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CA2540773A1 - Fuel cell with gas separator which discharges retained water - Google Patents

Fuel cell with gas separator which discharges retained water Download PDF

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Publication number
CA2540773A1
CA2540773A1 CA002540773A CA2540773A CA2540773A1 CA 2540773 A1 CA2540773 A1 CA 2540773A1 CA 002540773 A CA002540773 A CA 002540773A CA 2540773 A CA2540773 A CA 2540773A CA 2540773 A1 CA2540773 A1 CA 2540773A1
Authority
CA
Canada
Prior art keywords
reactant gas
flow field
gas flow
fuel cell
electrode assembly
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002540773A
Other languages
French (fr)
Other versions
CA2540773C (en
Inventor
Hiromichi Yoshida
Shigeru Inai
Minoru Koshinuma
Ryo Jinba
Seiji Sugiura
Naoki Mitsuta
Katsumi Hayashi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honda Motor Co Ltd
Original Assignee
Honda Motor Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2005089588A external-priority patent/JP4966507B2/en
Application filed by Honda Motor Co Ltd filed Critical Honda Motor Co Ltd
Publication of CA2540773A1 publication Critical patent/CA2540773A1/en
Application granted granted Critical
Publication of CA2540773C publication Critical patent/CA2540773C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0258Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0258Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
    • H01M8/0263Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant having meandering or serpentine paths
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0258Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
    • H01M8/0265Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant the reactant or coolant channels having varying cross sections
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H01M8/04228Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells during shut-down
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/241Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2457Grouping of fuel cells, e.g. stacking of fuel cells with both reactants being gaseous or vaporised
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • H01M8/2483Details of groupings of fuel cells characterised by internal manifolds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0271Sealing or supporting means around electrodes, matrices or membranes
    • H01M8/0286Processes for forming seals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

An oxygen-containing gas flow field is formed on a surface of a first metal separator. The oxygen-containing gas flow field is connected between an oxygen-containing gas supply passage and an oxygen-containing gas discharge passage. The oxygen-containing gas flow field comprises oxygen-containing gas flow grooves, and ends of the oxygen-containing gas flow grooves are extended outwardly beyond ends of electrode catalyst layer of a membrane electrode assembly, and connected to an inlet buffer and an outlet buffer. When the purging process is performed at the time of stopping operation of the fuel cell, the purging air supplied to the oxygen-containing gas flow field discharges water retained in the electrode catalyst layers from the ends to the outlet buffer.

Claims (16)

1. A fuel cell formed by stacking an electrolyte electrode assembly and separators horizontally, said electrolyte electrode assembly including a pair of electrodes and an electrolyte interposed between said electrodes, wherein a reactant gas flow field is formed between said electrolyte electrode assembly and one of separators sandwiching said electrolyte electrode assembly for supplying a reactant gas along a surface of said electrode, and a reactant gas passage connected to an inlet or an outlet of said reactant gas flow field extends through said fuel cell in a stacking direction;
said separator has a buffer between said reactant gas flow field and said reactant gas passage; and an end of said reactant gas flow field near said reactant gas passage is oriented in a substantially horizontal direction, extended outwardly beyond an end of an electrode catalyst layer of said electrolyte electrode assembly, and connected to said buffer.
2. A fuel cell according to claim 1, wherein said electrode includes said electrode catalyst layer and a gas diffusion layer; and said gas diffusion layer is extended outwardly beyond the end of said electrode catalyst layer, and covers said buffer.
3. A fuel cell according to claim 1, wherein at least at the outlet of said reactant gas flow field, the end of said reactant gas flow field is inclined downwardly from the horizontal direction toward said buffer.
4. A fuel cell according to claim 1, wherein the distance between the end of said reactant gas flow field and bosses of said buffer is equal to the width of grooves in said reactant gas flow field.
5. A fuel cell according to claim 1, wherein ends of a plurality of grooves of said reactant gas flow field are merged between said electrode catalyst layer and said buffer.
6. A fuel cell according to clam 1, wherein at the end of said reactant gas flow field, grooves of said reactant gas flow field are tapered to decrease the size of the openings of the grooves in cross section toward the reactant gas passage.
7. A fuel cell according to claim 1, wherein the lowermost position of said buffer is under the lowermost position of the end of said reactant gas flow field.
8. A fuel cell according to claim 1, wherein the height of the bottom surface of said buffer is the same as the height of the bottom surface of said reactant gas passage.
9. A fuel cell according to claim 1, wherein said separator has a hydrophilic portion between the end of said reactant gas flow field and said reactant gas passage.
10. A fuel cell formed by stacking an electrolyte electrode assembly and separators horizontally, said electrolyte electrode assembly including a pair of electrodes and an electrolyte interposed between said electrodes, wherein a reactant gas flow field is formed between said electrolyte electrode assembly and one of separators sandwiching said electrolyte electrode assembly for supplying a reactant gas along a surface of said electrode, and a reactant gas passage connected to an inlet or an outlet of said reactant gas flow field extends through said fuel cell in a stacking direction;
said separator has a plurality of holes between said reactant gas flow field and said reactant gas passage; and an end of said reactant gas flow field near said reactant gas passage is oriented in a substantially horizontal direction, extended outwardly beyond an end of an electrode catalyst layer of said electrolyte electrode assembly, and connected to said holes.
11. A fuel cell according to claim 10, wherein said ends are merged with each other in a direction toward said reactant gas passage.
12. A fuel cell according to claim 10, wherein grooves at said ends are tapered to decrease the size of the openings of the grooves in cross section toward the reactant gas passage.
13. A fuel cell according to claim 10, wherein a hydrophilic portion is provided between said reactant gas flow field and said holes.
14. A fuel cell formed by stacking an electrolyte electrode assembly and separators horizontally, said electrolyte electrode assembly including a pair of electrodes and an electrolyte interposed between said electrodes, wherein a reactant gas flow field is formed between said electrolyte electrode assembly and one of separators sandwiching said electrolyte electrode assembly for supplying a reactant gas along a surface of said electrode, and a reactant gas passage connected to an inlet or an outlet of said reactant gas flow field extends through said fuel cell in a stacking direction;
an end of said reactant gas flow field near said reactant gas passage is extended outwardly beyond an end of an electrode catalyst layer of said electrolyte electrode assembly; and a reinforcement impregnation portion is provided at an end of said electrolyte electrode assembly extended from the end of said electrode catalyst layer to said reactant gas passage.
15. A fuel cell according to claim 14, wherein ends of said electrolyte electrode assembly protrude outwardly from four corners of said electrolyte electrode assembly; and at each of the ends of said electrolyte electrode assembly, said reinforcement impregnation portion is provided in a gas diffusion layer of one of said electrodes.
16. A fuel cell according to claim 15, wherein, in said electrolyte electrode assembly, the size of the gas diffusion layer of one of said electrodes is larger than the size of the gas diffusion layer of the other of said electrodes; and said reinforcement impregnation portion is provided in the gas diffusion layer having the larger size.
CA2540773A 2005-03-25 2006-03-22 Fuel cell with gas separator which discharges retained water Expired - Fee Related CA2540773C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2005089588A JP4966507B2 (en) 2004-08-26 2005-03-25 Fuel cell
JP2005-89588 2005-03-25

Publications (2)

Publication Number Publication Date
CA2540773A1 true CA2540773A1 (en) 2006-09-25
CA2540773C CA2540773C (en) 2011-10-18

Family

ID=37035590

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2540773A Expired - Fee Related CA2540773C (en) 2005-03-25 2006-03-22 Fuel cell with gas separator which discharges retained water

Country Status (2)

Country Link
US (1) US7901826B2 (en)
CA (1) CA2540773C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7824817B2 (en) 2006-11-09 2010-11-02 Honda Motor Co., Ltd. Fuel cell

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8475972B2 (en) * 2006-05-01 2013-07-02 Honda Motor Co., Ltd. Fuel cell
JP5130688B2 (en) * 2006-09-29 2013-01-30 株式会社日立製作所 Fuel cell separator
US8211585B2 (en) * 2008-04-08 2012-07-03 GM Global Technology Operations LLC Seal for PEM fuel cell plate
JP5334469B2 (en) * 2008-06-27 2013-11-06 本田技研工業株式会社 Fuel cell stack
JP5208059B2 (en) * 2009-06-25 2013-06-12 本田技研工業株式会社 Fuel cell
JP2013528908A (en) * 2010-05-11 2013-07-11 ユーティーシー パワー コーポレイション Improved stampable flow field to improve flow distribution in PEM fuel cell channels
JP5777892B2 (en) * 2011-01-12 2015-09-09 本田技研工業株式会社 Fuel cell
JP5915613B2 (en) 2013-10-02 2016-05-11 トヨタ自動車株式会社 Separator and fuel cell
JP6274197B2 (en) * 2015-12-21 2018-02-07 トヨタ自動車株式会社 Fuel cell and fuel cell system
JP6848580B2 (en) * 2017-03-24 2021-03-24 トヨタ自動車株式会社 Fuel cell stack
CN107834086A (en) * 2017-10-30 2018-03-23 黑泰(上海)材料科技有限公司 Fuel battery double plates
DE102018200673B4 (en) * 2018-01-17 2021-05-12 Audi Ag Bipolar plate, fuel cell and a motor vehicle

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FR2564251B1 (en) * 1984-05-11 1986-09-12 Alsthom Atlantique IMPROVEMENTS TO FUEL CELL STRUCTURES
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JP3632468B2 (en) * 1998-04-22 2005-03-23 トヨタ自動車株式会社 Gas separator for fuel cell and fuel cell using the gas separator for fuel cell
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7824817B2 (en) 2006-11-09 2010-11-02 Honda Motor Co., Ltd. Fuel cell

Also Published As

Publication number Publication date
US7901826B2 (en) 2011-03-08
US20060216572A1 (en) 2006-09-28
CA2540773C (en) 2011-10-18

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Effective date: 20200831