CN104026149B - Agriculturally useful compositions containing sulphur Yu organophosphor insecticidal constituent - Google Patents
Agriculturally useful compositions containing sulphur Yu organophosphor insecticidal constituent Download PDFInfo
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- CN104026149B CN104026149B CN201410311995.3A CN201410311995A CN104026149B CN 104026149 B CN104026149 B CN 104026149B CN 201410311995 A CN201410311995 A CN 201410311995A CN 104026149 B CN104026149 B CN 104026149B
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- sulphur
- useful compositions
- agriculturally useful
- insecticidal constituent
- organophosphor
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- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 53
- 239000005864 Sulphur Substances 0.000 title claims abstract description 52
- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 239000000470 constituent Substances 0.000 title claims abstract description 15
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- 241000607479 Yersinia pestis Species 0.000 claims abstract description 19
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- DUFVKSUJRWYZQP-UHFFFAOYSA-N fosthiazate Chemical compound CCC(C)SP(=O)(OCC)N1CCSC1=O DUFVKSUJRWYZQP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000008187 granular material Substances 0.000 claims abstract description 6
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- 239000012752 auxiliary agent Substances 0.000 description 1
- CJPQIRJHIZUAQP-MRXNPFEDSA-N benalaxyl-M Chemical compound CC=1C=CC=C(C)C=1N([C@H](C)C(=O)OC)C(=O)CC1=CC=CC=C1 CJPQIRJHIZUAQP-MRXNPFEDSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 description 1
- 230000000035 biogenic effect Effects 0.000 description 1
- GAMFEMAXLMWCRG-UHFFFAOYSA-N bis(dimethylcarbamothioylsulfanyl)arsanyl n,n-dimethylcarbamodithioate Chemical compound CN(C)C(=S)S[As](SC(=S)N(C)C)SC(=S)N(C)C GAMFEMAXLMWCRG-UHFFFAOYSA-N 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- HJJVPARKXDDIQD-UHFFFAOYSA-N bromuconazole Chemical compound ClC1=CC(Cl)=CC=C1C1(CN2N=CN=C2)OCC(Br)C1 HJJVPARKXDDIQD-UHFFFAOYSA-N 0.000 description 1
- 229940117949 captan Drugs 0.000 description 1
- 239000000073 carbamate insecticide Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000006013 carbendazim Substances 0.000 description 1
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 1
- IRUJZVNXZWPBMU-UHFFFAOYSA-N cartap Chemical compound NC(=O)SCC(N(C)C)CSC(N)=O IRUJZVNXZWPBMU-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 description 1
- UISUNVFOGSJSKD-UHFFFAOYSA-N chlorfluazuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1Cl)=CC(Cl)=C1OC1=NC=C(C(F)(F)F)C=C1Cl UISUNVFOGSJSKD-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 229940127108 compound 5g Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
- CWVRPJSBNHNJSI-XQNSMLJCSA-N coumoxystrobin Chemical compound C1=C2OC(=O)C(CCCC)=C(C)C2=CC=C1OCC1=CC=CC=C1\C(=C/OC)C(=O)OC CWVRPJSBNHNJSI-XQNSMLJCSA-N 0.000 description 1
- YXKMMRDKEKCERS-UHFFFAOYSA-N cyazofamid Chemical compound CN(C)S(=O)(=O)N1C(C#N)=NC(Cl)=C1C1=CC=C(C)C=C1 YXKMMRDKEKCERS-UHFFFAOYSA-N 0.000 description 1
- 230000035613 defoliation Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 description 1
- 229940019503 diflubenzuron Drugs 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- AWZOLILCOUMRDG-UHFFFAOYSA-N edifenphos Chemical compound C=1C=CC=CC=1SP(=O)(OCC)SC1=CC=CC=C1 AWZOLILCOUMRDG-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 1
- LMVPQMGRYSRMIW-KRWDZBQOSA-N fenamidone Chemical compound O=C([C@@](C)(N=C1SC)C=2C=CC=CC=2)N1NC1=CC=CC=C1 LMVPQMGRYSRMIW-KRWDZBQOSA-N 0.000 description 1
- RLQJEEJISHYWON-UHFFFAOYSA-N flonicamid Chemical compound FC(F)(F)C1=CC=NC=C1C(=O)NCC#N RLQJEEJISHYWON-UHFFFAOYSA-N 0.000 description 1
- RYLHNOVXKPXDIP-UHFFFAOYSA-N flufenoxuron Chemical compound C=1C=C(NC(=O)NC(=O)C=2C(=CC=CC=2F)F)C(F)=CC=1OC1=CC=C(C(F)(F)F)C=C1Cl RYLHNOVXKPXDIP-UHFFFAOYSA-N 0.000 description 1
- GBOYJIHYACSLGN-UHFFFAOYSA-N fluopicolide Chemical compound ClC1=CC(C(F)(F)F)=CN=C1CNC(=O)C1=C(Cl)C=CC=C1Cl GBOYJIHYACSLGN-UHFFFAOYSA-N 0.000 description 1
- FQKUGOMFVDPBIZ-UHFFFAOYSA-N flusilazole Chemical compound C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 FQKUGOMFVDPBIZ-UHFFFAOYSA-N 0.000 description 1
- PTCGDEVVHUXTMP-UHFFFAOYSA-N flutolanil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C(F)(F)F)=C1 PTCGDEVVHUXTMP-UHFFFAOYSA-N 0.000 description 1
- HKIOYBQGHSTUDB-UHFFFAOYSA-N folpet Chemical compound C1=CC=C2C(=O)N(SC(Cl)(Cl)Cl)C(=O)C2=C1 HKIOYBQGHSTUDB-UHFFFAOYSA-N 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- ZXQYGBMAQZUVMI-GCMPRSNUSA-N gamma-cyhalothrin Chemical compound CC1(C)[C@@H](\C=C(/Cl)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-GCMPRSNUSA-N 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- RGNPBRKPHBKNKX-UHFFFAOYSA-N hexaflumuron Chemical compound C1=C(Cl)C(OC(F)(F)C(F)F)=C(Cl)C=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F RGNPBRKPHBKNKX-UHFFFAOYSA-N 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- VBCVPMMZEGZULK-NRFANRHFSA-N indoxacarb Chemical compound C([C@@]1(OC2)C(=O)OC)C3=CC(Cl)=CC=C3C1=NN2C(=O)N(C(=O)OC)C1=CC=C(OC(F)(F)F)C=C1 VBCVPMMZEGZULK-NRFANRHFSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229960002418 ivermectin Drugs 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229960000521 lufenuron Drugs 0.000 description 1
- PWPJGUXAGUPAHP-UHFFFAOYSA-N lufenuron Chemical compound C1=C(Cl)C(OC(F)(F)C(C(F)(F)F)F)=CC(Cl)=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F PWPJGUXAGUPAHP-UHFFFAOYSA-N 0.000 description 1
- 229940041033 macrolides Drugs 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- ZQEIXNIJLIKNTD-GFCCVEGCSA-N metalaxyl-M Chemical compound COCC(=O)N([C@H](C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-GFCCVEGCSA-N 0.000 description 1
- XWPZUHJBOLQNMN-UHFFFAOYSA-N metconazole Chemical compound C1=NC=NN1CC1(O)C(C)(C)CCC1CC1=CC=C(Cl)C=C1 XWPZUHJBOLQNMN-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 229940079888 nitenpyram Drugs 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 description 1
- 244000039328 opportunistic pathogen Species 0.000 description 1
- 239000003986 organophosphate insecticide Substances 0.000 description 1
- UWVQIROCRJWDKL-UHFFFAOYSA-N oxadixyl Chemical compound CC=1C=CC=C(C)C=1N(C(=O)COC)N1CCOC1=O UWVQIROCRJWDKL-UHFFFAOYSA-N 0.000 description 1
- 150000002916 oxazoles Chemical class 0.000 description 1
- WBTYBAGIHOISOQ-UHFFFAOYSA-N pent-4-en-1-yl 2-[(2-furylmethyl)(imidazol-1-ylcarbonyl)amino]butanoate Chemical compound C1=CN=CN1C(=O)N(C(CC)C(=O)OCCCC=C)CC1=CC=CO1 WBTYBAGIHOISOQ-UHFFFAOYSA-N 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 description 1
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 description 1
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 description 1
- QHMTXANCGGJZRX-WUXMJOGZSA-N pymetrozine Chemical compound C1C(C)=NNC(=O)N1\N=C\C1=CC=CN=C1 QHMTXANCGGJZRX-WUXMJOGZSA-N 0.000 description 1
- URXNNPCNKVAQRA-XMHGGMMESA-N pyraoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1COC1=CC(C=2C=CC(Cl)=CC=2)=NN1C URXNNPCNKVAQRA-XMHGGMMESA-N 0.000 description 1
- 150000003217 pyrazoles Chemical class 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011593 sulfur Chemical group 0.000 description 1
- 229910052717 sulfur Chemical group 0.000 description 1
- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 1
- BAKXBZPQTXCKRR-UHFFFAOYSA-N thiodicarb Chemical compound CSC(C)=NOC(=O)NSNC(=O)ON=C(C)SC BAKXBZPQTXCKRR-UHFFFAOYSA-N 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- WPALTCMYPARVNV-UHFFFAOYSA-N tolfenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(OC=3C=CC(C)=CC=3)=CC=2)=C1Cl WPALTCMYPARVNV-UHFFFAOYSA-N 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
- AMHNZOICSMBGDH-UHFFFAOYSA-L zineb Chemical compound [Zn+2].[S-]C(=S)NCCNC([S-])=S AMHNZOICSMBGDH-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to plant protection art, the agriculturally useful compositions more particularly to containing sulphur Yu organophosphor insecticidal constituent, the quality parts ratio of sulphur and organophosphor insecticidal constituent is 0.1 200:1, organic phosphates insecticidal constituent is the one kind in fosthiazate, isazofos, chlopyrifos, phoxim and Profenofos.Agriculturally useful compositions of the invention can improve sterilized or Insecticiding-miticiding effect, can be processed into granule, suspending agent etc., prevent and treat the pest and disease damage of multiple kinds of crops, it is especially useful in preventing and treating crop nematode, red spider or blister mite etc..
Description
The application is the divisional application of " agriculturally useful compositions containing sulphur " application for a patent for invention, original application day：2013 7
The moon 26, application number：2013103193571.
Technical field
The invention belongs to plant protection art, the more particularly to agriculturally useful compositions containing sulphur and application.
Background technology
In agricultural production, crop disease and insect gradually strengthens the resistance to the action of a drug of Pesticidal products, and, the disease pest of same crop
Evil often occurs simultaneously, and peasant often attends to one thing and lose sight of another in independent pest control or disease, not only delays work and miss preventing and treating opportunity,
So as to increase dosage etc. again.Due to single and not Scientific Usage of Drugs, cause peasant's cost improve, environmental pollution and ecological environment
Destruction etc..Compounded, and rationally added auxiliary agent with different structure, the different mechanisms of action, environmentally friendly active component
New agriculturally useful compositions are made, are to reduce prevent and treat target, raising drug effect with delaying drug resistance insect, expansion, reduce having for environmental pollution
Effect approach.
Sulphur is an important kind in inorganic pesticide.Commodity are yellow solid or powder, there is obvious smell, can be waved
Hair.Sulphur aqueous suspensions are in subacidity, water insoluble.Sulphur belongs to multipurpose agent, in addition to having bactericidal action, moreover it is possible to mite killing, desinsection,
With fertilizer efficiency, to people, animal safety, it is difficult to make crop produce poisoning.
Inventor has carried out the test of pesticide effectiveness of a large amount of sulphur and other farm chemical ingredients, it was found that many unexpected effects
Really.The invention improves drug effect and expansion preventing and treating target, is imitated beneficial to reducing times for spraying, reducing agriculture sheet and improving agricultural product economy
Benefit.
The content of the invention
It is an object of the invention to provide a kind of agriculturally useful compositions containing sulphur, drug effect is improved, expanded preventing and treating target, had
Fertilizer efficiency.
The present invention provides a kind of agriculturally useful compositions containing sulphur, and another or two kinds are also contained in the agriculturally useful compositions
The quality parts ratio of farm chemical ingredients, sulphur and farm chemical ingredients is 0.1-200:1, it is preferred that quality parts ratio is 1-100:1.
The present invention provides a kind of agriculturally useful compositions containing sulphur, and another or two kinds are also contained in the agriculturally useful compositions
The quality parts ratio of farm chemical ingredients, sulphur and farm chemical ingredients is 0.1-200:1, it is preferred that quality parts ratio is 1-100:1.On
In stating composition, farm chemical ingredients be methoxy acrylic composition orysastrobin, pyraclostrobin, trifloxystrobin, ZEN 90160,
One kind in alkene oxime amine, ZJ0712, SSF 126, SYP-3375, pyraoxystrobin, 2-cyano-3-amino-3-phenylancryic acetate, or triazole type sterilization component
Tebuconazole, propiconazole, Difenoconazole, nitrile bacterium azoles, Flusilazole, triazolone, bromuconazole, hexaconazole, metconazole, Triadimenol, fluorine
One kind in ring azoles, tetraconazole, triticonazole, or sulfur-bearing class sterilization component zineb, S-Ethyl ethylthio sulfonate, Propineb, Carbatene, hundred bacterium
Clearly, in carbendazim, thiophanate-methyl, thiram, asomate, captan, folpet, sulfonat, fenaminosulf, ambam
Kind, or the one kind in miazines sterilization component cyprodinil, fluorine mepanipyrim, mepanipyrim, or many anti-mildews of biogenic substances sterilization component
In one kind in element, jinggangmeisu, kasugarnycin, Zhongshengmycin, or organic phosphates sterilization component IBP, edifenphos one
Kind, or in amide-type sterilization component dimethomorph, zoxamide, mefenoxam, benalaxyl-M, fluopicolide one
Kind, or one kind in imidazoles sterilization component Prochloraz, cyazofamid, Fenamidone, pefurazoate, or oxazole class sterilization Cheng Fen oxazole bacterium
One kind in ketone, Wakil, or for macrolides AVM, emamectin-benzoate (calling emamectin benzoate in the following text),
One kind in ivermectin, pleocidin, or organic phosphates insecticidal constituent fosthiazate, isazofos, chlopyrifos, phoxim and the third bromine
One kind in phosphorus, or anabasine insecticidal constituent Nitenpyram, Diacloden, imidacloprid, Acetamiprid, thiacloprid, MTI-446 and thiophene
One kind in worm amine, or amide-type insecticidal constituent cyanogen insect amide, flutolanil, Tolfenpyrad, flonicamid and chlorine worm benzoyl
One kind in amine, or pyrethroid insecticidal constituent Biphenthrin, ethofenprox, gamma cyhalothrin, effective cypermethrin,
One kind in one kind in cypermethrin and Tefluthrin, or carbamate insecticides Mobucin, thiodicarb, or benzoyl
One kind in urea insecticide HEXAFLUMURON, flufenoxuron, chlorfluazuron, lufenuron, novaluron, d ichlorbenzuron, diflubenzuron and Teflubenzuron, or
Nereistoxin constituents are selected from the one kind in Cupric sulfate, dimehypo, cartap, or other constituents Envidor, Bifenazate, spiral shells
One kind in worm ethyl ester, pyridaben, chlorfenapyr, indoxacarb, pymetrozine.Preferably, above-mentioned farm chemical ingredients are orysastrobin, pyrazoles
Kresoxim-methyl, Tebuconazole, zineb, S-Ethyl ethylthio sulfonate, cyprodinil, polyoxin, AVM, emamectin benzoate, fosthiazate, isazofos,
One kind in Envidor, Bifenazate, spiral shell worm ethyl ester, pyridaben.
Above-mentioned agriculturally useful compositions processing of the invention be configured to suspending agent, granule, wettable powder, water dispersible granules,
Microemulsion or aqueous emulsion, it is preferred that be configured to suspending agent or granule.
Present invention also offers the purposes that above-mentioned agriculturally useful compositions are used for controlling crop diseases and insect pests, the pest and disease damage is white powder
Disease, nematode, rust, downy mildew, epidemic disease, banded sclerotial blight, spot defoliation, canker, red spider, blister mite, trialeurodes vaporariorum, rice fly
Lice, diamondback moth, flea beetle, tea lesser leafhopper, thrips, beet armyworm, rice leaf roller, aphid, scale insect, pachydiplosis oryzae.Preferably,
The pest and disease damage is powdery mildew, nematode, red spider, blister mite.
Composition of the invention compared with prior art, produces following beneficial effect：
(1) agriculturally useful compositions of the invention are significantly improved to crop disease or the effect of insect pest, beneficial to reduce dosage or
Times for spraying；
(2) composition pesticide is expanded using target and effect, and a dispenser can be while pest control and disease, improve
Crop growing state；
(3) because the mechanism of action of active component in composition pesticide is different, according to pest resistance insecticide theory and practice, its
Using resistance development of the pest and disease damage to medicament can be delayed, extend single dose service life.
Specific embodiment
It is as described below to be only used for explaining the present invention, for made without departing from spirit of the invention and principle modification, replace or
Improve, belong to the scope of protection of present invention.
The sulphur Abamectin of embodiment 150%
By sulphur 49.5g, AVM 0.5g, naphthalenesulfonate formaldehyde condensation compound 5g, sodium alkyl benzene sulfonate 5g, fine sand 10g,
Bentonite 30g mixes, by mixture carry out granulation after ultra-fine grinding, dry, screening, be both made 50% sulphur AVM
Granula.
The sulphur tebuconazole suspension concentrates of embodiment 240%
By sulphur 30g, Tebuconazole 10g, sodium lignin sulfonate 3g, tea seed cake powder 5g, bentonite 5g, Magnesiumaluminumsilicate 2g, second two
Alcohol 5g is sufficiently mixed, and the 15g that adds water is fully ground, and water complements to 100g, is configured to 40% sulphur tebuconazole suspension concentrates.
Effect of agriculturally useful compositions of the embodiment 3 containing sulphur to wheat powdery mildew
Single compound or composition are prepared into the suspending agent mother liquor of 1000mg/L.According to trial test, will be a certain amount of
Above-mentioned mother liquor is diluted with 0.1% Tween 80, is configured to the concentration for needing.During measure, liquid medicine jet is first imposed on into potted plant wheat plant,
Then wheat powdery mildew opportunistic pathogen is inoculated with, after moisturizing culture 24h, is placed in greenhouse and is cultivated, plant leaf surface determined after certain hour and is invaded
The percentage of dye.Using Abbot formula, percentage is converted into preventive effect.The results are shown in Table 1.
Effect of agriculturally useful compositions of the table 1 containing sulphur to sterilization component
Agriculturally useful compositions containing sulphur are shown in Table 1 to the effect of wheat powdery mildew.As can be seen that under specific dosage,
Sulphur is combined with orysastrobin, sulphur is combined with pyraclostrobin, sulphur is combined with Tebuconazole, sulphur is combined with zineb, sulphur
Sulphur is combined with S-Ethyl ethylthio sulfonate, sulphur is combined with cyprodinil, sulphur is combined to the effect of wheat powdery mildew compared with it with polyoxin
The effect to wheat powdery mildew of single component is high, and leaf color is greener, and wheat growing way is good, increases beneficial to reducing dosage and increasing production
Receive.
Agriculturally useful compositions of the embodiment 4 containing sulphur prevent and treat the effect of nematode
By taking macrolide constituents AVM, emamectin benzoate and organophosphorus insecticide composition fosthiazate, isazofos as an example, say
Bright sulfureted agriculturally useful compositions prevent and treat the effect of nematode.Compost is mixed into sterilizing river sand with sterilized soil, composition is mixed into
Or the granule of single dose, fully mix thoroughly, add clear water to make water content 40%, load basin alms bowl, growth 20d cotton plants are transplanted to
In basin, 10d after transplanting accesses 2 instar larvae of Meloidogyne incognita 500 per basin, is placed in greenhouse, quantitative watering management.If often locating
3 repetitions of reason, according to trial test, if blank and different single doses, binary mixture treatment.After 30d, when blank plant
When rhizosphere has a large amount of root knots, the average root knot number of every plant of investigation records, and be classified by Liu Weizhi (1995)：0 grade, without root knot；1
Level, 1-2 root knots；2 grades, 3-10 root knot；3 grades, 11-30 root knot；4 grades, 31-100 root knot；5 grades, more than 100 root knots.
The results are shown in Table 2.
Effect of the sulfureted agriculturally useful compositions of table 2 to nematode
The effect of the agriculturally useful compositions preventing and treating nematode containing sulphur is shown in Table 2.As can be seen that under certain medication, sulphur with
AVM is combined, sulphur is combined with emamectin benzoate, sulphur is combined with fosthiazate, sulphur combines equal to cotton root knot number with isazofos
Root knot number compared with its single component is few, and cotton root knot number is respectively 2,3,2,2, and sick level is 1,2,1,1 grade.It can be seen that, contain sulphur
The effect that sulphur any combination thing is closed to the significantly excellent single dose of preventive effect of root-knot nematode.Surprisingly, relative to single component, appoint
Binary combination has promotion to cotton plants, and leaf is green, strong sprout effect.It can be seen that, the agriculturally useful compositions containing sulphur can improve preventing and treating nematode
Effect, and leaf is green, strong sprout effect promotion.
Effect of agriculturally useful compositions of the embodiment 5 containing sulphur to apple pest
By taking mite killing composition Envidor, Bifenazate as an example, the effect of the agriculturally useful compositions to apple pest of sulphur is illustrated.
Red spider on listed branch is investigated in experimental field apple flower later stage listing mark, before dispenser, a situation arises for powdery mildew.It is accurate respectively
Different medicine components is really configured to suspending agent, is diluted before carrying out medicine according to dosing, use manual sprayer even spraying,
1 plant of often treatment spray, and set corresponding medicament control and blank.The generation feelings of each listed treatment red spider of 10d investigation after medicine
Sprayed again after condition 1 time, a situation arises for the listed treatment powdery mildew of 7d investigation after the 2nd medicine, and observes growing way situation.Statistics
It is shown in Table 3.
Effect of agriculturally useful compositions of the table 3 containing sulphur to apple pest
Agriculturally useful compositions containing sulphur are shown in Table 3 to the effect of apple pest.As can be seen that under specific dosage,
Sulphur is combined with Envidor, sulphur is combined with Bifenazate and is above each single dose to the preventive effect of European red mite, apple mildew
Effect, and composition is greener to apple leaf color.
Effect of agriculturally useful compositions of the embodiment 6 containing sulphur to oranges and tangerines pest and disease damage
Later stage listing mark is spent in experimental field oranges and tangerines, powdery mildew, the generation feelings of blister mite on listed branch are investigated before dispenser
Condition.Different medicine components is accurately configured to suspending agent respectively, is diluted before carrying out medicine according to dosing, use manual sprayer
Even spraying, 1 plant of often treatment spray, and set corresponding medicament control and blank.10d investigates each listed treatment blister mite after medicine
Generation quantity after spray again 1 time, a situation arises for the listed treatment powdery mildew of 7d investigation after the 2nd medicine, and observes growing way situation.
Statistics is shown in Table 4.
Effect of agriculturally useful compositions of the table 4 containing sulphur to oranges and tangerines pest and disease damage
Agriculturally useful compositions containing sulphur are shown in Table 4 to the effect of oranges and tangerines pest and disease damage.As can be seen that under specific dosage,
The effect that sulphur is combined with spiral shell worm ethyl ester, sulphur is combined to the effect of oranges and tangerines blister mite compared with its single component with pyridaben is high,
And leaf color is greener, plant growing way is good, beneficial to reduction dosage and increasing both production and income.
Claims (4)
1. the agriculturally useful compositions containing sulphur and organophosphor insecticidal constituent are used for the purposes of controlling crop diseases and insect pests, sulphur and organic
The quality parts ratio of phosphorus insecticidal constituent is 9:1, organic phosphates insecticidal constituent is the one kind in fosthiazate, isazofos.
2. purposes according to claim 1, agriculturally useful compositions processing is configured to suspending agent, granule, wettable powder, moisture and dissipates
Granula, microemulsion or aqueous emulsion.
3. purposes according to claim 2, is configured to suspending agent or granule.
4. purposes according to claim 3, the pest and disease damage is nematode.
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| CN1646019A (en) * | 2002-04-23 | 2005-07-27 | 巴斯福股份公司 | Method for chemically decontaminating soil by applying a mixture of sulphur and complexing agents |
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| CN102934639B (en) * | 2012-11-26 | 2014-02-26 | 海南正业中农高科股份有限公司 | Dithiocyano-methane/organophosphorus pesticide composition |
| CN103141500B (en) * | 2013-03-20 | 2015-06-10 | 海南正业中农高科股份有限公司 | Insect killing and sterilizing composition containing tiadinil |
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Non-Patent Citations (4)
| Title |
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| Effects of chlorpyrifos and sulfur on spider mites（Acari：Tetranychidae）and their natural enemies;Deirdre A. Prischmann et al.，;《Biological Control》;20050407;第33卷;第324-334页 * |
| Efficacy of selected miticides and spray tank mixtures used to control rust mite in Florida citrus;J.E.Eger，JR. et al.,;《Proceedings of the annual meeting of the Florida State Horticultural Society》;19851231;第98卷;第11-14页 * |
| 农用杀菌杀螨剂-50%硫悬浮剂;李范;《农药》;19901231;第29卷(第6期);第46页 * |
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Denomination of invention: Agricultural compound containing sulphur and organophosphorus pest killing constituent Effective date of registration: 20190215 Granted publication date: 20170630 Pledgee: Bank of Hainan Limited by Share Ltd. Pledgor: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. Registration number: 2019460000001 |
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Address after: Fuchang Village, Laocheng Development Zone, Chengmai County, Hainan Province, 571923 Patentee after: Hainan Zhengye Biotechnology Co.,Ltd. Address before: 571924 Fuchang village, Laocheng Development Zone, Chengmai County, Hainan Province Patentee before: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. |