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CA3119677A1 - Apparatuses and methods for carbon dioxide capturing and electrical energy producing system - Google Patents

Apparatuses and methods for carbon dioxide capturing and electrical energy producing system Download PDF

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Publication number
CA3119677A1
CA3119677A1 CA3119677A CA3119677A CA3119677A1 CA 3119677 A1 CA3119677 A1 CA 3119677A1 CA 3119677 A CA3119677 A CA 3119677A CA 3119677 A CA3119677 A CA 3119677A CA 3119677 A1 CA3119677 A1 CA 3119677A1
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hydrogen
carbon dioxide
oxygen
unit
gases
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French (fr)
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Solomon Asfha
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0407—Constructional details of adsorbing systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1475—Removing carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/229—Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
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    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/50—Processes
    • C25B1/55—Photoelectrolysis
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C25B15/081—Supplying products to non-electrochemical reactors that are combined with the electrochemical cell, e.g. Sabatier reactor
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
    • F02C3/20—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products
    • F02C3/22—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products the fuel or oxidant being gaseous at standard temperature and pressure
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M16/00—Structural combinations of different types of electrochemical generators
    • H01M16/003—Structural combinations of different types of electrochemical generators of fuel cells with other electrochemical devices, e.g. capacitors, electrolysers
    • H—ELECTRICITY
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    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
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    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • H01M8/184—Regeneration by electrochemical means
    • H01M8/186—Regeneration by electrochemical means by electrolytic decomposition of the electrolytic solution or the formed water product
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/22—Fuel cells in which the fuel is based on materials comprising carbon or oxygen or hydrogen and other elements; Fuel cells in which the fuel is based on materials comprising only elements other than carbon, oxygen or hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/30—Alkali metal compounds
    • B01D2251/304—Alkali metal compounds of sodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
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    • B01D2251/60—Inorganic bases or salts
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D2252/102—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D2252/204—Amines
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20484—Alkanolamines with one hydroxyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
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    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
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    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D2258/0283—Flue gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
    • H—ELECTRICITY
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    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01—ELECTRIC ELEMENTS
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    • H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
    • H01M2250/40—Combination of fuel cells with other energy production systems
    • H01M2250/402—Combination of fuel cell with other electric generators
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    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M2250/40—Combination of fuel cells with other energy production systems
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    • H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
    • H01M2250/40—Combination of fuel cells with other energy production systems
    • H01M2250/407—Combination of fuel cells with mechanical energy generators
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    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02E60/30—Hydrogen technology
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Abstract

The present invention is an integrated system of a carbon dioxide capturing processes from the atmosphere and producing electrical energy from the integrated system. The objective of the current invention is; capturing carbon dioxide from the air through the tree fashioned carbon dioxide capturing system and generating electric power through the integrated systems. To generate electric power at maximum efficiency, and capture carbon dioxide, the present invention comprises different integrated processes, integrated systems, and techniques. The present system comprises; an ionized and non-ionized hydrogen gas turbine system unit, carbon dioxide capturing tree system unit, a hybrid thermoelectric-generator and solid oxide fuel cell system unit, a hybrid hydrogen-chlorine fuel cell and carbon dioxide reactor core system unit. Furthermore, to capture carbon dioxide and generate electric power, the present invention comprises various other alternative embodiments.

Description

Title: APPARATUSES AND METHODS FOR CARBON DIOXIDE CAPTURING AND ELECTRICAL
ENERGY PRODUCING SYSTEM
Inventor and owner: SOLOMON ALEMA ASFHA
Field of the Invention The present invention relates to processes, apparatus, and methods for carbon dioxide capturing through a tree fashioned carbon dioxide capturing system and electrical energy producing system. More specifically, the present invention relates to an integrated system of producing electrical energy through the integrated system and capturing carbon dioxide through a tree fashioned system.
Background of the invention The present invention relates to carbon dioxide capture systems, and electric power generating system, more specifically to carbon dioxide capture systems that capture from the atmosphere.
On our Earth, billions of metric tons of greenhouse gases are annually released into the atmosphere. Carbon emission is the major pollutant of the atmosphere. This in turn has made the polar icebergs meltdown, exposing to various health threats, irregular rainfall, desertification, and the like. The huge amounts of carbon dioxide emissions coming out from vehicles and factories have worsened the world's climate from time to time.
Emissions of carbon dioxide have made to increase the temperature of the globe. Due to recent global warming, the polar icecaps have been melting, causing a rise in the sea level.
Recent climate changes have caused unusual weather phenomena around the world.
Global warming is known to be attributed to increased carbon dioxide emissions.
Different Strategies to reduce the emission of carbon dioxide have been directed towards the development of alternative energy sources, such as hydrogen energy, solar energy and wind energy capable of replacing fossil fuels, and techniques for the capture and storage of carbon dioxide from the atmosphere or fossil fuels while preventing the carbon dioxide from being released into the.
Page 1 of 49 Date recue/Date received 2023-04-19 Producing electricity from coal, natural gas and biomass leads to the emission of carbon dioxide. The carbon dioxide capturing technologies are utilized to capture carbon dioxide from power plant stations or from the air/atmosphere. There are different types of carbon dioxide capture; pre-combustion, post-combustion, oxyfuel with post-combustion, ambient air capture, and biosequestration. The pre-combustion process converts fuel into the gaseous mixture of hydrogen and carbon dioxide. The hydrogen gas is separated and can be burnt without producing any carbon dioxide, and the carbon dioxide can then be compressed for transport and storage. The post-combustion process separates carbon dioxide from combustion exhausted gases. The carbon dioxide can be captured using a liquid solvent or other separation methods. The oxyfuel combustion is use oxygen rather than air for the combustion of fuel. This produces exhaust gas that mainly water vapour and carbon dioxide, and then separates the carbon dioxide from the water vapour. The ambient air capture is a process of capturing carbon dioxide directly from ambient air/
atmosphere/ and generating a concentrated stream of carbon dioxide for sequestrating or utilizing or production of carbon based products. The biosequestration capture is capturing and storing carbon dioxide from the atmosphere by plants and micro-organisms by continual or enhanced biological process.
Furthermore, based on the carbon dioxide separation techniques, there are different kinds of carbon dioxide capture techniques; the membrane separation, liquid separation, solid separation and cryogenic separation. The membrane separation techniques use separation membranes to concentrate carbon dioxide, the liquid separation techniques use liquid adsorbents such as amines or aqueous ammonia, the solid separation techniques use solid adsorbents such as alkali or alkaline earth metals, and the cryogenic separation is the separation of material at a temperature that is below the freezing point.
To capture carbon dioxide from environment or flue gas, most carbon capturing technologies consume a huge amount of external energy. This is the main cause to increase the cost of the carbon dioxide capturing technologies. Therefore, to solve this problem it is very important to develop new and efficient carbon dioxide capturing and electrical energy producing technology by designing a new hybrid and integrated system. The present Page 2 of 49 Date recue/Date received 2023-04-19 invention is capturing carbon dioxide from the atmosphere or flue gases, and generating electrical energy by itself.
Benefits of the present invention The present invention captures carbon dioxide from the atmosphere or flue gases, and the invention creates a difference to reduce climate change, global warming, and air pollution, and at the same time which can increase the availability of energy from the oil. In addition to that, the present invention included an integrated system to produce electrical energy for output commercialization purposes. Direct capturing of carbon dioxide from the atmosphere is one of the excellent techniques to reduce carbon dioxide emissions. The art of the present invention is capturing carbon dioxide from the atmosphere and producing electric power from the integrated system.
The objective of the present invention is;
i. Capturing carbon dioxide from the atmosphere ii. Generating electric power iii. Creating economically viable carbon dioxide capturing and electric power generating system iv. minimizing external gird power consumption for carbon dioxide capturing purpose and utilizing from internally generated electric power v. Increasing carbon dioxide capturing efficiency vi. Increase electric power generating efficiency In the present invention, several systems and techniques are hybrid, working together and integrated for the purpose of; carbon dioxide capturing and electric power generating system.
In the current invention, the integration of the various systems creates;
i. to increase in efficiency, ii. to create new output; to capturing carbon dioxide and generating electric power iii. to create new cost-effective capturing carbon dioxide and generating electric power system.
Problem to be solved: - nowadays to capture carbon dioxide from the atmosphere or flue gas is an excellent way to treat carbon emission and climate change problems.
However, Page 3 of 49 Date recue/Date received 2023-04-19 capturing carbon dioxide from the atmosphere or flue gas consumes a lot of external energy. In most carbon capturing technologies, the electrical energy comes from external gird/sources. The high electric power consumption in carbon dioxide capturing technologies is the most challenging part in most carbon dioxide capturing technologies.
To address this problem, the current invention is designed to captures carbon dioxide and to generate electric power by itself. For the purpose of carbon dioxide capturing and electric power generating, the present invention comprises an integrated and hybrid system, techniques and processes. In the present invention, enough electric power is generated in the system. And to capture carbon dioxide, the system utilizes electric power from internally generated power. Furthermore, the generated electric power from the system is utilizes for external output power for commercialization purposes.
Some of the solved problems by the current invention are;
1. To reduce external power consumption for carbon dioxide capturing process.
by 95%, and instead of that generating Electric power from the integrated system,
2. To increase the carbon dioxide absorption rate. The carbon dioxide reactor core system unit and tree fashioned carbon dioxide capturing system unit, designed to utilize exhausted waste heat from hydrogen gas turbine and solid oxide fuel cells. To utilize the exhaust waste heat; the exhaust waste heat circulates in the carbon dioxide reactor core system unit and tree fashioned carbon dioxide capturing system unit. When the temperature of the reactants increase, the absorption rate and reaction rate of carbon dioxide also increase. Therefore, to increase the temperature of the gases inside of the carbon dioxide reactor core system unit and carbon dioxide capturing tree system utilizes exhausted waste heat, and it does not need to install the electric heater. Instead, the present systems use heat energy from waste heat, the waste heat flows through the carbon dioxide reactor core and tree fashioned carbon dioxide capturing system. And increase the temperature of the gases inside of the carbon dioxide reactor core and tree fashioned carbon dioxide capturing system. When the temperature of the gases increase the absorbing rate of carbon dioxide in sodium hydroxide solution increase and the efficiency also parallel increased. Therefore, the present invention utilizes Page 4 of 49 Date recue/Date received 2023-04-19 exhausted waste heat to increase the efficiency of the carbon dioxide capturing rate.
The philosophy of the invention is; capturing carbon dioxide and at the same time generating electric power and this creates to reduce carbon emission impacts in our environment. In the present system, it produces a large amount of electrical power, with zero Carbone emission and zero air pollutions. This helps to create a difference in improving climate change and global warming problems.
In the brief description part of the present invention, the terms of carbon dioxide reactor core is equal meaning with carbon dioxide reactor chamber, the hydrogen gas turbine is equal meaning with hydrogen gas combustion turbine, the meaning of "carbon dioxide capturing tree" is the same term as "tree fashioned carbon dioxide capturing system", and means the carbon dioxide capturing machine is having tree structure, the word integrated is meaning with working to gather or connected or fixed or mounted.
For purposes of clarity, the description of the invention is divided into the form of a unit of systems. The combination and integration of all units of systems create the carbon dioxide capturing and electrical energy producing system invention. And in each unit of the system;
the processes, arrangements, physical structures, methods, and systems are briefly described.
Other aspects, embodiments, and features of the invention will become apparent from the following detailed description when considered in conjunction with the accompanying drawings. For purposes of clarity, some common or known systems, knowledge, parts, and arrangements are not described. Nor is every component of the embodiment of the invention described or shown where illustrations not necessary to allow those of ordinary skill in the art to understand the invention. For purposes of clarity, some common components or known systems are not labeled in every figure.
In a different way, the present invention uses as a power plant which means to produce electric power, from water/hydrogen. At the same time, the system captures Co2 from the environment. Due to these facts, the current invention is an environmentally friendly green-energy invention. For the benefit of human being, the core principle of the present invention is; "capturing carbon emission from the environment and producing electrical energy by itself".
Page 5 of 49 Date recue/Date received 2023-04-19 Summary of the present invention The current invention relates to the apparatuses and methods for capturing carbon dioxide and generating electrical power from the integrated system. The art of the invention creates to increasing the efficiency of electricity production from the system, and to boost the carbon dioxide reaction systems by designing an efficient reactor core. In the present invention, a lot of different techniques, systems, and processes are integrated, embedded, and working together. The description of the present invention focuses on the new way of the art and skills of the carbon dioxide capturing and electric power generating system.
The current invention comprising;
(a) non-ionized hydrogen gas turbine unit; to generating electric power from hydrogen and oxygen gases, (b) Ionized hydrogen gas turbine unit; to generating electric power from ionized hydrogen and oxygen gases, (c) hybrid thermoelectric-generator and solid oxide fuel cell unit; for cogenerating electrical power from hydrogen-oxygen solid oxide fuel cell and from waste heat which released from the solid oxide fuel cell (d) Tree fashioned carbon dioxide capturing system unit /carbon dioxide capturing tree unit/; to extracting and capturing carbon dioxide from the atmosphere, and the physical structure of carbon dioxide capturing system unit is fashioned as a tree structure.
(e) The hybrid solar hydrogen-oxygen gas generator system unit is; to produce uninterrupted hydrogen gas and oxygen gas, and to feeding hydrogen gas to the other parts of the present invention.
(f) Electrolysis of brine unit: for producing sodium hydroxide to carbon dioxide reactor core, and for producing hydrogen and chlorine gases for hybrid hydrogen-chlorine fuel cell and carbon dioxide reactor core system unit (g) hybrid hydrogen-chlorine fuel cell and carbon dioxide reactor core system unit;
for generating electrical power from output chlorine gas, and to powered carbon dioxide reactor core by hydrogen chlorine fuel cell, and to converting Co2 gas into carbonate outputs, and to reduce the consumption of electrical power by carbon dioxide reactor core Page 6 of 49 Date recue/Date received 2023-04-19 (h) a waste recovery system unit; to utilize the energy of exhaust heat from hydrogen gas turbine, solid oxide fuel cell, hydrogen-chlorine fuel cell, and carbon dioxide reactor core. The waste heat recovery system unit uses to recover waste heat, and utilized to drive an additional steam turbine, and generate additional electric power.
The present invention comprises different "other alternative systems", for example; the ionized hydrogen gas turbine having the other alternative embodiment of non-ionized hydrogen gas turbine, the carbon dioxide reactor core having the other alternative embodiment of the carbon dioxide reactor core.
Furthermore, the present invention of the carbon dioxide and electrical energy producing system comprises three different other alternative embodiments. The other three alternative embodiments create different choices with different kinds of products for customers. The other three alternative embodiments of the invention include different alternative embodiments, and each embodiment has different arrangements, integrations, efficiencies, and costs.
The carbon dioxide capturing and electrical energy producing system wherein a hydrogen gas turbine unit, hybrid thermoelectric-generator solid oxide fuel cell unit, solar hybrid hydrogen-oxygen gas generator system unit, hybrid hydrogen chlorine fuel cell with carbon dioxide reactor core unit and waste heat recovery system units are physically or electrically or mechanically coupled and integrated each other. The hybrid and integration of a variety units of systems create to achieve the objective of capturing carbon dioxide and generating electrical power from the system.
The descriptions of the current processes, integrations, hybrids, and methods, are exemplary and non-limiting. Certain Substitutions, modifications, and/ or rearrangements over the present invention are disclosed by the owner of the invention.
Page 7 of 49 Date recue/Date received 2023-04-19 Brief description of the drawing Fig.1. A system and apparatus of a carbon dioxide capturing and electrical energy producing invention- with non-ionized hydrogen gas turbine.
Fig.2. A system and apparatus of a carbon dioxide capturing and electrical energy producing invention- with ionized hydrogen gas turbine.
Fig 3.ionized hydrogen gas turbine system unit Fig 4. The resonant radiation emitters diode array Fig 5.Hydrogen/oxygen gas ionization system Fig 6.Hydrogen burning rate regulators and sensors in ionized hydrogen gas turbine fig 7. Hydrogen burning rate regulators and sensors in non-ionized hydrogen gas turbine Fig 8. Arrangements and integrations of hybrid solid oxide fuel cell and thermoelectric generator unit with other unit systems Fig 9. Hybrid solid oxide fuel cell and thermoelectric generator unit system Fig 10. Arrangements and integrations of hybrid solar hydrogen-oxygen gas generator unit with another unit systems Fig 11.Hybrid solar hydrogen-oxygen gas generator unit Fig 12. Arrangements and integrations of hybrid carbon dioxide reactor core and hydrogen-chlorine gas fuel cell unit with another unit systems Fig 13. Hybrid carbon dioxide reactor core and hydrogen-chlorine gas fuel cell unit Fig 14.carbon dioxide reactor core parts Fig 15. The other alternative embodiment of carbon dioxide reactor core Fig 16A. Arrangements and integrations of waste heat generator system unit with another unit system Fig 16B. Arrangements and integrations of waste heat generator system unit with steam turbine unit and another unit system Fig 17. Waste heat generator system unit Fig 18. The other alternative embodiment of a waste heat generator system unit Fig 19. Arrangements and integrations of tree fashioned carbon dioxide capturing system unit with another unit system Page 8 of 49 Date recue/Date received 2023-04-19 Fig 20.Tree fashioned carbon dioxide capturing system unit/carbon dioxide capturing tree unit/
Fig 21. The other alternative embodiment-one of the "carbon dioxide capturing and energy generating system" unit Fig 22. The other alternative embodiment tree fashioned direct carbon dioxide capturing process Fig 23. Tree fashioned direct carbon dioxide capturing process design; for the other alternative embodiment-one, embodiment-two, and embodiment three of "carbon dioxide capturing and energy generating system" units Fig 24. The other alternative embodiment-two of the "carbon dioxide capturing and energy generating system" unit Fig 25. The other alternative embodiment-three of the "carbon dioxide capturing and energy generating system" unit Page 9 of 49 Date recue/Date received 2023-04-19 Detailed Descriptions of the Invention The current invention relates to the apparatuses and methods for capturing carbon dioxide and generating electrical power and the integrated system comprises the unit systems of;
(a) non- ionized hydrogen gas turbine unit; to generating electric power from hydrogen and oxygen gases, (b) Ionized hydrogen gas turbine unit; to generating electric power from ionized hydrogen and oxygen gases, (c) hybrid thermoelectric-generator and solid oxide fuel cell unit; for cogenerating electrical power from hydrogen-oxygen solid oxide fuel cell and from waste heat which released from the solid oxide fuel cell (d) tree fashioned carbon dioxide capturing unit; to extracting and capturing carbon dioxide from the atmosphere, and the physical structure of the carbon dioxide capturing system unit is fashioned as a tree structure.
(e) hybrid solar hydrogen-Oxygen gas generator system unit is; to produce uninterrupted hydrogen gas and oxygen gas, and to feeding hydrogen gas to the other parts of the present invention.
(f) Electrolysis of brine unit: for producing sodium hydroxide to carbon dioxide reactor core, and for producing hydrogen and chlorine gases for hybrid hydrogen-chlorine fuel cell and carbon dioxide reactor core system unit (g) hybrid hydrogen-chlorine fuel cell and carbon dioxide reactor core system unit;
for generating electrical power from output chlorine gas, and to powered carbon dioxide reactor core by hydrogen chlorine fuel cell, and to converting Co2 gas into carbonate outputs, and to reduce the consumption of electrical power by carbon dioxide reactor core.
(h) a waste recovery system unit; to utilize the energy of exhaust heat from hydrogen gas turbine, solid oxide fuel cell, hydrogen-chlorine fuel cell, and from carbon dioxide reactor core. The waste heat recovery system unit uses to recover waste heat, and utilized to drive an additional steam turbine, and generate additional electric power.
Page 10 of 49 Date recue/Date received 2023-04-19 Hydrogen gas turbine unit;
A. Ionized hydrogen gas turbine unit;
In the one embodiment of the present invention, the carbon dioxide capturing and electric power generating system comprises the ionized gas turbine unit system for generating electric power from ionized hydrogen and oxygen. And the ionized gas turbine unit system at least comprises; hydrogen gas and oxygen gas sources, automatic hydrogen gas regulator, oxygen and ambient gases mixing regulator, hydrogen and oxygen resonant cavity, temperature sensor, pressure sensor, compressor, turbine, combustor, and electric generator. In the embodiment of the present invention, a gas turbine utilizes as hydrogen gas turbine, and to control the combustion rate and to increase the efficiency of hydrogen gas turbine the above certain parts are connected and integrated with it.
The ionized gas turbine system unit the oxygen and hydrogen gases are ionized before the gases flow to the combustor. The oxygen and hydrogen gases ionized in the resonant cavity 15 as illustrated in fig 2. And the ionized oxygen and hydrogen ignited in the combustor 16.
As illustrated in fig 2, Oxygen 10 and hydrogen 11 gases interred into different resonant cavities 15, and the oxygen and hydrogen gases ionizes through high voltage and laser energy stimulation, and they become ionized, and the ionized gases of oxygen and hydrogen atoms interred into combustion, in the combustion area oxygen and hydrogen atoms contacted and ignited through igniters in the combustion, finally, high thermal explosive energy is produced, the energy level of ionized hydrogen and oxygen atoms burning is dramatically increased, than normal oxygen and hydrogen gases burning state.
The high thermal explosive energy drives the gas turbine 19 and lastly, it produces electrical energy 20. To ionize oxygen and hydrogen gases a series of ultraviolet or infrared light emitting diodes 40 are assembled with Series and parallel, as illustrated in fig 3 and fig 4. Furthermore, concentrate lenses 47 are assembled in the internal part of the resonant cavity 15. Additionally, high voltage positive plate 41 and negative plate 48 are assembled inside of the resonant cavity. When the oxygen gas and hydrogen gases exposed to concentrated laser energy/radiation 40 and to the high voltage positive plate 41 and Page 11 0f49 Date recue/Date received 2023-04-19 negative plates 48, the gases become partially ionized, and the energy level of the gases is increased when combusted in the combustion.
In the embodiment of fig 4, light-emitting diodes 40 arranged in a Cluster-Array, provides and emits a narrow band of IR/x-ray/Uv-ray light energy fig-- into the voltage stimulated hydrogen gas, as illustrated in Figure 3 as to Figure 4 The absorbed Laser Energy (Electromagnetic Energy) by hydrogen gas fig 5 causes many atoms to lose electrons while highly energizing the liberated combustible gas ions before and during thermal gas-ignition.
The exposing the displaced and moving combustible gas atoms passing through Gas Resonant Cavity 15 at higher voltage levels plates 41 & 48 causes more electrons to be "pulled away" or "dislodged" from the gas atoms, as illustrated in Figure 5.
The absorbed laser energy "deflects" the electrons away from the gas atom nucleus during voltage-pulse off-time. As illustrated in fig 3 the high voltage driver circuit 49 produces more than 15 kilovolt and the produced high voltage is supplied to the positive and negative plates wherein the resonant cavity fig 15 to ionize the gases. The recurring positive voltage-pulse fig 5 attracts the liberated negative electrically charged electrons 55 to positive voltage zone 47 While, at the same time, the pulsating negative electrical voltage potential 48 attracts the positive electrical charged nucleus 56. The Positive Electrical Voltage Field 48 and Negative Electrical Voltage Fields 47 are triggered "Simultaneously"
during the same duty-pulse.
Electron Extraction system fig 5 removes, captures, and consumes the "dislodged"
electrons (from the gas atoms) to cause the gas atoms to go into and reach "Critical State", forming highly energized combustible gas atoms having missing electrons.
The absorbed Laser energy 40 weakens the "Electrical Bond" between the orbital electrons and the nucleus of the atoms; while, at the same time, electrical attraction-force, being stronger than "Normal" due to the lack of covalent electrons. "Locks Onto" and "Keeps" the hydrogen electrons. These "abnormal" or "unstable" conditions cause the combustible gas ions to overcompensate and breakdown into thermal explosive energy. By simply attenuating or varying voltage amplitude in direct relationship to voltage pulse-rate determines Atomic Power-Yield under the controlled state.
Page 12 of 49 Date recue/Date received 2023-04-19 In combustion 16 high thermal explosive energy is released. As maintained above, exposing hydrogen and oxygen gases separately into two different resonant cavities to laser energy and high voltage potential causes to increase the output energy level in the combustion.
Finally, combustible gas ions ignited in the combustion through thermal sparks and causes releasing thermal explosive energy beyond the gas-flame Stage, and the thermal explosive energy 46 flows to the turbine, as illustrated in Figure 3.
The hydrogen, oxygen, and non-combustible gas injection process;
As illustrated fig 6 and fig 7, in both embodiments which means in non-ionized hydrogen gas turbine system unit fig 2 and in ionized hydrogen gas turbine system unit fig 2 comprising the following methods and process; the injecting and intermixing of non-combustible gas (non-burnable ambient gas) with the -'burnable" gas-mixture 10 "changes" or "alters" the "Burn-Rate" of hydrogen in the combustion.
Increasing the volume-amount of non-Combustible gas 17 diminishes and/or decreases the "Burn-Rate"
of the gas-mixture hydrogen and oxygen gases. With this mechanism, the burning-rate of hydrogen in the combustion is constant through "gas mixing-regulator 17 or 9 and adjuster to intermixing of the non-combustible gases.
In terms of operational performance, the non-burnable gas "restricts" the speed of the burning-rate hydrogen atoms and the oxygen atom in the combustion. The "gas restricting process" is, of course, applicable to any type or combination of burnable gases or burnable gas mixture.
The gas mixing regulator And Flame Temperature Adjuster;
In both embodiments of non-ionized hydrogen gas turbine system unit fig 2 and ionized hydrogen gas turbine system unit fig 1comprises the methods of; the gas mixing regulator and the flame temperature adjustment.
Fundamentally, the hydrogen gas turbine allows the "Burn-Rate" of hydrogen to be "Changed" or "adjusted" from 325 cm/sec to 42 cm/sec, and the combustion temperature adjusted from 1000 to 5000 degree f, but not limited. The combustion temperature adjusted and fixed at a suitable temperature of the combustion turbine 16. The gas flame-temperature remains constant with the constant gas flow-rate of the combustion gases.
Temperature sensor 7 is mounted in the combustion, and pressure sensor 6 also mounted Page 13 of 49 Date recue/Date received 2023-04-19 in the gas turbine to give feedback for "automatic hydrogen gas flow controller 14, and finally to control the burning rate of the hydrogen. Continual the feedback and control of the temperature in the combustion and the pressure in the gas turbine is, hereinafter, called "The Gas Combustion Stabilization Process" creates uniform combustion temperature. As illustrated fig 6 and fig 7 the regulating system works with the integration of automatic hydrogen gas flow controller 14, with the temperature sensor 7, and the pressure sensor in the combustion 16.
Thereafter the automatic hydrogen gas flow controller 14, controls the flow rate of hydrogen gas and controls the burring rate and regulates the out power of the hydrogen gas tribune. Automatically, the gas "Combustion Stabilization Process" changes the "Burn-Rate" of the hydrogen gases and obtaining the favourite gas-flame temperature.
When the amount of hydrogen flow to the combustion increase, the burning-rate increase, and the amount of temperature in the combustion increase, and the pressure in gas turbine also increase. The amount of hydrogen gas flow is directly proportional to the burning-rate.
In other embodiment, to control the burning-rate of hydrogen in the combustion, the Gas-Mixing regulator 9 system mixes the oxygen gas 10, with non-combustion ambient gases.
The "gas-Mixing Regulator 9 fitted in the outer top of oxygen gas and ambient gas cylinders.
The "Gas-Mixing Regulator" 9 mixes non-combustion ambient gases with the desired amount of oxygen gases, and the mixed gases finally supplied to combustion.
And the mixed gases burn with hydrogen gas in the combustion. The "gas-mixing regulator works with integration of temperature sensor, pressure sensor, and automatic hydrogen gas regulator.
Based on the continuous feedback from the temperature sensor, pressure sensor, and automatic hydrogen gas regulator, the gas mixing regulator 9 mixes the desired amount of oxygen 10 with non-combustible ambient gases. When the amount of oxygen in the mixed gas is higher, the burning-rate also increases. The amount of oxygen in the mixed gas is directly proportional to the burning-rate. This system supplies a uniform gas-mixture to combustion 9, and it plays a vital role in hydrogen burning-rate regulation.
The ionized hydrogen gas turbine fig 2 utilizes ionized hydrogen 44 or ionized oxygen 43 or both ionized gases. As illustrated in fig 2, fig 3, fig 4, and fig 5 the method of generating power from ionized hydrogen combustion gas turbine, comprising the steps of:
Page 14 0f49 Date recue/Date received 2023-04-19 i. producing sodium hydroxide from brine electrolysis 30, by using sodium hydroxide 31 producing hydrogen and oxygen gases from hydrogen-oxygen generator 24, ii. regulating hydrogen 14, oxygen 13 and non-combustion ambient gases 17, iii. Ionize oxygen and hydrogen gases through resonant cavities 16, iv. burning ionized hydrogen atom in ionized oxygen atom and ambient gases in combustion 16, and thereby generating a source of super high-temperature gas 46, and driving one or more gas turbines 19 with the super high-temperature gas to generate electrical power 20 or to drive a shaft for some useful.
The generated electric power from this system utilizes for external output electric energy supplies and for running the internal systems of the carbon dioxide capturing process.
As illustrated in fig 2 and fig 1, the method of generating power from the ionized and non-ionized hydrogen combustion gas turbine system works with the integration of other units of the carbon dioxide capturing and producing electrical energy system invention. And the ionized and non-ionized hydrogen combustion gas turbine system units at least integrated with the other system units of;
i. hybrid solar hydrogen-oxygen fuel cell unit 21 & 24; to produce hydrogen and oxygen gases for ionized or non-ionized hydrogen combustion gas turbine system units ii. waste heat recovery system unit 39,8 & 25: to convert exhaust waste heat from ionized or non-ionized hydrogen gas turbine system units iii. Hybrid of Carbon dioxide reactor core and hydrogen chlorine fuel cell unit 33 & 32;
to utilize exhaust waste heat from ionized or non-ionized hydrogen gas turbine system units and to increase carbon dioxide absorbing rate.
iv. Carbon dioxide capturing system unit 38: the carbon dioxide absorber and regeneration part of the carbon dioxide capturing system unit utilizes exhausted waste heat released from an ionized or non-ionized hydrogen gas turbine system to increase to capture carbon dioxide from the atmosphere or flue gases.
Page 15 of 49 Date recue/Date received 2023-04-19 B. Non-Ionized hydrogen gas turbine unit The carbon dioxide capturing and electrical energy producing system invention comprising non-ionized hydrogen gas turbine system unit fig 1 for generating electrical power from hydrogen and the other alternative embodiment system comprising: hydrogen gas 11 and oxygen gas 10 sources, automatic hydrogen gas regulator 13, oxygen and ambient gases mixing regulator 9, temperature sensor 6, pressure sensor 7, compressor 18, turbine 19, combustor 16 and electric generator 20. The non-ionized hydrogen gas turbine system fig 1 utilizes the same thing as illustrated in the above in the ionized hydrogen gas turbine, the difference is; in the ionized hydrogen gas turbine unit fig 2 utilizes hydrogen and oxygen ionizer resonant cavity to stimulate the hydrogen and oxygen gases. But, in the non-ionized hydrogen gas turbine unit fig 1 and fig 7 does not utilizes hydrogen and oxygen ionizer resonant cavity, it uses directly hydrogen and oxygen gases to run the turbine.
Hydrogen is combusted into oxygen to generate extremely high temperature gas.
The hydrogen is produced from both brine electrolysis 30 and from hydrogen-oxygen generator fig 2 of 24. To produce hydrogen and oxygen gas from the hydrogen-oxygen generator it utilizes sodium hydroxide 31 which produced in the electrolysis of sodium chloride 30. The automatic hydrogen gas regulator 13, oxygen and ambient gases mixing regulator 9, temperature sensor 6 and pressure sensor 7 utilizes to control to regulate the burning rate of hydrogen gas and oxygen gas in the combustion 16, the same as described in the above in ionized hydrogen gas turbine unit fig 2.
By feeding the combustion generated gas 46 directly into gas turbine 19, unprecedented high conversional efficiency of electricity is achieved, and the generated electric power utilized for carbon dioxide capturing process and for output power commercialization.
As illustrated in fig-1 and fig-3 the hydrogen combustion gas turbine system comprises a source of hydrogen 11, a Source of oxygen 10, a combustor 16. the super high temperature gas 46 exhaust from the combustor 16, and super high temperature gas turbine 19, and an electric generator 20.
Instead of ionized hydrogen gas turbine the other alternative embodiment utilizes a non-ionized hydrogen gas turbine as illustrated in fig 1 and the system directly burning hydrogen 11 and oxygen 10 gases in combustion 16 and generate electric power.
Page 16 of 49 Date recue/Date received 2023-04-19 In the other alternative embodiment of non-ionized hydrogen gas turbine uses directly hydrogen and oxygen gases as illustrated in fig 1, and fig 7, and the method of generating power from non-ionized hydrogen gas turbine, comprising the steps of:
i. producing sodium hydroxide from brine electrolysis 30, by using sodium hydroxide producing hydrogen 11 and oxygen 10 gases from hydrogen-oxygen generator 24, ii. Regulating hydrogen, oxygen and non-combustion ambient gases, iii. burning hydrogen gas in mixed oxygen and ambient gases, in combustion and thereby generating a Source of Super high temperature gas 46 and driving one or more gas turbines with the Super high temperature gas to generate electrical power or to drive a shaft for some useful.
Hybrid thermoelectric-generator Solid oxide fuel cell unit A carbon dioxide capturing and electrical energy producing system comprises a "hybrid thermoelectric generator and solid oxide fuel cell system" as illustrated in fig 8 & fig 9, for cogenerating electrical power from hydrogen-oxygen and from waste heat which released from solid oxide fuel cell. As illustrated in fig 9 the hybrid thermoelectric generator and solid oxide fuel cell system is the combination of thermoelectric generator 27 and fuel cell techniques 26. In this embodiment, the combination of thermoelectric generator 27 and fuel cell techniques are very useful to increase the production of electrical energy and to get maximum efficiency of electric power, from the system. In the present system, as illustrated in fig 8 & fig 9 the hybrid thermoelectric generator and Solid oxide fuel cell Cogenerates electrical energy 61 from thermoelectric generator 27 and Solid oxide fuel cell 26 at maximum thermodynamics efficiencies. The Solid oxide fuel cell 26 generates electric power based on a chemical reaction between a fuel /hydrogen/ 66 and an oxidizer /oxygen or ambient air/ 60. The Solid oxide fuel cell /SOFC/ 26 comprising cathode 67 and anode 68 and based on a chemical reaction between a fuel /hydrogen/ 66 and an oxidizer /oxygen or ambient air/ 60 produces electric power. The Solid oxide fuel cell also generates a high temperature of heat energy 57 as a byproduct of the chemical reaction. The average waste heat temperature from Solid oxide fuel cell /SOFC/
is from Page 17 of 49 Date recue/Date received 2023-04-19 50000 to 100000. And this high temperature waste heat 57 & 65 uses to generate additional electrical energy.
In the current embodiment fig 9 the waste heat 57 & 65 from "Solid oxide fuel cell /SOFC/" converts into electrical energy by using two different systems and arrangements, i.e. some amount of the waste heat 57 is directed into thermoelectric generator 27 and produce additional electrical energy, and the rest of waste heat 65 from SOFC
directed to waste heat recovery generator 39, and generate additional electric power through steam turbine 8. Therefore, the exhausted waste heat from solid oxide fuel cell 26 is utilizing to generate electrical energy through thermoelectric generator system 27 and through waste heat recovery system unit 39. The waste heat recovery system unit 39 generates pressurized steam and the steam drives steam turbine 8 and generates electric power 25.
The thermoelectric generator 27 generates electric power by routing exhaust waste heat 57 from the solid oxide fuel cell 26. The exhaust waste heat inters into a hot side of the thermoelectric generator and routing cold intake gases from the ambient air into a cold side of the thermoelectric generator as illustrated in fig 9. The thermoelectric generator produces electric energy based on a temperature differential experienced across the thermoelectric electrodes 58 & 57. The amount or rate of electric energy generation by a thermoelectric generator may depend on the magnitude of the temperature differential across it. When the temperature difference in the thermoelectric generator increase, the magnitude of the production of electrical energy also increases.
In summery the hybrid of solid oxide fuel cell and thermoelectric generator system fig 8 working with integration of other system units. The "Carbone dioxide capturing and Electrical energy producing system" comprising the "hybrid thermoelectric generator and Solid oxide fuel Cell" unit systems to cogenerating electric power at maximum efficiency. As illustrated in fig 8 and fig 9 and the system of cogenerating power from "Hybrid Thermoelectric generator and Solid oxide Fuel cell" comprising the steps of:
producing sodium hydroxide from brine electrolysis 30, by using sodium hydroxide producing hydrogen and oxygen gases from hydrogen-oxygen generator 24, directing hydrogen and oxygen gases to solid oxide fuel cell 26, the solid oxide fuel cell generates electric power based on a chemical reaction between hydrogen and an oxidizer /oxygen or ambient air/
67 & 68 and it produces heat energy 57 as a byproduct, routing some amount of waste heat Page 18 of 49 Date recue/Date received 2023-04-19 57 released from solid oxide fuel cell 26 into thermoelectric generator 27 and producing additional electrical energy from waste heat.
furthermore, routing the reset waste heat 65 which released from solid oxide fuel cell 26 directed into waste heat recovery system in 39, and waste heat recovery system creates hot steam, and utilized to drive an additional steam turbine, and produce additional electrical energy waste heat.
Hybrid Solar hydrogen-Oxygen gas generator system unit As illustrated in fig 10 and 11 the "Co2 capturing and electrical energy producing system"
comprises the "Hybrid Solar hydrogen-Oxygen gas generator system unit" fig 11.
The "Hybrid Solar hydrogen-Oxygen gas generator system" unit comprises; solar-based hydrogen-oxygen generator 24 and internal power sources based hydrogen-oxygen generator 5.
The main objective of the Hybrid Solar hydrogen-Oxygen gas generator system unit is; to produce uninterrupted hydrogen gas and oxygen gas, and to feeding hydrogen gas to the other parts of the system.
To start-up, the system, some cells of hydrogen-Oxygen gas generators 24 are powered by solar energy 21 to produce initial hydrogen and oxygen gases. And the rest cells of hydrogen-Oxygen gas generators 5 are powered from internal sources of electrical energy 28 as shown in fig 11. In the other way, the partial hydrogen-oxygen gas generator cells are powered by solar energy.
The importance of the "Hybrid Solar hydrogen-Oxygen gas generator system" is to reserve energy to start-up the system, or for start-up "Co2 capturing and electrical energy producing system". The operation of the invention utilizes start-up energy from solar 21;
the solar energy powers to hydrogen-oxygen gases generator 24 to produces hydrogen and oxygen gases. Some "hydrogen-Oxygen gas generator cells" 24 are powered by solar energy and the hydrogen-Oxygen gas generators produce hydrogen 22 and oxygen 23 gases. The produced hydrogen and oxygen gases are stored in the hydrogen tanks 11 and oxygen gas tanks 10 respectively. When the "Co2 capturing and electrical energy producing system"
needs to start-up the system; it utilizes the stored hydrogen and oxygen gases from the Page 19 of 49 Date recue/Date received 2023-04-19 tankers 10 & 11. And the hydrogen gas turbine 19 utilizes the stored hydrogen and oxygen gases to start the production of electric power. And the produced electrical energy utilizes;
a) to operate the rest of hydrogen-oxygen gas generator cells 5 and produce more hydrogen and oxygen gases, b) to operate the other systems of "Co2 capturing and electrical energy producing system". Furthermore, electric power is produced from one or more hydrogen gas turbines. The power utilizes for output commercial purposes.
Likewise, the present invention produces megawatts of electric power and the present system uses as a power plant.
To produce hydrogen and oxygen gases through the "Hybrid Solar hydrogen-Oxygen gas generator system" fig 10 & fig 11 uses sodium hydroxide base 31 which is processed from the electrolysis of brine unit 30.
The solar hybrid hydrogen-oxygen gas generator system, produces hydrogen and oxygen gases from water. By the method of electrolysis, the water molecules split into hydrogen and oxygen gases. As illustrated in fig 11, hydrogen is produced in cathode 69, and oxygen is produced in the anode 70 part of the Hydrogen -oxygen generator cell system. The hydrogen-oxygen gas generator system comprising: a source of electrical energy from solar 21, cathode 69 and anode 70 electrodes, and electrolysis alkali chemicals like sodium hydroxide 31 or potassium hydroxide base or any other alkali base.
The "Hybrid Solar hydrogen-Oxygen gas generator system" works with integrating other systems of the "Co2 capturing and electrical energy producing system". The Hydrogen and oxygen gases are produced from "Hybrid Solar hydrogen-Oxygen gas generator system"
unit fig 10 & fig 11 and the Hydrogen and oxygen gases utilizes to operate hydrogen gas turbine 19 and produce electric power 20 from the system.
In this embodiment, the sodium hydroxide base 31 which produced in the electrolysis of brine unit 31 utilizes for a dual purpose; one is utilized for carbon dioxide reactor core unit 33 or for tree fashioned Co2 capturing system unit 38 to converting carbon dioxide into useful carbonate products, and the second is utilizes for electrolysis to produce hydrogen and oxygen gases from water 6 & 24. Therefore, the sodium hydroxide base utilizes for hydrogen-oxygen gas generator 6& 24 to generate hydrogen and oxygen gases.
Lastly, Hydrogen and oxygen gases stored in hydrogen tanks 11 and oxygen tanks 10 and utilizes Page 20 of 49 Date recue/Date received 2023-04-19 to produce electrical energy through the gas turbine system 19. The hydrogen and oxygen gases utilize to operate solid oxide fuel cells and uses to run other parts of the system.
In the present system, the hydrogen gas is produced from two sources; one is from the hybrid Solar hydrogen-Oxygen gas generator system fig 11, and the second is from the brine electrolysis system 30. In the brine electrolysis unit 30 hydrogen gas is produced from the cathode part of the electrolysis and chlorine gas is produced from the anode part of the electrolysis.
In some embodiments of the invention, the hybrid solar hydrogen-oxygen gas generator system works with integrating other systems of the Co2 capturing and electrical energy producing system, such as;
i. Hydrogen gas turbine unit: the hydrogen and oxygen gases are produced from hybrid solar hydrogen-oxygen gas generator system unit fig 11 and fig 10 and the produced hydrogen and oxygen gases utilize to generate electrical power through hydrogen gas turbine unit system ii. Hybrid thermoelectric generator solid oxide fuel cell unit; to generate electric power and heat energy through the solid oxide fuel cell the system utilizes hydrogen and oxygen gases from hybrid solar hydrogen-oxygen gas generator system unit system fig 10 & fig 11.
iii. Electrolysis of brine unit: to generate hydrogen and oxygen gases, the hybrid solar hydrogen-oxygen gas generator system unit utilizes sodium hydroxide from the electrolysis of brine unit 30, In other embodiment of the hybrid solar hydrogen-oxygen gas generator system unit utilizes potassium hydroxide and other alkali bases.
As described in other units of the co2 capturing and electrical energy producing system, enough electric power is generated from hydrogen gas turbine, hybrid thermoelectric generator unit, and waste recovery system unit. Therefore, the electrolysis of brine unit 30, and the other hydrogen-oxygen gas generator 24 wherein the hybrid solar hydrogen-oxygen gas generator system unit is powered from internally generated electric power.
The hybrid solar hydrogen-oxygen gas generator system unit comprises the processes and steps of:
Page 21 0f49 Date recue/Date received 2023-04-19 i. Producing electrical energy from solar 21 and powering some parts of hydrogen-oxygen gas generator cells 5 ii. Producing hydrogen 22 and oxygen 23 gases from the hydrogen-oxygen generator, by using electrolysis of sodium hydroxide 31 or other alkali bases.
iii. Storing energy in the form hydrogen 11, iv. Routing Hydrogen and oxygen gases to hydrogen gas turbine 19 and start the operation and produce electric power 20 from the system, v. Storing and distributing electric power, vi. Powering the rest of hydrogen-oxygen gas generator cells 24 and produce enough amount of hydrogen 22 and oxygen gases 23 and continuing the operation of the system.
The Tree fashioned carbon dioxide capturing system unit In the other embodiment of carbon dioxide capturing and electrical energy producing system invention comprises a tree fashioned carbon dioxide capturing unit fig 21 of 125, or fig 20, for extracting and capturing carbon dioxide from the atmosphere or flue gases 71.
And the physical structure of a carbon dioxide capturing system unit is fashioned as a tree structure as illustrated in fig 20.
In the present invention, the objectives of the tree fashioned carbon dioxide capturing system unit are;
i. To utilize waste heat: the carbon dioxide absorbing/separating step, and regeneration step, utilizes waste exhausting heat which relisted from solid oxide fuel cell unit or hydrogen gas turbine unit, ii. To design a unique, less cost-effective, easily implemented, attractive, and high-efficiency carbon dioxide capturing system unit. The physical structure of the present system of a carbon dioxide capturing system unit is fashioned like a tree.
Which means the carbon dioxide capturing system machine is having a tree physical structure.
iii. To reduce high external electric power consumption: the carbon dioxide capturing system unit works with the integration of other units of the system. As described in Page 22 of 49 Date recue/Date received 2023-04-19 the other units of the present invention, enough amount of electric power is generated from hydrogen gas turbine unit 19, hybrid thermoelectric solid oxide fuel cell system unit 26 & 27 and waste heat recovery system unit 39 & 25.
Therefore, the tree fashioned carbon dioxide capturing system unit 38 is powered from internal generated electric powers, and this solves the high external energy consumption problem by carbon dioxide capturing system technologies.
The tree fashioned carbon dioxide capturing system unit comprises;
i. Exhausted waste heat-based heater 77; as shown in fig 20 the gases are absorbed from the atmosphere 71 through the fans 73, and the gases the absorber or separator part. As shown in fig 20 the carbon dioxide absorbing/separating step 76, and the regeneration step 78 utilizes waste exhausted heat 79 which relisted from hybrid thermoelectric generator solid oxide fuel cell unit 26, from hydrogen gas turbine unit 19, and from waste heat recovery unit 39 & 8, as shown in fig 19 and fig ii. Carbon dioxide solvents/sorbents/adsorbents chemicals 76: the system utilizes different methods to absorb and capture carbon dioxide, such as solid absorbent, adsorbents, and solvents as shown in fig 20 of 76.
iii. Carbon dioxide absorber part 76: as shown in fig 20 the ambient gases containing carbon dioxide gases are absorbed from the atmosphere 71 through the fans 73, and thereafter the gases heat up to the right temperature 77 for the absorber or separator part. And the hot gases flow to the solvents/ sorbents/adsorbents 76, and the solvents/ sorbents/adsorbents absorb carbon dioxide. The absorbing efficiency of the carbon dioxide depends on the temperature of the gases and solvents/
sorbents/ adsorbents absorb. To get maximum efficiency of carbon dioxide capturing, the system utilizes waste heat. The waste heat uses to increase the carbon dioxide absorption rate in solvents/ sorbents/ adsorbents.
iv. Regeneration part 78; the reached solvents/sorbents/adsorbents 76 flows into regeneration part 78 and heat up, and thereafter the carbon dioxide gas 80 is produced from the reached solvents/sorbents/adsorbents and the solvents/
sorbents/adsorbents become unreached. Therefore, the solvents/
sorbents/adsorbents are also produced for re-use. The produced solvents/
Page 23 of 49 Date recue/Date received 2023-04-19 sorbents/adsorbents are cooled through the cooler 84 which adapted in the base of the tree fashioned. Thereafter, the solvents/ sorbents/adsorbents returned for re-use into carbon dioxide absorbing/separating part 76, in addition the produced carbon dioxide gases pumped 81 and compressed 80 into carbon dioxide tanker 37.
v. Carbon dioxide compressor 81: utilizing to compressing and storing Carbon dioxide in the tanker 37.
There are different kinds of carbon dioxide capture techniques such as solvents, sorbents, membranes and cryogenics. The solvents separation techniques use liquid adsorbents such as amines, mono-ethanolamine, or aqueous ammonia. The membrane separation technique uses separation membranes to concentrate carbon dioxide, cryogenics technique utilizes a cooling and condensation system. The solid separation techniques use solid adsorbents such as alkali or alkaline earth metals, alkali carbonates like sodium carbonate, potassium carbonate and others.
In the present invention, the tree fashioned carbon dioxide capturing system unit utilizes some of the following solvents or sorbents or adsorbents are listed as follows;
i. Amines, mono-ethanolamine solvents, alkali metal base solvents like potassium hydroxide, sodium hydro oxide or calcium hydroxide, and other metal base solvents, or ii. Solid sorbents/adsorbents such as; alkali metal carbonates; sodium carbonate, potassium carbonate or alkaline earth metals, solid amines and mono-ethanolamine, and zeolites based sorbents. But the system is not only limited to these solvents/
sorbents/adsorbents. Furthermore, the tree fashioned carbon dioxide capturing system unit also integrated, designed and working with a membrane-based carbon dioxide capture system.
In the present invention, to precede the carbon dioxide absorbing/separating step 76, and the regeneration step 78, it utilizes waste heat.
As illustrated in fig 20, the system captures carbon dioxide from the atmosphere 71, and to absorb carbon dioxide it needs to heat-up the gases to the right temperature for the absorber or separator, and the system utilizes a waste heat-based heater 77.
The waste heat-based heater 77 utilizes to increase the temperature of ambient gases and solvents/
sorbents/adsorbents 76. The waste exhausted heat from hybrid thermoelectric solid oxide Page 24 of 49 Date recue/Date received 2023-04-19 fuel cell unit 26, from hydrogen gas turbine unit 19, and from waste heat recovery system unit 39 & 8 flows through pipe 79 to the heat exchange area 77, to create the desired temperature on the system. The waste heat gas flow through the external parts of pipe 77, and the carbon dioxide containing gases atmospheric gases flow through the internal parts of the pipes 76, and the gases inside the pipes become hot, to the right temperature for the absorber or separator part 76. And the hot gases flow into the absorber and separator part 76, and the carbon dioxide is separated and absorbed through using different solvents or adsorbents or sorbent chemicals.
In the other embodiment of the tree fashioned carbon dioxide capturing system unit, the system also absorbs carbon dioxide from flue gas. The released flue gas from the factory becomes to cool down through the heat exchangers adapted on it. The flue gases cooler part uses to cool down the flue gas to the right temperature for the absorber or separator part. The processes and systems of the carbon dioxide capturing from flue gas are almost the same as the carbon dioxide capturing from the atmosphere, and in the present invention, the processes and systems of the carbon dioxide capturing from the atmosphere are also utilized in the processes and systems of a carbon dioxide capturing from flue system.
As illustrated above, the present system, the carbon dioxide absorbing step 76 and regeneration step 78 utilizes exhausted waste heat 79 which released from hydrogen gas turbine unit or hybrid thermoelectric generator solid oxide fuel cell unit, waste heat recovery system unit, as illustrated in fig 20 and fig 19. Due to this, the present system of having a unique physical structure and the system is designed to operate with the exhausted waste heat. And the tree fashioned present carbon dioxide capturing system unit is different from other carbon dioxide capturing technologies.
The purpose of heating ambient gases is; to increase the absorbing rate of carbon dioxide gas in solvents/absorbents or adsorbents.
As illustrated in fig 20 the next carbon dioxide capturing process is the regeneration step.
As illustrated in fig 20, to capture carbon dioxide the system utilizes different solvents, absorbents, or adsorbents 76. As shown in fig 20 the carbon dioxide is absorbed through solvents/sorbents/adsorbents, the reached solvents/absorbents or adsorbents 76 flows into the regeneration step 78. The reached solvents/absorbents or adsorbents heat-up to Page 25 of 49 Date recue/Date received 2023-04-19 produce carbon dioxide and to regenerate the solvents/ sorbents/adsorbents for re-use. To heat-up the reached solvents/sorbents/adsorbents, the present system utilizes exhausted waste heat from hydrogen gas turbine, solid oxide fuel cell and waste hear recovery system unit. As shown in fig 20, the carbon dioxide flows 80 into carbon dioxide tanker 38 and the carbon dioxide reactor core 33 utilizes carbon dioxide from tanker 38 as shown in fig 19.
And the carbon dioxide reactor core 33 converts carbon dioxide into carbonate and bicarbonate byproducts 35.
Alternatively, the output waste heat from carbon dioxide absorber part 76 and regeneration part 78 is returned into the waste heat recovery system unit to generate additional electric power The tree fashioned carbon dioxide capturing unit fig 20 and fig 19 of 38 works with integration of different units of a carbon dioxide capturing and electrical energy generating system, such as;
i. hydrogen gas turbine unit, hybrid thermoelectric solid oxide unit, and waste heat recovery generator system unit; to use exhausted waste heat for carbon dioxide absorber part 76 and regeneration part 78 ii. Carbon dioxide reactor core unit; to capture and convert carbon dioxide into useful byproducts.
iii. Waste heat recovery system unit; the output waste heat from tree fashioned carbon dioxide capturing system unit is returned to the waste heat recovery system.
The out-put waste heat is returned to recover waste heat released from the carbon dioxide absorber part and regeneration part and utilizes to generate additional electric power. The waste heat recovery system 39 collects waste heat released from different parts, and units of the system. And the waste heat recovery system changes the waste heat into electric power.
As illustrated in fig 20, the physical structure and shape of the carbon dioxide capturing system unit is fashioned as a tree structure. As illustrated in fig 20, in the ergonomics of leaf type of fans 73 are functioning to suck carbon dioxide and ambient gases from the atmosphere 71.
Page 26 of 49 Date recue/Date received 2023-04-19 In the tree fashioned carbon dioxide tree fig 20 of 76 carbon dioxide sorbents/adsorbents/solvents are adapted on it. In the fashioned trunk of the tree regeneration part 78 are adapted on it. In the circular base of the tree the carbon dioxide tanker 38 is adapted on it. And the color of the tree fashioned carbon dioxide capturing system unit fig 22 is green or other colors.
In the tree fashioned carbon dioxide capturing system unit fig 22 at least comprises; fans, circulation pumps, heat exchangers, regeneration part, carbon dioxide absorber part (sorbents/adsorbents/solvents part), re-boiler, stripper, intercoolers Co2 pumps and carbon dioxide tankers. And these parts are adapted and integrated on the tree fashioned carbon dioxide capturing system unit.
As described above, the carbon dioxide capturing and electrical energy generating system invention comprises the tree fashioned carbon dioxide capturing system unit fig 21 of 135, or 20. And, the tree fashioned carbon dioxide capturing system unit fig 20 comprises at least the steps of;
i. By using the fans which adapted on the leaf of the tree fashioned carbon dioxide capturing tree, absorb atmospheric gases from the atmosphere. If the carbon dioxide is captured from flue gas, the flue gases directly flow into the cooler part and then next flow into the carbon dioxide separator/absorber part.
ii. Heating the atmospheric air in the tree fashioned carbon dioxide capturing, by utilizing the waste heat iii. Flowing the hot atmospheric air into carbon dioxide separator/absorber part and absorb carbon dioxide by utilizing solvents/ sorbents/adsorbents 78, iv. Flowing the carbon dioxide reached solvents/ sorbents/adsorbents into the regeneration part 78 in the tree fashioned carbon dioxide capturing tree v. Heating the carbon dioxide reached solvents/ sorbents/adsorbents 78 and produce carbon dioxide. When the reached carbon dioxide solvents/ sorbents/adsorbents heating up, the solvents/ sorbents/adsorbents becomes unreached. Thereafter, regenerate the solvents/ sorbents/adsorbents for re-use to the tree fashioned carbon dioxide capturing unit vi. Pumping and storing carbon dioxide gas into carbon dioxide tankers.
Page 27 of 49 Date recue/Date received 2023-04-19 In the present system, the carbon dioxide absorbing step 76 and regeneration step 78 is designed to operate with the exhausted waste heat. To process the carbon dioxide capturing wherein the carbon dioxide absorber part 76 and regeneration part 78 are utilizes waste heat. As illustrated in fig 20, to proceeded the carbon capturing processes;
wherein the ambient gas absorber fans 73, intercoolers, solvents/sorbents/adsorbents 84, circulation pumps, heat exchangers, re-boiler and stripper, pumps and other parts of carbon capturing unit are powered from internally generated electric power.
To capture carbon dioxide from the atmosphere or flue gas, most technology utilizes a large amount of external energy. The high energy consumption is a serious problem in most carbon dioxide capturing industries, and it raises the cost of carbon dioxide capturing and some of them are not economically viable. The current invention solves this problem. The present invention is designed to generate electric power by itself. The parts of carbon dioxide capturing unit are powered by internally generated electric power.
This reduces the external electric power consumption highly, and the present invention is easily applicable and economically viable.
The hybrid hydrogen chlorine fuel cell and carbon dioxide reactor core unit The other embodiment of carbon dioxide capturing and electrical energy producing system comprises a "hybrid hydrogen-chlorine fuel cell and carbon dioxide reactor core system" unit fig 13 for generating electrical power from output chlorine gas and at the same time for dissolving and converting carbon dioxide gas into carbonate outputs.
The objective of the "hybrid hydrogen chlorine fuel cell and carbon dioxide reactor core" is;
i. For producing electrical energy from brine electrolysis byproduct gases.
This means; the hydrogen and chlorine gases are utilized to produce electrical energy through hydrogen-chlorine fuel cell 32.
ii. To power carbon dioxide reactor core by hydrogen chlorine fuel cell, and to reduce the consumption of electrical energy by carbon dioxide reactor core.
Page 28 of 49 Date recue/Date received 2023-04-19 iii. To convert carbon dioxide into sodium carbonate and sodium bicarbonate or alkali carbonates 35.
iv. To create a cost-efficient and energy-efficient carbon dioxide reactor core. And, finally to increase the value and efficiency of the "Co2 capturing and electrical energy producing system" invention.
In other embodiment of "Carbon dioxide capturing and Electrical energy producing system"
fig 13 comprises; brine electrolysis system unit 30 and, sodium hydroxide 31, hydrogen gas 85, and chlorine gases 86 supply. Hydrogen and chlorine gases utilized to produce electrical energy through hydrogen-chlorine fuel cell 32. The Hydrogen-chlorine fuel cell is an electrochemical cell that converts the chemical energy of a fuel (hydrogen 85) and an oxidizing agent (chlorine 86) into electricity through a pair of redox reaction. As illustrated in fig 13 the Chlorine and Hydrogen gases are supplied respectively through the anode 89 and cathode gas 90 diffusion, and hydrogen chloride is produced, thereafter the hydrogen chloride reacts with water and converted into hydrochloric acid 36. In particular, hydrogen-chlorine gases exchange fuel cell that utilizes hydrogen as a fuel and chlorine as an oxidant.
As illustrated in fig 13 "hybrid hydrogen chlorine fuel cell and Carbone dioxide reactor core" system unit, the Hydrogen-Chlorine fuel cell 32 cogenerates electrical energy and hydrochloric acid is produced by-product. The generated power from the hydrogen-chlorine fuel cell utilizes for powering the carbon dioxide reactor core. The generated power from hydrogen-chlorine fuel cell is stored in battery 34 and the battery further comprises AC to Dc inverter. The hydrochloric acid produced in the hydrogen-chlorine fuel cell and the hydrochloric acid 35 utilizes for different chemical industries.
Therefore, the byproduct hydrochloric acid creates additional income.
As illustrated in fig 13 the "hybrid hydrogen chlorine fuel cell and Carbone dioxide reactor core" system unit comprises the integrated systems and combination systems of hydrogen chlorine fuel cell 32 and carbon dioxide reactor core systems 33. The carbon dioxide reactor core system 33 converts carbon dioxide into carbonate and bicarbonate byproducts35, and the system at least comprising;
i. a high pressure compressing system 91; to increase the pressure in the reactor core and to increase the reaction between carbon dioxide with an alkali base Page 29 of 49 Date recue/Date received 2023-04-19 ii. a concentrated lather/ray emitters system 104; to emit radiation to the carbon dioxide and alkali base, and carbon dioxide molecules are exposed to concentrated radiations, the carbon dioxide molecule bonds become vibrate and the kinetic energy of carbon dioxide molecule bonds increases and the system creates to increase the reaction rate of carbon dioxide with alkali base increase.
1. a heat-absorbing system/heat jacket/ 99 gi 98 ; some amount of waste heat exhausted from hydrogen gas turbine is directed into the heat-absorbing system, wherein the external part of the carbon dioxide reactor core, and the waste heat is circulated into the body 101 of the reactor core and heat is absorbed by the heat-absorbing system, creates to increase the temperature inside of the reactor core, finally the system utilized to increase the reaction rate of carbon dioxide with sodium hydroxide.
As illustrated in fig 14 the lather/radiation emitters 104 are installed on the top of the reactor core and it has an automatic opening and clothing housing system 102 on it. In the lather/radiation emitters system 104, the automatic controller and sensors are integrated to control the timing of Emitting radiations to the Co2 reactor core. These controlling systems and sensors are used to control and to follow the reaction procedure on the reactor. When the alkali base and carbon dioxides are ready in the reactor core, the sensor transfers signal to the light emitter lather/radiation emitters controller and the lather/radiation emitters start to emit concentrated radiations 104 to the carbon dioxide and alkali base 105. As shown in fig 14, to concentrate the light intensity, lenses, or glasses 103 are installed with light emitters 104.
After the carbon dioxide molecules are exposed to concentrated radiations, the carbon dioxide molecule bonds become vibrate and the kinetic energy of carbon dioxide molecule bonds increases and at the end the reaction rate of carbon dioxide with alkali base increase.
The emitting of concentrated radiations/laser to carbon dioxide creates to increase the reaction rate of carbon dioxide with an alkali base and this system plays its own role to increase the efficiency of carbon dioxide reactor core. The purpose of the emitting of concentrated radiations/laser to carbon dioxide is; to increase the reaction rate of carbon Page 30 of 49 Date recue/Date received 2023-04-19 dioxide with an alkali base and converted into carbonates and sodium bicarbonate byproducts.
As illustrated in fig 14 the high pressure compressing system 91 installed at the top of the reactor core. The compressing system 91, compresses carbon dioxide with sodium hydroxide, and increase the pressure and finally increase the reaction rate of carbon dioxide with sodium hydro oxide.
The high pressure compressing system 91 installed at the top of the reactor and the system comprises; integrated automatic controlling system, compressing system 91, and sensors installed on it. The integrated automatic controlling system 91 systems and sensors used to control and to operate the reaction procedure on the system.
As shown in fig 14 in the head of the reactor core, the compressing piston and the radiation emitters are designed to fit with the head of the compressing piston 93 and these systems are installed and integrated on the head of the piston. In the reaction core, carbon dioxide reacts with sodium hydroxide or other alkali bases.
In the current embodiment, the high carbon dioxide reactor system operation is partially powered by the hydrogen chlorine fuel cell. The objective of the hybrid of hydrogen chlorine fuel cell and carbon dioxide reactor core is to reduce external electric power consumption in the reactor and to powered by hydrogen chlorine fuel cell.
Therefore, the integration of the "carbon dioxide reactor core system with a hydrogen-chlorine fuel cell"
creates a self-powered carbon dioxide reactor core. And this integrated system reduces external power consumption and this system greatly helps to increases the efficiency of carbon dioxide reactor core, and finally increases the efficiency of the "Carbon dioxide capturing and electrical energy producing system" invention.
The carbon dioxide reactor core 33 comprises heat-absorbing system 99 & 98;
and the system designed on the outer side of the reactor core. In this system, the heat absorber part is another system which utilized to boost the reaction rate of carbon dioxide with sodium hydroxide.
The waste heat from steam turbine 8 is directed into the outer side of the carbon dioxide reactor core 101. And the waste heat is circulated in the body of the reactor core 101, and heat is absorbed by heat absorbers 99 & 98 from the waste hot gases. Then the temperature inside of the reactor core becomes increased, finally, the reaction rate of Page 31 0f49 Date recue/Date received 2023-04-19 carbon dioxide with sodium hydroxide is boosted. The magnitude of temperature in the reactor core is directly proportional to the dissolving rate of carbon dioxide in sodium hydroxide solution or alkali base.
In one embodiment of the carbon dioxide reactor core, to increase mass transfer and to increase kinetic collisions of carbon dioxide with sodium hydroxide, the carbon dioxide reactor core utilizes different methods; such as scattering sodium hydroxide solution at the top of the reactor core over carbon dioxide containing reactor core, bubbling method or film method.
The heat-absorbing system reduces electric energy utilization by electric heaters inside of the reactor and at the same time, it increases the efficiency of conversion of carbonate products. To increase the reaction rate and conversion rate of carbon dioxide into carbonate products, It's not important to installed electrical heaters in the reactor core, instead of that, the current system uses hot output waste gas from hydrogen turbine and the waste hot gas directly directed into the body of the reactor core 105, and the hot waste gas circulating in the prepared lines of the body of reactor core, and the heat absorber system absorbs heat and the reactor core becomes hot. Due to increasing the temperature in the reactor core, the dissolving rate of carbon dioxide with alkali base is increased.
In the present embodiment the heat absorber part system uses to increase the efficiency of carbon dioxide conversion rate by reducing electrical energy consumption in the reaction process. Instead of electric heaters, it uses waste heat from hydrogen gas turbine output hot gas.
In one embodiment, the carbon dioxide reactor core comprising an aqueous sodium hydroxide solution contains 35 to 60% (preferably 40% to 50%) by weight of sodium hydroxide. In this embodiment, the aqueous sodium hydroxide solution starts carbonating at a temperature, above 30 C and lower than 120 C, at a different range of pressure.
The laboratory test result on the efficiency of carbon dioxide capture in sodium hydroxide solution depends on the concentration of sodium hydroxide and temperature of the inner reactor core. The concentration of sodium hydroxide in the solution at 50% by weight and the temperature of the inner reactor core at 80 C, the efficiency of absorption is from 85%
to 90%.
Page 32 of 49 Date recue/Date received 2023-04-19 In other embodiment of the invention, the laboratory test result on the efficiency of carbon dioxide reaction with sodium hydroxide solution depends on the concentration of sodium hydroxide, temperature of the inner reactor core, applied pressure over the reactants, and light/lather emitting intensity 94 over the reactants. When the magnitude of the temperature, pressure, and light/lather emitting intensity over the reactants increase; the efficiency of the conversion rate to sodium carbonate and sodium bicarbonate increases.
The conversion efficiency of carbon dioxide is directly proportional to the magnitude of temperature, pressure, and light/lather intensity inside of the reactor core.
In one embodiment, the carbon dioxide reactor core unit comprises; the high pressure compressing system 91, the concentrated lather ray emitters system 104, and the heat-absorbing system, and these systems create to increase and boost the absorbing rate of carbon dioxide with alkali base at high efficiency. In the carbon dioxide reactor core unit, the sodium hydroxide/alkali base is sprayed over the carbon dioxide through sprayer 106.
The hydrogen-chlorine fuel cell generates electric power for the carbon dioxide reactor operation. Carbonates and hydrogen carbonates are by-products and released from the reaction core. The sodium carbonates and sodium hydrogen carbonates byproduct use for the different chemical industries, and the byproducts create additional income.
Overall, the integration of the art, skill, and embodiment of the hybrid hydrogen chlorine fuel cell with the carbon dioxide reactor core unit system plays a big role to increases the efficiency of the "carbon dioxide capturing and energy producing systems"
invention.
The hybrid hydrogen chlorine fuel cell and carbon dioxide reactor core system unit at least comprising the steps of;
i. collecting chlorine and hydrogen gas from the electrolysis of sodium chloride, ii. producing electric power from the hydrogen-chlorine fuel cell, iii. powering the carbon dioxide reactor core, iv. sequestration carbon dioxide from the atmosphere and storing in the tankers v. pumping carbon dioxide gas into carbon dioxide reactor core, vi. Pumping and spraying sodium hydroxide solution or alkali base into the reactor core Page 33 of 49 Date recue/Date received 2023-04-19 vii. pressing with high-pressure compressing system the carbon dioxide gas and sodium hydroxide solution together, viii. by using waste heat from hydrogen gas turbine, heating the carbon dioxide reactor core ix. Releasing concentrated light/laser over carbon dioxide gas and sodium hydroxide solution, and mixing.
x. By using mixer blades mixing the carbon dioxide gas and sodium hydroxide solution and creating more collusion The final output byproducts from the hybrid hydrogen chlorine fuel cell and carbon dioxide reactor core system unit are; sodium carbonate /sodium bicarbonate/alkali carbonates 35, and hydrochloric acid 36, and the byproduct uses for the different chemical industry, and the byproducts create additional income.
The another alternative embodiment of carbon dioxide reactor core system /fig 15/
The "another alternative design of carbon dioxide reactor core" unit objectives are;
(a) to design a less cost-effective reactor core, and;
(b) to create different alternatives of carbon dioxide reactor core for different plants, In other alternative embodiment of the hybrid hydrogen-chlorine fuel cell and carbon dioxide reactor core system wherein said the carbon dioxide reactor core system the other alternative embodiment system comprises;
a heat-absorbing jacket system 98 and 99; the heat-absorbing system fashioned and adapted in the external part of the carbon dioxide reactor core system.
Some amount of waste heat exhausted from hydrogen gas turbine is directed into heat-absorbing jacket system, wherein the external part of the carbon dioxide reactor core, and the waste heat is circulated into the external body of the reactor core and heat is absorbed by heat-absorbing jacket system, and the system creates to increase the temperature inside of the reactor core, finally the system utilized to increase the reaction rate of carbon dioxide with sodium hydroxide.
Page 34 of 49 Date recue/Date received 2023-04-19 As illustrated in fig 15, the another alternative embodiment of the carbon dioxide reactor core system also operates and works without a high-pressure pressing system and concentrated light emitters. In another alternative embodiment of the carbon dioxide reactor core system, the system utilizes a heat-absorbing jacket system 98 and 99. As illustrated in fig 15, to increase the reaction rate of carbon dioxide with sodium hydroxide it utilizes heat energy, and the other alternative design of carbon dioxide reactor core creates less cost carbon dioxide reactor core, and to create different alternatives of carbon dioxide reactor core for customers. The working system and methods of the another alternative embodiment of carbon dioxide reactor core is the same as described in the above carbon dioxide reactor core fig, the difference is the another alternative embodiment of carbon dioxide reactor core doesn't utilize the high-pressure pressing system and concentrated light emitters system.
The working system and methods of the another alternative embodiment of carbon dioxide reactor core system fig 15 utilizes; all systems, processes, and methods that previously described in the carbon dioxide reactor core, except the high-pressure processing system and the concentrated light emitters system.
The other alternative of carbon dioxide reactor core system integrated and hybrid with a hydrogen-chlorine fuel cell, and the other alternative method working together with all systems, process, and methods of hydrogen-chlorine fuel cell which described in previous pages /from page 27-32/.
The final output byproducts from the other alternative carbon dioxide reactor core system fig 15 are; sodium carbonate, sodium bicarbonate, the same as other carbon dioxide reactor core system fig 14. The other alternative embodiment of carbon dioxide reactor core fig 15 working with integration of other system units, as described in previous pages.
Page 35 of 49 Date recue/Date received 2023-04-19 Waste heat recovery system unit A carbon dioxide capturing and electrical energy producing system invention comprises a waste recovery system fig 17. To utilize the energy of exhaust heat from carbon dioxide capturing and electrical energy producing system, specifically exhaust heat from hydrogen gas turbine 19, solid oxide fuel cell 26, and hydrogen-chlorine fuel cell 32.
waste heat recovery system unit utilizes to recovered waste heat and utilized to drive an additional steam turbine, and to generate additional electric power, as shown in fig 16A, fig 16B, and fig 17.
The waste heat recovery system at least comprises; waste heat exhausted sources from hydrogen gas turbine and waste heat exhausted from different parts of the system, waste heat recovery generator 39, steam turbine 8, hydrogen-oxygen super heater 111 and electric generator 25.
According to the various embodiment of the current invention, the waste heat exhausted from different systems utilized for different applications. As described in previous pages, the waste heat exhausted from hydrogen gas turbine 19 flows into waste heat recovery generator 39, to drive the steam turbine. The output waste heat from waste heat recovery generator 39 flows to carbon dioxide capturing unit 38 and carbon dioxide reactor core 33 to heating the systems. In addition, the waste heat exhausted from solid oxide fuel cell 26 utilized for the thermoelectric generator to generate electric power fig 9, and the rest of exhausted waste heat from solid oxide utilized fuel cell utilized for waste heat recovery system unit, as illustrated in fig 9 of 65, fig 16A and Fig 16B.
In the present embodiment of the invention, the waste heat exhausted from hydrogen gas turbine 19, solid oxide fuel cell 26, and hydrogen-chlorine fuel cell 32 is collected, recycled, and turned to drive steam turbine 8 and generates additional electrical power 25.
The waste heat exhausted from hydrogen gas turbine, solid oxide fuel cell 26, and hydrogen-chlorine fuel cell 32 flows to waste heat recovery steam generator 39. The waste heat recovery steam generator 39 has a duct 112 for receiving hot exhaust gas from hydrogen gas turbine, solid oxide fuel cell and hydrogen-chlorine fuel cell.
The waste heat recovery steam generator is also associated with a heating system for receiving feed water for heating to steam. A heat pipe having a first end disposed within the duct operates to Page 36 of 49 Date recue/Date received 2023-04-19 remove heat therefrom. A second end of the heat pipe disposed within the heating system operates to transfer heat to the feed water. The waste heat recovery steam generator 39 is essentially a large duct 112 with water-filled tube bundles disposed of therein. To recover waste heat from hydrogen gas turbine, solid oxide fuel cell, and hydrogen-chlorine fuel cell, feed water is circulated through the tube bundles such that the water is heated to steam as the exhaust waste gas passes through the duct and over the tube bundles. The waste heat steam generator 39 produces steams from waste exhausted heat and the produced steam flows to hydrogen-oxygen superheater 111, to re-heat the steam and to produce high pressurized steam. The high-pressure steam 119 drives steam turbine 8 and the steam turbine drives electric generator 25 and it produces additional electric power.
As described in fig 17, the hydrogen-oxygen superheater 111 system comprises;
ignition system 118, hydrogen and oxygen gas lines, hydrogen gas flow regulator 114, oxygen flow rate regulator 113, and temperature sensing device. The ignition system is 118 located in a steam line for burning hydrogen and oxygen directly.
The hydrogen and oxygen are introduced into the burner and an ignition system in a manner to get intimate mixing of the two, and thus stable burning. By firing hydrogen and oxygen directly into the steam line in super heater 111, the steam temperature can be raised to a temperature where no thermal problems are created in the turbine.
As illustrated in fig 17, when the steam flows from waste heat recovery steam generator 39 to hydrogen-oxygen super heater111, the hydrogen-oxygen super heater 111 starts operation and increases the temperature of the steam as suitable temperature and pressure to the steam turbine. During operation, hydrogen and oxygen are supplied to super heater which includes a burner 118, through supply lines and from storage tanks 10 and 11, respectively.
The hydrogen and oxygen flow regulator 113 and 114, feed the proper amount of hydrogen and oxygen to the burner 118 in super heater 111 in order to maintain the temperature leaving super heater at the desired value. The valves are controlled by a regulator that receives a temperature signal from a temperature sensing device which adapted in the super heater. Flow meters are used to measure the amount of hydrogen and oxygen flowing to the burners in super heater 118, and these signals are fed to the regulators and controllers to position the valves as to maintain a stoichiometric ratio. The hydrogen and Page 37 of 49 Date recue/Date received 2023-04-19 oxygen are burned directly in the steam flowing through super heater 111, thus increasing the temperature of such steam.
As illustrated in fig 17 the high temperature pressurised steam 119 turned to steam turbine 8 and the steam turbine drive electric generator 25 and produce additional electric power. The exhaust steam from the steam turbine is directed to tree fashioned carbon dioxide capturing system unit, carbon dioxide reactor core for additional usage. The Final working waste heat from tree fashioned carbon dioxide capturing system unit 38 and carbon dioxide reactor core 33 is directed to a condenser where it returns its heat to cooling water. The resulting condensate is pumped out to the waste heat recovery steam generator 39. Low absolute pressure is maintained in the condenser, increasing thereby the heat drop and plant power.
The waste heat recovery system unit utilizes to generate additional electric power from exhaust waste heat and, this system increases the values and efficiencies of carbon dioxide capturing and electrical energy producing system invention.
The waste heat recovery system unit comprising the steps of;
i. Collecting waste heat exhausted from hydrogen gas turbine 9, solid oxide fuel cell 26, and hydrogen-chlorine fuel cell 32, ii. Turning the waste heat into waste heat recovery steam generator 39, and the waste heat steam generator 39, produce steams from waste exhausted heat, and the produced steam flows to hydrogen-oxygen super heater 111 & 116, iii. In the hydrogen-oxygen super heater 111, burning hydrogen and oxygen gases and re-heat the steam and produce high pressurized steam 119. The high pressure and temperature steam drive steam turbine 8 and the steam turbine drives electric generator 25 and it produces additional electric power.
The other alternative embodiment of super heater /fig 18/
The other alternative embodiment of super heater /fig 18/ is the alternative system of super heater fig 17. As illustrated in fig 18, the other alternative embodiment of super heater comprises; ignition system 112, hydrogen and oxygen gas lines, hydrogen gas flow regulator 114 oxygen flow rate regulator 113, temperature sensor, burner 123, and steam Page 38 of 49 Date recue/Date received 2023-04-19 flowing pipe 121. The regulated hydrogen and oxygen gases flow into the burner 123. In the other alternative embodiment of super heater fig 18, the hydrogen and oxygen burned over the steam containing pipes 121, and the volume expansion of the steam boosted. At the same time, the pressure of the fluid also increased. And the high-pressure fluid flows through the pipe 121, and at the last, the pressurized steam 119 drives the steam turbine 8.
The super heater fig 17 and the other alternative embodiment of super heater fig 18 almost the same working principles. The difference is; in super heater fig 17 the hydrogen and oxygen burned over the steam flowing line as shown in 116 & 118. But in the other alternative embodiment of super heater fig 18, the hydrogen and oxygen are burned over the steam flowing containing pipes as shown in 121, 122 & 123. The other alternative embodiment of super heater working with integration of other system units, as described in previous pages.
The Other Alternative embodiments of "the carbon dioxide capturing and electrical energy producing system" invention The present invention of the carbon dioxide and electrical energy producing system comprises different other alternative embodiments. To create different choices for customers, the present invention includes different alternative embodiments, and each embodiment has different arrangements, integrations, efficiencies and costs.
In the present invention, three different other alternative embodiments are included. The goals of the other alternative embodiments one, two and three are described as follows but not limited:
i. To generate electric power ii. To capture carbon dioxide from the atmosphere or flue gas iii. To create innovative alternative designs for customers, to create different choices at different costs, and this helps to implement the technology easily.
iv. To create an alternative embodiment for easy production The three other Alternative embodiments of "the carbon dioxide capturing and electrical energy producing system" invention are described as follows;
Page 39 of 49 Date recue/Date received 2023-04-19 A. The other alternative embodiment-one of the "carbon dioxide and electrical energy producing system" invention The other alternative embodiment one as shown in fig 21 and fig 23 the arrangements and integrations of the system at least comprising;
i. Non-ionized hydrogen gas turbine unit; to generate electric power ii. Hybrid solar hydrogen-oxygen gas generator unit; to produce hydrogen and oxygen gases for hydrogen gas turbine, iii. Tree fashioned carbon dioxide capturing unit /fig 23/: to capture carbon dioxide from the atmosphere iv. Waste heat recovery system unit; to recover waste heat released from non-ionized hydrogen gas turbine unit v. Brine electrolysis unit; to produce sodium hydroxide for Tree fashioned carbon dioxide capturing unite and for hybrid solar hydrogen-oxygen gas generator unit vi. Chlorine fuel cell: to convert exhausted chlorine gas into electric power and hydrochloric acid.
As illustrated in other alternative embodiment one, in fig 21 the hybrid solar hydrogen-oxygen gas generator unit 21 & 24 produce hydrogen 22 and oxygen 23 gases, and the gases flow into non-ionized hydrogen gas turbine unit 19 to generate electric power. The detailed working systems, embodiments, and parts of the non-ionized hydrogen gas turbine unit and hybrid solar hydrogen-oxygen gas generator units are the same as described in previous units.
As illustrated in other alternative embodiment one in fig 21, the tree fashioned carbon dioxide capturing system unit fig 21 of 125, fig 22 & fig 23 directly captures and absorbs carbon dioxide, and inside of the tree fashioned system the carbon dioxide directly converted into carbonate and bicarbonate products. In this other alternative embodiment one, the system does not utilize carbon dioxide tankers. This alternative system fig 22 & fig 23 is directly capturing carbon dioxide from the air and converting it into carbonates.
In the other alternative embodiment-one of carbon dioxide capturing and electrical energy producing system invention, and the physical structure of carbon dioxide capturing system unit is fashioned as a tree structure. In this alternative system, the carbon Page 40 of 49 Date recue/Date received 2023-04-19 dioxide capturing system unit /fig 23/ is fashioned as tree, and the working processes and methods is different from previously described of tree fashioned carbon dioxide capturing system units fig 20.
In the other alternative embodiment one fig 21, new carbon dioxide capturing process and methods 23 are introduced. In the other alternative embodiment one, the objectives of the alternative tree fashioned carbon dioxide capturing system unit fig 22 and fig 23 is;
i. To capture carbon dioxide from the atmosphere, and to convert directly into carbonates and bicarbonate products fig 21 of 35.
ii. The capturing process utilizes the short method, and this helps > to create an alternative design and to reduce the cost of a carbon dioxide capturing process system As illustrated in another alternative embodiment one, fig 21 of 38, fig 22 &
fig 23 the tree fashioned system captures carbon dioxide from the atmosphere 126, through fans adapted in the leaf 72.
And to increase the absorption rate of carbon dioxide it needs to heating-up the sucked gases to the right temperature for the absorber, and the absorber system 134 utilizes waste heat-based heater 135. To heat-up the incoming gases, the present other alternative embodiment one utilizes waste heat exhausted 79 which relisted from steam turbine unit 8. The exhaust waste heat from the steam turbine 8 is pumped into the absorber part fig 22 of 134. The absorber part adapted in branches 127 and trunk 134 of the tree fashioned carbon dioxide capturing system, and heat exchange occurs between the atmospheric gases in the pipe and waste heat. Subsequently, the temperature of the gases inside the pipe becomes increase and the absorption rate between carbon dioxide and sodium hydroxide or potassium hydroxide increases. The solution of sodium hydroxide or potassium hydroxide is sprayed fig 22 of 132 over the hot atmospheric gases in the branches fig 22 of 127 & 131. The branches are made up of hollow pipes. And the gases and sodium hydroxide/potassium hydroxide flows together inside the pipe wherein the branches 133 of the tree fashioned system, thereafter the gases and sodium hydroxide/potassium hydroxide flow together into vertical helical tube 134 wherein the trunk of the tree fashioned system. Thereafter, the collusion of carbon dioxide with sodium/potassium hydroxide increase inside of the vertical helical tube 134, and the absorbing rate also Page 41 of 49 Date recue/Date received 2023-04-19 increase. The vertical circular helical tube 134 is heating up from the waste heat, and as a result, increases the temperature of the compulsions of gases and alkali bases to the right temperature. And the carbon dioxide is converting into carbonates and bicarbonates as shown in 137, and the other atmospheric gases are released through the outlet pipe 138 to the atmosphere 143. The converted carbonates and bicarbonates byproducts are accumulated in the base of the trunk as shown in fig 23 of 35.
In another alternative embodiment one, the tree fashioned carbon dioxide capturing system unit at least comprises the parts of; intercoolers, sodium hydroxide or potassium hydroxide circulation pumps, heat exchangers, controlling part, carbon dioxide absorption part, stripper, and carbonates and bicarbonates tanker.
Furthermore, the other alternative embodiment one, wherein the tree fashioned carbon dioxide capturing system unit fig 23 at least comprises;
i. Leaf 72; To absorb carbon dioxide and ambient gases from the atmosphere in the ergonomics of the tree fashioned carbon dioxide capturing system unit the fans are adapted in the leaf structure 72 body, ii. Branches 131; in the tree fashioned system, the carbon dioxide absorbing process starts from the branches. The branches of the tree fashioned as tubes, inside of the tubes atmospheric gases and sodium hydroxide or potassium hydroxide intermixing together. As shown in fig 22 sprayers 132 are adapted on the branches and spraying sodium hydroxide or potassium hydroxide over atmospheric gases and start absorbing carbon dioxide and subsequently flowing together into vertical helical tube 134 wherein the trunk of the tree, in the tree fashioned system.
iii. trunk: in the ergonomics of the tree, the carbon dioxide is absorbing through the vertical helical tube 134 which is adapted in the trunk. The gases and sodium hydroxide/potassium hydroxide, flowing together, and increasing mass transfers inside of vertical helical tube 134 and converted into carbonates/bicarbonates.
Due to the temperature and the structure of the vertical helical tube 134 the absorption rate of carbon dioxide increase. The carbonates and bicarbonates product accumulated in the base of the trunk and finally the filtered atmospheric gases released into the atmosphere.
Page 42 of 49 Date recue/Date received 2023-04-19 iv. the base of the tree 136; in the ergonomics of the tree, at least carbonate and bicarbonate tankers and circulation pumps, controllers are installed in the base of the tree, In other alternative embodiment one, the color of the tree fashioned carbon dioxide capturing system unit is green or other colors.
In other alternative embodiment one, tree fashioned carbon dioxide capturing system unit fig 22 and fig 23 comprises at least the steps of;
i. By using the fans which adapted on the leaf of the tree fashioned system, sucking atmospheric gases from the atmosphere, ii. By utilizing waste heat from hydrogen gas turbine heating the atmospheric gases iii. Flowing the hot atmospheric gases into carbon dioxide absorber 135.
spraying sodium hydroxide/potassium hydroxide over the gases through the sprayer which adapted in the branches. And thereafter flowing together through the vertical helical tube, and converting carbon dioxide into carbonates and bicarbonates in the fashioned carbon dioxide capturing tree The tree fashioned carbon dioxide capturing system unit fig 22 and fig 23 utilizes sodium hydroxide from brine electrolysis unit 30 and captures carbon dioxide from the atmosphere and converts it into carbonate and bicarbonate products. The tree fashioned carbon dioxide capturing system utilizes exhausted waste heat from the steam turbine for carbon dioxide absorbing part 134 wherein the tree fashioned carbon dioxide capturing system. The tree fashioned carbon dioxide capturing system unit utilizes electric power from hydrogen gas turbine and waste heat recovery system unit.
In other alternative embodiment one, tree fashioned carbon dioxide capturing system units fig 22 and fig 23; sucking atmospheric gases, absorbing Co2 and convert into carbonate and bicarbonate products, but as discussed in previous units the tree fashioned carbon dioxide capturing system units fig 20; sucking atmospheric gases, and absorbing Co2 and regeneration absorbents/adsorbents/solvents and storing carbon dioxide in the tankers and thereafter the carbon dioxide flows into carbon dioxide reactor unit. The working systems of the other alternative tree fashioned carbon dioxide capturing system units fig 23 and fig 22 is different from the tree fashioned carbon dioxide capturing system unit fig 20 which described in previous units.
Page 43 of 49 Date recue/Date received 2023-04-19 As illustrated in other alternative embodiment one of "carbon dioxide capturing and electrical energy producing system" fig 21 the exhausted waste heat from non-ionized hydrogen gas turbine directed into waste heat recovery system unit 39 and waste heat recovery system unit processes and converts the waste heat to generate additional electric power trough steam turbine 8. The detailed working systems, parts, and embodiment of the waste heat recovery system unit are the same as described in previous units, specifically in the "waste heat recovery system unit". The hydrogen-chlorine fuel cell system is hybrid and adapted with the brine electrolysis system unit 31. The system utilizes hydrogen and exhausted chlorine gases to convert into electrical energy and hydrochloric acid. The chlorine gas is exhausted from brine electrolysis. The generated power from hydrogen-chlorine fuel cells turned into brine electrolysis. In the other alternative embodiment one fig 21, the hydrogen-chlorine fuel cell utilizing to power the brine electrolysis system 30. The detailed working systems, parts and embodiment of the hydrogen-chlorine fuel cell system unit are the same as described in previous units, specifically in "the hybrid hydrogen-chlorine carbon dioxide reactor core system unit".
In other alternative embodiment one fig 21, wherein the carbon dioxide capturing and energy producing system, at least comprising the following processes;
i. Producing hydrogen and oxygen gases from hybrid solar hydrogen-oxygen gas generator 42 ii. By utilizing hydrogen and oxygen gases, producing electric power from non-ionized hydrogen gas turbine 19 iii. Producing sodium hydroxide, hydrogen, and chlorine through brine electrolysis 30 iv. Providing hydrogen and chlorine gases, and producing electric power from hydrogen-chlorine fuel cell 32 v. Sucking atmospheric gases through the tree fashioned carbon dioxide capturing system unit 135, fig 22 St fig 23, and absorbing carbon dioxide through sodium hydroxide or potassium hydroxide, and directly converting into carbonate and bicarbonate products wherein through the tree fashioned carbon dioxide capturing system unit. Utilizing exhausted waste heat to perform the carbon dioxide capturing process in the system.
Page 44 of 49 Date recue/Date received 2023-04-19 vi. By utilizing exhausted waste heat generating additional electric power through the waste heat generator 39 B. The other alternative embodiment-two of the "carbon dioxide and electrical energy producing system" invention The other alternative embodiment two of the carbon dioxide capturing and energy producing system; the arrangements and integrations at least comprising;
i. Hybrid solar hydrogen and oxygen gas generator unit ii. Non-ionized hydrogen gas turbine unit iii. Tree fashioned carbon dioxide capturing unite As illustrated in other alternative embodiment two, in fig 24 the hybrid solar hydrogen-oxygen gas generator unit 24 & 21 produce hydrogen and oxygen gases, and the gases flow into non-ionized hydrogen gas turbine unit 19 to generate electric power. The detailed working systems, embodiments, and parts of non-ionized hydrogen gas turbine unit 19 and hybrid solar hydrogen-oxygen gas generator unit 24 & 21 are the same as described in previous units, as shown in fig 1 and fig 11 respectively.
As illustrated in other alternative embodiment two, in fig 24, the tree fashioned carbon dioxide capturing system unit 125 directly captures and absorbs carbon dioxide from atmospheric gases and directly converts into carbonate and bicarbonate products. The detailed working systems, embodiments, and parts of tree fashioned carbon dioxide capturing system unit 125 are the same as described in other alternative embodiment one, fig 22 and fig 23.
In other alternative embodiment two, the brine electrolysis unit is not utilized. The input chemicals for hybrid solar hydrogen-oxygen gas generator 24 and for tree fashioned carbon dioxide capturing system 125 utilizes from external sources. The other alternative embodiment-two of the carbon dioxide capturing and energy producing system helps to reduce the cost of the plant and creates an alternative opportunity for customers.
The other alternative embodiment two of the carbon dioxide capturing and energy producing system at least comprising the processes and steps of;
Page 45 of 49 Date recue/Date received 2023-04-19 i. Producing hydrogen and oxygen gases from hybrid solar hydrogen-oxygen gas generator ii. By utilizing hydrogen and oxygen gases, and producing electric power from non-ionized hydrogen gas turbine vii. Sucking atmospheric gases through the tree fashioned carbon dioxide capturing system unit, Sucking atmospheric gases through the tree fashioned carbon dioxide capturing system unit 135, fig 22 & fig 23, and absorbing carbon dioxide through sodium hydroxide or potassium hydroxide, and directly converting into carbonate and bicarbonate products wherein through the tree fashioned carbon dioxide capturing system unit fig 23. The system utilizes exhausted waste heat to perform the carbon dioxide capturing process in the system.
C. The other alternative embodiment-Three of the "carbon dioxide and electrical energy producing system" invention The other alternative embodiment three of the carbon dioxide capturing and energy producing system; the arrangements and integrations at least comprising;
i. Solar cells and hydrogen-oxygen gas generator unit ii. Fuel cell /solid oxide fuel cell or proton exchange membrane full cell/
ill. Tree fashioned carbon dioxide capturing unit As illustrated in other alternative embodiment three, in fig 25 the solar cells 141 are adapted in the leaves of the tree fashioned carbon dioxide capturing system fig 25, and generate electric power. The generated power from solar cells 141, utilizes to powering the hydrogen-oxygen gas generator fig 25 of 24 and produce hydrogen and oxygen gases, and thereafter the gases flow into hydrogen-oxygen fuel cells fig 25 of 142 and generate electric power. The detailed working systems, embodiments, and parts of hydrogen-oxygen gas generator unit 24, is the same as described in previous units, as shown in fig 11. As illustrated in fig 25, the hydrogen-oxygen generator unit 24 and the fuel cells unit 142 are adapted on the base of the carbon dioxide capturing tree. Moreover, the sodium hydroxide Page 46 of 49 Date recue/Date received 2023-04-19 or potassium hydroxide circulation pumps, heat exchangers, controlling part, and carbonates/ bicarbonates tanker, controllers and sensors are installed on the base 136 of tree fashioned carbon dioxide capturing tree, the same as described in other alternative embodiment one and two. Furthermore, the third other alternative embodiment is very similar to other alternative embodiment two.
As illustrated in other alternative embodiment three, in fig 25, the tree fashioned carbon dioxide capturing system unit is directly captures and absorbs carbon dioxide from atmospheric gases 71 and directly converts into carbonate and bicarbonate products. The detailed working systems, embodiments, and parts of the tree fashioned carbon dioxide capturing system unit fig 25 are the same as described in other alternative embodiment two /fig 22 and fig 23/. In other alternative embodiment three, the solar cells 141 are adapted in the top of the tree, beside of the fans 75 as shown in fig 25.
In other alternative embodiment three, the brine electrolysis unit is not utilized. The input chemicals for hydrogen-oxygen gas generator 24 and for tree fashioned carbon dioxide capturing system fig 25 utilizes from external sources. Furthermore, in this alternative embodiment, the ionized or the non-ionized hydrogen-gas turbine is not included. The hydrogen-oxygen gas generator 24 and the full cells 142 are adapted in the base of the tree fashioned carbon dioxide capturing system unit fig 25. The purpose of this other alternative embodiment is to design small-scale of a carbon dioxide capturing and electrical energy producing system invention, without a hydrogen gas turbine. This other alternative embodiment does not have a nose or pollution. This third other alternative embodiment fig 25 is easily applicable in streets, parks, in front of hotels, schools, etc.
The other alternative embodiment-three of the carbon dioxide capturing and energy producing system fig 25 helps to reduce the cost of the plant and creates an alternative opportunity for customers. Furthermore, the other alternative embodiment helps the technology to produce easily.
The other alternative embodiment three of the carbon dioxide capturing and energy producing system fig 25 at least comprising the processes and steps of;
Page 47 of 49 Date recue/Date received 2023-04-19 I. By utilizing solar power and producing hydrogen and oxygen gases from hydrogen-oxygen gas generator ii. By utilizing hydrogen and oxygen gases, producing electric power from fuel cells iii. Sucking atmospheric gases through the tree fashioned carbon dioxide capturing system unit fig 22 & fig 25, and absorbing carbon dioxide through sodium hydroxide or potassium hydroxide chemicals, and directly converting into carbonate and bicarbonate products wherein through the tree fashioned carbon dioxide capturing system unit fig 25.
The Other Alternative embodiments of "the carbon dioxide capturing and electrical energy producing system" invention are exemplary and non-limiting.
As described in the above detailed description section of the carbon dioxide capturing and electrical energy producing system wherein a hydrogen gas turbine unit, hybrid thermoelectric-generator solid oxide fuel cell unit, solar hybrid hydrogen-oxygen gas generator system unit, hybrid hydrogen chlorine fuel cell with carbon dioxide reactor core unit and waste heat recovery system units are physically or electrically or mechanically coupled and integrated each other. The hybrid and integration of variety units of systems create to achieve the objective of capturing carbon dioxide and generating electrical power from the system.
The present invention comprising various alternative embodiments, such as; the carbon dioxide capturing and energy production system invention at least having four alternative embodiments / fig 1, f1g2, fig 21, fig 24, fig 25/. Furthermore, the carbon reactor core having two alternative embodiment /fig 14 and fig 15 /, the hydrogen gas turbine having two alternative embodiments /the ionized hydrogen gas turbine unit fig 3 and fig 6, and the non-ionized hydrogen gas turbine unit fig 7/, the super heater having two alternative embodiment fig 17 and fig 18, the tree fashioned carbon dioxide capturing system unit having three another alternative embodiments /fig 20, fig 23 and fig 25/.
The descriptions of the current processes, integrations, physical structures, hybrids, methods, arrangements and devices, including those in the appendices, are exemplary and Page 48 of 49 Date recue/Date received 2023-04-19 non-limiting. Certain Substitutions, modifications, additions and/ or rearrangements over the present invention is disclosed by the owner of the invention.
The present invention captures carbon dioxide and generating electric energy by itself, with zero Carbone emission and zero air pollutions. The economical and environmental benefits of the present invention are; reducing carbon emission and air pollutions, improving climate change and global warming problems and promoting a clean technology of the future. Therefore, the present invention creates a difference in solving of the present challenges and problems of climate change, and it's a helpful invention for the benefit of mankind.
Page 49 of 49 Date recue/Date received 2023-04-19

Claims (25)

I Claim
1. A method and apparatus of carbon dioxide capturing and electrical energy producing system and comprising;
(a) a non- ionized hydrogen gas turbine unit; to generating electric power from hydrogen and oxygen gases, (b) an ionized hydrogen gas turbine unit; to generating electric power from ionized hydrogen and oxygen gases, (c) a hybrid thermoelectric-generator and solid oxide fuel cell unit; for cogenerating electrical power from hydrogen-oxygen solid oxide fuel cell and from waste heat which released from a solid oxide fuel cell (d) a tree fashioned carbon dioxide capturing unit (e) a hybrid solar hydrogen-Oxygen gas generator system unit is; to produce uninterrupted hydrogen gas and oxygen gas and to feeding hydrogen gas to the other parts of the present system (f) an electrolysis of brine unit: for producing sodium hydroxide to carbon dioxide reactor core, and for producing hydrogen and chlorine gases for hybrid hydrogen-chlorine fuel cell and carbon dioxide reactor core system unit (g) a hybrid hydrogen-chlorine fuel cell and carbon dioxide reactor core system unit;
for generating electrical power from output chlorine gas, and to powered carbon dioxide reactor core by hydrogen chlorine fuel cell, and to converting carbon dioxide gas into carbonate outputs, and to reduce the consumption of electrical power by carbon dioxide reactor core, and (h) a waste recovery system unit; to utilize the energy of exhaust heat from hydrogen gas turbine, solid oxide fuel cell, hydrogen-chlorine fuel cell, and carbon dioxide reactor core, and the waste heat recovery system unit is used to recover waste heat, and utilized to drive an additional steam turbine and generate additional electric power.
Date Recue/Date Received 2021-05-26
2. The apparatus carbon dioxide capturing and electrical energy producing system of claim 1, wherein the ionized hydrogen gas turbine system unit comprising;
(a) a resonant cavity; to ionize and to increase energy the level of oxygen and hydrogen gases through high voltage and laser energy stimulation, and to create high thermal explosive energy in the combustion; and wherein the hydrogen and oxygen gases resonant cavities are installed with the combustion of the hydrogen gas turbine, and the gas resonant cavity means the hydrogen and oxygen gases ionized and stimulated in two different resonant cavities, and the ionized hydrogen and oxygen gases flow into combustion and become to contact and ignited in the combustion, (b) a gas mixing regulator; to mixes the oxygen gas with non-combustion ambient gases and to control the temperature in the combustion of ionized hydrogen gas turbine, and wherein the gas mixing regulator adapted with oxygen and ambient air gas pipes and mixing such gases at the desired ratio and the mixed gases flow to combustion, (c) a temperature sensor; for continual feedback signals and control of the temperature in the combustion of ionized hydrogen gas turbine, and wherein the temperature sensor is adapted in the combustion and sends a continuous signal to automatic hydrogen gas controller, to create stable temperature in combustion, (d) a pressure sensor; for continual feedback signals and control pressure in the ionized gas turbine, (e) an automatic hydrogen gas flow controller; for receiving feedback signals from the temperature sensor and for controlling hydrogen gas flow rate and for adjusting combustion temperature, and wherein an automatic hydrogen gas flow controller connected with hydrogen gas pipe and controlling the flow rate of hydrogen gas to combustion; and (f) a compressor Date Recue/Date Received 2021-05-26
3. The hydrogen gas turbine system of claim 2, wherein the gas resonant cavity ionizes and stimulates the hydrogen and oxygen gases, and the apparatus at least comprising;
(a) a light or lather sources; the light emitting diodes are installed in the resonant cavity tube and are arranged in a cluster-array provides and emits a narrow band of ultraviolet ray light energy into the voltage stimulated hydrogen gas, and oxygen gas, the absorbed laser energy or electromagnetic energy by hydrogen and oxygen gases causes many atoms to lose electrons while highly energizing the liberated combustible gas ions before and during thermal gas-ignition, and (b) a high voltage plates: adapted in the resonant cavity tube and are arranged in negative and positive polarities; and the hydrogen and oxygen gases exposing to the high voltage plates and the gases passing through the gas resonant cavity, at higher voltage of positive and negative plates, and causes more electrons to be pulled away or dislodged from the gas atoms, and the absorbed laser energy deflects the electrons away from the gas atom nucleus during voltage-pulse off-time; and wherein the resonant cavity further comprising the high voltage circuit and connected to the negative and positive plates, and wherein the high voltage circuit produces more than 15 kilovolts and the produced high voltage is supplied to the resonant cavity to ionize the gases, and the recurring positive voltage zone attracts the liberated negative electrically charged electrons to positive voltage plate, and while, at the same time, the negative electrical voltage potential plate attracts the positive electrical charged nucleus, and finally the ionized hydrogen and oxygen gases ignited in the combustion through thermal sparks and causes to releasing thermal explosive energy, and the thermal explosive energy drives the turbine.
4. The apparatus of electrical energy generating system from ionized hydrogen gas turbine system of claim 2, comprising at least the processes and steps of:
i. producing sodium hydroxide from brine electrolysis, Date Recue/Date Received 2021-05-26 ii. utilizing sodium hydroxide and producing hydrogen and oxygen gases from a hydrogen-oxygen generator, iii. regulating hydrogen, regulating oxygen and non-combustion ambient gases, iv. ionizing oxygen and hydrogen gases in the resonant cavities, and flows the ionized gases into the combustor, v. burning ionized hydrogen atom with an ionized oxygen atom and ambient gases in combustion, and vi. thereby generating a source of super high temperature gas, and driving one or more gas turbines with the super high temperature gas to generate electrical power or to drive a shaft for some useful.
5. The carbon dioxide capturing and electrical energy producing system of claim 1, wherein the non-ionized hydrogen gas turbine system unit is the other alternative embodiment to generate electric power from hydrogen and oxygen gases, and the system at least comprising;
(a) a gas mixing regulator; to mixes the oxygen gas with non-combustion ambient gases and to control the temperature in the combustion, (b) a temperature sensor; for continual feedback signals and control of the temperature in the combustion, (c) a pressure sensor; for continual feedback signals and control pressure in the gas turbine, and (d) an automatic hydrogen gas flow controller; for receiving feedback signals from the temperature sensor and for controlling hydrogen gas flow rate and for adjusting combustion temperature, and wherein the automatic hydrogen gas flow controller adapted with hydrogen gas pipe and controlling the flow rate of hydrogen gas to combustion.
6. The apparatus of generating electric energy from ionized and non-ionized hydrogen gas turbine system of claim 2, and claim 5 works with integration of other units of the capturing carbon dioxide and producing electrical energy system, and the ionized and non-ionized hydrogen gas turbine system units at least integrated with the;
Date Recue/Date Received 2021-05-26 (a) hybrid solar hydrogen-oxygen fuel cell unit; to produce hydrogen and oxygen gases for ionized and non-ionized hydrogen gas turbine system units, (b) waste heat recovery system unit: to convert exhaust waste heat from ionized and non-ionized hydrogen gas turbine system units, and to generate additional electric power, and (c) carbon dioxide reactor core unit; to utilize exhaust waste heat from ionized and non-ionized hydrogen gas turbine system units and to increase carbon dioxide absorbing rate.
7. The method and apparatuses of generating power from non-ionized hydrogen gas turbine system claim 11 at comprising the steps and process of:
i. producing sodium hydroxide from brine electrolysis, ii. by using sodium hydroxide, producing hydrogen and oxygen from hydrogen-oxygen generator, iii. regulating hydrogen, regulating oxygen and non-combustion ambient gases, and iv. directly flowing hydrogen gases into the combustor and burning hydrogen gas with oxygen and ambient air, and v. thereby generating a source of high temperature gas, driving one or more gas turbines with the high temperature gas to generate electrical power or to drive a shaft for some useful.
8. The carbon dioxide capturing and electrical energy producing system of claim 1, wherein the hybrid thermoelectric-generator and solid oxide fuel cell unit comprising;
(a) a solid oxide fuel cell: to generate electric power based on a chemical reaction between hydrogen fuel and oxidizer oxygen or ambient air, and the solid oxide fuel cell also generates a high temperature of heat energy as a byproduct of the chemical reaction and the average waste heat temperature from solid oxide fuel cell is at least from 50000 to 120000 , and the high-temperature waste heat utilizes to generate electrical energy from thermoelectric generator system, and wherein the solid oxide fuel cell produces waste heat energy byproducts and the waste heat energy further utilizes for;
Date Recue/Date Received 2021-05-26 i. a carbon dioxide capturing system unit; to increase the carbon dioxide absorbing rate on the system, and ii. a waste heat recovery unit; to generate electric power; and further, the solid oxide fuel cell connected and coupled with the carbon dioxide capturing system unit and waste heat recovery unit, and (b) a thermoelectric generator: generates electric power by routing exhaust waste heat from the solid oxide fuel cell, and the exhaust waste heat inter into a hot side of the thermoelectric generator and routing cold intake gases from the ambient air into a cold side of the thermoelectric generator and the thermoelectric generator produces electric energy based on a heat flux differences across the thermoelectric electrodes;
and wherein the thermoelectric generator and solid oxide fuel cell are geometrically, electrically and mechanically coupled to generate electric power at maximum thermodynamics efficiencies.
9. The carbon dioxide capturing and electrical energy producing system of claim 1, wherein the hybrid thermoelectric-generator and solid oxide fuel cell unit comprising the process and steps of:
i. producing sodium hydroxide from brine electrolysis, ii. by using sodium hydroxide producing hydrogen and oxygen gases from the hydrogen-oxygen generator, iii. routing hydrogen and oxygen gases to solid oxide fuel cell and generate electric power and heat energy, and iv. routing the waste heat released from solid oxide fuel cell into the hot side of the thermoelectric generator and routing cold intake gases from the ambient air into a cold side and generate additional electrical energy from waste heat.
10. The carbon dioxide capturing and electrical energy producing system of claim 1 comprises a carbon dioxide capturing unit for extracting and capturing carbon dioxide from the atmosphere or flue gas, and the physical structure and shape of a carbon dioxide capturing system unit is fashioned as a tree structure, and the tree fashioned carbon dioxide capturing system unit at least comprises;
Date Recue/Date Received 2021-05-26 (a) a fans; in the ergonomics of the tree fans are adapted in the leaves, to absorb carbon dioxide and ambient gases from the atmosphere, (b) an exhaust waste heat-based heater; the carbon dioxide absorbing part, and regeneration part utilizes exhausted waste heat which relisted from hybrid thermoelectric generator solid oxide fuel cell unit and waste heat released from hydrogen gas turbine unit, and wherein the heat-absorbing system fitted on the external surface of the absorbing part and regeneration part, and wherein the tree fashioned carbon dioxide capturing system unit is mechanically coupled and integrated with hydrogen gas turbine and hybrid thermoelectric solid oxide fuel cell system units, and wherein the used output waste heat from carbon dioxide absorbing part and regeneration part returned into the waste heat recovery system unit, (c) an absorbing part: absorb carbon dioxide through the solvents, sorbents, or adsorbents system; and wherein the carbon dioxide absorber part adapted in the branches and trunk of the tree fashioned system, and the absorber part comprises sorbents, adsorbents or solvents, (d) a carbon dioxide solvents, sorbents, adsorbents chemicals: the absorbing part utilizes liquid solvents, solid sorbents, or adsorbents to absorb and separate carbon dioxide from the atmosphere or flue gas, and the chemicals are mounted on the absorbing part of the system, and wherein the carbon dioxide separator part further utilizes a membrane method to capture carbon dioxide from the air or flue gas, (e) a regeneration part; the reached carbon dioxide solvents, sorbents, or adsorbents from absorbing part flows into the regenerator part and heat up, and carbon dioxide gas is produced, and solvents, sorbents, or adsorbents also produced for reuse, and wherein the regeneration part is mounted in the trunk of the tree fashioned system, and (f) a base of the tree; in the ergonomics of the tree at least carbon dioxide tankers, pumps, and controllers are mounted in the base of the tree; and Date Recue/Date Received 2021-05-26 wherein the base of the tree is coupled and connected with the upper level of the tree fashioned system, and wherein the tree fashioned carbon dioxide capturing system unit further comprising; a circulation pumps, stripper, carbon dioxide pumps, and carbon dioxide tankers.
11. The tree fashioned carbon dioxide capturing system unit claim 10 wherein the carbon dioxide absorbing part and regenerating part utilizes exhausted waste heat, and increase the temperature of the gases, sorbents, adsorbents, and solvents, and increase the carbon dioxide absorption rate in the system; and wherein the tree fashioned carbon dioxide capturing system unit is powered by the internally generated electric power from; the hydrogen gas turbine unit, and hybrid thermoelectric generator solid oxide fuel cell and waste heat recovery generator, and wherein the tree fashioned carbon dioxide capturing system is at least electrically and mechanically coupled and integrated with the hydrogen gas turbine unit, hybrid thermoelectric solid oxide fuel cell unit, and waste heat recovery generator unit.
12. The tree fashioned carbon dioxide capturing system unit claim 10 comprises at least the process and steps of;
i. by using the fans which adapted on the leaves of the fashioned carbon dioxide capturing tree, sucking atmospheric gases from the atmosphere, the carbon dioxide capturing is from flue gas, the flue gases directly flow into the carbon dioxide absorber part ii. heating-up the atmospheric gases in the fashioned carbon dioxide capturing tree iii. flowing the hot atmospheric gases into carbon dioxide absorber part, and absorb carbon dioxide in the fashioned carbon dioxide capturing tree iv. flowing the carbon dioxide reached solvents, sorbents or adsorbents into regeneration part in the fashioned carbon dioxide capturing tree, and v. heating the carbon dioxide reached solvents, sorbents or adsorbents and produces carbon dioxide and regenerate solvents, sorbents or adsorbents for re-use, in the fashioned carbon dioxide capturing tree.
Date Recue/Date Received 2021-05-26
13. The carbon dioxide capturing and electrical energy producing system of claim 1, wherein the hybrid solar hydrogen-oxygen gas generator system unit produces hydrogen and oxygen gases, and the system comprising;
(a) a solar powered hydrogen-oxygen gas generator; functioning with the integration of solar cells, and utilizes solar energy, and based on the electrolysis method it produces hydrogen and oxygen gases from the hydrogen-oxygen generator, and feeding hydrogen and oxygen gases to the hydrogen gas turbine unit and utilizes to startup the carbon dioxide capturing and electrical energy producing system, and wherein the solar powered hydrogen-oxygen gas generator further produces hydrogen and oxygen gases and stores in the tankers and utilizes as backup and startup for the hydrogen gas turbine, wherein a solar powered hydrogen-oxygen gas generator and the solar systems are physically and electrically integrated, to generate hydrogen and oxygen gases from solar energy, and (b) an internally powered hydrogen-oxygen gas generator; functioning with the integration of solid oxide fuel cell, thermoelectric generator, and hydrogen gas turbine, and utilizes electrical energy generated from solid oxide fuel cell, thermoelectric generator or hydrogen gas turbine, and powering the other hydrogen-oxygen gas generator cells and produce hydrogen and oxygen gases based on the electrolysis method, and feeding uninterrupted hydrogen and oxygen gases to hydrogen gas turbine and solid oxide fuel cell, and further the hydrogen gas feeding to the hydrogen-chlorine fuel cell; and wherein said hydrogen-oxygen gas generator system produces hydrogen and oxygen gases to the whole system, and the hydrogen-oxygen gas generator system at least comprises:
an alkali chemical: the electrolysis utilizes alkali chemicals such as sodium hydroxide, potassium hydroxide, and other alkali bases, and an integrated sources of power, and wherein said hydrogen-oxygen gas generator system powered from two sources of energy;
Date Recue/Date Received 2021-05-26 some of the hydrogen-oxygen gas generator cells are powered from solar energy and utilizes to produce for backup and reserving hydrogen gas, and and the rest of the hydrogen-oxygen gas generator cells are powered from internal generated electric power from thermoelectric generator solid oxide fuel cell unit, and hydrogen gas turbine unit, and produces enough amount of hydrogen and oxygen gases for the carbon dioxide capturing and electrical energy producing system,
14. The hybrid solar hydrogen-oxygen gas generator system unit claim 13 the system works with integrating of other units of the carbon dioxide capturing and electrical energy producing system units, and at least integrated with the;
(a) hydrogen gas turbine unit: utilize hydrogen and oxygen gases which produced in the hybrid solar hydrogen-oxygen gas generator system unit, and generate electrical power from hydrogen gas turbine unit, (b) hybrid thermoelectric generator solid oxide fuel cell unit; utilizes hydrogen and oxygen gases from the hybrid solar hydrogen-oxygen gas generator system unit, and generate electric power and heat energy through the solid oxide fuel cell, and (c) electrolysis of brine unit: to generate hydrogen and oxygen gases, the hybrid solar hydrogen-oxygen gas generator system unit utilizes sodium hydroxide from the electrolysis of the brine unit.
15. The hybrid solar hydrogen-oxygen gas generator system unit claim 13 the system works with integrating of other units of the carbon dioxide capturing and electrical energy producing system units, and at least integrated with the;
(a) hydrogen gas turbine unit: utilize hydrogen and oxygen gases which produced in the hybrid solar hydrogen-oxygen gas generator system unit, and generate electrical power from hydrogen gas turbine unit, (b) hybrid thermoelectric generator solid oxide fuel cell unit; utilizes hydrogen and oxygen gases from the hybrid solar hydrogen-oxygen gas generator system unit, and generate electric power and heat energy through the solid oxide fuel cell, and Date Recue/Date Received 2021-05-26 (c) electrolysis of brine unit: to generate hydrogen and oxygen gases, the hybrid solar hydrogen-oxygen gas generator system unit utilizes sodium hydroxide from the electrolysis of the brine unit, and wherein the hybrid solar hydrogen-oxygen gas generator system unit at least comprises the processes and steps of:
i. producing electrical energy from solar and powering hydrogen-oxygen gas generator, ii. producing hydrogen and oxygen gases from hydrogen-oxygen generator, by using electrolysis of sodium hydroxide or other alkali bases, iii. storing energy in the form of hydrogen, iv. routing hydrogen and oxygen gases to hydrogen gas turbine and start the operation and produce electric power from the system, v. storing and distributing electric power, and vi. powering the rest of hydrogen-oxygen gas generator cells and produce enough amount of hydrogen and oxygen gases and continuing the operation of the system.
16. The carbon dioxide capturing and electrical energy producing system of claim 1 wherein said hybrid hydrogen-chlorine fuel cell and carbon dioxide reactor core system unit comprising;
(a) a hydrogen chlorine fuel cell; mounted and integrated with reactor core, and generating electrical power from hydrogen and chlorine gas, and utilized to powering carbon dioxide reactor core by hydrogen chlorine fuel cell, and it reduces the consumption of electrical energy by carbon dioxide reactor core, and wherein the hydrogen chlorine fuel cell system that utilizes hydrogen as a fuel and chlorine gas as an oxidant, and the chlorine and hydrogen supplied respectively through the anode and cathode gas diffusion, and the system converts chemical energy into electrical energy, and the generated power utilized to power and operate the carbon dioxide reactor core, and wherein the hydrogen chlorine fuel cell system releases hydrogen chloride gas byproduct, and further, the hydrogen chloride gas reacts with water and is Date Recue/Date Received 2021-05-26 converted into hydrochloric acid, and the system cogenerates electrical energy and hydrochloric acid, and (b) a carbon dioxide reactor core system; converts carbon dioxide into carbonate and bicarbonate byproducts, and the system at least comprising;
i. a high-pressure compressing system; to increase the pressure in the reactor core and to increase the reaction between carbon dioxide with an alkali base, ii. a concentrated lather or ray emitters system; to emit radiation to the carbon dioxide and alkali base, and carbon dioxide molecules are exposed to concentrated radiations, the carbon dioxide molecule bonds become vibrate and the kinetic energy of carbon dioxide molecule bonds increase and the system creates to increase the reaction rate of carbon dioxide with alkali base increase, and wherein concentrated radiation emitters adapted in the head of compressing piston, and comprises radiation controlling system and diode housing, and the automatic controlling system receive signal and operate the opening and clothing, and wherein concentrated radiation emitters are light emitting diodes, and the light emitting diode emits light, and to concentrate the light, the concave lenses are fitted on it, and iii. a heat absorbing system; some amount of waste heat exhausted from hydrogen gas turbine is directed into heat absorbing system, wherein the external part of the carbon dioxide reactor core, and the waste heat is circulated into the body of the reactor core and heat is absorbed by heat absorbing system, creates to increase the temperature inside of the reactor core, finally the system utilized to increase the reaction rate of carbon dioxide with sodium hydroxide or alkali base, and wherein said heat absorber system fashioned to circulate hot gas and the hot waste gas circulating in the prepared lines of the body of reactor core, and heat absorbs by the reactor core, and wherein the heat-absorbing system fitted on the external surface of the reactor core.
Date Recue/Date Received 2021-05-26
17. The carbon dioxide reactor core system claim 16 wherein the high-pressure compressing system installed in the top of the reactor and the system at least comprises;
(a) an integrated automatic controlling system; utilizes at least to control compressing piston systems and pressure sensors, (b) a compressing piston; is adapted in the head of the reactor core, and (c) an automatic controlling system; receives a signal from pressure sensors and control the operation of the compressing system; and wherein the carbon dioxide reactor core system comprises a method to increase mass transfer and to increase kinetic collisions of carbon dioxide with sodium hydroxide, and the system further comprises different methods; such as spraying sodium hydroxide solution over carbon dioxide, in the reactor core, or bubbling carbon dioxide method;
and wherein the hybrid hydrogen chlorine fuel cell and carbon dioxide reactor core system unit converts carbon dioxide into carbonate and bicarbonate byproducts, and at least comprising the processes and steps of;
i. collecting chlorine and hydrogen gas from the electrolysis of sodium chloride, ii. producing electric power from hydrogen-chlorine fuel cell, powering the carbon dioxide reactor core, iii. capturing carbon dioxide from the atmosphere or flue gas and storing in the tankers iv. pumping carbon dioxide gas into carbon dioxide reactor core, v. pumping sodium hydroxide solution or alkali base into the reactor core, and spraying over the carbon dioxide, and vi. converting carbon dioxide to carbonate and bicarbonate products.
18. The hybrid hydrogen-chlorine fuel cell and carbon dioxide reactor core system unit claim 16 comprises the other alternative embodiment of carbon dioxide reactor core and the other alternative embodiment system comprises;
(a) the heat-absorbing system; some amount of waste heat exhausted from the steam turbine is directed into the heat-absorbing system, wherein the external part of the carbon dioxide reactor core, and the waste heat is circulated into the body of the reactor core, and heat is absorbed by the heat-absorbing system, creates to Date Recue/Date Received 2021-05-26 increase the temperature inside of the reactor core, finally the system utilized to increase the reaction rate of carbon dioxide with sodium hydroxide, wherein the heat-absorbing system fitted on the external surface of the carbon dioxide reactor core, (b) the hydrogen chlorine fuel cell; system that utilizes hydrogen as a fuel and chlorine gas as an oxidant, and generates electric power wherein the hydrogen chlorine fuel cell integrated and coupled with the carbon dioxide reactor core (c) the carbon dioxide reactor core: comprises a sprayer, and spraying sodium hydroxide solution over carbon dioxide gas, in the reactor core, and the system converts into carbonates and bicarbonate byproducts; and wherein the other alternative embodiment of carbon dioxide reactor core comprising a sodium hydroxide or alkali base sprayer: and the sprayer is mounted on the top of the reactor core and spray sodium hydroxide or alkali base solution over the carbon dioxide zone.
19. The carbon dioxide capturing and electrical energy producing system of claim 1 wherein said waste heat recovery unit utilizes exhaust waste heat which released from hydrogen gas turbine, solid oxide fuel cell, hydrogen-chlorine fuel cell, carbon dioxide capturing unit and from carbon dioxide reactor core, and the waste heat recovery system unit used to recovered waste heat and utilized to drive an additional steam turbine and generate additional electric power, and the waste heat recovery system at least comprising;
(a) a waste heat recovery generator; to recover waste heat exhausted from hydrogen gas turbine, solid oxide fuel cell, hydrogen-chlorine fuel cell, carbon dioxide capturing unit and from carbon dioxide reactor core, and wherein said waste heat recovery generator produce steams from exhausted waste heat and the produced steam flows into hydrogen-oxygen superheater, and wherein said waste heat recovery generator has a duct for receiving hot exhaust gas from hydrogen gas turbine, solid oxide fuel cell, hydrogen-chlorine fuel cell, carbon dioxide capturing unit, and from carbon dioxide reactor core, and the waste heat Date Recue/Date Received 2021-05-26 recovery steam generator is also associated with a heating system for receiving feed water for heating to steam and producing steam, (b) a hydrogen oxygen superheater; to re-heat the recovered steam and to produce high pressurized steam, and wherein the hydrogen-oxygen superheater system at least comprises;
(a) an ignition system; for burning hydrogen and oxygen directly into the steam and creating superheat steam, and wherein the ignition system is mounted in a steam line for burning hydrogen and oxygen directly in the steam flowing through the superheater zone, thus increasing the temperature of such steam, (b) a hydrogen and oxygen gas supply lines; to supply hydrogen and oxygen to superheater zone (c) a hydrogen and oxygen flow rate regulator; to control the flow rate of hydrogen and oxygen gases, and to control the burning temperature in the superheater zone, and wherein the hydrogen and oxygen flow rate regulator receives a continuous signal from the temperature sensor to control the burning temperature in the superheater zone and to control the temperature of the steam (d) a temperature sensing device; is mounted in the superheater zone and utilized to feed continuous signals to the hydrogen and oxygen gas regulators and controllers and to position the hydrogen and oxygen gas valves to maintain the desired value; and wherein the hydrogen-oxygen superheater increases the temperature of the incoming steam to the desired value and the high temperature pressurized steam turned into the steam turbine and the steam turbine drives the electric generator and produce electric power, and (c) a steam turbine; to utilize the recovered waste steam and to drives the electric generator and it produces additional electric power; and wherein the waste heat recovery system unit comprises the other alternative hydrogen-oxygen superheater system, and the system comprising; burner, steam flowing pipe, Date Recue/Date Received 2021-05-26 ignition system, hydrogen and oxygen gas lines, hydrogen gas flow regulator, oxygen flow rate regulator, and temperature sensor; and wherein the other alternative embodiment of the hydrogen-oxygen superheater the hydrogen and oxygen gases burned over the steam containing pipes and the volume and pressure of the steam inside the pipe increased,
20. The waste heat recovery system unit claim 21 collects waste heat from carbon dioxide capturing and electrical energy system and converts into electrical energy, and the system comprising at least the process and steps of;
(a) collecting waste heat exhausted from hydrogen gas turbine, solid oxide fuel cell, hydrogen-chlorine fuel cell, and carbon dioxide reactor core, (b) turning the collected waste heat into waste heat recovery steam generator, and the waste heat steam generator produce steams from exhausted waste heat, and the produced steam flows to hydrogen-oxygen superheater system, and (c) through the hydrogen-oxygen superheater, burning hydrogen and oxygen gases directly in the steam line and reheat the steam and produce high pressurized steam, the high pressure, and temperature steam flow into the steam turbine and the steam turbine drives the electric generator and produces additional electric power.
21. The carbon dioxide and electrical energy producing system claim 1 comprises the other alternative embodiments one, for alternative producing electric power and capturing carbon dioxide from the system, and the arrangements and integrations of the system at least comprising;
(a) the non-ionized hydrogen gas turbine unit; to generate electric power (b) the hybrid solar hydrogen-oxygen gas generator unit; to produce hydrogen and oxygen gases for hydrogen gas turbine, (c) the tree fashioned carbon dioxide capturing unit: to capture carbon dioxide from the atmosphere (d) the waste heat recovery system unit; to recover waste heat released from non-ionized hydrogen gas turbine unit Date Recue/Date Received 2021-05-26 (e) the brine electrolysis unit; to produce sodium hydroxide for tree fashioned carbon dioxide capturing unite and for hybrid solar hydrogen-oxygen gas generator unit, and (f) the hydrogen chlorine fuel cell: to convert exhausted chlorine gas and hydrogen into electric power and hydrochloric acid.
22. The other alternative embodiment one, claim 21 wherein the tree fashioned carbon dioxide capturing system sucking atmospheric gases and directly converted carbon dioxide into carbonate and bicarbonate products, and the system at least comprising;
(a) the fans; to absorb carbon dioxide and ambient gases from the atmosphere in the ergonomics of the tree fashioned carbon dioxide capturing system unit wherein the fans are adapted in the leaves of the tree fashioned, (b) the absorber part; in the tree fashioned system, carbon dioxide absorber parts are adapted in the branches and trunk, and the branches and trunk of the tree fashioned are hollow tubes, and the sprayers are adapted on the top of the tubes to spry sodium hydroxide or potassium hydroxide over the hot atmospheric gases, and inside of the tubes, carbon dioxide gases and sodium hydroxide or potassium hydroxide are intermixing together, (c) a vertical circular helical tube: in the ergonomics of the tree, the carbon dioxide absorbing performs in the vertical circular helical tube and mounted in the trunk tree fashioned system, and the carbon dioxide gas and sodium hydroxide or potassium hydroxide flows together inside of the vertical helical tube, and converted into carbonates;
and due to the temperature and the structure of the vertical helical tube the absorption rate of carbon dioxide increase, and the carbonates and bicarbonates product accumulated in the base of the trunk, and (d) the base of the tree fashioned; at least the base of the tree fashioned comprises;
carbonate and bicarbonate tankers and circulation pumps, and controllers; and wherein the tree fashioned carbon dioxide capturing system utilizes waste heat to increase the absorption of carbon dioxide, and the waste heat is pumped from Date Recue/Date Received 2021-05-26 hydrogen gas turbine, and the waste heat flows through the tubes in the branches and vertical helical tube wherein the trunk fashioned tree; and wherein the heat-absorbing system fitted on the external surface of the absorbing part of the branches and vertical helical tube, and wherein the another alternative embodiment one of carbon dioxide capturing and energy producing system, at least comprises the steps of;
(a) producing hydrogen and oxygen gases from hybrid solar hydrogen-oxygen gas generator (b) by utilizing hydrogen and oxygen gases, producing electric power from non-ionized hydrogen gas turbine (c) producing sodium hydroxide, hydrogen, and chlorine through brine electrolysis (d) providing hydrogen and chlorine gases, and producing electric power from hydrogen-chlorine fuel cell, and (e) sucking atmospheric gases through the tree fashioned carbon dioxide capturing system unit; and to absorb carbon dioxide the system utilizes sodium hydroxide or potassium hydroxide, and directly converting into carbonate and bicarbonate products through the tree fashioned carbon dioxide capturing system unit.
23. The carbon dioxide and electrical energy producing system claim 1 comprises the other alternative embodiment two, for alternative producing electric power and capturing carbon dioxide from the system, and at least comprising;
(a) the hybrid solar hydrogen and oxygen gas generator unit (b) the non-ionized hydrogen gas turbine unit, and (c) the tree fashioned carbon dioxide capturing unite; and the fans, the absorber part, the vertical circular tube, the base of the tree fashioned system, the waste heat, pumps, controllers, carbonate and bicarbonate tankers, and alkali base sprayer are further utilized in the other alternative embodiment two of the carbon dioxide capturing and energy producing system arrangements; and wherein the other alternative embodiment two of the carbon dioxide capturing and electrical energy producing system at least comprising the processes and steps of;
Date Recue/Date Received 2021-05-26 (a) producing hydrogen and oxygen gases from hybrid solar hydrogen-oxygen gas generator (b) by utilizing hydrogen and oxygen gases, and producing electric power from non-ionized hydrogen gas turbine, and (c) sucking atmospheric gases through the tree fashioned carbon dioxide capturing system unit and directly converts carbon dioxide into carbonate and bicarbonate products.
24. The carbon dioxide and electrical energy producing system claim 1 comprises the other alternative embodiment three, for alternative producing electric power and capturing carbon dioxide from the system, and the system at least comprising; hybrid solar hydrogen and oxygen gas generator unit, fuel cell unit, and tree fashioned carbon dioxide capturing unit; and the fans, the absorber part, the vertical circular tube, the base of the tree fashioned system, carbonate and bicarbonate tankers, pumps, controllers, and alkali base sprayer, further utilized in the other alternative embodiment three of the carbon dioxide capturing and energy producing system arrangements; and wherein the other alternative embodiment three of the carbon dioxide capturing and energy producing system, the hydrogen-oxygen generator unit and the fuel cells unit are adapted on the base of the carbon dioxide capturing tree, and the solar cells are adapted in the top of the tree fashioned carbon dioxide capturing, beside the fans; and wherein the other alternative embodiment three of the carbon dioxide capturing and energy producing system at least comprising the processes and steps of;
(a) utilizing solar power and producing hydrogen and oxygen gases from the hydrogen-oxygen gas generator (b) by utilizing hydrogen and oxygen gases, producing electric power from fuel cells, and powering tree fashioned carbon dioxide capturing system unit Date Recue/Date Received 2021-05-26 (c) sucking atmospheric gases through the tree fashioned carbon dioxide capturing system unit, and absorbing carbon dioxide through sodium hydroxide or potassium hydroxide, and directly converting into carbonate and bicarbonate products.
25. The carbon dioxide capturing and electrical energy producing system of claim 1 wherein the hydrogen gas turbine unit, hybrid thermoelectric-generator solid oxide fuel cell unit, solar hybrid hydrogen-oxygen gas generator system unit, hybrid hydrogen chlorine fuel cell and carbon dioxide reactor core unit, and waste recovery system units are physically, electrically, and mechanically coupled and integrated to perform the carbon dioxide capturing and electrical energy producing process from the system.
Date Recue/Date Received 2021-05-26
CA3119677A 2021-05-26 2021-05-26 Apparatuses and methods for carbon dioxide capturing and electrical energy producing system Pending CA3119677A1 (en)

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