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CN104212427B - Method for preventing corrosion of sand control pump tail pipe used for sand production well - Google Patents

Method for preventing corrosion of sand control pump tail pipe used for sand production well Download PDF

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Publication number
CN104212427B
CN104212427B CN201310220181.4A CN201310220181A CN104212427B CN 104212427 B CN104212427 B CN 104212427B CN 201310220181 A CN201310220181 A CN 201310220181A CN 104212427 B CN104212427 B CN 104212427B
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sand
tail pipe
imidazoline
corrosion
plug
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CN104212427A (en
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付亚荣
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Petrochina Co Ltd
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Petrochina Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/54Compositions for in situ inhibition of corrosion in boreholes or wells
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B41/00Equipment or details not covered by groups E21B15/00 - E21B40/00
    • E21B41/02Equipment or details not covered by groups E21B15/00 - E21B40/00 in situ inhibition of corrosion in boreholes or wells

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Chemical & Material Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Lubricants (AREA)

Abstract

The invention relates to a method for preventing the corrosion of a sand control pump tail pipe used in a sand production well, which comprises the following steps of mixing 12.5-13.0% by weight of imidazoline quaternary ammonium salt IS-130; 7.5 to 8.5 percent of 2-alkyl-1- (N-polyoxyethylene-2-aminoethyl) imidazoline-1-benzyl ammonium chloride fatty acid salt; 15.8 to 16.5 percent of naphthenic acid imidazoline glacial acetate; 10.2 to 11.0 percent of naphthenic acid radical 1- (2-ethoxyl) imidazoline quaternary ammonium salt; benzyl chloride alpha-naphthylmethyl quinoline ammonium condensate, 3.5-5.0%; 4.0 to 4.5 percent of N-aminoethyl dodecyl imidazoline thioether; propiolic alcohol, 1.5-2.0 percent, and the rest of the corrosion inhibitor of the methanol are put into a tail pipe of the sand control pump; after the corrosion inhibitor is added into the tail pipe of the sand control pump used in a sand production well, the corrosion of the tail pipe is not found after more than 100 wells are applied.

Description

A kind of method preventing sand well from using the corrosion of sand-preventing pump tail pipe
Technical field
The present invention relates to a kind of method preventing sand well from using the corrosion of sand-preventing pump tail pipe.
Background technology
On sand well, it is existing that conventional oil well pump often occurs that sand card plunger, sand bury sucker rod, sand milling pump barrel and plunger etc. As, make oil well pump premature failure.Technical staff devises the sand-preventing pump that long-plunger short pump barrel combines with annular space sand setting, successfully should With well more than 700 time, extend sand well and be excused from a college course phase more than 3 times, reduce production cost.But to some High water cut, high mineralization The sand well of degree, " stagnant water " in tail pipe often results in tail pipe corrosion failure, causes sand-preventing pump cisco unity malfunction, and oil well needs Tail pipe is changed in operation to be repeated, and increases oil recovery production cost.
Summary of the invention
It is an object of the invention to: a kind of method preventing sand well from using the corrosion of sand-preventing pump tail pipe is provided.Make at inspection pump During industry, the corrosion inhibiter of exploitation is added in sand-preventing pump tail pipe, enter sand-preventing pump down, play the effect preventing tail pipe from corroding.
A kind of method preventing sand well from using the corrosion of sand-preventing pump tail pipe of the present invention, step is as follows:
Step 1: preparing each component percentage by weight of corrosion inhibiter A: corrosion inhibiter A is:
Imidazoline quaternary ammonium salt IS-130,12.5-13.0%;
Chlorination 2-alkyl-1-(N-polyoxyethylene-2-amine ethyl) imidazoline-1-benzyl group ammonium soap, 7.5-8.5%;
Naphthenic acid imidazoline glacial acetic acid salt, 15.8-16.5%;
Cycloalkanes acidic group 1-(2-ethoxy) imidazoline quaternary ammonium salt, 10.2-11.0%;
The condensation substance of chlorination benzyl group α-menaphthyl quinoline ammonium, 3.5-5.0%;
N-amine ethyl lauryl imidazoline thioether, 4.0-4.5%;
Propilolic alcohol, 1.5-2.0%,
Remaining is methanol;
First, by imidazoline quaternary ammonium salt IS-130, chlorination 2-alkyl-1-(N-polyoxyethylene-2-amine ethyl) imidazoline-1- Benzyl group ammonium soap, naphthenic acid imidazoline glacial acetic acid salt, cycloalkanes acidic group 1-(2-ethoxy) imidazoline quaternary ammonium salt, chlorination benzyl group The condensation substance of α-menaphthyl quinoline ammonium, N-amine ethyl lauryl imidazoline thioether, seven kinds of components of propilolic alcohol are by weight adding Enamel reaction still;Slowly it is warmed up to 45~50 DEG C, after stirring 60 minutes, adds methanol under constant agitation, continue stirring After 60 minutes, stopping heating, cooling limit, limit is stirred, and cools down room temperature, obtains corrosion inhibiter A.
Described propilolic alcohol colourless transparent liquid, has Herba Pelargonii Graveolentis abnormal smells from the patient, is long placed in easy yellowing when especially meeting light;Be dissolved in water, alcohol, Ether;As rust remover, chemical intermediate, corrosion inhibitor, solvent, stabilizer etc..Propilolic alcohol is published in 2012 prunus mume (sieb.) sieb.et zucc. equality people Corrosion inhibition and the synergistic function of the imidazoline sulfate salt on year volume 22 the 1st phase " oil gas field environmental conservation " magazine grind Study carefully in a literary composition and its effect is discussed in detail.
Described imidazoline quaternary ammonium salt IS-130, the another name: " China of oil field middle temperature corrosion inhibiter IS-130, Huang Hongzhou chief editor Surfactant overview " book, Chemical Industry Press, JIUYUE the 1st edition in 2003, page 53 there is narration;Manufacturer: lake Northing Katyuan company limited.
Described chlorination 2-alkyl-1-(N-polyoxyethylene-2-amine ethyl) imidazoline-1-benzyl group ammonium soap, another name: Acidification of oil field corrosion inhibiter CIDS-1;Imidazoline double salt CIDS-1." China's surfactant overview " book of Huang Hongzhou chief editor, changes Learn industry publishing house, JIUYUE the 1st edition in 2003, page 50 has narration;Manufacturer: Chemical Inst., Shandong Prov., huge port, Tianjin Technique institute of oilfield downhole operation company.
Described naphthenic acid imidazoline glacial acetic acid salt, " China's surfactant overview " book of Huang Hongzhou chief editor, chemistry Industry publishing house, JIUYUE the 1st edition in 2003, page 55 there is narration;Manufacturer: Yueyang general petrochemicals factory academy.
Described cycloalkanes acidic group 1-(2-ethoxy) imidazoline quaternary ammonium salt, chemical name: 2-cycloalkanes acidic group-1-2-ethoxy Bian Ammonium chloride." China's surfactant overview " book of Huang Hongzhou chief editor, Chemical Industry Press, JIUYUE the 1st edition in 2003, Page 55 there is narration;Manufacturer: Yueyang general petrochemicals factory academy.
The condensation substance of described chlorination benzyl group α-menaphthyl quinoline ammonium, another name: quinoline quaternary ammonium salt QN-3.Huang Hongzhou chief editor's " China's surfactant overview " book, Chemical Industry Press, JIUYUE the 1st edition in 2003, page 103 there is narration;Factory Family: chemical system of He'nan University.
Described N-amine ethyl lauryl imidazoline thioether, another name: 2-[2-(1-aminoethyl) imidazolinyl] propyl group ten Dialkyl sulfide." China's surfactant overview " book of Huang Hongzhou chief editor, Chemical Industry Press, JIUYUE the 1st in 2003 Version, has narration in page 103;Manufacturer: chemical system of He'nan University.
Described methanol oil is commercially available.
Step 2: playing flow string in producing well, flow string includes: oil pipe column and sucker rod roofbolt, oil pipe column from It is followed successively by down tubing nipple, oil pipe, sand-preventing pump pump barrel, tail pipe, plug.Sucker rod roofbolt is followed successively by 25mm from top to bottom and takes out Beam hanger, 22mm sucker rod, 19mm sucker rod, sand-preventing pump plunger.
Step 3: under enter to prevent sand well use sand-preventing pump tail pipe corrosion flow string.Prevent sand well from using anti- The flow string of sand pump tail pipe corrosion includes: boll-weevil hanger 1, tubing nipple 2, oil pipe 3, sand-preventing pump 4, tail pipe 5, plug 6.
Its operational approach:
(1) tail pipe 5 with plug 6 is entered under;
(2), in the tail pipe 5 with plug 6, corrosion inhibiter A is filled it up with;
(3) upper end at the tail pipe 5 with plug 6 is sequentially connected with sand-preventing pump 4, oil pipe 3, tubing nipple 2, boll-weevil hanger 1.Screwed connection between boll-weevil hanger 1, tubing nipple 2, oil pipe 3, sand-preventing pump 4, tail pipe 5, plug 6.
Step 4: after entering sand-preventing pump plunger, sucker rod roofbolt under arrangement and method for construction, completion puts into normal production.
Beneficial effects of the present invention: after adding corrosion inhibiter A in sand well uses sand-preventing pump tail pipe, more than 100 wells time should With, do not find that tail pipe corrodes.
Accompanying drawing explanation
Fig. 1 is that the present invention prevents sand well from using the flow string structural representation of sand-preventing pump tail pipe corrosion.
In figure, 1. boll-weevil hanger, 2. tubing nipple, 3. oil pipe, 4. sand-preventing pump, 5. tail pipe, 6 plugs.
Detailed description of the invention
Described boll-weevil hanger, tubing nipple, oil pipe, plug are that downhole tool is commonly used in oil field, commercially available;
Described tail pipe is exactly conventional oil pipe, is referred to as tail pipe the most traditionally, commonly uses downhole tool for oil field, and market has Sell;
Described sand-preventing pump, specification is φ 38, φ 44, φ 56, and Shandong Wei Mabeng industry company limited produces.
Embodiment 1
A kind of method preventing sand well from using the corrosion of sand-preventing pump tail pipe of the present invention, step is as follows:
Step 1: preparing each component percentage by weight of corrosion inhibiter A: corrosion inhibiter A is:
Imidazoline quaternary ammonium salt IS-130,12.8%;
Chlorination 2-alkyl-1-(N-polyoxyethylene-2-amine ethyl) imidazoline-1-benzyl group ammonium soap, 8%;
Naphthenic acid imidazoline glacial acetic acid salt, 16%;
Cycloalkanes acidic group 1-(2-ethoxy) imidazoline quaternary ammonium salt, 10.8%;
The condensation substance of chlorination benzyl group α-menaphthyl quinoline ammonium, 4.0%;
N-amine ethyl lauryl imidazoline thioether, 4.2%;
Propilolic alcohol, 1.8%,
Remaining is methanol;
First, by imidazoline quaternary ammonium salt IS-130, chlorination 2-alkyl-1-(N-polyoxyethylene-2-amine ethyl) imidazoline-1- Benzyl group ammonium soap, naphthenic acid imidazoline glacial acetic acid salt, cycloalkanes acidic group 1-(2-ethoxy) imidazoline quaternary ammonium salt, chlorination benzyl group The condensation substance of α-menaphthyl quinoline ammonium, N-amine ethyl lauryl imidazoline thioether, seven kinds of components of propilolic alcohol are by weight adding Enamel reaction still;Slowly it is warmed up to 47 DEG C, after stirring 60 minutes, adds methanol under constant agitation, continue stirring 60 points Zhong Hou, stops heating, and cooling limit, limit is stirred, and cools down room temperature, obtains corrosion inhibiter A.
Step 2: playing flow string in producing well, flow string includes: oil pipe column and sucker rod roofbolt, oil pipe column from It is followed successively by down tubing nipple, oil pipe, sand-preventing pump pump barrel, tail pipe, plug.Sucker rod roofbolt is followed successively by 25mm from top to bottom and takes out Beam hanger, 22mm sucker rod, 19mm sucker rod, sand-preventing pump plunger.
Step 3: under enter to prevent sand well use sand-preventing pump tail pipe corrosion flow string.Prevent sand well from using anti- The flow string of sand pump tail pipe corrosion includes: boll-weevil hanger 1, tubing nipple 2, oil pipe 3, sand-preventing pump 4, tail pipe 5, plug 6.
Its operational approach:
(1) tail pipe 5 with plug 6 is entered under;
(2), in the tail pipe 5 with plug 6, corrosion inhibiter A is filled it up with;
(3) upper end at the tail pipe 5 with plug 6 is sequentially connected with sand-preventing pump 4, oil pipe 3, tubing nipple 2, boll-weevil hanger 1.Screwed connection between boll-weevil hanger 1, tubing nipple 2, oil pipe 3, sand-preventing pump 4, tail pipe 5, plug 6.
Step 4: after entering sand-preventing pump plunger, sucker rod roofbolt under arrangement and method for construction, completion puts into normal production.
Embodiment 2
A kind of method preventing sand well from using the corrosion of sand-preventing pump tail pipe of the present invention, step is as follows:
Step 1: preparing each component percentage by weight of corrosion inhibiter A: corrosion inhibiter A is:
Imidazoline quaternary ammonium salt IS-130,13.0%;
Chlorination 2-alkyl-1-(N-polyoxyethylene-2-amine ethyl) imidazoline-1-benzyl group ammonium soap, 8.5%;
Naphthenic acid imidazoline glacial acetic acid salt, 16.5%;
Cycloalkanes acidic group 1-(2-ethoxy) imidazoline quaternary ammonium salt, 11.0%;
The condensation substance of chlorination benzyl group α-menaphthyl quinoline ammonium, 5.0%;
N-amine ethyl lauryl imidazoline thioether, 4.5%;
Propilolic alcohol, 2.0%,
Remaining is methanol;
First, by imidazoline quaternary ammonium salt IS-130, chlorination 2-alkyl-1-(N-polyoxyethylene-2-amine ethyl) imidazoline-1- Benzyl group ammonium soap, naphthenic acid imidazoline glacial acetic acid salt, cycloalkanes acidic group 1-(2-ethoxy) imidazoline quaternary ammonium salt, chlorination benzyl group The condensation substance of α-menaphthyl quinoline ammonium, N-amine ethyl lauryl imidazoline thioether, seven kinds of components of propilolic alcohol are by weight adding Enamel reaction still;Slowly it is warmed up to 50 DEG C, after stirring 60 minutes, adds methanol under constant agitation, continue stirring 60 points Zhong Hou, stops heating, and cooling limit, limit is stirred, and cools down room temperature, obtains corrosion inhibiter A.
Step 2: playing flow string in producing well, flow string includes: oil pipe column and sucker rod roofbolt, oil pipe column from It is followed successively by down tubing nipple, oil pipe, sand-preventing pump pump barrel, tail pipe, plug.Sucker rod roofbolt is followed successively by 25mm from top to bottom and takes out Beam hanger, 22mm sucker rod, 19mm sucker rod, sand-preventing pump plunger.
Step 3: under enter to prevent sand well use sand-preventing pump tail pipe corrosion flow string.Prevent sand well from using anti- The flow string of sand pump tail pipe corrosion includes: boll-weevil hanger 1, tubing nipple 2, oil pipe 3, sand-preventing pump 4, tail pipe 5, plug 6.
Its operational approach:
(1) tail pipe 5 with plug 6 is entered under;
(2), in the tail pipe 5 with plug 6, corrosion inhibiter A is filled it up with;
(3) upper end at the tail pipe 5 with plug 6 is sequentially connected with sand-preventing pump 4, oil pipe 3, tubing nipple 2, boll-weevil hanger 1.Screwed connection between boll-weevil hanger 1, tubing nipple 2, oil pipe 3, sand-preventing pump 4, tail pipe 5, plug 6.
Step 4: after entering sand-preventing pump plunger, sucker rod roofbolt under arrangement and method for construction, completion puts into normal production.
Embodiment 3
A kind of method preventing sand well from using the corrosion of sand-preventing pump tail pipe of the present invention, step is as follows:
Step 1: preparing each component percentage by weight of corrosion inhibiter A: corrosion inhibiter A is:
Imidazoline quaternary ammonium salt IS-130,12.5%;
Chlorination 2-alkyl-1-(N-polyoxyethylene-2-amine ethyl) imidazoline-1-benzyl group ammonium soap, 7.5%;
Naphthenic acid imidazoline glacial acetic acid salt, 15.8%;
Cycloalkanes acidic group 1-(2-ethoxy) imidazoline quaternary ammonium salt, 10.2%;
The condensation substance of chlorination benzyl group α-menaphthyl quinoline ammonium, 3.5%;
N-amine ethyl lauryl imidazoline thioether, 4.0%;
Propilolic alcohol, 1.5%,
Remaining is methanol;
First, by imidazoline quaternary ammonium salt IS-130, chlorination 2-alkyl-1-(N-polyoxyethylene-2-amine ethyl) imidazoline-1- Benzyl group ammonium soap, naphthenic acid imidazoline glacial acetic acid salt, cycloalkanes acidic group 1-(2-ethoxy) imidazoline quaternary ammonium salt, chlorination benzyl group The condensation substance of α-menaphthyl quinoline ammonium, N-amine ethyl lauryl imidazoline thioether, seven kinds of components of propilolic alcohol are by weight adding Enamel reaction still;Slowly it is warmed up to 45 DEG C, after stirring 60 minutes, adds methanol under constant agitation, continue stirring 60 points Zhong Hou, stops heating, and cooling limit, limit is stirred, and cools down room temperature, obtains corrosion inhibiter A.
Step 2: playing flow string in producing well, flow string includes: oil pipe column and sucker rod roofbolt, oil pipe column from It is followed successively by down tubing nipple, oil pipe, sand-preventing pump pump barrel, tail pipe, plug.Sucker rod roofbolt is followed successively by 25mm from top to bottom and takes out Beam hanger, 22mm sucker rod, 19mm sucker rod, sand-preventing pump plunger.
Step 3: under enter to prevent sand well use sand-preventing pump tail pipe corrosion flow string.Prevent sand well from using anti- The flow string of sand pump tail pipe corrosion includes: boll-weevil hanger 1, tubing nipple 2, oil pipe 3, sand-preventing pump 4, tail pipe 5, plug 6.
Its operational approach:
(1) tail pipe 5 with plug 6 is entered under;
(2) in the tail pipe 5 with plug 6, corrosion inhibiter A is filled it up with;
(3) upper end at the tail pipe 5 with plug 6 is sequentially connected with sand-preventing pump 4, oil pipe 3, tubing nipple 2, boll-weevil hanger 1.Screwed connection between boll-weevil hanger 1, tubing nipple 2, oil pipe 3, sand-preventing pump 4, tail pipe 5, plug 6.
Step 4: after entering sand-preventing pump plunger, sucker rod roofbolt under arrangement and method for construction, completion puts into normal production.

Claims (1)

1. one kind prevents the method that sand well uses the corrosion of sand-preventing pump tail pipe, it is characterised in that:
Step 1: preparing each component percentage by weight of corrosion inhibiter A: corrosion inhibiter A is:
Imidazoline quaternary ammonium salt IS-130,12.5-13.0%;
Chlorination 2-alkyl-1-(N-polyoxyethylene-2-amine ethyl) imidazoline-1-hexadecyldimethyl benzyl ammonium soap, 7.5-8.5%;
Naphthenic acid imidazoline glacial acetic acid salt, 15.8-16.5%;
Cycloalkanes acidic group 1-(2-ethoxy) imidazoline quaternary ammonium salt, 10.2-11.0%;
The condensation substance of zephiran chloride α-menaphthyl quinoline ammonium, 3.5-5.0%;
N-amine ethyl lauryl imidazoline thioether, 4.0-4.5%;
Propilolic alcohol, 1.5-2.0%;
Remaining is methanol;
First, by imidazoline quaternary ammonium salt IS-130, chlorination 2-alkyl-1-(N-polyoxyethylene-2-amine ethyl) imidazoline-1-benzyl Ammonium soap, naphthenic acid imidazoline glacial acetic acid salt, cycloalkanes acidic group 1-(2-ethoxy) imidazoline quaternary ammonium salt, zephiran chloride α-naphthalene The condensation substance of methylquinoline ammonium, N-amine ethyl lauryl imidazoline thioether, seven kinds of components of propilolic alcohol add enamel by weight Reactor;Slowly it is warmed up to 45~50 DEG C, after stirring 60 minutes, adds methanol under constant agitation, continue stirring 60 points Zhong Hou, stops heating, and cooling limit, limit is stirred, and cools down room temperature, obtains corrosion inhibiter A;
Step 2: playing flow string in producing well, flow string includes: oil pipe column and sucker rod roofbolt, oil pipe column is from up to Under be followed successively by tubing nipple, oil pipe, sand-preventing pump pump barrel, tail pipe, plug, sucker rod roofbolt be followed successively by from top to bottom 25mm oil pumping Bar, 22mm sucker rod, 19mm sucker rod, sand-preventing pump plunger;
Step 3: under enter to prevent sand well use sand-preventing pump tail pipe corrosion flow string;
Prevent sand well from using the flow string of sand-preventing pump tail pipe corrosion to include: boll-weevil hanger (1), tubing nipple (2), oil Pipe (3), sand-preventing pump (4), tail pipe (5), plug (6);
Its operational approach: 1) under enter the tail pipe (5) with plug (6);
2) in the tail pipe (5) with plug (6), corrosion inhibiter A is filled it up with;
3) upper end at the tail pipe (5) with plug (6) is sequentially connected with sand-preventing pump (4), oil pipe (3), tubing nipple (2), oil pipe Hanger (1), silk between boll-weevil hanger (1), tubing nipple (2), oil pipe (3), sand-preventing pump (4), tail pipe (5), plug (6) Button connects;
Step 4: after entering sand-preventing pump plunger, sucker rod under arrangement and method for construction, completion puts into normal production.
CN201310220181.4A 2013-06-05 2013-06-05 Method for preventing corrosion of sand control pump tail pipe used for sand production well Active CN104212427B (en)

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CN107365576B (en) * 2017-07-12 2019-05-14 中国地质大学(北京) For hypotonic or Oil in Super-low Permeability oil reservoir CO2The fluidity control system of the displacement of reservoir oil and application
CN113046046B (en) * 2021-03-29 2023-05-16 中海油常州涂料化工研究院有限公司 Corrosion inhibitor suitable for hydrochloric acid system with mass fraction of 20-28%
CN116410725A (en) * 2021-12-29 2023-07-11 中国石油天然气股份有限公司 Corrosion inhibition type foam discharging agent for gas field, preparation method and application

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