such as surfactant, conduct
Foam booster, it is used as aqueous emollient, NMF etc..Its moisture-retaining capacity is probably mainly because it can be in skin surface formation one
Plant ventilative film.And in the presence of manganese compound and the polyethylene glycol of the present invention are common, it is likely that because both synergy, into
More preferably, formation film is finer and close for film, and experiment finds that its water conservation moisture-retaining capacity is improved.Experiment is found, manganese is contained simultaneously
The moisturizer of compound and polyethylene glycol, than the moisturizer without manganese compound, its moisturizing validity improves 25%.
Therefore, the drawn wire product of the invention containing manganese chloride and polyethylene glycol/polyoxyethylene vinyl polymerization thing, is especially suitable for
It is used as a kind of wire drawing moisturizer.
Alternatively, content of the manganese element compound in drawn wire product can be 0.001-2% (w/w).It is poly-
The content of ethylene glycol or polyoxyethylene vinyl polymerization thing in drawn wire product can be 0.01-2% (w/w).
In order to further be beneficial to the modulation of drawn wire product, the invention provides a kind of combination for having and stablizing wire-drawing effect
Thing, it is counted including following components by weight：
0.1-200 parts of compound containing manganese element (in terms of manganese element), polyethylene glycol or polyoxyethylene vinyl polymerization thing 1-200
Part, 10-3000 parts of alcohol.
Described alcohol can be monohydric alcohol or dihydric alcohol or polyalcohol or combinations thereof.
Above-mentioned composition may also include water or aqueous carrier.
Preferably, above-mentioned composition is counted including following components by weight：
1~50 part of compound containing manganese element (in terms of manganese element), polyethylene glycol or polyoxyethylene vinyl polymerization thing 1~100
Part, 200~2000 parts of alcohol.
In one exemplary embodiment of the present invention, composition includes following components：
Compound containing manganese element (in terms of manganese element) 0.001-2% (w/w), polyethylene glycol or polyoxyethylene vinyl polymerization thing
0.01-2% (w/w), monohydric alcohol or dihydric alcohol or polyalcohol 0.1-30% (w/w), surplus are deionized water.
In the composition, dihydric alcohol or polyalcohol can preferably disperse wire drawing agent, can more good dissolving in water after disperseing.
Therefore, said composition can need the raw material of wire drawing character product as with the composition for stablizing wire-drawing effect as a variety of,
Beneficial to the modulation of drawn wire product.
Above-mentioned alcohols is also simultaneously NMF.Alternatively, for example, ethanol, isopropanol, propane diols, glycerine, alkylol,
One or more mixtures in butanediol, pentanediol；Preferably dihydric alcohol or polyalcohol, for example, propane diols, butanediol, sweet
Oil or combinations thereof.Above-mentioned alcohol plays moisture-keeping function while as dispersant so that above-mentioned composition is more suitable for making
With the moisture-keeping composition for stablizing wire-drawing effect, to be used as the raw material of wire drawing moisturizer.
Above-mentioned composition can be prepared via a method which to obtain：First polyethylene glycol/polyoxyethylene vinyl polymerization thing is disperseed
In alcohol；Manganese compound solution is configured, adds with the scattered polyethylene glycol/polyoxyethylene vinyl polymerization thing of alcohol, stirs extremely
It is completely dissolved, produces.
As a kind of optional embodiment, deionized water is first heated to 70-85 DEG C and is incubated more than 10 minutes, is cooled to
50-35 DEG C, add manganese chloride stirring and dissolving complete；The addition good polyethylene glycol oxide of disperse polyol, stirring to being completely dissolved,
Produce.
As preferred scheme, the process of above-mentioned dissolving manganese chloride is：Deionized water is first heated to 82-85 DEG C of insulation
10-20 minutes, 35-37 DEG C is cooled to, manganese chloride stirring and dissolving is added complete.
Above-mentioned has the composition for stablizing wire-drawing effect, can be with 0.1-30% (w/w) addition, or preferred 1-
20% (w/w) addition, or preferred 10~20% (w/w) addition, in skin care item/cosmetic product.
In addition to containing above-mentioned composition, the usual composition of suitable cosmetics can be added as suitably desired, such as
The matrix components such as NMF, emollient, water, surfactant, preservative, essence.
The formulation of product is not particularly limited, and can be toner, facial mask, emulsion, cream etc..But it is particularly preferred that it is
Toner or cream.
Invention is simultaneously there is provided a kind of skin-protection product or cosmetics, and it contains polyethylene glycol or polyoxyethylene vinyl polymerization
Thing, and also contain compound containing manganese element.Preferably it also contains monohydric alcohol or dihydric alcohol or polyalcohol.
In an exemplary toner/the compact frost of the present invention prepares embodiment, the wire drawing agent used for polyethylene glycol-
90M, No. CAS is 25322-68-3, and molecular weight is 4000000.
In a preferred embodiment in accordance with this invention, described cosmetics are toner, and it is except containing above-mentioned
With outside the composition for stablizing wire-drawing effect, also containing following cosmetic composition：Allantoin, glycerin polyether -26, glycine betaine,
Hyaluronic acid, methylisothiazolinone, iodine propilolic alcohol butyl mephenesin Carbamate, rilanit special, water, can also contain essence.These
Cosmetic composition is present in cosmetics with conventional content.Inventor has found, is deposited when with the composition for stablizing wire-drawing effect
When being in above-mentioned toner matrix components, its wire drawing stablizing effect is further lifted, and is carried out 90 days in degradation
Good wire-drawing performance still can be kept afterwards.
In another preferred embodiment of the present invention, described cosmetics are the frost that compacts, and it is except containing above-mentioned
Have and stablize outside the composition of wire-drawing effect, also containing following cosmetic composition：Caprylic/capric triglyceride, palmitic acid
Octyl Nitrite, dimethyl silicone polymer, Parleam, cetostearyl alcohol, stearate, stearine, spermaceti are hard
The smooth stearate of lipidol polyethers -20, sorb, polysorbate -60, methyl hydroxybenzoate, Nipasol, glycerine, butanediol, hyalomitome
Acid, niacinamide, allantoin, EDETATE SODIUM, polyacrylamide, xylitol, aloe leaf juice powder, Curacao, Phenoxyethanol, water, also
Essence can be contained.These cosmetic compositions are present in cosmetics with conventional content.Inventor has found, when with stablizing wire drawing
When the composition of effect is present in the above-mentioned white matrix components that compact, its wire drawing stablizing effect is further lifted, old
Changing after experiment is carried out 90 days still can keep good wire-drawing performance.
As the citing of checking test, present invention employs tests below sample and check sample, carry out after sample aging
String test：
The constituent content (w/w) of the test sample of table 1. and check sample
| Test sample 1 | Test sample 2 | Test sample 3 | Check sample | |
| Mn2+ | 1% | 0.5% | 0.05% | 0 |
| Polyethylene glycol | 2% | 1.5% | 0.5% | 2% |
| Propane diols | 20% | 20% | 20% | 20% |
Two sample surpluses are deionized water.
Stability test is carried out using the wire-drawing effect evaluation after sample aging, and specific method is：
Normal temperature, -15 DEG C it is cold-resistant, at a temperature of 48 DEG C, and under the conditions of illumination is shone, place 90 days respectively, when different
Between put sampling, the wire-drawing effect of test sample, identify with table 2 be standard progress, as a result as shown in table 3.
The wire-drawing effect of table 2. evaluates score criteria
The test sample of table 3. and the contrast of check sample wire drawing stability test
As a result show, test specimen 1, test specimen 2, test specimen 3 and control sample initial period score up to 4~
5 points, but after high-temperature circulation test and sunlight irradiation degradation, all wire drawing of sample containing manganese element stability are significantly better than pair
In the same old way originally.
The there is provided composition of invention, stable wire-drawing effect, said composition solves wire drawing agent degradation problem, applies in shield
In skin product, with unique product sense organ, and being capable of more long-acting moisturizing.
Brief description of the drawings
Fig. 1 is 90 days room temperature wire-drawing effect contrast test results of wire drawing moisturizing astringent；
Fig. 2 is 90 days -15 DEG C of cold-resistant wire-drawing effect contrast test results of wire drawing moisturizing astringent；
Fig. 3 is the heat-resisting wire-drawing effect contrast test result of 48 DEG C of wire drawing moisturizing astringent 90 day；
Fig. 4 is 90 days sunlight of wire drawing moisturizing astringent according to solarization wire-drawing effect contrast test result；
Fig. 5 compacts white 90 days room temperature wire-drawing effect contrast test results for wire drawing moisturizing elastic force；
Fig. 6 compacts white 90 days -15 DEG C of cold-resistant wire-drawing effect contrast test results for wire drawing moisturizing elastic force；
Fig. 7 compacts white 90 days 48 DEG C of heat-resisting wire-drawing effect contrast test results for wire drawing moisturizing elastic force；
Fig. 8 compacts 90 days sunlight of frost according to fruit wire-drawing effect contrast test result for wire drawing moisturizing elastic force.
Embodiment
The present invention is further explained below in conjunction with specific embodiment, but these embodiments are not done to the present invention
Appoint the restriction of form.
Embodiment 1. has composition (I~V) formula and preparation method for stablizing wire-drawing effect
The present embodiment is enumerated as shown in table 4 with the composite formula for stablizing wire-drawing effect.
The constituent content (w/w) of the composition of table 4.
| Composition | Ⅰ | Ⅱ | Ⅲ | Ⅳ | Ⅴ |
| Deionized water | TO100% | TO100% | TO100% | TO100% | TO100% |
| Mn2+(manganese chloride) | 0.001 | 0.1 | 2.0 | 0.5 | 1.0 |
| Polyethylene glycol -90M | 0.01 | 0.15 | 2.0 | 0.5 | 1.0 |
| Propane diols | 0.5 | 0.0 | 10.0 | 5 | 10.0 |
| Butanediol | 0.0 | 15 | 0.0 | 5 | 10.0 |
| Glycerine | 0.0 | 0.0 | 20 | 10 | 0.0 |
| Ethanol | 0.0 | 0.0 | 0.0 | 5 | 0.0 |
The preparation method of composition：Deionized water is heated to 70-85 DEG C of insulation and is cooled within 15 minutes 50-35 DEG C, addition
Manganese chloride stirring and dissolving is complete.Add with the scattered polyethylene glycol -90M of alcohol, stir to being completely dissolved, produce.
Embodiment 2, which contains to have, stablizes wire drawing moisturizing astringent of wire-drawing effect composition and preparation method thereof
The formula for the wire drawing moisturizing astringent that the present embodiment is enumerated is as shown in table 5.Wire-drawing effect is stablized in having for being added
Composition be embodiment 1 composition II.
The wire drawing moisturizing astringent formula (w/w) of the present invention of table 5
| Toner | Ⅵ | Ⅶ | Ⅷ |
| Allantoin | 0.1 | 0.1 | 0.1 |
| Glycerin polyether -26 | 2 | 2 | 2 |
| Glycine betaine | 1 | 1 | 1 |
| Hyaluronic acid | 0.1 | 0.1 | 0.1 |
| With the composition for stablizing wire-drawing effect | 10 | 15 | 20 |
| Methylisothiazolinone | In right amount | In right amount | In right amount |
| Iodine propilolic alcohol butyl mephenesin Carbamate | In right amount | In right amount | In right amount |
| Cremophor RH40 | 0.03 | 0.03 | 0.03 |
| Essence | 0.01 | 0.01 | 0.01 |
| Deionized water | Surplus | Surplus | Surplus |
Wire drawing moisturizing astringent preparation method：Deionized water is added in agitated kettle, allantoin, glycerine is sequentially added and gathers
Ether -26, glycine betaine, hyaluronic acid, are heated with stirring to 82 DEG C, stirring and dissolving is incubated cooling in 15 minutes completely, are cooled to 45 DEG C and add
Enter to have the composition for stablizing wire-drawing effect, methylisothiazolinone, iodine propilolic alcohol butyl mephenesin Carbamate and use PEG-40 hydrogen
Change the good essence of castor oil solubilising, stir, be cooled to 38 DEG C.
The common wire drawing moisturizing astringent of comparative example 1
The common wire drawing moisturizing astringent formula that this comparative example is enumerated is as shown in table 6.
The common wire drawing moisturizing astringent formula (w/w) of table 6.
| Component | Content |
| Glycerine | 20 |
| Propane diols | 10 |
| Allantoin | 0.1 |
| Glycerin polyether -26 | 2 |
| Glycine betaine | 1 |
| Hyaluronic acid | 0.1 |
| Polyethylene glycol -90M | 0.15 |
| Methylisothiazolinone | In right amount |
| Iodine propilolic alcohol butyl mephenesin Carbamate | In right amount |
| Cremophor RH40 | 0.03 |
| Essence | 0.01 |
| Deionized water | Surplus |
Its preparation method be the same as Example 2.
The estimation of stability of the wire drawing moisturizing astringent of embodiment 3.
At a temperature of -15 DEG C, at a temperature of 48 DEG C, and under the conditions of illumination is shone, place 90 days respectively, carry out it is cold-resistant,
High temperature resistant and resistance to ultraviolet experiment, in different time points sampling, the wire-drawing effect of test sample, score evaluation is entered with table 2 for standard
OK.As a result it is as shown in table 7.
The wire drawing stability test score of the toner of the present invention of table 7. and comparative example toner
As shown in table 7, wire drawing moisturizing astringent VI-VIII than common wire drawing moisture retention water (comparative example 1) wire drawing good stability,
The wherein wire drawing stability of toner VIII is best.According to above test data, wire drawing moisturizing astringent VI-VIII and common wire drawing are protected
Broken line graph is made according to wire drawing stability under the conditions of shining in room temperature, -15 DEG C of cold-resistant, 48 DEG C of heat-resisting, sunlight in wet water (comparative example 1), point
Not as shown in Figure 1,2,3, 4.
Formula and preparation method that the wire drawing moisturizing elastic force of embodiment 4. compacts white
The wire drawing moisturizing elastic force that the present embodiment is enumerated compact frost formula it is as shown in table 8.Wire drawing is stablized in having for being added
The composition of effect is the composition III of embodiment 1.
The wire drawing moisturizing elastic force of the present invention of table 8. compact frost formula
| Wire drawing moisturizing elastic force compacts frost | Ⅸ | Ⅹ | Ⅺ | Ⅻ |
| Caprylic/capric triglyceride | 5 | 5 | 5 | 5 |
| Ethylhexyl palmitate | 6 | 6 | 6 | 6 |
| Dimethyl silicone polymer | 2 | 2 | 2 | 2 |
| Parleam | 6 | 6 | 6 | 6 |
| Cetostearyl alcohol | 1.5 | 1.5 | 1.5 | 1.5 |
| PEG-100 stearates | 1 | 1 | 1 | 1 |
| Stearine | 1 | 1 | 1 | 1 |
| Ceteareth -20 | 0.8 | 0.8 | 0.8 | 0.8 |
| The smooth stearate of sorb | 2 | 2 | 2 | 2 |
| Polysorbate -60 | 2.5 | 2.5 | 2.5 | 2.5 |
| Methyl hydroxybenzoate | In right amount | In right amount | In right amount | In right amount |
| Nipasol | In right amount | In right amount | In right amount | In right amount |
| Water | Surplus | Surplus | Surplus | Surplus |
| Glycerine | 6 | 6 | 6 | 6 |
| Butanediol | 5 | 5 | 5 | 5 |
| Hyaluronic acid | 0.05 | 0.05 | 0.05 | 0.05 |
| Niacinamide | 0.3 | 0.3 | 0.3 | 0.3 |
| Allantoin | 0.2 | 0.2 | 0.2 | 0.2 |
| EDETATE SODIUM | 0.1 | 0.1 | 0.1 | 0.1 |
| Polyacrylamide | 1.5 | 1.5 | 1.5 | 1.5 |
| With the composition for stablizing wire-drawing effect | 8 | 12 | 15 | 20 |
| Xylitol | 0.2 | 0.2 | 0.2 | 0.2 |
| Aloe barbadensis Miller leaf juice powder | 0.1 | 0.1 | 0.1 | 0.1 |
| Phenoxyethanol | In right amount | In right amount | In right amount | In right amount |
| Essence | 0.1 | 0.1 | 0.1 | 0.1 |
Wire drawing moisturizing elastic force compacts white preparation method：
(1) by caprylic/capric triglyceride, ethylhexyl palmitate, dimethyl silicone polymer, Parleam, whale
Wax stearyl alcohol, PEG-100 stearates, stearine, ceteareth -20, the smooth stearate of sorb, poly- sorb
In the clean oil phase agitated kettle that alcohol ester -60, methyl hydroxybenzoate, Nipasol, input have been sterilized, stirring is warming up to 70-85 DEG C, perseverance
Temperature 10 minutes.
(2) by deionized water add aqueous phase agitated kettle in, by glycerine, butanediol, hyaluronic acid, niacinamide, allantoin,
EDETATE SODIUM is sequentially added in aqueous phase agitated kettle, and stirring is warming up to 80-85 DEG C, constant temperature 10 minutes.
(3) vacuumize, stir, be pumped into the material in water oil phase pot in emulsification pot through screen pack using negative pressure, add poly-
Acrylamide, stirring, homogeneous, open cycle water cooling keeps vacuum.
(4) stirring is cooled to 45 DEG C and sequentially added with the composition, xylitol, Aloe Barbadensis Miller for stablizing wire-drawing effect
Juice powder, Phenoxyethanol, essence, stir, when temperature is down to 38-30 DEG C, examine qualified filtering and discharging.
Pressure position 0.04Mpa after being vacuumized described in step (3).
The common stretch of comparative example 2 compacts frost
The common stretch that this comparative example is enumerated compacts frost formula as shown in table 9.
The common stretch of table 9. compact frost formula (w/w)
| Material title | Mass fraction |
| Caprylic/capric triglyceride | 5 |
| Ethylhexyl palmitate | 6 |
| Dimethyl silicone polymer | 2 |
| Parleam | 6 |
| Cetostearyl alcohol | 1.5 |
| PEG-100 stearates | 1 |
| Stearine | 1 |
| Ceteareth -20 | 0.8 |
| The smooth stearate of sorb | 2 |
| Polysorbate -60 | 2.5 |
| Methyl hydroxybenzoate | In right amount |
| Nipasol | In right amount |
| Water | Surplus |
| Glycerine | 6 |
| Butanediol | 5 |
| Hyaluronic acid | 0.1 |
| Niacinamide | 0.3 |
| Allantoin | 0.2 |
| EDETATE SODIUM | 0.1 |
| Polyacrylamide | 1.5 |
| Polyethylene glycol -90M | 0.2 |
| Xylitol | 0.2 |
| Aloe barbadensis Miller leaf juice powder | 0.1 |
| Phenoxyethanol | In right amount |
| Tocopherol (vitamin E) | 1 |
| Essence | 0.1 |
Its preparation method be the same as Example 4.
The moisturizing elastic force of embodiment 5. compact frost wire drawing estimation of stability
Assess the present invention wire drawing moisturizing elastic force compact frost stability experimental method such as embodiment 3.As a result such as chart
Shown in 10.
The present invention of table 10. compact frost and comparative example compact frost wire drawing stability test score
As shown in table 10, wire drawing moisturizing elastic force compacts the wire drawing stability that frost Ⅸ-Ⅻ compacts white comparative example 2 than common stretch
Good, the wherein wire drawing stability of embodiment Ⅻ is best.According to above test data, by wire drawing moisturizing elastic force compact frost VI-VIII with it is general
Logical wire drawing moisturizing compact white comparative example 2 in room temperature, -15 DEG C cold-resistant, 48 DEG C of heat-resisting, sunlight are made according to wire drawing stability under the conditions of shining
Broken line graph, respectively as shown in Fig. 5,6,7,8.
The skin irritation test of embodiment 6.
Using 60 women as object, test sample is compacted frost Ⅸ-Ⅻ and comparative example 2 for the present invention.Taken with syringe
0.03ml samples are placed in the coyote hole of spot examination adhesive tape, and since bottom the spot try for being equipped with sample is affixed on longitudinal direction into forearm immediately
On normal skin, while light pressing room and is uniformly distributed trier to drive away air one by one.Mark is carried out at experiment position, with
Just observe.Every 24 hours patch skins once, half an hour after paster is opened, is then carried out according to the term of CTFA guides (1981)
Check.6 patch experiments have been carried out altogether, are pasted the 6th day after skin terminates, in order to observe delayed response, have been carried out additional inspection.
Data are then compared using last time inspection result.Identify and carried out with table 10 for standard.As a result it is as shown in table 11.
The irritant experiment evaluation criteria of table 11.
| Grade | Symbol | Standard of perfection |
| 0 | - | Negative reaction：It is non-stimulated, without erythema |
| 1 | ± | Suspicious reaction：Slight erythema |
| 2 | + | Weakly positive is reacted：Erythema |
| 3 | ++ | Strong positive reaction：Erythema, papule, blister |
| 4 | +++ | Extremely strong positive reaction：Serious edema, bulla |
The irritant test result that the wire drawing moisturizing elastic force of table 12. compacts frost Ⅸ-Ⅻ and common stretch compacts white (comparative example 2)
| Lagging number of times | Embodiment Ⅸ | Embodiment Ⅹ | Embodiment Ⅺ | Embodiment Ⅻ | Blank assay | Comparative example 2 |
| 1 | 0 | 0 | 0 | 0 | 0 | 0 |
| 2 | 0 | 0 | 0 | 0 | 0 | 0 |
| 3 | 0 | 0 | 0 | 0 | 0 | 0 |
| 4 | 0 | 0 | 0 | 0 | 0 | 0 |
| 5 | 0 | 0 | 0 | 0 | 0 | 1 time ± |
| 6 | 0 | 0 | 0 | 0 | 0 | 1 time ± |
| The 6th day after end | 0 | 0 | 0 | 0 | 0 | 1 time ± |
| It is total | 0 | 0 | 0 | 0 | 0 | 3 times ± |
As shown in table 12, wire drawing moisturizing elastic force compacts, and white Ⅸ-Ⅻ security is good, and property is gentle.
The performance of keeping humidity of embodiment 7. is tested
The test philosophy of German CK moisture of skin tester Corneomter CM825 test moisture be based on water (81) and
Other materials dielectric constant (<7) change is quite big, according to the difference of water content, and the measuring capacitor of suitable shape can be with
The change of the capacitance of skin and change, and the capacitance of skin is in the range of measurement, can thus to measure
The moisture of skin, so as to be judged to product using rear performance of keeping humidity.
Important technological parameters：
1st, test philosophy：Capacitance principle
2nd, test area：7×7mm2
3rd, probe parameter：Length about 11cm
4th, time of measuring frequency：0.9-1.2MHz
5th, test pressure：1.1-1.5N
6th, precision：± 3%
7th, number range：0-130
8th, weight：About 41g
Using German CK moisture of skin tester Corneomter CM825, using 120 20-30 Sui women as object, survey
Test agent compacts for the present invention and frost Ⅸ-Ⅻ and common compacted white (comparative example 2).First record uses the keratoderma of preceding subject
Moisture, starts continuously to use experimental products in privileged site afterwards, painting is with the skin that position is 3.0 × 3.0cm areas in upper arm
Skin, chooses skin at six, the corresponding laboratory sample of fixed painting and comparative sample, and any skin care item are not smeared at another place, daily
Once in the morning and once at night, it is continuous apply use 2 months after, the keratoderma moisture tested respectively in painting area, with tested preceding work
Contrast, (i.e. using after product, moisture content of skin ratio does not make effective percentage the effective percentage of every group of tester's moisture content of skin lifting of evaluation
With being increased before product), as a result as shown in table 13.
Table 13. compacts, and to improve skin moisture content efficient for frost
| Test sample | Efficient (%) |
| Compact frost Ⅸ | 100% |
| Compact frost Ⅹ | 100% |
| Compact frost Ⅺ | 100% |
| Compact frost Ⅻ | 100% |
| Comparative example 2 | 80% |
| Blank | - 0.6% |
Relative to blank group it can be seen from the test result of table 13, having for comparative example 2 (common stretch compact frost) is used
Efficiency can only achieve 80%, and blank group is probably that the tester for having 0.6% due to reasons such as ambient influnence and natural agings occurs
The phenomenon of skin moisture content reduction, and frost VIII-Ⅺ is compacted (containing the moisture-keeping composition for stablizing wire-drawing effect using the present invention
Elastic force compacts frost) effective percentage reach 100%, tester's skin moisture content of the wherein sample 40% of embodiment Ⅻ is improved
More than 60%, 35% tester's skin moisture content improves more than 40%, and 20% tester's moisture of skin is improved
More than 25%, remaining 5% tester's skin moisture content is also all improved, it is seen that the product containing wire drawing moisture-keeping composition is mended
Water performance of keeping humidity is more superior.
Claims (6)
1. a kind of have the composition for stablizing wire-drawing effect, it is characterised in that contains manganous compound and wire drawing agent；
The wire drawing agent is polyethylene glycol -90M；
Contained manganous compound and the parts by weight of wire drawing agent are respectively 0.1-200 parts, 1-200 parts；
Described composition also contains alcohol, and described alcohol is the one or two in propane diols or butanediol, the parts by weight of alcohol
For 10-3000 parts；
Described composition is used as the product with wire drawing and moisture-keeping function.
2. composition as claimed in claim 1, it is characterised in that contained manganous compound and the parts by weight of wire drawing agent
Respectively 1~50 part, 1~100 part；
The parts by weight of the alcohol are 200~2000 parts.
3. the composition as described in claim 1-2 is any, it is characterised in that the composition is wire drawing Moisturizer/cosmetic
Product or wire drawing Moisturizer/cosmetic material.
4. the preparation method of composition as claimed in claim 2, it is characterised in that comprise the following steps：Prepare bivalent manganese chemical combination
Thing solution, adds with the scattered polyethylene glycol -90M polymer of alcohol, stirs to being completely dissolved, produce.
5. a kind of skin care item/cosmetics, it is characterised in that contain the composition as described in claim 1-2 is any.
6. skin care item/cosmetics as claimed in claim 5, it is characterised in that described cosmetics are toner, cream, emulsion
Or facial mask.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410788253.XA CN104523453B (en) | 2014-12-16 | 2014-12-16 | A kind of wire drawing stabilizer, with composition for stablizing wire-drawing effect and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410788253.XA CN104523453B (en) | 2014-12-16 | 2014-12-16 | A kind of wire drawing stabilizer, with composition for stablizing wire-drawing effect and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104523453A CN104523453A (en) | 2015-04-22 |
| CN104523453B true CN104523453B (en) | 2017-07-18 |
Family
ID=52839217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410788253.XA Active CN104523453B (en) | 2014-12-16 | 2014-12-16 | A kind of wire drawing stabilizer, with composition for stablizing wire-drawing effect and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104523453B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109528562A (en) * | 2018-12-28 | 2019-03-29 | 中山市天图精细化工有限公司 | A kind of ozone wire drawing cleansing mousse of use in personal care and preparation method thereof |
| CN112111344A (en) * | 2019-06-20 | 2020-12-22 | 杭州船王实业有限公司 | Female wiredrawing moisturizing handmade soap and preparation method thereof |
| CN114634848A (en) * | 2020-12-16 | 2022-06-17 | 江西初芙化妆品有限公司 | Facial soap and preparation method thereof |
| CN115569076A (en) * | 2022-09-26 | 2023-01-06 | 华东理工大学 | A kind of liquid crystal hair mask and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10017998A1 (en) * | 2000-04-11 | 2001-10-18 | Henkel Kgaa | Anti-plaque liquid tooth cleaning gel |
| EP2473561B1 (en) * | 2009-09-03 | 2016-11-16 | Dow Corning Corporation | Personal care compositions with pituitous silicone fluids |
| CN102895145A (en) * | 2012-09-21 | 2013-01-30 | 启东市中远机械有限公司 | Anti-hair loss shampoo |
-
2014
- 2014-12-16 CN CN201410788253.XA patent/CN104523453B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104523453A (en) | 2015-04-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI730023B (en) | Hair growth composition and method | |
| CN104523453B (en) | A kind of wire drawing stabilizer, with composition for stablizing wire-drawing effect and preparation method thereof | |
| EP2907501A1 (en) | Cosmetic method | |
| CN103202783B (en) | Non-irritant sunscreen cream and preparation method thereof | |
| CN112156033B (en) | Essence containing ultra-small molecule sodium hyaluronate and preparation method thereof | |
| JPWO2014058066A1 (en) | Beauty method | |
| CN111511366A (en) | Ascorbic acid and/or external composition containing salt thereof | |
| CN106606426A (en) | Peel-off type eyebrow coloring composition and manufacturing method thereof | |
| CN107362090A (en) | A kind of water class cosmetics that can produce the long-acting moisturizing of pearly-lustre | |
| KR102172199B1 (en) | Cosmetic composition for skin antiaging containing sodium dna and astazanthine | |
| CN115969762A (en) | Long-acting high-efficiency moisturizing supermolecule liposome mask and preparation method thereof | |
| CN110279626A (en) | With the cosmetic composition and preparation method thereof for cooperateing with long-acting moistening effect | |
| CN109394640A (en) | A kind of ferment skin care compositions and its application | |
| CN104666172B (en) | A kind of skin whitening, moisturizing skin care item | |
| CN117598915A (en) | Permeation promotion inclusion of 4-tert-butylcyclohexanol and preparation method and application thereof | |
| TWI787623B (en) | A cosmetic composition for preventing and/or improving skin aging and its application | |
| CN115400067A (en) | Whitening composition for skin | |
| JP5349719B2 (en) | Topical skin preparation | |
| JP4167247B2 (en) | Skin preparation | |
| KR100809404B1 (en) | Percutaneous absorption adhesive sheet type cosmetic composition containing liposome-ized nanosolvent and preparation method | |
| CN115919687B (en) | Moisturizing cleansing composition and preparation method and application thereof | |
| KR100681705B1 (en) | Water-in-oil cosmetic composition containing fatty alcohol and cellulose alkyl ether as active ingredients | |
| Thorat et al. | General review on face serum | |
| CN108969414A (en) | Cordyceps sinensis composition, cordyceps sinensis face cream and preparation method, application | |
| CN110101596B (en) | Preparation method and application of beta-glucan containing compound composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20201015 Address after: 510800 No. two, No. 23, SAST Road, Huadu Town, Huadu District, Guangdong, Guangzhou Patentee after: GUANGZHOU KENENG COSMETIC RESEARCH Co.,Ltd. Patentee after: GUANGDONG DANZ GROUP Co.,Ltd. Address before: Anson road Yongxing Industrial Zone Baiyun District of Guangzhou City, Guangdong Province, No. 510412 6-1 Patentee before: GUANGZHOU BAIYUN LIANJIA FINE CHEMICAL FACTORY |