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CN104218001B - A manufacturing method of flash memory gate - Google Patents

A manufacturing method of flash memory gate Download PDF

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Publication number
CN104218001B
CN104218001B CN201310210343.6A CN201310210343A CN104218001B CN 104218001 B CN104218001 B CN 104218001B CN 201310210343 A CN201310210343 A CN 201310210343A CN 104218001 B CN104218001 B CN 104218001B
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layer
flash memory
silicon nitride
grid
polysilicon layer
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CN104218001A (en
Inventor
郭振强
陈瑜
罗啸
赵阶喜
马斌
陈华伦
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Shanghai Huahong Grace Semiconductor Manufacturing Corp
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Shanghai Huahong Grace Semiconductor Manufacturing Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/283Deposition of conductive or insulating materials for electrodes conducting electric current
    • H01L21/285Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/401Multistep manufacturing processes
    • H01L29/4011Multistep manufacturing processes for data storage electrodes
    • H01L29/40117Multistep manufacturing processes for data storage electrodes the electrodes comprising a charge-trapping insulator
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B43/00EEPROM devices comprising charge-trapping gate insulators

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Ceramic Engineering (AREA)
  • Non-Volatile Memory (AREA)
  • Semiconductor Memories (AREA)

Abstract

The invention discloses a manufacturing method of flash memory gate. The manufacturing method comprises the following steps: forming shallow trench field oxide in order to isolate an active region; forming a well region of the flash memory by ion implantation; growing an ONO layer and a polysilicon layer sequentially on the surface of the silicon substrate and doping the polysilicon layer; depositing a layer of tungsten silicide on the surface of the polysilicon layer; growing the fourth and the fifth silicon nitride layers sequentially by using the processes of furnace tube and chemical vapor deposition, and stacking them to form the gate hard mask layer; and by means of photolithographic etching process, etching the gate hard mask layer, tungsten silicide layer and polysilicon layer in sequence to form the gate of the flash memory. The inventive method is capable of enabling the gate to maintain better morphology, better repairing the ONO defect of the flash memory to prolong the lifespan thereof and eliminate the durability test problem caused by forming the silicon nitride layer only using chemical vapor deposition, and preventing effectively the depletion of the polysilicon.

Description

The manufacture method of flash memory grid
Technical field
The present invention relates to a kind of semiconductor integrated circuit method of manufacturing technology, more particularly to a kind of manufacture of flash memory grid Method.
Background technology
As shown in figure 1, being the top view of the flash memory that existing method is formed;As shown in Fig. 2 being the flash memory of the AA ' line along along Fig. 1 Sectional view.Existing method comprises the steps when forming the grid of flash memory:
Step one, form shallow trench using lithographic etch process on silicon substrate 101, active area is defined by shallow trench; In shallow trench, filling silica forms shallow trench field oxygen 103, by shallow trench field oxygen 103, active area is isolated.
Step 2, silicon substrate 101 surfaces of active regions grow one layer of sacrificial oxide layer.
Carry out the well region 102 that ion implanting forms flash memory, the ion implanting of well region 102 passes through sacrificial oxide layer.Flash memory Well region 102 includes for including N-type well region or P type trap zone, and N-type well region is located in the flash area that channel type is P-type channel, P type trap zone is located in the flash area that channel type is N-type channel.
Well region 102 removes sacrificial oxide layer using wet-etching technology after being formed.
Step 3, silicon substrate 101 surface grow ground floor silica, second layer silicon nitride and third layer oxygen successively SiClx, forms ONO layer 104 by the superposition of ground floor silica, second layer silicon nitride and third layer silica, in 4ONO layer 104 table Deposit one layer of polysilicon layer 105 on face, and p-type or n-type doping are carried out to polysilicon layer 105 using ion implantation technology;Contraposition Carry out p-type doping in channel type is for the polysilicon layer 105 in the flash area of P-type channel, being pointed to channel type is N-type Carry out n-type doping in described polysilicon layer in the flash area of raceway groove.
Step 4, in polysilicon layer 105 surface deposited metal tungsten silicide layer 106.
Step 5, using furnace process in metal silication tungsten layer 106 surface deposition one silicon nitride layer 107 and by this silicon nitride Layer 107 composition grid hard mask layer 107.
Step 6, photoetching offset plate figure is formed using photoetching process and is defined the grid figure of flash memory by this photoetching offset plate figure Shape;Grid hard mask layer 107 is performed etching for mask using photoetching offset plate figure, using photoetching offset plate figure and grid hard mask layer 107 perform etching and are formed with grid hard mask layer, metal silication tungsten successively for mask to metal silication tungsten layer and polysilicon layer Layer and the grid of polysilicon layer superposition formation flash memory.
The grid hard mask layer being made up of silicon nitride layer in existing semiconductor flash memory grid technology method is typically to utilize Boiler tube mode grows;The benefit of the grid hard mask layer that boiler tube mode grows is during grid etch, grid hard mask layer Grid can be provided and protect well, keep the gate topography after etching.But at the high warm of long furnace process Comprehend and cause the boron ion of p-type polysilicon layer to be diffused into metal silication tungsten layer, so that the boron ion concentration of p-type polysilicon layer subtracts Light, cause, during transistor work, depletion of polysilicon occurs.
Silicon nitride layer in existing method also can be using the relatively low chemical vapor deposition method growth of technological temperature, if adopted Although it can be avoided that furnace process produces if doing grid hard mask layer with the silicon nitride layer being formed by chemical vapor deposition method The boron ion of p-type polysilicon layer be diffused into the defect of metal silication tungsten layer, but due to the ONO layer existing defects in flash memory, Chemical vapor deposition method cannot eliminate the defect in ONO layer, and the presence of these defects can reduce service life the meeting of flash memory Cause the durability test problem of flush memory device.
Content of the invention
The technical problem to be solved is to provide a kind of manufacture method of flash memory grid, and grid can be made to keep good Good pattern, can eliminate durability test problem, can effectively prevent depletion of polysilicon.
For solving above-mentioned technical problem, the manufacture method of the flash memory grid that the present invention provides comprises the steps:
Step one, form shallow trench on a silicon substrate using lithographic etch process, active area is defined by described shallow trench; In described shallow trench, filling silica forms shallow trench field oxygen, by described shallow trench field oxygen, described active area is isolated.
Step 2, carry out ion implanting formed well region.
Step 3, grow ground floor silica, second layer silicon nitride and third layer oxygen successively on the surface of described silicon substrate SiClx, removes described ground floor silica outside flash area, described second layer silicon nitride and described third layer silica, by protecting The described ground floor silica in described flash area, described second layer silicon nitride and the superposition of described third layer silica is stayed to be formed ONO layer;Described surface of silicon outside described flash area forms the gate dielectric layer with the integrated cmos device of flash memory, in institute State one layer of polysilicon layer of deposition on ONO layer and described gate dielectric layer surface, and using ion implantation technology to described polysilicon layer Carry out p-type or n-type doping.
Step 4, in described polysilicon layer surface deposited metal tungsten silicide layer.
Step 5, using furnace process in described metal silication tungsten layer surface deposition the 4th silicon nitride layer;Using chemical gas Phase depositing technics in described 4th silicon nitride layer surface deposition the 5th silicon nitride layer, by described 4th silicon nitride layer and the described 5th Silicon nitride layer superposition forms grid hard mask layer;The temperature conditionss of the furnace process of described 4th silicon nitride layer can be to described ONO The boundary defect of the silicon nitride of layer and silica carries out repairing and can make the boron ion of the described polysilicon layer of p-type doping to expand It is scattered in described metal silication tungsten layer, under conditions of described grid hard mask layer gross thickness is constant, described 4th silicon nitride layer It is set to the thickness of described 5th silicon nitride layer:Enable to described in the furnace process time of described 4th silicon nitride layer Under conditions of the boundary defect of ONO layer is fully repaired, the thickness of described 4th silicon nitride layer gets over Bao Yuehao.
Step 6, define the gate patterns of described flash memory using photoetching process;Gate patterns according to lithographic definition according to Secondary described grid hard mask layer, described metal silication tungsten layer and described polysilicon layer are performed etching, etching post tensioned unbonded prestressed concrete region outside Described grid hard mask layer, described metal silication tungsten layer and described polysilicon layer be all removed, by remaining in described gate regions The described grid hard mask layer in domain, described metal silication tungsten layer and the superposition of described polysilicon layer form the grid of described flash memory.
Further improvement is that the thickness of the 4th silicon nitride layer described in step 5 is 300~600, described 5th nitrogen The thickness of SiClx layer is 900~1200.
Further improvement is that well region described in step 2 includes N-type well region or P type trap zone, and N-type well region is located at described In PMOS device region in cmos device, the NMOS device that P type trap zone is located in described flash area and described cmos device In part region.
Further improvement is to be pointed to the nmos device in described flash area and described cmos device in step 3 Carry out n-type doping in described polysilicon layer in region, be pointed to described in the PMOS device region in described cmos device Carry out p-type doping in polysilicon layer.
Further improvement is that furnace process described in step 5 is LPCVD, and described chemical vapor deposition method is PECVD.
Further improvement is that the temperature of described furnace process is 720 DEG C, and the temperature of described chemical vapor deposition method is 400℃.
Further improvement be, the abundant reparation of the boundary defect of ONO layer described in step 5 is by meeting durability test It is defined.
Further improvement is that the condition meeting durability test is:Under 55 DEG C of temperature conditionss, described flash memory is entered After the circulation erase and program operations that row is 110K time, flash memory can normally run.
The present invention by by the grid being made up of silicon nitride layer hard mask layer be divided into two-layer and successively adopt furnace process and Chemical vapor deposition method is formed, and grid hard mask layer can carry out good protection to grid in grid etch, so as to The pattern of enough good holding grids;Simultaneously the inventive method using furnace process can be good at the silicon nitride to ONO layer and The boundary defect of silica is repaired, it is possible to increase the service life of flash memory simultaneously eliminates and individually adopts chemical vapor deposition method Form the durability test problem brought during silicon nitride layer;Then it is avoided that long-time boiler tube is high using chemical vapor deposition method In p-type polysilicon layer caused by temperature, boron is diffused into the defect in metal silication tungsten layer, can effectively prevent depletion of polysilicon.
Brief description
The present invention is further detailed explanation with reference to the accompanying drawings and detailed description:
Fig. 1 is the top view of the flash memory that existing method is formed;
Fig. 2 is the sectional view of the flash memory of AA ' line along along Fig. 1;
Fig. 3 is the flow chart of present invention method;
Fig. 4 is the profile of flash memory in present invention method;
Fig. 5 is the profile of the flash memory of BB ' line along along Fig. 4.
Specific embodiment
As shown in figure 3, being the flow chart of present invention method;As shown in figure 4, being to dodge in present invention method The profile deposited;As shown in figure 5, being the profile of the flash memory of BB ' line along along Fig. 4.The manufacture of embodiment of the present invention flash memory grid Method comprises the steps:
Step one, using lithographic etch process, shallow trench is formed on silicon substrate 1, defined by described shallow trench active Area;In described shallow trench, filling silica forms shallow trench field oxygen 3, by described shallow trench field oxygen 3, described active area is carried out Isolation;
Step 2, carry out ion implanting formed flash memory well region 2.In the embodiment of the present invention flash memory and for flash memory periphery electricity The cmos device on road integrates making, and cmos device includes PMOS device and nmos device two types.Described well region 2 wraps Include N-type well region 2 or P type trap zone 2, N-type well region 2 is located in PMOS device region, and P type trap zone 2 is located at flash area and NMOS device In part region.
Step 3, grow ground floor silica, second layer silicon nitride and third layer oxygen successively on the surface of described silicon substrate 1 SiClx, using etching technics remove flash area outside described ground floor silica, described second layer silicon nitride and the described 3rd Layer silica, by the described ground floor silica, described second layer silicon nitride and the described third layer that remain in described flash area Silica superposition forms ONO layer 4;The grid that described silicon substrate 1 surface outside described flash area forms described cmos device are situated between Matter layer, deposits one layer of polysilicon layer 5 on described ONO layer and described gate dielectric layer surface, and using ion implantation technology to institute State polysilicon layer 5 and carry out p-type or n-type doping.Concrete doped region is to be pointed to described flash area and described cmos device In nmos device region in described polysilicon layer in carry out n-type doping, be pointed to the PMOS device in described cmos device Carry out p-type doping in described polysilicon layer in region.
Step 4, in described polysilicon layer 5 surface deposited metal tungsten silicide layer 6.
Step 5, using furnace process in described metal silication tungsten layer 6 surface deposition the 4th silicon nitride layer 7, described boiler tube Technique is LPCVD, and technological temperature is 720 DEG C.Using chemical vapor deposition method in described 4th silicon nitride layer 7 surface deposition Five silicon nitride layers 8, described chemical vapor deposition method is PECVD, and technological temperature is 400 DEG C.By described 4th silicon nitride layer 7 He Described 5th silicon nitride layer 8 superposition forms grid hard mask layer.The temperature conditionss meeting of the furnace process of described 4th silicon nitride layer 7 The defect of described ONO layer 4 is carried out repairing and can make the boron ion of the described polysilicon layer 5 of p-type doping to be diffused into described gold Belong in tungsten silicide layer 6, under conditions of described grid hard mask layer gross thickness is constant, described 4th silicon nitride layer 7 and described the The thickness of five silicon nitride layers 8 is set to:Enable to described ONO layer 4 in the furnace process time of described 4th silicon nitride layer 7 Under conditions of defect is fully repaired, the thickness of described 4th silicon nitride layer 7 gets over Bao Yuehao;The filling of the boundary defect of described ONO layer 4 Point repair and to be defined by meeting durability test;The condition meeting durability test is:Under 55 DEG C of temperature conditionss, to described sudden strain of a muscle After depositing into the circulation erase and program operations of row 110K time, flash memory can normally run.Preferably, the thickness of described 4th silicon nitride layer Spend for 300~600, the thickness of described 5th silicon nitride layer is 900~1200.
Step 6, using photoetching process formed photoetching offset plate figure, defined in described flash area by described photoetching offset plate figure Go out the gate patterns of described flash memory, described photoetching offset plate figure also defines described cmos device in described cmos device region simultaneously Gate patterns;The hard mask pattern of formation is performed etching for mask with described photoetching offset plate figure to described grid hard mask layer, by Described photoetching offset plate figure and described hard mask pattern be mask or individually with described hard mask pattern for mask successively to described gold Belong to tungsten silicide layer 6 and described polysilicon layer 5 performs etching, the described grid hard mask layer outside etching post tensioned unbonded prestressed concrete region, described gold Belong to tungsten silicide layer 6 and described polysilicon layer 5 is all removed, by the described grid hard mask layer, the institute that remain in described area of grid State metal silication tungsten layer 6 and described polysilicon layer 5 forms institute in described flash area and the superposition of described cmos device region respectively State flash memory and the grid of described cmos device.
Above by specific embodiment, the present invention is described in detail, but these have not constituted the limit to the present invention System.Without departing from the principles of the present invention, those skilled in the art also can make many deformation and improve, and these also should It is considered as protection scope of the present invention.

Claims (7)

1. a kind of manufacture method of flash memory grid is it is characterised in that comprise the steps:
Step one, form shallow trench on a silicon substrate using lithographic etch process, active area is defined by described shallow trench;Institute State filling silica in shallow trench and form shallow trench field oxygen, by described shallow trench field oxygen, described active area is isolated;
Step 2, carry out ion implanting formed well region;
Step 3, grow ground floor silica, second layer silicon nitride and third layer silica successively on the surface of described silicon substrate, Remove described ground floor silica outside flash area, described second layer silicon nitride and described third layer silica, by remaining in The described ground floor silica of described flash area, described second layer silicon nitride and the superposition of described third layer silica form ONO Layer;Described surface of silicon outside described flash area forms the gate dielectric layer with the integrated cmos device of flash memory, described Deposit one layer of polysilicon layer on ONO layer and described gate dielectric layer surface, and using ion implantation technology, described polysilicon layer is entered Row p-type or n-type doping;
It is pointed to carry out N in the described polysilicon layer in the nmos device region in described flash area and described cmos device Type adulterates, and is pointed to carry out p-type doping in the described polysilicon layer in the PMOS device region in described cmos device;
Step 4, in described polysilicon layer surface deposited metal tungsten silicide layer;
Step 5, using furnace process in described metal silication tungsten layer surface deposition the 4th silicon nitride layer;Formed sediment using chemical gaseous phase Long-pending technique, in described 4th silicon nitride layer surface deposition the 5th silicon nitride layer, is nitrogenized by described 4th silicon nitride layer and the described 5th Silicon layer superposition forms grid hard mask layer;The temperature conditionss of the furnace process of described 4th silicon nitride layer can be to described ONO layer The boundary defect of silicon nitride and silica carries out repairing and can make the boron ion of the described polysilicon layer of p-type doping to be diffused into In described metal silication tungsten layer, under conditions of described grid hard mask layer gross thickness is constant, described 4th silicon nitride layer and institute The thickness stating the 5th silicon nitride layer is set to:Enable to described ONO layer in the furnace process time of described 4th silicon nitride layer Boundary defect fully repair under conditions of, the thickness of described 4th silicon nitride layer gets over Bao Yuehao;
Step 6, define the gate patterns of described flash memory using photoetching process;Right successively according to the gate patterns of lithographic definition Described grid hard mask layer, described metal silication tungsten layer and described polysilicon layer perform etching, the institute outside etching post tensioned unbonded prestressed concrete region State grid hard mask layer, described metal silication tungsten layer and described polysilicon layer to be all removed, by remaining in described area of grid Described grid hard mask layer, described metal silication tungsten layer and the superposition of described polysilicon layer form the grid of described flash memory.
2. flash memory grid as claimed in claim 1 manufacture method it is characterised in that:4th silicon nitride layer described in step 5 Thickness beThe thickness of described 5th silicon nitride layer is
3. flash memory grid as claimed in claim 1 manufacture method it is characterised in that:Described in step 2, well region includes N-type Well region or P type trap zone, N-type well region is located in the PMOS device region in described cmos device, and P type trap zone is located at described flash memory area In nmos device region in domain and described cmos device.
4. flash memory grid as claimed in claim 1 manufacture method it is characterised in that:Described in step 5, furnace process is LPCVD, described chemical vapor deposition method is PECVD.
5. the flash memory grid as described in claim 1 or 4 manufacture method it is characterised in that:The temperature of described furnace process is 720 DEG C, the temperature of described chemical vapor deposition method is 400 DEG C.
6. flash memory grid as claimed in claim 1 manufacture method it is characterised in that:The interface of ONO layer described in step 5 The abundant reparation of defect is defined by meeting durability test.
7. flash memory grid as claimed in claim 6 manufacture method it is characterised in that:The condition meeting durability test is: Under 55 DEG C of temperature conditionss, after described flash memory is carried out with the circulation erase and program operations of 110K time, flash memory can normally run.
CN201310210343.6A 2013-05-30 2013-05-30 A manufacturing method of flash memory gate Active CN104218001B (en)

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CN108538835B (en) * 2018-05-16 2024-02-06 长鑫存储技术有限公司 Capacitor array structure and preparation method thereof

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CN101099236A (en) * 2004-12-22 2008-01-02 桑迪士克股份有限公司 Eeprom array with self-aligned shallow-trench isolation
CN102054675A (en) * 2009-11-02 2011-05-11 中芯国际集成电路制造(上海)有限公司 Method for forming offset side wall and MOS (metal oxide semiconductor) transistor
CN102097308A (en) * 2009-12-15 2011-06-15 中芯国际集成电路制造(上海)有限公司 Side wall etching method
CN102956492A (en) * 2011-08-24 2013-03-06 中芯国际集成电路制造(上海)有限公司 Semiconductor structure and manufacture method thereof and MOS (metal oxide semiconductor) transistor and manufacture method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101099236A (en) * 2004-12-22 2008-01-02 桑迪士克股份有限公司 Eeprom array with self-aligned shallow-trench isolation
CN102054675A (en) * 2009-11-02 2011-05-11 中芯国际集成电路制造(上海)有限公司 Method for forming offset side wall and MOS (metal oxide semiconductor) transistor
CN102097308A (en) * 2009-12-15 2011-06-15 中芯国际集成电路制造(上海)有限公司 Side wall etching method
CN102956492A (en) * 2011-08-24 2013-03-06 中芯国际集成电路制造(上海)有限公司 Semiconductor structure and manufacture method thereof and MOS (metal oxide semiconductor) transistor and manufacture method thereof

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