CN104521979B - Insecticide composition containing thiobenzamide and neonicotinoid insecticide - Google Patents

Abstract

The invention relates to the technical field of pesticides, and in particular relates to an insecticide composition containing thiobenzamide and a neonicotinoid insecticide. The insecticide composition is composed of thiobenzamide and the neonicotinoid insecticide, wherein thiobenzamide is 3-bromo-N-[4-chloro-2-methyl-6-(methylaminothioformyl) benzene]-1-(3-chloropyridine-2-yl)-1H-pyrazol-5-formamide; the neonicotinoid insecticide is any one of dinotefuran, clothianidin, thiamethoxam, imidacloprid, cycloxaprid, acetamiprid, nitenpyram, imidaclothiz or thiacloprid; and the mass ratio of thiobenzamide to the neonicotinoid insecticide ranges from (1:50) to (50:1). The insecticide composition and the insecticide thereof have the obvious synergistic effect when compared with a single dosage, and can be used for effectively preventing and treating various crop insects; and the use dosage of pesticides is reduced, and the drug use cost is saved.

Description

Pesticidal combination containing Aminothiocarbonylbenzene and nicotinic insecticide

Technical field

The present invention relates to technical field of pesticide, a kind of killing containing Aminothiocarbonylbenzene and nicotinic insecticide is specifically related to Worm compositionss and its preparation.

Background technology

Chinese invention patent CN103109816A discloses thiobenzoyl amine compound and its application, thiobenzoyl The general structure 1 of aminated compoundss is：

Thiobenzoyl amine compound with above-mentioned formula 1, not only has high activity to lepidoptera pest, and to thorn Suction insect (such as planthopper) also has unexpected high activity, and there is this kind of compound simultaneous controlling well to act on and comprehensive work( Energy.The applicant is chlorine according to the preferred R1 of formula 1, and R2 is methyl, is synthesized with reference to the method in Chinese patent CN103109816A The compound I (hereinafter referred to as Aminothiocarbonylbenzene) of the present invention, structural formula is as follows：

Although compound I (i.e. Aminothiocarbonylbenzene) also has prominent parasite killing as thiobenzoyl amine compound Effect.But its it is long-term it is single use, be also easy to produce Drug resistance, insecticidal activity declines.Jing lot of experiments find, Aminothiocarbonylbenzene with Nicotinic insecticide is compounded, and not only acts as potentiation, and also delays pest and disease damage to Aminothiocarbonylbenzene and nicotinic insecticide Drug resistance, improve prevention effect.

Up to now, there is not yet Aminothiocarbonylbenzene and the bactericide compounded relevant report of nicotinoids.

The content of the invention

It is an object of the invention to provide a kind of Pesticidal combination and its insecticide, the Pesticidal combination and its insecticide phase For single dose has obvious potentiation, various crop pests can be effectively prevented and treated, reduce the using dosage of pesticide, be saved Drug cost.

To realize above-mentioned purpose, the technical solution used in the present invention is as follows：

Pesticidal combination containing Aminothiocarbonylbenzene and nicotinic insecticide, the Pesticidal combination by Aminothiocarbonylbenzene and Nicotinic insecticide is constituted, and the Aminothiocarbonylbenzene is the bromo- N- of 3- [4- chloro-2-methyl -6- (methylamino thioformyl) Benzene] -1- (3- chloropyridine -2- bases) -1H- pyrazoles -5- Methanamides.Reactive compound is with specified weight in Pesticidal combination of the present invention Than in the presence of, syneryistic effect highly significant.Preferably, the weight ratio of Aminothiocarbonylbenzene and nicotinic insecticide is 1:50 ～50:1.

Preferably, the weight ratio of the Aminothiocarbonylbenzene and nicotinic insecticide is 1:30～30:1.

In the present invention, the structural formula of the Aminothiocarbonylbenzene is as follows：

The nicotinic insecticide referred in the present invention, is all pesticide species that are known and being disclosed.Currently preferred cigarette Bases insecticide is MTI-446, clothianidin, Diacloden, imidacloprid, cycloxaprid, Acetamiprid, Nitenpyram, imidaclothiz or thiophene worm Any one in any one in quinoline, more preferably MTI-446, clothianidin, Diacloden, imidacloprid.Wherein cycloxaprid CAS No.：116705, it is super-active of new generation, the agricultural insecticide of special bottom toxicity of East China University of Science's research and development.Change Scientific name claims：9- ((6- chloropyridine -3- bases) methyl) -4- nitro -8- oxa- -10,11- glyoxalidine simultaneously (2,3-a) it is bicyclic (3,2, 1) octyl- 3- alkene, English common name：cycloxaprid.

The present invention also provides a kind of agricultural insecticide, is made up of acceptable adjuvant on above-mentioned Pesticidal combination and pesticide. Wherein adjuvant is solid carrier or a kind of mixture with auxiliary agent in liquid-carrier.Preferably kill to ensure that insecticide has Worm effect, preferably, Pesticidal combination accounts for the 0.1%～80% of the gross weight of the agricultural insecticide, it is further preferred that Pesticidal combination accounts for the 1%～60% of the insecticidal total weight.It is highly preferred that Pesticidal combination accounts for the insecticidal total weight 5%～41%.

Carrier of the present invention can be solid or liquid, and any carrier for being generally used for preparing insecticides is equal Can use.Liquid-carrier includes organic solvent and water, organic solvent include N-Methyl pyrrolidone, two wires oil, methyl oleate, One or more in C10 aromatic hydrocarbons, methyl naphthalene.Solid carrier include Kaolin, kieselguhr, ammonium chloride, calcium superphosphate, one Ammonium, carbamide, Borax, potassium chloride, carbamide, humic acidss, white carbon, precipitated calcium carbonate, bentonite, it is talcous one or more.

The auxiliary agent can according to the requirement of different dosage form comprising include surfactant, defoamer, thickening agent, disintegrating agent, Binding agent and antifreezing agent, can also as needed include the other functions auxiliary agent that the industry is commonly used.

In the present invention, surfactant includes emulsifying agent, wetting agent and dispersant, and surfactant is alkyl phenol polyoxy It is vinyl Ether, dispersing agent MF, aliphatic alcohol polyoxyvinethene phosphate, naphthalene sulfonic acid formaldehyde polymer sodium salt, wooden Plain sodium sulfonate, alkylnaphthalene sulfonate, SOPA-270, sodium lauryl sulphate, polymeric polycarboxylic acid salt, polycarboxylate, phenethyl Phenol polyethenoxy ether, calcium dodecyl benzene sulfonate, castor oil polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, methylene dinaphthalene sulphur Sour sodium, fatty alcohol polyoxyethylene ether sulfate, methyl naphthalene sulfonate formaldehyde condensate, calcium lignosulfonate, TERWET-1007, Alkyl benzene calcium sulfonate, Negel, methyl naphthalene sulfonic acid sodium, naphthalene sulfonic acid condensate sodium salt, fatty alcohol ethyl oxide, EO/ PO block polyethers, maleic acid-acrylic acid copolymer sodium salt, agriculture breast 601#, tallow ethyoxyl ammonium salt, phenolsulfonic acid condensation substance sodium One or more in salt, lauryl alcohol polyethylene glycol oxide base ether, pull open powder.

Film former is included in sodium carboxymethyl cellulose, xanthan gum, polyvinyl alcohol, carboxymethyl cellulose, methylcellulose One or more.Binding agent includes one or more in starch, polyvinyl alcohol, methylcellulose, xanthan gum.Disintegrating agent includes One or more in ammonium sulfate, sodium sulfate, Sodium Chloride.Thickening agent includes the one kind in polyvinyl alcohol, Magnesiumaluminumsilicate, xanthan gum Or it is several.Antifreezing agent includes one or more in glycerol, Propylene Glycol, carbamide.Defoamer is organosilicon.Preservative includes pungent One or more in starch alkenyl succinate sodium, Phenylsalicylate.Warning coloration includes carmine, Xylene Red or magenta.

According to different use demands, the insecticide that the present invention is provided is according to can be according to method preparation generally in the art Become various dosage forms.The dosage form of insecticide of the present invention can for seed treatment formulations, ultra low volume liquids, granule, cream, can One kind of WP, water dispersible granules or suspending agent.

Described seed treatment formulations include seed treatment solid preparation and seed treatment liquid preparation.Seed treatment solid Preparation is seed treatment dry powder doses, seed treatment dispersibles the solvable powder of powder, seed treatment；Seed treatment liquid preparation is to plant Subprocessing liquor, seed treatment Emulsion, seed treatment suspending agent, suspension seed-coating agent and seed treatment microcapsule suspending agent.As excellent Choosing, the present invention provide seed treatment formulations embodiment be seed treatment dry powder doses, suspension seed-coating agent, seed treatment microcapsule hang Floating agent.

The present invention provides the application of above-mentioned Pesticidal combination and insecticide in preventing and treating crop pests.Especially to crops Planthopper, thrips, aphid have specially good effect.

The Pesticidal combination and insecticide of the present invention can be applied by commonsense method, such as spraying cauline leaf process, also can soil Process, such as solid root spreads fertilizer over the fields or liquid pouring root, moreover it is possible to dress seed, soak seed or seed pelleting is used.

The present invention has the advantages that relative to prior art：

1st, Pesticidal combination of the invention and its insecticide, with obvious potentiation compared with single dose, after mixture The insecticidal effect of Pesticidal combination is significantly improved compared with its single dose, and its lasting period is long.

2nd, using dosage is reduced, reduces cost accounting.

3rd, reasonably mixture is carried out using the two kinds of active components model of action different to insect, the different mechanism of action, Both the Pesticide use life-span had been extended, the generation of pest resistance to insecticide had been delayed again.

Specific embodiment：

The present invention is further described with reference to specific embodiment, but does not limit the invention to these tools Body embodiment.Following Aminothiocarbonylbenzenes each mean the bromo- N- of its chemical entitled 3-, and [(methylamino is thio for 4- chloro-2-methyls -6- Formoxyl) benzene] -1- (3- chloropyridine -2- bases) -1H- pyrazoles -5- Methanamides material, Aminothiocarbonylbenzene synthesizes by laboratory, Other medicaments are commercial；Unless otherwise indicated, all percentage ratios are weight percentage.

First, the preparation of seed treatment formulations

The Aminothiocarbonylbenzene MTI-446 suspension seed-coating agent (9 of embodiment 1 10%:1)

Aminothiocarbonylbenzene 9%, MTI-446 1%, alkylphenol polyoxyethylene 2.5%, dispersing agent MF 2%th, carboxymethyl cellulose 2%, xanthan gum 1.5%, glycerol 2%, carmine 0.5%, water are mended to 100%.

Preparation technology：By formula proportion by Aminothiocarbonylbenzene and MTI-446, surfactant alkylphenol polyoxyethylene, Dispersing agent MF mix homogeneously, is subsequently adding suitable quantity of water, uses sand mill wet grinding, then transfers the material into cutting kettle It is interior, add film former carboxymethyl cellulose, xanthan gum, antifreezing agent glycerol, carmine and remaining water, Jing high speed shear is to viscous Degree, particle diameter conformance with standard, obtain final product the suspension seed-coating agent containing 10% Aminothiocarbonylbenzene MTI-446.

According to the identical preparation technology of embodiment 1, embodiment 2- embodiment 3 is prepared.

The Aminothiocarbonylbenzene clothianidin suspension seed-coating agent (1 of embodiment 2 10%:1)

Aminothiocarbonylbenzene 5%, clothianidin 5%, aliphatic alcohol polyoxyvinethene phosphate 2%, naphthalene sulfonic acid formaldehyde polymer Sodium salt 2.5%, sodium lignin sulfonate 1%, polyvinyl alcohol 2%, Propylene Glycol 2%, Xylene Red 0.5%, water are mended to 100%.

The Aminothiocarbonylbenzene imidacloprid suspension seed-coating agent (14 of embodiment 3 15%:1)

Aminothiocarbonylbenzene 14%, imidacloprid 1%, alkylphenol polyoxyethylene 3%, alkylnaphthalene sulfonate 1.5%, poly- second Enol 1%, carboxymethyl cellulose 1%, Propylene Glycol 2%, pinkish red 1%, water are mended to 100%.

The Aminothiocarbonylbenzene Diacloden seed treatment dry powder doses (1 of embodiment 4 11%:10)

Aminothiocarbonylbenzene 1%, Diacloden 10%, SOPA-2702%, naphthalene sulfonic acid formaldehyde polymer sodium salt 2%, dodecane Base sodium sulfate 1.3%, sodium carboxymethyl cellulose 2%, azogeramine .5%, Kaolin are mended to 100%.

Preparation technology：By above-mentioned formula proportion by Aminothiocarbonylbenzene, Diacloden, surfactant aliphatic alcohol polyethenoxy Ether phosphate, naphthalene sulfonic acid formaldehyde polymer sodium salt, sodium lauryl sulphate, binding agent sodium carboxymethyl cellulose, Xylene Red, kaolinite Soil is crushed and mix homogeneously obtains final product 11% Aminothiocarbonylbenzene Diacloden seed treatment dry powder doses.

According to the identical preparation technology of embodiment 4, embodiment 5- embodiment 8 is prepared.

The Aminothiocarbonylbenzene MTI-446 seed treatment dry powder doses (1 of embodiment 5 15%:14)

Aminothiocarbonylbenzene 1%, MTI-446 14%, aliphatic alcohol polyoxyvinethene phosphate 1.5%, di-2-ethylhexylphosphine oxide methyl naphthalene Sodium sulfonate 2%, sodium lignin sulfonate 1.5%, polyvinyl alcohol 2%, pinkish red 0.5%, Kaolin are mended to 100%.

The Aminothiocarbonylbenzene cycloxaprid seed treatment dry powder doses (1 of embodiment 6 12%:1)

It is Aminothiocarbonylbenzene 6%, cycloxaprid 6%, polymeric polycarboxylic acid salt 3%, sodium lauryl sulphate 2.5%, poly- Vinyl alcohol 2%, carmine 1.2%, Kaolin are mended to 100%.

The Aminothiocarbonylbenzene Acetamiprid seed treatment dry powder doses (20 of embodiment 7 21%:1)

Aminothiocarbonylbenzene 20%, Acetamiprid 1%, naphthalene sulfonic acid formaldehyde polymer sodium salt 2%, polymeric polycarboxylic acid salt 1.5%th, sodium lignin sulfonate 1%, methylcellulose 2%, carmine 1%, Kaolin are mended to 100%.

The Aminothiocarbonylbenzene thiacloprid seed treatment dry powder doses (3 of embodiment 8 8%:1)

It is Aminothiocarbonylbenzene 6%, thiacloprid 2%, naphthalene sulfonic acid formaldehyde polymer sodium salt 2%, polycarboxylate 1.2%, wooden Plain sodium sulfonate 1.3%, methylcellulose 2%, pinkish red 1%, kieselguhr are mended to 100%.

2nd, the preparation of ultra low volume liquids

Embodiment 9:6% Aminothiocarbonylbenzene MTI-446 ultra low volume liquids (5:1)

Aminothiocarbonylbenzene 5%, MTI-446 1%, N-Methyl pyrrolidone 12%, phenethyl phenol polyethenoxy ether 3%, ten Dialkyl benzene sulfonic acids calcium 1.5%, two wires oil complement to 100%.

Preparation technology：By formula proportion first with solvent by Aminothiocarbonylbenzene, MTI-446 stirring and dissolving after, add surface Activating agent, is thoroughly mixed uniformly, obtains final product 6% Aminothiocarbonylbenzene MTI-446 ultra low volume liquids.

According to the identical preparation technology of embodiment 9, embodiment 10- embodiment 11 is prepared.

Embodiment 10:8% Aminothiocarbonylbenzene clothianidin ultra low volume liquids (1:3)

Aminothiocarbonylbenzene 2%, clothianidin 6%, N-Methyl pyrrolidone 15%, methyl oleate 5%, Oleum Ricini polyoxy second Alkene ether 2%, fatty alcohol-polyoxyethylene ether 1.5%, calcium dodecyl benzene sulfonate 1%, C10 aromatic hydrocarbons complement to 100%.

Embodiment 11:11% Aminothiocarbonylbenzene Diacloden ultra low volume liquids (10:1)

Aminothiocarbonylbenzene 10%, Diacloden 1%, N-Methyl pyrrolidone 20%, methyl naphthalene 6%, alkyl phenol polyoxy second Alkene ether 3.5%, calcium dodecyl benzene sulfonate 2%, ethyl oleate complement to 100%.

3rd, the preparation of granule

Embodiment 12:1% Aminothiocarbonylbenzene dinotefuran granules (1:9)

Aminothiocarbonylbenzene 0.1%, MTI-446 0.9%, sodium lignin sulfonate 3%, fatty alcohol-polyoxyethylene ether 2% gathers Vinyl alcohol 3%, ammonium chloride 3%, calcium superphosphate 2%, an ammonium 1%, carbamide supplies 100%.

Preparation technology：By above-mentioned recipe ingredient mix homogeneously, crush, add pelletize in roller pelletizer, be drying to obtain and contain The granule of 1% Aminothiocarbonylbenzene MTI-446.

According to the identical preparation technology of embodiment 12, embodiment 10- embodiment 17 is prepared.

Embodiment 13:5% Aminothiocarbonylbenzene dinotefuran granules (1:4)

Aminothiocarbonylbenzene 1%, MTI-446 4%, naphthalene sulfonic acid formaldehyde polymer sodium salt 3%, sodium metnylene bis-naphthalene sulfonate 2%, fatty alcohol-polyoxyethylene ether 1%, methylcellulose 3%, ammonium chloride 3%, calcium superphosphate 2%, humic acidss 1%, carbamide is mended Foot 100%.

Embodiment 14:6% Aminothiocarbonylbenzene clothianidin granule (1:5)

Aminothiocarbonylbenzene 1%, clothianidin 5%, naphthalene sulfonic acid formaldehyde polymer sodium salt 2%, polymeric polycarboxylic acid salt 1.5%th, methylcellulose 2%, carbamide 2%, Borax are mended to 100%.

Embodiment 15:0.5% Aminothiocarbonylbenzene Diacloden granule (1:4)

Aminothiocarbonylbenzene 0.1%, Diacloden 0.4%, sodium metnylene bis-naphthalene sulfonate 3%, sodium lauryl sulphate 1%, Polyvinyl alcohol 1%, ammonium chloride 2%, potassium chloride 2%, carbamide are mended to 100%.

The Aminothiocarbonylbenzene imidacloprid granule (1 of embodiment 16 6%:2)

Aminothiocarbonylbenzene 2%, imidacloprid 4%, sodium lignin sulfonate 2%, naphthalene sulfonic acid formaldehyde polymer sodium salt 3%, shallow lake Powder 2%, humic acidss 5%, carbamide are mended to 100%.

The Aminothiocarbonylbenzene cycloxaprid granule (30 of embodiment 17 9.3%:1)

Aminothiocarbonylbenzene 9%, cycloxaprid 0.3%, fatty alcohol polyoxyethylene ether sulfate 1%, naphthalenesulfonateformaldehyde formaldehyde gather Compound sodium salt 3.5%, starch 2%, Kaolin are mended to 100%.

4th, the preparation of wettable powder

Embodiment 18：51% Aminothiocarbonylbenzene clothianidin wettable powder (1:50)

Aminothiocarbonylbenzene 1%, clothianidin 50%, sodium lauryl sulphate 4%, sodium lignin sulfonate 3.6%, white carbon 10%th, Kaolin supplies 100%.

Preparation technology：Above-mentioned recipe ingredient mix homogeneously, then Jing comminution by gas stream are obtained into 51% sulfur to certain particle diameter For Benzoylamide clothianidin wettable powder.

According to the identical preparation technology of embodiment 18, embodiment 18- embodiment 28 is prepared.

Embodiment 19：21% Aminothiocarbonylbenzene clothianidin wettable powder (20:1)

Aminothiocarbonylbenzene 20%, clothianidin 1%, methyl naphthalene sulfonate formaldehyde condensate 2.5%, polymeric polycarboxylic acid salt 2.4%th, precipitated calcium carbonate 3%, bentonite supplies 100%.

The Aminothiocarbonylbenzene clothianidin wettable powder (1 of embodiment 20 33%:10)

Aminothiocarbonylbenzene 3%, clothianidin 30%, methyl naphthalene sulfonic acid sodium 3%, alkyl benzene calcium sulfonate 2.5%TERWET- 10072%th, Kaolin complements to 100%.

Embodiment 21:31% Aminothiocarbonylbenzene MTI-446 wettable powder (30:1)

Aminothiocarbonylbenzene 30%, MTI-446 1%, polymeric polycarboxylic acid salt 3%, Negel 4%, lightweight carbonic acid Calcium 5%, Kaolin supplies 100%.

CK1:20% Aminothiocarbonylbenzene wettable powder

Aminothiocarbonylbenzene 20%, polymeric polycarboxylic acid salt 3%, Negel 4%, precipitated calcium carbonate 5%, kaolinite Soil supplies 100%.

The Aminothiocarbonylbenzene MTI-446 wettable powder (1 of embodiment 22 20%:9)

Aminothiocarbonylbenzene 2%, MTI-446 18%, calcium lignosulfonate 5%, methyl naphthalene sulfonic acid sodium 3%, polycarboxylate 5%th, precipitated calcium carbonate 10%, bentonite complements to 100%.

The Aminothiocarbonylbenzene cycloxaprid wettable powder (1 of embodiment 23 21%:20)

Aminothiocarbonylbenzene 1%, cycloxaprid 20%, calcium lignosulfonate 5%, alkylphenol polyoxyethylene 3%, pull open Powder 5%, white carbon 6%, Kaolin complement to 100%.

CK2:20% cycloxaprid wettable powder

Cycloxaprid 20%, calcium lignosulfonate 5%, alkylphenol polyoxyethylene 3%, pull open powder 5%, white carbon 6%, Kaolin complements to 100%.

The Aminothiocarbonylbenzene Diacloden wettable powder (4 of embodiment 24 60%：1)

Aminothiocarbonylbenzene 48%, Diacloden 12%, naphthalene sulfonic acid condensate sodium salt 5%, polycarboxylate 3%, lightweight carbonic acid Calcium 10%, kieselguhr complements to 100%.

Embodiment 25：55% Aminothiocarbonylbenzene thiacloprid wettable powder (1:10)

Aminothiocarbonylbenzene 5%, thiacloprid 50%, naphthalene sulfonic acid condensate sodium salt 4.3%, calcium lignosulfonate 2%, high score Sub- polycarboxylate 1%, Kaolin supplies 100%.

Embodiment 26：30% Aminothiocarbonylbenzene imidaclothiz wettable powder (1:14)

It is Aminothiocarbonylbenzene 2%, imidaclothiz 28%, naphthalene sulfonic acid condensate sodium salt 3.5%, polymeric polycarboxylic acid salt 2%, white White carbon black 2%, kieselguhr supplies 100%.

Embodiment 27：18% Aminothiocarbonylbenzene imidacloprid wettable powder (2:1)

Aminothiocarbonylbenzene 12%, imidacloprid 6%, dispersing agent MF 3%, polymeric polycarboxylic acid salt 2%, White carbon 10%, Kaolin supplies 100%.

Embodiment 28：80% Aminothiocarbonylbenzene Nitenpyram wettable powder (9:1)

Aminothiocarbonylbenzene 72%, Nitenpyram 8%, naphthalene sulfonic acid formaldehyde polymer sodium salt 3.5%, sodium lignin sulfonate 2%th, white carbon 6%, Kaolin supplies 100%.

5th, the preparation of suspending agent

Embodiment 29：11% Aminothiocarbonylbenzene MTI-446 suspending agent (1:10)

Aminothiocarbonylbenzene 1%, MTI-446 10%, fatty alcohol ethyl oxide 4%, EO/PO block polyethers 1%, Malaysia Acid-acrylic copolymer sodium salt 2%, polymeric polycarboxylic acid salt 3%, polyvinyl alcohol 0.5%, carbamide 2%, organosilicon 0.1%, water Supply 100%.

Preparation technology：Above-mentioned formula is put in high shear homogeneous emulsifying machine, high speed shear 25 minutes, then pump is to sand milling Sand milling 90 minutes in machine, obtain final product 11% Aminothiocarbonylbenzene MTI-446 suspending agent (1:10).

According to the identical preparation technology of embodiment 30, embodiment 30- embodiment 37 is prepared.

Embodiment 30：20.5% Aminothiocarbonylbenzene MTI-446 suspending agent (40:1)

Aminothiocarbonylbenzene 20%, MTI-446 0.5%, agriculture breast 601#2%, polymeric polycarboxylic acid salt 4%, dodecyl sulfur Sour calcium 1%, Magnesiumaluminumsilicate 0.4%, carbamide 2%, organosilicon 0.1%, water supply 100%.

Embodiment 31：22% Aminothiocarbonylbenzene clothianidin suspending agent (10:1)

Aminothiocarbonylbenzene 20%, clothianidin 2%, fatty alcohol-polyoxyethylene ether 3%, sodium metnylene bis-naphthalene sulfonate 2.5%, EO/PO block co-polyethers 2%, xanthan gum 0.3%, glycerol 2%, organosilicon 0.01%, water are mended to 100%.

Embodiment 32：15% Aminothiocarbonylbenzene acetamiprid suspending agent (4:1)

Aminothiocarbonylbenzene 12%, Acetamiprid 3%, tallow ethyoxyl ammonium salt 2%, phenolsulfonic acid condensation substance sodium salt 2%, Methyl naphthalene sulfonate formaldehyde condensate 2.5%, starch sodium octenyl succinate 2%, glycerol 2%, organosilicon 0.2%, water are mended Foot 100%.

Embodiment 33：10% Aminothiocarbonylbenzene cycloxaprid suspending agent (4:1)

Aminothiocarbonylbenzene 8%, cycloxaprid 2%, alkylnaphthalene sulfonate 2%, fatty alcohol polyoxyethylene ether sulfate 1.3%th, phenolsulfonic acid condensation substance sodium salt 2%, glycerol 2%, organosilicon 0.1%, water supply 100%.

Embodiment 34：11% Aminothiocarbonylbenzene imidacloprid suspending agent (10:1)

Aminothiocarbonylbenzene 10%, imidacloprid 1%, fatty alcohol-polyoxyethylene ether 2.5%, alkylnaphthalene sulfonate 3%, methylene Base sodium dinaphthalenesulfonate 1%, maleic-acrylic acid homopolymer sodium salt 3%, xanthan gum 0.5%, glycerol 2%, organosilicon 0.1%, Water supplies 100%.

Embodiment 35：6.2% Aminothiocarbonylbenzene imidacloprid suspending agent (30：1)

Aminothiocarbonylbenzene 6%, imidacloprid 0.2%, fatty alcohol-polyoxyethylene ether 2%, alkylnaphthalene sulfonate 3.2%, horse Come sour-acrylate homopolymer sodium salt 3%, Magnesiumaluminumsilicate 0.6%, Propylene Glycol 2%, organosilicon 0.1%, water and supply 100%.

Embodiment 36：21% Aminothiocarbonylbenzene imidacloprid suspending agent (1:20)

Aminothiocarbonylbenzene 1%, imidacloprid 20%, lauryl alcohol polyethylene glycol oxide base ether 2.3%, alkylnaphthalene sulfonate 3%, Asia Methyl sodium dinaphthalenesulfonate 4%, xanthan gum 0.05%, Magnesiumaluminumsilicate 0.6%, glycerol 2%, organosilicon 0.1%, water are supplied 100%.

Embodiment 37：6.3% Aminothiocarbonylbenzene thiacloprid suspending agent (20:1)

Aminothiocarbonylbenzene 6%, thiacloprid 0.3%, fatty alcohol-polyoxyethylene ether 2%, alkylnaphthalene sulfonate 3.2%, Asia Methyl sodium dinaphthalenesulfonate 1%, Magnesiumaluminumsilicate 0.6%, glycerol 2%, Phenylsalicylate 0.4%, organosilicon 0.1%, water are supplied 100%.

6th, the preparation of water dispersible granules

Embodiment 38：21% Aminothiocarbonylbenzene MTI-446 water dispersible granules (20:1)

Aminothiocarbonylbenzene 20%, MTI-446 1%, lignosulfonates 3%, naphthalene sulfonate 3.0%, ammonium sulfate 15%, Xanthan gum 1%, Pulvis Talci 1%, Kaolin are supplied 100% and are sufficiently mixed, then by comminution by gas stream, granulating and forming obtains water-dispersible grain Agent.Contain 21% content reactive compound in water dispersible granules, product cut size is 0.8-2mm.

Preparation technology：Superfine grinding is carried out by above-mentioned formula proportion mix homogeneously, pelletize is then compressed or rotating disk is made Grain, is dried and obtains final product 21% Aminothiocarbonylbenzene MTI-446 water dispersible granules.

According to the identical preparation technology of embodiment 38, embodiment 39- embodiment 51 is prepared.

Embodiment 39：30% Aminothiocarbonylbenzene MTI-446 water dispersible granules (1:1)

Aminothiocarbonylbenzene 15%, MTI-446 15%, EO/PO block polyethers 4%, naphthalene sulfonate 3%, starch 5%, xanthan Glue 1%, kieselguhr supplies 100%.

Embodiment 40:1% Aminothiocarbonylbenzene MTI-446 water dispersible granules (1:4)

Aminothiocarbonylbenzene 0.02%, MTI-446 0.08%, lignosulfonates 5.0%, sodium metnylene bis-naphthalene sulfonate 3%th, sodium sulfate 10%, xanthan gum 1%, bentonite supply 100%.

Embodiment 41:21% Aminothiocarbonylbenzene clothianidin water dispersible granules (1:20)

Aminothiocarbonylbenzene 1%, clothianidin 20%, fatty alcohol-polyoxyethylene ether 5%, lignosulfonates 3.5%, methyl Cellulose 3%, ammonium sulfate 2%, white carbon 5%, bentonite supplies 100%.

Embodiment 42:62% Aminothiocarbonylbenzene clothianidin water dispersible granules (1:30)

Aminothiocarbonylbenzene 2%, clothianidin 60%, sodium lauryl sulphate 5%, fatty alcohol-polyoxyethylene ether 5%, sulphuric acid Sodium 4%, xanthan gum 1%, Kaolin supply 100%.

Embodiment 43:25% Aminothiocarbonylbenzene Diacloden water dispersible granules (4:1)

Aminothiocarbonylbenzene 20%, Diacloden 5%, EO/PO block polyethers 3.8%, fatty alcohol-polyoxyethylene ether 6%, chlorine Change sodium 11%, xanthan gum 2%, white carbon 10%, kieselguhr and supply 100%.

Embodiment 44:15% Aminothiocarbonylbenzene Diacloden water dispersible granules (1:14)

Aminothiocarbonylbenzene 1%, Diacloden 14%, sodium lauryl sulphate 4.2%, fatty alcohol-polyoxyethylene ether 5.8%, Methylcellulose 2%, Kaolin supplies 100%.

Embodiment 45:31% Aminothiocarbonylbenzene Diacloden water dispersible granules (30:1)

It is Aminothiocarbonylbenzene 30%, Diacloden 1%, lignosulfonates 6%, naphthalene sulfonate 3%, polyvinyl alcohol 1%, light Matter Calcium Carbonate 5%, Kaolin supplies 100%.

Embodiment 46:41% Aminothiocarbonylbenzene imidacloprid water dispersible granule (40:1)

Aminothiocarbonylbenzene 40%, imidacloprid 1%, lignosulfonates 5.0%, naphthalene sulfonate 3%, sodium sulfate 10%, Xanthan gum 1%, bentonite supplies 100%.

Embodiment 47：32% Aminothiocarbonylbenzene cycloxaprid water dispersible granule (1:15)

Aminothiocarbonylbenzene 2%, cycloxaprid 30%, naphthalene sulfonic acid formaldehyde polymer sodium salt 4%, lignosulfonates 1.8%th, starch 3%, white carbon 5%, Kaolin supply 100%.

Embodiment 48：51% Aminothiocarbonylbenzene cycloxaprid water dispersible granule (1:50)

Aminothiocarbonylbenzene 1%, cycloxaprid 50%, naphthalene sulfonic acid formaldehyde polymer sodium salt 3%, lignosulfonates 2.5%th, polyvinyl alcohol 3%, white carbon 5%, bentonite supply 100%.

Embodiment 49:51% Aminothiocarbonylbenzene Nitenpyram water dispersible granules (1:50)

Aminothiocarbonylbenzene 1%, Nitenpyram 50%, EO/PO block polyethers 4%, lignosulfonates 2.8%, starch 5%th, polyvinyl alcohol 2%, precipitated calcium carbonate 3%, kieselguhr supply 100%.

Embodiment 50：25% Aminothiocarbonylbenzene Nitenpyram water dispersible granules (24:1)

Aminothiocarbonylbenzene 24%, Nitenpyram 1%, fatty alcohol-polyoxyethylene ether 4.0%, lignosulfonates 3.0%, Sodium sulfate 15.0%, methylcellulose 2.0%, white carbon 2%, Kaolin supply 100%.

Embodiment 51：10.2% Aminothiocarbonylbenzene Nitenpyram water dispersible granules (50:1)

Aminothiocarbonylbenzene 10%, Nitenpyram 0.2%, fatty alcohol-polyoxyethylene ether 4%, lignosulfonates 3%, sulfur Sour sodium 15.0%, polyvinyl alcohol 2%, white carbon 10%, Kaolin supply 100%.

Bioassay test：

To determine the potentiation of Aminothiocarbonylbenzene and nicotinic insecticide compounding, the applicant uses both compositions Toxicity Determination is carried out.

Data processing method：Prevention effect is converted into into niqueMin (y), liquor strength (μ g/m l) is converted into logarithm value X (), concentration LC50 in being calculated virulence equation and suppressed with method of least square calculates the toxicity index and altogether of medicament according to the abundant methods of Sun Yun Malicious coefficient (CTC).

Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agents LC50) × 100

Percentage composition+B the medicament toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed The percentage composition of B in agent

Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100

Evaluation criterion：When CTC≤80, then compositionss show as antagonism, when 80 ＜ CTC ＜ 120, then compositionss performance For summation action, when CTC >=120, then compositionss show as potentiation.

The Toxicity Determination test of the preventing and treating planthopper of bioassay example 1

Test method：Reference《The part of NY/T1154.11-2008 farm-chemical indoor determination test rules insecticide the 11st： Rice-stem dipping method》.

The Aminothiocarbonylbenzene of table 1 and the dinotefuran mixed Toxicity Determination result for preventing and treating planthopper

Process	LC50(μg/ml)	ATI	TTI	CTC
					Aminothiocarbonylbenzene (A)	38.25	100.00	/	/
MTI-446 (B)	8.61	444.25	/	/
					A:B=50:1	28.50	134.21	106.75	125.72
A:B=40:1	26.30	145.44	108.40	134.17
					A:B=30:1	21.49	177.99	111.10	160.20

A:B=20:1	19.41	197.06	116.39	169.31
					A:B=14:1	15.28	250.33	122.95	203.60
A:B=10:1	12.86	297.43	131.30	226.54
					A:B=9:1	14.54	263.07	134.43	195.70
A:B=5:1	12.92	296.05	157.38	188.12
					A:B=4:1	12.78	299.30	168.85	177.26
A:B=2:1	10.42	367.08	214.75	170.93
					A:B=1:1	8.19	467.03	272.13	171.62
A:B=1:2	7.06	541.78	329.50	164.43
					A:B=1:4	6.32	605.22	375.40	161.22
A:B=1:5	6.15	621.95	386.88	160.76
					A:B=1:9	5.84	654.97	409.83	159.82
A:B=1:10	6.02	635.38	412.96	153.86
					A:B=1:14	5.97	640.70	421.30	152.08
A:B=1:20	5.66	675.80	427.86	157.95
					A:B=1:30	5.72	668.71	433.15	154.38
A:B=1:34	5.90	648.31	434.42	149.24
					A:B=1:40	6.32	605.22	435.85	138.86
A:B=1:50	6.84	559.21	437.50	127.82

The Aminothiocarbonylbenzene of table 2 prevents and treats the Toxicity Determination result of planthopper with clothianidin mixture

Process	LC50(μg/ml)	ATI	TTI	CTC
					Aminothiocarbonylbenzene (A)	38.17	100.00	/	/
Clothianidin (C)	8.31	459.33	/	/
					A:C=50:1	32.06	119.06	107.05	111.22
A:C=40:1	27.91	136.76	108.76	125.74
					A:C=30:1	21.3	179.20	111.59	160.59
A:C=20:1	20.8	183.51	117.11	156.70
					A:C=15:1	18.55	205.77	122.46	168.03
A:C=10:1	16.53	230.91	132.67	174.06
					A:C=5:1	14.2	268.80	159.89	168.12

A:C=3:1	12.17	313.64	189.83	165.22
					A:C=1:1	8.50	449.06	279.66	160.57
A:C=1:3	6.65	573.98	369.49	155.34
					A:C=1:5	6.10	625.74	399.44	156.65
A:C=1:10	5.87	650.26	426.66	152.41
					A:C=1:15	5.53	690.24	436.87	158.00
A:C=1:20	6.10	625.74	442.22	141.50
					A:C=1:30	5.20	734.04	447.73	163.94
A:C=1:40	6.60	578.33	450.56	128.36
					A:C=1:50	6.81	560.50	452.28	123.93

The Aminothiocarbonylbenzene of table 3 prevents and treats the Toxicity Determination result of planthopper with Diacloden mixture

Process	LC50(μg/ml)	ATI	TTI	CTC
					Aminothiocarbonylbenzene (A)	38.09	100.00	/	/
Diacloden (D)	69.12	55.11	/	/
					A:D=50:1	30.26	125.88	99.12	126.99
A:D=40:1	28.15	135.31	98.91	136.81
					A:D=30:1	26.56	143.41	98.55	145.52
A:D=20:1	23.48	162.22	97.86	165.77
					A:D=14:1	23.06	165.18	97.01	170.27
A:D=10:1	22.31	170.73	95.92	177.99
					A:D=4:1	22.57	168.76	91.02	185.41
A:D=2:1	21.30	178.83	85.04	210.30
					A:D=1:1	24.71	154.15	77.55	198.76
A:D=1:2	27.63	137.86	70.07	196.74
					A:D=1:4	32.27	118.04	64.09	184.18
A:D=1:10	35.85	106.25	59.19	179.51
					A:D=1:14	38.20	99.71	58.10	171.62
A:D=1:20	39.11	97.39	57.24	170.13
					A:D=1:30	42.54	89.54	56.56	158.32
A:D=1:40	46.73	81.51	56.20	145.03

A:D=1:50

49.50

76.95

55.99

137.44

The Aminothiocarbonylbenzene of table 4 prevents and treats the Toxicity Determination result of planthopper with imidacloprid mixture

Process	LC50(μg/ml)	ATI	TTI	CTC
					Aminothiocarbonylbenzene (A)	38.16	100.00	/	/
Imidacloprid (E)	35.23	108.32	/	/
					A:E=50:1	29.65	128.70	100.16	128.49
A:E=40:1	27.21	140.24	100.20	139.96
					A:E=30:1	25.08	152.15	100.27	151.75
A:E=24:1	23.17	164.70	100.33	164.15
					A:E=20:1	24.43	156.20	100.40	155.59
A:E=10:1	22.06	172.98	100.76	171.68
					A:E=4:1	19.60	194.69	101.66	191.51
A:E=2:1	20.56	185.60	102.77	180.60
					A:E=1:1	21.14	180.51	104.16	173.30
A:E=1:2	19.81	192.63	105.54	182.51
					A:E=1:4	20.75	183.90	106.65	172.43
A:E=1:10	21.66	176.18	107.56	163.79
					A:E=1:14	22.54	169.30	107.76	157.10
A:E=1:20	23.19	164.55	107.92	152.48
					A:E=1:30	23.42	162.94	108.05	150.80
A:E=1:40	25.65	148.77	108.11	137.61
					A:E=1:50	27.34	139.58	108.15	129.05

The Aminothiocarbonylbenzene of table 5 prevents and treats the Toxicity Determination result of planthopper with cycloxaprid mixture

Process	LC50(μg/ml)	ATI	TTI	CTC
					Aminothiocarbonylbenzene (A)	37.99	100.00	/	/
Cycloxaprid (F)	0.35	10854.29	/	/
					A:F=50:1	9.65	393.68	310.87	126.64
A:F=40:1	7.33	518.28	362.30	143.05
					A:F=30:1	5.85	649.40	446.91	145.31

A:F=20:1	4.12	922.09	612.11	150.64
					A:F=19:1	3.27	1161.77	637.71	182.18
A:F=10:1	1.82	2087.36	1077.66	193.69
					A:F=9:1	1.75	2170.86	1175.43	184.69
A:F=4:1	0.98	3876.53	2250.86	172.22
					A:F=1:1	0.43	8834.88	5477.14	161.30
A:F=1:4	0.3	12663.33	8703.43	145.50
					A:F=1:9	0.25	15196.00	9778.86	155.40
A:F=1:10	0.26	14611.54	9876.62	147.94
					A:F=1:15	0.27	14070.37	10182.14	138.19
A:F=1:20	0.28	13567.86	10342.18	131.19
					A:F=1:30	0.27	14070.37	10507.37	133.91
A:F=1:40	0.28	13567.86	10591.99	128.10
					A:F=1:50	0.29	13100.00	10643.42	123.08

The Aminothiocarbonylbenzene of table 6 prevents and treats the Toxicity Determination result of planthopper with Nitenpyram mixture

Process	LC50(μg/ml)	ATI	TTI	CTC
					Aminothiocarbonylbenzene (A)	38.46	100.00	/	/
Nitenpyram (H)	8.82	436.05	/	/
					A:H=50:1	27.36	140.57	106.59	131.88
A:H=40:1	26.52	145.02	108.20	134.04
					A:H=30:1	23.11	166.42	110.84	150.15
A:H=24:1	22.25	172.85	113.44	152.37
					A:H=20:1	20.78	185.08	116.00	159.55
A:H=19:1	20.06	191.72	116.80	164.14
					A:H=10:1	18.37	209.36	130.55	160.37
A:H=9:1	17.61	218.40	133.61	163.47
					A:H=4:1	12.75	301.65	167.21	180.40
A:H=1:1	7.60	506.05	268.03	188.81
					A:H=1:4	5.19	741.04	368.84	200.91
A:H=1:9	4.88	788.11	402.45	195.83

A:H=1:10	5.47	703.11	405.50	173.39
					A:H=1:15	5.79	664.25	415.05	160.04
A:H=1:20	5.81	661.96	420.05	157.59
					A:H=1:30	5.90	651.86	425.21	153.30
A:H=1:40	6.14	626.38	427.86	146.40
					A:H=1:50	7.08	543.22	429.47	126.49

The Aminothiocarbonylbenzene of table 7 prevents and treats the Toxicity Determination result of planthopper with imidaclothiz mixture

Process	LC50(μg/ml)	ATI	TTI	CTC
					Aminothiocarbonylbenzene (A)	38.7	100.00	/	/
Imidaclothiz (I)	37.3	103.75	/	/
					A:I=50:1	31.2	124.04	100.07	123.95
A:I=40:1	29.23	132.40	100.09	132.28
					A:I=30:1	27.51	140.68	100.12	140.51
A:I=20:1	25.46	152.00	100.18	151.73
					A:I=10:1	22.37	173.00	100.34	172.41
A:I=9:1	19.41	199.38	100.38	198.64
					A:I=4:1	19.67	196.75	100.75	195.28
A:I=1:1	21.43	180.59	101.88	177.26
					A:I=1:4	22.96	168.55	103.00	163.64
A:I=1:9	22.82	169.59	103.38	164.05
					A:I=1:10	24.65	157.00	103.41	151.82
A:I=1:14	25.20	153.57	103.50	148.37
					A:I=1:20	26.06	148.50	103.57	143.38
A:I=1:30	26.73	144.78	103.63	139.71
					A:I=1:40	27.25	142.02	103.66	137.00
A:I=1:50	29.68	130.39	103.68	125.76

The Aminothiocarbonylbenzene of table 8 prevents and treats the Toxicity Determination result of planthopper with thiacloprid mixture

Process	LC50(μg/ml)	ATI	TTI	CTC
					Aminothiocarbonylbenzene (A)	38.8	100.00	/	/

Thiacloprid (J)	52.58	73.79	/	/
					A:J=50:1	29.45	131.75	99.49	132.43
A:J=40:1	26.37	147.14	99.36	148.08
					A:J=30:1	23.16	167.53	99.15	168.96
A:J=20:1	21.75	178.39	98.75	180.65
					A:J=10:1	20.37	190.48	97.62	195.13
A:J=9:1	21.41	181.22	97.38	186.10
					A:J=3:1	23.62	164.27	93.45	175.78
A:J=1:1	25.31	153.30	86.90	176.42
					A:J=1:3	27.96	138.77	80.34	172.72
A:J=1:9	30.23	128.35	76.41	167.97
					A:J=1:10	29.85	129.98	76.17	170.64
A:J=1:14	33.17	116.97	75.54	154.85
					A:J=1:20	35.56	109.11	75.04	145.40
A:J=1:30	35.97	107.87	74.64	144.52
					A:J=1:40	37.44	103.63	74.43	139.23
A:J=1:50	38.28	101.36	74.31	136.41

Toxicity Determination result table 1- tables 8 show, when water rice hopper is prevented and treated Aminothiocarbonylbenzene respectively with MTI-446 It is 1 in mass ratio Deng nicotinic insecticide：50～50：Co-toxicity coefficient is compounded in the range of 1 and is more than 120, increased with significantly collaboration Effect is acted on；It is 1 especially in mass ratio：30～30：When 1, potentiation is especially more projected.

Assays Example 2 prevents and treats black bean aphid activity test

Experimental technique：With reference to《The part of NYT 1154.14-2008 farm-chemical indoor determination test rules insecticide the 14th: Leaf dipping method》

The Aminothiocarbonylbenzene of table 9 is with imidacloprid mixture to black bean aphid toxicity test

Process	LC50(μg/ml)	ATI	TTI	CTC
					Aminothiocarbonylbenzene (A)	22.16	100.00	/	/
Imidacloprid (E)	10.29	215.35	/	/

A:E=50:1	17.08	129.74	102.26	126.87
					A:E=40:1	16.26	136.29	102.81	132.56
A:E=30:1	15.12	146.56	103.72	141.30
					A:E=20:1	14.84	149.33	105.49	141.55
A:E=10:1	12.14	182.54	110.49	165.21
					A:E=4.5:1	9.39	236.00	120.97	195.08
A:E=1:1	8.11	273.24	157.68	173.29
					A:E=1:4.5	6.77	327.33	194.38	168.39
A:E=1:10	6.9	321.16	204.87	156.76
					A:E=1:20	6.77	327.33	209.86	155.97
A:E=1:30	7.16	309.50	211.63	146.24
					A:E=1:40	7.39	299.86	212.54	141.09
A:E=1:50	8.23	269.26	213.09	126.36

The Aminothiocarbonylbenzene of table 10 is with Acetamiprid mixture to black bean aphid toxicity test

Process	LC50(μg/ml)	ATI	TTI	CTC
					Aminothiocarbonylbenzene (A)	22.64	100.00	/	/
Acetamiprid (G)	19.65	115.22	/	/
					A:G=50:1	17.53	129.15	100.30	128.77
A:G=40:1	15.98	141.68	100.37	141.15
					A:G=30:1	17.51	129.29	100.49	128.66
A:G=20:1	16.15	140.17	100.72	139.16
					A:G=10:1	15.33	147.73	101.38	145.71
A:G=4:1	14.53	155.84	103.04	151.24
					A:G=1:1	13.20	171.46	107.61	159.34
A:G=1:4	12.17	186.03	112.17	165.84
					A:G=1:10	13.23	171.10	113.83	150.31
A:G=1:20	14.09	160.65	114.49	140.32
					A:G=1:30	15.10	149.93	114.73	130.69
A:G=1:40	14.87	152.25	114.85	132.57
					A:G=1:50	15.24	148.56	114.92	129.27

The Aminothiocarbonylbenzene of table 11 is with Nitenpyram mixture to black bean aphid toxicity test

Process	LC50(μg/ml)	ATI	TTI	CTC
					Aminothiocarbonylbenzene (A)	22.74	100.00	/	/
Nitenpyram (H)	10.25	221.85	/	/
					A:H=50:1	17.65	128.84	102.39	125.83
A:H=40:1	17.59	129.28	102.97	125.55
					A:H=30:1	13.36	170.21	103.93	163.77
A:H=20:1	13.8	164.78	105.80	155.75
					A:H=10:1	10.45	217.61	111.08	195.91
A:H=2:1	9.17	247.98	140.62	176.35
					A:H=1:1	9.39	242.17	160.93	150.49
A:H=1:5	6.35	358.11	201.54	177.68
					A:H=1:10	6.64	342.47	210.78	162.48
A:H=1:20	6.57	346.12	216.05	160.20
					A:H=1:30	6.23	365.01	217.92	167.49
A:H=1:40	7.96	285.68	218.88	130.52
					A:H=1:50	8.13	279.70	219.46	127.45

Toxicity Determination result table 9- tables 11 show, when black bean aphid is prevented and treated, Aminothiocarbonylbenzene is respectively with imidacloprid etc. Nicotinic insecticide is 1 in mass ratio：50～50：Co-toxicity coefficient is compounded in the range of 1 and is more than 120, with obvious Synergistic Effect；It is 1 especially in mass ratio：30～30：When 1, potentiation is especially more projected.

Field test embodiment

In the following table, medicament Aminothiocarbonylbenzene is referred to as thio.

Comparison medicament

CK1：20% Aminothiocarbonylbenzene wettable powder, self-control.

CK2：20% cycloxaprid wettable powder, self-control.

CK3：20% MTI-446 soluble granule, registration card number is LS20130077, Mitsui chemistry AGRO Co., Ltd..

CK4：20% clothianidin suspending agent, registration card number is LS20130279, the limited public affairs of Hebei Weiyuan biochemical industry share Department.

CK5：25% Diacloden water dispersible granules, registration card number is PD20122066, and extra large rel Pharmaceutical group share is limited Company.

CK6：25% imidacloprid wettable powder, registration card number is PD20130581, Shandong Cao Da Chemical Co., Ltd.s.

CK7：40% acetamiprid water dispersible granules, registration card number is PD20131398, the limited public affairs of Guangdong Zhong Xunnong sections share Department.

CK8：60% Nitenpyram wettable powder registration card number be PD20130674, Jiangsu Fengshan Group Co.

CK9：50% thiacloprid water dispersible granules, registration card number is LS20110019, and Shaanxi Wei Erqi crop protections are limited Company.

CK10：40% imidaclothiz water dispersible granules, registration card number is PD20096024, Jiangsu Province Nantong rivers and mountains pesticide chemical Limited company.

Experimental technique：Reference《GB/T 17980.4-2000 pesticide field efficacy medicine test criterion (one) insecticide control Oryza sativa L. Plant hopper》.Controlling object：Planthopper；Application method：Conventional spraying.

Drug effect computational methods：

Result of the test：It is shown in Table 12- tables 15 (data are the meansigma methodss of 4 repetitions in table)

Preventing and treating water rice hopper field test results of table 12 (one)

Result of the test table 12 shows, Aminothiocarbonylbenzene respectively with MTI-446, clothianidin, Diacloden, imidacloprid, epoxy insect Pyridine, Acetamiprid, thiacloprid compounding preventing and treating water rice hopper preventive effect are high and are all higher than 81%；Compared with single dose, the preventive effect after compounding is high In single dose more than 9%.

Preventing and treating water rice hopper field test results of table 13 (two)

Result of the test table 13 shows that Aminothiocarbonylbenzene flies respectively with MTI-446, clothianidin, Thiamethoxam compound preventing and treating Oryza sativa L. Louse effect is good, and preventive effect is all higher than 85%；Compared with single dose, the preventive effect after compounding is higher than single dose more than 13%.

Preventing and treating water rice hopper field test results of table 14 (three)

Result of the test table 14 shows, Aminothiocarbonylbenzene respectively with MTI-446, clothianidin, Diacloden, imidacloprid, epoxy insect Pyridine, Acetamiprid, Nitenpyram, thiacloprid, imidaclothiz compounding preventing and treating water rice hopper effect are good, and the preventive effect after compounding is all higher than 84%；Compared with single dose, the preventive effect after compounding is higher than single dose more than 11%.

Preventing and treating water rice hopper field test results of table 15 (four)

Result of the test table 15 shows, Aminothiocarbonylbenzene respectively with MTI-446, clothianidin, Diacloden, imidacloprid, epoxy insect Pyridine compounding preventing and treating water rice hopper effect is good, and the preventive effect after compounding is all higher than 83%；Compared with single dose, the preventive effect after compounding is higher than single Agent more than 13%.

The compound synergic effect of the present composition, it is not limited to the listed activity experiment of invention.The verified present invention Compositionss, have broad application prospects in sucking pest preventing and treating, particularly in planthopper, thrips, aphid, red The upper effect of Aranea preventing and treating is projected very much.Simultaneously the present invention also has preferable preventive effect to some lepidoptera pests, is a kind of wide spectrum Insecticide.In addition, the above-mentioned Pesticidal combination and its preparation prevention effect of 7d after medicine remains to reach more than 85%, it is of the invention The Pesticidal combination lasting period is long.

Although bromo- N- of reactive compound I 3- [4- chloro-2-methyl -6- (methylamino thioformyl) benzene] in the present invention - 1- (3- chloropyridine -2- bases) -1H- pyrazoles -5- Methanamides and special insecticidal active compound II are known compound, on State reactive compound compounding to realize the desired more excellent insecticidal effect of the present invention for those skilled in the art's then right and wrong Obviously.

Claims (8)

1. the Pesticidal combination of Aminothiocarbonylbenzene and nicotinic insecticide is contained, it is characterised in that：The Pesticidal combination is by sulfur For Benzoylamide and nicotinic insecticide composition, the Aminothiocarbonylbenzene is the bromo- N- of 3- [4- chloro-2-methyl -6- (methylaminos Thioformyl) benzene] -1- (3- chloropyridine -2- bases) -1H- pyrazoles -5- Methanamides, the Aminothiocarbonylbenzene and nicotinoids are killed The weight ratio of worm agent is 1:50～50:1, the nicotinic insecticide is cycloxaprid.

2. the Pesticidal combination containing Aminothiocarbonylbenzene and nicotinic insecticide according to claim 1, it is characterised in that： The weight ratio of the Aminothiocarbonylbenzene and nicotinic insecticide is 1:30～30:1.

3. a kind of agricultural insecticide, it is characterised in that：Killing containing Aminothiocarbonylbenzene and nicotinoids by described in claim 1 or 2 The Pesticidal combination of worm agent is constituted with adjuvant, wherein, the Pesticidal combination accounts for the 1%～80% of the insecticidal total weight.

4. a kind of agricultural insecticide according to claim 3, it is characterised in that：The Pesticidal combination accounts for the insecticide The 1%～60% of gross weight.

5. a kind of agricultural insecticide according to claim 4, it is characterised in that：The Pesticidal combination accounts for the insecticide The 5%～41% of gross weight.

6. a kind of agricultural insecticide according to claim 4 or 5, it is characterised in that：The insecticide can be configured to seed Process preparation, ultra low volume liquids, granule, cream, wettable powder, water dispersible granules or suspending agent.

7. application of a kind of agricultural insecticide any one of claim 3-6 in preventing and treating crop pest.

8. application of a kind of agricultural insecticide according to claim 7 in preventing and treating crop pest, it is characterised in that：It is described Application of the agricultural insecticide on preventing and treating planthopper, thrips, aphid.