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CN104513578A - Lasting antifouling antirusting paint and preparation method thereof - Google Patents

Lasting antifouling antirusting paint and preparation method thereof Download PDF

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Publication number
CN104513578A
CN104513578A CN201410701777.0A CN201410701777A CN104513578A CN 104513578 A CN104513578 A CN 104513578A CN 201410701777 A CN201410701777 A CN 201410701777A CN 104513578 A CN104513578 A CN 104513578A
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China
Prior art keywords
parts
diatomite
powder
added
antifouling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410701777.0A
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Chinese (zh)
Inventor
闫秦峻
邹峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BENGBU NANZI INSTRUMENT Co Ltd
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BENGBU NANZI INSTRUMENT Co Ltd
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Priority to CN201410701777.0A priority Critical patent/CN104513578A/en
Publication of CN104513578A publication Critical patent/CN104513578A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D147/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a lasting antifouling antirusting paint which is characterized by comprising the following raw materials by weight: 4-6 parts of styrene-acrylic emulsion, 0.4-0.8 part of polyoxyethylene fatty alcohol ether, 1-2 parts of sodium tripolyphosphate, 3-4 parts of butoxyethyl acetate, 3-5 parts of super fine mica powder, 0.4-1 part of an anti-skinning agent, 1-2 parts of antioxidant 1010, 3-4 parts of zinc molybdate, 2-3 parts of wool grease, 1-2 parts of 3-ammonia propyl trimethoxy silane, 9-12 parts of toluene, 2-3 parts of sulfonated castor oil, 33-35 parts of polybutadiene resin, 28-32 parts of epoxy phenolic resin, 8-11 parts of n-butanol, 3-5 parts of diatomite, 4-6 parts of light calcium carbonate, and 4-7 parts of an assistant; the lasting antifouling antirusting paint has long antirusting time, also has the antifouling function, is easy to scrub, has good hardness and wear resistance and high scrub resistance degree, and is not easy to scratch, the lasting antifouling antirusting paint has the advantages of wide raw material sources, simple preparation process, convenient operation, low cost, complete function, and suitability for promotion.

Description

A kind of lasting antifouling rust-inhibiting paint and preparation method thereof
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly a kind of lasting antifouling rust-inhibiting paint and preparation method thereof.
Background technology
coating is a kind ofly coated in protected and decorated matrix surface and can forms novel high polymer material and the matching construction material of the continuous film of firm attachment, and Application Areas is extremely extensive.City build establish in the middle of; the use of the metallic substance such as iron and steel serves very important effect in development; the mechanical means such as most of boats and ships, automobile, outdoor power protection usually needs to change, and they are not scrapped to useful life period, but by Exposure to Sunlight, the corrosion that drenches with rain damage.According to pertinent data, the financial loss that the annual because material corrosions such as metal in the whole world cause is greatly about 7,000 hundred million dollars, and account for 2 ~ 4% of various countries' gross national product, the annual metallic corrosion loss of China also accounts for about 4% of gross national product.Compared with other various protection against corrosion means, rust proof paint is most economical, that most convenient effective, application is the most general impregnating material, therefore, people habitually can under field conditions (factors) (namely among air, water and soil etc.) prevent the priming paint of metallic corrosion from calling rust proof paint (or anti-corrosion primer, protective system, rust-proofing primer), rust proof paint accounts for coating total amount about 1/4th, is the most important integral part of coating.
Summary of the invention
The object of this invention is to provide a kind of lasting antifouling rust-inhibiting paint and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of lasting antifouling rust-inhibiting paint, is made up of the raw material of following weight part: styrene-acrylate emulsion 4-6, polyoxyethylene aliphatic alcohol ether 0.4-0.8, tripoly phosphate sodium STPP 1-2,2-Butoxyethyl acetate 3-4, ultrafine mica powder 3-5, anti skinning agent 0.4-1.0, antioxidant 1010 1-2, zinc molybdate 3-4, lanolin 2-3,3-aminopropyl trimethoxysilane 1-2, toluene 9-12, sulfonated castor oil 2-3, polybutadiene 33-35, epoxy phenolics 28-32, propyl carbinol 8-11, diatomite 3-5, light calcium carbonate 4-6, auxiliary agent 4-7;
Described auxiliary agent is made up of the raw material of following weight part: nano ceramic fibers 6-8, rock wool fibers 4-6, oxidized petrolatum barium soap 2-3, barium mahogany sulfonate 2-3, gelatin 2-3, white oil 10-15, glyceryl monostearate 1-3, ethanol 10-14, epoxy castor oil 2-4, morpholine 2-4, vermiculite power 3-4, Silane coupling agent KH550 1-2, dimethyl silicone oil 1-2, vinylbenzene 7-11, rubber powder 4-6, diatomite in powder 3-5, high wear-resistant carbon black 3-4; Preparation method is that vermiculite power, vinylbenzene, rubber powder and diatomite in powder mix by (1), is added in fluidized-bed; (2) nano ceramic fibers, rock wool fibers, glyceryl monostearate, gelatin and ethanol are mixed, be heated to 50-60 ° of C, form mixed solution through strong concussion, then input fluidized-bed and make it be atomized, be sprayed on the mixture of step (1); (3) white oil is heated to 100-120 ° of C, then adds Silane coupling agent KH550, the product of step (2) and other surplus materials, after stirring reaction 1-2 hour, fully grinding can obtain.
The lasting antifouling rust-inhibiting paint of one of the present invention, be made up of following concrete steps:
(1) ultrafine mica powder, diatomite, light calcium carbonate are added in the mixing solutions of propyl carbinol and toluene, ultrasonic disperse 20-30 minute, when being heated to 50-80 ° of C, add sulfonated castor oil, antioxidant 1010, auxiliary agent continuation stirring reaction 30-40 minute;
(2) product of step (1) is continued raised temperature to 70-90 ° of C, add styrene-acrylate emulsion, polyoxyethylene aliphatic alcohol ether, 2-Butoxyethyl acetate, polybutadiene, epoxy phenolics, 3-aminopropyl trimethoxysilane, 1200-1400 rev/min of lower high-speed mixing stirring reaction 1-2 hour;
(3) surplus materials is added in the product of step (2), is added to grinding machine for grinding after mixing and is uniformly dispersed, filter and obtain the material that fineness is 20-40 μm, pack.
Advantage of the present invention is: rust-inhibiting paint antirust time of the present invention is long, also has antifouling function, easily cleans, and hardness and wear resistance good, washability number of times is high, not easily has cut, and raw material sources of the present invention are extensive, and preparation technology is simple, easy to operate, cost is low, and function is complete, suitable popularization.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of lasting antifouling rust-inhibiting paint, is made up of the raw material of following weight part (kilogram): styrene-acrylate emulsion 5, polyoxyethylene aliphatic alcohol ether 0.6, tripoly phosphate sodium STPP 1,2-Butoxyethyl acetate 3, ultrafine mica powder 4, anti skinning agent 0.7, antioxidant 1010 1, zinc molybdate 4, lanolin 2,3-aminopropyl trimethoxysilane 1, toluene 10, sulfonated castor oil 3, polybutadiene 34, epoxy phenolics 28, propyl carbinol 9, diatomite 3, light calcium carbonate 4, auxiliary agent 5;
Described auxiliary agent is made up of the raw material of following weight part (kilogram): nano ceramic fibers 6, rock wool fibers 5, oxidized petrolatum barium soap 2, barium mahogany sulfonate 2, gelatin 3, white oil 12, glyceryl monostearate 1, ethanol 13, epoxy castor oil 2, morpholine 3, vermiculite power 3, Silane coupling agent KH550 2, dimethyl silicone oil 1, vinylbenzene 10, rubber powder 5, diatomite in powder 4, high wear-resistant carbon black 3; Preparation method is that vermiculite power, vinylbenzene, rubber powder and diatomite in powder mix by (1), is added in fluidized-bed; (2) nano ceramic fibers, rock wool fibers, glyceryl monostearate, gelatin and ethanol are mixed, be heated to 50-60 ° of C, form mixed solution through strong concussion, then input fluidized-bed and make it be atomized, be sprayed on the mixture of step (1); (3) white oil is heated to 100-120 ° of C, then adds Silane coupling agent KH550, the product of step (2) and other surplus materials, after stirring reaction 1-2 hour, fully grinding can obtain.
The lasting antifouling rust-inhibiting paint of one of the present invention, be made up of following concrete steps:
(1) ultrafine mica powder, diatomite, light calcium carbonate are added in the mixing solutions of propyl carbinol and toluene, ultrasonic disperse 20-30 minute, when being heated to 50-80 ° of C, add sulfonated castor oil, antioxidant 1010, auxiliary agent continuation stirring reaction 30-40 minute;
(2) product of step (1) is continued raised temperature to 70-90 ° of C, add styrene-acrylate emulsion, polyoxyethylene aliphatic alcohol ether, 2-Butoxyethyl acetate, polybutadiene, epoxy phenolics, 3-aminopropyl trimethoxysilane, 1200-1400 rev/min of lower high-speed mixing stirring reaction 1-2 hour;
(3) surplus materials is added in the product of step (2), is added to grinding machine for grinding after mixing and is uniformly dispersed, filter and obtain the material that fineness is 20-40 μm, pack.
Paint of the present invention is that uniform fluid is without lump, sticking power: 2 grades, snappiness: 1 grade, shock strength >=65, hardness >=2H, high temperature resistant (130 ° of C) >=450H, oil-proofness (90# gasoline, 56h): non-foaming, do not come off, paint film knockout wear resistance experiment (L/um) >=3, artificial weathering ageing resistance tested: by 1200 hours, and alkali resistance is tested: 120h paint film is without breakage.

Claims (2)

1. a lasting antifouling rust-inhibiting paint, it is characterized in that, be made up of the raw material of following weight part: styrene-acrylate emulsion 4-6, polyoxyethylene aliphatic alcohol ether 0.4-0.8, tripoly phosphate sodium STPP 1-2,2-Butoxyethyl acetate 3-4, ultrafine mica powder 3-5, anti skinning agent 0.4-1.0, antioxidant 1010 1-2, zinc molybdate 3-4, lanolin 2-3,3-aminopropyl trimethoxysilane 1-2, toluene 9-12, sulfonated castor oil 2-3, polybutadiene 33-35, epoxy phenolics 28-32, propyl carbinol 8-11, diatomite 3-5, light calcium carbonate 4-6, auxiliary agent 4-7;
Described auxiliary agent is made up of the raw material of following weight part: nano ceramic fibers 6-8, rock wool fibers 4-6, oxidized petrolatum barium soap 2-3, barium mahogany sulfonate 2-3, gelatin 2-3, white oil 10-15, glyceryl monostearate 1-3, ethanol 10-14, epoxy castor oil 2-4, morpholine 2-4, vermiculite power 3-4, Silane coupling agent KH550 1-2, dimethyl silicone oil 1-2, vinylbenzene 7-11, rubber powder 4-6, diatomite in powder 3-5, high wear-resistant carbon black 3-4; Preparation method is that vermiculite power, vinylbenzene, rubber powder and diatomite in powder mix by (1), is added in fluidized-bed; (2) nano ceramic fibers, rock wool fibers, glyceryl monostearate, gelatin and ethanol are mixed, be heated to 50-60 ° of C, form mixed solution through strong concussion, then input fluidized-bed and make it be atomized, be sprayed on the mixture of step (1); (3) white oil is heated to 100-120 ° of C, then adds Silane coupling agent KH550, the product of step (2) and other surplus materials, after stirring reaction 1-2 hour, fully grinding can obtain.
2. a kind of lasting antifouling rust-inhibiting paint according to claim 1, is characterized in that, be made up of following concrete steps:
(1) ultrafine mica powder, diatomite, light calcium carbonate are added in the mixing solutions of propyl carbinol and toluene, ultrasonic disperse 20-30 minute, when being heated to 50-80 ° of C, add sulfonated castor oil, antioxidant 1010, auxiliary agent continuation stirring reaction 30-40 minute;
(2) product of step (1) is continued raised temperature to 70-90 ° of C, add styrene-acrylate emulsion, polyoxyethylene aliphatic alcohol ether, 2-Butoxyethyl acetate, polybutadiene, epoxy phenolics, 3-aminopropyl trimethoxysilane, 1200-1400 rev/min of lower high-speed mixing stirring reaction 1-2 hour;
(3) surplus materials is added in the product of step (2), is added to grinding machine for grinding after mixing and is uniformly dispersed, filter and obtain the material that fineness is 20-40 μm, pack.
CN201410701777.0A 2014-11-28 2014-11-28 Lasting antifouling antirusting paint and preparation method thereof Pending CN104513578A (en)

Priority Applications (1)

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CN201410701777.0A CN104513578A (en) 2014-11-28 2014-11-28 Lasting antifouling antirusting paint and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201410701777.0A CN104513578A (en) 2014-11-28 2014-11-28 Lasting antifouling antirusting paint and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107902893A (en) * 2017-11-01 2018-04-13 安徽省金正塑业有限公司 A kind of refrigerator shelf prepared using discarded glass
CN108587072A (en) * 2018-05-02 2018-09-28 安徽九牛塑业科技有限公司 A kind of exterior wall high performance composited aluminum and plastic decking protective film and preparation method thereof
CN109161305A (en) * 2018-09-19 2019-01-08 铜陵市明诚铸造有限责任公司 A kind of anti-corrosive primer of mining production machinery

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1428762A1 (en) * 2001-09-17 2004-06-16 Takeuchi Press Industries Co., Ltd. Metal container having coating applied to inner surface thereof and method for production thereof
CN102234465A (en) * 2010-05-05 2011-11-09 陈建斌 Anti-corrosive primer for hoisting machinery
CN102321413A (en) * 2011-08-18 2012-01-18 广州立邦涂料有限公司 A kind of water-borne coatings that is used for the anti-rusty stain of metope and preparation method thereof
CN102977666A (en) * 2012-11-02 2013-03-20 铜陵市明诚铸造有限责任公司 Zirconia loaded metal antirust paint and its preparation method
CN102977667A (en) * 2012-11-02 2013-03-20 铜陵市明诚铸造有限责任公司 Metal antirust paint containing modified water-soluble nanometer silica sol, and its preparation method
CN103756453A (en) * 2013-12-27 2014-04-30 吴江市东泰电力特种开关有限公司 Water soluble damping antirust coating and preparation method thereof
CN104017404A (en) * 2014-06-11 2014-09-03 张家港保税区冠祥贸易有限公司 Metal anti-rust paint capable of being directly applied and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1428762A1 (en) * 2001-09-17 2004-06-16 Takeuchi Press Industries Co., Ltd. Metal container having coating applied to inner surface thereof and method for production thereof
CN102234465A (en) * 2010-05-05 2011-11-09 陈建斌 Anti-corrosive primer for hoisting machinery
CN102321413A (en) * 2011-08-18 2012-01-18 广州立邦涂料有限公司 A kind of water-borne coatings that is used for the anti-rusty stain of metope and preparation method thereof
CN102977666A (en) * 2012-11-02 2013-03-20 铜陵市明诚铸造有限责任公司 Zirconia loaded metal antirust paint and its preparation method
CN102977667A (en) * 2012-11-02 2013-03-20 铜陵市明诚铸造有限责任公司 Metal antirust paint containing modified water-soluble nanometer silica sol, and its preparation method
CN103756453A (en) * 2013-12-27 2014-04-30 吴江市东泰电力特种开关有限公司 Water soluble damping antirust coating and preparation method thereof
CN104017404A (en) * 2014-06-11 2014-09-03 张家港保税区冠祥贸易有限公司 Metal anti-rust paint capable of being directly applied and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107902893A (en) * 2017-11-01 2018-04-13 安徽省金正塑业有限公司 A kind of refrigerator shelf prepared using discarded glass
CN108587072A (en) * 2018-05-02 2018-09-28 安徽九牛塑业科技有限公司 A kind of exterior wall high performance composited aluminum and plastic decking protective film and preparation method thereof
CN109161305A (en) * 2018-09-19 2019-01-08 铜陵市明诚铸造有限责任公司 A kind of anti-corrosive primer of mining production machinery

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