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CN104419166A - PC flame retardant master batch - Google Patents

PC flame retardant master batch Download PDF

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Publication number
CN104419166A
CN104419166A CN201310397403.XA CN201310397403A CN104419166A CN 104419166 A CN104419166 A CN 104419166A CN 201310397403 A CN201310397403 A CN 201310397403A CN 104419166 A CN104419166 A CN 104419166A
Authority
CN
China
Prior art keywords
fire
retardant
master granule
flame retardant
retardant master
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310397403.XA
Other languages
Chinese (zh)
Inventor
不公告发明人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Xinzhan Plastic Co Ltd
Original Assignee
Qingdao Xinzhan Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Xinzhan Plastic Co Ltd filed Critical Qingdao Xinzhan Plastic Co Ltd
Priority to CN201310397403.XA priority Critical patent/CN104419166A/en
Publication of CN104419166A publication Critical patent/CN104419166A/en
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92009—Measured parameter
    • B29C2948/92209—Temperature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2369/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2469/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/22—Halogen free composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses PC flame retardant master batch which is prepared from the following components in percentage by mass: 20-70% of PC resin, 15-30% of phosphorus based flame retardant, 10-15% of silicon based flame retardant, 5-10% of boron based flame retardant, 3-5% of a dispersing agent and 0-5% of other additives. Compared with the prior art, the PC flame retardant master batch disclosed by the invention has the advantages of good flame retardancy effect, good dispersity, wide adaptability, convenience in use and the like, can meet the requirements of no halogen- environment-friendliness, high efficiency and UL94V-0 grade flame retardancy property can be met when used in PC, is low in cost, and has remarkable social and economic benefits.

Description

A kind of PC fire-retardant master granule
Technical field
The present invention relates to a kind of PC fire-retardant master granule.
Background technology
Polycarbonate (PC) has outstanding impact property, the transparency, dimensional stability, excellent mechanical property and electrical property, higher second-order transition temperature (140 DEG C ~ 150 DEG C), heat-drawn wire (132 DEG C ~ 138 DEG C), and wider use temperature scope (-60 DEG C ~ 120 DEG C) is widely used in the field such as electric, building, packaging, medicine equipment, opticinstrument, communications and transportation, and be rapidly to the development of the field such as Aeronautics and Astronautics, computer.(oxygen index is 21% ~ 24% to the flame retardant resistance of PC, flame retardant properties reaches UL94 V-2 level) although be better than common thermoplastic polymer (as polyethylene, polypropylene etc.), but still be difficult to meet the requirement of some Application Areas to flame retardant properties, therefore must carry out flame-retardant modified to PC.Current PC is flame-retardant modified is adopt directly to add fire retardant mostly, but each based flame retardant is owing to mostly being powder, direct interpolation existence dispersiveness is bad, production technique is not easy to control and operation, be difficult to guarantee flame retardant effect etc., use fire-retardant master granule to address these problems well, and be conducive to avoiding waste and reducing environmental pollution.
Summary of the invention
The object of the present invention is to provide a kind of good flame retardation effect, PC fire-retardant master granule easy to use.
The technical solution adopted for the present invention to solve the technical problems is: a kind of PC fire-retardant master granule, and its component by mass percent proportioning is: PC resin 20% ~ 70%, phosphorus flame retardant 15% ~ 30%, silicon-series five-retardant 10% ~ 15%, boron flame retardant 5% ~ 10%, dispersion agent 3% ~ 5%, other additive 0 ~ 5%.
Described PC resin is polycarbonate, and its proportion is 1.18 ~ 1.20g/cm 3, molding shrinkage is 0.5% ~ 0.8%.
Described phosphorus flame retardant is dihydroxyphenyl propane-bis-(diphenyl phosphoester) (BDP).
Described silicon-series five-retardant is the one in polydimethylsiloxane, PSI, polysilsesquioxane.
Described boron flame retardant is zinc borate.
Described dispersion agent is TAS-2A dispersion agent.
Other described additive is anti-dripping agent and/or oxidation inhibitor, anti-dripping agent preferably polytetrafluoroethylene (PTFE), the preferred Hinered phenols antioxidant of oxidation inhibitor and phosphite ester kind antioxidant compound.
The preparation method of above-mentioned a kind of PC fire-retardant master granule is: take each component by weight ratio, and to add respectively in high-speed mixer and fully stir after 3 ~ 15 minutes, discharging adds in twin screw extruder, extrude through melting mixing at 210 DEG C ~ 280 DEG C, cooling granulation, drying packing, obtain a kind of PC fire-retardant master granule of the present invention.
The invention has the beneficial effects as follows, compared with prior art, a kind of PC fire-retardant master granule that the present invention obtains has good flame retardation effect, dispersed good, wide adaptability and the advantage such as easy to use, and in PC, use that can to realize halogen-free flame-proof environmental protection efficient and reach the requirement of UL94 V-0 level flame retardant properties, cost is also low, thus has significant economic results in society.
Embodiment
Technical scheme of the present invention is further illustrated below in conjunction with specific embodiment.
Embodiment 1:
A kind of PC fire-retardant master granule, its component by mass percent proportioning is: PC resin 60%, dihydroxyphenyl propane-bis-(diphenyl phosphoester) (BDP) 20%, polydimethylsiloxane 10%, zinc borate 5%, TAS-2A dispersion agent 4%, polytetrafluoroethylene (PTFE) 1%.Wherein, described PC resin is polycarbonate, and its proportion is 1.18 ~ 1.20g/cm 3, molding shrinkage is 0.5% ~ 0.8%.
Preparation method: take each component by weight ratio, and to add respectively in high-speed mixer and fully stir after 3 ~ 15 minutes, discharging adds in twin screw extruder, extrude through melting mixing at 210 DEG C ~ 280 DEG C, cooling granulation, drying packing, obtain a kind of PC fire-retardant master granule of the present invention.
Embodiment 2:
A kind of PC fire-retardant master granule, its component by mass percent proportioning is: PC resin 35%, dihydroxyphenyl propane-bis-(diphenyl phosphoester) (BDP) 30%, PSI 15%, zinc borate 10%, TAS-2A dispersion agent 5%, polytetrafluoroethylene (PTFE) 3%, Hinered phenols antioxidant and phosphite ester kind antioxidant compound 2%.Wherein, described PC resin is polycarbonate, and its proportion is 1.18 ~ 1.20g/cm 3, molding shrinkage is 0.5% ~ 0.8%.
Preparation method: take each component by weight ratio, and to add respectively in high-speed mixer and fully stir after 3 ~ 15 minutes, discharging adds in twin screw extruder, extrude through melting mixing at 210 DEG C ~ 280 DEG C, cooling granulation, drying packing, obtain a kind of PC fire-retardant master granule of the present invention.

Claims (8)

1. a PC fire-retardant master granule, it is characterized in that, its component by mass percent proportioning is: PC resin 20% ~ 70%, phosphorus flame retardant 15% ~ 30%, silicon-series five-retardant 10% ~ 15%, boron flame retardant 5% ~ 10%, dispersion agent 3% ~ 5%, other additive 0 ~ 5%.
2. a kind of PC fire-retardant master granule according to claim 1, is characterized in that, described PC resin is polycarbonate, and its proportion is 1.18 ~ 1.20g/cm 3, molding shrinkage is 0.5% ~ 0.8%.
3. a kind of PC fire-retardant master granule according to claim 1, is characterized in that, described phosphorus flame retardant is dihydroxyphenyl propane-bis-(diphenyl phosphoester) (BDP).
4. a kind of PC fire-retardant master granule according to claim 1, is characterized in that, described silicon-series five-retardant is the one in polydimethylsiloxane, PSI, polysilsesquioxane.
5. a kind of PC fire-retardant master granule according to claim 1, is characterized in that, described boron flame retardant is zinc borate.
6. a kind of PC fire-retardant master granule according to claim 1, is characterized in that, described dispersion agent is TAS-2A dispersion agent.
7. a kind of PC fire-retardant master granule according to claim 1, it is characterized in that, other described additive is anti-dripping agent and/or oxidation inhibitor, anti-dripping agent preferably polytetrafluoroethylene (PTFE), the preferred Hinered phenols antioxidant of oxidation inhibitor and phosphite ester kind antioxidant compound.
8. the preparation method of a kind of PC fire-retardant master granule according to claim 1, it is characterized in that, comprise the following steps: take each component by weight ratio, and to add respectively in high-speed mixer and fully stir after 3 ~ 15 minutes, discharging adds in twin screw extruder, extrude through melting mixing at 210 DEG C ~ 280 DEG C, cooling granulation, drying packing, obtain a kind of PC fire-retardant master granule of the present invention.
CN201310397403.XA 2013-09-05 2013-09-05 PC flame retardant master batch Pending CN104419166A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310397403.XA CN104419166A (en) 2013-09-05 2013-09-05 PC flame retardant master batch

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310397403.XA CN104419166A (en) 2013-09-05 2013-09-05 PC flame retardant master batch

Publications (1)

Publication Number Publication Date
CN104419166A true CN104419166A (en) 2015-03-18

Family

ID=52969327

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310397403.XA Pending CN104419166A (en) 2013-09-05 2013-09-05 PC flame retardant master batch

Country Status (1)

Country Link
CN (1) CN104419166A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106751692A (en) * 2017-02-24 2017-05-31 同济大学 A kind of preparation method with solvent resistant cracking behavior fire-retardant polycarbonate composite
CN106751677A (en) * 2016-12-25 2017-05-31 合肥会通新材料有限公司 A kind of fire-retardant miberal powder filled polycarbonate material of superhigh tenacity and preparation method thereof
CN114316561A (en) * 2021-12-29 2022-04-12 上海品诚控股集团有限公司 High-gloss low-filling halogen-free hybrid flame-retardant PC material and preparation and application thereof
CN114874602A (en) * 2022-04-26 2022-08-09 泰力（安徽）电器股份有限公司 Production process of halogen-free flame-retardant socket granules

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106751677A (en) * 2016-12-25 2017-05-31 合肥会通新材料有限公司 A kind of fire-retardant miberal powder filled polycarbonate material of superhigh tenacity and preparation method thereof
CN106751692A (en) * 2017-02-24 2017-05-31 同济大学 A kind of preparation method with solvent resistant cracking behavior fire-retardant polycarbonate composite
CN114316561A (en) * 2021-12-29 2022-04-12 上海品诚控股集团有限公司 High-gloss low-filling halogen-free hybrid flame-retardant PC material and preparation and application thereof
CN114874602A (en) * 2022-04-26 2022-08-09 泰力（安徽）电器股份有限公司 Production process of halogen-free flame-retardant socket granules

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Legal Events

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C06 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150318