CN104513578A - Lasting antifouling antirusting paint and preparation method thereof - Google Patents
Lasting antifouling antirusting paint and preparation method thereof Download PDFInfo
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- CN104513578A CN104513578A CN201410701777.0A CN201410701777A CN104513578A CN 104513578 A CN104513578 A CN 104513578A CN 201410701777 A CN201410701777 A CN 201410701777A CN 104513578 A CN104513578 A CN 104513578A
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- diatomite
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- antifouling
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- 239000003973 paint Substances 0.000 title claims abstract description 22
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 15
- 230000002045 lasting effect Effects 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000000843 powder Substances 0.000 claims abstract description 19
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004359 castor oil Substances 0.000 claims abstract description 10
- 235000019438 castor oil Nutrition 0.000 claims abstract description 10
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 9
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 8
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 7
- 239000005062 Polybutadiene Substances 0.000 claims abstract description 7
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 7
- 239000000839 emulsion Substances 0.000 claims abstract description 7
- 239000010445 mica Substances 0.000 claims abstract description 7
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 7
- 229920002857 polybutadiene Polymers 0.000 claims abstract description 7
- -1 polyoxyethylene Polymers 0.000 claims abstract description 7
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 235000019388 lanolin Nutrition 0.000 claims abstract description 4
- XAEWLETZEZXLHR-UHFFFAOYSA-N zinc;dioxido(dioxo)molybdenum Chemical compound [Zn+2].[O-][Mo]([O-])(=O)=O XAEWLETZEZXLHR-UHFFFAOYSA-N 0.000 claims abstract description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 13
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000835 fiber Substances 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- 230000002401 inhibitory effect Effects 0.000 claims description 10
- 239000004593 Epoxy Substances 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000000227 grinding Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 6
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims description 6
- 108010010803 Gelatin Proteins 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- 229910052788 barium Inorganic materials 0.000 claims description 6
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000919 ceramic Substances 0.000 claims description 6
- 229920001971 elastomer Polymers 0.000 claims description 6
- 229920000159 gelatin Polymers 0.000 claims description 6
- 239000008273 gelatin Substances 0.000 claims description 6
- 235000019322 gelatine Nutrition 0.000 claims description 6
- 235000011852 gelatine desserts Nutrition 0.000 claims description 6
- 229940075507 glyceryl monostearate Drugs 0.000 claims description 6
- 239000011490 mineral wool Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 235000013824 polyphenols Nutrition 0.000 claims description 6
- 239000005060 rubber Substances 0.000 claims description 6
- 235000019354 vermiculite Nutrition 0.000 claims description 6
- 239000010455 vermiculite Substances 0.000 claims description 6
- 229910052902 vermiculite Inorganic materials 0.000 claims description 6
- 239000004166 Lanolin Substances 0.000 claims description 3
- 241000158728 Meliaceae Species 0.000 claims description 3
- 239000004264 Petrolatum Substances 0.000 claims description 3
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 230000009514 concussion Effects 0.000 claims description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 229940039717 lanolin Drugs 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 3
- 235000019271 petrolatum Nutrition 0.000 claims description 3
- 229940066842 petrolatum Drugs 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 239000005007 epoxy-phenolic resin Substances 0.000 abstract 1
- 150000002191 fatty alcohols Chemical class 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 abstract 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D147/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a lasting antifouling antirusting paint which is characterized by comprising the following raw materials by weight: 4-6 parts of styrene-acrylic emulsion, 0.4-0.8 part of polyoxyethylene fatty alcohol ether, 1-2 parts of sodium tripolyphosphate, 3-4 parts of butoxyethyl acetate, 3-5 parts of super fine mica powder, 0.4-1 part of an anti-skinning agent, 1-2 parts of antioxidant 1010, 3-4 parts of zinc molybdate, 2-3 parts of wool grease, 1-2 parts of 3-ammonia propyl trimethoxy silane, 9-12 parts of toluene, 2-3 parts of sulfonated castor oil, 33-35 parts of polybutadiene resin, 28-32 parts of epoxy phenolic resin, 8-11 parts of n-butanol, 3-5 parts of diatomite, 4-6 parts of light calcium carbonate, and 4-7 parts of an assistant; the lasting antifouling antirusting paint has long antirusting time, also has the antifouling function, is easy to scrub, has good hardness and wear resistance and high scrub resistance degree, and is not easy to scratch, the lasting antifouling antirusting paint has the advantages of wide raw material sources, simple preparation process, convenient operation, low cost, complete function, and suitability for promotion.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly a kind of lasting antifouling rust-inhibiting paint and preparation method thereof.
Background technology
coating is a kind ofly coated in protected and decorated matrix surface and can forms novel high polymer material and the matching construction material of the continuous film of firm attachment, and Application Areas is extremely extensive.City build establish in the middle of; the use of the metallic substance such as iron and steel serves very important effect in development; the mechanical means such as most of boats and ships, automobile, outdoor power protection usually needs to change, and they are not scrapped to useful life period, but by Exposure to Sunlight, the corrosion that drenches with rain damage.According to pertinent data, the financial loss that the annual because material corrosions such as metal in the whole world cause is greatly about 7,000 hundred million dollars, and account for 2 ~ 4% of various countries' gross national product, the annual metallic corrosion loss of China also accounts for about 4% of gross national product.Compared with other various protection against corrosion means, rust proof paint is most economical, that most convenient effective, application is the most general impregnating material, therefore, people habitually can under field conditions (factors) (namely among air, water and soil etc.) prevent the priming paint of metallic corrosion from calling rust proof paint (or anti-corrosion primer, protective system, rust-proofing primer), rust proof paint accounts for coating total amount about 1/4th, is the most important integral part of coating.
Summary of the invention
The object of this invention is to provide a kind of lasting antifouling rust-inhibiting paint and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of lasting antifouling rust-inhibiting paint, is made up of the raw material of following weight part: styrene-acrylate emulsion 4-6, polyoxyethylene aliphatic alcohol ether 0.4-0.8, tripoly phosphate sodium STPP 1-2,2-Butoxyethyl acetate 3-4, ultrafine mica powder 3-5, anti skinning agent 0.4-1.0, antioxidant 1010 1-2, zinc molybdate 3-4, lanolin 2-3,3-aminopropyl trimethoxysilane 1-2, toluene 9-12, sulfonated castor oil 2-3, polybutadiene 33-35, epoxy phenolics 28-32, propyl carbinol 8-11, diatomite 3-5, light calcium carbonate 4-6, auxiliary agent 4-7;
Described auxiliary agent is made up of the raw material of following weight part: nano ceramic fibers 6-8, rock wool fibers 4-6, oxidized petrolatum barium soap 2-3, barium mahogany sulfonate 2-3, gelatin 2-3, white oil 10-15, glyceryl monostearate 1-3, ethanol 10-14, epoxy castor oil 2-4, morpholine 2-4, vermiculite power 3-4, Silane coupling agent KH550 1-2, dimethyl silicone oil 1-2, vinylbenzene 7-11, rubber powder 4-6, diatomite in powder 3-5, high wear-resistant carbon black 3-4; Preparation method is that vermiculite power, vinylbenzene, rubber powder and diatomite in powder mix by (1), is added in fluidized-bed; (2) nano ceramic fibers, rock wool fibers, glyceryl monostearate, gelatin and ethanol are mixed, be heated to 50-60 ° of C, form mixed solution through strong concussion, then input fluidized-bed and make it be atomized, be sprayed on the mixture of step (1); (3) white oil is heated to 100-120 ° of C, then adds Silane coupling agent KH550, the product of step (2) and other surplus materials, after stirring reaction 1-2 hour, fully grinding can obtain.
The lasting antifouling rust-inhibiting paint of one of the present invention, be made up of following concrete steps:
(1) ultrafine mica powder, diatomite, light calcium carbonate are added in the mixing solutions of propyl carbinol and toluene, ultrasonic disperse 20-30 minute, when being heated to 50-80 ° of C, add sulfonated castor oil, antioxidant 1010, auxiliary agent continuation stirring reaction 30-40 minute;
(2) product of step (1) is continued raised temperature to 70-90 ° of C, add styrene-acrylate emulsion, polyoxyethylene aliphatic alcohol ether, 2-Butoxyethyl acetate, polybutadiene, epoxy phenolics, 3-aminopropyl trimethoxysilane, 1200-1400 rev/min of lower high-speed mixing stirring reaction 1-2 hour;
(3) surplus materials is added in the product of step (2), is added to grinding machine for grinding after mixing and is uniformly dispersed, filter and obtain the material that fineness is 20-40 μm, pack.
Advantage of the present invention is: rust-inhibiting paint antirust time of the present invention is long, also has antifouling function, easily cleans, and hardness and wear resistance good, washability number of times is high, not easily has cut, and raw material sources of the present invention are extensive, and preparation technology is simple, easy to operate, cost is low, and function is complete, suitable popularization.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of lasting antifouling rust-inhibiting paint, is made up of the raw material of following weight part (kilogram): styrene-acrylate emulsion 5, polyoxyethylene aliphatic alcohol ether 0.6, tripoly phosphate sodium STPP 1,2-Butoxyethyl acetate 3, ultrafine mica powder 4, anti skinning agent 0.7, antioxidant 1010 1, zinc molybdate 4, lanolin 2,3-aminopropyl trimethoxysilane 1, toluene 10, sulfonated castor oil 3, polybutadiene 34, epoxy phenolics 28, propyl carbinol 9, diatomite 3, light calcium carbonate 4, auxiliary agent 5;
Described auxiliary agent is made up of the raw material of following weight part (kilogram): nano ceramic fibers 6, rock wool fibers 5, oxidized petrolatum barium soap 2, barium mahogany sulfonate 2, gelatin 3, white oil 12, glyceryl monostearate 1, ethanol 13, epoxy castor oil 2, morpholine 3, vermiculite power 3, Silane coupling agent KH550 2, dimethyl silicone oil 1, vinylbenzene 10, rubber powder 5, diatomite in powder 4, high wear-resistant carbon black 3; Preparation method is that vermiculite power, vinylbenzene, rubber powder and diatomite in powder mix by (1), is added in fluidized-bed; (2) nano ceramic fibers, rock wool fibers, glyceryl monostearate, gelatin and ethanol are mixed, be heated to 50-60 ° of C, form mixed solution through strong concussion, then input fluidized-bed and make it be atomized, be sprayed on the mixture of step (1); (3) white oil is heated to 100-120 ° of C, then adds Silane coupling agent KH550, the product of step (2) and other surplus materials, after stirring reaction 1-2 hour, fully grinding can obtain.
The lasting antifouling rust-inhibiting paint of one of the present invention, be made up of following concrete steps:
(1) ultrafine mica powder, diatomite, light calcium carbonate are added in the mixing solutions of propyl carbinol and toluene, ultrasonic disperse 20-30 minute, when being heated to 50-80 ° of C, add sulfonated castor oil, antioxidant 1010, auxiliary agent continuation stirring reaction 30-40 minute;
(2) product of step (1) is continued raised temperature to 70-90 ° of C, add styrene-acrylate emulsion, polyoxyethylene aliphatic alcohol ether, 2-Butoxyethyl acetate, polybutadiene, epoxy phenolics, 3-aminopropyl trimethoxysilane, 1200-1400 rev/min of lower high-speed mixing stirring reaction 1-2 hour;
(3) surplus materials is added in the product of step (2), is added to grinding machine for grinding after mixing and is uniformly dispersed, filter and obtain the material that fineness is 20-40 μm, pack.
Paint of the present invention is that uniform fluid is without lump, sticking power: 2 grades, snappiness: 1 grade, shock strength >=65, hardness >=2H, high temperature resistant (130 ° of C) >=450H, oil-proofness (90# gasoline, 56h): non-foaming, do not come off, paint film knockout wear resistance experiment (L/um) >=3, artificial weathering ageing resistance tested: by 1200 hours, and alkali resistance is tested: 120h paint film is without breakage.
Claims (2)
1. a lasting antifouling rust-inhibiting paint, it is characterized in that, be made up of the raw material of following weight part: styrene-acrylate emulsion 4-6, polyoxyethylene aliphatic alcohol ether 0.4-0.8, tripoly phosphate sodium STPP 1-2,2-Butoxyethyl acetate 3-4, ultrafine mica powder 3-5, anti skinning agent 0.4-1.0, antioxidant 1010 1-2, zinc molybdate 3-4, lanolin 2-3,3-aminopropyl trimethoxysilane 1-2, toluene 9-12, sulfonated castor oil 2-3, polybutadiene 33-35, epoxy phenolics 28-32, propyl carbinol 8-11, diatomite 3-5, light calcium carbonate 4-6, auxiliary agent 4-7;
Described auxiliary agent is made up of the raw material of following weight part: nano ceramic fibers 6-8, rock wool fibers 4-6, oxidized petrolatum barium soap 2-3, barium mahogany sulfonate 2-3, gelatin 2-3, white oil 10-15, glyceryl monostearate 1-3, ethanol 10-14, epoxy castor oil 2-4, morpholine 2-4, vermiculite power 3-4, Silane coupling agent KH550 1-2, dimethyl silicone oil 1-2, vinylbenzene 7-11, rubber powder 4-6, diatomite in powder 3-5, high wear-resistant carbon black 3-4; Preparation method is that vermiculite power, vinylbenzene, rubber powder and diatomite in powder mix by (1), is added in fluidized-bed; (2) nano ceramic fibers, rock wool fibers, glyceryl monostearate, gelatin and ethanol are mixed, be heated to 50-60 ° of C, form mixed solution through strong concussion, then input fluidized-bed and make it be atomized, be sprayed on the mixture of step (1); (3) white oil is heated to 100-120 ° of C, then adds Silane coupling agent KH550, the product of step (2) and other surplus materials, after stirring reaction 1-2 hour, fully grinding can obtain.
2. a kind of lasting antifouling rust-inhibiting paint according to claim 1, is characterized in that, be made up of following concrete steps:
(1) ultrafine mica powder, diatomite, light calcium carbonate are added in the mixing solutions of propyl carbinol and toluene, ultrasonic disperse 20-30 minute, when being heated to 50-80 ° of C, add sulfonated castor oil, antioxidant 1010, auxiliary agent continuation stirring reaction 30-40 minute;
(2) product of step (1) is continued raised temperature to 70-90 ° of C, add styrene-acrylate emulsion, polyoxyethylene aliphatic alcohol ether, 2-Butoxyethyl acetate, polybutadiene, epoxy phenolics, 3-aminopropyl trimethoxysilane, 1200-1400 rev/min of lower high-speed mixing stirring reaction 1-2 hour;
(3) surplus materials is added in the product of step (2), is added to grinding machine for grinding after mixing and is uniformly dispersed, filter and obtain the material that fineness is 20-40 μm, pack.
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CN108587072A (en) * | 2018-05-02 | 2018-09-28 | 安徽九牛塑业科技有限公司 | A kind of exterior wall high performance composited aluminum and plastic decking protective film and preparation method thereof |
CN109161305A (en) * | 2018-09-19 | 2019-01-08 | 铜陵市明诚铸造有限责任公司 | A kind of anti-corrosive primer of mining production machinery |
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CN109161305A (en) * | 2018-09-19 | 2019-01-08 | 铜陵市明诚铸造有限责任公司 | A kind of anti-corrosive primer of mining production machinery |
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