CA2502423A1 - Acidic cleaning method for machine dishwashing - Google Patents
Acidic cleaning method for machine dishwashing Download PDFInfo
- Publication number
- CA2502423A1 CA2502423A1 CA002502423A CA2502423A CA2502423A1 CA 2502423 A1 CA2502423 A1 CA 2502423A1 CA 002502423 A CA002502423 A CA 002502423A CA 2502423 A CA2502423 A CA 2502423A CA 2502423 A1 CA2502423 A1 CA 2502423A1
- Authority
- CA
- Canada
- Prior art keywords
- acid
- cleaning solution
- tableware
- aqueous cleaning
- acidic aqueous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004140 cleaning Methods 0.000 title claims abstract 28
- 238000000034 method Methods 0.000 title claims abstract 26
- 230000002378 acidificating effect Effects 0.000 title claims abstract 23
- 238000004851 dishwashing Methods 0.000 title claims abstract 4
- 239000002689 soil Substances 0.000 claims abstract 3
- 230000003472 neutralizing effect Effects 0.000 claims abstract 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims 4
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims 4
- 239000002253 acid Substances 0.000 claims 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims 2
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- 239000004063 acid-resistant material Substances 0.000 claims 2
- 150000007513 acids Chemical class 0.000 claims 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 2
- 235000019253 formic acid Nutrition 0.000 claims 2
- 239000000174 gluconic acid Substances 0.000 claims 2
- 235000012208 gluconic acid Nutrition 0.000 claims 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims 2
- 239000000126 substance Substances 0.000 claims 2
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 claims 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims 1
- 239000005711 Benzoic acid Substances 0.000 claims 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- 229920002125 Sokalan® Polymers 0.000 claims 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 1
- 235000011054 acetic acid Nutrition 0.000 claims 1
- 239000001361 adipic acid Substances 0.000 claims 1
- 235000011037 adipic acid Nutrition 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims 1
- 235000010233 benzoic acid Nutrition 0.000 claims 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims 1
- 239000006260 foam Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- 239000004310 lactic acid Substances 0.000 claims 1
- 235000014655 lactic acid Nutrition 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 1
- 239000011976 maleic acid Substances 0.000 claims 1
- 229940098779 methanesulfonic acid Drugs 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 150000007522 mineralic acids Chemical class 0.000 claims 1
- DUWWHGPELOTTOE-UHFFFAOYSA-N n-(5-chloro-2,4-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC(OC)=C(NC(=O)CC(C)=O)C=C1Cl DUWWHGPELOTTOE-UHFFFAOYSA-N 0.000 claims 1
- 229910017604 nitric acid Inorganic materials 0.000 claims 1
- 150000007524 organic acids Chemical class 0.000 claims 1
- 235000005985 organic acids Nutrition 0.000 claims 1
- 235000006408 oxalic acid Nutrition 0.000 claims 1
- 150000003009 phosphonic acids Chemical class 0.000 claims 1
- 235000011007 phosphoric acid Nutrition 0.000 claims 1
- 235000019260 propionic acid Nutrition 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- 239000002351 wastewater Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 abstract 4
- 239000007864 aqueous solution Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/06—Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/08—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/34—Organic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/44—Multi-step processes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Cleaning By Liquid Or Steam (AREA)
Abstract
The process of continuous machine dishwashing, which can be carried out in single-tank or multi-tank machines, is improved by the machine-operated process disclosed. This is achieved, in particular, by treatment of the tableware at least in one process step with an acidic cleaning solution and in another process step with an alkaline cleaning solution, comprising the steps of: a) applying an acidic aqueous cleaning solution to the at least partly soiled tableware and b) removing the acidic aqueous solution and the soil in one or more following steps, the at least one alkaline treatment taking place before and/or after the acidic treatment and the alkaline and at least acidic aqueous cleaning solution at least partially neutralizing one another.
Claims (19)
1. A process for continuous or discontinuous machine dishwashing, in which the tableware is treated at least in one process step with an acidic cleaning solution and, in another process step, with an alkaline cleaning solution, comprising the steps of a) applying an acidic aqueous cleaning solution before the final rinse cycle or the final rinse zone to the at least partly soiled tableware and b) removing the acidic aqueous cleaning solution and the soil in one or more following steps, the at least one alkaline treatment taking place before and/or after the acidic treatment and the alkaline and at least one acidic aqueous cleaning solution at least partially neutralizing one another.
2. A process as claimed in claim 1, characterized in that the acidic aqueous cleaning solution contains one or more acids selected from the mineral and/or organic acids.
3. A process as claimed in claim 2, characterized in that at least one acid is present which is selected from sulfuric acid, nitric acid, phosphoric acid, formic acid, acetic acid, propanoic acid, glycolic acid, citric acid, maleic acid, lactic acid, gluconic acid, alkane sulfonic acid, amidosulfonic acid, succinic acid, glutaric acid, adipic acid, oxalic acid, benzoic acid, phosphonic acids, polyacrylic acids or mixtures thereof.
4. A process as claimed in claim 3, characterized in that at least one acid is present which is selected from formic acid, glycolic acid, gluconic acid, amidosulfonic acid or the alkanesulfonic acids, more particularly methanesulfonic acid or mixtures thereof.
5. A process as claimed in one or more of claims 1 to 4, characterized in that the acidic aqueous cleaning solution contains between 0.01 and 10% by weight of one or more detersive substances, based on the cleaning solution.
6. A process as claimed in claim 5, characterized in that the acidic aqueous cleaning solution contains less than 0.9% by weight, preferably less than 0.8% by weight and more preferably less than 0.5% by weight of one or more detersive substances, based on the cleaning solution.
7. A process as claimed in one or more of claims 1 to 6, characterized in that the acidic aqueous cleaning solution is allowed to act on to the tableware and the soil for a certain contact time (during which spraying stops), the contact time of this aqueous cleaning solution with the tableware preferably being 2 to 100 seconds, more preferably 5 to 100 seconds and most preferably 8 to 25 seconds.
8. A process as claimed in claim 7, characterized in that the tableware is not intentionally sprayed during the contact time.
9. A process as claimed in claims 1 to 8, characterized in that the acidic aqueous cleaning solution is sprayed onto the tableware as a fine, gentle, mist-like liquid spray.
10. A process as claimed in one or more of claims 1 to 8, characterized in that the acidic aqueous cleaning solution is applied to the tableware as foam.
11. A process as claimed in claim 9 or 10, characterized in that the acidic aqueous cleaning solution is applied through suitable nozzles.
12. A process as claimed in one or more of claims 1 to 11, characterized in that the treatment with the acidic aqueous cleaning solution is preceded by an alkaline treatment.
13. A process as claimed in claim 12, characterized in that an aqueous cleaning solution having a pH above 10 is used for the alkaline treatment of the tableware.
14. A process as claimed in one or more of claims 1 to 13, characterized in that the treatment with the acidic aqueous cleaning solution is followed by an alkaline treatment of the tableware.
15. A process as claimed in one or more of claims 12 to 14, characterized in that the tableware is subjected in all to at least three cleaning steps, an alkaline treatment of the tableware being carried out before and after the treatment with the acidic aqueous cleaning solution.
16. A process as claimed in one or more of claims 12 to 15, characterized in that, during the alkaline treatment, the tableware is contacted with one or more aqueous cleaning solutions which contain between 0.1 and 4% by weight of an alkali carrier, preferably a hydroxide selected from sodium hydroxide, potassium hydroxide or mixtures thereof.
17. A process as claimed in one or more of claims 1 to 16, characterized in that the pH of the wastewater produced by the process is below 12, preferably below 11.
18. An institutional dishwashing machine comprising several tanks which are arranged adjacent one another in known manner on the cascade principle and from which rinse or wash liquor is sprayed onto the tableware and then drains back into the tanks, characterized in that the tanks intended for one or more acidic cleaning steps in accordance with the invention with one or more claims 1 to 17 are made of and/or lined with acid-resistant material.
19. A single-tank washing machine, for example a domestic dishwasher, which is suitable for the process claimed in one or more of claims 1 to 15 and which is made of and/or lined with acid-resistant material, more particularly in the places where it comes in to contact with acidic cleaning solutions.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10257391.3 | 2002-12-06 | ||
| DE10257391A DE10257391A1 (en) | 2002-12-06 | 2002-12-06 | Continuous or discontinuous machine dishwashing of soiled tableware comprises applying acidic aqueous cleaning solution to soiled tableware and performing alkaline treatment before and/or after acidic treatment |
| PCT/EP2003/012366 WO2004052564A1 (en) | 2002-12-06 | 2003-11-06 | Acidic cleaning method for machine dishwashing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2502423A1 true CA2502423A1 (en) | 2004-06-24 |
| CA2502423C CA2502423C (en) | 2010-08-03 |
Family
ID=32336137
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2502423A Expired - Lifetime CA2502423C (en) | 2002-12-06 | 2003-11-06 | Acidic cleaning method for machine dishwashing |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1567289B2 (en) |
| AT (1) | ATE362807T2 (en) |
| AU (1) | AU2003279362B2 (en) |
| CA (1) | CA2502423C (en) |
| DE (2) | DE10257391A1 (en) |
| WO (1) | WO2004052564A1 (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8092613B2 (en) | 2002-05-31 | 2012-01-10 | Ecolab Usa Inc. | Methods and compositions for the removal of starch |
| WO2005068598A1 (en) * | 2003-12-18 | 2005-07-28 | Ecolab Inc. | Methods and compositions for the removal of starch |
| US8426349B2 (en) * | 2009-05-26 | 2013-04-23 | Delaval Holding Ab | Chlorinated alkaline pipeline cleaner with methane sulfonic acid |
| DE102011017294A1 (en) | 2011-04-15 | 2012-10-18 | Meiko Maschinenbau Gmbh & Co. Kg | Transport dishwasher with special treatment zones |
| ES2752079T3 (en) | 2011-05-20 | 2020-04-02 | Ecolab Usa Inc | Acidic formulations for use in a utensil washing system |
| BR112013028007A2 (en) * | 2011-05-20 | 2017-01-10 | Ecolab Usa Inc | non-phosphate detergents and non-phosphoric acids in an alternating system alkalinity / acidity for dishwashing |
| EP3282004B1 (en) | 2011-12-13 | 2019-07-31 | Ecolab USA Inc. | Warewashing method |
| EP3210517B1 (en) | 2011-12-13 | 2021-03-31 | Ecolab USA Inc. | Dishmachine |
| WO2016179009A1 (en) * | 2015-05-07 | 2016-11-10 | Cryovac, Inc. | Container washing and detergent for use thereof |
| US11421191B1 (en) | 2018-11-15 | 2022-08-23 | Ecolab Usa Inc. | Acidic cleaner |
| WO2024164162A1 (en) * | 2023-02-08 | 2024-08-15 | Ecolab Usa Inc. | A low-temperature, caustic dishware sanitizing method |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1628632C3 (en) * | 1966-11-26 | 1980-10-09 | Henkel Kgaa, 4000 Duesseldorf | Process for machine washing of dishes |
| DE1703441A1 (en) * | 1968-05-21 | 1971-12-09 | Bosch Hausgeraete Gmbh | Dishwasher |
| DE3532552A1 (en) * | 1985-09-12 | 1987-03-12 | Henkel Kgaa | METHOD FOR ADJUSTING A PH AREA IN THE WASTE WATER AND DEVICE FOR CARRYING OUT THE METHOD |
| DE3707366A1 (en) * | 1987-03-07 | 1988-09-15 | Diversey Gmbh | METHOD FOR THE CONTINUOUS OR DISCONTINUOUS MACHINE CLEANING OF CLEANING UTENSILS |
| DE4113024A1 (en) * | 1991-04-20 | 1992-10-22 | Henkel Kgaa | METHOD FOR THE MACHINE CLEANING OF Crockery |
| TW338713B (en) * | 1995-09-06 | 1998-08-21 | Sharp Kk | A dishwasher |
| US5879469A (en) * | 1997-01-06 | 1999-03-09 | Deeay Technologies Ltd. | Dishwashing method and detergent composition therefor |
| WO2000046329A1 (en) * | 1999-02-05 | 2000-08-10 | Unilever Plc | Dish washing process and compositions relating thereto |
| AU2002220549A1 (en) * | 2000-10-10 | 2002-04-22 | Johnsondiversey, Inc. | A detergent composition and method for warewashing |
| DE10127919A1 (en) * | 2001-06-08 | 2002-12-19 | Ecolab Gmbh & Co Ohg | Washing processes, for removing mineral or starch deposits in industrial or domestic dishwashers is effected with both alkaline and acidic stages |
-
2002
- 2002-12-06 DE DE10257391A patent/DE10257391A1/en not_active Ceased
-
2003
- 2003-11-06 EP EP03772309.5A patent/EP1567289B2/en not_active Expired - Lifetime
- 2003-11-06 AT AT03772309T patent/ATE362807T2/en active
- 2003-11-06 CA CA2502423A patent/CA2502423C/en not_active Expired - Lifetime
- 2003-11-06 WO PCT/EP2003/012366 patent/WO2004052564A1/en active IP Right Grant
- 2003-11-06 AU AU2003279362A patent/AU2003279362B2/en not_active Ceased
- 2003-11-06 DE DE60314007.6T patent/DE60314007T3/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1567289B1 (en) | 2007-05-23 |
| AU2003279362B2 (en) | 2009-03-12 |
| EP1567289A1 (en) | 2005-08-31 |
| EP1567289B2 (en) | 2017-06-07 |
| DE60314007T3 (en) | 2017-10-12 |
| CA2502423C (en) | 2010-08-03 |
| DE60314007T2 (en) | 2008-01-24 |
| DE10257391A1 (en) | 2004-06-24 |
| ATE362807T2 (en) | 2007-06-15 |
| AU2003279362A2 (en) | 2004-06-30 |
| BR0316171A (en) | 2005-09-27 |
| WO2004052564A1 (en) | 2004-06-24 |
| DE60314007D1 (en) | 2007-07-05 |
| AU2003279362A1 (en) | 2004-06-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKEX | Expiry |
Effective date: 20231106 |