CN104262854A - Antibacterial polyvinyl chloride sole material and preparation method thereof - Google Patents
Antibacterial polyvinyl chloride sole material and preparation method thereof Download PDFInfo
- Publication number
- CN104262854A CN104262854A CN201410566279.XA CN201410566279A CN104262854A CN 104262854 A CN104262854 A CN 104262854A CN 201410566279 A CN201410566279 A CN 201410566279A CN 104262854 A CN104262854 A CN 104262854A
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- China
- Prior art keywords
- polyvinyl chloride
- sole
- antibacterial polyvinyl
- shoe
- nano
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides an antibacterial polyvinyl chloride sole material which comprises the following components in parts by weight: 45-60 parts of polyvinyl chloride, 8-20 parts of nano silver powder, 3-5 parts of coupling agent, 0.5-2 parts of antioxidant, 18-30 parts of plasticizer, 3-5 parts of calcium stearate, 2-4 parts of CPE (Chlorinated Polyethylene) and 3-10 parts of diatomite. The invention also discloses a preparation method of the antibacterial polyvinyl chloride sole material. The antibacterial polyvinyl chloride sole material provided by the invention has better antibacterial performance.
Description
Technical field:
The present invention relates to a kind of material for sole of shoe, particularly relate to a kind of antibacterial polyvinyl chloride material for sole of shoe and manufacture method thereof.
Background technology:
Along with the raising of people's living standard, people require also more and more higher to each side of footwear.People are after walking and motion, pin can be perspired, pin sweat is difficult in shoe lining face effectively be got rid of, time can produce peculiar smell in shoe lining face breed bacteria after having grown, bring inconvenience, so people to the requirement of footwear except fitting, light, comfortable except, also have higher requirement to the anti-microbial property of footwear.Current material for sole of shoe is on the market mostly synthetic rubber, the wherein large percentage of polyvinyl chloride material for sole of shoe, and price is lower, better performances, but does not possess good anti-microbial property, can not meet antibacterial requirement.
Summary of the invention:
The technical problem to be solved in the present invention is to provide a kind of antibacterial polyvinyl chloride material for sole of shoe, possesses good anti-microbial property.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A kind of antibacterial polyvinyl chloride material for sole of shoe, its weight part consists of:
Preferably, coupling agent of the present invention is silane coupling agent.
Preferably, oxidation inhibitor of the present invention is antioxidant 1010.
Preferably, softening agent of the present invention is one or more in dioctyl phthalate (DOP), dibutyl phthalate, dioctyl sebacate, tritolyl phosphate, triphenylphosphate.
Another technical problem that the present invention will solve is to provide the manufacture method of above-mentioned antibacterial polyvinyl chloride material for sole of shoe.
For solving the problems of the technologies described above, technical scheme is:
A manufacture method for antibacterial polyvinyl chloride material for sole of shoe, comprises the following steps:
(1) take raw material by formula, fully stir after nano-silver powder being added coupling agent, dry after suction filtration, obtain nano-mixture;
(2) nano-mixture obtained in other raw materials in formula and step (1) is added in high mixer mixing, obtain blend;
(3) blend that step (2) obtains is added extruding pelletization in twin screw extruder, obtain antibacterial polyvinyl chloride material for sole of shoe.
Therefore compared with prior art, the present invention has following beneficial effect:
The specific surface area effect of nano-silver powder is larger, it can be adsorbed on bacterium surface and enter in bacterial body when bacterium under the effect of attractive coulombic force, hinder the eubolism of bacterium and normal breeding, cause bacterial death, thus playing extraordinary anti-microbial effect, therefore the material for sole of shoe adding nano-silver powder has also possessed good anti-microbial property; During manufacture, coupling agent can improve its dispersity to the surface modification of nano-silver powder, and and polyvinyl chloride between bond strength, improve further the anti-microbial property of material for sole of shoe; Nano-silver powder activity is comparatively large, the oxygen generation oxidizing reaction easily and in air, and adding of oxidation inhibitor effectively can stop previous reaction, extends the Durability of antimicrobial effect of nano-silver powder.
Embodiment:
Describe the present invention in detail below in conjunction with specific embodiment, be used for explaining the present invention in this illustrative examples of the present invention and explanation, but not as a limitation of the invention.
Embodiment 1
A kind of antibacterial polyvinyl chloride material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) take raw material by formula, fully stir after nano-silver powder being added coupling agent, dry after suction filtration, obtain nano-mixture;
(2) nano-mixture obtained in other raw materials in formula and step (1) is added in high mixer mixing, obtain blend;
(3) blend that step (2) obtains is added extruding pelletization in twin screw extruder, obtain antibacterial polyvinyl chloride material for sole of shoe.
Embodiment 2
A kind of antibacterial polyvinyl chloride material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) take raw material by formula, fully stir after nano-silver powder being added coupling agent, dry after suction filtration, obtain nano-mixture;
(2) nano-mixture obtained in other raw materials in formula and step (1) is added in high mixer mixing, obtain blend;
(3) blend that step (2) obtains is added extruding pelletization in twin screw extruder, obtain antibacterial polyvinyl chloride material for sole of shoe.
Embodiment 3
A kind of antibacterial polyvinyl chloride material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) take raw material by formula, fully stir after nano-silver powder being added coupling agent, dry after suction filtration, obtain nano-mixture;
(2) nano-mixture obtained in other raw materials in formula and step (1) is added in high mixer mixing, obtain blend;
(3) blend that step (2) obtains is added extruding pelletization in twin screw extruder, obtain antibacterial polyvinyl chloride material for sole of shoe.
Embodiment 4
A kind of antibacterial polyvinyl chloride material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) take raw material by formula, fully stir after nano-silver powder being added coupling agent, dry after suction filtration, obtain nano-mixture;
(2) nano-mixture obtained in other raw materials in formula and step (1) is added in high mixer mixing, obtain blend;
(3) blend that step (2) obtains is added extruding pelletization in twin screw extruder, obtain antibacterial polyvinyl chloride material for sole of shoe.
Embodiment 5
A kind of antibacterial polyvinyl chloride material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) take raw material by formula, fully stir after nano-silver powder being added coupling agent, dry after suction filtration, obtain nano-mixture;
(2) nano-mixture obtained in other raw materials in formula and step (1) is added in high mixer mixing, obtain blend;
(3) blend that step (2) obtains is added extruding pelletization in twin screw extruder, obtain antibacterial polyvinyl chloride material for sole of shoe.
Embodiment 6
A kind of antibacterial polyvinyl chloride material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) take raw material by formula, fully stir after nano-silver powder being added coupling agent, dry after suction filtration, obtain nano-mixture;
(2) nano-mixture obtained in other raw materials in formula and step (1) is added in high mixer mixing, obtain blend;
(3) blend that step (2) obtains is added extruding pelletization in twin screw extruder, obtain antibacterial polyvinyl chloride material for sole of shoe.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention.Any person skilled in the art scholar all without prejudice under spirit of the present invention and category, can modify above-described embodiment or changes.Therefore, such as have in art usually know the knowledgeable do not depart from complete under disclosed spirit and technological thought all equivalence modify or change, must be contained by claim of the present invention.
Claims (5)
1. an antibacterial polyvinyl chloride material for sole of shoe, is characterized in that: its weight part consists of:
2. a kind of antibacterial polyvinyl chloride material for sole of shoe according to claim 1, is characterized in that: described coupling agent is silane coupling agent.
3. a kind of antibacterial polyvinyl chloride material for sole of shoe according to claim 1, is characterized in that: described oxidation inhibitor is antioxidant 1010.
4. a kind of antibacterial polyvinyl chloride material for sole of shoe according to claim 1, is characterized in that: described softening agent is one or more in dioctyl phthalate (DOP), dibutyl phthalate, triphenylphosphate.
5. the manufacture method of a kind of antibacterial polyvinyl chloride material for sole of shoe according to Claims 1 to 4 any one, is characterized in that: comprise the following steps:
(1) take raw material by formula, fully stir after nano-silver powder being added coupling agent, dry after suction filtration, obtain nano-mixture;
(2) nano-mixture obtained in other raw materials in formula and step (1) is added in high mixer mixing, obtain blend;
(3) blend that step (2) obtains is added extruding pelletization in twin screw extruder, obtain antibacterial polyvinyl chloride material for sole of shoe.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410566279.XA CN104262854A (en) | 2014-10-22 | 2014-10-22 | Antibacterial polyvinyl chloride sole material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410566279.XA CN104262854A (en) | 2014-10-22 | 2014-10-22 | Antibacterial polyvinyl chloride sole material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104262854A true CN104262854A (en) | 2015-01-07 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410566279.XA Pending CN104262854A (en) | 2014-10-22 | 2014-10-22 | Antibacterial polyvinyl chloride sole material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104262854A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104761844A (en) * | 2015-03-19 | 2015-07-08 | 苏州市景荣科技有限公司 | Novel antibacterial and deodorant PVC shoe material and preparation method thereof |
| CN105400104A (en) * | 2015-12-22 | 2016-03-16 | 河南谢人安防门帘有限公司 | Antibacterial plastic and antibacterial plastic curtain, and preparation method thereof |
| CN105602006A (en) * | 2016-01-21 | 2016-05-25 | 苏州市景荣科技有限公司 | Antibacterial masterbatch for shoe materials and preparation method of antibacterial masterbatch |
| CN106964214A (en) * | 2017-04-27 | 2017-07-21 | 舒尔环保科技（合肥）有限公司 | A kind of air cleaning antibacterial basket strainer and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102516627A (en) * | 2011-12-03 | 2012-06-27 | 广东聚缘塑料科技有限公司 | Silver-ion antibacterial plastic |
| CN103408861A (en) * | 2013-07-18 | 2013-11-27 | 苏州富通高新材料科技股份有限公司 | Plastic floor substrate and making method thereof |
| CN103590247A (en) * | 2013-10-15 | 2014-02-19 | 苏州市景荣科技有限公司 | Antibacterial odor-resistant insole shoe material |
| CN103589087A (en) * | 2013-10-15 | 2014-02-19 | 苏州市景荣科技有限公司 | Antibacterial odor-resistant PVC (Polyvinyl Chloride) sole material |
-
2014
- 2014-10-22 CN CN201410566279.XA patent/CN104262854A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102516627A (en) * | 2011-12-03 | 2012-06-27 | 广东聚缘塑料科技有限公司 | Silver-ion antibacterial plastic |
| CN103408861A (en) * | 2013-07-18 | 2013-11-27 | 苏州富通高新材料科技股份有限公司 | Plastic floor substrate and making method thereof |
| CN103590247A (en) * | 2013-10-15 | 2014-02-19 | 苏州市景荣科技有限公司 | Antibacterial odor-resistant insole shoe material |
| CN103589087A (en) * | 2013-10-15 | 2014-02-19 | 苏州市景荣科技有限公司 | Antibacterial odor-resistant PVC (Polyvinyl Chloride) sole material |
Non-Patent Citations (1)
| Title |
|---|
| 汪多仁等: "《电子化学品清洁生产工艺》", 31 March 2005 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104761844A (en) * | 2015-03-19 | 2015-07-08 | 苏州市景荣科技有限公司 | Novel antibacterial and deodorant PVC shoe material and preparation method thereof |
| CN105400104A (en) * | 2015-12-22 | 2016-03-16 | 河南谢人安防门帘有限公司 | Antibacterial plastic and antibacterial plastic curtain, and preparation method thereof |
| CN105400104B (en) * | 2015-12-22 | 2018-01-09 | 河南谢人安防门帘有限公司 | A kind of antibiotic plastic, antibiotic plastic door curtain, preparation method |
| CN105602006A (en) * | 2016-01-21 | 2016-05-25 | 苏州市景荣科技有限公司 | Antibacterial masterbatch for shoe materials and preparation method of antibacterial masterbatch |
| CN106964214A (en) * | 2017-04-27 | 2017-07-21 | 舒尔环保科技（合肥）有限公司 | A kind of air cleaning antibacterial basket strainer and preparation method thereof |
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| PB01 | Publication | ||
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Application publication date: 20150107 |