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CN104289396B - A kind of method of the hot galvanizing piece heavy antisepsis for high-voltage electrical equipment - Google Patents

A kind of method of the hot galvanizing piece heavy antisepsis for high-voltage electrical equipment Download PDF

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Publication number
CN104289396B
CN104289396B CN201410232882.4A CN201410232882A CN104289396B CN 104289396 B CN104289396 B CN 104289396B CN 201410232882 A CN201410232882 A CN 201410232882A CN 104289396 B CN104289396 B CN 104289396B
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hot galvanizing
heavy antisepsis
electrical equipment
voltage electrical
galvanizing piece
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CN104289396A (en
Inventor
张颖杰
廉继英
张柳丽
李宏楼
郝留成
王路平
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State Grid Corp of China SGCC
Pinggao Group Co Ltd
Henan Pinggao Electric Co Ltd
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State Grid Corp of China SGCC
Pinggao Group Co Ltd
Henan Pinggao Electric Co Ltd
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Abstract

A kind of method that the invention discloses hot galvanizing piece heavy antisepsis for high-voltage electrical equipment, comprises the following steps: 1) take pending hot galvanizing piece, carry out weak base defat, surface coarsening process successively;2) taking the hot galvanizing piece after surface coarsening processes, surface spraying epoxy micaceous iron intermediate coat, levelling is also dried, and forms prime coat;3) after primer coat surface being carried out sanded treatment, spraying weatherability finish paint, levelling is also dried, and forms top coat layer.The method of the hot galvanizing piece heavy antisepsis for high-voltage electrical equipment of the present invention, solve the problem that in the most anti-region, between ferrous metal parts hot galvanized layer and isolation coating, adhesion is poor, technique is simple, easy to operate, improve qualification rate and the production efficiency of part, reduce repair rate and the production cost of part;Between film and the hot galvanized layer of gained heavy antisepsis part, adhesive force is strong, and film difficult drop-off improves antiseptic property, extends its service life in heavy antisepsis region.

Description

A kind of method of the hot galvanizing piece heavy antisepsis for high-voltage electrical equipment
Technical field
The invention belongs to surface antiseptisis technology field, be specifically related to a kind of hot galvanizing piece heavy antisepsis for high-voltage electrical equipment Method.
Background technology
Galvanizing or galvanizing by dipping are also in galvanizing, are that the steel part after eliminating rust immerses in melted zinc liquid, make steel piece surface attached Zinc layers, thus play antiseptical purpose.Hot galvanized layer typically more than 35 μm, even as high as 200 μm;Covering power Good, plated layer compact, it is mingled with without Organic substance.The weather-resistant mechanism of zinc coat has mechanical protection and electrochemical protection, greatly Under the conditions of gas corrosion, there are ZnO, Zn (OH) in zinc layers surface2And basic zinc carbonate protecting film, slow down the corrosion of zinc to a certain extent, This protecting film can be formed again new protecting film by destroying;When zinc layers is destroyed serious, and when jeopardizing iron-based body, matrix is produced by zinc Electrochemical protection, the normal potential-0.76V of zinc, the normal potential-0.44V of ferrum, when zinc forms micro cell with ferrum, zinc is as sun The most dissolved, ferrum is protected as negative electrode, and therefore galvanizing is a kind of effective anti-corrosion of metal mode, galvanizing product pair The corrosion inhibitor of iron and steel is lengthened the life, energy-saving material-saving plays inestimable and irreplaceable effect.
In recent years, along with high voltage power transmission, traffic, the developing rapidly of communication career, increasing high-voltage electrical equipment is at family Outer or field is run and work, and steel and iron parts therein is more and more higher for the requirement of protection.In normal circumstances, galvanizing Corrosion protection part individually just can use;But, in the damp and hot region of heavy antisepsis, such as industrial area or the corrosive atmosphere of coastal area In, the hot galvanized layer corrosion rate of steel and iron parts is very fast, is unable to reach the most far away preferable service life.In order to improve heavy antisepsis The anti-corrosion capability of the Summoning part in region, prior art is application again after steel and iron parts is zinc-plated, i.e. uses at hot galvanized layer surface spraying In completely cutting off pollution gas and there is the coating of weatherability, improve the corrosion resistance of product.For hot galvanized layer, its surface The material isolation such as water, corrosion are carried out slowly by film;For film, beneath zinc layers corrosion is slow, damages itself Reduce.Based on above-mentioned both sides reason, application again after galvanizing, make the corrosion-resistant life of hot galvanizing piece, relative to individually heat The life-span sum of zinc-plated and independent application improves 1.5-2.3 times, and this is that one has for needing the occasion of long-term heavy antisepsis The method of effect, but it there is problems of, atopic due to zinc, and film is poor with the adhesion of hot galvanized layer;Giving birth to During product, the film obscission that causes owing between film and hot galvanized layer adhesive force is bad often occurs, reduces The qualification rate of part and production efficiency, the production cost causing part is higher, repair rate is higher;Have impact on hot galvanizing piece simultaneously Service life in heavy antisepsis region, it is impossible to reach the requirement of life-time service.
Summary of the invention
A kind of method that it is an object of the invention to provide hot galvanizing piece heavy antisepsis for high-voltage electrical equipment, solves existing film And between hot galvanized layer, adhesive force is poor and that the cause caducous phenomenon of film.
In order to realize object above, the technical solution adopted in the present invention is: a kind of hot galvanizing piece for high-voltage electrical equipment The method of heavy antisepsis, comprises the following steps:
1) take pending hot galvanizing piece, carry out weak base defat, surface coarsening process successively;
2) taking the hot galvanizing piece after surface coarsening processes, surface spraying epoxy micaceous iron intermediate coat, levelling is also dried, and forms the end Enamelled coating;
3) after primer coat surface being carried out sanded treatment, spraying weatherability finish paint, levelling is also dried, and forms top coat layer.
Step 1) described in weak base defat refer to use pH value be 9~10 alkalescence degreaser carry out defat;Described weak base In property degreaser, the concentration of alkalescence degreasing agent is 55~65g/L.
Alkalescence degreasing agent is dissolved in water and makes by described alkalescence degreaser.
Preferably, described alkalescence degreasing agent is made up of the component of following mass percent: natrium carbonicum calcinatum 5%~12%, nothing Water sodium metasilicate 8%~20%, tetrasodium pyrophosphate 15%~30%, sodium tripolyphosphate 40%~65%, Polyethoxylated fatty Alcohol (also referred to as ethoxylated alcohol) 4%~10%.
The method of described weak base defat comprises the following steps:
After pending hot galvanizing piece is sprayed or soaks 5~10min by the alkalescence degreaser using 60~70 DEG C, use room temperature Water spray or immersion once wash, then the heat water-spraying or immersion with more than 60 DEG C carries out secondary washing.
The described time once washed is 20~60s;The time of described secondary washing is 20~60s.
Step 1) described in surface coarsening process be use to be sprayed of sand papering, after by compressed air, face to be sprayed is blown Only.
Step 2) in, described epoxy micaceous iron intermediate coat is double-component paint.
Step 2) and step 3) in, described levelling is carried out at normal temperatures, and flow time is 10~20min.
Step 2) and step 3) in, described being dried refers to dry or natural drying;The temperature of described drying is 80~100 DEG C, Time is 40~60min.
Step 2) in, the thickness of described prime coat is more than 30 μm.The thickness of described prime coat preferably 30~50 μm.
Step 3) in, the thickness of described top coat layer is more than 20 μm.The thickness of described top coat layer preferably 20~40 μm.
Step 3) described in weatherability finish paint be F-C paint.
Described F-C paint is double-component paint.
The method of the hot galvanizing piece heavy antisepsis for high-voltage electrical equipment of the present invention, uses the method for weak base defat to enter before japanning Row pre-treatment, neither solving zinc film can remove again the greasy dirt on surface the most thoroughly;Use epoxy micaceous iron intermediate coat the end of as Coating, the adhesion between epoxy micaceous iron intermediate coat and zinc layers and finish paint is good, and cloud iron-dope has excellent insulating Can, in its coating, the Yun Tieneng of lamellar effectively plays isolation performance;The method of the hot galvanizing piece heavy antisepsis of the present invention, solves The problem of adhesion difference between ferrous metal parts hot galvanized layer and isolation coating (film) in the most anti-region, technique is simple, Easy to operate, improve qualification rate and the production efficiency of part, reduce repair rate and the production cost of part;Gained is the most anti- Between film and the hot galvanized layer of rotten part, adhesive force is strong, and film difficult drop-off improves antiseptic property, extends it the most anti- The service life in rotten region.
The method of the hot galvanizing piece heavy antisepsis for high-voltage electrical equipment of the present invention, it is adaptable to the 126Kv in heavy antisepsis region is extremely The anticorrosion of the hot galvanizing pieces such as switchgear, chopper and the disconnecting switch of each electric pressure of 1100Kv.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the present invention is further illustrated.
Epoxy micaceous iron intermediate coat used in following detailed description and F-C paint are commercial goods, open up vertical making purchased from Zhengzhou Paint company limited.
Embodiment 1
The method of the hot galvanizing piece heavy antisepsis for high-voltage electrical equipment of the present embodiment, comprises the following steps:
1) take pending hot galvanizing piece, carry out weak base defat, described weak base defat be use pH value be 10, temperature be After pending hot galvanizing piece is soaked 8min by the alkalescence degreaser of 60 DEG C, once wash with the Water spray 60s of room temperature, Secondary washing is carried out again with the hot-water soak 20s of 80 DEG C;After checking that surface does not has greasy dirt, carry out surface coarsening process;Described It is to use to be sprayed of 120# sand papering that surface coarsening processes, and face to be sprayed is blown off by rear clean compressed air;
Wherein, in described alkalescence degreaser, the concentration of alkalescence degreasing agent is 55g/L;Described alkalescence degreasing agent by with The component composition of lower mass percent: natrium carbonicum calcinatum 8%, anhydrous sodium metasilicate 13%, tetrasodium pyrophosphate 22%, trimerization Sodium phosphate 50%, polyethoxylated fatty alcohols 7%.
2) hot galvanizing piece after surface coarsening processes, surface spraying epoxy micaceous iron intermediate coat (double-component), levelling under room temperature are taken After 20min, under conditions of temperature is 100 DEG C, dries 40min, forms the prime coat that thickness is 50 μm;
3) after primer coat surface being carried out sanded treatment with scouring pad, blow off paint powder by compressed air, spray at primer coat surface It is coated with F-C paint (double-component), under room temperature after levelling 10min, under conditions of temperature is 80 DEG C, dries 40min, forms thickness Degree is the top coat layer of 20 μm;
4) post processing: remove veil, repairs the defective film of unnecessary liniment, cleaning polishing painting face and non-painting face The film of intersection, is allowed to rounding off, obtains heavy antisepsis part.
Embodiment 2
The method of the hot galvanizing piece heavy antisepsis for high-voltage electrical equipment of the present embodiment, comprises the following steps:
1) take pending hot galvanizing piece, carry out weak base defat, described weak base defat be use pH value be 9, temperature be 70 DEG C Alkalescence degreaser pending hot galvanizing piece is soaked 5min after, once wash with the water soaking 20s of room temperature, then Secondary washing is carried out with the hot-water soak 40s of 70 DEG C;After checking that surface does not has greasy dirt, carry out surface coarsening process;Described table Face roughening treatment is to use to be sprayed of 120# sand papering, and face to be sprayed is blown off by rear clean compressed air;
Wherein, in described alkalescence degreaser, the concentration of alkalescence degreasing agent is 60g/L;Described alkalescence degreasing agent by with The component composition of lower mass percent: natrium carbonicum calcinatum 5%, anhydrous sodium metasilicate 8%, tetrasodium pyrophosphate 15%, trimerization phosphorus Acid sodium 62%, polyethoxylated fatty alcohols 10%.
2) hot galvanizing piece after surface coarsening processes, surface spraying epoxy micaceous iron intermediate coat (double-component), levelling under room temperature are taken After 10min, under conditions of temperature is 80 DEG C, dries 60min, forms the prime coat that thickness is 30 μm;
3) after primer coat surface being carried out sanded treatment with scouring pad, blow off paint powder by compressed air, spray at primer coat surface It is coated with F-C paint (double-component), under room temperature after levelling 15min, under conditions of temperature is 90 DEG C, dries 40min, forms thickness Degree is the top coat layer of 30 μm;
4) post processing: remove veil, repairs the defective film of unnecessary liniment, cleaning polishing painting face and non-painting face The film of intersection, is allowed to rounding off, obtains heavy antisepsis part.
Embodiment 3
The method of the hot galvanizing piece heavy antisepsis for high-voltage electrical equipment of the present embodiment, comprises the following steps:
1) take pending hot galvanizing piece, carry out weak base defat, described weak base defat be use pH value be 9.5, temperature be After pending hot galvanizing piece is soaked 10min by the alkalescence degreaser of 65 DEG C, carry out a water with the water soaking 40s of room temperature Wash, then carry out secondary washing with the hot-water soak 20s of 60 DEG C;After checking that surface does not has greasy dirt, carry out surface coarsening process; It is to use to be sprayed of 120# sand papering that described surface coarsening processes, and face to be sprayed is blown off by rear clean compressed air;
Wherein, in described alkalescence degreaser, the concentration of alkalescence degreasing agent is 65g/L;Described alkalescence degreasing agent by with The component composition of lower mass percent: natrium carbonicum calcinatum 11%, anhydrous sodium metasilicate 18%, tetrasodium pyrophosphate 27%, trimerization Sodium phosphate 40%, polyethoxylated fatty alcohols 4%.
2) hot galvanizing piece after surface coarsening processes, surface spraying epoxy micaceous iron intermediate coat (double-component), levelling under room temperature are taken After 15min, under conditions of temperature is 90 DEG C, dries 50min, forms the prime coat that thickness is 40 μm;
3) after primer coat surface being carried out sanded treatment with scouring pad, blow off paint powder by compressed air, spray at primer coat surface It is coated with F-C paint (double-component), under room temperature after levelling 20min, under conditions of temperature is 100 DEG C, dries 50min, forms thickness Degree is the top coat layer of 40 μm;
4) post processing: remove veil, repairs the defective film of unnecessary liniment, cleaning polishing painting face and non-painting face The film of intersection, is allowed to rounding off, obtains heavy antisepsis part.
Experimental example
Film adhesive and the production cost of the heavy antisepsis method gained heavy antisepsis part of embodiment 1-3 are detected by this experimental example And evaluation, result is as shown in table 1,2.
Wherein, the hot galvanizing piece heavy antisepsis method of comparative example 1 is to use organic solvent soak degreasing, and its prime coat uses epoxy Priming paint, remaining is with embodiment 1.The hot galvanizing piece heavy antisepsis method of comparative example 2 is to use organic solvent soak degreasing, remaining With embodiment 1.The prime coat of the hot galvanizing piece heavy antisepsis method of comparative example 3 uses epoxy primer, and remaining is with embodiment 1.
The heavy antisepsis method of table 1 embodiment 1-3 and the film adhesive comparative result of comparative example
Heavy antisepsis method Degreasing method Priming paint kind Film adhesive
Embodiment 1 Weak base defat Epoxy micaceous iron intermediate coat 0 grade
Embodiment 2 Weak base defat Epoxy micaceous iron intermediate coat 0 grade
Embodiment 3 Weak base defat Epoxy micaceous iron intermediate coat 0 grade
Comparative example 1 Organic solvent soak degreasing Epoxy primer 1-2 level, local film comes off
Comparative example 2 Organic solvent soak degreasing Epoxy micaceous iron intermediate coat 0 grade, locally poor adhesive force
Comparative example 3 Weak base defat Epoxy primer 1-2 level
As it can be seen from table 1 the painting binding force of membrane of embodiment 1-3 gained heavy antisepsis part is substantially better than comparative example 1-3, reason exists In the hot galvanizing piece heavy antisepsis method of embodiment 1-3, the mode of weak base defat can comprehensively remove the oil of component surface Dirt, improves the quality of oil removing;Epoxy micaceous iron intermediate coat can be obviously improved the adhesive force of coating and hot galvanized layer.And comparative example 1, in 2, organic solvent soak degreasing, the greasy dirt of parts local is used to be difficult to Ex-all, affect the quality of follow-up film;Right In ratio 3, prime coat uses epoxy primer, and it is poor with the adhesion of hot galvanized layer.
The heavy antisepsis method of table 2 embodiment 1-3 and the film cost comparative result of comparative example
Heavy antisepsis method Outward appearance Coating thickness, μm Film cost, unit/m2
Embodiment 1 Flat smooth 70 20
Embodiment 2 Flat smooth 60 20
Embodiment 3 Flat smooth 80 20
Comparative example 1 Flat smooth 70 31
Comparative example 2 Flat smooth 70 26
Comparative example 3 Flat smooth 70 31

Claims (7)

1. the method for the hot galvanizing piece heavy antisepsis of high-voltage electrical equipment, it is characterised in that: comprise the following steps:
1) take pending hot galvanizing piece, carry out weak base defat, surface coarsening process successively;
2) taking the hot galvanizing piece after surface coarsening processes, surface spraying epoxy micaceous iron intermediate coat, levelling is also dried, and forms prime coat;
3) after primer coat surface being carried out sanded treatment, spraying weatherability finish paint, levelling is also dried, and forms top coat layer;
Weak base defat described in step 1) refers to that the alkalescence degreaser using pH value to be 9~10 carries out defat;In described alkalescence degreaser, the concentration of alkalescence degreasing agent is 55~65g/L;
The method of described weak base defat comprises the following steps:
After pending hot galvanizing piece is sprayed or soaks 5~10min by the alkalescence degreaser using 60~70 DEG C, Water spray or immersion with room temperature are once washed, then the heat water-spraying or immersion with more than 60 DEG C carries out secondary washing;
Weatherability finish paint described in step 3) is F-C paint;
Alkalescence degreasing agent is dissolved in water and makes by described alkalescence degreaser;
Described alkalescence degreasing agent is made up of the component of following mass percent: natrium carbonicum calcinatum 5%~12%, anhydrous sodium metasilicate 8%~20%, tetrasodium pyrophosphate 15%~30%, sodium tripolyphosphate 40%~65%, polyethoxylated fatty alcohols 4%~10%.
The method of the hot galvanizing piece heavy antisepsis for high-voltage electrical equipment the most according to claim 1, it is characterised in that: the described time once washed is 20~60s;The time of described secondary washing is 20~60s.
The method of the hot galvanizing piece heavy antisepsis for high-voltage electrical equipment the most according to claim 1, it is characterised in that: surface coarsening described in step 1) process be use to be sprayed of sand papering, after by compressed air, face to be sprayed is blown off.
4. according to the method for the hot galvanizing piece heavy antisepsis for high-voltage electrical equipment described in claim 1, it is characterised in that: step 2) and step 3) in, described levelling is carried out at normal temperatures, and flow time is 10~20min.
5. according to the method for the hot galvanizing piece heavy antisepsis for high-voltage electrical equipment described in claim 1, it is characterised in that: step 2) and step 3) in, described be dried refer to dry or natural drying;The temperature of described drying is 80~100 DEG C, and the time is 40~60min.
The method of the hot galvanizing piece heavy antisepsis for high-voltage electrical equipment the most according to claim 1, it is characterised in that: step 2) described in the thickness of prime coat be 30~50 μm.
The method of the hot galvanizing piece heavy antisepsis for high-voltage electrical equipment the most according to claim 1, it is characterised in that: the thickness of top coat layer described in step 3) is 20~40 μm.
CN201410232882.4A 2014-05-28 2014-05-28 A kind of method of the hot galvanizing piece heavy antisepsis for high-voltage electrical equipment Active CN104289396B (en)

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CN105521930A (en) * 2015-12-08 2016-04-27 中国航空工业集团公司洛阳电光设备研究所 Assembly painting method for improving coating adhesion force
CN106563627A (en) * 2016-10-31 2017-04-19 河南平高电气股份有限公司 Anti-corrosion coating for cathode protection and preparation method of coating
CN111155079A (en) * 2019-12-13 2020-05-15 中国电子科技集团公司第十四研究所 Tempering agent for enhancing adhesion of organic material coated on surface of hot-dip galvanized steel and tempering method thereof
CN116833071A (en) * 2023-06-28 2023-10-03 葫芦岛市圣德信轻型起重设备有限公司 Corrosion prevention method for offshore crane

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