CA2858155C - Procede et appareil pour retirer de l'azote d'une composition d'hydrocarbures cryogeniques - Google Patents
Procede et appareil pour retirer de l'azote d'une composition d'hydrocarbures cryogeniques Download PDFInfo
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- CA2858155C CA2858155C CA2858155A CA2858155A CA2858155C CA 2858155 C CA2858155 C CA 2858155C CA 2858155 A CA2858155 A CA 2858155A CA 2858155 A CA2858155 A CA 2858155A CA 2858155 C CA2858155 C CA 2858155C
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- vapour
- nitrogen
- stream
- stripping
- fraction
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title claims abstract description 312
- 229910052757 nitrogen Inorganic materials 0.000 title claims abstract description 157
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 140
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 139
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 130
- 238000000034 method Methods 0.000 title claims abstract description 115
- 239000000203 mixture Substances 0.000 title claims abstract description 59
- 239000007788 liquid Substances 0.000 claims abstract description 110
- 239000003507 refrigerant Substances 0.000 claims abstract description 104
- 230000008569 process Effects 0.000 claims abstract description 83
- 239000007789 gas Substances 0.000 claims abstract description 44
- 238000001816 cooling Methods 0.000 claims abstract description 41
- 238000010438 heat treatment Methods 0.000 claims abstract description 39
- 238000010992 reflux Methods 0.000 claims abstract description 31
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 84
- 238000002485 combustion reaction Methods 0.000 claims description 26
- 239000012530 fluid Substances 0.000 claims description 19
- 238000004891 communication Methods 0.000 claims description 18
- 239000000446 fuel Substances 0.000 claims description 14
- 239000002737 fuel gas Substances 0.000 claims description 12
- 239000007791 liquid phase Substances 0.000 claims description 12
- 239000012071 phase Substances 0.000 claims description 12
- 238000000926 separation method Methods 0.000 claims description 10
- JVFDADFMKQKAHW-UHFFFAOYSA-N C.[N] Chemical compound C.[N] JVFDADFMKQKAHW-UHFFFAOYSA-N 0.000 claims description 9
- 238000007599 discharging Methods 0.000 claims description 2
- 239000000047 product Substances 0.000 description 48
- 238000011068 loading method Methods 0.000 description 21
- 239000003949 liquefied natural gas Substances 0.000 description 14
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- 230000008901 benefit Effects 0.000 description 10
- 239000003345 natural gas Substances 0.000 description 9
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
- 230000001105 regulatory effect Effects 0.000 description 8
- 238000011144 upstream manufacturing Methods 0.000 description 8
- 238000011084 recovery Methods 0.000 description 7
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 230000004044 response Effects 0.000 description 5
- 239000001294 propane Substances 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical class CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 235000013844 butane Nutrition 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 238000005057 refrigeration Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000002207 thermal evaporation Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
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- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0022—Hydrocarbons, e.g. natural gas
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- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
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- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
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- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/004—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by flash gas recovery
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- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
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- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0042—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by liquid expansion with extraction of work
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- F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
- F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
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- F25J1/0216—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle with one SCR cycle using a C3 pre-cooling cycle
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J1/0235—Heat exchange integration
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0244—Operation; Control and regulation; Instrumentation
- F25J1/0254—Operation; Control and regulation; Instrumentation controlling particular process parameter, e.g. pressure, temperature
- F25J1/0255—Operation; Control and regulation; Instrumentation controlling particular process parameter, e.g. pressure, temperature controlling the composition of the feed or liquefied gas, e.g. to achieve a particular heating value of natural gas
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- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
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- F25J1/0281—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc. characterised by the type of prime driver, e.g. hot gas expander
- F25J1/0284—Electrical motor as the prime mechanical driver
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/50—Processes or apparatus using separation by rectification using multiple (re-)boiler-condensers at different heights of the column
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/74—Refluxing the column with at least a part of the partially condensed overhead gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/02—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/06—Splitting of the feed stream, e.g. for treating or cooling in different ways
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/60—Processes or apparatus involving steps for increasing the pressure of gaseous process streams the fluid being hydrocarbons or a mixture of hydrocarbons
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2240/00—Processes or apparatus involving steps for expanding of process streams
- F25J2240/30—Dynamic liquid or hydraulic expansion with extraction of work, e.g. single phase or two-phase turbine
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2245/00—Processes or apparatus involving steps for recycling of process streams
- F25J2245/02—Recycle of a stream in general, e.g. a by-pass stream
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2245/00—Processes or apparatus involving steps for recycling of process streams
- F25J2245/90—Processes or apparatus involving steps for recycling of process streams the recycled stream being boil-off gas from storage
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2280/00—Control of the process or apparatus
- F25J2280/02—Control in general, load changes, different modes ("runs"), measurements
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
De l'azote est retiré d'une composition d'hydrocarbures cryogéniques. Au moins une première partie de la composition d'hydrocarbures cryogéniques est introduite dans une colonne de strippage d'azote. La colonne de strippage d'azote fonctionne à une pression de strippage. Une vapeur de strippage est amenée à passer à travers la colonne de strippage d'azote, comprenant au moins une partie de strippage d'une vapeur de traitement comprimée qui a été produite à partir du liquide ayant subi le strippage d'azote, qui a été dépressurisé après son soutirage de la colonne de strippage d'azote. Un reflux est généré et mettant en jeu une condensation partielle de la vapeur de tête de la colonne de strippage d'azote par passage de chaleur de la vapeur de tête à un courant de réfrigérant auxiliaire à un dispositif de refroidissement. Un gaz d'échappement consistant en une fraction de vapeur non condensée provenant de la vapeur de tête est déchargé. Le dispositif de refroidissement est ajusté pour réguler une valeur de chauffage de la fraction de vapeur qui est déchargée.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11192920.4 | 2011-12-12 | ||
EP11192920 | 2011-12-12 | ||
PCT/EP2012/074959 WO2013087571A2 (fr) | 2011-12-12 | 2012-12-10 | Procédé et appareil pour retirer de l'azote d'une composition d'hydrocarbures cryogéniques |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2858155A1 CA2858155A1 (fr) | 2013-06-20 |
CA2858155C true CA2858155C (fr) | 2020-04-28 |
Family
ID=47351660
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2858155A Active CA2858155C (fr) | 2011-12-12 | 2012-12-10 | Procede et appareil pour retirer de l'azote d'une composition d'hydrocarbures cryogeniques |
Country Status (7)
Country | Link |
---|---|
US (1) | US20140345319A1 (fr) |
CN (1) | CN104011489B (fr) |
AU (1) | AU2012354774B2 (fr) |
CA (1) | CA2858155C (fr) |
MY (1) | MY185531A (fr) |
RU (1) | RU2607708C2 (fr) |
WO (1) | WO2013087571A2 (fr) |
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EP2857782A1 (fr) * | 2013-10-04 | 2015-04-08 | Shell International Research Maatschappij B.V. | Échangeur de chaleur à bobine enroulée et procédé de refroidissement d'un flux de procédé |
US10563913B2 (en) * | 2013-11-15 | 2020-02-18 | Black & Veatch Holding Company | Systems and methods for hydrocarbon refrigeration with a mixed refrigerant cycle |
US20150276307A1 (en) * | 2014-03-26 | 2015-10-01 | Dresser-Rand Company | System and method for the production of liquefied natural gas |
US20150308737A1 (en) | 2014-04-24 | 2015-10-29 | Air Products And Chemicals, Inc. | Integrated Nitrogen Removal in the Production of Liquefied Natural Gas Using Intermediate Feed Gas Separation |
US9945604B2 (en) * | 2014-04-24 | 2018-04-17 | Air Products And Chemicals, Inc. | Integrated nitrogen removal in the production of liquefied natural gas using refrigerated heat pump |
EP2977430A1 (fr) * | 2014-07-24 | 2016-01-27 | Shell Internationale Research Maatschappij B.V. | Stabilisateur de condensat d'hydrocarbure et procédé de production d'un flux de condensat d'hydrocarbure stabilisé |
AR105277A1 (es) | 2015-07-08 | 2017-09-20 | Chart Energy & Chemicals Inc | Sistema y método de refrigeración mixta |
US10330382B2 (en) | 2016-05-18 | 2019-06-25 | Fluor Technologies Corporation | Systems and methods for LNG production with propane and ethane recovery |
BR112019003090A2 (pt) * | 2016-09-09 | 2019-05-21 | Fluor Technologies Corporation | métodos e configuração para reformar usina de ngl para alta recuperação de etano |
CN106885713B (zh) * | 2017-03-20 | 2019-06-11 | 上海锐宇流体系统有限公司 | 高压易闪蒸混合液体取样装置 |
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-
2012
- 2012-12-10 RU RU2014128666A patent/RU2607708C2/ru active
- 2012-12-10 AU AU2012354774A patent/AU2012354774B2/en active Active
- 2012-12-10 CA CA2858155A patent/CA2858155C/fr active Active
- 2012-12-10 CN CN201280061162.5A patent/CN104011489B/zh active Active
- 2012-12-10 WO PCT/EP2012/074959 patent/WO2013087571A2/fr active Application Filing
- 2012-12-10 MY MYPI2014701217A patent/MY185531A/en unknown
- 2012-12-10 US US14/364,262 patent/US20140345319A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
WO2013087571A3 (fr) | 2014-05-01 |
RU2014128666A (ru) | 2016-02-10 |
CA2858155A1 (fr) | 2013-06-20 |
WO2013087571A2 (fr) | 2013-06-20 |
AU2012354774B2 (en) | 2015-09-10 |
MY185531A (en) | 2021-05-19 |
CN104011489B (zh) | 2016-03-23 |
US20140345319A1 (en) | 2014-11-27 |
RU2607708C2 (ru) | 2017-01-10 |
AU2012354774A1 (en) | 2013-07-18 |
CN104011489A (zh) | 2014-08-27 |
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