CN104026134B - A kind of wood floors Bactericidal cleaner - Google Patents
A kind of wood floors Bactericidal cleaner Download PDFInfo
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- CN104026134B CN104026134B CN201410233430.8A CN201410233430A CN104026134B CN 104026134 B CN104026134 B CN 104026134B CN 201410233430 A CN201410233430 A CN 201410233430A CN 104026134 B CN104026134 B CN 104026134B
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Abstract
The present invention relates to a kind of wood floors Bactericidal cleaner, belong to cleaning supplies technical field.It is made up of raw material: water, N-(2,6-dioxo-3-piperidyl)-phthalimide, (2-ethoxy) diisopropyl methyl bromide ammonium cluck ton-9-carboxylate, 2-(acetoxyl group) benzoic acid, diphenyl acetic acid 2-(diethylamino) ester hydrochloride, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate, 2-ethylaminoethanol, diethyl ether.This cleaning agent is not containing excitant surface reactive material, the raw material components used is harmless, and according to the character matched combined of each raw material components, there is obvious bactericidal effect, especially in sterilizing cleaning process to flooring board matter without any injury, be particularly suitable for the extensive use in floor-cleaning field.
Description
Technical field
The present invention relates to a kind of wood floors Bactericidal cleaner, belong to cleaning supplies technical field.
Background technology
Have the cleaning agent of bactericidal action at present, the cationic surfactant that sterilization component is wherein mainly clorox or has a bactericidal action is as quaternary ammonium salt.Though clorox has very strong bactericidal effect, there are stronger excitant and sensitization, article during use, also can be caused to fade.Cationic surfactant development rapidly, because it has bactericidal effect, the cationic surfactant that China commonly uses is mainly quaternary ammonium salt, its bactericidal effect is remarkable, but still have the following disadvantages: its bactericidal effect can weaken by the impact of composition in system, during as there is protein or anion in system, its bactericidal effect can weaken; Cationic surfactant has very low LD50, and toxicity is higher, has excitant to skin.
Adopt wood floors in existing house decoration, but after wood floors use a period of time, bacterium easily grows, and dirt is not easy to clean more, bactericidal effect is good, the active demand Bactericidal cleaner of no skin irritation become on market.
Summary of the invention
The bactericidal effect that the object of the invention is to solve the existence of above-mentioned prior art is unstable, has irritating deficiency, provides a kind of bactericidal effect good, non-irritating wood floors Bactericidal cleaner.
Technical problem of the present invention, is achieved by following technical proposals:
A kind of wood floors Bactericidal cleaner, special character is to be made up of the raw material of following weight: 70 parts, water, N-(2, 6-dioxo-3-piperidyl)-phthalimide 15-18 part, (2-ethoxy) diisopropyl methyl bromide ammonium cluck ton-9-carboxylate 13-15 part, 2-(acetoxyl group) benzoic acid 10-12 part, diphenyl acetic acid 2-(diethylamino) ester hydrochloride 8-10 part, 2, 3, 4, 5, 6-penta hydroxy group-2-hexenoic acid-4-lactone 8-10 part, N, N-diethyl-2-[4-(1, 2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4-6 part, 2-ethylaminoethanol 6-8 part, diethyl ether 2-4 part.
Preparation method of the present invention: add pure water, adds N-(2,6-dioxo-3-piperidyl)-phthalimide while stirring, continues to be stirred to be uniformly dispersed, and is then heated to 50-65 DEG C; Slowly add (2-ethoxy) diisopropyl methyl bromide ammonium cluck ton-9-carboxylate, stir and make it to dissolve; After add 2-(acetoxyl group) benzoic acid, diphenyl acetic acid 2-(diethylamino) ester hydrochloride, 2 successively, 3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate, 2-ethylaminoethanol, diethyl ether, stir; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes, namely obtain this floor Bactericidal cleaner.
Described wood floors Bactericidal cleaner uses in 10-35 DEG C of temperature range.
This wood floors Bactericidal cleaner, not containing the excitant such as clorox and quaternary ammonium salt surface reactive material, the raw material components used is harmless, and according to the character matched combined of each raw material components, there is obvious bactericidal effect, especially its in sterilizing cleaning process to flooring board matter without any injury, be particularly suitable for the extensive use in floor-cleaning field.
Embodiment
Below provide the specific embodiment of the present invention, be used for being further described the present invention.In the present invention, if no special instructions, each raw material all in working substance content for 100%.
In following examples and comparative example, raw material introduction:
N-(2,6-dioxo-3-piperidyl)-phthalimide, CAS accession number is 50-35-1;
(2-ethoxy) diisopropyl methyl bromide ammonium cluck ton-9-carboxylate, CAS accession number is 50-34-0;
2-(acetoxyl group) benzoic acid, CAS accession number is 50-78-2;
Diphenyl acetic acid 2-(diethylamino) ester hydrochloride, CAS accession number is 50-42-0;
2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone, CAS accession number is 50-81-7;
N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate, CAS accession number is 50-41-9;
2-ethylaminoethanol, CAS accession number is 141-43-5;
Diethyl ether, CAS accession number is 60-29-7.
Embodiment 1
The wood floors Bactericidal cleaner of the present embodiment is made up of the raw material of following weight:
Water 70kg, N-(2,6-dioxo-3-piperidyl)-phthalimide 18kg, (2-ethoxy) diisopropyl methyl bromide ammonium cluck ton-9-carboxylate 13kg, 2-(acetoxyl group) benzoic acid 10kg, diphenyl acetic acid 2-(diethylamino) ester hydrochloride 8kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 10kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4 kg, 2-ethylaminoethanol 8kg, diethyl ether 2kg.
Add pure water 70kg, add N-(2,6-dioxo-3-piperidyl)-phthalimide 18 kg while stirring, continue to be stirred to and be uniformly dispersed, be then heated to 50-65 DEG C; Slowly add (2-ethoxy) diisopropyl methyl bromide ammonium cluck ton-9-carboxylate 13kg, stir and make it to dissolve; After add 2-(acetoxyl group) benzoic acid 10 kg, diphenyl acetic acid 2-(diethylamino) ester hydrochloride 8 kg, 2 successively, 3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 10 kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4kg, 2-ethylaminoethanol 8kg, diethyl ether 2 kg, stir; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes, namely obtain this floor Bactericidal cleaner.
The properties of product of the present embodiment:
Sterilizing power: staphylococcus aureus 99.9%, Escherichia coli 99.5%, Candida albicans 99.2%.
Embodiment 2
The wood floors Bactericidal cleaner of this comparative example is made up of the raw material of following weight:
Water 70kg, N-(2,6-dioxo-3-piperidyl)-phthalimide 15kg, (2-ethoxy) diisopropyl methyl bromide ammonium cluck ton-9-carboxylate 14kg, 2-(acetoxyl group) benzoic acid 11kg, diphenyl acetic acid 2-(diethylamino) ester hydrochloride 10kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 8kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 6 kg, 2-ethylaminoethanol 6kg, diethyl ether 4kg.
Preparation method is with embodiment 1 for this wood floors Bactericidal cleaner.
The properties of product of the present embodiment:
Sterilizing power: staphylococcus aureus 99.7%, Escherichia coli 99.6%, Candida albicans 99.2%.
Embodiment 3
The wood floors Bactericidal cleaner of the present embodiment is made up of the raw material of following weight:
Water 70kg, N-(2,6-dioxo-3-piperidyl)-phthalimide 16kg, (2-ethoxy) diisopropyl methyl bromide ammonium cluck ton-9-carboxylate 15kg, 2-(acetoxyl group) benzoic acid 12kg, diphenyl acetic acid 2-(diethylamino) ester hydrochloride 9kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 9kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 5kg, 2-ethylaminoethanol 7kg, diethyl ether 3kg.
Preparation method is with embodiment 1 for this wood floors Bactericidal cleaner.
The properties of product of the present embodiment:
Sterilizing power: staphylococcus aureus 99.6%, Escherichia coli 99.4%, Candida albicans 99.5%.
Comparative example 1
The wood floors Bactericidal cleaner of this comparative example is made up of the raw material of following weight:
Water 70kg, N-(2,6-dioxo-3-piperidyl)-phthalimide 18kg, 2-(acetoxyl group) benzoic acid 10kg, diphenyl acetic acid 2-(diethylamino) ester hydrochloride 8kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 10kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4kg, diethyl ether 2kg.
Add pure water 70kg, add N-(2,6-dioxo-3-piperidyl)-phthalimide 18kg while stirring, continue to be stirred to and be uniformly dispersed, be then heated to 50-65 DEG C; After add 2-(acetoxyl group) benzoic acid 10kg, diphenyl acetic acid 2-(diethylamino) ester hydrochloride 8kg, 2 successively, 3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 10kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4kg, diethyl ether 2kg, stir; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes, namely obtain this floor Bactericidal cleaner.
The properties of product of the present embodiment:
Sterilizing power: staphylococcus aureus 80.6%, Escherichia coli 78.4%, Candida albicans 75.5%.
Comparative example 2
The wood floors Bactericidal cleaner of the present embodiment is made up of the raw material of following weight:
Water 70kg, N-(2,6-dioxo-3-piperidyl)-phthalimide 18kg, (2-ethoxy) diisopropyl methyl bromide ammonium cluck ton-9-carboxylate 13kg, 2-(acetoxyl group) benzoic acid 10kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 10kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4 kg, 2-ethylaminoethanol 8kg.
Its preparation method is with comparative example 1.
The properties of product of this comparative example:
Sterilizing power: staphylococcus aureus 92.9%, Escherichia coli 92.4%, Candida albicans 91.5%.
The floor Bactericidal cleaner of above embodiment and comparative example all uses in 10-35 DEG C of temperature range.
Clean wood floors with embodiment 1-3 and comparative example gained finished product, its performance parameter sees the following form.
Embodiment 1-3 and comparative example gained finished product clear water are diluted 25 times, picks dilution with clean rag, spread upon dirty place, use clear water wiping, namely recover the bright and clean of wood floors.
Infiltrating time is after finished product dilution is spread upon dirty place, dissolves the dirty time of bursting completely;
Effect comprises following several situation:
1. represent that dirty bursting is removed completely, floor is completely bright and clean;
2. represent and still have the residual dirt of minute quantity to burst, do not affect floor attractive in appearance;
3. represent and still have a small amount of residual dirt to burst, floor surface is bright not;
4. represent that removing a small amount of dirt bursts, and still needs secondary to clean.
Product wiping properties parameter list
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | |
| Smear number of times | 1 | 1 | 1 | 1 | 1 |
| Infiltrating time/s | 8 | 12 | 10 | 18 | 18 |
| Wiping effect | 1 | 1 | 1 | 3 | 2 |
Claims (2)
1. a wood floors Bactericidal cleaner, it is characterized in that being made up of the raw material of following weight: 70 parts, water, N-(2, 6-dioxo-3-piperidyl)-phthalimide 15-18 part, (2-ethoxy) diisopropyl methyl bromide ammonium cluck ton-9-carboxylate 13-15 part, ASA 10-12 part, diphenyl acetic acid 2-(diethylamino) ester hydrochloride 8-10 part, 2, 3, 4, 5, 6-penta hydroxy group-2-hexenoic acid-4-lactone 8-10 part, N, N-diethyl-2-[4-(1, 2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4-6 part, 2-ethylaminoethanol 6-8 part, diethyl ether 2-4 part,
The preparation method of wood floors Bactericidal cleaner: add pure water, adds N-(2 while stirring, 6-dioxo-3-piperidyl)-phthalimide, continues to be stirred to and is uniformly dispersed, be then heated to 50-65 DEG C; Slowly add (2-ethoxy) diisopropyl methyl bromide ammonium cluck ton-9-carboxylate, stir and make it to dissolve; After add ASA, diphenyl acetic acid 2-(diethylamino successively) ester hydrochloride, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate, 2-ethylaminoethanol, diethyl ether, stir; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes.
2. wood floors Bactericidal cleaner as claimed in claim 1, is characterized in that described wood floors Bactericidal cleaner uses in 10-35 DEG C of temperature range.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410233430.8A CN104026134B (en) | 2014-05-29 | 2014-05-29 | A kind of wood floors Bactericidal cleaner |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410233430.8A CN104026134B (en) | 2014-05-29 | 2014-05-29 | A kind of wood floors Bactericidal cleaner |
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| CN104026134A CN104026134A (en) | 2014-09-10 |
| CN104026134B true CN104026134B (en) | 2015-09-23 |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106635506A (en) * | 2016-11-30 | 2017-05-10 | 四川中塑高分子材料有限公司 | Efficient sports floor cleaning agent |
| CN106635511A (en) * | 2016-11-30 | 2017-05-10 | 四川中塑高分子材料有限公司 | Sports floor cleaner |
| CN106635435A (en) * | 2016-11-30 | 2017-05-10 | 四川中塑高分子材料有限公司 | An improved type sports floor cleaning agent |
| CN106675792A (en) * | 2016-11-30 | 2017-05-17 | 四川中塑高分子材料有限公司 | Antibacterial sports floor cleaning agent |
| CN106635436A (en) * | 2016-11-30 | 2017-05-10 | 四川中塑高分子材料有限公司 | Novel cleaning agent for sports floor |
| CN106854574A (en) * | 2017-01-05 | 2017-06-16 | 长沙协浩吉生物工程有限公司 | A kind of compound method of wood furniture cleaning agent |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009045443A2 (en) * | 2007-10-02 | 2009-04-09 | The University Of Rochester | Methods and compositions related to synergistic responses to oncogenic mutations |
| CN103255002A (en) * | 2013-05-21 | 2013-08-21 | 苏州富通高新材料科技股份有限公司 | Antibacterial floor cleaner and preparation method thereof |
| CN103555457A (en) * | 2013-10-30 | 2014-02-05 | 青岛叁鼎卫生制品有限公司 | Floor cleaner |
-
2014
- 2014-05-29 CN CN201410233430.8A patent/CN104026134B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009045443A2 (en) * | 2007-10-02 | 2009-04-09 | The University Of Rochester | Methods and compositions related to synergistic responses to oncogenic mutations |
| CN103255002A (en) * | 2013-05-21 | 2013-08-21 | 苏州富通高新材料科技股份有限公司 | Antibacterial floor cleaner and preparation method thereof |
| CN103555457A (en) * | 2013-10-30 | 2014-02-05 | 青岛叁鼎卫生制品有限公司 | Floor cleaner |
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| CN104026134A (en) | 2014-09-10 |
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Inventor after: Kang Dongping Inventor before: Liu Yong |
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| TR01 | Transfer of patent right |
Effective date of registration: 20170316 Address after: Five East Road 710399 Shaanxi city of Xi'an province Huxian Fengjing Industrial Park. Patentee after: Shaanxi Kaili Chemical Co., Ltd. Address before: 239000 Anhui city of Chuzhou province to two County Road C District Industrial Park weft Patentee before: Chuzhou Smet Compound Materials Co., Ltd. |
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Granted publication date: 20150923 Termination date: 20170529 |
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