CN104087427A - Novel acidic anti-staining soap lotion and preparation method thereof - Google Patents
Novel acidic anti-staining soap lotion and preparation method thereof Download PDFInfo
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- CN104087427A CN104087427A CN201410315216.7A CN201410315216A CN104087427A CN 104087427 A CN104087427 A CN 104087427A CN 201410315216 A CN201410315216 A CN 201410315216A CN 104087427 A CN104087427 A CN 104087427A
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Abstract
The invention discloses a novel acidic anti-staining soap lotion and a preparation method thereof. The novel acidic anti-staining soap lotion is prepared from aliphatic amine polyoxyethylene ether biquaternary ammonium salt, a maleic anhydride-acrylic acid-N-vinyl pyrrolidone terpolymer, a carboxyalkylthiosuccinic acid and water. The acidic anti-staining soap lotion has extremely strong dispersing and chelating abilities, and has the strong affinity to hydrolyzed reactive dyes and dissociative reactive dyes. When the acidic anti-staining soap lotion is applied to a soaping aftertreatment process of reactive dye dyeing cotton fabrics, the production procedures are reduced, the water consumption is lowered, the dyeing fastness of the fabrics is obviously improved and the good anti-staining effect is realized. Thus, under the same condition, the usage amount of the soap lotion is reduced, so that the damage to fibers is reduced. Therefore, the novel acidic anti-staining soap lotion has high performance-price ratio.
Description
Technical field
The present invention relates to technical field of textile printing, relate in particular to the anti-soaping agent and preparation method thereof of being stained with of a kind of novel acid.
Background technology:
Reactive dyestuffs are mainly used in cellulose dyeing and stamp.Upper dye with set in, reactive dyestuffs are owing to being easily hydrolyzed, dye utilization rate is low, loose colour is serious, not only affects the colour fastness of fabric, and very easily makes white background staining.Loose colour be removed totally, difficulty is large, and the consumption energy consumption water yield is many, and the technique of soaping can effectively be removed loose colour, guarantees colour fastness, and makes coloured light more bright-coloured and pure, effectively improves and guarantee the set of dyestuff.Therefore, soap washing is one of committed step of dyeing and printing products quality.
Reactive dyestuffs soaping agent is along with reactive dyestuffs application develops rapidly and development.But common soaping agent exists the problems such as washing power is not good, staining is serious, so having the soaping agent of strong washing and anti-staining function, exploitation shoulders heavy responsibilities.Along with soaping agent exploitation and going deep into of applying, it is found that in soaping agent component, antistain agent is most important.The polymolecularity of polymeric surface active agent has caused people's attention.
Publication number is in the Chinese patent of CN102876476A, a kind of acid scouring agent is disclosed, by carboxyethyl thiosuccinic acid, maleic acid-acrylic acid copolymer, quadrol two salicyl sodium acetates with defoamer is composite forms, this soaping agent can reduce one pickling or the washing of a few road, reduce the pressure of sewage disposal, and the maleic acid-acrylic acid copolymer of its use low cost, low bubble, nontoxic, biodegradable, but also there is suitable big-difference in its anti-staining and ideal.
In the journal > > of < < Xi'an Polytechnic University the 6th phase in 2011 " research and development of a novel acid soaping agent and application " literary composition, introduced a kind of acid scouring agent, composite and obtain by maleic acid anhydride-propenoic acid-N vinyl pyrrolidone terpolymer, carboxyethyl thiosuccinic acid and 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid, this acid scouring agent is applied in to be soaped in technique, can reduce production process, reduce water consumption, improve dyefastness, but its anti-staining effect is still not ideal enough.
Publication number is in the Chinese patent of CN102994259A, a kind of low temperature soaping agent is disclosed, in formula, added Polyvinylpyrolidone (PVP) (PVP), it has good solubility, dispersiveness and good compatibleness, there is extremely strong avidity with a lot of dyestuffs, can reach splendid anti-staining, but Polyvinylpyrolidone (PVP) (PVP) is expensive, from cost consideration discomfort, is fit to do antistain agent.
Summary of the invention
In order to address the above problem, an object of the present invention is to provide low, the anti-staining of a kind of production cost good, the anti-soaping agent of being stained with of novel acid that can improve dyefastness, second object of the present invention is to provide the anti-preparation method who is stained with soaping agent of described novel acid.
For first realizes object, the present invention has adopted following technical scheme:
Novel acid is anti-is stained with a soaping agent, aliphatic amine polyoxyethylene ether biquaternary, maleic acid anhydride-propenoic acid-NVP terpolymer, carboxyethyl thiosuccinic acid and water, consists of.
As further improvement, described acidity prevents that being stained with the raw materials used massfraction of soaping agent is: aliphatic amine polyoxyethylene ether biquaternary 5%-20%, maleic acid anhydride-propenoic acid-NVP terpolymer 20%-40% and carboxyethyl thiosuccinic acid 1%-10%, surplus moisturizing to 100%.
As further improvement, the structural formula of described aliphatic amine polyoxyethylene ether biquaternary is:
In formula, R is C
12-C
18the alkyl of saturated direct-connected or side chain, general formula is C
ah
2a+1, a=12-18 wherein, m+n=12-50.
As further improvement, the preparation method of described aliphatic amine polyoxyethylene ether biquaternary is: first aliphatic amine polyoxyethylene ether is reacted to 4h with biphenyl benzyl dichloride at 100 ℃-150 ℃, then be cooled to 50 ℃, finally add aliphatic amine polyoxyethylene ether and biphenyl benzyl dichloride quality and the deionized water of 10%-30%, insulation reaction 10h.
As further improvement, the mol ratio of described aliphatic amine polyoxyethylene ether and biphenyl benzyl dichloride is 1:0.5-1:0.8.
As further improvement, the preparation method of described maleic acid anhydride-propenoic acid-NVP terpolymer is: first maleic anhydride is dissolved in to water, being heated to 60 ℃ of-80 ℃ of stirrings dissolves it completely, then add the NaOH aqueous solution to regulate pH to neutral, while being warming up to again 80 ℃-90 ℃, drip vinylformic acid, NVP and initiator solution, within 2-4 hour, be added dropwise to complete, at 80 ℃ of-90 ℃ of isothermal reaction 6-8h, finally with the NaOH aqueous solution, adjust pH to 3-5, be cooled to 50 ℃.
As further improvement, described initiator is one or more mixtures in Potassium Persulphate, Sodium Persulfate, ammonium persulphate.
As further improvement, the mass ratio of described vinylformic acid, maleic anhydride and NVP is 6:2:0.5-6:2:0.9.
In order to realize second object, the present invention has adopted following technical scheme:
First in aliphatic amine polyoxyethylene ether diquaternary amine salt, add deionized water, stir it is dissolved, then add successively maleic acid anhydride-propenoic acid-NVP terpolymer and carboxyethyl thiosuccinic acid, finally continue to be stirred to evenly.
The present invention, owing to having adopted technique scheme, with respect to prior art, has the following advantages:
Novel acid soaping agent of the present invention is by special surface active agent aliphatic amine polyoxyethylene ether biquaternary and superpolymer is composite forms, and raw material is easy to get, and this product has extremely strong dispersion and sequestering power, and hydrolysed reactive dye and free reactive dyestuffs are had to extremely strong avidity.This product application is in the aftertreatment technology of soaping of cotton fabrics dyed with reactive dyes, not only can reduce production process, reduce water consumption, significantly improve the dyefastness of fabric, and there is good anti-staining effect, under the same terms, can reduce the consumption of soaping agent, the damage of minimizing to fiber is a kind of acid scouring agent of high performance-price ratio.
Embodiment:
Below in conjunction with embodiment, the invention will be further described, and other embodiment that those of ordinary skills obtain under the prerequisite of not making creative work, all in protection scope of the present invention.
The preparation of the two lauryl amine Soxylat A 25-7 bi-quaternary ammonium salts of embodiment 1-1
Two lauryl amine Soxylat A 25-7 715.6g (0.30mol) and biphenyl benzyl dichloride 37.5g (0.15mol) are added in four-hole boiling flask, be warming up to 100 ℃-150 ℃, reaction 4h, be cooled to 50 ℃, add 85.3g deionized water, insulation reaction 10h, obtains brown viscous liquid.
The preparation of embodiment 1-2 maleic acid anhydride-propenoic acid-NVP terpolymer
In being furnished with the four-hole boiling flask of reflux condensing tube, tear drop funnel, add maleic anhydride 50.0g and water 55.0g, being heated to 60 ℃ of-70 ℃ of stirrings, that it is dissolved is completely transparent; Add the NaOH aqueous solution to regulate pH to neutral, continue to heat up, when rising to 80 ℃-90 ℃, drip vinylformic acid 150.0g, NVP 12.5g and ammonium persulfate solution 5.0g simultaneously, within 2-4 hour, be added dropwise to complete, keep 80 ℃ of-90 ℃ of isothermal reaction 6h, reaction finishes, with the NaOH aqueous solution, adjust pH to 3-5, be cooled to 50 ℃, obtain light yellow thick liquid.
The preparation of embodiment 1-3 soaping agent
In four-hole boiling flask, add two lauryl amine Soxylat A 25-7 diquaternary amine salt 100.0g and deionized water 235.0g, be heated to 60 ℃-70 ℃ and stir; Add successively maleic acid anhydride-propenoic acid-NVP terpolymer 150.0g and carboxyethyl thiosuccinic acid 15.0g, continue to stir 30 minutes.Make this and test soaping agent used.
The preparation of embodiment 2-1 double hexadecyl amine Soxylat A 25-7 bi-quaternary ammonium salt
Double hexadecyl amine Soxylat A 25-7 327.8g (0.21mol) and biphenyl benzyl dichloride 42.5g (0.17mol) are added in four-hole boiling flask, be warming up to 100 ℃-150 ℃, reaction 10h, be cooled to 50 ℃, add deionized water 75.0g, insulation reaction 6h, obtains brown viscous liquid.
The preparation of embodiment 2-2 maleic acid anhydride-propenoic acid-NVP terpolymer
In being furnished with the four-hole boiling flask of reflux condensing tube, tear drop funnel, add maleic anhydride 45.0g and water 55.0g, being heated to 70 ℃ of-80 ℃ of stirrings, that it is dissolved is completely transparent; Add the NaOH aqueous solution to regulate pH to neutral, continue to heat up, when rising to 80 ℃-90 ℃, drip vinylformic acid 135.0g, NVP 20.2g and Sodium Persulfate solution 8.0g simultaneously, within 2-4 hour, be added dropwise to complete, keep 80 ℃ of-90 ℃ of isothermal reaction 8h, reaction finishes, with NaOH aqueous solution 157.0g, adjust pH to 3-5, be cooled to 50 ℃, obtain light yellow thick liquid.
The preparation of embodiment 2-3 soaping agent
In four-hole boiling flask, add double hexadecyl amine Soxylat A 25-7 diquaternary amine salt 75.0g and deionized water 215.0g, be heated to 80 ℃ of-85 ℃ of stirrings and make its dissolving; Add successively maleic acid anhydride-propenoic acid-NVP terpolymer 200.0g and carboxyethyl thiosuccinic acid 5.0g, continue to stir 30 minutes.Make this and test soaping agent used.
The preparation of embodiment 3-1 dioctadecylamine Soxylat A 25-7 bi-quaternary ammonium salt
Dioctadecylamine Soxylat A 25-7 287.0g (0.25mol) and biphenyl benzyl dichloride 37.5g (0.15mol) are added in four-hole boiling flask, be warming up to 100 ℃-150 ℃, reaction 10h, be cooled to 50 ℃, add deionized water 97.4g, insulation reaction 6h, obtains brown viscous liquid.
The preparation of embodiment 3-2 maleic acid anhydride-propenoic acid-NVP terpolymer
In being furnished with the four-hole boiling flask of reflux condensing tube, tear drop funnel, add maleic anhydride 45.0g and water 55.0g, being heated to 70 ℃ of-80 ℃ of stirrings, that it is dissolved is completely transparent; Add the NaOH aqueous solution to regulate pH to neutral, continue to heat up, when rising to 80 ℃-90 ℃, drip vinylformic acid 135.0g, NVP 15.7g and Sodium Persulfate solution 8.0g simultaneously, within 2-4 hour, be added dropwise to complete, keep 80 ℃ of-90 ℃ of isothermal reaction 8h, reaction finishes, with the NaOH aqueous solution, adjust pH to 3-5, be cooled to 50 ℃, obtain light yellow thick liquid.
The preparation of embodiment 3-3 soaping agent
In four-hole boiling flask, add dioctadecylamine Soxylat A 25-7 diquaternary amine salt 25.0g and deionized water 325.0g, be heated to 80 ℃ of-85 ℃ of stirrings and make its dissolving; Add successively maleic acid anhydride-propenoic acid-NVP terpolymer 100.0g and carboxyethyl thiosuccinic acid 50.0g, continue to stir 30 minutes.Make this and test soaping agent used.
Claims (9)
1. novel acid is anti-is stained with a soaping agent, it is characterized in that: described acidity prevents that being stained with soaping agent is comprised of aliphatic amine polyoxyethylene ether biquaternary, maleic acid anhydride-propenoic acid-NVP terpolymer, carboxyethyl thiosuccinic acid and water.
2. novel acid according to claim 1 prevents being stained with soaping agent, it is characterized in that: described acidity prevents that being stained with the raw materials used massfraction of soaping agent is: aliphatic amine polyoxyethylene ether biquaternary 5%-20%, maleic acid anhydride-propenoic acid-NVP terpolymer 20%-40% and carboxyethyl thiosuccinic acid 1%-10%, surplus moisturizing to 100%.
3. novel acid as claimed in claim 1 or 2 is anti-is stained with soaping agent, it is characterized in that: the structural formula of described aliphatic amine polyoxyethylene ether biquaternary is:
In formula, R is C
12-C
18saturated straight chain or the alkyl of side chain, general formula is C
ah
2a+1, a=12-18 wherein, m+n=12-50.
4. novel acid according to claim 3 prevents being stained with soaping agent, it is characterized in that: the preparation method of described aliphatic amine polyoxyethylene ether biquaternary is: first aliphatic amine polyoxyethylene ether is reacted to 4h with biphenyl benzyl dichloride at 100 ℃-150 ℃, then be cooled to 50 ℃, finally add deionized water, insulation reaction 10h.
5. novel acid according to claim 4 is anti-is stained with soaping agent, it is characterized in that: the mol ratio of described aliphatic amine polyoxyethylene ether and biphenyl benzyl dichloride is 1:0.5-1:0.8.
6. novel acid according to claim 1 and 2 prevents being stained with soaping agent, it is characterized in that: the preparation method of described maleic acid anhydride-propenoic acid-NVP terpolymer is: first maleic anhydride is dissolved in to water, being heated to 60 ℃ of-80 ℃ of stirrings dissolves it completely, then add the NaOH aqueous solution to regulate pH to neutral, while being warming up to again 80 ℃-90 ℃, drip vinylformic acid, NVP and initiator solution, within 2-4 hour, be added dropwise to complete, at 80 ℃ of-90 ℃ of isothermal reaction 6-8h, finally with the NaOH aqueous solution, adjust pH to 3-5, be cooled to 50 ℃.
7. novel acid according to claim 6 is anti-is stained with soaping agent, and its feature exists: described initiator is one or more mixtures in Potassium Persulphate, Sodium Persulfate, ammonium persulphate.
8. novel acid according to claim 6 is anti-is stained with soaping agent, it is characterized in that: the mass ratio of described vinylformic acid, maleic anhydride and NVP is 6:2:0.5-6:2:0.9.
9. prepare the anti-method of being stained with soaping agent of the novel acid described in any one in claim 1 to 8 for one kind, first in aliphatic amine polyoxyethylene ether diquaternary amine salt, add deionized water, stirring makes its dissolving, then add successively maleic acid anhydride-propenoic acid-NVP terpolymer and carboxyethyl thiosuccinic acid, finally continue to be stirred to evenly.
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106190652A (en) * | 2016-07-21 | 2016-12-07 | 合肥市东方美捷分子材料技术有限公司 | A kind of environment-friendly low-temperature soaping agent |
| CN106609466A (en) * | 2016-12-16 | 2017-05-03 | 吴江市北厍盛源纺织品助剂厂 | Textile refining agent with addition of cocoamidopropyl betaine and preparation method thereof |
| CN106833940A (en) * | 2017-02-10 | 2017-06-13 | 苏州市统业化工有限公司 | Anti- staining laundry detergents, anti-staining liquid detergent and anti-staining laundry cloth |
| CN107057896A (en) * | 2016-12-25 | 2017-08-18 | 常州市鼎日环保科技有限公司 | A kind of preparation method of environment-friendly type releasing soaping agent |
| CN107151929A (en) * | 2017-05-26 | 2017-09-12 | 东莞市博科纺织科技有限公司 | A kind of stamp releasing soaping agent and preparation method thereof |
| CN109810802A (en) * | 2019-01-31 | 2019-05-28 | 余可嘉 | A kind of anti-net detergent of staining silk hair and preparation method thereof |
| CN110499218A (en) * | 2019-09-17 | 2019-11-26 | 黄河三角洲京博化工研究院有限公司 | A kind of efficient and environment-friendly type acid scouring agent and preparation method thereof |
| CN110684144A (en) * | 2019-10-28 | 2020-01-14 | 浙江理工大学上虞工业技术研究院有限公司 | Preparation method of anti-staining soaping agent |
| CN110777020A (en) * | 2019-11-01 | 2020-02-11 | 江门职业技术学院 | Composite washing assistant and preparation method and application thereof |
| CN112593429A (en) * | 2020-12-14 | 2021-04-02 | 浙江理工大学 | Single-season ammonium salt type acid dye anti-staining agent, anti-staining soaping agent and preparation method thereof |
| CN113529444A (en) * | 2021-08-20 | 2021-10-22 | 广东传化富联精细化工有限公司 | White-bottom anti-staining soaping agent for nylon and preparation method thereof |
| CN114232365A (en) * | 2021-12-20 | 2022-03-25 | 广东三兴高新材料科技有限公司 | Method for preparing acidic soaping agent |
| US11292957B2 (en) | 2020-01-21 | 2022-04-05 | King Fahd University Of Petroleum And Minerals | Gemini surfactants containing an arylene linker for clay swelling inhibition |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106190652A (en) * | 2016-07-21 | 2016-12-07 | 合肥市东方美捷分子材料技术有限公司 | A kind of environment-friendly low-temperature soaping agent |
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| CN106609466A (en) * | 2016-12-16 | 2017-05-03 | 吴江市北厍盛源纺织品助剂厂 | Textile refining agent with addition of cocoamidopropyl betaine and preparation method thereof |
| CN107057896A (en) * | 2016-12-25 | 2017-08-18 | 常州市鼎日环保科技有限公司 | A kind of preparation method of environment-friendly type releasing soaping agent |
| CN106833940A (en) * | 2017-02-10 | 2017-06-13 | 苏州市统业化工有限公司 | Anti- staining laundry detergents, anti-staining liquid detergent and anti-staining laundry cloth |
| CN107151929A (en) * | 2017-05-26 | 2017-09-12 | 东莞市博科纺织科技有限公司 | A kind of stamp releasing soaping agent and preparation method thereof |
| CN109810802A (en) * | 2019-01-31 | 2019-05-28 | 余可嘉 | A kind of anti-net detergent of staining silk hair and preparation method thereof |
| CN110499218A (en) * | 2019-09-17 | 2019-11-26 | 黄河三角洲京博化工研究院有限公司 | A kind of efficient and environment-friendly type acid scouring agent and preparation method thereof |
| CN110684144A (en) * | 2019-10-28 | 2020-01-14 | 浙江理工大学上虞工业技术研究院有限公司 | Preparation method of anti-staining soaping agent |
| CN110777020A (en) * | 2019-11-01 | 2020-02-11 | 江门职业技术学院 | Composite washing assistant and preparation method and application thereof |
| US11292957B2 (en) | 2020-01-21 | 2022-04-05 | King Fahd University Of Petroleum And Minerals | Gemini surfactants containing an arylene linker for clay swelling inhibition |
| CN112593429A (en) * | 2020-12-14 | 2021-04-02 | 浙江理工大学 | Single-season ammonium salt type acid dye anti-staining agent, anti-staining soaping agent and preparation method thereof |
| CN113529444A (en) * | 2021-08-20 | 2021-10-22 | 广东传化富联精细化工有限公司 | White-bottom anti-staining soaping agent for nylon and preparation method thereof |
| CN114232365A (en) * | 2021-12-20 | 2022-03-25 | 广东三兴高新材料科技有限公司 | Method for preparing acidic soaping agent |
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Application publication date: 20141008 |