[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

CH367921A - Liquid suitable as a lubricant and for power transmission - Google Patents

Liquid suitable as a lubricant and for power transmission

Info

Publication number
CH367921A
CH367921A CH5261957A CH5261957A CH367921A CH 367921 A CH367921 A CH 367921A CH 5261957 A CH5261957 A CH 5261957A CH 5261957 A CH5261957 A CH 5261957A CH 367921 A CH367921 A CH 367921A
Authority
CH
Switzerland
Prior art keywords
sep
liquid according
castor oil
liquid
polyoxyalkylene
Prior art date
Application number
CH5261957A
Other languages
German (de)
Inventor
Pierre Coant
Jean Conan
Original Assignee
Bataafsche Petroleum
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum filed Critical Bataafsche Petroleum
Publication of CH367921A publication Critical patent/CH367921A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M3/00—Liquid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single liquid substances
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046—Hydroxy ethers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/286—Esters of polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/402—Castor oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/082—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/106—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing four carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
    • C10M2211/022—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aliphatic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/06—Perfluorinated compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/041—Triaryl phosphates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02—Unspecified siloxanes; Silicones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/08—Hydraulic fluids, e.g. brake-fluids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Lubricants (AREA)

Description

  

  Als Schmiermittel und     zur        Kraftübertragung    geeignete Flüssigkeit    Die vorliegende Erfindung bezieht sich auf eine  Flüssigkeit, die für Schmierzwecke und zur mecha  nischen Kraftübertragung verwendet werden kann.  Derartige Flüssigkeiten werden insbesondere für  Bremseinrichtungen sowie     Aufhänge-    bzw. Lager  und Lenkvorrichtungen bei mit Motoren ausgerüste  ten Wagen und für Getriebe verwendet.  



  Damit Flüssigkeiten dieser Art unter den Anwen  dungsbedingungen befriedigend arbeiten, müssen sie  über einen weiten Temperatur- und Druckbereich  gute Schmiereigenschaften aufweisen. Sie müssen  auch eine geeignete Viskosität haben. Eine hoch  viskose Flüssigkeit vermeidet zwar übermässiges  Lecken oder Gleiten in hydraulischen Pumpen, er  zeugt aber einen hohen Widerstand gegenüber der  Bewegung und verursacht so hohen Kraftverbrauch.  Anderseits fliessen zwar Flüssigkeiten von sehr gerin  ger Viskosität rasch; sie fördern aber ein     übermässiges     Lecken und ergeben schlechte Wirkung. In vielen  Fällen sind     Viskositäten    von etwa 12 bis 13     Centi-          stokes    bei 50  erforderlich.

   Hydraulische Flüssig  keiten müssen über einen sehr weiten Temperatur  bereich verwendbar sein. Sie müssen daher einen  hohen     Viskositätsindex    aufweisen, das heisst eine ge  ringe Verschiebung der Viskosität bei Temperatur  änderungen zeigen. Sie dürfen nicht ausfrieren oder  selbst bei sehr niederen Wintertemperaturen sich nicht  verfestigen. Ihr Siedepunkt muss ausreichend hoch  sein, so dass sie während des Gebrauchs nicht ver  dampfen. Es ist auch ein hoher Flammpunkt und  eine gewisse Toleranz gegenüber Wasser erforderlich.  Chemisch soll die Flüssigkeit praktisch     inert    sein  gegenüber den Stoffen, aus welchen die verschie  denen Teile eines hydraulischen Systems hergestellt  sind.

   Zum Beispiel darf die Flüssigkeit keine auf  Metalle korrodierend wirkenden Substanzen enthal  ten, und sie darf auch Kautschuk nicht angreifen.    Eine bekannte Art von Flüssigkeit dieses     Typs     besteht aus einem schmierend wirkenden Bestandteil  und einem verdünnend wirkenden Bestandteil.

   Ein  spezielles Beispiel für eine Flüssigkeit dieser Art ent  hält etwa 50     Vol:o/o    Rizinusöl und etwa 50     Vol.o/o          Diacetonalkohol.    In anderen Flüssigkeiten dieser     Art     werden als     schmierendes    Element andere Verbindun  gen verwendet, wie die Ester der     Rizinolsäure    oder       Polypropylenglykol,    oder andere Alkohole oder Äther  im Verdünnungsmittel, oder das Schmiermittel und  die verdünnenden Elemente werden in anderen Ver  hältnissen als 50: 50 gemischt.  



  Es ist jedoch sehr schwer, eine optimale Kombi  nation von Eigenschaften zu erzielen, und bisher ist  es nicht möglich gewesen, eine Flüssigkeit herzu  stellen, die gleichzeitig in jeder Hinsicht den sehr  strengen Anforderungen entspricht. Es ist ein Ziel  der vorliegenden Erfindung, dieses Problem in- tech  nisch befriedigender Weise zu lösen.  



  Die Flüssigkeit gemäss vorliegender Erfindung  enthält ebenfalls schmierende und verdünnende Kom  ponenten. Als     Schmiermittel    wirkende     Bestandteile:     Eine wesentliche Komponente wird erhalten,  indem man Rizinusöl so lang erhitzt, bis es eine  Viskosität zwischen 20 und 600     Poise    bei 20  erreicht  hat. Das Rizinusöl wird dabei auf eine verhältnis  mässig niedere Temperatur erhitzt, so dass es eine  Säurezahl unter 20 und vorzugsweise unter 5 erhält.  Das Rizinusöl wird     während    des     Erhitzens    wahr  scheinlich polymerisiert. Dieses Produkt wird nach  stehend als  modifiziertes     Rizinusöl     bezeichnet.  



  Um eine Flüssigkeit mit hoher Beständigkeit  gegenüber Wasser     zu    erhalten, das heisst, um zu errei  chen, dass die Flüssigkeit verhältnismässig grosse Men  gen Wasser aufnehmen kann, ohne dass Phasentren  nung eintritt, kann das     Rizinusöl    während des     Er-          hitzens    oxydiert werden, z. B. indem man Luft oder      irgendein anderes, Sauerstoff enthaltendes Gas durch  das Öl     hindurchperlen    lässt. Es scheint, dass Sauer  stoffbrücken zwischen den Doppelbindungen der       Rizinolsäure    gebildet werden und dadurch     Polyme-          risation    eintritt.  



  Als weitere schmierend wirkende Komponente  enthält die     erfindungsgemässe    Flüssigkeit ein     flüssiges          Polyoxyalkylen,    vorzugsweise der Formel         Rl7        O-[R20]ri        R3.       In dieser Formel bedeuten     R1    und     R3        jeweils     ein Wasserstoffatom oder einen Kohlenwasser  stoffrest (vorzugsweise     aliphatisch)    oder eine     Acyl-          gruppe.        R2    bedeutet einen     Alkylenrest    und n eine  ganze Zahl.

   In der     Polyoxyalkylenkette        -[R20]ri     kann der     R2    Rest jeden     Alkylenrest    bedeuten, vor  zugsweise einen     Alkylenrest    mit 2 bis 8 Kohlenstoff  atomen.  



  Die     Polyoxyalkylenkette        -[R20]ri        kann        Alkylen-          reste    enthalten, die eine verschiedene Zahl von     Koh-          lenstoffatomen    aufweisen. Beispielsweise kann diese  Kette     Oxyäthylen-    und     Oxypropylenreste    enthalten.

    Wenn die     Polyoxyalkylenkette    verschiedene     Alkylen-          reste    enthält, können diese willkürlich über das Mole  kül verteilt oder in regelmässig sich wiederholenden  Einheiten oder Blöcken angeordnet     sein,    von welchen  jeder aus einem oder mehreren ähnlichen     Oxyalkylen-          resten    besteht.  



  Die     Polyoxypropylenglykole    sind für die Verwen  dung in Flüssigkeiten gemäss der vorliegenden Erfin  dung besonders geeignet.  



       Bevorzugte        Polyoxyalkylene    haben     Molgewichte     zwischen 800     und    4000 oder besonders zweckmässig  zwischen 1000 und 3000.     Polyoxypropylenglykole     mit einem     Molgewicht    von etwa 2000 sind ganz  ausserordentlich wirksam.  



  Anstatt der     Polyoxyalkylene    oder in Verbindung  mit diesen können neutrale Ester     aliphatischer        Di-          carbonsäuren    verwendet werden, am besten solche  der Formel     WOOC    - R -     COOR",    in welcher R     einen     zweiwertigen, gesättigten     aliphatischen    Kohlenwasser  stoffrest und R' und R"     Alkyl-,        Aralkyl-    oder     Cyclo-          alkylreste    bedeuten, die mehr als zwei Kohlenstoff  atome enthalten.  



  Die Ester sind vorzugsweise von gesättigten     ali-          phatischen        Dicarbonsäuren    abgeleitet, z. B. von       Malon-,        Äthylmalon-,    Bernstein-,     Methyl-bernstein-,     1,1- oder     1,2-Diäthyl-bernstein-,    Glutar-, 1- oder  2     Methyl-glutar-,        1,3-Diäthyl-glutar-,        Adipin-l-    oder       2-Methyladipin-,        Pimelin-,        1,2,5-Trimethyl-pimelin-,          Suberin-,        Azelain-,

          Sebacin-,        Nonan-,        1,9-dicarbon-          und        Decan-1,10-dicarbonsäure,    sowie vorzugsweise  von     Propanolen,        Butanolen,        Hexanolen,        Octanolen     und     Nonanolen,    oder     Aralkanolen,    z. B.     Benzyl-    und       Phenyläthylalkohol,    oder     Cycloalkanole,    z.

   B.     Cyclo-          pentanol,        Cyclohexanol    und     Methylcyclohexanol.    Bei  spiele geeigneter flüssiger Ester sind       Adipinsäure-di-(2-methyl-heptyl)-ester,          Adipinsäure-di-(3,5,5-trimethyl-hexyl)-ester    oder         Sebacinsäure-di-(3,5,5-trimethyl-hexyl)-ester,          Adipinsäure-di-(3-äthyl-hexyl)-ester    oder       Sebacinsäure-di-(3-äthyl-hexyl)-ester,          Pünelinsäure-di-hexylester,          Sebacinsäure-di-(2-äthyl-hexyl)-ester,          Sebacinsäure-di-sec-butylester,

            Malonsäure-di-sec.-butylester,          Azelainsäure-di-(1-äthylpropyl)-ester    und       Malonsäure-dibutyläthylester.     Um eine Flüssigkeit mit hoher Wasserbeständig  keit zu erhalten, ist die Anwendung einer     Polyoxy-          alkylenflüssigkeit    der Verwendung eines neutralen  Esters einer     aliphatischen        Dicarbonsäure    vorzuziehen.

         Verdünnende    Komponenten:  Ihr Anteil beträgt 35 bis 70     Gew.O/o,        vorzugs-          weise        40        bis        60        Gew.%        der        Flüssigkeit.     



  Es werden dafür ein oder mehrere     Alkyläther     mehrwertiger Alkohole verwendet.     Alkyläther        alipha-          tischer    mehrwertiger Alkohole, insbesondere die       Monoalkyläther,    werden bevorzugt. Die     Monoalkyl-          äther    von Glykol und     Diglykol    sind ganz besonders  geeignet.  



  Beispiele geeigneter Äther sind     Monoäthyläther,          Monopropyläther,        Mono-n-butyläther,        Monoisobutyl-          äther,        Mono-tert.-butyläther,        Monohexylbutyläther     von     Äthylenglykol,    der     Monoisoamyläther    von     Pro-          pylenglykol,    der     Monomethyläther    von     Diäthylen-          glykol,        Monoäthyläther    von     Diäthylenglykol,

          Mono-          n-propyläther    von     Diäthylenglykol,        Monoisopropyl-          äther    von     Diäthylenglykol,        Monobutyläther    von     Di-          äthylenglykol,        Monodecyläther    von     Diäthylenglykol,          Monoäthyläther    von     Dipropylenglykol,        Monoisopro-          pyläther    von     Dipropylenglykol,

          Monoisoamyläther     von     Dipropylenglykol,        Monoisopropyläther    von     Di-          isobutylenglykol,        Monoäthyläther    von     Äthylenpro-          pylenglykol,        Monoisopropyläther    von     Äthyleniso-          butylenglykol.     



  Die folgende Zusammenstellung zeigt günstige  Mengenverhältnisse (nach Gewicht) für die verschie  denen Komponenten der Flüssigkeit.  
EMI0002.0167     
  
    Verdünnende <SEP> Komponenten: <SEP> 40 <SEP> bis <SEP> 60 <SEP> 0/0
<tb>  Schmierende <SEP> Komponenten: <SEP> 60 <SEP> bis <SEP> 4011/o
<tb>  modifiziertes <SEP> Rizinusöl
<tb>  (oxydiert <SEP> oder <SEP> nicht <SEP> oxydiert) <SEP> 5-40%
<tb>  Polyoxyalkylen <SEP> und/oder <SEP> neu  traler <SEP> Ester <SEP> einer <SEP> aliphatische
<tb>  Dicarbonsäure <SEP> 5-30%       Andere Komponenten, die als Bestandteile für  hydraulische Flüssigkeiten bekannt sind, können zu  gesetzt werden, wie z.

   B. nicht modifiziertes Rizinusöl,       Rizinolsäureester,    Phosphate,     Halogenkohlenwasser-          stoffe    und     Silicone    als schmierende Komponenten,  und     Hexylenglykol    und andere     Alkohole    und Äther  als verdünnende Komponenten. Ausserdem können  die üblichen Zusatzstoffe, wie     Antioxydationsmittel,          Antikorrosionsmittel    usw., verwendet werden.  



  Beispiele von Flüssigkeiten gemäss der Erfindung  und ihre Eigenschaften sind in der nachstehenden  Tabelle zusammengestellt.    
EMI0003.0001     
  
    Verdünnungskomponenten <SEP> Äthyldiglykol <SEP> 56/o <SEP> Butylglykol <SEP> <B>g <SEP> o/'</B> <SEP> Butylglykol <SEP> <B>7-/'</B> <SEP> Butylglykol <SEP> 10
<tb>  Butyldiglykol <SEP> 50% <SEP> Äthyldiglykol <SEP> 37 /a <SEP> Butyldiglykol <SEP> 50%
<tb>  Schmierende <SEP> Komponenten <SEP> oxydiertes <SEP> nichtoxydiertes <SEP> oxydiertes <SEP> oxydiertes
<tb>  modifiziertes <SEP> Rizinusöl <SEP> modifiziertes <SEP> Rizinusöl <SEP> modifiziertes <SEP> Rizinusöl <SEP> modifiziertes <SEP> Rizinusöl
<tb>  (Viskosität <SEP> 55 <SEP> Poise <SEP> bei <SEP> (Viskosität <SEP> 30 <SEP> Poise <SEP> (Viskosität <SEP> 100 <SEP> Poise <SEP> (Viskosität <SEP> 600 <SEP> Poise
<tb>  200;

   <SEP> Säurezahl <SEP> 5) <SEP> 21% <SEP> bei <SEP> 20o) <SEP> <B>260/,</B> <SEP> bei <SEP> 200) <SEP> 210/, <SEP> bei <SEP> 20-) <SEP> 20
<tb>  Sebacinsäure  Polyoxypropylenglykol <SEP> Sebacinsäure- <SEP> Dioctylester <SEP> 210/, <SEP> Sebacinsäure  (Molgewicht2000) <SEP> 23% <SEP> Dioctylester <SEP> 16% <SEP> Rizinusöl <SEP> 14% <SEP> Dioctylester <SEP> .20 /a
<tb>  Viskositätsindex <SEP> 173 <SEP> 192 <SEP> 151 <SEP> <B>131</B>
<tb>  Viskosität, <SEP> Centistokes <SEP> bei <SEP> 50  <SEP> 12,8 <SEP> 12,6 <SEP> 12,4 <SEP> 12,0
<tb>  Fliesspunkt <SEP> (ASTM)

   <SEP>  <  <SEP> - <SEP> 60  <SEP>  < -51o <SEP>  <  <SEP> - <SEP> 40  <SEP>  <  <SEP> - <SEP> 40 
<tb>  Flammpunkt <SEP> 9401 <SEP> <B>106112</B> <SEP> - <SEP>   Fraktion <SEP> destilliert <SEP> bei <SEP> 175  <SEP> nichts <SEP>  <  <SEP> 10/0 <SEP> 10/0 <SEP>  <  <SEP> 1 <SEP>  /a
<tb>  Absorbierbares <SEP> Wasser <SEP> 81)/o <SEP> 2 <SEP> % <SEP> <B>3,51/0 <SEP> 3,51/0</B>
<tb>  Schaum-Neigung <SEP> keine <SEP> ' <SEP> ' <SEP> f
<tb>  Säurezahl <SEP> 0,8 <SEP> 1,3 <SEP> 2,5 <SEP>   Hochdruckverhalten,
<tb>  Belastung,

   <SEP> kg <SEP> <B>803</B> <SEP> - <SEP> - <SEP>   Wirkung <SEP> auf <SEP> Aluminium  legierungen <SEP> keine <SEP> keine <SEP> - <SEP>   Wirkung <SEP> auf <SEP> Kautschuk  dichtung
<tb>  Gewichtsverlust <SEP> pro <SEP> em2 <SEP> 3 <SEP> mg <SEP> - <SEP> - <SEP>   Gewichtszunahme <SEP> pro <SEP> cm2 <SEP> keine <SEP> - <SEP> - <SEP>   Abnahme <SEP> der <SEP> Härte
<tb>  (ASTM-Durometer) <SEP>  <  <SEP> 2 <SEP> Punkte <SEP> - <SEP> - <SEP>   1 <SEP> In <SEP> geschlossenem <SEP> Becher <SEP> (AFNOR).
<tb>  2 <SEP> In <SEP> offenem <SEP> Cleveland-Becher.
<tb>  3 <SEP> Anfressen <SEP> nach <SEP> 2,5 <SEP> Sekunden <SEP> in <SEP> einem <SEP> Vierkugelapparat <SEP> (Bauart <SEP> Shell).



  Fluid suitable as a lubricant and power transmission The present invention relates to a fluid which can be used for lubrication purposes and for mechanical power transmission. Such liquids are used in particular for braking devices as well as suspension or storage and steering devices in vehicles equipped with motors and for transmissions.



  For liquids of this type to work satisfactorily under the application conditions, they must have good lubricating properties over a wide temperature and pressure range. They also need to have a suitable viscosity. A highly viscous liquid avoids excessive leakage or sliding in hydraulic pumps, but it shows a high resistance to movement and thus causes high power consumption. On the other hand, liquids of very low viscosity flow rapidly; however, they encourage excessive licking and produce poor effects. In many cases, viscosities of about 12 to 13 centistokes at 50 are required.

   Hydraulic fluids must be usable over a very wide temperature range. They must therefore have a high viscosity index, i.e. show a slight shift in viscosity with changes in temperature. They must not freeze out or solidify even in very low winter temperatures. Their boiling point must be high enough so that they do not evaporate during use. It also requires a high flash point and some tolerance to water. Chemically, the liquid should be practically inert to the substances from which the various parts of a hydraulic system are made.

   For example, the liquid must not contain any substances that corrode metals, and it must not attack rubber. A known type of fluid of this type consists of a lubricating component and a diluting component.

   A specific example of a liquid of this type contains about 50 vol. O / o castor oil and about 50 vol. O / o diacetone alcohol. In other liquids of this type other compounds are used as the lubricating element, such as the esters of ricinoleic acid or polypropylene glycol, or other alcohols or ethers in the diluent, or the lubricant and the diluting elements are mixed in ratios other than 50:50.



  However, it is very difficult to achieve an optimal combination of properties, and so far it has not been possible to produce a liquid which at the same time meets the very strict requirements in all respects. It is an aim of the present invention to solve this problem in an internally satisfactory manner.



  The liquid according to the present invention also contains lubricating and thinning components. Ingredients that act as lubricants: An essential component is obtained by heating castor oil until it has a viscosity between 20 and 600 poise at 20. The castor oil is heated to a relatively low temperature so that it has an acid number below 20 and preferably below 5. The castor oil will likely polymerize as it is heated. This product is hereinafter referred to as modified castor oil.



  In order to obtain a liquid with high resistance to water, that is to say in order to achieve that the liquid can absorb relatively large amounts of water without phase separation occurring, the castor oil can be oxidized during heating, e.g. B. by bubbling air or some other oxygen-containing gas through the oil. It appears that oxygen bridges are formed between the double bonds of ricinoleic acid and that polymerization occurs as a result.



  As a further lubricating component, the liquid according to the invention contains a liquid polyoxyalkylene, preferably of the formula R17 O- [R20] ri R3. In this formula, R1 and R3 each denote a hydrogen atom or a hydrocarbon radical (preferably aliphatic) or an acyl group. R2 denotes an alkylene radical and n an integer.

   In the polyoxyalkylene chain - [R20] ri, the R2 radical can mean any alkylene radical, preferably an alkylene radical having 2 to 8 carbon atoms.



  The polyoxyalkylene chain - [R20] ri can contain alkylene radicals which have a different number of carbon atoms. For example, this chain can contain oxyethylene and oxypropylene radicals.

    If the polyoxyalkylene chain contains various alkylene radicals, these can be distributed arbitrarily over the molecule or arranged in regularly repeating units or blocks, each of which consists of one or more similar oxyalkylene radicals.



  The polyoxypropylene glycols are particularly suitable for use in liquids according to the present invention.



       Preferred polyoxyalkylenes have molecular weights between 800 and 4000 or, particularly advantageously, between 1000 and 3000. Polyoxypropylene glycols with a molecular weight of about 2000 are extremely effective.



  Instead of or in connection with the polyoxyalkylenes, neutral esters of aliphatic dicarboxylic acids can be used, preferably those of the formula WOOC - R - COOR ", in which R is a divalent, saturated aliphatic hydrocarbon radical and R 'and R" are alkyl, aralkyl - Or cycloalkyl radicals which contain more than two carbon atoms.



  The esters are preferably derived from saturated aliphatic dicarboxylic acids, e.g. B. of malon, ethyl malon, amber, methyl amber, 1,1- or 1,2-diethyl amber, glutar, 1- or 2 methyl-glutar, 1,3-diethyl-glutar -, adipine-1 or 2-methyladipine, pimeline, 1,2,5-trimethyl-pimeline, suberine, azelaine,

          Sebacic, nonane, 1,9-dicarboxylic and decane-1,10-dicarboxylic acid, and preferably propanols, butanols, hexanols, octanols and nonanols, or aralkanols, e.g. B. benzyl and phenylethyl alcohol, or cycloalkanols, e.g.

   B. cyclopentanol, cyclohexanol and methylcyclohexanol. Examples of suitable liquid esters are di- (2-methyl-heptyl) adipate, di- (3,5,5-trimethylhexyl) adipate or di- (3,5,5-trimethyl sebacate) -hexyl) ester, adipic acid di- (3-ethyl-hexyl) -ester or sebacic acid-di- (3-ethyl-hexyl) -ester, penelic acid-di-hexyl ester, sebacic acid-di- (2-ethyl-hexyl) ) ester, di-sec-butyl sebacate,

            Malonic acid di-sec-butyl ester, azelaic acid di (1-ethylpropyl) ester and malonic acid dibutylethyl ester. In order to obtain a liquid with high water resistance, the use of a polyoxyalkylene liquid is preferable to the use of a neutral ester of an aliphatic dicarboxylic acid.

         Diluting components: Their proportion is 35 to 70% by weight, preferably 40 to 60% by weight of the liquid.



  One or more alkyl ethers of polyhydric alcohols are used for this. Alkyl ethers of aliphatic polyhydric alcohols, in particular the monoalkyl ethers, are preferred. The monoalkyl ethers of glycol and diglycol are particularly suitable.



  Examples of suitable ethers are monoethyl ether, monopropyl ether, mono-n-butyl ether, monoisobutyl ether, mono-tert-butyl ether, monohexylbutyl ether of ethylene glycol, the monoisoamyl ether of propylene glycol, the monomethyl ether of diethylene glycol,

          Mono-n-propyl ether of diethylene glycol, monoisopropyl ether of diethylene glycol, monobutyl ether of diethylene glycol, monodecyl ether of diethylene glycol, monoethyl ether of dipropylene glycol, monoisopropyl ether of dipropylene glycol,

          Monoisoamyl ether of dipropylene glycol, monoisopropyl ether of diisobutylene glycol, monoethyl ether of ethylene propylene glycol, monoisopropyl ether of ethylene isobutylene glycol.



  The following list shows favorable proportions (by weight) for the various components of the liquid.
EMI0002.0167
  
    Thinning <SEP> components: <SEP> 40 <SEP> to <SEP> 60 <SEP> 0/0
<tb> Lubricating <SEP> components: <SEP> 60 <SEP> to <SEP> 4011 / o
<tb> modified <SEP> castor oil
<tb> (oxidizes <SEP> or <SEP> not <SEP> oxidizes) <SEP> 5-40%
<tb> Polyoxyalkylene <SEP> and / or <SEP> neutral <SEP> ester <SEP> of an <SEP> aliphatic
<tb> Dicarboxylic acid <SEP> 5-30% Other components that are known as components for hydraulic fluids can be added, such as

   B. unmodified castor oil, ricinoleic acid esters, phosphates, halogenated hydrocarbons and silicones as lubricating components, and hexylene glycol and other alcohols and ethers as diluting components. In addition, the usual additives such as antioxidants, anticorrosive agents, etc. can be used.



  Examples of liquids according to the invention and their properties are compiled in the table below.
EMI0003.0001
  
    Diluent components <SEP> Ethyl diglycol <SEP> 56 / o <SEP> Butyl glycol <SEP> <B> g <SEP> o / '</B> <SEP> Butyl glycol <SEP> <B> 7- /' </B> <SEP> butyl glycol <SEP> 10
<tb> butyl diglycol <SEP> 50% <SEP> ethyl diglycol <SEP> 37 / a <SEP> butyl diglycol <SEP> 50%
<tb> Lubricating <SEP> components <SEP> oxidized <SEP> non-oxidized <SEP> oxidized <SEP> oxidized
<tb> modified <SEP> castor oil <SEP> modified <SEP> castor oil <SEP> modified <SEP> castor oil <SEP> modified <SEP> castor oil
<tb> (viscosity <SEP> 55 <SEP> poise <SEP> at <SEP> (viscosity <SEP> 30 <SEP> poise <SEP> (viscosity <SEP> 100 <SEP> poise <SEP> (viscosity <SEP > 600 <SEP> poise
<tb> 200;

   <SEP> acid number <SEP> 5) <SEP> 21% <SEP> with <SEP> 20o) <SEP> <B> 260 /, </B> <SEP> with <SEP> 200) <SEP> 210 / , <SEP> at <SEP> 20-) <SEP> 20
<tb> sebacic acid polyoxypropylene glycol <SEP> sebacic acid <SEP> dioctyl ester <SEP> 210 /, <SEP> sebacic acid (molecular weight 2000) <SEP> 23% <SEP> dioctyl ester <SEP> 16% <SEP> castor oil <SEP> 14% <SEP> dioctyl ester <SEP> .20 / a
<tb> Viscosity index <SEP> 173 <SEP> 192 <SEP> 151 <SEP> <B> 131 </B>
<tb> Viscosity, <SEP> Centistokes <SEP> at <SEP> 50 <SEP> 12.8 <SEP> 12.6 <SEP> 12.4 <SEP> 12.0
<tb> Flow point <SEP> (ASTM)

   <SEP> <<SEP> - <SEP> 60 <SEP> <-51o <SEP> <<SEP> - <SEP> 40 <SEP> <<SEP> - <SEP> 40
<tb> Flash point <SEP> 9401 <SEP> <B> 106112 </B> <SEP> - <SEP> fraction <SEP> distilled <SEP> at <SEP> 175 <SEP> nothing <SEP> <<SEP> 10/0 <SEP> 10/0 <SEP> <<SEP> 1 <SEP> / a
<tb> Absorbable <SEP> water <SEP> 81) / o <SEP> 2 <SEP>% <SEP> <B> 3.51 / 0 <SEP> 3.51 / 0 </B>
<tb> Foam tendency <SEP> none <SEP> '<SEP>' <SEP> f
<tb> acid number <SEP> 0.8 <SEP> 1.3 <SEP> 2.5 <SEP> high pressure behavior,
<tb> burden,

   <SEP> kg <SEP> <B> 803 </B> <SEP> - <SEP> - <SEP> Effect <SEP> on <SEP> aluminum alloys <SEP> none <SEP> none <SEP> - <SEP > Effect <SEP> on <SEP> rubber seal
<tb> Weight loss <SEP> per <SEP> em2 <SEP> 3 <SEP> mg <SEP> - <SEP> - <SEP> Weight gain <SEP> per <SEP> cm2 <SEP> none <SEP> - <SEP > - <SEP> decrease <SEP> of the <SEP> hardness
<tb> (ASTM durometer) <SEP> <<SEP> 2 <SEP> points <SEP> - <SEP> - <SEP> 1 <SEP> In <SEP> closed <SEP> cup <SEP> (AFNOR) .
<tb> 2 <SEP> In <SEP> open <SEP> Cleveland cup.
<tb> 3 <SEP> erosion <SEP> after <SEP> 2.5 <SEP> seconds <SEP> in <SEP> a <SEP> four-ball apparatus <SEP> (type <SEP> Shell).

Claims (1)

PATENTANSPRUCH Als Schmiermittel und für mechanische Kraft übertragung geeignete Flüssigkeit, dadurch gekenn zeichnet, dass sie einen oder mehrere Alkyläther mehrwertiger Alkohole als Verdünner in einer Menge von 35 bis 70 Gew: PATENT CLAIM As a lubricant and fluid suitable for mechanical power transmission, characterized in that it contains one or more alkyl ethers of polyhydric alcohols as thinners in an amount of 35 to 70% by weight: o/o enthält, sowie als schmierend wirkende Komponenten in einer Gesamtmenge von 30 bis 65 Gew.o/o ein modifiziertes Rizinusöl mit einer Viskosität von 20 bis 600 Poise bei 20 und einer Säurezahl unter 20, wie es durch Erhitzen allein oder unter Erhitzen und Durchleiten von sauerstoff haltigen Gasen erhalten wird, und ferner ein flüssiges Polyoxyalkylen und/oder einen neutralen Ester einer aliphatischen Dicarbonsäure. UNTERANSPRÜCHE 1. o / o contains, as well as lubricating components in a total amount of 30 to 65 wt. o / o a modified castor oil with a viscosity of 20 to 600 poise at 20 and an acid number below 20, as is achieved by heating alone or with heating Passing oxygen-containing gases is obtained, and also a liquid polyoxyalkylene and / or a neutral ester of an aliphatic dicarboxylic acid. SUBCLAIMS 1. Flüssigkeit nach Patentanspruch, dadurch ge kennzeichnet, dass sie einen oder mehrere Monoalkyl- äther mehrwertiger aliphatischer Alkohole enthält. 2. Flüssigkeit nach Unteranspruch 1, dadurch gekennzeichnet, dass die Alkyläther mehrwertiger Alkohole von Glykol oder Diglykol abgeleitet sind. 3. Flüssigkeit nach Patentanspruch, dadurch ge kennzeichnet, dass sie 5 bis 40 Gew:O/o modifiziertes Rizinusöl enthält. 4. Liquid according to patent claim, characterized in that it contains one or more monoalkyl ethers of polyvalent aliphatic alcohols. 2. Liquid according to dependent claim 1, characterized in that the alkyl ethers of polyhydric alcohols are derived from glycol or diglycol. 3. Liquid according to claim, characterized in that it contains 5 to 40 wt: O / o modified castor oil. 4th Flüssigkeit nach Patentanspruch, dadurch ge kennzeichnet, dass sie ein modifiziertes Rizinusöl ent hält, wie es unter Erhitzen und Durchleiten eines sauerstoffhaltigen Gases, z. B. Luft, erhältlich ist. 5. Flüssigkeit nach Patentanspruch, dadurch ge kennzeichnet, dass das Polyoxyalkylen ein Molgewicht zwischen 800 und 4000 aufweist. 6. Flüssigkeit nach Patentanspruch, dadurch ge kennzeichnet, dass als Polyoxyalkylen Polyoxypro- pylenglykol verwendet wird. 7. Liquid according to claim, characterized in that it holds a modified castor oil ent as it is heated and passed through an oxygen-containing gas, for. B. air is available. 5. Liquid according to claim, characterized in that the polyoxyalkylene has a molecular weight between 800 and 4000. 6. Liquid according to claim, characterized in that the polyoxyalkylene used is polyoxypropylene glycol. 7th Flüssigkeit nach Patentanspruch, dadurch ge kennzeichnet, dass das Polyoxyalkylen und/oder der neutrale Ester einer aliphatischen Dicarbonsäure 5 bis 30 Gew:o/o der Flüssigkeit beträgt. B. Flüssigkeit nach Patentanspruch, dadurch ge kennzeichnet, dass sie zusätzlich nicht modifiziertes Rizinusöl enthält. Liquid according to claim, characterized in that the polyoxyalkylene and / or the neutral ester of an aliphatic dicarboxylic acid is 5 to 30% by weight of the liquid. B. Liquid according to claim, characterized in that it additionally contains unmodified castor oil.
CH5261957A 1956-11-15 1957-11-13 Liquid suitable as a lubricant and for power transmission CH367921A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR725783A FR1160313A (en) 1956-11-15 1956-11-15 Fluid usable for lubrication and mechanical transmission of forces

Publications (1)

Publication Number Publication Date
CH367921A true CH367921A (en) 1963-03-15

Family

ID=8703949

Family Applications (1)

Application Number Title Priority Date Filing Date
CH5261957A CH367921A (en) 1956-11-15 1957-11-13 Liquid suitable as a lubricant and for power transmission

Country Status (8)

Country Link
AT (1) AT202252B (en)
BE (1) BE562331A (en)
CH (1) CH367921A (en)
DE (1) DE1041623B (en)
DK (1) DK95147C (en)
FR (1) FR1160313A (en)
GB (1) GB824478A (en)
NL (2) NL222432A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1218096B (en) * 1961-07-26 1966-06-02 Huels Chemische Werke Ag Hydraulic fluid
US3652411A (en) * 1969-12-04 1972-03-28 Mobil Oil Corp Polyglycol base lubricant
US20220251465A1 (en) * 2019-04-26 2022-08-11 3M Innovative Properties Company Lubricating oil compositions

Also Published As

Publication number Publication date
GB824478A (en) 1959-12-02
DK95147C (en) 1963-01-14
NL222432A (en)
NL107075C (en)
DE1041623B (en) 1958-10-23
FR1160313A (en) 1958-07-11
AT202252B (en) 1959-02-25
BE562331A (en)

Similar Documents

Publication Publication Date Title
DE2147416C2 (en) Hydraulic fluids that are insensitive to water
DE19703083A1 (en) Low-foaming emulsifier system and emulsion concentrate containing it
DE2107095C3 (en) Functional fluids and their uses
EP2721126A1 (en) Lubricating grease based on perfluoropolyether
DE1104103B (en) High pressure additive for lubricating oils
CH367921A (en) Liquid suitable as a lubricant and for power transmission
DE1063311B (en) Lubricating oil
EP0184043A2 (en) Lubricant additive
DE2039785A1 (en) Lubricant additive and its use in lubricants for gas turbines
DE1262486B (en) Synthetic lubricant additives based on diorthosilicic acid esters
DE19622573A1 (en) Damping medium used in damper device
DE2244028A1 (en) SURFACE-ACTIVE AGENTS CONTAINING HIGHLY FLUOROUS GROUPS
DE1056314B (en) High pressure lubricant for turbine jet engines and turbine propeller machines of aircraft
DE1006998B (en) Hydraulic fluid
DE68916200T2 (en) Anti-rust and anti-corrosion compositions.
DE2600879C2 (en) Hydraulic fluid for central vehicle hydraulic systems
DE1105547B (en) Lubricating oil
DE2456852A1 (en) LIQUID PREPARATIONS AND THEIR USE AS LUBRICANTS AND HYDRAULIC LIQUIDS
DE972646C (en) Synthetic lubricating oil
DE711387C (en) Pressing and lubricating fluid for hydraulic pressure systems
WO1991009096A2 (en) Non-volatile solvent for aroma-containing active ingredients
EP0013925A1 (en) Brake fluids for motor vehicles
DE974140C (en) Process for improving the solubility and miscibility of naphthenic acid salts which contain monovalent or polyvalent cations in or with hydrocarbons
DE1003900B (en) Grease
DE946652C (en) Lubricant and hydraulic fluid