CN104054728A - Bactericidal composition containing famoxadone and propineb - Google Patents
Bactericidal composition containing famoxadone and propineb Download PDFInfo
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- CN104054728A CN104054728A CN201410237724.8A CN201410237724A CN104054728A CN 104054728 A CN104054728 A CN 104054728A CN 201410237724 A CN201410237724 A CN 201410237724A CN 104054728 A CN104054728 A CN 104054728A
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Abstract
The invention relates to a bactericidal composition containing famoxadone and propineb. The effective component of the bactericidal composition is dually compounded through famoxadone and propineb, wherein the weight ratio of the famoxadone and the propineb is (1-50):(50-1), the weight percentage ratio of the effective component famoxadone and the effective component propineb in a preparation is 1%-80%, and the balance is an auxiliary component which is permitted to use and accepted in a pesticide. The dosage form of the bactericidal composition is missible oil, a suspending agent, wettable powder, water, water dispersible granule, an emulsion in water, a microemulsion, a granule and a microcapsule. The famoxadone and propineb containing bactericidal composition disclosed by the invention is mainly used for preventing and controlling the powdery mildew of apples, oranges, pears, grapes, cucumbers, melons, watermelons, pumpkins, strawberries, roses, ornamental plants and cereal crops and the downy mildew of crops, such as vegetables, the grapes, tobaccos and hops.
Description
Technical field
The present invention relates to agriculture chemical compounding technical field, particularly relate to a kind of bactericidal composition that contains nitre benzene bacterium ester and Propineb.
Background technology
Nitre benzene bacterium ester (meptyldinocap, chemical name: 2-is different pungent-4,6-dinitrophenyl-2-butenoate, CAS:131-72-6) is non-internal-absorting miticide, has certain contact bactericidal action simultaneously.This medicine is developed by The Dow Agrosciences, LLC., and nitre benzene bacterium ester is one of isomer with high bioactivity of separating from 6 kinds of isomer of sterilization (mite) agent karathane (dinocap, CAS:39300-45-3).Be mainly used in preventing and treating two spotted spider mite and the powdery mildew of apple, oranges and tangerines, pears, grape, cucumber, muskmelon, watermelon, pumpkin, strawberry, rose and ornamental plants, mulberry tree powdery mildew and eggplant two spotted spider mite are had to good control efficiency, also there is the effect of killing mite ovum simultaneously.
The protective fungicide of the broad spectrum activity that Propineb (propineb, chemical name: acrylic bisdithiocarbamic zinc, No. CAS: 12071-83-9) Beyer Co., Ltd develops.Its bactericidal mechanism is the oxidation that suppresses pyruvic acid in cause of disease thalline.Propineb all has good protective effect, and the disease of powdery mildew, rust and Botrytis is also had to certain inhibitory action the downy mildew of crop such as vegetables, grape, tobacco and lupulus and the morning of tomato and potato, late blight.
Using chemical agent is the most effectively means of controlling plant diseases.But long-term use single chemical bactericide continuously high dose, easily cause the problem such as residual, environmental pollution and resistance to pesticide resistance fungi development of medicament.Reasonably the composite or mixture of chemical bactericide has expansion fungicidal spectrum, improve control efficiency, extend the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce residual, delay the positive feature such as Antifungal resistance and drug-fast generation and development, bactericide compounded is one of the effective method the most addressing the above problem.Exploitation new product bactericide price is constantly soaring, and by contrast, exploitation is efficient with research, composite and the mixture of low toxicity, low-residual has small investment, the lead time is short and be subject to domestic and international attention, and numerous and confused increasing develops dynamics.We filter out nitre benzene bacterium ester and Propineb and carry out compositely on the basis of lab screening and field trial, have obvious synergistic effect.And there is no at present people about the composite bactericidal composition of nitre benzene bacterium ester and Propineb and application reported.
Summary of the invention
Based on above situation, the object of the invention is to provide a kind of new and effective pesticide sterilizing composite.Be mainly used in the downy mildew of the crop such as powdery mildew and vegetables, grape, tobacco and lupulus that prevents and treats apple, oranges and tangerines, pears, grape, cucumber, muskmelon, watermelon, pumpkin, strawberry, rose, ornamental plants and cereal crop etc.
Technical scheme of the present invention realizes by following measures:
A bactericidal composition that contains nitre benzene bacterium ester and Propineb, active ingredient nitre benzene bacterium ester and two yuan of the Propinebs of this bactericidal composition are composite, and all the other are auxiliary element.In wherein said bactericidal composition, the mass ratio of active ingredient nitre benzene bacterium ester and Propineb is 1～50: 50～1, described bactericidal composition of the present invention is through toxicity test experimental verification, the mass ratio of nitre benzene bacterium ester and Propineb is 1～10: 10～1 o'clock, and synergistic effect is better.
The formulations of pesticide that described bactericidal composition of the present invention can be prepared are missible oil, suspending agent, wetting powder, aqua, water dispersible granules, aqueous emulsion, microemulsion, granule, microcapsule formulations.Wherein active ingredient nitre benzene bacterium ester and the gross mass of Propineb in preparation account for 1%～80% of the whole quality of the pharmaceutical preparations, while wherein accounting for 10%～60%, and toxicity and residually reach good balance, cost is also lower.
The specific embodiments of the formulations of pesticide that bactericidal composition of the present invention is mixed with is as follows:
Described bactericidal composition is cream preparation, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of Propineb; 10～30 parts of conventional emulsifiers; 20～50 parts of conventional solvents; 1～5 part of conventional synergist.The concrete production stage of this cream preparation is first active ingredient nitre benzene bacterium ester and Propineb to be added in solvent to the oily liquids that becomes transparent and homogeneous after adding again emulsifier, synergist to stir after dissolving completely, filling, can be made into the cream preparation of the present composition.
Described bactericidal composition is suspending agent, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of Propineb; 5～20 parts of dispersants; 1～5 part of antifreezing agent; 0.1～2 part of thickener; 0.1～0.8 part of defoamer; 0～10 part of penetrating agent; 0.1～5 part of pH value conditioning agent; Water, surplus.The concrete production stage of this suspending agent is for first mixing other auxiliary agents, mix through high speed shear, add active ingredient nitre benzene bacterium ester and Propineb, abrading-ball 2～3 hours in ball crusher, make a diameter all below 5mm, can be made into the suspending agent preparation of the present composition.
Described bactericidal composition is wetting powder, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of Propineb; 3～10 parts of dispersants; 1～5 part of wetting agent; Filler, surplus.The concrete production stage of this wetting powder is: by above-mentioned formula, active ingredient nitre benzene bacterium ester is mixed with Propineb and dispersant, wetting agent and filler, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, can be made into the wetting powder of the present composition.
Described bactericidal composition is water dispersible granules, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of Propineb; 3～10 parts of dispersants; 1～10 part of wetting agent; 1～5 part of disintegrant; Filler, surplus.The concrete production stage of this water dispersible granules is: by above-mentioned formula, active ingredient nitre benzene bacterium ester is mixed with Propineb and dispersant, wetting agent, disintegrant and filler, pulverize with micro jet, through mediating, then add and in fluidized bed prilling dryer, carry out after granulation, dry, screening, through sample analysis, can be made into the water dispersible granules of the present composition.
Described bactericidal composition is aqueous emulsion, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of Propineb; 3～30 parts of emulsifier; 5～15 parts of solvents; 2～15 parts of stabilizing agents; 1～5 part of antifreezing agent; 0.1～8 part of defoamer; 0.2～2 part of thickener; Water, surplus.The concrete production stage of this aqueous emulsion is: first nitre benzene bacterium ester and Propineb, solvent and emulsifier, cosolvent are added together, make to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes into uniform water; When reactor high speed stirs, oil phase is added to water, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type, can be made into the aqueous emulsion of the present composition.
Described bactericidal composition is microemulsion, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of Propineb; 10～30 parts of emulsifier, 1～8 part of antifreezing agent, 0.5～10 part of stabilizing agent, 20～50 parts of conventional solvent cosolvents.Nitre benzene bacterium ester and Propineb are dissolved completely with cosolvent, then add other compositions such as emulsifier, antifreezing agent stabilizing agent, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
Described bactericidal composition is granule, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of Propineb; 1～10 part of wetting dispersing agent; 0.1～5 part of thickener; 0.1～5 part of defoamer; Castor oil, surplus is supplied.Each components such as active ingredient nitre benzene bacterium ester and Propineb, dispersant, stabilizing agent, defoamer and solvent are mixed in the ratio of formula, put into after the grinding of sand milling still, send in mixer for well-distribution and mix and get product.
Described bactericidal composition is aqua, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of Propineb; 0.1～30 part of wetting dispersing agent; 2～8 parts of antifreezing agents; 0.1～1 part of defoamer; 0.1～3 part of thickener; 5～15 parts of spreader-stickers; Water, surplus is supplied.Dissolve completely by active ingredient nitre benzene bacterium ester and Propineb, with cosolvent, then add other compositions such as dispersant, antifreezing agent, defoamer, evenly mix, finally add water, after fully stirring, get final product to obtain finished product.
Described bactericidal composition is microcapsule formulations, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of Propineb; 5～20 parts, urea; 5～20 parts, formaldehyde; 5～20 parts of emulsifying dispersants; 1～5 part of antifreezing agent; 0.1～2 part of thickener; 0.1～0.8 part of defoamer; Water, surplus.In the there-necked flask that agitating device is housed, add urea and formaldehyde (amount of substance ratio is about l:1.5～2.0), with the left and right, pH value to 8～9 of sodium hydroxide solution regulator solution, then be warming up to 70～80 DEG C, reaction obtains stable urea resin prepolymer.Get a certain amount of nitre benzene bacterium ester and Propineb and be dissolved in cyclohexane, and add emulsifying dispersant in solution, follow vigorous stirring, be made into the O/W type stable emulsion taking the aqueous solution containing emulsifying dispersant as water.Above-mentioned urea resin prepolymer is added in emulsion, regulate pH value, polymerization reaction take place under acid catalysis condition, is wrapped oil phase substance, forms microcapsule granule.Slowly heat up, solidify, temperature is controlled at 40～50 DEG C, hardening time 1h.Selection adds appropriate auxiliary agent, the microcapsules that gets final product stablely.
Wherein above-described emulsifier is selected from calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, any or more than one any mixtures than forming in polyoxyethylene aliphatic alcohol ether.
Described solvent is dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine-based vegetable oil code name is ND-45, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), one or more in water equal solvent are arbitrarily than the mixture of composition.
It is LG-3, GY-D1252, GY-D1256, SNWGF-01 that described dispersant is selected from polycarboxylate code name, lignosulfonates code name is 201107,201108, alkylphenol polyoxyethylene methyl ether condensate sulfate, alkylsulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, polyoxyethylene carboxylate, aliphatic amine polyoxyethylene ether, one or more in fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, Nekal BX, moistening bleeding agent F, alkylbenzenesulfonate polyoxyethylene triphen phosphenylic acid salt dimly, spaonin powder, silkworm excrement, one or more in soapberry powder.
Described disintegrant is selected from bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, one or more in sodium bicarbonate.
Described thickener is selected from xanthans, carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose, Magnesiumaluminumsilicate, in polyvinyl alcohol one or more.
Described stabilizing agent is selected from sodium citrate, the one in resorcinol.
Described antifreezing agent is selected from ethylene glycol, propane diols, one or more in glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10one or more of fatty alcohol.
Described filler is selected from kaolin, diatomite, bentonite, attapulgite, white carbon, starch, one or more in precipitated calcium carbonate.
The present invention has obvious synergistic effect taking nitre benzene bacterium ester and Propineb as the composite bactericide of active ingredient, delay the drug-fast generation in key, and reduced to become to produce cost and use cost, be mainly used in the downy mildew of the crop such as powdery mildew and vegetables, grape, tobacco and lupulus that prevents and treats apple, oranges and tangerines, pears, grape, cucumber, muskmelon, watermelon, pumpkin, strawberry, rose, ornamental plants and cereal crop etc.
Embodiment
For making technical scheme of the present invention, object and advantage are clearer, and the present invention describes with following specific embodiment, but the present invention is not limited to these examples.The mode that effect experiment of the present invention adopts indoor biometrics and field trial to combine, if no special instructions, the ratio of below mentioning is all ratio of quality and the number of copies.
Embodiment: nitre benzene bacterium ester proportioning co-toxicity experiments different from Propineb.
1.1 reagent agent
The former medicine of 98% Propineb, the former medicine of 95% nitre benzene bacterium ester, above-mentioned former medicine provides by research and development department of extra large rel medicine company limited company.
1.2 test targets
Wheat powdery mildew germ, separation and purification gained the wheat powdery mildew incidence of leaf taking back from Fengyang County is cultivated and is preserved in 4 DEG C of refrigerators on PDA inclined-plane.
For examination medium
:
PDA medium
:potato 200g, glucose 20g, agar 20g, water 1000ml.
AEA medium
:dusty yeast 5g/L, glycerine 20mL/L, MgSO
40.25g/L, NaNO
36g/L, KCl 0.5g/L, KH
2pO
41.5g/L, agar powder 20g/L, deionized water 1L.
1.3 test method
1.3.1 medicament preparation
First use the former medicine of acetone solution, according to the result of preliminary experiment, two appropriate former medicines are made into several different proportionings, then it is stand-by with acetone, each processing to be diluted to respectively to several concentration gradients.
Susceptible wheat cultivation, in pot for growing seedlings, is placed in to greenhouse and cultivates, and plant grows to three to four leaf after dates, gathers the blade of identical leaf age, for cultivation and the mensuration of wheat powdery mildew.
1.3.2 the cultivation of wheat powdery mildew and the preparation of spore suspension
Wheat powdery mildew adopts plants method to cultivate under 20 DEG C, the condition of 12h alternation of light and darkness, and every 30 d turn culture 1 time.When inoculation, with the conidium on sterile water wash-out incidence of leaf, being mixed with spore concentration is l × 10
6the suspension of individual/mL.
1.3.3 strains tested sensitivity testing
Adopt leaf dish moisturizing method to carry out toxicity test.First the blade of collection is prepared into the leaf dish that diameter is 1.5cm, mix at random, be placed in respectively the series concentration liquid configuring and soak lh, 50 leaf dishes of each concentration, test is with the blank that is treated to of adding medicine not, after immersion finishes, leaf faces up and puts on the wetting blotting paper of identical liquor strength, liquid on leaf dish is blotted, the spore suspension l0L preparing is inoculated in to leaf dish central authorities, and room temperature is placed after 5 min, is placed under 20 DEG C, the condition of 1 2h alternation of light and darkness and cultivates, after 10d, measure the onset area on leaf dish, calculate EC
50.
The percentage that accounts for leaf disc area according to lesion area is divided sick level
0 grade: anosis;
1 grade: sorus area accounts for below 5% of whole leaf area;
3 grades: sorus area accounts for below the 6%-10% of whole leaf area;
5 grades: sorus area accounts for below the 11%-20% of whole leaf area;
7 grades: sorus area accounts for below the 21%-50% of whole leaf area;
9 grades: sorus area accounts for the more than 50% of whole leaf area.
1.3.4 mixture toxicity test and interpretation of result
Carry out the toxicity test of mixture according to mixed ratio by single dose toxicity test method.
If contrast lethality <5%, does not proofread and correct, contrast lethality, between 5%-20%, is proofreaied and correct by formula 2, contrast lethality >20%, and test need be reformed.
Taking the logarithm value of drug concentration (mg/L) as independent variable x, taking the probability value of corrected mortality as dependent variable y, set up respectively virulence regression equation formula, adopt DPS software to calculate the EC of single dose and each proportioning mixture
50calculate co-toxicity coefficient (CTC) according to the abundant method of Sun Yun.Co-toxicity coefficient CTC, computing formula is as follows: (taking nitre benzene bacterium ester as standard medicament, its toxicity index is 100):
The EC of toxicity index (TI)=nitre benzene bacterium ester of Propineb
50the EC of/Propineb
50× 100
The EC of true toxicity index (ATI)=nitre benzene bacterium ester of M
50the EC of/M
50× 100
TI × P Propineb of TI × P nitre benzene bacterium ester+Propineb of theoretical toxicity index (TTI)=nitre benzene bacterium ester of M
TTI × 100 of the ATI/M of co-toxicity coefficient (CTC)=M of M
In formula:
M is nitre benzene bacterium ester and the mixture of the different proportionings of Propineb
P nitre benzene bacterium ester is nitre benzene bacterium ester shared ratio in mixture
P Propineb is Propineb shared ratio in mixture.
2.1 toxicity test results
Table 1 Propineb and the toxicity test of nitre benzene bacterium ester to wheat powdery mildew
As can be seen from the table, the result of the test of different proportion proportioning shows, dilute respectively and all show stronger synergistic effect in active ingredient ratio, wherein taking nitre benzene bacterium ester and Propineb as 1:10～10:1 time the good suggestion of synergistic effect suitable proportion 1:10～10:1 left and right mixture preparation is carried out to further field control effectiveness test, to evaluate its field practical application effect.
3, field trial control wheat powdery mildew, the experimental result of powdery mildew of cucumber
3.1 field trial control wheat powdery mildews
3.1.1 test method
Test site, in great Tong Qiao village, capital town, Fengyang County, is wheat for studying thing, and kind is short morning 781, broadcasts sowing, and growing way is better, and test is established every mu and established contrast totally 10 processing.Every processing repeats 4 times, and random district group is arranged, 30 square metres of community areas.
3.1.2 control time and number of times
Before dispenser, after the 1st medicine after 10 days and the 2nd dispenser 10 days, 20 days, every community adopted 5 samplings of diagonal, every some investigation 20 strains, before blooming, 2 leaves are got in every strain from upper end, after blooming, sword-like leave 2 leaves are got in every strain, by leaf classification investigation occurring degree, calculate disease and refer to and control efficiency.
Grade scale is as follows:
0 grade: anosis;
1 grade: lesion area accounts for below 5% of one-piece blade area;
3 grades: lesion area accounts for the 6%-15% of one-piece blade area;
5 grades: lesion area accounts for the 16%-25% of one-piece blade area;
7 grades: lesion area accounts for the 26%-50% of one-piece blade area;
9 grades: lesion area accounts for the more than 50% of one-piece blade area.
3.1.3 drug effect computational methods
The total number of sheets × 100 of sick leaf rate (%)=sick number of sheets/investigate
Disease index=∑ (the sick number of sheets × relative level numerical value at different levels)/(investigating the total number of sheets × 9) × 100
Control efficiency (%)=(disease index after the front disease index × treatment region medicine of 1-(blank district medicine)/(the front disease index of disease index × treatment region medicine after blank district medicine)) × 100.
3.1.4 poisoning investigation method
After dispenser, whether 20d range estimation medicament has poisoning to crop continuously.
3.1.5 result of the test and analysis
Each effect of processing control wheat powdery mildew.(table 2)
As shown in Table 2 20% nitre benzene bacterium ester Propineb composite bactericide for wheat powdery mildew control successful higher than nitre benzene bacterium ester and Propineb single dose, bactericidal effect increases progressively with the increase of dosage.According to field range estimation, within the scope of test dose, plant growth is normal, and the poisoning phenomenon to wheat does not all appear in each treatment agent, illustrates that it is safe to wheat.Advise that the bactericide different from the mechanism of action mixes use to delay the drug-fast generation of germ.
3.2 field trials are prevented and treated powdery mildew of cucumber
3.2.1 test method
Test site, in the Pingdu herbary of Shandong, is cucumber for examination vegetables, and growing way is better, and test is established every mu and established contrast totally 10 processing.Every processing repeats 4 times, and random district group is arranged, 14 square metres of community areas.
3.2.2 control time and number of times
Before dispenser, after the 1st medicine after 10 days and the 2nd dispenser 10 days, 20 days, every community adopted 5 samplings of diagonal, every some investigation 2 strains, and totally 10 strains, investigation complete stool blade, by leaf classification investigation occurring degree, calculates disease and refers to and control efficiency.
Grade scale is as follows:
0 grade: anosis;
1 grade: lesion area accounts for below 5% of one-piece blade area;
3 grades: lesion area accounts for the 6%-15% of one-piece blade area;
5 grades: lesion area accounts for the 16%-25% of one-piece blade area;
7 grades: lesion area accounts for the 26%-50% of one-piece blade area;
9 grades: lesion area accounts for the more than 50% of one-piece blade area.
3.2.3 drug effect computational methods
The total number of sheets × 100 of sick leaf rate (%)=sick number of sheets/investigate
Disease index=∑ (the sick number of sheets × relative level numerical value at different levels)/(investigating the total number of sheets × 9) × 100
Control efficiency (%)=(disease index after the front disease index × treatment region medicine of 1-(blank district medicine)/(the front disease index of disease index × treatment region medicine after blank district medicine)) × 100.
3.2.4 poisoning investigation method
After dispenser, whether 20d range estimation medicament has poisoning to crop continuously.
3.2.5 result of the test and analysis
Each effect of preventing and treating powdery mildew of cucumber of processing.(table 3)
The Mixed Pharmacy of different proportion as can be seen from Table 3, tests by different consumptions, and 20% its right control of nitre benzene bacterium ester Propineb composite bactericide is all better than contrasting medicament and bactericidal effect increases progressively with the increase of dosage.According to field range estimation, within the scope of test dose, plant growth is normal, and the poisoning phenomenon to cucumber does not all appear in each treatment agent, illustrates that it is safe to cucumber.Advise that the bactericide different from the mechanism of action mixes use to delay the drug-fast generation of germ.
In sum, the bactericidal composition that the present invention contains nitre benzene bacterium ester and Propineb, has good control efficiency to wheat powdery mildew, powdery mildew of cucumber, and it is to target crop safety.Complex preparation has not only improved preventive effect, and has expanded fungicidal spectrum, widens the scope of application, reduces costs, and multiple diseases is played to the double effect of controlling of a medicine, alleviates manpower and materials, improves productivity effect.So the invention of this complex preparation is of great significance social tool with popularization.
Claims (4)
1. a bactericidal composition that contains nitre benzene bacterium ester and Propineb, it is characterized in that: the active ingredient of this bactericidal composition is nitre benzene bacterium ester and Propineb binary built, all the other are auxiliary element, and wherein the mass ratio of active ingredient nitre benzene bacterium ester and Propineb is 1～50: 50～1.
2. bactericidal composition according to claim 1, is characterized in that: nitre benzene bacterium ester and the gross weight of Propineb in preparation account for 1%～80% of the whole quality of the pharmaceutical preparations.
3. bactericidal composition according to claim 2, is characterized in that: nitre benzene bacterium ester and the gross weight of Propineb in preparation account for 5%～60% of the whole quality of the pharmaceutical preparations.
4. according to the bactericidal composition described in claim 1 or 2 or 3, it is characterized in that: the formulation of this bactericidal composition is missible oil, suspending agent, aqua, wetting powder, water dispersible granules, aqueous emulsion, microemulsion, granule, microcapsule formulations
.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1257407A (en) * | 1997-05-22 | 2000-06-21 | 巴斯福股份公司 | Fungicidal mixtures |
| WO2005022999A2 (en) * | 2003-09-08 | 2005-03-17 | Agrichem Ltd. | Pesticidal compositions containing dinocap |
| CN1889840A (en) * | 2003-12-10 | 2007-01-03 | 巴斯福股份公司 | Fungicidal mixtures |
| WO2011056463A2 (en) * | 2009-11-04 | 2011-05-12 | E. I. Du Pont De Nemours And Company | Fungicidal mixtures |
-
2014
- 2014-05-31 CN CN201410237724.8A patent/CN104054728A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1257407A (en) * | 1997-05-22 | 2000-06-21 | 巴斯福股份公司 | Fungicidal mixtures |
| WO2005022999A2 (en) * | 2003-09-08 | 2005-03-17 | Agrichem Ltd. | Pesticidal compositions containing dinocap |
| CN1889840A (en) * | 2003-12-10 | 2007-01-03 | 巴斯福股份公司 | Fungicidal mixtures |
| WO2011056463A2 (en) * | 2009-11-04 | 2011-05-12 | E. I. Du Pont De Nemours And Company | Fungicidal mixtures |
Non-Patent Citations (1)
| Title |
|---|
| CIGLAR, IVAN等: "Importance of side effects of pesticides in pomology", 《JUGOSLOVENSKO VOCARSTVO》 * |
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Application publication date: 20140924 |