CN104350139B - Cleaning agent for automatic cleaning machine of tableware composition - Google Patents
Cleaning agent for automatic cleaning machine of tableware composition Download PDFInfo
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- CN104350139B CN104350139B CN201280073452.1A CN201280073452A CN104350139B CN 104350139 B CN104350139 B CN 104350139B CN 201280073452 A CN201280073452 A CN 201280073452A CN 104350139 B CN104350139 B CN 104350139B
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- cleaning machine
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- 238000010189 synthetic method Methods 0.000 description 1
- OHOTVSOGTVKXEL-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C(C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-UHFFFAOYSA-K 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of cleaning agent for automatic cleaning machine of tableware composition, it contains following (A 1), (A 2) and (B 1), (A 1) a kind in methylglycine diacetic acid ester and its alkali metal salt or two or more, its content is more than 6 mass % and below 18 mass %；(A 2) a kind in citric acid and its alkali metal salt or two or more, its content is more than 20 mass % and below 30 mass %；(B 1) selected from on the alcohol that the carbon number of side chain is more than 10 and less than 14 successively block be combined with a kind in the nonionic surfactant of ethylene oxide and propylene oxide or two or more, its content is more than 3 mass % and below 7 mass %, total content of (A 1) and (B 1) is more than 10 mass % and below 25 mass %, and mass ratio (A 1)/(B 1) of the content of (A 1) and the content of (B 1) is more than 1 and less than 5.
Description
Technical field
The present invention relates to cleaning agent for automatic cleaning machine of tableware composition.More particularly to be adapted to business it is water-saving
The cleaning agent for automatic cleaning machine of tableware composition used in dish cleaning machine.
Background technology
Dish cleaning machine is the equipment for cleaning the tablewares such as the plate made dirty, glass, cooking apparatus, for family or meal
In the kitchen of shop, coffee-house etc..In general, wash dishes are carried out with the order of cleaning process-flushing process, make in cleaning process
With the cleaning agent for automatic cleaning machine of tableware of the still property different from hand washing cleaning agent for dinnerware or low bubble property.
In recent years, with the popularization for the cleaning machine for being referred to as Water-saving cleaner, the use of flushing water is than pervious model
It is greatly reduced, reduces about half.Therefore, without the displacement of the cleaning solution flowed into flushing water, so as to residue in
The increased tendency of dirt amount in rinse bath, in such a situa-tion tea stain attachment or water spots etc. cause the drop of significant beauty
It is low.
, it is necessary in addition implement to have used the dipping of chlorine system bleaching agent to bleach in the case of tea stain attachment is increased.However, deposit
The situation in the space for carrying out dipping bleaching is difficult to ensure that in the scale due to equipment.Further, since repeat by chlorine system
The dipping of bleaching agent is bleached and causes the deterioration of tableware, it is possible to the state for being easier to adhere to as tea stain.
In order to make tea stain adhere to unobvious, propose there is the automatic cleaning machine of tableware use for coordinating hypochlorous acid as bleach additive composition
Cleaning agent.In the case where dirt amount is few, which inhibits tea stain attachment.On the other hand, in the case of more than dirt amount, due to having
Machine fouling etc. and cause hypochlorous effective chlorine density to inactivate, it is thus impossible to expect the bleaching function such as tea stain tachment inhibiting.
Water spots be flushing water water droplet in the drying of the hardness components such as institute's calcic, magnesium, silica, as the remaining thing of hickie
Matter, particularly in the case of glass system tableware, infringement significantly is beautiful.For this reason, at the restaurant, in the kitchen of coffee-house etc., with
Business with dish cleaning machine when clean tableware, in addition to cleaning agent, in order to water droplet is easily flowed down from tableware and
Rinse in process and use irrigation.
The work of the non-ionic surfaces such as fatty acid glyceride or sorbitan fatty acid ester is combined with common irrigation
Property agent, will rinse water emulsification reduces with the surface tension of tableware so that water droplet easily drips.As a result, the drying of tableware becomes
Quickly, it is possible to reduce water spots.
On the other hand, although confirming to be reduced the effect of water spots for irrigation, its effect must not make us full
Foot, in order to remove the water spots being attached on tableware at the restaurant or in coffee-house etc., carries out the operation wiped with towel.In addition, punching
Lotion in process is rinsed due to using, and therefore, it is necessary to the different feedway of the cleaning agent from being used in cleaning process.This
Outside, it is necessary to which the purchase fee and stock control expense of irrigation, actual conditions are the big burden as restaurant or coffee-house.
Increase the dirt in rinse bath due to the popularization of Water-saving cleaner, from tea stain tachment inhibiting effect and water spots
From the viewpoint of suppression, seek further technological development.
The chelating agent or polycarboxylic acid for being mixed with and including manganese and methylglycine diacetic acid etc. are recorded in patent document 1
High molecular bleach-activating component (A), inorganic peroxide (B), the dish cleaning machine of low bubble property surfactant (C) are with clearly
Detergent composition.Record in patent document and contain a) specific monomer such as single ethene unsaturated monocarboxylic with specified conditions
Copolymer, b) glycine-N, N- diacetic acid derivatives etc. as obtained from polymerization specific complexing agent, c) non-ionic surface
The cleaning modulator of activating agent, the further mechanical wash dishes of arbitrary bleaching agent, builder, enzyme etc..In patent text
Recorded in offering 3 and contained (A) alkali metal salt, (B) metal ion block agent, (C) surfactant, (D) carbonic acid with specified conditions
The dish cleaning machine cleansing composition of alkali metal salt, (E) polyelectrolyte polymer.Recorded in patent document 4
Containing the specific polymer such as (a) glycine-N, N- diacetic acid derivatives, (b) polyethylene glycol and can be matched with for kitchen use clear
Mixed-powder in lotion.
Prior art literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 2009-149777 publications
Patent document 2：Japanese Unexamined Patent Application Publication 2010-500431 publications
Patent document 3：Japanese Unexamined Patent Publication 2008-50410 publications
Patent document 4：Japanese Unexamined Patent Application Publication 2008-505236 publications
The content of the invention
The present invention relates to a kind of cleaning agent for automatic cleaning machine of tableware composition, its contain following (A-1), (A-2) and
(B-1),
(A-1) a kind in methylglycine diacetic acid ester and its alkali metal salt or two or more [hereinafter referred to as
(A-1) component], its content is more than 6 mass % and below 18 mass %；
(A-2) a kind in citric acid and its alkali metal salt or two or more [hereinafter referred to as (A-2) component], its
Content is more than 20 mass % and below 30 mass %；
(B-1) selected from block combines oxidation successively on the alcohol that the carbon number with side chain is more than 10 and less than 14
1 kind in the nonionic surfactant of ethene and propylene oxide or two or more [hereinafter referred to as (B-1) component], its content
For more than 3 mass % and below 7 mass %,
(A-1) and total content of (B-1) is more than 10 mass % and below 25 mass %,
(A-1) mass ratio (A-1)/(B-1) of content and the content of (B-1) is more than 1 and less than 5.
Embodiment
In the cleaning of tableware, the dirt composition that is attached on tableware produced due to the hardness components in water it is insoluble not
Molten thing.Therefore, if the cleaning of tableware, rinse it is insufficient, which residues on tableware, the beauty of the tableware after cleaning
Significantly reduce.As specific insoluble matter, the casein of the protein as dirt composition can be enumerated and be used as hardness components
The obtained calcium binding of casein Ca salt, the tannin from the polyphenol in beverage and hardness components of calcium binding obtain
The insoluble Ca salt such as tannin Ca salt.
Water-saving cleaner since the amount of water being supplied to by flushing water in rinse bath is few compared to pervious cleaning machine, because
This, has the insoluble matters such as the insoluble Ca salt produced in cleaning solution compared to existing tendencies a large amount of in the past.Thus, Water-saving cleaner
In, the insoluble matter such as insoluble Ca salt is easily residued on tableware or glass after cleaning, as a result, becoming easily to produce tea stain
It is attached to the water spots on tableware or glass surface.Therefore, Water-saving cleaner easily makes the beauty of the tableware after cleaning significantly
Reduce.
In the technology of the dish cleaning machine cleansing composition of patent document 1, water-saving cleaning is not corresponded to, to tea stain
Tachment inhibiting deficiency.
In the technology of the cleaning modulator of the wash dishes for being related to machinery of patent document 2, do not assign with wet
The flushing effect that lubricant nature improves, suppresses water spots deficiency, and, it is difficult to it is formulation.
In being related in the technology of dish cleaning machine cleansing composition for patent document 3, in the situation more than soil load
Lower effective chlorine density reduces, to tea stain tachment inhibiting deficiency.
In the technology of the mixed-powder that can be matched with cleaning agent for kitchen use of patent document 4, do not assign adjoint
The flushing effect that wettability improves, suppresses deficiency to water spots.
In technology disclosed above, from the viewpoint for taking into account tea stain tachment inhibiting and the water spots reduction relative to increased dirt
Set out, it is also insufficient.
The technical problem of the present invention is punching providing a kind of situation even in as cleaned with Water-saving cleaner
Under conditions of the usage amount of wash water is few, also the automatic of excellent effect is shown in terms of the suppression of tea stain attachment and the reduction of water spots
Dish cleaning machine cleansing composition.
Hereinafter, (A-1) component and (A-2) component are illustrated as (A) component in the lump.
According to the present invention it is possible to provide the usage amount even in flushing water the situation as cleaned with Water-saving cleaner
Under conditions of few, display that the automatic cleaning machine of tableware of excellent effect is used in terms of the suppression of tea stain attachment and the reduction of water spots
Cleansing composition.
In the present invention, Water-saving cleaner is the automatic cleaning machine of tableware for referring to carry out following cleaning, makes NaOH
0.2 mass % aqueous solutions be 60 DEG C, oppose 20 test film (shapes of 1 in glass supporter：15cm×15cm×
0.2cm, Nippon Testpanel Co., Ltd.s manufacture soda-lime glass) carry out more than 40 seconds and less than 60 seconds cleaning it
Afterwards, horizontal plane is set per 2500cm with relative to tableware2For 2L water and be allowed to be rinsed for 80 DEG C, then, at 25 DEG C
NaOH residual quantities on the air drying test film of 10 minutes are 0.15 μ g/cm2Below, it is preferably 0.12 μ g/cm2Below,
More preferably 0.1 μ g/cm2Below.Here, NaOH residual quantities are that every 1 test film is impregnated in 25 DEG C, the distillation of 200g
10 second time in water, extraction are residued in after the NaOH on test film, and acid-base titration is carried out with the hydrochloric acid (HCl) of 0.01mol/L,
The amount of NaOH in quantitative extracting solution, obtains the average value relative to the test film of 20.In addition, tableware sets the face of horizontal plane
Product, in the case where using shelf (shelf of tableware storage), is defined with the area of the bottom surface of the shelf.The present invention from
Dynamic dish cleaning machine can be used in the cleaning using the Water-saving cleaner so defined with cleansing composition.
In the present invention, Water-saving cleaner be refer to implement with the water fewer than pervious automatic cleaning machine of tableware into
The automatic cleaning machine of tableware for the water-saving cleaning that row rinses, is not limited to the special machine of water-saving cleaning, also includes with can be water-saving clear
Wash the cleaning machine of function.For example, in pervious automatic cleaning machine of tableware, it is to be set relative to tableware that every 1 time, which is rinsed required water,
Horizontal plane is put per 2500cm2For 4~6L；In Water-saving cleaner, it is to set water relative to tableware that every 1 time, which is rinsed required water,
Plane is per 2500cm2For 2~3L.Therefore, can be relative to tableware setting horizontal plane by the water that can implement every 1 flushing
Per 2500cm2For 2~3L flushing automatic cleaning machine of tableware as Water-saving cleaner.
<(A) component>
[(A-1) component]
The cleaning agent for automatic cleaning machine of tableware composition of the present invention contains selected from methylglycine diacetic acid ester and its alkali
1 kind in metal salt or two or more conduct (A-1) component.
The cleaning agent for automatic cleaning machine of tableware composition of the present invention, thus it is speculated that due to methylglycine diacetic acid ester (MGDA)
Or its alkali metal salt can suppress easy increased casein Ca salt or tannin in the case of being cleaned in Water-saving cleaner
The generation of the insoluble Ca salt such as Ca salt and crystalline growth, so as to obtain the excellent effect for suppressing tea stain attachment.
(A-1) species of the alkali metal salt of component, can enumerate sodium salt, sylvite etc., from the viewpoint of as universal product,
Preferably sodium salt.
The content of (A-1) component in the cleaning agent for automatic cleaning machine of tableware composition of the present invention, from suppressing, tea stain is attached
It is more than 6 mass % from the viewpoint of, is preferably more than 7 mass %, be more preferably more than 8 mass %, moreover, is 18
Below quality %, is preferably below 15 mass %, is more preferably below 12 mass %.In addition, for the same reason, (A-
1) content of component is 6~18 mass %, is preferably 7~15 mass %, more preferably 8~12 mass %.
<(A-2) component>
The cleaning agent for automatic cleaning machine of tableware composition of the present invention, from the viewpoint of tea stain attachment is suppressed, contains choosing
From a kind in citric acid and its alkali metal salt or two or more conduct (A-2) component.As alkali metal salt, be preferably sodium salt,
Sylvite, more preferably sodium salt.It is preferably trisodium citrate as (A-2) component of the present invention.(A- as the present invention
2) component, is preferably two water salt of trisodium citrate.
The content of (A-2) component in the cleaning agent for automatic cleaning machine of tableware composition of the present invention, from suppressing, tea stain is attached
It is more than 20 mass % from the viewpoint of, is preferably more than 23 mass %, is preferably 27 matter moreover, being below 30 mass %
Measure below %.In addition, for the same reason, the content of (A-2) component is 20~30 mass %, is preferably 23~27 matter
Measure %.
<(B-1) component>
The cleaning agent for automatic cleaning machine of tableware composition of the present invention, goes out from the viewpoint that water spots is reduced with flushing effect
Hair, containing selected from the carbon number with side chain be more than 10 and less than 14 alcohol on successively block be combined with ethylene oxide and
1 kind in the nonionic surfactant of propylene oxide or two or more conduct (B-1) component.
(B-1) the average addition molal quantity of the ethylene oxide of component is preferably more than 4, and more preferably more than 4.5, more
Add preferably more than 5, also, it is preferred that be less than 10, more preferably less than 9, it is more preferably less than 8.
In addition, the average addition molal quantity of the propylene oxide of (B-1) component is preferably more than 2, more preferably 3 with
On, it is more preferably more than 4, is even more preferably more than 5, also, it is preferred that be less than 10, more preferably less than 9.5,
More preferably less than 9.
(B-1) component is preferably selected from the alcohol that the carbon number with side chain is more than 10 and less than 14 block successively
Be combined with the nonionic surfactant of ethylene oxide and propylene oxide, and the average addition molal quantity of ethylene oxide for 4 with
Upper and less than 10, propylene oxide average addition molal quantity be a kind in more than 2 and less than 10 nonionic surfactant or
Person two or more.
As (B-1) component, be preferably selected from carbon number be more than 10, preferably carbon number is more than 12 and carbon is former
Block is combined with the nonionic surfactant that ethylene oxide and propylene oxide form successively on the secondary alcohol that subnumber is less than 14
1 kind or two or more.Further, as (B-1) component, be preferably selected from carbon number be more than 10, preferred carbon atom
Block is combined with ethylene oxide successively and propylene oxide forms on the secondary alcohol that number is more than 12 and carbon number is less than 14
Nonionic surfactant, and the average addition molal quantity of ethylene oxide adds for more than 4 and the average of less than 10, propylene oxide
Into molal quantity be more than 2 and less than 10 nonionic surfactant in a kind or two or more.
It is preferably the nonionic table represented by the following general formula (b-1) from the viewpoint of effectiveness as (B-1) component
Face activating agent.
R1-O-(EO)s-(PO)t-H (b-1)
[in formula, R1The alkyl or carbon number for representing the side chain that carbon number is more than 10 and less than 14 are more than 10
And the alkenyl of less than 14 side chain, in addition, the alkyl or carbon number of the side chain that carbon number is 10~14 are 10~14
The alkenyl of side chain, EO represent ethyleneoxy, and PO represents propenyloxy group.S, t represents average addition molal quantity respectively, s for more than 4 and
Less than 10, t are more than 2 and less than 10, t/s are more than 0.3 and less than 1.5, in addition, s=4~10, t=2~10,0.3≤(t/
s)≤1.5。“-(EO)s-(PO)t- " combined for block.]
In general formula (b-1), R1The alkyl for being 10~14 for the carbon number with side chain or the carbon original with side chain
Subnumber is 10~14 alkenyl, it is however preferred to have the carbon number of side chain is 10~14 alkyl.R1Preferably carbon number is
10~14 secondary alkyl or carbon number is 10~14 secondary alkenyl, and more preferably carbon number is 10~14 secondary alkane
Base.As secondary alkyl, the group represented by following formula can be enumerated.R in general formula (b-1)1Can also be represented by the formula
Secondary alkyl.
[in formula, R11、R12Alkyl or alkenyl respectively with or without side chain, be preferably straight chain alkyl or alkene
The alkyl of base, more preferably straight chain, R11、R12Carbon number add up to more than 9 and less than 13.]
In general formula (b-1), s is preferably more than 5 and less than 9, t are preferably more than 5 and less than 9, additionally, it is preferred that s=5~
9th, preferred t=5~9.As the specific example of the nonionic surfactant of general formula (b-1), can enumerate selected from polyoxyethylene
(7) the secondary lauryl ether of polyoxypropylene (8.5), the secondary tridecyl ether of polyoxyethylene (7) polyoxypropylene (8.5), polyoxyethylene (7)
1 kind in polyoxypropylene (8.5) secondary myristyl ether or two or more.Here, it is ethylene oxide or propylene oxide in ()
Average addition molal quantity () in the nonionic surfactant of general formula (b-2) similarly.
In general formula (b-1), t/s is preferably more than 0.3, and more preferably more than 0.5, it is more preferably more than 0.7,
Even more preferably be more than 0.9, also, it is preferred that for less than 1.5, more preferably less than 1.4, even more preferably for
It is 1.3 following.
The compound of general formula (b-1) can by with carbon number be 10~14 side chain alkyl alcohol (preferably
For secondary alcohol) or the alcohol (be preferably secondary alcohol) of alkenyl with the side chain that carbon number is 10~14 on addition ethylene oxide
Afterwards, addition propylene oxide is synthesized.
(B-1) weight average molecular weight of component is preferably more than 200, is more preferably 2 also, it is preferred that being 5, less than 000,
Less than 000.In addition, the weight average molecular weight of (B-1) component is preferably 200~5,000, more preferably 200~2,000.It is logical
The compound of formula (b-1) can be bought with the trade name of " SOFTANOL " from Nippon Shokubai Co., Ltd.
The viewpoint of the physical property with the cleaning agent for automatic cleaning machine of tableware composition of the present invention during fabrication is reduced from water spots
To set out, the content of (B-1) component in cleaning agent for automatic cleaning machine of tableware composition of the invention, is more than 3 mass %, and
And be below 7 mass %, it is preferably below 6 mass %, is more preferably below 5 mass %.In addition, for the same reason,
(B-1) content of component in the composition is 3~7 mass %, is preferably 3~6 mass %, more preferably 3~5 matter
Measure %.
From the viewpoint of suppressing tea stain attachment and reducing water spots, cleaning agent for automatic cleaning machine of tableware of the invention combination
Total content of (A-1) component and (B-1) component is more than 10 mass % in thing, is preferably more than 12 mass %, more preferably
More than 14 mass %, are more preferably more than 16 mass %, are preferably below 23 mass %, more moreover, being below 25 mass %
It is more preferably below 19 mass % preferably below 21 mass %.In addition, for the same reason, (A-1) in composition
Total content of component and (B-1) component is 10~25 mass %, is preferably 12~23 mass %, more preferably 14~21 matter
% is measured, is more preferably 16~19 mass %.
From the viewpoint of suppressing tea stain attachment and reducing water spots, cleaning agent for automatic cleaning machine of tableware of the invention combination
Mass ratio (A-1)/(B-1) of the content of the content of (A-1) component and (B-1) component is more than 1 in thing, more preferably 1.5 with
On, it is more preferably more than 2, is more preferably more than 2.5, moreover, be less than 5, more preferably less than 4.5, it is more preferably 4
Hereinafter, it is still more preferably less than 3.5.In addition, for the same reason, which is 1~5, preferably
It is even more preferably 2.5~3.5 for 1.5~4.5, more preferably 2~4.
<(B) component>
The cleaning agent for automatic cleaning machine of tableware composition of the present invention can contain the non-ionic surface beyond (B-1) component
Activating agent.Hereinafter, the nonionic surfactant for also including (B-1) component is illustrated as (B) component.
<(B-2) component>
From the viewpoint of effectiveness, cleaning agent for automatic cleaning machine of tableware composition of the invention, as (B-1) component
Nonionic surfactant in addition, it is being more than 8 and less than 18 with carbon number to preferably comprise as (B-2) component
Block is combined with ethylene oxide and propylene oxide forms on the alcohol of alkyl or alcohol with the alkyl that carbon number is 8~18
Nonionic surfactant [remove (B-1) component the carbon number with side chain be more than 10 and less than 14 alcohol on
Block is combined with the nonionic surfactant that ethylene oxide and propylene oxide form successively].(B-2) component can also be to have
There is block knot on the alcohol for the alkyl that carbon number is more than 8 and less than 18 or the alcohol for the alkyl for being 8~18 with carbon number
Close have nonionic surfactant that ethylene oxide and propylene oxide form [remove (B-1) component carbon number for 10 with
Block is combined with the nonionic surfactant that ethylene oxide and propylene oxide form successively on upper and less than 14 secondary alcohol].
It is preferably the nonionic surfactant represented by general formula (b-2) as (B-2) component.
R2-O-(EO)p-(PO)q-(EO)r-H (b-2)
[in formula, R2Represent the alkyl that carbon number is more than 8 and less than 18 alkyl or carbon number is 8~18, EO tables
Show ethyleneoxy, PO represents propenyloxy group.P, q, r represent average addition molal quantity respectively, and p is more than 1 and less than 10, q 0.5
Above and less than 5, r are more than 1 and less than 10, in addition, p=1~10, q=0.5~5, r=1~10.“-(EO)p-(PO)q-
(EO)r- " combined for block.]
In general formula (b-2), R2Preferably carbon number is 10~14 alkyl, and more preferably carbon number is 10
~14 alkyl, is more preferably the straight chained alkyl that carbon number is 10~14.In general formula (b-2), p is preferably more than 2 and 8
Below or 2~8.In general formula (b-2), q is preferably more than 0.5, is more preferably more than 1, also, it is preferred that being less than 4.5, more
Preferably less than 3, it is more preferably less than 2.In addition, q is preferably 0.5~4.5, and more preferably 1~3, it is more preferably 1
~2.In general formula (b-2), r is preferably more than 2 and less than 8 or 2~8.In general formula (b-2), p+r is preferably more than 1, more excellent
Elect more than 2 as, be more preferably more than 4, also, it is preferred that be less than 30, more preferably less than 20, it is more preferably less than 15.
In addition, p+r is preferably 1~30, and more preferably 2~20, it is more preferably 4~15.
As the specific example of the nonionic surfactant of general formula (b-2), can enumerate selected from polyoxyethylene (3) polyoxy
Propylene (1.5) polyoxyethylene (3) lauryl ether, polyoxyethylene (5) polyoxypropylene (1.5) polyoxyethylene (5) lauryl ether, polyoxy
1 kind in ethene (5) polyoxypropylene (4.5) polyoxyethylene (5) lauryl ether or two or more.
(B-2) weight average molecular weight of component is preferably more than 200, is more preferably 2 also, it is preferred that being 5, less than 000,
Less than 000.In addition, the weight average molecular weight of (B-2) component is preferably 200~5,000, more preferably 200~2,000.It is logical
The compound of formula (b-2) can be bought with the trade name of " EMULGEN " from Kao Corp.
In the case where the cleaning agent for automatic cleaning machine of tableware composition of the present invention contains (B-2) component, in composition
(B-1) component and (B-2) component total content, from water spots reduce and the present invention cleaning agent for automatic cleaning machine of tableware group
It is preferably more than 3 mass % from the viewpoint of physical property during the manufacture of compound, more preferably more than 3.5 mass %, more preferably
For more than 4 mass %, also, it is preferred that being below 7 mass %, more preferably below 6.5 mass %, are more preferably 6 mass %
Below.In addition, for the same reason, total content of (B-1) component and (B-2) component in composition is preferably 3~7 matter
%, more preferably 3.5~6.5 mass % are measured, is more preferably 4~6 mass %.
In the case where the cleaning agent for automatic cleaning machine of tableware composition of the present invention contains (B-2) component, from reduction water
From the viewpoint of spot, mass ratio (B-1)/(B-2) of the content of (B-1) component and the content of (B-2) component, is preferably more than 1,
More preferably more than 2, also, it is preferred that be less than 15, more preferably less than 10, it is more preferably less than 8, still more preferably
For less than 6.For the same reason, which is preferably 1~15, and more preferably 1~10, more
Preferably 2~8, it is even more preferably 2~6.
The cleaning agent for automatic cleaning machine of tableware composition of the present invention can make in the range of the effect with the present invention
(B) component is used as by the use of other nonionic surfactants.As other nonionic surfactants, glycerine fatty acid can be enumerated
Ester, polyglyceryl fatty acid ester, methyl glycol fatty acid ester, cithrol, sorbitan fatty acid ester, sucrose fat
Acid esters, polyoxyethylene sorbitan fatty acid ester.
In addition, in (B) component, total ratio of (B-1) component and (B-2) component is preferably more than 90 mass %, more
It is more preferably more than 98 mass %, also, it is preferred that being below 100 mass % preferably more than 95 mass %, or
100 mass %.In addition, in (B) component, total ratio of (B-1) component and (B-2) component is preferably 90~100 mass %,
More preferably 95~100 mass %, are more preferably 98~100 mass %.
In the cleaning agent for automatic cleaning machine of tableware composition of the present invention, total the containing of (A) component and (B-1) component
Amount, from the viewpoint of reducing water spots and suppressing tea stain attachment, in the composition preferably more than 30 mass %, is more preferably
More than 35 mass %, are more preferably below 45 mass % also, it is preferred that being below 50 mass %.For the same reason, group
Total content of (A) component and (B-1) component in compound is preferably 30~50 mass %, more preferably 35~45 matter
Measure %.
In addition, from the viewpoint of reducing water spots and suppressing tea stain attachment, in automatic cleaning machine of tableware of the invention with clearly
In detergent composition, (A) component, total content of (B-1) component and (B-2) component be preferably 30 mass % in the composition with
On, it is more preferably more than 35 mass %, is more preferably below 45 mass % also, it is preferred that being below 50 mass %.It is based on
The reasons why same, total content of (A) component, (B-1) component and (B-2) component in composition is preferably 30~50 matter
Measure %, more preferably 35~45 mass %.
In addition, from the viewpoint of reducing water spots and suppressing tea stain attachment, in automatic cleaning machine of tableware of the invention with clearly
In detergent composition, total content of (A) component and (B) component is preferably more than 30 mass % in the composition, more preferably
It is more preferably below 45 mass % also, it is preferred that being below 50 mass % for more than 35 mass %.For the same reason,
Total content of (A) component and (B) component in composition is preferably 30~50 mass %, more preferably 35~45 matter
Measure %.
From the viewpoint of reducing water spots and suppressing tea stain attachment, cleaning agent for automatic cleaning machine of tableware of the invention combination
In thing, mass ratio (A)/(B-1) of the content of (A) component and the content of (B-1) component, is preferably more than 3, more preferably 4 with
On, it is more preferably more than 5, also, it is preferred that be less than 12, more preferably less than 11, it is more preferably less than 10.In addition, base
In same the reasons why, which is preferably 3~12, and more preferably 4~11, it is more preferably 5~10.
In addition, from the viewpoint of reducing water spots and suppressing tea stain attachment, in automatic cleaning machine of tableware of the invention with clearly
In detergent composition, the content of (A) component and (B-1) component and the mass ratio (A) of total content of (B-2) component/[(B-1)+
(B-2)] it is preferably, more than 3, more preferably more than 4, it is more preferably more than 5, also, it is preferred that be less than 12, more preferably 11
Hereinafter, it is more preferably less than 10.In addition, for the same reason, the mass ratio (A)/[(B-1)+(B-2)] be preferably 3~
12, more preferably 4~11, are more preferably 5~10.
In addition, from the viewpoint of reducing water spots and suppressing tea stain attachment, in automatic cleaning machine of tableware of the invention with clearly
In detergent composition, mass ratio (A)/(B) of the content of (A) component and the content of (B) component, is preferably more than 3, more preferably
More than 4, it is more preferably more than 5, also, it is preferred that be less than 12, more preferably less than 11, it is more preferably less than 10.In addition,
For the same reason, which is preferably 3~12, and more preferably 4~11, it is more preferably 5~10.
<(C) component>
The cleaning agent for automatic cleaning machine of tableware composition of the present invention, which preferably comprises, is selected from (C-1) polyacrylic acid and its salt
[hereinafter referred to as (C-1) component] and (C-2) has the copolymer and its salt [following, title of the monomeric unit from maleic acid
For (C-2) component] in more than a kind of high-molecular compound be used as (C) component.
It is preferably alkali metal salt as the salt of (C-1) component, is more preferably sodium salt, sylvite.
As (C-2) component, copolymer, the carbon number for being preferably selected from acrylic acid and maleic acid are more than 1, further
For more than 5, and it is less than 10, or the alkene and maleic acid that carbon number is 1~10, further carbon number is 5~10
Copolymer, polystyrolsulfon acid and maleic acid copolymer and their salt in more than a kind, be more preferably selected from
More than a kind in the copolymer and its salt of acrylic acid and maleic acid.
It is preferably alkali metal salt as the salt of (C-2) component, is more preferably sodium salt, sylvite.
In the acrylic acid and the copolymer of maleic acid of (C-2) component or its salt, the Component units from acrylic acid/come
Molar ratio from the Component units of maleic acid is preferably more than 90/10, is more preferably more than 75/25, also, it is preferred that being 50/
Less than 50, it is more preferably less than 65/35.In addition, the molar ratio is preferably 90/10~50/50, more preferably 75/25
~65/35.Here, the molar ratio of the Component units from acrylic acid/Component units from maleic acid can be by using heat
The hot lysate of pyrolysis gas chromatography (PGC) detection copolymer is tried to achieve.
From the viewpoint of incrustation scale tachment inhibiting, the polyacrylic acid of (C-1) component or the weight average molecular weight of its salt, preferably
For 1, more than 000, more preferably 3, more than 000, also, it is preferred that being 10, less than 000,8, less than 000 are more preferably, more
Preferably 6, less than 000, it is still more preferably 5, less than 000.In addition, for the same reason, the polypropylene of (C-1) component
The weight average molecular weight of acid or its salt is preferably 1,000~10,000, and more preferably 3,000~8,000, it is more preferably 3,
000~6,000, it is even more preferably 3,000~5,000.
From the viewpoint of incrustation scale tachment inhibiting, the copolymer with the unit from maleic acid of (C-2) component or
The weight average molecular weight of its salt is preferably 1, more than 000, is more preferably 3, more than 000, also, it is preferred that being 10, less than 000, more
Add preferably less than 5,000.In addition, for the same reason, the copolymer with the unit from maleic acid of (C-2) component
Or the weight average molecular weight of its salt is preferably 1,000~10,000, more preferably 3,000~5,000.
In addition, from the viewpoint of incrustation scale tachment inhibiting, the attachment of suppression tea stain and reducing water spots, (C-2) component
The weight average molecular weight of copolymer or its salt with the unit from maleic acid, is preferably 10, more than 000, and more preferably 30,
More than 000, it is more preferably 50, more than 000, also, it is preferred that be 150, less than 000, more preferably 120, less than 000, more
Preferably less than 100,000.
Here, for the weight average molecular weight of (C) component, the mixed solvent of acetonitrile and water (phosphate buffer solution) can be made
For solvent, tried to achieve by the use of gel permeation chromatography using polyacrylic acid as standard substance.
In the present invention, both (C-1) component and (C-2) component are preferably comprised as (C) component.That is, as (C) component
Preferably comprise (C-1) component and (C-2) component.(C-1) in the combination of component and (C-2) component, (C-1) component is selected from poly- third
More than a kind of high-molecular compound in olefin(e) acid and its salt, (C-2) component for selected from acrylic acid and maleic acid copolymer and its
More than a kind of high-molecular compound in salt.In the case of containing both (C-1) component and (C-2) component, (C-1) component
Mass ratio (C-1)/(C-2) of (C-2) component is preferably more than 1, and more preferably more than 2, it is more preferably more than 3,
Also, it is preferred that be less than 30, more preferably less than 20, it is more preferably less than 10.
From the viewpoint of incrustation scale attachment is suppressed, (C) in cleaning agent for automatic cleaning machine of tableware composition of the invention
The content of component in the composition be preferably more than 5 mass %, more preferably more than 6 mass %, be more preferably 7 mass % with
On, also, it is preferred that being below 15 mass %, more preferably below 14 mass %, are more preferably below 13 mass %.In addition,
For the same reason, the content of (C) component is preferably 5~15 mass %, more preferably 6~14 matter in the composition
% is measured, is more preferably 7~13 mass %.
In addition, the cleaning agent for automatic cleaning machine of tableware composition of the present invention, adheres to and reduces water spots from tea stain is suppressed
Viewpoint is set out, and total content of (A-1) component, (A-2) component and (C) component is preferably more than 30 mass % more preferably 33
More than quality %, is more preferably more than 35 mass %, is more preferably more than 40 mass %, also, it is preferred that being 50 mass %
Hereinafter, below 47 mass % are more preferably, are more preferably below 45 mass %.In addition, for the same reason, in composition
(A-1) component, total content of (A-2) component and (C) component be preferably 30~50 mass %, more preferably 33~47 matter
% is measured, is even more preferably 35~45 mass %.
<(D) component>
From the viewpoint of formulation, cleaning agent for automatic cleaning machine of tableware composition of the invention is preferably comprised with liquid
The inorganic particle that body supports ability is used as (D) component.In addition, as (D) component, preferably comprise selected from amorphous silica and
More than a kind of the inorganic particle that ability is supported with liquid in crystallinity calcium silicates.The liquid that can be supported as (D) component
Body, can enumerate under moisture, the solution of polymer, room temperature (for example, 25 DEG C) as the surfactant of liquid, surfactant
Solution etc..
In the present invention, " there is liquid to support ability " of (D) component refers to what is recorded by JIS K 6220 (- 1995)
The oil suction that method obtains can be more than 120ml/100g.(D) component is preferably that the oil suction can be more than 120ml/100g, and
It is further the inorganic particle of below 600ml/100g for 1, below 000ml/100g.In addition, (D) component is preferably the suction
Oil can be 120~1,000ml/100g, be further the inorganic particle of 120~600ml/100g.
(D) average grain diameter of component is preferably more than 0.5 μm, be more preferably more than 1 μm, also, it is preferred that for 300 μm with
Under, it is more preferably less than 150 μm.In addition, the average grain diameter of (D) component is preferably 0.5~300 μm, more preferably 1~
150μm。
Average grain diameter mentioned here is the value calculated with dimension criteria, is filled using laser diffraction formula particle size distribution
Put：The value of LA-500 (hole field makes the manufacture of Co., Ltd. of institute) measure.
(D) specific surface area of component is preferably 30m2/ more than g, is more preferably 50m2/ more than g, also, it is preferred that being
600m2/ below g, is more preferably 400m2/ below g.In addition, the specific surface area of (D) component is preferably 30~600m2/ g, into one
Step is preferably 50~400m2/g.It is the value measured by BET formula surface areas meter.
As the amorphous silica of (D) component of the present invention, can use as TOKUSIL series and FINESIL
The synthesis amorphous silica that serial (Tokuyama Corporation) is sold.Here, amorphous silica refer to by
The net structure of Si-O is formed, and the silica without certain crystalline texture.
It is preferably 2CaO3SiO as the crystallinity calcium silicates of (D) component of the present invention2·mSiO2·nH2(m, n are O
1<m<2、2<n<3 number) represented by crystallinity calcium silicates, can use and be used as FLUORITE series (Tokuyama
Corporation) various commercially available crystallinity calcium silicates.
It is excellent from the viewpoint of formulation as the inorganic particle that ability is supported with liquid of (D) component of the present invention
Elect amorphous silica as.
The content of (D) component in the cleaning agent for automatic cleaning machine of tableware composition of the present invention, from formulation viewpoint
Set out, in the composition preferably more than 0.5 mass %, more preferably more than 0.7 mass %, be more preferably 1 mass % with
On, also, it is preferred that being below 2 mass %.For the same reason, the content of (D) component is preferably 0.5~2 in the composition
Quality %, more preferably 0.7~2 mass %, are more preferably 1~2 mass %.
<(E) component>
The cleaning agent for automatic cleaning machine of tableware composition of the present invention, from the viewpoint of cleaning, preferably comprises and is selected from
More than a kind of alkaline agent (but not including that (D) component) in the anhydride of silicate and the anhydride of carbonate as (E) into
Point.
As the alkaline agent of (E) component, be preferably selected from silicic acid alkali metal salt anhydride and alkali metal carbonate salt it is anhydrous
More than a kind of alkaline agent in thing, more preferably 1 in natrium carbonicum calcinatum, Anhydrous potassium carbonate and anhydrous sodium metasilicate
The alkaline agent of the kind above.
As the inorganic compound of (E) component, preferably and with the anhydride of carbonate and the anhydride of silicate.That is, make
For (E) component, the anhydride of carbonate and the anhydride of silicate are preferably comprised.From the viewpoint of cleaning, preferably it is used in combination
The anhydride of alkali metal carbonate salt and the anhydride of silicic acid alkali metal salt, further preferably and with natrium carbonicum calcinatum and silicic acid anhydride
Sodium.And with the case of natrium carbonicum calcinatum and anhydrous sodium metasilicate, the content of natrium carbonicum calcinatum and the content of anhydrous sodium metasilicate
Mass ratio (content of natrium carbonicum calcinatum)/(content of anhydrous sodium metasilicate) is preferably more than 1.5, and more preferably more than 2, it is more excellent
Elect more than 2.5 as, also, it is preferred that be less than 4, more preferably less than 3.5, it is more preferably less than 3.In addition, mass ratio (the nothing
Aqueous sodium carbonate)/(anhydrous sodium metasilicate) be preferably 1.5~4, and more preferably 2~3.5, it is more preferably 2.5~3.
The content of (E) component in the cleaning agent for automatic cleaning machine of tableware composition of the present invention, from the viewpoint of cleaning
Set out, be preferably more than 40 mass % in the composition, also, it is preferred that be below 70 mass %, more preferably 65 mass % with
Under, it is more preferably below 60 mass %.For the same reason, the content of (E) component is preferably 40~80 in the composition
Quality %, more preferably 40~70 mass %, are more preferably 40~60 mass %.
<Cleaning agent for automatic cleaning machine of tableware composition>
The cleaning agent for automatic cleaning machine of tableware composition of the present invention contains (A) component, (B) component, and preferably comprises
1 kind or component of more than two kinds in (C) component, (D) component and (E) component, further preferably (C) component,
(D) whole components of component and (E) component.
In the case where the cleaning agent for automatic cleaning machine of tableware composition of the present invention contains (A)~(E) components, from suppression
From the viewpoint of tea stain attachment, 100 mass % are added up to relative to the content of (A)~(E) components, the content of (A) component is excellent
Elect as more than 20 mass %, more preferably more than 23 mass %, be more preferably more than 26 mass %, also, it is preferred that being 55 matter
Below %, more preferably below 50 mass % are measured, is more preferably below 45 mass %.In addition, for the same reason, relatively
100 mass % are added up in the content of (A)~(E) components, and the content of (A) component is preferably 20~55 mass %, further
Preferably 23~50 mass %, are more preferably 26~45 mass %.
In addition, in the case where the cleaning agent for automatic cleaning machine of tableware composition of the present invention contains (A)~(E) components,
From the viewpoint of reduce water spots, 100 mass % are added up to relative to the content of (A)~(E) components, preferably (B) component
Content, be further that total content of (B-1) component and (B-2) component is more than 3 mass %, also, it is preferred that being 10 matter
Below %, more preferably below 9 mass % are measured, is more preferably below 8 mass %.In addition, for the same reason, preferably phase
100 mass % are added up to for the content of (A)~(E) components, and the content of (B) component, be further (B-1) component and (B-
2) total content of component is 3~10 mass %, more preferably 3~9 mass %, is more preferably 3~8 mass %.
In addition, from the viewpoint of tea stain attachment is reduced, in the cleaning agent for automatic cleaning machine of tableware composition of the present invention
In the case of containing (A)~(E) components, 100 mass % are added up to preferably with respect to the content of (A)~(E) components, (C) into
The content divided is more than 5 mass %, more preferably more than 6 mass %, is more preferably more than 7 mass %, also, it is preferred that being 15
Below quality %, more preferably below 14 mass %, are more preferably below 13 mass %.In addition, for the same reason, excellent
Phase selection is for the 100 mass % that add up to of the content of (A)~(E) components, and the content of (C) component is 5~15 mass %, further
Preferably 6~14 mass %, are more preferably 7~13 mass %.
In addition, in the case where the cleaning agent for automatic cleaning machine of tableware composition of the present invention contains (A)~(E) components,
From the viewpoint of formulation, 100 mass % are added up to preferably with respect to the content of (A)~(E) components, (D) component contains
Measure as more than 0.5 mass %, more preferably more than 0.7 mass %, be more preferably more than 1 mass %, also, it is preferred that being 2 matter
Measure below %.In addition, for the same reason, 100 mass % are added up to preferably with respect to the content of (A)~(E) components,
(D) content of component is 0.5~2 mass %, more preferably 0.7~2 mass %, is more preferably 1~2 mass %.
In addition, in the case where the cleaning agent for automatic cleaning machine of tableware composition of the present invention contains (A)~(E) components,
From the viewpoint of reduce incrustation scale attachment, 100 mass % are added up to preferably with respect to the content of (A)~(E) components, (E) into
The content divided is more than 40 mass %, also, it is preferred that be below 80 mass %, more preferably below 70 mass %, more preferably
For below 60 mass %.In addition, for the same reason, 100 matter are added up to preferably with respect to the content of (A)~(E) components
% is measured, the content of (E) component is 40~80 mass %, more preferably 40~70 mass %, is more preferably 40~60 matter
Measure %.
The cleaning agent for automatic cleaning machine of tableware composition of the present invention can further contain with the suction produced by hydrogen bond
The organic high molecular compound of water-based powder.Specifically, can enumerate dextrin, carragheen, xanthans, guar gum, pectin,
The polysaccharide such as locust bean gum or their derivative, producing starch, methylcellulose, carboxymethyl cellulose, polyvinyl
Synthetic macromolecular compounds such as alcohol, polyacrylamide, polyoxyethylene etc..Containing the organic high of these spongy powders of tool
In the case of molecular compound, from the viewpoint of storage stability, its content is used clear in the automatic cleaning machine of tableware of the present invention
It is preferably more than 0.1 mass % in detergent composition, also, it is preferred that be below 20 mass %, more preferably below 15 mass %,
More preferably below 5 mass %.For the same reason, these have the organic high molecular compound of spongy powder
Content is preferably 0.1~20 mass %, more preferably 0.1~15 mass % in the composition, is more preferably 0.1~5
Quality %.
The present invention composition it can in addition contain containing anion surfactant (for example, International Publication No. 99/58633
Anion surfactant described in number pamphlet), amphoteric surfactant, enzyme, the bleaching agent [bleaching beyond (B) component
Agent], defoamer, antirust agent, hydrotropic solvent, surface modifier, spices etc..
The cleaning agent for automatic cleaning machine of tableware composition of the present invention may be used as business and use and home-use wash dishes
Machine is used, and is especially suitable as that each scavenging period is short (for example, 40~60 seconds), and each cleaning materials is a large amount of, and 1 day into
The dish cleaning machine for the business that row is cleaned multiple times is used.At this time, composition of the invention is few even in the usage amount of flushing water
Condition relative to tableware (for example, set horizontal plane per 2500cm2Often rinsed once for 2~3L/) under, suppress tea stain attachment and
Excellent effect is also showed that in terms of reducing water spots.In addition, the tableware as object, can also enumerate by ware, glass,
Cup, glass, jorum, bowl, chopsticks, plate, the meal of a variety of materials such as melamine resin, polycarbonate resin, wood, metal composition
Knife, fork, soupspoon etc. can be in the tablewares that dish cleaning machine cleans in.
When being cleaned with the dish cleaning machine of business, for example, together with the special magazine of business dish cleaning machine
In the container such as plastics filled with cleaning agent for automatic cleaning machine of tableware composition be installed on definite direction, or will be filled in
The cleaning agent for automatic cleaning machine of tableware composition displacement special magazine of business dish cleaning machine in bag container etc..Then, it is right
In mounted composition, water or warm water are sprayed by sprayer or shower etc., dissolved cleaning solution supplying is used to business
Inside dish cleaning machine, the cleaning for tableware.
The cleaning agent for automatic cleaning machine of tableware composition of the present invention when in use, can be used as and be diluted to suitably with water etc.
Concentration cleaning solution use, in such a case it is possible to be diluted to the concentration of said composition for example as 0.05~0.3 mass %
To use.In such a situation it is preferred that pH of the cleaning solution after dilution at 25 DEG C is more than 10.5 and less than 11.5.The present invention's
PH of the cleaning agent for automatic cleaning machine of tableware composition preferably 0.1 mass % aqueous solutions at 25 DEG C for more than 10.5 and 11.5 with
Under.
The cleaning agent for automatic cleaning machine of tableware composition of the present invention is preferably solid, i.e. the shape such as solid block, particle, powder
State, it is more preferably powdered from the viewpoint of the storage stability for ensuring operability and cleaning agent.
In the case where the cleaning agent for automatic cleaning machine of tableware composition of the present invention is powder or granular composition,
The average grain diameter of the cleaning agent for automatic cleaning machine of tableware composition of the present invention is preferably more than 200 μm, also, it is preferred that being 1000
It it is even more preferably 600 μm below below μm.In addition, the average grain diameter is preferably 200~1000 μm, more preferably
200~600 μm.
In addition, average grain diameter mentioned here is the value calculated with dimension criteria, it is to use laser diffraction formula size distribution
Measurement device：The value of LA-500 (hole field makes the manufacture of Co., Ltd. of institute) measure.
In addition, it is the feelings of powder or granular composition in cleaning agent for automatic cleaning machine of tableware composition of the invention
Under condition, cleaning agent for automatic cleaning machine of tableware composition of the invention by JIS K3362 (:2008) apparent density of measure
Preferably more than 0.5g/ml, is more preferably more than 0.6g/ml, is more preferably 1g/ also, it is preferred that being below 1.2g/ml
Below ml.In addition, the apparent density is preferably 0.5~1.2g/ml, more preferably 0.6~1g/ml.
The cleaning agent for automatic cleaning machine of tableware composition of the present invention can be manufactured by usual way, without especially
Limitation, is preferably manufactured by Nauta mixer (Nauta Mixer).Manufacture containing (A)~(E) components, i.e. (A) into
Point, in the case of the composition of (B) component, (C) component, (D) component and (E) component, cleaned from the automatic tableware of the present invention
From the viewpoint of operability when machine is manufactured with cleansing composition, it is preferred to use there is the manufacture method of following process, work
Sequence 1, the anhydride of mixing (A-2) component, (D) component and the carbonate in (E) component；Process 2, obtains in the process 1
(B) component is mixed in mixture；Process 3, (A-1) component, (C) component and (E) are mixed in the mixture obtained in the process 2
The anhydride of silicate in component.As (E) component and with the situation of the anhydride of silicate and the anhydride of carbonate
Under, i.e. in the case where containing the anhydride of the anhydride of silicate and carbonate as (E) component, the preferred nothing of carbonate
Water thing mixes in process 1, and the anhydride of silicate mixes in process 3.As carried out in these processes 1~3 it is each into
Divide the device of mixing, Nauta mixer, Henschel mixer (Henschel mixer) etc. can be enumerated, be preferably Nuo Ta mixing
Device.In addition, (B) component as liquid component is preferably mixed by being added dropwise, it is preferably 2 as rate of addition in this case
~5 minutes, preferably it is added batch-wise (interval is added).Mixing temperature is preferably more than 10 DEG C, is more preferably more than 20 DEG C, and
And be preferably less than 50 DEG C, it is more preferably less than 40 DEG C.In addition, mixing temperature is preferably 10~50 DEG C, more preferably
20~40 DEG C.
Following presentation embodiments of the present invention.
<Item 1>A kind of cleaning agent for automatic cleaning machine of tableware composition, wherein, contain following (A-1), (A-2) and (B-
1),
(A-1) a kind in methylglycine diacetic acid ester and its alkali metal salt or two or more [hereinafter referred to as
(A-1) component], its content is more than 6 mass % and below 18 mass %；
(A-2) a kind in citric acid and its alkali metal salt or two or more [hereinafter referred to as (A-2) component], its
Content is more than 20 mass % and below 30 mass %；
(B-1) selected from block is combined with oxidation successively on the alcohol that the carbon number with side chain is more than 10 and less than 14
1 kind in the nonionic surfactant of ethene and propylene oxide or two or more [hereinafter referred to as (B-1) component], its content
For more than 3 mass % and below 7 mass %,
(A-1) and total content of (B-1) is more than 10 mass % and below 25 mass %,
(A-1) mass ratio (A-1)/(B-1) of content and the content of (B-1) is more than 1 and less than 5.
<Item 2>Such as<Item 1>The cleaning agent for automatic cleaning machine of tableware composition, wherein, the content of (A-1) component is
More than 7 mass %, more preferably more than 8 mass %, moreover, be below 15 mass %, more preferably 12 mass %
Hereinafter, it is further 8~12 mass % alternatively, being 7~15 mass %.
<Item 3>Such as<Item 1>Or<Item 2>The cleaning agent for automatic cleaning machine of tableware composition, wherein, (A-2) component
Content be more than 23 mass %, and be below 27 mass %, or be 23~27 mass %.
<Item 4>Such as<Item 1>~<Item 3>Any one of cleaning agent for automatic cleaning machine of tableware composition, wherein,
(B-1) be the carbon number with side chain be more than 10, preferably carbon number is more than 12 and carbon number is less than 14
Alcohol on successively block be combined with the nonionic surfactant of ethylene oxide and propylene oxide, and be to be selected from ethylene oxide
The average nonionic that addition molal quantity is more than 4 and the average addition molal quantity of less than 10, propylene oxide is more than 2 and less than 10
1 kind in surfactant or nonionic surfactant of more than two kinds.
<Item 5>Such as<Item 1>~<Item 4>Any one of cleaning agent for automatic cleaning machine of tableware composition, wherein,
(B-1) component be selected from be more than 10 in carbon number, preferably carbon number be more than 12 and carbon number be less than 14 it is secondary
On alcohol successively block be combined with a kind in the nonionic surfactant of ethylene oxide and propylene oxide or two or more.
<Item 6>Such as<Item 1>~<Item 5>Any one of cleaning agent for automatic cleaning machine of tableware composition, wherein,
(B-1) component be carbon number be more than 10, the secondary alcohol that preferably carbon number is more than 12 and carbon number is less than 14
On successively block be combined with the nonionic surfactant that ethylene oxide and propylene oxide form, and for selected from ethylene oxide
The average nonionic that addition molal quantity is more than 4 and the average addition molal quantity of less than 10, propylene oxide is more than 2 and less than 10
1 kind in surfactant or nonionic surfactant of more than two kinds.
<Item 7>Such as<Item 1>~<Item 6>Any one of cleaning agent for automatic cleaning machine of tableware composition, wherein,
(B-1) nonionic surfactant of the component represented by the following general formula (b-1).
R1-O-(EO)s-(PO)t-H (b-1)
[in formula, R1The alkyl or carbon number for representing the side chain that carbon number is more than 10 and less than 14 are more than 10
And the alkenyl or carbon number of less than 14 side chain be 10~14 side chain alkyl or carbon number be 10~14 side chain
Alkenyl, EO represent ethyleneoxy, PO represent propenyloxy group.S, t represents average addition molal quantity respectively, and s is more than 4, preferably
For more than 5, and be less than 10, to be preferably less than 9, t be more than 2, is preferably more than 5, and for less than 10, preferably 9 with
Under, t/s is more than 0.3, is preferably more than 0.5, more preferably more than 0.7, more preferably more than 0.9, and is 1.5
Below, it is preferably less than 1.4, more preferably less than 1.3.In addition, s=4~10, preferably s=5~9, t=2~10,
Preferably t=5~9, more preferably 0.3≤(t/s)≤1.5, preferably 0.5≤(t/s)≤1.4,0.7≤(t/s)≤
1.3。“-(EO)s-(PO)t- " combined for block.]
<Item 8>Such as<Item 1>~<Item 7>Any one of cleaning agent for automatic cleaning machine of tableware composition, wherein,
(B-1) content of component is more than 3 mass % and below 6 mass %, is further more than 3 mass % and below 5 mass %, or
Person, is 3~6 mass %, is further 3~5 mass %.
<Item 9>Such as<Item 1>~<Item 8>Any one of cleaning agent for automatic cleaning machine of tableware composition, wherein,
(A-1) total content of component and (B-1) component is more than 12 mass %, is further more than 14 mass %, being further
More than 16 mass %, moreover, for below 23 mass %, be further below 21 mass %, be further below 19 mass %,
Alternatively, it is 12~23 mass %, is further 14~21 mass %, is further 16~19 mass %.
<Item 10>Such as<Item 1>~<Item 9>Any one of cleaning agent for automatic cleaning machine of tableware composition, wherein,
(A-1) mass ratio (A-1)/(B-1) of the content of component and the content of (B-1) component is more than 1.5, is further more than 2, more
Be further more than 2.5, moreover, for less than 4.5, be further less than 4, be further less than 3.5, alternatively, for 1.5~
4.5, further for 2~4, be further 2.5~3.5.
<Item 11>Such as<Item 1>~<Item 10>Any one of cleaning agent for automatic cleaning machine of tableware composition, wherein,
[nonionic surfactant of (B-1) component below, will be also included containing the nonionic surfactant beyond (B-1) component
As (B) component].
<Item 12>Such as<Item 11>The cleaning agent for automatic cleaning machine of tableware composition, wherein, as (B) component, contain
There is (B-2) block on the alcohol with the alkyl that carbon number is more than 8 and less than 18 to be combined with ethylene oxide and propylene oxide
Nonionic surfactant [remove (B-1) component the carbon number with side chain be more than 10 and less than 14 alcohol on
Block is combined with the nonionic surfactant of ethylene oxide and propylene oxide successively] [hereinafter referred to as (B-2) component].
<Item 13>Such as<Item 12>The cleaning agent for automatic cleaning machine of tableware composition, wherein, (B-2) component is general formula
(b-2) nonionic surfactant represented by.
R2-O-(EO)p-(PO)q-(EO)r-H (b-2)
[in formula, R2Represent the alkyl that carbon number is more than 8 and less than 18 alkyl or carbon number is 8~18, EO tables
Show ethyleneoxy, PO represents propenyloxy group.P, q, r represent average addition molal quantity respectively, and p is more than 1 and less than 10, q 0.5
Above and less than 5, r are more than 1 and less than 10, in addition, p=1~10, q=0.5~5, r=1~10.“-(EO)p-(PO)q-
(EO)r- " combined for block.]
<Item 14>Such as<Item 12>Or<Item 13>The cleaning agent for automatic cleaning machine of tableware composition, wherein, (B-1) into
Point and total content of (B-2) component be more than 3 mass %, be further more than 3.5 mass %, being further 4 mass %
More than, moreover, for below 7 mass %, be further below 6.5 mass %, be further below 6 mass %, alternatively, being 3
~7 mass %, further for 3.5~6.5 mass %, be further 4~6 mass %.
<Item 15>Such as<Item 12>~<Item 14>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, mass ratio (B-1)/(B-2) of the content of (B-1) component and the content of (B-2) component is more than 1, is further more than 2,
Moreover, for less than 15, be further less than 10, be further less than 8, be further less than 6, alternatively, for 1~15, into
One step is 1~10, is further 2~8, is further 2~6.
<Item 16>Such as<Item 12>~<Item 15>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, in (B) component, total ratio of (B-1) component and (B-2) component is more than 90 mass %, is further 95 mass %
Above, it is further more than 98 mass %, moreover, being below 100 mass %, alternatively, being 90~100 mass %, further
For 95~100 mass %, be further 98~100 mass %.
<Item 17>Such as<Item 1>~<Item 16>Any one of cleaning agent for automatic cleaning machine of tableware composition, wherein,
(A-1) total content of component and (A-2) component [following, to be known as (A) component in the lump by this 2] and (B-1) component or
(A) total content of component and (B) component is more than 30 mass %, is further more than 35 mass %, moreover, being 50 mass %
Below, it is further below 45 mass %, alternatively, being 30~50 mass %, being further 35~45 mass %.
<Item 18>Such as<Item 12>~<Item 17>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, (A) component, total content of (B-1) component and (B-2) component be more than 30 mass %, is further more than 35 mass %,
It is further below 45 mass % moreover, being below 50 mass %, alternatively, being 30~50 mass %, being further 35~45 matter
Measure %.
<Item 19>Such as<Item 1>~<Item 18>Any one of cleaning agent for automatic cleaning machine of tableware composition, wherein,
(A) content of component and mass ratio (A)/(B-1) or the content of (A) component of the content of (B-1) component and containing for (B) component
Mass ratio (A)/(B) of amount is more than 3, is further more than 4, is further more than 5, moreover, being less than 12, being further
Less than 11, further it is less than 10, alternatively, being 3~12, being further 4~11, being further 5~10.
<Item 20>Such as<Item 12>~<Item 19>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, content and (B-1) component and mass ratio (A)/[(B-1)+(B-2)] of total content of (B-2) component of (A) component are 3
Above, it is further more than 4, is further more than 5, moreover, is less than 12, being further less than 11, being further 10
Hereinafter, alternatively, being 3~12, being further 4~11, being further 5~10.
<Item 21>Such as<Item 1>~<Item 20>Any one of cleaning agent for automatic cleaning machine of tableware composition, wherein,
Further contain to have selected from (C-1) polyacrylic acid and its salt [hereinafter referred to as (C-1) component] and (C-2) and come from maleic acid
Monomeric unit copolymer and its salt [hereinafter referred to as (C-2) component] in more than a kind of high-molecular compound (C) [with
Under, it is known as (C) component].
<Item 22>Such as<Item 21>The cleaning agent for automatic cleaning machine of tableware composition, wherein, (C-2) component be selected from
More than a kind of high-molecular compound in the copolymer and its salt of acrylic acid and maleic acid, the Component units from acrylic acid/come
Molar ratio from the Component units of maleic acid is more than 90/10, is further more than 75/25, moreover, for less than 50/50, into one
Walk as less than 65/35, alternatively, for 90/10~50/50, be further 75/25~65/35.
<Item 23>Such as<Item 21>Or<Item 22>The cleaning agent for automatic cleaning machine of tableware composition, wherein, (C-1) into
Point polyacrylic acid and its weight average molecular weight of salt be 1, more than 000, be further 3, more than 000, moreover, be 10,000 with
Under, be further 8, less than 000, be further 6, less than 000, be further 5, less than 000, alternatively, for 1,000~
10,000th, it is further 3,000~5,000.
<Item 24>Such as<Item 21>~<Item 23>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, the copolymer with the unit from maleic acid of (C-2) component or the weight average molecular weight of its salt be 1, more than 000, into
One step is 3, more than 000, moreover, be 10, less than 000, be further 5, less than 000, alternatively, being 1,000~10,000, into one
Walk as 3,000~5,000.
<Item 25>Such as<Item 21>~<Item 24>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, the copolymer with the unit from maleic acid of (C-2) component or the weight average molecular weight of its salt be 10, more than 000, into
One step be 30, more than 000, be further 50, more than 000, moreover, be 150, less than 000, be further 120, less than 000,
Further it is less than 100,000.
<Item 26>Such as<Item 21>~<Item 25>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, as (C) component, containing (C-1) component and (C-2) component, mass ratio (C-1)/(C- of (C-1) component and (C-2) component
2) it is more than 1, is preferably more than 2, is more preferably more than 3, moreover, is less than 30, being preferably less than 20, further preferably
For less than 10.
<Item 27>Such as<Item 21>~<Item 26>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, the content of (C) component is more than 5 mass %, is further more than 6 mass %, is further more than 7 mass %, moreover,
For below 15 mass %, be further below 14 mass %, be further below 13 mass %, alternatively, being 5~15 matter
Measure %, further for 6~14 mass %, be further 7~13 mass %.
<Item 28>Such as<Item 21>~<Item 27>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, (A-1) component, total content of (A-2) component and (C) component be more than 30 mass %, be further more than 33 mass %,
It is further more than 35 mass %, is further more than 40 mass %, moreover, being below 50 mass %, being further 47
Below quality %, be further below 45 mass %, alternatively, being 30~50 mass %, being further 33~47 mass %, more
It is further 35~45 mass %.
<Item 29>Such as<Item 1>~<Item 28>Any one of cleaning agent for automatic cleaning machine of tableware composition, wherein,
Further contain the inorganic particle (D) [hereinafter referred to as (D) component] that ability is supported with liquid.
<Item 30>Such as<Item 29>The cleaning agent for automatic cleaning machine of tableware composition, wherein, (D) component is selected from non-
More than a kind of the inorganic particle that ability is supported with liquid in crystalloid silica and crystallinity calcium silicates.
<Item 31>Such as<Item 29>Or<Item 30>The cleaning agent for automatic cleaning machine of tableware composition, wherein, (D) component
The obtained oil suction of method recorded by JIS K6220 (- 1995) can be more than 120ml/100g, moreover, being 1,000ml/
Below 100g, be further below 600ml/100g, alternatively, being 120~1,000ml/100g, being further 120~600ml/
100g。
<Item 32>Such as<Item 29>~<Item 31>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, the content of (D) component is more than 0.5 mass %, is further below 0.7 mass %, is further more than 1 mass %,
Moreover, it is below 2 mass %, alternatively, being 0.5~2 mass %, being further 0.7~2 mass %, being further 1~2 matter
Measure %.
<Item 33>Such as<Item 1>~<Item 32>Any one of cleaning agent for automatic cleaning machine of tableware composition, wherein,
Further containing more than a kind of alkaline agent (E) [hereinafter referred to as (E) in anhydride and the anhydride of carbonate selected from silicate
Component].
<Item 34>Such as<Item 33>The cleaning agent for automatic cleaning machine of tableware composition, wherein, (E) component is selected from silicon
More than a kind of alkaline agent in the anhydride of acid alkali metal salt and the anhydride of alkali metal carbonate salt.
<Item 35>Such as<Item 33>Or<Item 34>The cleaning agent for automatic cleaning machine of tableware composition, wherein, (E) component
For more than a kind of the alkaline agent in natrium carbonicum calcinatum, Anhydrous potassium carbonate, anhydrous sodium metasilicate.
<Item 36>Such as<Item 33>~<Item 35>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, contain the anhydride of carbonate and the anhydride of silicate as (E) component.
<Item 37>Such as<Item 33>~<Item 36>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, the anhydride and anhydrous sodium metasilicate of the carbonate in natrium carbonicum calcinatum and Anhydrous potassium carbonate are contained as (E) component.
<Item 38>Such as<Item 33>~<Item 37>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, contain natrium carbonicum calcinatum and anhydrous sodium metasilicate as (E) component, the content of natrium carbonicum calcinatum and the content of anhydrous sodium metasilicate
Mass ratio (content of natrium carbonicum calcinatum)/(content of anhydrous sodium metasilicate) is more than 1.5, is further more than 2, is further
More than 2.5, moreover, being less than 4, being further less than 3.5, being further less than 3, alternatively, being 1.5~4, being further 2
~3.5, further it is 2.5~3.
<Item 39>Such as<Item 33>~<Item 38>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, the content of (E) component is more than 40 mass %, moreover, be further below 70 mass %, be further 65 mass % with
Under, further be below 60 mass %, alternatively, be 40~70 mass %, be further 40~65 mass %, be further
40~60 mass %.
<Item 40>Such as<Item 33>~<Item 39>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, containing (A)~(E) components, 100 mass % are added up to relative to the content of (A)~(E) components, the content of (A) component is
More than 20 mass %, be further more than 23 mass %, be further more than 26 mass %, moreover, for below 55 mass %,
It is further below 50 mass %, is further below 45 mass %, alternatively, being 20~55 mass %, being further 23~50
Quality %, be further 26~45 mass %.
<Item 41>Such as<Item 33>~<Item 40>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, containing (A)~(E) components, 100 mass % are added up to relative to the content of (A)~(E) components, the content of (B) component,
The total content for being further (B-1) component and (B-2) component be more than 3 mass %, moreover, being below 10 mass %, into one
Walk as below 9 mass %, be further below 8 mass %, alternatively, for 3~10 mass %, be further 3~9 mass %,
It is further 3~8 mass %.
<Item 42>Such as<Item 33>~<Item 41>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, containing (A)~(E) components, 100 mass % are added up to relative to the content of (A)~(E) components, the content of (C) component is
More than 5 mass %, be further more than 6 mass %, be further more than 7 mass %, moreover, for below 15 mass %, into
One step is below 14 mass %, is further below 13 mass %, alternatively, for 5~15 mass %, be further 6~14 matter
Measure %, be further 7~13 mass %.
<Item 43>Such as<Item 33>~<Item 42>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, containing (A)~(E) components, 100 mass % are added up to relative to the content of (A)~(E) components, the content of (D) component is
More than 0.5 mass %, be further more than 0.7 mass %, be further more than 1 mass %, moreover, be below 2 mass %, or
Person, is 0.5~2 mass %, is further 0.7~2 mass %, is further 1~2 mass %.
<Item 44>Such as<Item 33>~<Item 43>Any one of cleaning agent for automatic cleaning machine of tableware composition, its
In, containing (A)~(E) components, 100 mass % are added up to relative to the content of (A)~(E) components, the content of (E) component is
More than 40 mass %, moreover, for below 80 mass %, be further below 70 mass %, be further below 60 mass %,
Alternatively, it is 40~80 mass %, is further 40~70 mass %, is further 40~60 mass %.
<Item 45>Such as<Item 1>~<Item 44>Any one of cleaning agent for automatic cleaning machine of tableware composition, wherein,
Cleaning for the Water-saving cleaner using following definitions.
[Water-saving cleaner]
For that can carry out the automatic cleaning machine of tableware of following cleanings, the 0.2 mass % aqueous solutions for making NaOH are 60 DEG C, opposition
20 test film (shapes of 1 in glass supporter：15cm × 15cm × 0.2cm, Nippon Testpanel Co.,
Ltd. the soda-lime glass manufactured) carry out more than 40 seconds and after the cleaning of less than 60 seconds, set horizontal plane every with relative to tableware
2500cm2For 2L water and be allowed to be rinsed for 80 DEG C, then, the test film after ten minutes in 25 DEG C of air dryings
On NaOH residual quantities be 0.15 μ g/cm2Below, it is preferably 0.12 μ g/cm2Below, it is more preferably 0.1 μ g/cm2Below.
Here, 10 second time in the distilled water that NaOH residual quantities are the 200g that every 1 test film is impregnated in 25 DEG C, extraction residue in examination
Test after the NaOH of on piece, acid-base titration is carried out with the hydrochloric acid (HCl) of 0.01mol/L, the amount of the NaOH in quantitative extracting solution, is asked
Go out the average value relative to the test film of 20.In addition, tableware sets the area of horizontal plane, it is using shelf (tableware storage
Shelf) in the case of, defined with the area of the bottom surface of the shelf.
<Item 46>A kind of manufacture method of cleaning agent for automatic cleaning machine of tableware composition, wherein, the manufacture method is
Containing described<Item 36>~<Item 45>Any one of cleaning agent for automatic cleaning machine of tableware composition in (A) component,
(B) manufacture method of the cleaning agent for automatic cleaning machine of tableware composition of component, (C) component, (D) component and (E) component,
The manufacture method has following process,
Process 1, mixing (A-2) component, (D) component, the anhydride of carbonate in (E) component；
Process 2, (B) component is mixed in the mixture obtained in the process 1；
Process 3, the silicic acid in (A-1) component, (C) component, (E) component is mixed in the mixture obtained in the process 2
The anhydride of salt.
<Item 47>Such as<Item 46>The manufacture method of the cleaning agent for automatic cleaning machine of tableware composition, wherein, pass through
Nauta mixer carries out the mixing of component.
<Item 48>A kind of cleaning method of tableware, wherein, have：Using above-mentioned<Item 1>~<Item 45>Any one of
Cleaning agent for automatic cleaning machine of tableware composition pass through automatic cleaning machine of tableware clean tableware process；After rinsing the process
The process of tableware, horizontal plane is set per 2500cm in rinsing every time relative to tableware2With the water of 2~3L.
<Item 49>A kind of cleaning method of tableware, wherein, have：Using described<Item 1>~<Item 45>Any one of
Cleaning agent for automatic cleaning machine of tableware composition using Water-saving cleaners cleaning tablewares defined in following process；Rinse
The process of tableware after the process, horizontal plane is set per 2500cm in rinsing every time relative to tableware2With the water of 2~3L,
[Water-saving cleaner]
For that can carry out the automatic cleaning machine of tableware of following cleaning, the 0.2 mass % aqueous solutions for making NaOH are 60 DEG C, right
Found 20 test film (shapes of 1 in glass supporter：15cm × 15cm × 0.2cm, Nippon Testpanel Co.,
Ltd. the soda-lime glass manufactured) carry out more than 40 seconds and after the cleaning of less than 60 seconds, set horizontal plane every with relative to tableware
2500cm2For 2L water and be allowed to be rinsed for 80 DEG C, then, in 25 DEG C of air dryings on the test film of 10 minutes
NaOH residual quantities be 0.15 μ g/cm2Below, it is preferably 0.12 μ g/cm2Below, it is more preferably 0.1 μ g/cm2Below.
This, NaOH residual quantities be every test film is impregnated in 25 DEG C, the 10 second time in the distilled water of 200g, extraction residues in test film
On NaOH after, carry out acid-base titration with the hydrochloric acid (HCl) of 0.01mol/L, the amount of the NaOH in quantitative extracting solution, obtains phase
For the average value of the test film of 20.In addition, tableware sets the area of horizontal plane, the shelf (frame of tableware storage is being used
Son) in the case of, defined with the area of the bottom surface of the shelf.
<Item 50>Such as<Item 48>Or<Item 49>The cleaning method of the tableware, wherein, do not add in the water for flushing
Add irrigation.
<Item 51>Such as<Item 1>~<Item 45>Any one of cleaning agent for automatic cleaning machine of tableware composition be used as from
The purposes of dynamic dish cleaning machine cleaning agent.
<Item 52>Such as<Item 1>~<Item 45>Any one of cleaning agent for automatic cleaning machine of tableware composition as use
The purposes of cleaning agent for automatic cleaning machine of tableware in the cleaning by following defined Water-saving cleaners,
[Water-saving cleaner]
For that can carry out the automatic cleaning machine of tableware of following cleaning, the 0.2 mass % aqueous solutions for making NaOH are 60 DEG C, right
Found 20 test film (shapes of 1 in glass supporter：15cm × 15cm × 0.2cm, Nippon Testpanel Co.,
Ltd. the soda-lime glass manufactured) carry out more than 40 seconds and after the cleaning of less than 60 seconds, set horizontal plane every with relative to tableware
2500cm2For 2L water and be allowed to be rinsed for 80 DEG C, then, in 25 DEG C of air dryings on the test film of 10 minutes
NaOH residual quantities be 0.15 μ g/cm2Below, it is preferably 0.12 μ g/cm2Below, it is more preferably 0.1 μ g/cm2Below.
This, the 10 second time in the distilled water that NaOH residual quantities are the 200g that every test film is impregnated in 25 DEG C, extraction residues in experiment
After the NaOH of on piece, acid-base titration is carried out with the hydrochloric acid (HCl) of 0.01mol/L, the amount of the NaOH in quantitative extracting solution, is obtained
Relative to the average value of the test film of 20.In addition, tableware set horizontal plane area, using shelf (tableware storage
Shelf) in the case of, defined with the area of the bottom surface of the shelf.
Embodiment
<The modulation of cleaning agent for automatic cleaning machine of tableware composition>
According to the manufacture method with following processes 1, process 2 and process 3, mixing, process 1 are stirred：By table 1,2
The anhydride of (A-2) component, (D) component in component and the carbonate in (E) component mixes；Process 2：In the process 1
(B) component is mixed in obtained mixture；Process 3：(A-1) component (or generation is mixed in the mixture obtained in the process 2
Be sodium tripolyphosphate for (A-1) component, the hydrations of GLDA or two EDTA tetrasodium salts), the silicon in (C) component and (E) component
The anhydride of hydrochlorate.Thus, powdered cleaning agent for automatic cleaning machine of tableware composition (total use level of table 1,2 is obtained
For 10kg).
As the device for stirring and the mixing for carrying out each component, Nauta mixer, Henschel mixer etc. can be enumerated.Separately
Outside, the rate of addition in the case of mixing (B) component as liquid component as dropwise addition, is preferably 2~5 minutes, is preferably
It is added batch-wise (interval is added).The cleaning agent for automatic cleaning machine of tableware composition of table 1,2 uses Nauta mixer " Hosokawa
Micron Corporation, model：DBY-10R ", make dropwise addition mixing as liquid component (B) component in the case of drop
Acceleration is 3 minutes, and it is to be added batch-wise and (intermittently add) to modulate to make adding method.In addition, the revolution rotational speed regulation of propeller
For 8 (rpm/min), rotation rotational speed regulation is 225 (rpm/min), is mixed.
Using table 1,2 component in the case of fitting method in, from start stir (A-2) component, (D) component, nothing
Mixing temperature more than any one of aqueous sodium carbonate and Anhydrous potassium carbonate untill final mixture is obtained is 10~50 DEG C.
In addition, the required mixing time of each operation is respectively 3~7 minutes.In the cleaning agent for automatic cleaning machine of tableware of modulation table 1,2
When composition, from (A-2) component started in stirring (A-2) component, (D) component, natrium carbonicum calcinatum and Anhydrous potassium carbonate
Mixing temperature untill final mixture is obtained is 20~40 DEG C.In addition, the required mixing time of each operation is respectively 5
Minute.
<Cleaning is evaluated>
[1] evaluation of tea stain tachment inhibiting effect
By business dish cleaning machine [the Sanyo Electric strain of the cleansing composition input single-door of ormal weight (about 2kg)
Formula commercial firm manufacture, SANYO DR53] magazine in, by concentration of lotion become 0.1 mass % in a manner of set operating cleaning machine,
Cleaning temperature is 60 DEG C, cleansing composition concentration is 0.1 mass %, scavenging period is 40 seconds, rinses temperature is 80 DEG C, punching
The time is washed to carry out 50 idle running under conditions of 10 seconds, concentration when to operate control do not have it is devious in a manner of be adjusted.Separately
Outside, with the following method since cleaning start until cleaning end with rinse bath (38L) it is interior there are model dirt (casein Ca salt,
Tannin Ca salt, salad oil) mode set.
(cleaning condition)
Cleaning temperature：60℃
Cleansing composition concentration；0.1 mass %
Scavenging period：40 seconds
Rinse temperature：80℃
Washing time：10 seconds
The water rinsed every time：2L
Clean the water hardness：DH or 6 ° of dH of Deutschland hardness 3 °
Model dirt in rinse bath：Casein Ca salt, tannin Ca salt and salad oil
[method that model dirt is put into rinse bath]
As the model of casein Ca salt, albumin (is come from into egg, Wako Pure Chemical Industries, Ltd.'s manufacture：Reagent) with
The concentration of albumin in rinse bath continuously puts into cleaning as the mode of 25ppm or 50ppm from cleaning start to finish
In groove.In addition, the model as tannin Ca salt, the baking tea boiled is become with the concentration of the baking tea boiled in rinse bath
The mode of 100ppm is continuously put into rinse bath since cleaning to end.In addition, the model as greasy dirt, by salad oil
(Nisshin OilliO Group Ltd. are manufactured：Day clear salad oil) 100ppm become with the concentration of the salad oil in rinse bath
Mode since cleaning start to end continuously put into rinse bath.
(evaluation method of tea stain tachment inhibiting effect)
The cook that baking tea is added in 4 melamine cups (capacity about 150cc) (adds relative to the boiled water of 1.8L
Enter 10 and bakee tea bags to make tea, the material that is obtained after liquid cooling to room temperature after ten minutes will be boiled) until respectively eighty per cant, it is quiet
After putting 10~20 seconds, discard and bakee tea, cleaned under above-mentioned cleaning condition.Repeat the operation 50 times and (carry out 50 bakings
Roasting tea puts into, discards, cleaning) after, appearance is observed by visual observation, based on following standard determination tea stain tachment inhibiting effects.
In addition, in the cleaning of each cleansing composition, it is impossible to confirm the difference of the state between 4 cups.
* the evaluation criterion of tea stain tachment inhibiting effect
5：4 melamine cups are all without attachment tea stain.
4：4 melamine cups are all attached with tea stain slightly.(compared to evaluation 5, be able to confirm that has attachment slightly)
3：4 melamine cups have had been found that dark brown part attachment.
2：4 melamine cups have had been found that tea stain attachment.(it is able to confirm that more compared to the attachment of evaluation 3 or compared to commenting
The attachment of valency 1 is few)
1：4 melamine cups have been found that the attachment of thick and heavy tea stain.
In above-mentioned evaluation criterion, more than 4 are judged as qualification.
[2] water spots is evaluated
(making of evaluation glass)
The commercially available beverages of 1g are coated with new glass system cup (internal diameter 55mm, height 113mm) with milk (MEGMILK oxen
Milk, MEGMILK SNOW BRAND Co., Ltd.s) after, 50 DEG C dried 1 it is small when wineglass as being attached with model dirt
Evaluation glass, for water spots evaluate.
(cleaning method)
Thrown in rinse bath (38L) of the business with dish cleaning machine [the SANYO DR53 that Sanyo Electric Co., Ltd manufactures]
Enter 30g cleaning agent for automatic cleaning machine of tableware compositions, be allowed to dissolve with 55 DEG C of warm water.Placed in special racks on 4
Commentary valency glass, 60 second time is cleaned with 55 DEG C of cleaning solution, then, without using irrigation with 80 DEG C of the flushing of 2L
Water rinses 10 seconds.This sets horizontal plane per 2500cm equivalent to each flushing tableware2It is rinsed for the water of 2L.From special frame
Evaluation glass is taken out on son, drying is allowed at 25 DEG C.
In addition, the ejected wash water in cleaning using Deutschland hardness for 3 ° of dH or 6 ° of dH.It is and upper in addition, when being cleaned
State the evaluation of tea stain tachment inhibiting effect similarly, with rinse bath there are casein Ca salt dirt, tannin Ca salt dirt with
And the mode of grease is set.That is, as the dirt in rinse bath, the model as casein Ca salt (comes from albumin
Egg, Wako Pure Chemical Industries, Ltd.'s manufacture：Reagent) with the concentration of the albumin in rinse bath become 25ppm or 50ppm side
Formula is continuously put into rinse bath from cleaning start to finish.In addition, the model as tannin Ca salt, the baking tea that will be boiled
It is clear to terminating continuously to put into since cleaning in a manner of the concentration of the baking tea boiled in rinse bath becomes 100ppm
In washing trough.In addition, the model as greasy dirt, by salad oil, (Nisshin OilliO Group Ltd. are manufactured：Day clear salad oil)
Continuously put into a manner of the concentration of the salad oil in rinse bath becomes 100ppm since cleaning to end in rinse bath.
(water spots evaluation method)
Evaluated according to the number of the water spots on the surface that cleaning and dry evaluation glass have been carried out with the method
Effectiveness.The average water spots number of 4 glasses is recorded in table 1.Average water spots number is preferably less than 20, into one
Step is preferably less than 10.
Component in table is as follows.
Methylglycine diacetic acid salt：Methylglycine diacetic acid trisodium, trade name " Trilon M Compactate "
(BASF AG's manufacture)
Two water salt of trisodium citrate：Trade name " refined sodium citrate M " (Fukawa Chemical Industries Co., Ltd.'s manufacture)
Nonionic surfactant 1-1：R in general formula (b-1)1The secondary alkyl for being 12~14 for carbon number, s=
7.0th, the nonionic surfactant of t=8.5, trade name " SOFTANOLEP7085 " (Nippon Shokubai Co., Ltd's manufacture)
Nonionic surfactant 1-2：R in general formula (b-1)1The secondary alkyl for being 12~14 for carbon number, s=
5.0th, the nonionic surfactant of t=4.5, trade name " SOFTANOLEP5045 " (Nippon Shokubai Co., Ltd's manufacture)
Nonionic surfactant 2-1：R in general formula (b-2)2The straight chained alkyl for being 12~14 for carbon number, p=
3rd, the nonionic surfactant of q=1.5, r=3, trade name " EMULGENLS-106 " (Kao Corp's manufacture)
Nonionic surfactant 2-2：Pass through the ethylene oxide and propylene oxide of higher alcohol made from following synthesis examples
Block addition product [is expediently said, if represented with general formula (b-2), equivalent to the R in general formula (b-2)2It is 12 for carbon number
~13 alkyl, the nonionic surfactant of p=3, q=3, r=0]
Nonionic surfactant 2-3：R in general formula (b-2)2The straight chained alkyl for being 12~14 for carbon number, p=
5th, the nonionic surfactant of q=1.5, r=5, trade name " EMULGENLS-110 " (Kao Corp's manufacture)
Nonionic surfactant 3：Expediently say, if represented with general formula (b-1), the R in general formula (b-1)1For
Secondary alkyl, the nonionic surfactant of s=7.0, t=0 that carbon number is 12~14, the trade name " (strains of SOFTANOL 70 "
Japan of formula commercial firm catalyst manufacture)
Nonionic surfactant 4：Expediently say, if represented with general formula (b-2), the R in general formula (b-2)2For
Straight chained alkyl, the nonionic surfactant of p=6, q=0, r=0 that carbon number is 12~14, trade name " EMULGEN
106 " (Kao Corp's manufactures)
Nonionic surfactant 5：Propylene oxide and ethylene oxide and propylene oxide block polymers, weight average molecular weight
3,100, propylene oxide/ethylene oxide ratio=80/20, trade name " Pluronic RPE2520 " (manufacture of BASF Japan companies)
Polyacrylic acid：Sokalan PA25CL Granules (BASF AG manufactures, weight average molecular weight 5,400)
Acid-co-maleic acid：(BASF AG manufactures Sokalan CP5 Granules, and weight average molecular weight is
85,000)
Amorphous silica：TOKUSIL NR (Tokuyama Corporation manufactures), oil suction can be 250ml/
100g, average grain diameter are 130 μm, specific surface area 195m2/g
Natrium carbonicum calcinatum：Soda ash (light ash) (Central Glass Co., Ltd. manufacture)
Anhydrous potassium carbonate：Potassium carbonate (Asahi Glass Co., Ltd. manufacture)
Anhydrous sodium metasilicate：System ス イ メ タ ケ イ ソ-D (Koei Chemical Co., Ltd.'s manufacture)
Sodium tripolyphosphate：Trade name " tripolyphosphate sodium salt " (manufacture of ShiShimonoseki Mitsui Chemicals, Inc)
·GLDA：Four sodium of glutamine oxalic acid, trade name " Dissolvine GL-PD-S " (AkzoNobel company systems
Make)
Bis- water salt of EDTA4Na：Sodium ethylene diamine tetracetate, trade name " Triron B Powder " (BASF AG's systems
Make)
<Synthesis example：The synthetic method of nonionic surfactant 2-2>
Load in 2L autoclaves 386.8g Dobanol 23 (Mitsubishi chemical Co., Ltd manufactures, DODECANOL, 1- and its
The mixture of branched chain isomer, 1- tridecanols and its branched chain isomer) and 1.12g potassium hydroxide, after being replaced with drying nitrogen
110 DEG C are warming up to, after depressurizing lower dehydration 30 minutes, is warming up to 155 DEG C.Slowly it is pressed into when small with about 2 at 155 DEG C ± 5 DEG C
263.48g ethylene oxides and autoclave internal pressure is set to be not up to more than 0.4MPa.After press-in terminates, react until seeing not
Reduced to autoclave internal pressure.Thereafter, 120 DEG C are cooled to.347.4g propylene oxides are slowly pressed into when small with 2 at 120 DEG C ± 5 DEG C
And autoclave internal pressure is not set to reach more than 0.4MPa.After press-in terminates, reaction is carried out until can't see autoclave internal drop
It is low.It is cooled to after 80 DEG C, puts into 1.20g acetic acid, after mixing 30 minutes, filtering, obtains the ethylene oxide 3 of Dobanol 23
Mole, the block addition product of 3 moles of propylene oxide.
Claims (29)
1. a kind of cleaning agent for automatic cleaning machine of tableware composition, wherein,
Containing following (A-1), (A-2) and (B-1),
(A-1) a kind in methylglycine diacetic acid ester and its alkali metal salt or two or more, its content is 6 mass %
Above and below 18 mass %；
(A-2) a kind in citric acid and its alkali metal salt or two or more, its content is more than 20 mass % and 30 matter
Measure below %；
(B-1) selected from block is combined with ethylene oxide successively on the alcohol that the carbon number with side chain is more than 10 and less than 14
With a kind in the nonionic surfactant of propylene oxide or two or more, its content for more than 3 mass % and 7 mass % with
Under,
(A-1) and total content of (B-1) is more than 10 mass % and below 25 mass %,
(A-1) mass ratio (A-1)/(B-1) of content and the content of (B-1) is more than 1 and less than 5,
(B-1) be on the alcohol that the carbon number with side chain is more than 10 and less than 14 successively block be combined with ethylene oxide and
The nonionic surfactant of propylene oxide, is that the average addition molal quantity selected from ethylene oxide is more than 4 and less than 10, oxidation
The average addition molal quantity of propylene be more than 4 and less than 10 nonionic surfactant in a kind or it is of more than two kinds it is non-from
Sub- surfactant.
2. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 1, wherein,
Further contain be selected from (C-1) and (C-2) in more than a kind of high-molecular compound (C), (C-1) be polyacrylic acid and
Its salt, (C-2) are copolymer and its salt with the monomeric unit from maleic acid.
3. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 2, wherein,
(A-1), total content of (A-2) and (C) is more than 30 mass % and below 50 mass %.
4. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 1 or 2, wherein,
Further containing (B-2), block is combined with oxidation second on the alcohol with the alkyl that carbon number is more than 8 and less than 18
The nonionic surfactant of alkene and propylene oxide, it is more than 10 not include (B-1) in (B-2) in the carbon number with side chain
And block is combined with the nonionic surfactant of ethylene oxide and propylene oxide successively on less than 14 alcohol.
5. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 4, wherein,
(B-1) and total content of (B-2) is more than 3 mass % and below 7 mass %, the content of (B-1) and the content of (B-2)
Mass ratio (B-1)/(B-2) be more than 1 and less than 15.
6. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 1 or 2, wherein,
Further contain the inorganic particle (D) that ability is supported with liquid.
7. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 1 or 2, wherein,
Further containing more than a kind of alkaline agent (E) in anhydride and the anhydride of carbonate selected from silicate.
8. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 7, wherein,
As (E), the anhydride of anhydride and silicate containing carbonate.
9. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 1 or 2, wherein,
(A-1) mass ratio (A-1)/(B-1) of content and the content of (B-1) is more than 1.5 and less than 4.
10. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 1 or 2, wherein,
(A-1) and total content of (B-1) is more than 10 mass % and below 19 mass %.
11. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 2, wherein,
(A-1), total content of (A-2) and (C) is more than 40 mass % and below 47 mass %.
12. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 1 or 2, wherein,
(A-1) content is more than 6 mass % and below 15 mass %.
13. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 1 or 2, wherein,
(B-1) content is more than 3 mass % and below 5 mass %.
14. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 4, wherein,
(B-1) and total content of (B-2) is more than 4 mass % and below 6 mass %.
15. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 4, wherein,
(B-1) content and mass ratio (B-1)/(B-2) of the content of (B-2) is more than 2 and less than 8.
16. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 2, wherein,
(C-1) and (C-2) mass ratio (C-1)/(C-2) be more than 3 and less than 10.
17. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 2, wherein,
(C) content is more than 7 mass % and below 13 mass %.
18. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 1 or 2, wherein,
(A-1) and (A-2) is used as (A) in the lump, the mass ratio (A) of total content of the content of (A) and (B-1) and (B-2)/
[(B-1)+(B-2)] is more than 3 and less than 10.
19. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 1 or 2, wherein,
(B-1) nonionic surfactant represented by the following general formula (b-1),
R1-O-(EO)s-(PO)t-H (b-1)
In formula, R1Represent that carbon number is more than 10 and less than 14 secondary alkyl or carbon number is more than 10 and less than 14
Secondary alkenyl, EO represent ethyleneoxy, and PO represents propenyloxy group, and s, t represent average addition molal quantity respectively, s for more than 5 and 10 with
Under, t is more than 5 and less than 10, t/s are more than 0.5 and less than 1.5, "-(EO)s-(PO)t- " combined for block.
20. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 4, wherein,
(B-2) nonionic surfactant represented by the following general formula (b-2),
R2-O-(EO)p-(PO)q-(EO)r-H (b-2)
In formula, R2Represent the alkyl that carbon number is more than 8 and less than 18 alkyl or carbon number is 8~18, EO represents second
Alkenyloxy group, PO represent propenyloxy group, and p, q, r represent average addition molal quantity respectively, and p is more than 1 and less than 10, q are more than 0.5
And less than 5, r are more than 1 and less than 10, "-(EO)p-(PO)q-(EO)r- " combined for block.
21. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 6, wherein,
(D) for more than a kind in amorphous silica and crystallinity calcium silicates there is liquid to support the inorganic of ability
Powder.
22. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 6, wherein,
(D) oil suction that the method recorded by JIS K 6220 (- 1995) obtains can be more than 120ml/100g and 600ml/
Below 100g.
23. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 6, wherein,
(D) content of component is more than 1 mass % and below 2 mass %.
24. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 7, wherein,
(E) it is more than a kind of alkaline agent in anhydride and the anhydride of the alkali metal salt of carbonic acid selected from silicic acid alkali metal salt.
25. cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 7, wherein,
(E) content is more than 40 mass % and below 60 mass %.
26. a kind of manufacture method of cleaning agent for automatic cleaning machine of tableware composition, wherein,
The cleaning agent for automatic cleaning machine of tableware composition contains：
(A-1) a kind in methylglycine diacetic acid ester and its alkali metal salt or two or more, its content is 6 mass %
Above and below 18 mass %；
(A-2) a kind in citric acid and its alkali metal salt or two or more, its content is more than 20 mass % and 30 matter
Measure below %；
(B-1) selected from block is combined with ethylene oxide successively on the alcohol that the carbon number with side chain is more than 10 and less than 14
With a kind in the nonionic surfactant of propylene oxide or two or more, its content for more than 3 mass % and 7 mass % with
Under,
(A-1) and total content of (B-1) is more than 10 mass % and below 25 mass %,
(A-1) mass ratio (A-1)/(B-1) of content and the content of (B-1) is more than 1 and less than 5,
(B-1) be on the alcohol that the carbon number with side chain is more than 10 and less than 14 successively block be combined with ethylene oxide and
The nonionic surfactant of propylene oxide, is that the average addition molal quantity selected from ethylene oxide is more than 4 and less than 10, oxidation
The average addition molal quantity of propylene be more than 4 and less than 10 nonionic surfactant in a kind or it is of more than two kinds it is non-from
Sub- surfactant,
And further contain：
More than a kind of the high-molecular compound (C) in (C-1) and (C-2), (C-1) are polyacrylic acid and its salt, (C-2)
For copolymer and its salt with the monomeric unit from maleic acid,
The inorganic particle (D) of ability is supported with liquid, and
Anhydride selected from silicate and more than a kind in the anhydride of carbonate of alkaline agent (E),
Also,
The manufacture method has following process,
Process 1, mixing (A-2), (D), the anhydride of carbonate in (E)；
Process 2, mixes (B-1) in the mixture obtained in the process 1；
Process 3, the anhydride of the silicate in (A-1), (C) and (E) is mixed in the mixture obtained in the process 2.
27. the manufacture method of cleaning agent for automatic cleaning machine of tableware composition as claimed in claim 26, wherein,
The mixing of component is carried out by Nauta mixer.
28. a kind of cleaning method of tableware, wherein,
Have：Cleaning agent for automatic cleaning machine of tableware composition any one of usage right requirement 1~25 is using automatically
The process that dish cleaning machine cleans tableware；The process being rinsed for the tableware after the process, is rinsed relative to tableware every time
Horizontal plane is set per 2500cm2With the water of 2~3L.
29. the cleaning agent for automatic cleaning machine of tableware composition any one of claim 1~25 is clear as automatic tableware
The purposes of washing machine cleaning agent.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012119455 | 2012-05-25 | ||
| JP2012-119455 | 2012-05-25 | ||
| PCT/JP2012/080115 WO2013175659A1 (en) | 2012-05-25 | 2012-11-21 | Detergent composition for automatic dishwashing machines |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104350139A CN104350139A (en) | 2015-02-11 |
| CN104350139B true CN104350139B (en) | 2018-04-13 |
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| CN201280073452.1A Expired - Fee Related CN104350139B (en) | 2012-05-25 | 2012-11-21 | Cleaning agent for automatic cleaning machine of tableware composition |
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| Country | Link |
|---|---|
| JP (1) | JP5629404B2 (en) |
| CN (1) | CN104350139B (en) |
| TW (1) | TWI550081B (en) |
| WO (1) | WO2013175659A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12134749B2 (en) | 2018-02-23 | 2024-11-05 | Conopco Inc. | Shaped detergent product composition comprising aminopolycarboxylate |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2886634B1 (en) | 2013-12-20 | 2016-08-24 | Rohm and Haas Company | Automatic dishwashing detergent |
| JP6060097B2 (en) * | 2014-01-21 | 2017-01-11 | 深江商事株式会社 | Cleaning kit and cleaning method |
| JP2015151546A (en) * | 2014-02-13 | 2015-08-24 | シーバイエス株式会社 | Powder detergent composition and manufacturing method thereof |
| JP2016155943A (en) * | 2015-02-25 | 2016-09-01 | 東ソー株式会社 | Chloroprene latex, and production method thereof |
| JP6955746B2 (en) * | 2017-04-13 | 2021-10-27 | シーバイエス株式会社 | Powder detergent composition for automatic dishwasher and tableware cleaning method using it |
| CN107523427B (en) * | 2017-07-28 | 2021-02-19 | 广州立白企业集团有限公司 | Liquid phosphorus-free detergent composition and application thereof |
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| DE102004032320A1 (en) * | 2004-07-02 | 2006-01-19 | Basf Ag | Mixed powder or mixed granules based on MGDA |
| GB0525314D0 (en) * | 2005-12-13 | 2006-01-18 | Reckitt Benckiser Nv | Method and composition |
| JP2008037885A (en) * | 2006-08-01 | 2008-02-21 | Lion Corp | Detergent composition for dish washer |
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2012
- 2012-11-21 CN CN201280073452.1A patent/CN104350139B/en not_active Expired - Fee Related
- 2012-11-21 JP JP2014516624A patent/JP5629404B2/en active Active
- 2012-11-21 WO PCT/JP2012/080115 patent/WO2013175659A1/en active Application Filing
- 2012-11-22 TW TW101143804A patent/TWI550081B/en not_active IP Right Cessation
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| WO2009092699A1 (en) * | 2008-01-24 | 2009-07-30 | Unilever Nv | Machine dishwash detergent compositions |
| CN101597549A (en) * | 2008-06-04 | 2009-12-09 | 罗门哈斯公司 | Polymkeric substance and inhibition foulant cumulative application in automatic bowl is used thereof |
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| US12134749B2 (en) | 2018-02-23 | 2024-11-05 | Conopco Inc. | Shaped detergent product composition comprising aminopolycarboxylate |
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| Publication number | Publication date |
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| WO2013175659A1 (en) | 2013-11-28 |
| JP5629404B2 (en) | 2014-11-19 |
| TW201348435A (en) | 2013-12-01 |
| TWI550081B (en) | 2016-09-21 |
| JPWO2013175659A1 (en) | 2016-01-12 |
| CN104350139A (en) | 2015-02-11 |
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