CN104004137A - Solvent-type light-cured modified chlorinated polypropylene coating polymer for polypropylene films and preparation method and application thereof - Google Patents
Solvent-type light-cured modified chlorinated polypropylene coating polymer for polypropylene films and preparation method and application thereof Download PDFInfo
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Abstract
The invention belongs to the field of polymer coating materials, and discloses a solvent-type light-cured modified chlorinated polypropylene coating polymer for polypropylene films, a preparation method and an application thereof. The polymer has a structure as shown in the description, wherein R is H or CH3, and n=1-8. The coating polymer is prepared by graft modification of chlorinated polypropylene by various acrylates. Coating materials prepared by the coating polymer have excellent adhesion to BOPP. With the introduction of the acrylate structure, the prepared coating materials have strong binding power, and high surface energy, and provide printing ink with good spreading and bonding effects on the coating materials. The coating polymer contains a light-curable cinnamate group structure which can be embedded into a printing ink cross-linked network during printing, and thus improve the binding power between the coating materials and the printing ink. The coating polymer of the invention can reach the purpose of synchronous realization of binding power improvement between a coating and BOPP and between a coating and printing ink.
Description
Technical field
The invention belongs to polymeric coating Material Field, be specifically related to solvent-borne type photocuring modified chlorinated polypropylene coated polymeric and its preparation method and application for a kind of polypropylene film.
Background technology
Biaxially oriented polypropylene film (BOPP) (BOPP) film is a kind of flexible packing material growing up the sixties in last century, because processing stabilities such as physical property, printing etc. are good, be therefore widely used in food product pack, electric equipment products packing, daily necessities packing, garment packaging etc.Exquisite packing be unable to do without printing, and BOPP belongs to polyolefin film, does not have polar group and active function groups in molecule, and material surface adsorptive power is very poor, and surface tension is little, and ink sticking power on film is lower, thereby printing difficulty.
Certain macromolecular solution is coated on to film surface, then in coating, is coated with ink printing again, this is a kind of effective way that improves cohesive force between BOPP film and printing-ink.This floor height molecular film is called coating.Coating needs BOPP and ink to be bondd simultaneously, plays the effect of forming a connecting link.Coated polymeric structure is designed, make the coated material of preparation all there is to BOPP and ink the key that stronger reactive force is raising cohesive force.
Coated material for BOPP mainly contains polyacrylate(s), polyurethanes, Chlorinated Polypropylene III class etc. at present.Chlorinated Polypropylene III is polyacrylic modified product, and its molecular structure and BOPP molecular structure are closely similar, is conventional BOPP coated material.Nonpolarity group and active group in Chlorinated Polypropylene III molecular structure, the Chlorinated Polypropylene III coated material cohesive force of using is at present not good, can't meet application requiring.
Acrylic polymer is because of its initial bonding strength and the good sizing agent that is often used as of cohesive force.Therefore, on Chlorinated Polypropylene III molecular structure, introduce acrylate class formation, strengthen on the one hand the polarity of Chlorinated Polypropylene III, be expected to improve its surface can, strengthen cohesive force, reach the effect of ink uniform spreading and bonding in coating; On the other hand, by modification, on Chlorinated Polypropylene III molecule, introduce active group, then introduce ultraviolet curing group, being expected to realize part or all of ultraviolet curing group in printing process embeds in the cross-linked network structure of ink, make to produce chemical bond between coated polymeric and ink and be connected, thereby improve cohesive force.
Summary of the invention
In order to overcome the shortcoming and deficiency of above-mentioned prior art, primary and foremost purpose of the present invention is to provide solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for a kind of polypropylene film; Pass through Molecular Structure Design, solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for synthetic a kind of polypropylene film, in this polymer molecular structure, contain photosensitive group Chinese cassia tree ester group, Chinese cassia tree ester group is subject to the effect of a small amount of UV-light in environment, can there is photo-crosslinking in part Chinese cassia tree ester group, unreacted Chinese cassia tree ester group can embed in the cross-linked network of ink in the process with ink photocuring, and synchronous realization improved between coating and BOPP, the object of cohesive force between coating and ink.
Another object of the present invention is to provide the preparation method of a kind of above-mentioned polypropylene film with solvent-borne type photocuring modified chlorinated polypropylene coated polymeric.
Another object of the present invention is to provide the application of a kind of above-mentioned polypropylene film with solvent-borne type photocuring modified chlorinated polypropylene coated material.
Object of the present invention realizes by following proposal:
A solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for polypropylene film, this polymkeric substance has following structure:
Wherein R=H or CH
3; N=1～8.
The preparation method of solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for above-mentioned polypropylene film, comprise following operation steps: in container, add Chlorinated Polypropylene III 20～40 weight parts and solvent 60～100 weight parts, stir 30min, be warming up to 95～110 ℃, add Hydroxyethyl acrylate or hydroxyethyl methylacrylate 1～3 weight part, alkyl acrylate or alkyl methacrylate 1～4 weight part and initiator 1～3 weight part, reaction 6～9h; Under ice bath, add catalyzer 0.5～2 weight part, cinnamyl chloride 0.5～2 weight part, continue reaction 4～6h, after purifying, obtain solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for polypropylene film; Described solvent is at least one in toluene, dimethylbenzene, butylacetate, ethylene glycol monomethyl ether.
The chloride mass percent of described Chlorinated Polypropylene III is 20～60%; Described alkyl acrylate is at least one in methyl acrylate, ethyl propenoate, propyl acrylate, butyl acrylate, vinylformic acid isopentyl ester, Ethyl acrylate and Isooctyl acrylate monomer; Described alkyl methacrylate is at least one in methyl methacrylate, β-dimethyl-aminoethylmethacrylate, propyl methacrylate, butyl methacrylate, methacrylic isoamyl valerate, N-Hexyl methacrylate and Isooctyl methacrylate.
Described initiator is at least one in benzoyl peroxide, dilauroyl peroxide, di-t-butyl peroxide.
Described catalyzer is at least one in triethylamine, pyridine, DMAP.
Above-mentioned polypropylene film is being prepared the application in solvent-borne type photocuring modified chlorinated polypropylene coated material for polypropylene film with solvent-borne type photocuring modified chlorinated polypropylene coated polymeric, described application is according to following operation steps: polypropylene film is dissolved in 56～100 parts of solvents with solvent-borne type photocuring modified chlorinated polypropylene coated polymeric 15～40 weight parts, obtains the solvent-borne type photocuring modified chlorinated polypropylene coated material for polypropylene film of solid content 13～40%.
Described solvent is at least one in toluene, dimethylbenzene, butylacetate and ethylene glycol monomethyl ether.
The present invention, with respect to prior art, has following advantage and beneficial effect:
(1) the present invention utilizes acrylate modified Chlorinated Polypropylene III to prepare solvent-borne type photocuring Chlorinated Polypropylene III coated polymeric, and the photocurable coated material that utilizes this coated polymeric to make is excellent to BOPP cohesive force.
(2) polypropylene film of the present invention is with containing acrylate class formation in solvent-borne type photocuring modified chlorinated polypropylene coated polymeric structure, and coated material cohesive force is strong, and surface can be high, and it is good that ink is sprawled with bond effect on coated material.And in coated polymeric structure, contain photo curable Chinese cassia tree ester group, and in BOPP printing process, can embed in the cross-linked network of ink, realize the object that improves the cohesive force between coated material and ink.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited to this.
In the following example, each performance perameter is measured in accordance with the following methods:
Coated material application performance is measured:
Surface tension: press ISO8296-2003 and measure.
Sticking power: adopt 3M600 adhesive tape to measure.
Transparency: appearance method
Embodiment 1:
(1) by weight, get 20 parts of Chlorinated Polypropylene IIIs (chloride mass percent 20%), in 60 parts of reactors that are dissolved in agitator, prolong of toluene, stir 30min, be warming up to 110 ℃, add 1 part of Hydroxyethyl acrylate, 1 part of butyl acrylate, 1.2 parts of benzoyl peroxides, reaction 6h.Then cooling adds 0.5 part of triethylamine under ice bath, and 0.5 part of cinnamyl chloride continues reaction 4h, makes solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for polypropylene film after purifying;
Get 20 parts of above-mentioned coated polymerics and be dissolved in 60 parts of toluene, obtain the solvent-borne type photocuring modified chlorinated polypropylene coated material for polypropylene film of solid content 25%.
(2) get coated material and be coated with the thick film of 0.08mm at BOPP film surface, except desolventizing, the ultraviolet lamp 4cm that is 275nm apart from wavelength, irradiates 2min, then measures coated material application performance.
Products obtained therefrom performance test results is as shown in table 1.Test performance is as follows: surface tension: 39 dyne; Sticking power: coating does not come off; Transparency: unchanged before and after filming.
Embodiment 2:
(1) by weight, get 20 parts of Chlorinated Polypropylene IIIs (chloride mass percent 35%), in 75 parts of reactors that are dissolved in agitator, prolong of butylacetate, stir 30min, be warming up to 95 ℃, add 3 parts of hydroxyethyl methylacrylates, 1 part of ethyl propenoate, 1.2 parts of di-t-butyl peroxides, reaction 9h.Then cooling, adds 1 part of pyridine under ice bath, 0.5 part of DMAP, and 1.2 parts of cinnamyl chlorides, continue reaction 6h, make solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for polypropylene film after purifying;
Get 30 parts of above-mentioned coated polymerics and be dissolved in 60 parts of butylacetates, obtain the solvent-borne type photocuring modified chlorinated polypropylene coated material for polypropylene film of solid content 32%.
(2) get coated material and be coated with the thick film of 0.08mm at BOPP film surface, except desolventizing, the ultraviolet lamp 4cm that is 275nm apart from wavelength, irradiates 2min, then measures coated material application performance.
Products obtained therefrom performance test results is as shown in table 1.Test performance is as follows: surface tension: 40 dyne; Sticking power: coating does not come off; Transparency: unchanged before and after filming.
Embodiment 3:
(1) by weight, get 20 parts of Chlorinated Polypropylene IIIs (chloride mass percent 35%), in 60 parts of reactors that are dissolved in agitator, prolong of toluene, stir 30min, be warming up to 110 ℃, add 2.5 parts of hydroxyethyl methylacrylates, 1 part of methyl acrylate, 1.2 parts of benzoyl peroxides, reaction 6h.Then cooling, adds 2 parts of pyridines under ice bath, and 1.5 parts of cinnamyl chlorides continue reaction 4h, makes solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for polypropylene film after purifying;
Get 25 parts of above-mentioned coated polymerics and be dissolved in 58 parts of dimethylbenzene, obtain the solvent-borne type photocuring modified chlorinated polypropylene coated material for polypropylene film of solid content 30%.
(2) get coated material and be coated with the thick film of 0.08mm at BOPP film surface, except desolventizing, the ultraviolet lamp 4cm that is 275nm apart from wavelength, irradiates 2min, then measures coated material application performance.
Products obtained therefrom performance test results is as shown in table 1.Test performance is as follows: surface tension: 39 dyne; Sticking power: coating does not come off; Transparency: unchanged before and after filming.
Embodiment 4:
(1) by weight, get 40 parts of Chlorinated Polypropylene IIIs (chloride mass percent 60%), in 100 parts of reactors that are dissolved in agitator, prolong of toluene, stir 30min, be warming up to 110 ℃, add 0.8 part of Hydroxyethyl acrylate, 4 parts of butyl methacrylate, 3 parts of benzoyl peroxides, reaction 6h.Then cooling, adds 1 part of triethylamine under ice bath, and 1 part of cinnamyl chloride continues reaction 4h, makes solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for polypropylene film after purifying;
Get 40 parts of above-mentioned coated polymerics and be dissolved in 60 parts of dimethylbenzene, obtain the solvent-borne type photocuring modified chlorinated polypropylene coated material for polypropylene film of solid content 40%.
(2) get coated material and be coated with the thick film of 0.08mm at BOPP film surface, except desolventizing, the ultraviolet lamp 4cm that is 275nm apart from wavelength, irradiates 2min, then measures coated material application performance.
Products obtained therefrom performance test results is as shown in table 1.Test performance is as follows: surface tension: 41 dyne; Sticking power: coating does not come off; Transparency: unchanged before and after filming.
Embodiment 5:
(1) by weight, get 20 parts of Chlorinated Polypropylene IIIs (chloride mass percent 25% is 1:1 with the mass ratio of the Chlorinated Polypropylene III of chloride mass percent 40%), in 75 parts of reactors that are dissolved in agitator, prolong of dimethylbenzene, stir 30min, be warming up to 110 ℃, add 1.5 parts of Hydroxyethyl acrylates, 1 part of Isooctyl acrylate monomer, 1.5 parts of dilauroyl peroxides, reaction 6h.Then cooling, adds 1.5 parts of pyridines under ice bath, and 1.5 parts of cinnamyl chlorides continue reaction 4.5h, makes solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for polypropylene film after purifying;
Get 30 parts of above-mentioned coated polymerics and be dissolved in 77 parts of dimethylbenzene, obtain the solvent-borne type photocuring modified chlorinated polypropylene coated material for polypropylene film of solid content 28%.
(2) get coated material and be coated with the thick film of 0.08mm at BOPP film surface, except desolventizing, the ultraviolet lamp 4cm that is 275nm apart from wavelength, irradiates 2min, then measures coated material application performance.
Products obtained therefrom performance test results is as shown in table 1.Test performance is as follows: surface tension: 42 dyne; Sticking power: coating does not come off; Transparency: unchanged before and after filming.
Embodiment 6:
(1) by weight, get 20 parts of Chlorinated Polypropylene IIIs (chloride mass percent 30%), in 60 parts of reactors that are dissolved in agitator, prolong of toluene, stir 30min, be warming up to 110 ℃, add 3 parts of hydroxyethyl methylacrylates, 1 part of Isooctyl methacrylate, 1.2 parts of benzoyl peroxides, reaction 6h.Then cooling, adds 2 parts of triethylamines under ice bath, and 2 parts of cinnamyl chlorides continue reaction 6h, makes solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for polypropylene film after purifying;
Get 25 parts of above-mentioned coated polymerics and be dissolved in 58 parts of toluene, obtain the solvent-borne type photocuring modified chlorinated polypropylene coated material for polypropylene film of solid content 30%.
(2) get coated material and be coated with the thick film of 0.08mm at BOPP film surface, except desolventizing, the ultraviolet lamp 4cm that is 275nm apart from wavelength, irradiates 2min, then measures coated material application performance.
Products obtained therefrom performance test results is as shown in table 1.Test performance is as follows: surface tension: 40 dyne; Sticking power: coating does not come off; Transparency: unchanged before and after filming.
Embodiment 7:
(1) by weight, get 20 parts of Chlorinated Polypropylene IIIs (chloride mass percent 20%), in 60 parts of reactors that are dissolved in agitator, prolong of butylacetate, stir 30min, be warming up to 95 ℃, add 1.7 parts of Hydroxyethyl acrylates, 1 part of methacrylic isoamyl valerate, 1 part of benzoyl peroxide, reaction 9h.Then cooling, adds 1.5 parts of pyridines under ice bath, 0.5 part of DMAP, and 1.25 parts of cinnamyl chlorides, continue reaction 4h, make solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for polypropylene film after purifying;
Get 20 parts of above-mentioned coated polymerics and be dissolved in 56 parts of toluene, mix, obtain the solvent-borne type photocuring modified chlorinated polypropylene coated material for polypropylene film of solid content 26%.
(2) get coated material and be coated with the thick film of 0.08mm at BOPP film surface, except desolventizing, the ultraviolet lamp 4cm that is 275nm apart from wavelength, irradiates 2min, then measures coated material application performance.
Products obtained therefrom performance test results is as shown in table 1.Test performance is as follows: surface tension: 41 dyne; Sticking power: coating does not come off; Transparency: unchanged before and after filming.
Embodiment 8:
(1) by weight, get 40 parts of Chlorinated Polypropylene IIIs (chloride mass percent 25% is 2:1 with the mass ratio of the Chlorinated Polypropylene III of chloride mass percent 40%), in 95 parts of reactors that are dissolved in agitator, prolong of dimethylbenzene, stir 30min, be warming up to 105 ℃, add 2 parts of methacrylic hydroxyl ethyl esters, 2 parts of methyl methacrylates, 3 parts of dilauroyl peroxides, reaction 7h.Then cooling, adds 1.5 parts of pyridines under ice bath, and 1 part of cinnamyl chloride continues reaction 4h, makes solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for polypropylene film after purifying;
Get 30 parts of above-mentioned coated polymerics and be dissolved in 73 parts of ethylene glycol monomethyl ethers, obtain the solvent-borne type photocuring modified chlorinated polypropylene coated material for polypropylene film of solid content 29%.
(2) get coated material and be coated with the thick film of 0.08mm at BOPP film surface, except desolventizing, the ultraviolet lamp 4cm that is 275nm apart from wavelength, irradiates 2min, measures coated material application performance.
Products obtained therefrom performance test results is as shown in table 1.Test performance is as follows: surface tension: 41 dyne; Sticking power: coating does not come off; Transparency: unchanged before and after filming.
Embodiment 9:
(1) by weight, get 20 parts of Chlorinated Polypropylene IIIs (chloride mass percent 40%), in 65 parts of reactors that are dissolved in agitator, prolong of toluene, stir 30min, be warming up to 100 ℃, add 3 parts of hydroxyethyl methylacrylates, 1 part of propyl methacrylate, 1 part of benzoyl peroxide, reaction 7h.Then cooling, adds 2 parts of triethylamines under ice bath, and 2 parts of cinnamyl chlorides continue reaction 6h, makes solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for polypropylene film after purifying;
Get 25 parts of above-mentioned coated polymerics and be dissolved in 71 parts of toluene, obtain the solvent-borne type photocuring modified chlorinated polypropylene coated material for polypropylene film of solid content 26%.
(2) get coated material and be coated with the thick film of 0.08mm at BOPP film surface, except desolventizing, the ultraviolet lamp 4cm that is 275nm apart from wavelength, irradiates 2min, then measures coated material application performance.
Products obtained therefrom performance test results is as shown in table 1.Test performance is as follows: surface tension: 40 dyne; Sticking power: coating does not come off; Transparency: unchanged before and after filming.
Embodiment 10:
(1) by weight, get 20 parts of Chlorinated Polypropylene IIIs (chloride mass percent 40%), in 70 parts of reactors that are dissolved in agitator, prolong of ethylene glycol monomethyl ether, stir 30min, be warming up to 95 ℃, add 1 part of Hydroxyethyl acrylate, 1 part of Ethyl acrylate, 1.2 parts of reaction 6h of benzoyl peroxide.Then cooling, adds 1.2 parts of triethylamines under ice bath, and 1.5 parts of cinnamyl chlorides continue reaction 4h, makes solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for polypropylene film after purifying;
Get 15 parts of above-mentioned coated polymerics and be dissolved in 100 parts of ethylene glycol monomethyl ethers, obtain the solvent-borne type photocuring modified chlorinated polypropylene coated material for polypropylene film of solid content 13%.
(2) get coated material and be coated with the thick film of 0.08mm at BOPP film surface, except desolventizing, the ultraviolet lamp 4cm that is 275nm apart from wavelength, irradiates 10 seconds, then measures coated material application performance.
Products obtained therefrom performance test results is as shown in table 1.Test performance is as follows: surface tension: 43 dyne; Sticking power: coating does not come off; Transparency: unchanged before and after filming.
By table 1, can find out, the coated material sticking power on BOPP that adopts polypropylene film of the present invention to prepare with solvent-borne type photocuring modified chlorinated polypropylene coated polymeric is excellent; And coated material can carry out photocuring, in printing process, can embed in ink cross-linked network, realize the object that improves cohesive force between coated material and ink.
Solvent-borne type photocuring modified chlorinated polypropylene coated polymeric application performance index for table 1 polypropylene film
Above-described embodiment is preferably embodiment of the present invention; but embodiments of the present invention are not restricted to the described embodiments; other any do not deviate from change, the modification done under spirit of the present invention and principle, substitutes, combination, simplify; all should be equivalent substitute mode, within being included in protection scope of the present invention.
Claims (8)
1. a solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for polypropylene film, is characterized in that: this polymkeric substance has following structure:
Wherein R is H or CH
3, n=1～8.
2. the preparation method of solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for a kind of polypropylene film according to claim 1, it is characterized in that comprising following operation steps: in container, add Chlorinated Polypropylene III 20～40 weight parts and solvent 60～100 weight parts, stir 30min, be warming up to 95～110 ℃, add Hydroxyethyl acrylate or hydroxyethyl methylacrylate 1～3 weight part, alkyl acrylate or alkyl methacrylate 1～4 weight part and initiator 1～3 weight part, reaction 6～9h; Under ice bath, add catalyzer 0.5～2 weight part, cinnamyl chloride 0.5～2 weight part, continue reaction 4～6h, after purifying, obtain solvent-borne type photocuring modified chlorinated polypropylene coated polymeric for polypropylene film.
3. preparation method according to claim 2, is characterized in that: the chloride mass percent of described Chlorinated Polypropylene III is 20～60%; Described alkyl acrylate is at least one in methyl acrylate, ethyl propenoate, propyl acrylate, butyl acrylate, vinylformic acid isopentyl ester, Ethyl acrylate and Isooctyl acrylate monomer; Described alkyl methacrylate is at least one in methyl methacrylate, β-dimethyl-aminoethylmethacrylate, propyl methacrylate, butyl methacrylate, methacrylic isoamyl valerate, N-Hexyl methacrylate and Isooctyl methacrylate.
4. preparation method according to claim 2, is characterized in that: described solvent is at least one in toluene, dimethylbenzene, butylacetate, ethylene glycol monomethyl ether.
5. preparation method according to claim 2, is characterized in that: described initiator is at least one in benzoyl peroxide, dilauroyl peroxide, di-t-butyl peroxide.
6. preparation method according to claim 2, is characterized in that: described catalyzer is at least one in triethylamine, pyridine, DMAP.
7. a kind of polypropylene film according to claim 1 is being prepared the application in solvent-borne type photocuring modified chlorinated polypropylene coated material for polypropylene film with solvent-borne type photocuring modified chlorinated polypropylene coated polymeric, it is characterized in that: described application is according to following operation steps: polypropylene film is dissolved in solvent with solvent-borne type photocuring modified chlorinated polypropylene coated polymeric 15～40 weight parts, obtains the solvent-borne type photocuring modified chlorinated polypropylene coated material for polypropylene film of solid content 13～40%.
8. application according to claim 7, is characterized in that: described solvent is at least one in toluene, dimethylbenzene, butylacetate and ethylene glycol monomethyl ether.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104238824A (en) * | 2014-09-30 | 2014-12-24 | 江西省平波电子有限公司 | Manufacturing technology for touch screen of improved GFF structure |
| CN104267850A (en) * | 2014-09-30 | 2015-01-07 | 江西省平波电子有限公司 | Production technique of improved touch modules of GF2 two-sided conductive films and elargol wiring |
| CN104267851A (en) * | 2014-09-30 | 2015-01-07 | 江西省平波电子有限公司 | Manufacturing technology for improved touch module with GF2 double-surface conductive film structure |
| CN104298401A (en) * | 2014-09-30 | 2015-01-21 | 江西省平波电子有限公司 | Manufacturing process of improved touch screen of GG structure |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1715352A (en) * | 2005-07-29 | 2006-01-04 | 湖北大学 | A kind of modified chlorinated polypropylene adhesive |
| CN101445712A (en) * | 2008-12-29 | 2009-06-03 | 宁波信泰机械有限公司 | Method for preparing modified parlon adhesive and agglutinating method of modified parlon adhesive |
-
2014
- 2014-05-14 CN CN201410203472.7A patent/CN104004137B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1715352A (en) * | 2005-07-29 | 2006-01-04 | 湖北大学 | A kind of modified chlorinated polypropylene adhesive |
| CN101445712A (en) * | 2008-12-29 | 2009-06-03 | 宁波信泰机械有限公司 | Method for preparing modified parlon adhesive and agglutinating method of modified parlon adhesive |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104238824A (en) * | 2014-09-30 | 2014-12-24 | 江西省平波电子有限公司 | Manufacturing technology for touch screen of improved GFF structure |
| CN104267850A (en) * | 2014-09-30 | 2015-01-07 | 江西省平波电子有限公司 | Production technique of improved touch modules of GF2 two-sided conductive films and elargol wiring |
| CN104267851A (en) * | 2014-09-30 | 2015-01-07 | 江西省平波电子有限公司 | Manufacturing technology for improved touch module with GF2 double-surface conductive film structure |
| CN104298401A (en) * | 2014-09-30 | 2015-01-21 | 江西省平波电子有限公司 | Manufacturing process of improved touch screen of GG structure |
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| CN104004137B (en) | 2016-06-01 |
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