CA2037292A1 - Preparation of finely divided, water-soluble polymers - Google Patents
Preparation of finely divided, water-soluble polymersInfo
- Publication number
- CA2037292A1 CA2037292A1 CA2037292A CA2037292A CA2037292A1 CA 2037292 A1 CA2037292 A1 CA 2037292A1 CA 2037292 A CA2037292 A CA 2037292A CA 2037292 A CA2037292 A CA 2037292A CA 2037292 A1 CA2037292 A1 CA 2037292A1
- Authority
- CA
- Canada
- Prior art keywords
- surfactant
- polymerization
- water
- finely divided
- soluble polymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/10—Aqueous solvent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Finely divided, water-soluble polymers are prepared by polymerization of water-soluble, monoethylenically unsaturated monomers in not less than 20% strength by weight aqueous solution in the presence of a polymerization initiator in a kneader by a process in which from 0.1 to 10% by weight, based on the total monomers, of a surfactant are used in the polymerization, the polymerization initially being carried out to a conversion of the monomers of not less than 60% in the absence of the surfactant or in the presence of not more than 50% of the amount of surfactant, and the remaining amount of surfactant then being added to the reaction mixture and the polymerization completed. The addition of surfactant causes the polymer gel to disintegrate with formation of fine particles.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4007313.0 | 1990-03-08 | ||
DE4007313A DE4007313A1 (en) | 1990-03-08 | 1990-03-08 | METHOD FOR PRODUCING FINE-PART, WATER-SOLUBLE POLYMERISATS |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2037292A1 true CA2037292A1 (en) | 1991-09-09 |
CA2037292C CA2037292C (en) | 2000-09-26 |
Family
ID=6401692
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002037292A Expired - Fee Related CA2037292C (en) | 1990-03-08 | 1991-02-28 | Preparation of finely divided, water-soluble polymers |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0445619B1 (en) |
JP (1) | JP2901773B2 (en) |
AU (1) | AU633705B2 (en) |
CA (1) | CA2037292C (en) |
DE (2) | DE4007313A1 (en) |
ZA (1) | ZA911671B (en) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4316200A1 (en) * | 1993-05-14 | 1994-11-17 | Roehm Gmbh | Process for the preparation of low-viscosity, water-soluble polymer dispersions |
DE10037629A1 (en) * | 2000-08-02 | 2002-02-14 | Skw Bauwerkstoffe Deutschland | Water-soluble or water-swellable sulfo-containing associative thickening copolymers, process for their preparation and their use |
DE102005014291A1 (en) | 2005-03-24 | 2006-09-28 | Basf Ag | Process for the preparation of water-absorbing polymers |
FR2888240B1 (en) * | 2005-07-11 | 2007-09-07 | Biomerieux Sa | SOLUBLE ELECTROPOLYMERISABLE MONOMERS IN AQUEOUS SOLUTION AND ELECTROACTIVE PROBES THAT MAY BE OBTAINED WITH SUCH MONOMERS |
DE102005042604A1 (en) | 2005-09-07 | 2007-03-08 | Basf Ag | Neutralization process |
US8287664B2 (en) * | 2006-07-12 | 2012-10-16 | Vacuumschmelze Gmbh & Co. Kg | Method for the production of magnet cores, magnet core and inductive component with a magnet core |
EP2163266A1 (en) | 2008-09-12 | 2010-03-17 | The Procter & Gamble | Absorbent article comprising water-absorbing material |
US20120157302A1 (en) | 2009-08-28 | 2012-06-21 | Basf Se | Process For Producing Triclosan-Coated Superabsorbents |
BR112012005901A2 (en) | 2009-09-16 | 2019-09-24 | Basf Se | superabsorbent, process for producing a superabsorbent, article for absorbing fluids, and process for producing articles for absorbing fluids |
US8815770B2 (en) | 2009-09-17 | 2014-08-26 | Basf Se | Color-stable superabsorber |
EP2476714A1 (en) | 2011-01-13 | 2012-07-18 | Basf Se | Polyurethane integral foams with improved surface hardness |
EP2573153A3 (en) | 2011-09-26 | 2014-07-30 | Basf Se | Heat storing composition containing sodium sulfate, decahydrate and superabsorber |
US8741169B2 (en) | 2011-09-26 | 2014-06-03 | Basf Se | Heat storage composition comprising sodium sulfate decahydrate and superabsorbent |
WO2013144026A1 (en) | 2012-03-30 | 2013-10-03 | Basf Se | Color-stable super-absorbent |
KR20140142740A (en) | 2012-03-30 | 2014-12-12 | 바스프 에스이 | Color-stable super-absorbent |
EP2730596A1 (en) | 2012-11-13 | 2014-05-14 | Basf Se | Polyurethane soft foam materials containing plant seeds |
US10881555B2 (en) | 2016-03-30 | 2021-01-05 | Basf Se | Fluid-absorbent article |
CN111278551B (en) | 2017-11-10 | 2023-09-29 | 巴斯夫欧洲公司 | Super absorbent |
JP7361714B2 (en) | 2018-04-10 | 2023-10-16 | ビーエーエスエフ ソシエタス・ヨーロピア | Osmotic superabsorbent and method of manufacturing the same |
CN112512476A (en) | 2018-08-01 | 2021-03-16 | 巴斯夫欧洲公司 | Fluid-absorbent core |
DE102019216910A1 (en) | 2018-11-12 | 2020-05-14 | Basf Se | Process for post-crosslinking superabsorbents |
CN114174357A (en) | 2019-07-24 | 2022-03-11 | 巴斯夫欧洲公司 | Permeable superabsorbents and method for the production thereof |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3232915A (en) * | 1962-05-02 | 1966-02-01 | Du Pont | Suspension polymerization using 2-stage buffer salt addition to prevent clustering and to regulate bead size |
US4286082A (en) * | 1979-04-06 | 1981-08-25 | Nippon Shokubai Kagaku Kogyo & Co., Ltd. | Absorbent resin composition and process for producing same |
JPH0830098B2 (en) * | 1987-07-16 | 1996-03-27 | 日本合成化学工業株式会社 | Super absorbent resin manufacturing method |
DE3843780A1 (en) * | 1988-12-24 | 1990-07-05 | Basf Ag | METHOD FOR PRODUCING FINE-PARTICLE, GEL-SHAPED, WATER-SWELLABLE COPOLYMERS |
-
1990
- 1990-03-08 DE DE4007313A patent/DE4007313A1/en not_active Withdrawn
-
1991
- 1991-02-25 EP EP91102741A patent/EP0445619B1/en not_active Expired - Lifetime
- 1991-02-25 DE DE59103454T patent/DE59103454D1/en not_active Expired - Lifetime
- 1991-02-28 CA CA002037292A patent/CA2037292C/en not_active Expired - Fee Related
- 1991-03-06 JP JP3040021A patent/JP2901773B2/en not_active Expired - Lifetime
- 1991-03-07 AU AU72714/91A patent/AU633705B2/en not_active Ceased
- 1991-03-07 ZA ZA911671A patent/ZA911671B/en unknown
Also Published As
Publication number | Publication date |
---|---|
AU633705B2 (en) | 1993-02-04 |
DE59103454D1 (en) | 1994-12-15 |
JP2901773B2 (en) | 1999-06-07 |
EP0445619A3 (en) | 1991-10-16 |
EP0445619A2 (en) | 1991-09-11 |
JPH0597907A (en) | 1993-04-20 |
AU7271491A (en) | 1991-09-12 |
ZA911671B (en) | 1992-11-25 |
CA2037292C (en) | 2000-09-26 |
DE4007313A1 (en) | 1991-09-12 |
EP0445619B1 (en) | 1994-11-09 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |