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CN104264011B - A kind of aluminium wire - Google Patents

A kind of aluminium wire Download PDF

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Publication number
CN104264011B
CN104264011B CN201410520237.2A CN201410520237A CN104264011B CN 104264011 B CN104264011 B CN 104264011B CN 201410520237 A CN201410520237 A CN 201410520237A CN 104264011 B CN104264011 B CN 104264011B
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Prior art keywords
aluminium wire
aluminium
years
impurity
corrosion
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CN104264011A (en
Inventor
孟洪昌
李川
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SHIJIAZHUANG XINRI ZINC INDUSTRY Co Ltd
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SHIJIAZHUANG XINRI ZINC INDUSTRY Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Conductive Materials (AREA)

Abstract

A kind of aluminium wire, the chemical composition of described aluminium wire constitutes and is:Al:>=99.5%, Si:0.1 0.25%, Fe:0.2 0.35%, Cu:≤ 0.015%, remaining is impurity, and impurity is integrally less than or equal to 0.05%, and all elements total amount in addition to aluminium must not exceed 0.5%.In the state of ensureing that aluminium wire other performances are still good, the corrosion resistance and service life of aluminium are improve by adding the trace element such as silicon, iron, copper;Improve the performance of aluminium, obtained aluminium wire is set to be greatly improved compared to existing aluminium wire antiseptic power in wet environment, in the environment that humidity is 70%, prior art anti-corrosion life was at 4 years or so, the present invention can reach more than 8 years, in water environment, at 3 years or so, the present invention can reach more than 6 years prior art anti-corrosion life.

Description

A kind of aluminium wire
Technical field
The invention belongs to the technical field of aluminium wire, and in particular to a kind of for steamer, marine equipment, the equipment on bank, with And the anti-corrosion aluminium wire in area of often raining.
Background technology
Used as the most frequently used metal, the surface of aluminium forms thick about 50 angstroms dense oxidation film to aluminium immediately in dry air, Aluminium is not further aoxidized and energy is water-fast.But in the relatively large place of humidity, aluminium is easy to be corroded, and service life is significantly Reduce.
Publication date is 2010.08.11, a kind of rust-proof diecasting aluminum-silicon alloy of Publication No. CN 101798648A, wherein Disclosing chemical composition is:Si:9%-12%;Mg:0.3%-0.7%;Sn:≤ 0.01%;Cu:≤ 0.08%;Fe:≤ 1.0%;Zn:≤ 0.20%;Mn:0.3-0.6%;Ni:≤ 0.2%;Balance of Al.Alusil alloy obtained in the patent document exists Aluminium silicon class alloy range of application in the presence of a harsh environment is improved to a certain extent, but its corrosion resistance is still very poor, its Mainly it is applied under high load capacity endurance, service life is still very short.And, wherein the content of addition silicon metal is higher, and The fusing point of silicon metal is high, and silicon and calorize close incomplete in fusion process, thus, low production efficiency, silicon content are unbalanced, sial Chemical combination not exclusively, waste time and energy.
The content of the invention
The present invention is to solve the aluminium wire technology that antiseptic power is poor in the environment of high humidity, service life is short in the prior art Problem, there is provided a kind of raising antiseptic power and the aluminium wire in life-span.
The present invention is to realize that the technical scheme that its purpose is used is:
A kind of aluminium wire, the chemical composition of described aluminium wire constitutes and is:Based on quality percentage, Al:>=99.5%, Si: 0.1-0.25%, Fe:0.2-0.35%, Cu:≤ 0.015%, remaining is impurity, and impurity is integrally less than or equal to 0.05%, except aluminium All elements total amount in addition must not exceed 0.5%.
The chemical composition of described aluminium wire is constituted:Based on quality percentage, Al:99.5-99.6%, Si:0.1- 0.25%, Fe:0.2-0.35%, Cu:0.01-0.015%, remaining is impurity, and impurity is integrally less than or equal to 0.05%, except aluminium with Outer all elements total amount must not exceed 0.5%.
The chemical composition of described aluminium wire is constituted:Based on quality percentage, Al:99.5%, Si:0.1375%, Fe: 0.35%, Cu:0.01%, impurity:0.0025%.
The chemical composition of described aluminium wire is constituted:Based on quality percentage, Al:99.525%, Si:0.1375%, Fe: 0.3125%, Cu:0.01125%, impurity:0.01375%.
The chemical composition of described aluminium wire is constituted:Based on quality percentage, Al:99.575%, Si:0.175%, Fe: 0.2375%, Cu:0.0125%.
The chemical composition of described aluminium wire is constituted:Based on quality percentage, Al:99.6%, Si:0.1%, Fe: 0.275%, Cu:0.015%, impurity:0.01%.
The ratio between the quality percentage of described iron and the quality percentage of silicon are more than 1.
The beneficial effects of the invention are as follows:A kind of aluminium wire, in the state of ensureing that aluminium wire other performances are still good, by adding Plus the trace element such as silicon, iron, copper improves the corrosion resistance and service life of aluminium;The performance of aluminium is improved, makes obtained aluminium Silk is greatly improved in wet environment compared to existing aluminium wire antiseptic power, and in the environment that humidity is 70%, prior art is prevented The rotten life-span, the present invention can reach more than 8 years at 4 years or so, and in water environment, prior art anti-corrosion life was 3 years or so, this hair It is bright to reach more than 6 years.In the present invention, the ratio of each chemical constituent is just determined by long-term research and strict experiment Its feasibility, the ratio of each chemical constituent not only affects performance, antiseptic power and the service life of final aluminium wire, and The ratio of each chemical constituent female shank diameter of chemical combination, content equilibrium degree and last aluminium wire, fineness in fusion process have Influence, is the aluminium wire for obtaining using the anti-corrosion time limit higher, there is provided indispensable guarantee.
The intensity of alloy is improve by adding iron, silicon, copper, smelt surface tension is reduced, fluidity of molten is increased, Improve the proof stress of alloy, corrosion to split, improve mechanical property and the plastic working of alloy.It is solid by adding copper to enhance Molten reinforcing effect;Add silicon to improve the castability and corrosion stability of alloy, with copper, iron molten condition under counteract impurity to alloy The adverse effect of corrosion stability, it is ensured that alloy is not cracked, reduces alloy fragility;And the addition of iron, carried with copper, silicon collective effect Alloy raw material homogenization degree high, reduces homogenization time, and the tensile strength that improve alloy is, the surface for improving alloy Roughness, improves the mechanical property of alloy.
Ensure that the ratio between the quality percentage of iron and the quality percentage of silicon are more than 1 so that the aluminium wire of production is in tensile strength While reinforcement, corrosion resistance enhancing extends the anti-corrosion time limit.
Specific embodiment
The present invention is to solve the aluminium wire technology that antiseptic power is poor in the environment of high humidity, service life is short in the prior art Problem, there is provided a kind of raising antiseptic power and the aluminium wire in life-span.The present invention is made furtherly with reference to specific embodiment It is bright.
A kind of aluminium wire of embodiment 1., the chemical composition of described aluminium wire constitutes and is:Al:99.5%, Si:0.1375%, Fe: 0.35%, Cu:0.01%, impurity:0.0025%.
A kind of aluminium wire of embodiment 2., the chemical composition of described aluminium wire constitutes and is:Al:99.525%, Si:0.1375%, Fe:0.3125%, Cu:0.01125%, impurity:0.01375%.
A kind of aluminium wire of embodiment 3., the chemical composition of described aluminium wire constitutes and is:Al:99.575%, Si:0.175%, Fe:0.2375%, Cu:0.0125%.
A kind of aluminium wire of embodiment 4., the chemical composition of described aluminium wire constitutes and is:Al:99.6%, Si:0.1%, Fe: 0.275%, Cu:0.015%, impurity:0.01%.
The process that the present invention prepares aluminium wire is:
First, Al997 trade mark aluminium ingots are selected;Then the above-mentioned aluminium ingot fusing that will be obtained, then it is separately added into silicon, iron, copper;So It is stirred with magnetic stirrer afterwards, continuous casting and rolling, when female shank diameter that aluminium wire is formed is 9.5mm, coils and receive silk, finally uses water Case is hot candied, respectively obtains aluminium wire in embodiment, and the aluminium wire of 2.0-3.0mm can be pulled out according to different demands.
The minimum 100MPa of aluminium wire compression strength of the invention, aluminium wire surface cleaning, smooth, impulse- free robustness, without pit, without drawing Trace, flawless, non-oxidation layer, without impression, without layering, without defects such as doublings.
By salt spray test, the anti-corrosion time limit of aluminium wire see the table below 1 in the environment of different humidity:
Table 1:
The present invention see the table below 2 with the tensile strength of prior art aluminium wire:
Table 2:
Aluminium wire of the invention, it is micro- by adding silicon, iron, copper etc. in the state of ensureing that aluminium wire other performances are still good Secondary element improves the corrosion resistance and service life of aluminium;The performance of aluminium is improved, makes obtained aluminium wire in wet environment Greatly improved compared to existing aluminium wire antiseptic power, in the environment that humidity is 70%, prior art anti-corrosion life was on 4 years left sides The right side, the present invention can reach more than 8 years, in water environment, prior art anti-corrosion life at 3 years or so, the present invention can reach 6 years with On.Environment of the aluminium wire of the invention for different humidity can clearly be found out by table 1 very much, antiseptic power and service life are all It is significantly improved.And, embodiment 4 is most preferred embodiment, its anti-corrosion time limit be 2 times of the prior art aluminium wire anti-corrosion time limit with On.It can be seen from Table 2 that aluminium wire of the invention, tensile strength is substantially better than the aluminium wire of prior art.

Claims (2)

1. a kind of aluminium wire, it is characterised in that:The chemical composition of described aluminium wire is constituted:Based on quality percentage, by quality hundred Divide rate meter, Al:99.6%, Si:0.1%, Fe:0.275%, Cu:0.015%, impurity:0.01%.
2. a kind of aluminium wire according to claim 1, it is characterised in that:The quality percentage of described iron and the quality hundred of silicon The ratio between rate is divided to be more than 1.
CN201410520237.2A 2014-09-30 2014-09-30 A kind of aluminium wire Active CN104264011B (en)

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Application Number Priority Date Filing Date Title
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CN104264011A CN104264011A (en) 2015-01-07
CN104264011B true CN104264011B (en) 2017-06-20

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE112017005496T5 (en) * 2016-10-31 2019-09-12 Autonetworks Technologies, Ltd. Aluminum alloy cable, aluminum alloy power cable, covered electric cable and electric cord equipped with a terminal

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102682872A (en) * 2011-03-18 2012-09-19 上海电缆研究所 Semihard aluminum wire, overhead wire and preparation method of semihard aluminum wire
CN103572131A (en) * 2013-10-28 2014-02-12 任静儿 Aluminum alloy composite material for cooler of air conditioner

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3177079B2 (en) * 1993-10-29 2001-06-18 富士写真フイルム株式会社 Method for producing a lithographic printing plate support
EP1543899A3 (en) * 2003-12-17 2005-12-21 Fuji Photo Film B.V. Aluminium alloy substrate for digitally imageable lithographic printing plate and process for producing the same

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102682872A (en) * 2011-03-18 2012-09-19 上海电缆研究所 Semihard aluminum wire, overhead wire and preparation method of semihard aluminum wire
CN103572131A (en) * 2013-10-28 2014-02-12 任静儿 Aluminum alloy composite material for cooler of air conditioner

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