CN104342014B - A kind of ship antifouling paint - Google Patents
A kind of ship antifouling paint Download PDFInfo
- Publication number
- CN104342014B CN104342014B CN201410571080.6A CN201410571080A CN104342014B CN 104342014 B CN104342014 B CN 104342014B CN 201410571080 A CN201410571080 A CN 201410571080A CN 104342014 B CN104342014 B CN 104342014B
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- China
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- parts
- powder
- antifouling paint
- diene rubber
- mixing
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- 239000003973 paint Substances 0.000 title claims abstract description 27
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 24
- 239000000843 powder Substances 0.000 claims abstract description 62
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 38
- -1 polytrifluorochloroethylene Polymers 0.000 claims abstract description 32
- 229920002943 EPDM rubber Polymers 0.000 claims abstract description 27
- 239000004359 castor oil Substances 0.000 claims abstract description 22
- 235000019438 castor oil Nutrition 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 22
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 22
- 239000004113 Sepiolite Substances 0.000 claims abstract description 20
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 20
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 20
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 20
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 19
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 18
- ZGUQGPFMMTZGBQ-UHFFFAOYSA-N [Al].[Al].[Zr] Chemical compound [Al].[Al].[Zr] ZGUQGPFMMTZGBQ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000007822 coupling agent Substances 0.000 claims abstract description 18
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 18
- 239000005011 phenolic resin Substances 0.000 claims abstract description 18
- 239000000049 pigment Substances 0.000 claims abstract description 17
- 229920002635 polyurethane Polymers 0.000 claims abstract description 17
- 239000004814 polyurethane Substances 0.000 claims abstract description 17
- 239000000378 calcium silicate Substances 0.000 claims abstract description 16
- 229910052918 calcium silicate Inorganic materials 0.000 claims abstract description 16
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003112 inhibitor Substances 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims description 25
- 238000001723 curing Methods 0.000 claims description 16
- 238000001125 extrusion Methods 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 16
- 238000002844 melting Methods 0.000 claims description 16
- 230000008018 melting Effects 0.000 claims description 16
- 239000008247 solid mixture Substances 0.000 claims description 13
- 239000000945 filler Substances 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 238000007873 sieving Methods 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims 2
- 235000012239 silicon dioxide Nutrition 0.000 claims 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 229910052788 barium Inorganic materials 0.000 claims 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 1
- FYHXNYLLNIKZMR-UHFFFAOYSA-N calcium;carbonic acid Chemical compound [Ca].OC(O)=O FYHXNYLLNIKZMR-UHFFFAOYSA-N 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 6
- 230000007797 corrosion Effects 0.000 abstract description 6
- 230000002209 hydrophobic effect Effects 0.000 abstract description 4
- 239000002689 soil Substances 0.000 abstract description 3
- 235000012241 calcium silicate Nutrition 0.000 description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- 229910052731 fluorine Inorganic materials 0.000 description 6
- 238000004381 surface treatment Methods 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 238000000498 ball milling Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- USPURJZIFMFHCR-UHFFFAOYSA-N 2-chloro-4-methylsulfonylpyridine Chemical class CS(=O)(=O)C1=CC=NC(Cl)=C1 USPURJZIFMFHCR-UHFFFAOYSA-N 0.000 description 1
- 125000004189 3,4-dichlorophenyl group Chemical group [H]C1=C([H])C(Cl)=C(Cl)C([H])=C1* 0.000 description 1
- 229940099451 3-iodo-2-propynylbutylcarbamate Drugs 0.000 description 1
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 description 1
- ZLFMPCDXPSDKOQ-UHFFFAOYSA-N CC1=NC(=NC(=N1)NC(C)(C)C)N(C1CC1)S Chemical class CC1=NC(=NC(=N1)NC(C)(C)C)N(C1CC1)S ZLFMPCDXPSDKOQ-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000007590 electrostatic spraying Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000006115 industrial coating Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- LSUIEOBBDXBMCZ-NDENLUEZSA-N methyl 2-[(z)-(9-hydroxy-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-5-ylidene)methyl]thiophene-3-carboxylate Chemical group C1=CSC(\C=C/2C3=C4C(C)=CC(C)(C)NC4=CC=C3C3=C(OC)C(O)=CC=C3O\2)=C1C(=O)OC LSUIEOBBDXBMCZ-NDENLUEZSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 1
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 1
- XQZYPMVTSDWCCE-UHFFFAOYSA-N phthalonitrile Chemical compound N#CC1=CC=CC=C1C#N XQZYPMVTSDWCCE-UHFFFAOYSA-N 0.000 description 1
- 229920006391 phthalonitrile polymer Polymers 0.000 description 1
- WHMDPDGBKYUEMW-UHFFFAOYSA-N pyridine-2-thiol Chemical compound SC1=CC=CC=N1 WHMDPDGBKYUEMW-UHFFFAOYSA-N 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 229940100890 silver compound Drugs 0.000 description 1
- 150000003379 silver compounds Chemical class 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of ship antifouling paint, its raw material includes by weight：Castor oil modified 63 66 parts of aqueous polyurethane, 24 27 parts of phenolic resin, 12 15 parts of polytrifluorochloroethylene, 11 14 parts of powder ethylene propylene diene rubber, 15 18 parts of active calcium silicate, 57 parts of calcium carbonate superfine powder, 45 parts of blanc fixe, 11 13 parts of sepiolite powder, 41.1 1.4 parts of aluminum-zirconium coupling agent TL, 0.2 0.5 parts of curing agent, 0.5 0.8 parts of mould inhibitor, 20 23 parts of pigment.The present invention has excellent hydrophobic and lyophobic property, soil resistance and corrosion resistance, and marine organisms are difficult to adhere to, suitable for the use environment of ship.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of ship antifouling paint.
Background technology
Under the pulling of China's economic strong growth, the situation of rapid growth is presented in Chinese coating industry in recent years.Except building
Build coating increase substantially it is outer, grow up in industrial coating it is most fast, account for the highest non-ship of the market share and anticorrosive paint does not belong to, bag
The anticorrosive paint yield for including the various fields such as ship, container, ocean engineering, petrochemical industry, railway, highway, bridge reaches
More than 100 ten thousand tons.The species of existing marine paint is also more, but cannot tackle well seawater corrosion, marine climate it is prominent
The problem of becoming the attachment with marine organisms.
The content of the invention
Technical problem existing for basic background technology, the present invention propose a kind of ship antifouling paint, have excellent
Hydrophobic and lyophobic property, soil resistance and corrosion resistance, marine organisms are difficult to adhere to, suitable for the use environment of ship.
A kind of ship antifouling paint proposed by the present invention, its raw material include by weight：Castor oil modified water-based poly- ammonia
63-66 parts of ester, 24-27 parts of phenolic resin, 12-15 parts of polytrifluorochloroethylene, 11-14 parts of powder ethylene propylene diene rubber, activated silica
Sour calcium 15-18 parts, 5-7 parts of calcium carbonate superfine powder, 4-5 parts of blanc fixe, 11-13 parts of sepiolite powder, aluminum-zirconium coupling agent TL-
41.1-1.4 parts, 0.2-0.5 parts of curing agent, 0.5-0.8 parts of mould inhibitor, 20-23 parts of pigment；
It is in preparation process, calcium carbonate superfine powder, blanc fixe and sepiolite powder addition stirrer for mixing is uniform, then
After adding aluminum-zirconium coupling agent TL-4, surface treated filler is obtained with 100-120rpm mixing speeds stirring 35-38min；By table
Surface treatment filler, castor oil modified aqueous polyurethane, powder ethylene propylene diene rubber, polytrifluorochloroethylene, phenolic resin, activity
After mixing, after adding double screw extruder melting extrusion, cooling obtains solid for calcium silicates, curing agent, mould inhibitor and pigment
Mixed material, the temperature of melting extrusion is 160-165 DEG C, and the screw speed of double screw extruder is 67-70rpm；Solid is mixed
Compound material is added in ball mill after grinding 42-45min, and taking-up sieving obtains the ship antifouling paint of 470-500 mesh.
Preferably, the ethylene, propylene ratio of powder ethylene propylene diene rubber is 62-68:32-38.
Preferably, the weight ratio of active calcium silicate, calcium carbonate superfine powder, blanc fixe and sepiolite powder is 16-17：5.5-
6.7：4.2-4.5：11.7-12.3.
Preferably, castor oil modified aqueous polyurethane, phenolic resin, polytrifluorochloroethylene and powder ethylene propylene diene rubber
Weight ratio is 64-65：25-26：13-14：12-13.
Preferably, its raw material includes by weight：Castor oil modified aqueous polyurethane 64-65 parts, phenolic resin 25-26
Part, 13-14 parts of polytrifluorochloroethylene, 12-13 parts of powder ethylene propylene diene rubber, 16-17 parts of active calcium silicate, calcium carbonate superfine powder
5.5-6.7 parts, 4.2-4.5 parts of blanc fixe, 11.7-12.3 parts of sepiolite powder, TL-41.2-1.3 parts of aluminum-zirconium coupling agent, Gu
0.3-0.4 parts of agent, 0.6-0.7 parts of mould inhibitor, 21-22 parts of pigment.
Preferably, in preparation process, calcium carbonate superfine powder, blanc fixe and sepiolite powder are added into stirrer for mixing
Uniformly, after adding aluminum-zirconium coupling agent TL-4, surface treatment filling is obtained with 105-115rpm mixing speeds stirring 36-37min
Agent；By surface treated filler, castor oil modified aqueous polyurethane, powder ethylene propylene diene rubber, polytrifluorochloroethylene, phenolic aldehyde tree
Fat, active calcium silicate, curing agent, mould inhibitor and pigment after mixing, after adding double screw extruder melting extrusion, cool down
To solid mixture material, the temperature of melting extrusion is 162-163 DEG C, and the screw speed of double screw extruder is 68-69rpm；Will
Solid mixture material is added in ball mill after grinding 43-44min, and taking-up sieving obtains the ship antifouling paint of 480-490 mesh.
Present invention additionally comprises the antimicrobial or algae-resistant reagent of any conventional.Exemplary conventional antimicrobial or anti-algae
Class reagent include 3-Iodo-2-propynyl butyl carbamate, diiodomethyl to toluene sulfone, 1,2-benzisothiazolin-3-one,
2- methyl mercapto -4- tert-butylamino -6- cyclopropylamino-s- triazines, 2- (4- thiocyanomethylthios) benzothiazole, 2,3,5,6-
Four chloro- 4- (mesyl) pyridines, 3- (3,4- dichlorophenyl) -1,1- dimethyl ureas, Kathon,
The different phthalonitrile of tetrachloro, N- (fluorine dichloro methyl mercapto) phthalimide, N- dichloro fluorine methyl mercapto-N ', N '-dimethyl-
N- para toluene sulfonamides, α-[2- (4- chlorphenyls) ethyl]-α-(1,1- dimethyl ethyl) -1H-1,2,4- triazole -1- ethanol,
N, N- dimethyl-N '-phenyl-(fluorine dichloro methyl mercapto)-sulphamide, (2- thiopyridine -1- oxygen) zinc, (2- thiopyridines -1-
Oxygen) copper, silver compound and its mixture.
The present invention is using castor oil modified aqueous polyurethane, phenolic resin, polytrifluorochloroethylene and powder ethylene-propylene-diene monomer
Glue is enriched with surface fluorine element of the present invention, since fluorine atom electronegativity is big, diameter is small, and carbon-fluorine bond bond energy as film forming matter
For 485kJ/mol, it is far longer than carbon-hydrogen link and carbon-oxygen bond, also greater than silicon-oxygen key and silicon-carbon bond, makes the present invention that there is high knot
Structure stability, and fluorine atom is more easily than with hydrogen atom and shields carbon-fluorine bond, reduces of the water on surface of the present invention
Power, improves the hydrophobicity on surface of the present invention, so that the stain resistance of the present invention is improved, and also the present invention has low-surface-energy,
Make marine organisms be difficult to be attached to hull bottom existence growth, confirm after testing, water contact angle of the invention increases to 99 °, presents obvious
Hydrophobic " lotus leaf " keeps away water effect；By limiting the ethylene, propylene ratio of powder ethylene propylene diene rubber as 62-68:32-38, makes the present invention
Processing performance, low temperature tolerance characteristics and tensile strength reach balance；Active calcium silicate, calcium carbonate superfine powder, blanc fixe and Hai Pao
Mountain flour under the action of aluminum-zirconium coupling agent TL-4, is grafted with film forming matter as filler, improves the toughness after present invention film forming
And impact resistance, and sepiolite powder has abundant corrosion-resistant functional group, and blanc fixe is used cooperatively, and is further improved
The corrosion resistance of the present invention.In conclusion the present invention has excellent hydrophobic and lyophobic property, soil resistance and corrosion resistance, it is suitable for
The use environment of ship.
Embodiment
In the following, technical scheme is described in detail by specific embodiment.
Preparation in the embodiment of the present invention on castor oil modified aqueous polyurethane, specifically refers to Chinese invention patent one
The preparation method of the castor oil modified waterborne blocked polyurethane of kind, Application No. 201110415549.3, publication date are 2012 6
The moon 27, Publication No. 102516496A.
Embodiment 1
A kind of ship antifouling paint proposed by the present invention, its raw material include by weight：Castor oil modified water-based poly- ammonia
63 parts of ester, 27 parts of phenolic resin, 12 parts of polytrifluorochloroethylene, 14 parts of powder ethylene propylene diene rubber, 15 parts of active calcium silicate are ultra-fine
7 parts of calcium carbonate, 4 parts of blanc fixe, 13 parts of sepiolite powder, TL-41.1 parts of aluminum-zirconium coupling agent, 0.5 part of curing agent, mould inhibitor
0.5 part, the ethylene, propylene ratio of 23 parts of pigment, wherein powder ethylene propylene diene rubber is 62:38；
It is in preparation process, calcium carbonate superfine powder, blanc fixe and sepiolite powder addition stirrer for mixing is uniform, then
After adding aluminum-zirconium coupling agent TL-4, surface treated filler is obtained with 120rpm mixing speeds stirring 35min；Surface treatment is filled out
Fill agent, castor oil modified aqueous polyurethane, powder ethylene propylene diene rubber, polytrifluorochloroethylene, phenolic resin, active calcium silicate,
After mixing, after adding double screw extruder melting extrusion, cooling obtains solid mixture for curing agent, mould inhibitor and pigment
Material, the temperature of melting extrusion is 165 DEG C, and the screw speed of double screw extruder is 67rpm；Solid mixture material is added into ball milling
After grinding 45min in machine, take out sieving and obtain the ship antifouling paint of 470 mesh.
Embodiment 2
A kind of ship antifouling paint proposed by the present invention, its raw material include by weight：Castor oil modified water-based poly- ammonia
65 parts of ester, 25 parts of phenolic resin, 14 parts of polytrifluorochloroethylene, 12 parts of powder ethylene propylene diene rubber, 17 parts of active calcium silicate are ultra-fine
5.5 parts of calcium carbonate, 4.5 parts of blanc fixe, 11.7 parts of sepiolite powder, TL-41.3 parts of aluminum-zirconium coupling agent, 0.3 part of curing agent, prevents
Mould dose 0.7 part, the ethylene, propylene ratio of 21 parts of pigment, wherein powder ethylene propylene diene rubber is 64:36；
It is in preparation process, calcium carbonate superfine powder, blanc fixe and sepiolite powder addition stirrer for mixing is uniform, then
After adding aluminum-zirconium coupling agent TL-4, surface treated filler is obtained with 105rpm mixing speeds stirring 37min；Surface treatment is filled out
Fill agent, castor oil modified aqueous polyurethane, powder ethylene propylene diene rubber, polytrifluorochloroethylene, phenolic resin, active calcium silicate,
After mixing, after adding double screw extruder melting extrusion, cooling obtains solid mixture for curing agent, mould inhibitor and pigment
Material, the temperature of melting extrusion is 162 DEG C, and the screw speed of double screw extruder is 69rpm；Solid mixture material is added into ball milling
After grinding 43min in machine, take out sieving and obtain the ship antifouling paint of 490 mesh.
Embodiment 3
A kind of ship antifouling paint proposed by the present invention, its raw material include by weight：Castor oil modified water-based poly- ammonia
66 parts of ester, 24 parts of phenolic resin, 15 parts of polytrifluorochloroethylene, 11 parts of powder ethylene propylene diene rubber, 18 parts of active calcium silicate are ultra-fine
5 parts of calcium carbonate, 5 parts of blanc fixe, 11 parts of sepiolite powder, TL-41.4 parts of aluminum-zirconium coupling agent, 0.2 part of curing agent, mould inhibitor
0.8 part, the ethylene, propylene ratio of 20 parts of pigment, wherein powder ethylene propylene diene rubber is 68:32；
It is in preparation process, calcium carbonate superfine powder, blanc fixe and sepiolite powder addition stirrer for mixing is uniform, then
After adding aluminum-zirconium coupling agent TL-4, surface treated filler is obtained with 115rpm mixing speeds stirring 36min；Surface treatment is filled out
Fill agent, castor oil modified aqueous polyurethane, powder ethylene propylene diene rubber, polytrifluorochloroethylene, phenolic resin, active calcium silicate,
After mixing, after adding double screw extruder melting extrusion, cooling obtains solid mixture for curing agent, mould inhibitor and pigment
Material, the temperature of melting extrusion is 163 DEG C, and the screw speed of double screw extruder is 68rpm；Solid mixture material is added into ball milling
After grinding 44min in machine, take out sieving and obtain the ship antifouling paint of 480 mesh.
Embodiment 4
A kind of ship antifouling paint proposed by the present invention, its raw material include by weight：Castor oil modified water-based poly- ammonia
64 parts of ester, 26 parts of phenolic resin, 13 parts of polytrifluorochloroethylene, 13 parts of powder ethylene propylene diene rubber, 16 parts of active calcium silicate are ultra-fine
6.7 parts of calcium carbonate, 4.2 parts of blanc fixe, 12.3 parts of sepiolite powder, TL-41.2 parts of aluminum-zirconium coupling agent, 0.4 part of curing agent, prevents
Mould dose 0.6 part, the ethylene, propylene ratio of 22 parts of pigment, wherein powder ethylene propylene diene rubber is 66:34；
It is in preparation process, calcium carbonate superfine powder, blanc fixe and sepiolite powder addition stirrer for mixing is uniform, then
After adding aluminum-zirconium coupling agent TL-4, surface treated filler is obtained with 100rpm mixing speeds stirring 38min；Surface treatment is filled out
Fill agent, castor oil modified aqueous polyurethane, powder ethylene propylene diene rubber, polytrifluorochloroethylene, phenolic resin, active calcium silicate,
After mixing, after adding double screw extruder melting extrusion, cooling obtains solid mixture for curing agent, mould inhibitor and pigment
Material, the temperature of melting extrusion is 160 DEG C, and the screw speed of double screw extruder is 70rpm；Solid mixture material is added into ball milling
After grinding 42min in machine, take out sieving and obtain the ship antifouling paint of 500 mesh.
By the ship antifouling paint prepared by embodiment 1-4, through electrostatic spraying in marine surface, at 205-210 DEG C
20-25min crosslinking curings are toasted under baking temperature and obtain marine surface protecting film, performance survey is carried out to marine surface protecting film
Examination, it is as a result as follows：
| Detection project | Embodiment 1-4 average values | Establishing criteria |
| Adhesive force | 1 grade | GB/T 9286-1998 |
| Hardness | H | GB/T 6739-2006 |
| Impact resistance (kgcm) | 55 | GB/T 1732-1993 |
| Pliability | 1.5 | GB/T 1731-1993 |
| Fume resistance (h) | 288 | GB/T 1771-1991 |
| Translucency (%) | 60 | GB 2680-1994 |
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (5)
1. a kind of ship antifouling paint, it is characterised in that its raw material includes by weight：Castor oil modified aqueous polyurethane
63-66 parts, 24-27 parts of phenolic resin, 12-15 parts of polytrifluorochloroethylene, 11-14 parts of powder ethylene propylene diene rubber, active silicic acid
15-18 parts of calcium, 5-7 parts of calcium carbonate superfine powder, 4-5 parts of blanc fixe, 11-13 parts of sepiolite powder, aluminum-zirconium coupling agent TL-4 1.1-
1.4 parts, 0.2-0.5 parts of curing agent, 0.5-0.8 parts of mould inhibitor, 20-23 parts of pigment；The ethylene, propylene of powder ethylene propylene diene rubber
Than for 62-68:32-38；
It is in preparation process, calcium carbonate superfine powder, blanc fixe and sepiolite powder addition stirrer for mixing is uniform, add
After aluminum-zirconium coupling agent TL-4, surface treated filler is obtained with 100-120rpm mixing speeds stirring 35-38min；At surface
Manage filler, castor oil modified aqueous polyurethane, powder ethylene propylene diene rubber, polytrifluorochloroethylene, phenolic resin, active silicic acid
After mixing, after adding double screw extruder melting extrusion, cooling obtains solid mixing for calcium, curing agent, mould inhibitor and pigment
Material, the temperature of melting extrusion is 160-165 DEG C, and the screw speed of double screw extruder is 67-70rpm；By solid mixture
Material is added in ball mill after grinding 42-45min, and taking-up sieving obtains the ship antifouling paint of 470-500 mesh.
2. ship antifouling paint according to claim 1, it is characterised in that active calcium silicate, calcium carbonate superfine powder, precipitated sulfur
The weight ratio of sour barium and sepiolite powder is 16-17：5.5-6.7：4.2-4.5：11.7-12.3.
3. ship antifouling paint according to claim 1 or claim 2, it is characterised in that castor oil modified aqueous polyurethane, phenolic aldehyde
The weight ratio of resin, polytrifluorochloroethylene and powder ethylene propylene diene rubber is 64-65：25-26：13-14：12-13.
4. ship antifouling paint according to claim 1 or claim 2, it is characterised in that its raw material includes by weight：Castor oil
64-65 parts of modified aqueous polyurethane, 25-26 parts of phenolic resin, 13-14 parts of polytrifluorochloroethylene, powder ethylene propylene diene rubber 12-
13 parts, 16-17 parts of active calcium silicate, 5.5-6.7 parts of calcium carbonate superfine powder, 4.2-4.5 parts of blanc fixe, sepiolite powder 11.7-
12.3 parts, TL-41.2-1.3 parts of aluminum-zirconium coupling agent, 0.3-0.4 parts of curing agent, 0.6-0.7 parts of mould inhibitor, 21-22 parts of pigment.
5. ship antifouling paint according to claim 1 or claim 2, it is characterised in that in preparation process, by ultra-fine carbonic acid
Calcium, blanc fixe and sepiolite powder addition stirrer for mixing are uniform, after adding aluminum-zirconium coupling agent TL-4, with 105-
115rpm mixing speeds stirring 36-37min obtains surface treated filler；By surface treated filler, castor oil modified water-based
Polyurethane, powder ethylene propylene diene rubber, polytrifluorochloroethylene, phenolic resin, active calcium silicate, curing agent, mould inhibitor and pigment
After mixing, after adding double screw extruder melting extrusion, cooling obtains solid mixture material, and the temperature of melting extrusion is
162-163 DEG C, the screw speed of double screw extruder is 68-69rpm；Solid mixture material is added in ball mill and grinds 43-
After 44min, take out sieving and obtain the ship antifouling paint of 480-490 mesh.
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| CN105479835A (en) * | 2015-12-17 | 2016-04-13 | 太仓市美斯门窗有限公司 | Novel composite aluminum alloy door and window |
| CN107216786A (en) * | 2017-05-12 | 2017-09-29 | 巢湖市荷花渔网有限公司 | A kind of natural antifouling paint of fishing net |
| CN109266164A (en) * | 2018-07-27 | 2019-01-25 | 佛山市高明区生产力促进中心 | A kind of ceramic coating of chemical-resistance |
| CN109251624A (en) * | 2018-07-27 | 2019-01-22 | 佛山市高明区生产力促进中心 | A kind of ceramic coating resistant to high temperature |
| CN109266163A (en) * | 2018-07-27 | 2019-01-25 | 佛山市高明区生产力促进中心 | A kind of ceramic coating with preferable wearability |
| CN109207016A (en) * | 2018-07-27 | 2019-01-15 | 佛山市高明区生产力促进中心 | A kind of ceramic coating of corrosion resistance |
| CN109673539B (en) * | 2018-11-14 | 2021-05-18 | 浙江海洋大学 | Miichthys miiuy breeding equipment |
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| CN101128553A (en) * | 2005-02-24 | 2008-02-20 | Ppg工业俄亥俄公司 | Methods for preparing fluoropolymer powder coatings |
| CN102516496A (en) * | 2011-12-14 | 2012-06-27 | 燕山大学 | Method for preparing castor oil modified blocked waterborne polyurethane |
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| CN101128553A (en) * | 2005-02-24 | 2008-02-20 | Ppg工业俄亥俄公司 | Methods for preparing fluoropolymer powder coatings |
| CN102516496A (en) * | 2011-12-14 | 2012-06-27 | 燕山大学 | Method for preparing castor oil modified blocked waterborne polyurethane |
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