CN104278362B - A kind of preparation method of fire-retardant fibrous material - Google Patents
A kind of preparation method of fire-retardant fibrous material Download PDFInfo
- Publication number
- CN104278362B CN104278362B CN201410556943.2A CN201410556943A CN104278362B CN 104278362 B CN104278362 B CN 104278362B CN 201410556943 A CN201410556943 A CN 201410556943A CN 104278362 B CN104278362 B CN 104278362B
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- Prior art keywords
- fibrous material
- fire
- preparation
- retardant fibrous
- retardant
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 50
- 239000002657 fibrous material Substances 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title claims abstract description 36
- 239000007788 liquid Substances 0.000 claims abstract description 31
- 238000002156 mixing Methods 0.000 claims abstract description 31
- 238000009987 spinning Methods 0.000 claims abstract description 31
- 229920002101 Chitin Polymers 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims abstract description 20
- 239000004814 polyurethane Substances 0.000 claims abstract description 20
- 229920002635 polyurethane Polymers 0.000 claims abstract description 20
- 239000004709 Chlorinated polyethylene Substances 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 229920000090 poly(aryl ether) Polymers 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 11
- 238000001816 cooling Methods 0.000 claims abstract description 10
- 238000007872 degassing Methods 0.000 claims abstract description 10
- 238000002074 melt spinning Methods 0.000 claims abstract description 10
- 238000009998 heat setting Methods 0.000 claims description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- 239000000835 fiber Substances 0.000 description 8
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 7
- 229920002994 synthetic fiber Polymers 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 239000012209 synthetic fiber Substances 0.000 description 3
- 229920006052 Chinlon® Polymers 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 229920004933 Terylene® Polymers 0.000 description 2
- 210000005252 bulbus oculi Anatomy 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
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- Artificial Filaments (AREA)
Abstract
The invention belongs to fibrous material field, disclose the preparation method of a kind of fire-retardant fibrous material, the preparation method step of described fire-retardant fibrous material is as follows: (1) take polyurethanes be 15 28 parts, chitin be 15 22 parts, after polyurethanes and chitin being heated, high-speed mixer carries out melt blending；(2) add in melt blending material chlorinated polyethylene be 6 12 parts, polyarylether resin be 8 14 parts, remain temperature-resistant, then carry out melt blending；(3) melted blend composition is heated as spinning liquid, spinning liquid is de-gassed process, carry out melt spinning, cooling, hot-stretch and thermal finalization after degassing, prepare fire-retardant fibrous material.
Description
Technical field
The invention belongs to fibrous material field, relate to the preparation method of a kind of fibrous material, especially
Relate to the preparation method of a kind of fire-retardant fibrous material.
Background technology
The flame-proof heat-resistant performance of inherent flame retardant synthetic fibers is excellent, and various mechanical performances are outstanding, but
Owing to its synthesis technique is complicated, technical difficulty is big, the reason such as to add production cost high,
The country that can produce these fibers in the world is few, and its application is the most limited.Therefore in resistance
Combustion and high temperature resistant less demanding occasion, widely apply various flame-proof treatment textile and fire-retardant change
Property fiber.
Conventional textile fabric such as cotton, hair, silk, fiber crops and synthetic fibers such as terylene, chinlon, third
Synthetic fibre, viscose glue, eyeball synthetic fibre etc., heat-resistant fireproof poor-performing itself, but chemically modified or
After flame-proof treatment, these fibers can be given with certain fire resistance.Wherein application amount is bigger
Flame-retardant modified synthetic fibers have flame-resistant terylene, fire-retardant chinlon, fire-retardant eyeball synthetic fibre and anti-flaming viscose etc.,
Natural fiber has flame-retardant cotton fiber, flame resistant wool fiber etc..Along with the continuous progress of science and technology,
Various high-performance refractory fibers and flame-retardant finishing continue to bring out, fire-retardant heat resistanceheat resistant protective clothing
Dress is also in sustainable development, and performance increasingly tends to perfect.
Summary of the invention
Solve the technical problem that: fire resistance is extremely important for fibrous material, common fibre
Dimension material does not the most have fire-retardant performance, in some places being likely encountered naked light, has
Certain risk, the fire resistance improving fibrous material is very important, the purpose of the present invention
Just it is to provide the preparation method of a kind of new fire-retardant fibrous material.
Technical scheme: for the problems referred to above, the invention discloses a kind of fire-retardant fibrous material
Preparation method, the preparation method step of described fire-retardant fibrous material is as follows:
(1) take polyurethanes be 15-28 part, chitin be 15-22 part, by poly-ammonia
After carbamate and chitin are heated to 85-95 DEG C, high-speed mixer carries out melt blending；
(2) adding chlorinated polyethylene in melt blending material is that 6-12 part, polyarylether resin are
8-14 part, remains temperature-resistant, then carries out melt blending；
(3) melted blend composition is heated as spinning liquid, spinning liquid is de-gassed process,
Carrying out melt spinning, cooling, hot-stretch and thermal finalization after degassing, spinning liquid temperature is
110-125 DEG C, hot-stretch temperature be 125-135 DEG C, heat setting temperature is 140-155 DEG C, leads
The ratio of stretching is 150%-190%, prepares fire-retardant fibrous material.
The preparation method of described a kind of fire-retardant fibrous material, preparation method step is the most excellent
Select as follows:
(1) take polyurethanes be 18-24 part, chitin be 17-20 part, by poly-ammonia
After carbamate and chitin are heated to 85-95 DEG C, high-speed mixer carries out melt blending；
(2) adding chlorinated polyethylene in melt blending material is that 7-10 part, polyarylether resin are
9-13 part, remains temperature-resistant, then carries out melt blending；
(3) melted blend composition is heated as spinning liquid, spinning liquid is de-gassed process,
Carrying out melt spinning, cooling, hot-stretch and thermal finalization after degassing, spinning liquid temperature is
110-125 DEG C, hot-stretch temperature be 125-135 DEG C, heat setting temperature is 140-155 DEG C, leads
The ratio of stretching is 150%-190%, prepares fire-retardant fibrous material.
In the preparation method of described a kind of fire-retardant fibrous material, polyurethanes is 21
Part.
In the preparation method of described a kind of fire-retardant fibrous material, chitin is 18 parts.
In the preparation method of described a kind of fire-retardant fibrous material, chlorinated polyethylene is 9 parts.
In the preparation method of described a kind of fire-retardant fibrous material, polyarylether resin is 11 parts.
In the preparation method of described a kind of fire-retardant fibrous material spinning liquid temperature be 115 DEG C,
Hot-stretch temperature is 130 DEG C, and heat setting temperature is 150 DEG C, and drawing-off ratio is 170%.
Beneficial effect: polyurethanes and the chitin with certain fire resistance are mixed
Close, additionally added chlorinated polyethylene and polyarylether resin, the resistance of the fibrous material after blending
Combustion performance is greatly enhanced, and the Prospect for Flame Retardant Fiber Materials of the present invention all has higher oxygen index (OI),
When polyurethanes be 21 parts, chitin be 18 parts, chlorinated polyethylene be 9 parts, poly-virtue
When ether resin is 11 parts, the oxygen index (OI) of the fibrous material of preparation is the highest.
Detailed description of the invention
Embodiment 1
(1) take polyurethanes be 28Kg, chitin be 15Kg, by polyurethanes
After being heated to 95 DEG C with chitin, high-speed mixer carries out melt blending；
(2) in melt blending material add chlorinated polyethylene be 12Kg, polyarylether resin be
8Kg, remains temperature-resistant, then carries out melt blending；
(3) melted blend composition is heated as spinning liquid, spinning liquid is de-gassed process,
Melt spinning, cooling, hot-stretch and thermal finalization is carried out after degassing, spinning liquid temperature is 110 DEG C,
Hot-stretch temperature is 135 DEG C, and heat setting temperature is 155 DEG C, and drawing-off ratio is 190%, preparation
Obtain fire-retardant fibrous material.
Embodiment 2
(1) take polyurethanes be 15Kg, chitin be 22Kg, by polyurethanes
After being heated to 85 DEG C with chitin, high-speed mixer carries out melt blending；
(2) in melt blending material add chlorinated polyethylene be 6Kg, polyarylether resin be
14Kg, remains temperature-resistant, then carries out melt blending；
(3) melted blend composition is heated as spinning liquid, spinning liquid is de-gassed process,
Melt spinning, cooling, hot-stretch and thermal finalization is carried out after degassing, spinning liquid temperature is 125 DEG C,
Hot-stretch temperature is 125 DEG C, and heat setting temperature is 140 DEG C, and drawing-off ratio is 150%, preparation
Obtain fire-retardant fibrous material.
Embodiment 3
(1) take polyurethanes be 24Kg, chitin be 17Kg, by polyurethanes
After being heated to 85-95 DEG C with chitin, high-speed mixer carries out melt blending；
(2) in melt blending material add chlorinated polyethylene be 7Kg, polyarylether resin be
13Kg, remains temperature-resistant, then carries out melt blending；
(3) melted blend composition is heated as spinning liquid, spinning liquid is de-gassed process,
Melt spinning, cooling, hot-stretch and thermal finalization is carried out after degassing, spinning liquid temperature is 115 DEG C,
Hot-stretch temperature is 135 DEG C, and heat setting temperature is 145 DEG C, and drawing-off ratio is 180%, preparation
Obtain fire-retardant fibrous material.
Embodiment 4
(1) take polyurethanes be 18Kg, chitin be 20Kg, by polyurethanes
After being heated to 85-95 DEG C with chitin, high-speed mixer carries out melt blending；
(2) in melt blending material add chlorinated polyethylene be 10Kg, polyarylether resin be
9Kg, remains temperature-resistant, then carries out melt blending；
(3) melted blend composition is heated as spinning liquid, spinning liquid is de-gassed process,
Melt spinning, cooling, hot-stretch and thermal finalization is carried out after degassing, spinning liquid temperature is 125 DEG C,
Hot-stretch temperature is 135 DEG C, and heat setting temperature is 140 DEG C, and drawing-off ratio is 160%, preparation
Obtain fire-retardant fibrous material.
Embodiment 5
(1) take polyurethanes be 21Kg, chitin be 18Kg, by polyurethanes
After being heated to 95 DEG C with chitin, high-speed mixer carries out melt blending；
(2) in melt blending material add chlorinated polyethylene be 9Kg, polyarylether resin be
11Kg, remains temperature-resistant, then carries out melt blending；
(3) melted blend composition is heated as spinning liquid, spinning liquid is de-gassed process,
Melt spinning, cooling, hot-stretch and thermal finalization is carried out after degassing, spinning liquid temperature is 115 DEG C,
Hot-stretch temperature is 130 DEG C, and heat setting temperature is 150 DEG C, and drawing-off ratio is 170%, preparation
Obtain fire-retardant fibrous material.
The oxygen index (OI) of the Prospect for Flame Retardant Fiber Materials of embodiment 1 to 5 is as follows:
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Oxygen index (OI) | 25 | 27 | 33 | 32 | 39 |
The Prospect for Flame Retardant Fiber Materials prepared all has higher oxygen index.
Claims (7)
1. the preparation method of a fire-retardant fibrous material, it is characterised in that described is fire-retardant
The preparation method step of fibrous material as follows:
(1) take polyurethanes be 15-28 part, chitin be 15-22 part, by poly-ammonia
After carbamate and chitin are heated to 85-95 DEG C, high-speed mixer carries out melt blending；
(2) adding chlorinated polyethylene in melt blending material is that 6-12 part, polyarylether resin are
8-14 part, remains temperature-resistant, then carries out melt blending；
(3) melted blend composition is heated as spinning liquid, spinning liquid is de-gassed process,
Carrying out melt spinning, cooling, hot-stretch and thermal finalization after degassing, spinning liquid temperature is
110-125 DEG C, hot-stretch temperature be 125-135 DEG C, heat setting temperature is 140-155 DEG C, leads
The ratio of stretching is 150%-190%, prepares fire-retardant fibrous material.
The preparation method of a kind of fire-retardant fibrous material the most according to claim 1, its
Being characterised by, the preparation method step of described fire-retardant fibrous material is as follows:
(1) take polyurethanes be 18-24 part, chitin be 17-20 part, by poly-ammonia
After carbamate and chitin are heated to 85-95 DEG C, high-speed mixer carries out melt blending；
(2) adding chlorinated polyethylene in melt blending material is that 7-10 part, polyarylether resin are
9-13 part, remains temperature-resistant, then carries out melt blending；
(3) melted blend composition is heated as spinning liquid, spinning liquid is de-gassed process,
Carrying out melt spinning, cooling, hot-stretch and thermal finalization after degassing, spinning liquid temperature is
110-125 DEG C, hot-stretch temperature be 125-135 DEG C, heat setting temperature is 140-155 DEG C, leads
The ratio of stretching is 150%-190%, prepares fire-retardant fibrous material.
The preparation method of a kind of fire-retardant fibrous material the most according to claim 1, its
Being characterised by, in the preparation method of described fire-retardant fibrous material, polyurethanes is 21
Part.
The preparation method of a kind of fire-retardant fibrous material the most according to claim 1, its
Being characterised by, in the preparation method of described fire-retardant fibrous material, chitin is 18 parts.
The preparation method of a kind of fire-retardant fibrous material the most according to claim 1, its
Being characterised by, in the preparation method of described fire-retardant fibrous material, chlorinated polyethylene is 9 parts.
The preparation method of a kind of fire-retardant fibrous material the most according to claim 1, its
Being characterised by, in the preparation method of described fire-retardant fibrous material, polyarylether resin is 11 parts.
The preparation method of a kind of fire-retardant fibrous material the most according to claim 1, its
Be characterised by, in the preparation method of described fire-retardant fibrous material spinning liquid temperature be 115 DEG C,
Hot-stretch temperature is 130 DEG C, and heat setting temperature is 150 DEG C, and drawing-off ratio is 170%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410556943.2A CN104278362B (en) | 2014-10-20 | 2014-10-20 | A kind of preparation method of fire-retardant fibrous material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410556943.2A CN104278362B (en) | 2014-10-20 | 2014-10-20 | A kind of preparation method of fire-retardant fibrous material |
Publications (2)
| Publication Number | Publication Date |
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| CN104278362A CN104278362A (en) | 2015-01-14 |
| CN104278362B true CN104278362B (en) | 2016-10-19 |
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Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3970716A (en) * | 1974-06-05 | 1976-07-20 | Uniroyal, Inc. | Flame resistant thermoplastic blend |
| JPS5982410A (en) * | 1982-11-01 | 1984-05-12 | Kanebo Ltd | Flame-proofing acrylic composite fiber having latent crimpability |
| KR101070649B1 (en) * | 2009-07-07 | 2011-10-07 | 정진태 | Making method of the nonflamable fabric having the flexibility |
| CN103789862A (en) * | 2012-11-01 | 2014-05-14 | 苏州宝力塑胶材料有限公司 | Production method of flame retardant fibers |
| CN103497424A (en) * | 2013-10-01 | 2014-01-08 | 青岛三立新源电器有限公司 | Novel heat resisting macromolecule plastics formula |
| CN103739817A (en) * | 2013-12-27 | 2014-04-23 | 广西吉顺能源科技有限公司 | Polyurethane flame-retardant material and preparation method thereof |
| CN103923454A (en) * | 2014-04-18 | 2014-07-16 | 昆山金有利新材料科技有限公司 | Chitin film and preparation method thereof |
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2014
- 2014-10-20 CN CN201410556943.2A patent/CN104278362B/en not_active Expired - Fee Related
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Inventor after: Li Ruiping Inventor after: Zhou Xiaoqian Inventor before: Gu Zian |
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Effective date of registration: 20160905 Address after: Two, Guangdong Province, Longgang District, Shenzhen District, Buji street, Luo Gang Road, No. 16, B building, No. 518112, building 202 Applicant after: Shenzhen Jixiang Shijia Technology Co.,Ltd. Address before: 313014 Zhejiang Province, Huzhou city Nanxun District Xu Shuiqiao Shicong town Applicant before: HUZHOU LINGHU SHICONG YONGSHENG SILK WEAVING FACTORY |
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Effective date of registration: 20201224 Address after: 338034 photovoltaic market of new material industrial park in Xinyu hi tech Development Zone, Jiangxi Province Patentee after: Jiangxi kaisilong Garment Co.,Ltd. Address before: 518112 202, 2nd floor, building B, No.16, Luogang Jingnan Road, Buji street, Longgang District, Shenzhen City, Guangdong Province Patentee before: Shenzhen Jixiang Shijia Technology Co.,Ltd. |
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