CA2540000A1 - Low carbon alloy steel tube having ultra high strength and excellent toughness at low temperature and method of manufacturing the same - Google Patents
Low carbon alloy steel tube having ultra high strength and excellent toughness at low temperature and method of manufacturing the same Download PDFInfo
- Publication number
- CA2540000A1 CA2540000A1 CA002540000A CA2540000A CA2540000A1 CA 2540000 A1 CA2540000 A1 CA 2540000A1 CA 002540000 A CA002540000 A CA 002540000A CA 2540000 A CA2540000 A CA 2540000A CA 2540000 A1 CA2540000 A1 CA 2540000A1
- Authority
- CA
- Canada
- Prior art keywords
- steel tube
- low carbon
- tubing
- carbon alloy
- alloy steel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract 69
- 239000010959 steel Substances 0.000 title claims abstract 69
- 229910001339 C alloy Inorganic materials 0.000 title claims abstract 24
- 238000004519 manufacturing process Methods 0.000 title claims abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract 19
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract 18
- 229910052799 carbon Inorganic materials 0.000 claims abstract 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract 13
- 229910052804 chromium Inorganic materials 0.000 claims abstract 10
- 239000011651 chromium Substances 0.000 claims abstract 10
- 229910052802 copper Inorganic materials 0.000 claims abstract 10
- 239000010949 copper Substances 0.000 claims abstract 10
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract 10
- 229910052759 nickel Inorganic materials 0.000 claims abstract 10
- 229910052720 vanadium Inorganic materials 0.000 claims abstract 10
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract 9
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract 9
- 229910052782 aluminium Inorganic materials 0.000 claims abstract 9
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims abstract 9
- 239000012535 impurity Substances 0.000 claims abstract 9
- 229910052742 iron Inorganic materials 0.000 claims abstract 9
- 239000011733 molybdenum Substances 0.000 claims abstract 9
- 229910052758 niobium Inorganic materials 0.000 claims abstract 9
- 239000010955 niobium Substances 0.000 claims abstract 9
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract 9
- 229910052710 silicon Inorganic materials 0.000 claims abstract 9
- 239000010703 silicon Substances 0.000 claims abstract 9
- 229910052717 sulfur Inorganic materials 0.000 claims abstract 9
- 239000011593 sulfur Substances 0.000 claims abstract 9
- 239000010936 titanium Substances 0.000 claims abstract 9
- 229910052719 titanium Inorganic materials 0.000 claims abstract 9
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract 9
- 229910052748 manganese Inorganic materials 0.000 claims abstract 6
- 239000011572 manganese Substances 0.000 claims abstract 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract 5
- 238000000034 method Methods 0.000 claims 21
- 238000010438 heat treatment Methods 0.000 claims 8
- 238000010791 quenching Methods 0.000 claims 7
- 230000000171 quenching effect Effects 0.000 claims 7
- 239000007789 gas Substances 0.000 claims 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 4
- 238000005496 tempering Methods 0.000 claims 4
- 230000007704 transition Effects 0.000 claims 4
- 238000010622 cold drawing Methods 0.000 claims 2
- 238000001816 cooling Methods 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 239000012530 fluid Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/20—Ferrous alloys, e.g. steel alloys containing chromium with copper
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/10—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of tubular bodies
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Articles (AREA)
Abstract
A low carbon alloy steel tube and a method of manufacturing the same, in which the steel tube consists essentially of, by weight: about 0.06% to about 0.18%
carbon; about 0.5% to about 1.5% manganese; about 0.1% to about 0.5% silicon;
up to about 0.015% sulfur; up to about 0.025% phosphorous; up to about 0.50%
nickel; about 0.1% to about 1.0% chromium; about 0.1% to about 1.0%
molybdenum; about 0.01% to about 0.10% vanadium; about 0.01% to about 0.10%
titanium; about 0.05% to about 0.35% copper; about 0.010% to about 0.050%
aluminum; up to about 0.05% niobium; up to about 0.15% residual elements; and the balance iron and incidental impurities. The steel has a tensile strength of at least about 145 ksi and exhibits ductile behavior at temperatures as low as -60 ~C.
carbon; about 0.5% to about 1.5% manganese; about 0.1% to about 0.5% silicon;
up to about 0.015% sulfur; up to about 0.025% phosphorous; up to about 0.50%
nickel; about 0.1% to about 1.0% chromium; about 0.1% to about 1.0%
molybdenum; about 0.01% to about 0.10% vanadium; about 0.01% to about 0.10%
titanium; about 0.05% to about 0.35% copper; about 0.010% to about 0.050%
aluminum; up to about 0.05% niobium; up to about 0.15% residual elements; and the balance iron and incidental impurities. The steel has a tensile strength of at least about 145 ksi and exhibits ductile behavior at temperatures as low as -60 ~C.
Claims (39)
1. A low carbon alloy steel tube consisting essentially of, by weight: about 0.06% to about 0.18% carbon; about 0.5% to about 1.5% manganese; about 0.1% to about 0.5%
silicon; up to about 0.015% sulfur; up to about 0.025% phosphorous; up to about 0.50%
nickel; about 0.1% to about 1.0% chromium; about 0.1% to about 1.0%
molybdenum; about 0.01% to about 0.10% vanadium; about 0.01% to about 0.10% titanium; about 0.05% to about 0.35% copper; about 0.010% to about 0.050% aluminum; up to about 0.05%
niobium;
up to about 0.15% residual elements; and the balance iron and incidental impurities, wherein the steel tube has a tensile strength of at least about 145 ksi and has a ductile-to-brittle transition temperature below -60 °.
silicon; up to about 0.015% sulfur; up to about 0.025% phosphorous; up to about 0.50%
nickel; about 0.1% to about 1.0% chromium; about 0.1% to about 1.0%
molybdenum; about 0.01% to about 0.10% vanadium; about 0.01% to about 0.10% titanium; about 0.05% to about 0.35% copper; about 0.010% to about 0.050% aluminum; up to about 0.05%
niobium;
up to about 0.15% residual elements; and the balance iron and incidental impurities, wherein the steel tube has a tensile strength of at least about 145 ksi and has a ductile-to-brittle transition temperature below -60 °.
2. The low carbon alloy steel tube of claim 1, wherein the steel tube consists essentially of, by weight: about 0.07% to about 0.12% carbon; about 1.00% to about 1.40%
manganese;
about 0.15% to about 0.35% silicon; up to about 0.010% sulfur; up to about 0.015%
phosphorous; up to about 0.20% nickel; about 0.55% to about 0.80% chromium;
about 0.30% to about 0.50% molybdenum; about 0.01% to about 0.07% vanadium; about 0.01% to about 0.05% titanium; about 0.15% to about 0.30% copper; about 0.010% to about 0.050%
aluminum; up to about 0.05% niobium; up to about 0.15% residual elements; and the balance iron and incidental impurities.
manganese;
about 0.15% to about 0.35% silicon; up to about 0.010% sulfur; up to about 0.015%
phosphorous; up to about 0.20% nickel; about 0.55% to about 0.80% chromium;
about 0.30% to about 0.50% molybdenum; about 0.01% to about 0.07% vanadium; about 0.01% to about 0.05% titanium; about 0.15% to about 0.30% copper; about 0.010% to about 0.050%
aluminum; up to about 0.05% niobium; up to about 0.15% residual elements; and the balance iron and incidental impurities.
3. The low carbon alloy steel tube of claim 1, wherein the steel tube consists essentially of, by weight: about 0.08% to about 0.11% carbon; about 1.03% to about 1.18%
manganese;
about 0.15% to about 0.35% silicon; up to about 0.003% sulfur; up to about 0.012%
phosphorous; up to about 0.10% nickel; about 0.63% to about 0.73% chromium;
about 0.40% to about 0.45% molybdenum; about 0.03% to about 0.05% vanadium; about 0.025%
to about 0.035% titanium; about 0.15% to about 0.30% copper; about 0.010% to about 0.050% aluminum; up to about 0.05% niobium; up to about 0.15% residual elements; and the balance iron and incidental impurities.
manganese;
about 0.15% to about 0.35% silicon; up to about 0.003% sulfur; up to about 0.012%
phosphorous; up to about 0.10% nickel; about 0.63% to about 0.73% chromium;
about 0.40% to about 0.45% molybdenum; about 0.03% to about 0.05% vanadium; about 0.025%
to about 0.035% titanium; about 0.15% to about 0.30% copper; about 0.010% to about 0.050% aluminum; up to about 0.05% niobium; up to about 0.15% residual elements; and the balance iron and incidental impurities.
4. The low carbon alloy steel tube of claim 1, wherein the steel tube has a yield strength of at least about 125 ksi.
5. The low carbon alloy steel tube of claim 1, wherein the steel tube has a yield strength of at least about 135 ksi
6. The low carbon alloy steel tube of claim 1, wherein the steel tube has an elongation at break of at least about 9%.
7. The low carbon alloy steel tube of claim 1, wherein the steel tube has a hardness of no more than about 40 HRC.
8. The low carbon alloy steel tube of claim 1, wherein the steel tube has a hardness of no more than about 37 HRC.
9. The low carbon alloy steel tube of claim 1, wherein the steel tube has a carbon equivalent of less than about 0.63%, the carbon equivalent being determined according to the formula:
Ceq = %C + %Mn/6 + (%Cr + %Mo + %V)/5 + (%Ni + %Cu)/15.
Ceq = %C + %Mn/6 + (%Cr + %Mo + %V)/5 + (%Ni + %Cu)/15.
10. The low carbon alloy steel tube of claim 9, wherein the steel tube has a carbon equivalent of less than about 0.60%.
11. The low carbon alloy steel tube of claim 9, wherein the steel tube has a carbon equivalent of less than about 0.56%.
12. The low carbon alloy steel tube of claim 1, wherein the steel tube has a maximum microinclusion content of 2 or less --thin series--, and level 1 or less --heavy series--, measured in accordance with ASTM E45 Standard - Worst Field Method (Method A).
13 13. The low carbon alloy steel tube of claim 1, wherein the steel tube has a maximum microinclusion content measured in accordance with ASTM E45 Standard - Worst Field Method (Method A), as follows:
Inclusion Thin Heavy Type A 0.5 0 B 1.5 1.0 D 1.5 0.5
Inclusion Thin Heavy Type A 0.5 0 B 1.5 1.0 D 1.5 0.5
14. The low carbon alloy steel tube of claim 13, wherein oversize inclusion content with 30 µm or less in size is obtained.
15. The low carbon alloy steel tube of claim 14, wherein the total oxygen content is limited to 20 ppm.
16. The low carbon alloy steel tube of claim 1, wherein the tube has a seamless configuration.
17. A stored gas inflator pressure vessel comprising the low carbon alloy steel tube of claim 1.
18. An automotive airbag inflator comprising the low carbon alloy steel tube of claim 1.
19. A low carbon alloy steel tube consisting essentially of, by weight: about 0.08% to about 0.11% carbon; about 1.03% to about 1.18% manganese; about 0.15% to about 0.35%
silicon; up to about 0.003% sulfur; up to about 0.012% phosphorous; up to about 0.10%
nickel; about 0.63% to about 0.73% chromium; about 0.40% to about 0.45%
molybdenum;
about 0.03% to about 0.05% vanadium; about 0.025% to about 0.035% titanium;
about 0.15% to about 0.30% copper; about 0.010% to about 0.050% aluminum; up to about 0.05%
niobium; up to about 0.15% residual elements; and the balance iron and incidental impurities, wherein the steel tube has a yield strength of at least about 135 ksi, a tensile strength of at least about 145 ksi, an elongation at break of of at least about 9%, a hardness of no more than about 37 HRC, and has a ductile-to-brittle transition temperature below -60°C.
silicon; up to about 0.003% sulfur; up to about 0.012% phosphorous; up to about 0.10%
nickel; about 0.63% to about 0.73% chromium; about 0.40% to about 0.45%
molybdenum;
about 0.03% to about 0.05% vanadium; about 0.025% to about 0.035% titanium;
about 0.15% to about 0.30% copper; about 0.010% to about 0.050% aluminum; up to about 0.05%
niobium; up to about 0.15% residual elements; and the balance iron and incidental impurities, wherein the steel tube has a yield strength of at least about 135 ksi, a tensile strength of at least about 145 ksi, an elongation at break of of at least about 9%, a hardness of no more than about 37 HRC, and has a ductile-to-brittle transition temperature below -60°C.
20. The low carbon alloy steel tube of claim 19, wherein the tube has a seamless configuration.
21. A stored gas inflator pressure vessel comprising the low carbon alloy steel tube of claim 19.
22. An automotive airbag inflator comprising the low carbon alloy steel tube of claim 19.
23. A method of manufacturing a length of steel tubing for a stored gas inflator pressure vessel, comprising the following steps:
producing a length of tubing from a steel material consisting essentially of, by weight:
about 0.06% to about 0.18% carbon, about 0.5% to about 1.5% manganese, about 0.1% to about 0.5% silicon, up to about 0.015% sulfur, up to about 0.025% phosphorous, up to about 0.50% nickel, about 0.1% to about 1.0% chromium, about 0.1% to about 1.0%
molybdenum, about 0.01% to about 0.10% vanadium, about 0.01% to about 0.10% titanium, about 0.05%
to about 0.35% copper, about 0.010% to about 0.050% aluminum, up to about 0.05%
niobium, up to about 0.15% residual elements, and the balance iron and incidental impurities;
subjecting the steel tubing to a cold-drawing process to obtain desired dimensions;
austenizing by heating the cold-drawn steel tubing in an induction-type austenizing furnace to a temperature of at least Ac3, at a heating rate of at least about 100°C per second;
after the heating step, quenching the steel tubing in a quenching fluid until the tubing reaches approximately ambient temperature, at a cooling rate of at least about 100°C per second; and after the quenching step, tempering the steel tubing for about 2-30 minutes at a temperature below Acl.
producing a length of tubing from a steel material consisting essentially of, by weight:
about 0.06% to about 0.18% carbon, about 0.5% to about 1.5% manganese, about 0.1% to about 0.5% silicon, up to about 0.015% sulfur, up to about 0.025% phosphorous, up to about 0.50% nickel, about 0.1% to about 1.0% chromium, about 0.1% to about 1.0%
molybdenum, about 0.01% to about 0.10% vanadium, about 0.01% to about 0.10% titanium, about 0.05%
to about 0.35% copper, about 0.010% to about 0.050% aluminum, up to about 0.05%
niobium, up to about 0.15% residual elements, and the balance iron and incidental impurities;
subjecting the steel tubing to a cold-drawing process to obtain desired dimensions;
austenizing by heating the cold-drawn steel tubing in an induction-type austenizing furnace to a temperature of at least Ac3, at a heating rate of at least about 100°C per second;
after the heating step, quenching the steel tubing in a quenching fluid until the tubing reaches approximately ambient temperature, at a cooling rate of at least about 100°C per second; and after the quenching step, tempering the steel tubing for about 2-30 minutes at a temperature below Acl.
24. The method of claim 23, wherein the steel tubing produced consists essentially of, by weight: about 0.07% to about 0.12% carbon, about 1.00% to about 1.40%
manganese, about 0.15% to about 0.35% silicon, up to about 0.010% sulfur, up to about 0.015%
phosphorous, up to about 0.20% nickel, about 0.55% to about 0.80% chromium, about 0.30% to about 0.50% molybdenum, about 0.01% to about 0.07% vanadium, about 0.01% to about 0.05%
titanium, about 0.15% to about 0.30% copper, about 0.010% to about 0.050%
aluminum, up to about 0.05% niobium, up to about 0.15% residual elements, and the balance iron and incidental impurities.
manganese, about 0.15% to about 0.35% silicon, up to about 0.010% sulfur, up to about 0.015%
phosphorous, up to about 0.20% nickel, about 0.55% to about 0.80% chromium, about 0.30% to about 0.50% molybdenum, about 0.01% to about 0.07% vanadium, about 0.01% to about 0.05%
titanium, about 0.15% to about 0.30% copper, about 0.010% to about 0.050%
aluminum, up to about 0.05% niobium, up to about 0.15% residual elements, and the balance iron and incidental impurities.
25. The method of claim 23, wherein the steel tubing produced consists essentially of, by weight: about 0.08% to about 0.11% carbon, about 1.03% to about 1.18%
manganese, about 0.15% to about 0.35% silicon, up to about 0.003% sulfur, up to about 0.012%
phosphorous, up to about 0.10% nickel, about 0.63% to about 0.73% chromium, about 0.40%
to.about 0.45% molybdenum, about 0.03% to about 0.05% vanadium, about 0.025% to about 0.035%
titanium, about 0.15% to about 0.30% copper, about 0.010% to about 0.050%
aluminum, up to about 0.05% niobium, up to about 0.15% residual elements, and the balance iron and incidental impurities.
manganese, about 0.15% to about 0.35% silicon, up to about 0.003% sulfur, up to about 0.012%
phosphorous, up to about 0.10% nickel, about 0.63% to about 0.73% chromium, about 0.40%
to.about 0.45% molybdenum, about 0.03% to about 0.05% vanadium, about 0.025% to about 0.035%
titanium, about 0.15% to about 0.30% copper, about 0.010% to about 0.050%
aluminum, up to about 0.05% niobium, up to about 0.15% residual elements, and the balance iron and incidental impurities.
26. The method of claim 23, wherein the finished steel tubing has a yield strength of at least about 125 ksi.
27. The method of claim 23, wherein the finished steel tubing has a yield strength of at least about 135 ksi.
28. The method of claim 23, wherein the finished steel tubing has a tensile strength of at least about 145 ksi.
29. The method of claim 23, wherein the finished steel tubing has an elongation at break of at least about 9%.
30. The method of claim 23, wherein the finished steel tubing has a hardness of no more than about 40 HRC.
31. The method of claim 23, wherein the finished steel tubing has a hardness of no more than about 37 HRC.
32. The method of claim 23, wherein the finished steel tubing has a ductile-to-brittle transition temperature below -60 °C.
33. The method of claim 23, wherein in the austenizing heating step, the steel tubing is heated to a temperature between about 920-1050 °C.
34. The method of claim 33, wherein in the austenizing heating step, the steel tubing is heated at a rate of at least about 200 °C per second.
35. The method of claim 23, wherein in the quenching step, the steel tubing is cooled at a rate of at least about 200 °C per second.
36. The method of claim 23, wherein in the tempering step, the steel tubing is tempered at a temperature between about 400-600 °C.
37. The method of claim 36, wherein in the tempering step, the steel tubing is tempered for about 4-20 minutes.
38. The method of claim 23, further comprising a finishing step wherein the tempered steel tubing is pickled, phosphated, and oiled.
39. A method of manufacturing a length of steel tubing for a stored gas inflator pressure vessel, comprising the following steps:
producing a length of tubing from a steel material consisting essentially of, by weight:
about 0.08% to about 0.11% carbon, about 1.03% to about 1.18% manganese, about 0.15%
to about 0.35% silicon, up to about 0.003% sulfur, up to about 0.012%
phosphorous, up to about 0.10% nickel, about 0.63% to about 0.73% chromium, about 0.40% to about 0.45%
molybdenum, about 0.03% to about 0.05% vanadium, about 0.025% to about 0.035%
titanium, about 0.15% to about 0.30% copper, about 0.010% to about 0.050%
aluminum, up to about 0.05% niobium, up to about 0.15% residual elements, and the balance iron and incidental impurities;
subjecting the steel tubing to a cold-drawing process to obtain desired dimensions;
austenizing by heating the cold-drawn steel tubing in an induction-type austenizing furnace to a temperature between about 920-1050 °C, at a heating rate of at least about 200 °C per second;
after the heating step, quenching the steel tubing in a water-based quenching solution until the tubing reaches approximately ambient temperature, at a cooling rate of at least about 200 °C per second; and, after the quenching step, tempering the steel tubing for about 4-20 minutes at a temperature between about 450-550 °C, a finishing step wherein the tempered steel tubing is pickled, phosphated, and oiled, wherein the finished steel tubing has a yield strength of at least about 135 ksi, a tensile strength of at least about 145 ksi, an elongation at break of at least about 9%, a hardness of no more than about 37 HRC, a ductile-to-brittle transition temperature below -60 °C and a good surface appearance.
producing a length of tubing from a steel material consisting essentially of, by weight:
about 0.08% to about 0.11% carbon, about 1.03% to about 1.18% manganese, about 0.15%
to about 0.35% silicon, up to about 0.003% sulfur, up to about 0.012%
phosphorous, up to about 0.10% nickel, about 0.63% to about 0.73% chromium, about 0.40% to about 0.45%
molybdenum, about 0.03% to about 0.05% vanadium, about 0.025% to about 0.035%
titanium, about 0.15% to about 0.30% copper, about 0.010% to about 0.050%
aluminum, up to about 0.05% niobium, up to about 0.15% residual elements, and the balance iron and incidental impurities;
subjecting the steel tubing to a cold-drawing process to obtain desired dimensions;
austenizing by heating the cold-drawn steel tubing in an induction-type austenizing furnace to a temperature between about 920-1050 °C, at a heating rate of at least about 200 °C per second;
after the heating step, quenching the steel tubing in a water-based quenching solution until the tubing reaches approximately ambient temperature, at a cooling rate of at least about 200 °C per second; and, after the quenching step, tempering the steel tubing for about 4-20 minutes at a temperature between about 450-550 °C, a finishing step wherein the tempered steel tubing is pickled, phosphated, and oiled, wherein the finished steel tubing has a yield strength of at least about 135 ksi, a tensile strength of at least about 145 ksi, an elongation at break of at least about 9%, a hardness of no more than about 37 HRC, a ductile-to-brittle transition temperature below -60 °C and a good surface appearance.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US50980603P | 2003-10-10 | 2003-10-10 | |
US60/509,806 | 2003-10-10 | ||
US10/957,605 | 2004-10-05 | ||
US10/957,605 US20050076975A1 (en) | 2003-10-10 | 2004-10-05 | Low carbon alloy steel tube having ultra high strength and excellent toughness at low temperature and method of manufacturing the same |
PCT/IB2004/003311 WO2005035800A1 (en) | 2003-10-10 | 2004-10-11 | Low carbon alloy steel tube having ultra high strength and excellent toughnes at low temperature and method of manufacturing the same |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2540000A1 true CA2540000A1 (en) | 2005-04-21 |
CA2540000C CA2540000C (en) | 2012-05-15 |
Family
ID=34426131
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2540000A Expired - Lifetime CA2540000C (en) | 2003-10-10 | 2004-10-11 | Low carbon alloy steel tube having ultra high strength and excellent toughness at low temperature and method of manufacturing the same |
Country Status (8)
Country | Link |
---|---|
US (1) | US20050076975A1 (en) |
EP (1) | EP1678335B1 (en) |
JP (1) | JP2007508452A (en) |
KR (1) | KR101178954B1 (en) |
AT (1) | ATE541060T1 (en) |
BR (1) | BRPI0415340B1 (en) |
CA (1) | CA2540000C (en) |
WO (1) | WO2005035800A1 (en) |
Families Citing this family (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101087562B1 (en) * | 2003-03-31 | 2011-11-28 | 히노 지도샤 가부시키가이샤 | Piston for internal combustion engine and producing method thereof |
AU2003225402B2 (en) | 2003-04-25 | 2010-02-25 | Dalmine S.P.A. | Seamless steel tube which is intended to be used as a guide pipe and production method thereof |
US20050000601A1 (en) * | 2003-05-21 | 2005-01-06 | Yuji Arai | Steel pipe for an airbag system and a method for its manufacture |
US7922065B2 (en) | 2004-08-02 | 2011-04-12 | Ati Properties, Inc. | Corrosion resistant fluid conducting parts, methods of making corrosion resistant fluid conducting parts and equipment and parts replacement methods utilizing corrosion resistant fluid conducting parts |
US20060169368A1 (en) * | 2004-10-05 | 2006-08-03 | Tenaris Conncections A.G. (A Liechtenstein Corporation) | Low carbon alloy steel tube having ultra high strength and excellent toughness at low temperature and method of manufacturing the same |
CN100434561C (en) * | 2005-07-26 | 2008-11-19 | 武汉钢铁(集团)公司 | Steel in use for soldering pressure pipe in hydraulic power station under large line energy, and manufacturing method |
MXPA05008339A (en) * | 2005-08-04 | 2007-02-05 | Tenaris Connections Ag | High-strength steel for seamless, weldable steel pipes. |
DE102005046459B4 (en) * | 2005-09-21 | 2013-11-28 | MHP Mannesmann Präzisrohr GmbH | Process for the production of cold-finished precision steel tubes |
CN101374966B (en) * | 2006-02-09 | 2011-01-19 | 住友金属工业株式会社 | Process for manufacturing an airbag inflator bottle member |
WO2007140406A2 (en) * | 2006-05-30 | 2007-12-06 | Advanced Technology Materials, Inc. | Storage and transport container for materials susceptible to physical state change under variable ambient temperature conditions |
US8926771B2 (en) * | 2006-06-29 | 2015-01-06 | Tenaris Connections Limited | Seamless precision steel tubes with improved isotropic toughness at low temperature for hydraulic cylinders and process for obtaining the same |
US7862667B2 (en) | 2007-07-06 | 2011-01-04 | Tenaris Connections Limited | Steels for sour service environments |
JP5094272B2 (en) * | 2007-08-21 | 2012-12-12 | 株式会社日本製鋼所 | Low alloy high strength steel with excellent high pressure hydrogen environment embrittlement resistance and method for producing the same |
DE102007039591A1 (en) | 2007-08-22 | 2009-02-26 | Giesecke & Devrient Gmbh | grid image |
MX2010005532A (en) * | 2007-11-19 | 2011-02-23 | Tenaris Connections Ltd | High strength bainitic steel for octg applications. |
BRPI0904814B1 (en) * | 2008-11-25 | 2020-11-10 | Maverick Tube, Llc | method of manufacturing a steel product |
CN104694835A (en) * | 2008-11-26 | 2015-06-10 | 新日铁住金株式会社 | Seamless steel pipe and method for manufacturing same |
BRPI1016049A2 (en) * | 2009-04-24 | 2016-05-10 | Arihant Domestic Appliances Ltd | "low carbon welded pipe, and system and manufacturing process thereof" |
EP2325435B2 (en) | 2009-11-24 | 2020-09-30 | Tenaris Connections B.V. | Threaded joint sealed to [ultra high] internal and external pressures |
US8910409B1 (en) * | 2010-02-09 | 2014-12-16 | Ati Properties, Inc. | System and method of producing autofrettage in tubular components using a flowforming process |
MX2012005710A (en) * | 2010-06-03 | 2012-06-12 | Sumitomo Metal Ind | Steel pipe for air bag and process for producing same. |
JP5234226B2 (en) * | 2010-06-03 | 2013-07-10 | 新日鐵住金株式会社 | Manufacturing method of steel pipe for airbag |
US9163296B2 (en) | 2011-01-25 | 2015-10-20 | Tenaris Coiled Tubes, Llc | Coiled tube with varying mechanical properties for superior performance and methods to produce the same by a continuous heat treatment |
IT1403688B1 (en) | 2011-02-07 | 2013-10-31 | Dalmine Spa | STEEL TUBES WITH THICK WALLS WITH EXCELLENT LOW TEMPERATURE HARDNESS AND RESISTANCE TO CORROSION UNDER TENSIONING FROM SULFUR. |
IT1403689B1 (en) | 2011-02-07 | 2013-10-31 | Dalmine Spa | HIGH-RESISTANCE STEEL TUBES WITH EXCELLENT LOW TEMPERATURE HARDNESS AND RESISTANCE TO CORROSION UNDER VOLTAGE SENSORS. |
US8414715B2 (en) | 2011-02-18 | 2013-04-09 | Siderca S.A.I.C. | Method of making ultra high strength steel having good toughness |
US8636856B2 (en) | 2011-02-18 | 2014-01-28 | Siderca S.A.I.C. | High strength steel having good toughness |
US8869443B2 (en) | 2011-03-02 | 2014-10-28 | Ati Properties, Inc. | Composite gun barrel with outer sleeve made from shape memory alloy to dampen firing vibrations |
CN102181788A (en) * | 2011-04-18 | 2011-09-14 | 首钢总公司 | Ultra-high strength steel with yield strength level of 1100MPa-1200MPa and production method of steel |
US9340847B2 (en) | 2012-04-10 | 2016-05-17 | Tenaris Connections Limited | Methods of manufacturing steel tubes for drilling rods with improved mechanical properties, and rods made by the same |
CN102605283B (en) * | 2012-04-18 | 2013-12-25 | 江苏省沙钢钢铁研究院有限公司 | Low-cost high-toughness low-temperature pressure vessel steel and manufacturing method thereof |
CN102699031B (en) * | 2012-05-14 | 2014-03-26 | 莱芜钢铁集团有限公司 | 900 MPa grade ultrahigh-toughness low alloy steel and manufacture method thereof |
US10118259B1 (en) | 2012-12-11 | 2018-11-06 | Ati Properties Llc | Corrosion resistant bimetallic tube manufactured by a two-step process |
CA2897451C (en) | 2013-01-11 | 2019-10-01 | Tenaris Connections Limited | Galling resistant drill pipe tool joint and corresponding drill pipe |
US9187811B2 (en) | 2013-03-11 | 2015-11-17 | Tenaris Connections Limited | Low-carbon chromium steel having reduced vanadium and high corrosion resistance, and methods of manufacturing |
US9803256B2 (en) | 2013-03-14 | 2017-10-31 | Tenaris Coiled Tubes, Llc | High performance material for coiled tubing applications and the method of producing the same |
EP2789701A1 (en) | 2013-04-08 | 2014-10-15 | DALMINE S.p.A. | High strength medium wall quenched and tempered seamless steel pipes and related method for manufacturing said steel pipes |
EP2789700A1 (en) | 2013-04-08 | 2014-10-15 | DALMINE S.p.A. | Heavy wall quenched and tempered seamless steel pipes and related method for manufacturing said steel pipes |
CN105452515A (en) | 2013-06-25 | 2016-03-30 | 特纳瑞斯连接有限责任公司 | High-chromium heat-resistant steel |
JP6070617B2 (en) * | 2014-04-03 | 2017-02-01 | Jfeスチール株式会社 | Seamless steel pipe for fuel injection pipes with excellent internal pressure fatigue resistance |
KR101639327B1 (en) * | 2014-12-16 | 2016-07-13 | 주식회사 세아베스틸 | Steel for inflator tube of air bag having good impact value in low temperature |
DE102014018816A1 (en) * | 2014-12-19 | 2016-06-23 | Benteler Steel/Tube Gmbh | Gas pressure vessel and pipe element for an airbag system and method for its production |
US20160305192A1 (en) | 2015-04-14 | 2016-10-20 | Tenaris Connections Limited | Ultra-fine grained steels having corrosion-fatigue resistance |
DE102015111680A1 (en) | 2015-07-17 | 2017-01-19 | Benteler Steel/Tube Gmbh | inflator |
US11124852B2 (en) | 2016-08-12 | 2021-09-21 | Tenaris Coiled Tubes, Llc | Method and system for manufacturing coiled tubing |
US10434554B2 (en) | 2017-01-17 | 2019-10-08 | Forum Us, Inc. | Method of manufacturing a coiled tubing string |
DE102018106546A1 (en) * | 2018-03-20 | 2019-09-26 | Benteler Steel/Tube Gmbh | Pipe element for gas pressure vessel and gas pressure vessel |
CN109355455A (en) * | 2018-09-30 | 2019-02-19 | 舞阳钢铁有限责任公司 | A kind of smelting process of the low Silicon pressure container steel of slab |
CN109609747B (en) * | 2018-12-11 | 2022-01-25 | 信达科创(唐山)石油设备有限公司 | Homogenizing treatment process for coiled tubing |
EP4077483A1 (en) | 2019-12-19 | 2022-10-26 | Wacker Chemie AG | Antifoam compositions comprising branched siloxanes |
JP2023531248A (en) | 2020-06-23 | 2023-07-21 | テナリス・コネクシヨンズ・ベー・ブイ | Method for producing high-strength steel pipe from steel composition and components made therefrom |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3645725A (en) * | 1969-05-02 | 1972-02-29 | Armco Steel Corp | Austenitic steel combining strength and resistance to intergranular corrosion |
JPS60245721A (en) | 1984-05-21 | 1985-12-05 | Sumitomo Metal Ind Ltd | Heat treatment of steel material |
JPS61130462A (en) * | 1984-11-28 | 1986-06-18 | Tech Res & Dev Inst Of Japan Def Agency | High-touchness extra high tension steel having superior stress corrosion cracking resistance as well as yield stress of 110kgf/mm2 and above |
ATE47428T1 (en) * | 1985-06-10 | 1989-11-15 | Hoesch Ag | PROCESS AND USE OF A STEEL FOR THE MANUFACTURE OF STEEL PIPES WITH INCREASED SOUR GAS RESISTANCE. |
JPH01275739A (en) * | 1988-04-28 | 1989-11-06 | Sumitomo Metal Ind Ltd | Low si high strength and heat-resistant steel tube having excellent ductility and toughness |
JPH0772299B2 (en) * | 1990-06-19 | 1995-08-02 | 住友金属工業株式会社 | Manufacturing method of high yield steel plate with low yield ratio |
JPH04268016A (en) * | 1991-02-20 | 1992-09-24 | Kobe Steel Ltd | Production of high tensile strength steel sheet for door guide bar having excellent crushing characteristic |
US5348344A (en) * | 1991-09-18 | 1994-09-20 | Trw Vehicle Safety Systems Inc. | Apparatus for inflating a vehicle occupant restraint using a mixture of gases |
US5454883A (en) * | 1993-02-02 | 1995-10-03 | Nippon Steel Corporation | High toughness low yield ratio, high fatigue strength steel plate and process of producing same |
US5388322A (en) * | 1993-05-28 | 1995-02-14 | Simon; Joseph A. | Method of making a shatterproof air bag inflator pressure vessel |
DE19512725C1 (en) * | 1995-04-05 | 1996-09-12 | Orga Kartensysteme Gmbh | ID card or the like in the form of a chip card |
JP3220975B2 (en) * | 1996-11-12 | 2001-10-22 | 住友金属工業株式会社 | Manufacturing method of steel pipe for high strength and high toughness air bag |
US6056833A (en) * | 1997-07-23 | 2000-05-02 | Usx Corporation | Thermomechanically controlled processed high strength weathering steel with low yield/tensile ratio |
US6159312A (en) * | 1997-12-19 | 2000-12-12 | Exxonmobil Upstream Research Company | Ultra-high strength triple phase steels with excellent cryogenic temperature toughness |
JPH11199929A (en) * | 1998-01-06 | 1999-07-27 | Sumitomo Metal Ind Ltd | Production of seam welded steel pipe for air bag, having high strength and high dimensional precision |
JP3519966B2 (en) * | 1999-01-07 | 2004-04-19 | 新日本製鐵株式会社 | Ultra-high-strength linepipe excellent in low-temperature toughness and its manufacturing method |
US6187117B1 (en) * | 1999-01-20 | 2001-02-13 | Bethlehem Steel Corporation | Method of making an as-rolled multi-purpose weathering steel plate and product therefrom |
US6173495B1 (en) * | 1999-05-12 | 2001-01-16 | Trw Inc. | High strength low carbon air bag quality seamless tubing |
DE10022463B4 (en) * | 1999-05-12 | 2005-07-14 | Trw Inc., Lyndhurst | A method of manufacturing a container of an inflator of a vehicle occupant protection device |
US6386583B1 (en) * | 2000-09-01 | 2002-05-14 | Trw Inc. | Low-carbon high-strength steel |
US20020033591A1 (en) * | 2000-09-01 | 2002-03-21 | Trw Inc. | Method of producing a cold temperature high toughness structural steel tubing |
JP3678147B2 (en) | 2000-12-27 | 2005-08-03 | 住友金属工業株式会社 | Steel tube for high strength and toughness airbag and its manufacturing method |
EP1375683B1 (en) * | 2001-03-29 | 2012-02-08 | Sumitomo Metal Industries, Ltd. | High strength steel tube for air bag and method for production thereof |
JP3858615B2 (en) * | 2001-03-29 | 2006-12-20 | 住友金属工業株式会社 | Method for producing seamless steel pipe for high strength airbag with tensile strength of 900 MPa or more |
JP4197590B2 (en) * | 2001-12-05 | 2008-12-17 | 住友金属工業株式会社 | Steel tube and pressure accumulator for high strength and toughness airbag |
MXPA04010403A (en) * | 2002-06-26 | 2005-02-17 | Jfe Steel Corp | Method for producing seamless steel pipe for inflator of air bag. |
AU2003225402B2 (en) * | 2003-04-25 | 2010-02-25 | Dalmine S.P.A. | Seamless steel tube which is intended to be used as a guide pipe and production method thereof |
US20050000601A1 (en) | 2003-05-21 | 2005-01-06 | Yuji Arai | Steel pipe for an airbag system and a method for its manufacture |
US7278190B2 (en) * | 2003-07-03 | 2007-10-09 | Newfrey Llc | Two component fuel and brake line clip |
US20050087269A1 (en) * | 2003-10-22 | 2005-04-28 | Merwin Matthew J. | Method for producing line pipe |
-
2004
- 2004-10-05 US US10/957,605 patent/US20050076975A1/en not_active Abandoned
- 2004-10-11 BR BRPI0415340-5A patent/BRPI0415340B1/en active IP Right Grant
- 2004-10-11 CA CA2540000A patent/CA2540000C/en not_active Expired - Lifetime
- 2004-10-11 KR KR1020067006791A patent/KR101178954B1/en active IP Right Grant
- 2004-10-11 WO PCT/IB2004/003311 patent/WO2005035800A1/en active Application Filing
- 2004-10-11 EP EP04769605A patent/EP1678335B1/en not_active Expired - Lifetime
- 2004-10-11 AT AT04769605T patent/ATE541060T1/en active
- 2004-10-11 JP JP2006530753A patent/JP2007508452A/en active Pending
Also Published As
Publication number | Publication date |
---|---|
WO2005035800A1 (en) | 2005-04-21 |
CA2540000C (en) | 2012-05-15 |
EP1678335A1 (en) | 2006-07-12 |
BRPI0415340A (en) | 2006-12-05 |
JP2007508452A (en) | 2007-04-05 |
KR101178954B1 (en) | 2012-08-31 |
EP1678335B1 (en) | 2012-01-11 |
ATE541060T1 (en) | 2012-01-15 |
BRPI0415340B1 (en) | 2012-12-11 |
KR20060130551A (en) | 2006-12-19 |
US20050076975A1 (en) | 2005-04-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2540000A1 (en) | Low carbon alloy steel tube having ultra high strength and excellent toughness at low temperature and method of manufacturing the same | |
AU2008221597B8 (en) | Low alloy steel, seamless steel oil country tubular goods, and method for producing seamless steel pipe | |
US9869009B2 (en) | High strength low alloy steel and method of manufacturing | |
CA2849287C (en) | Method for producing high-strength steel material excellent in sulfide stress cracking resistance | |
US8852366B2 (en) | Method for producing steel pipe with excellent expandability | |
CA2885933C (en) | Quench and temper corrosion resistant steel alloy | |
WO2011061812A1 (en) | High-toughness abrasion-resistant steel and manufacturing method therefor | |
WO2010074017A1 (en) | Steel tempering method | |
CN101437973A (en) | Martensitic stainless seamless steel pipe for oil well pipe, and method for producing the same | |
US20090155118A1 (en) | High Strength Steel | |
US20190241989A1 (en) | Martensitic stainless steel seamless pipe for oil country tubular goods, and method for producing same | |
JP5499575B2 (en) | Martensitic stainless steel seamless pipe for oil well pipe and method for producing the same | |
JP6232324B2 (en) | Stabilizer steel and stabilizer with high strength and excellent corrosion resistance, and method for producing the same | |
US8652273B2 (en) | High tensile steel for deep drawing and manufacturing method thereof and high-pressure container produced thereof | |
WO2018011299A1 (en) | Micro alloyed steel and method for producing said steel | |
CA3183576A1 (en) | Method of manufacturing high strength steel tubing from a steel composition and components thereof | |
JP2007513259A (en) | Steel wire for cold heading having excellent low temperature impact characteristics and method for producing the same | |
JP2001158937A (en) | Tool steel for hot working, method for producing same and method for producing tool for hot working | |
RU2719212C1 (en) | High-strength corrosion-resistant seamless pipe from oil-field range and method of its production | |
CN114086083B (en) | 1100 MPa-grade sulfur-resistant high-pressure gas cylinder steel, high-pressure gas cylinder and manufacturing method thereof | |
WO2012172185A1 (en) | Method for manufacturing a medium carbon steel product and a hot rolled medium carbon steel product | |
CN107338396A (en) | High-hardenability gas storage seamless steel pipe and its production method | |
CA2561703A1 (en) | High strength steel | |
JPS61166919A (en) | Manufacture of unrefined warm-forged article having high toughness | |
JP2003342687A (en) | Steel pipe excellent in strength/ductility balance and its production method |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request |