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CA2017190A1 - Process for the preparation of ethylene polymers - Google Patents

Process for the preparation of ethylene polymers

Info

Publication number
CA2017190A1
CA2017190A1 CA2017190A CA2017190A CA2017190A1 CA 2017190 A1 CA2017190 A1 CA 2017190A1 CA 2017190 A CA2017190 A CA 2017190A CA 2017190 A CA2017190 A CA 2017190A CA 2017190 A1 CA2017190 A1 CA 2017190A1
Authority
CA
Canada
Prior art keywords
preparation
grain
products
ethylene polymers
metallocene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2017190A
Other languages
French (fr)
Other versions
CA2017190C (en
Inventor
Walter Spaleck
Martin Antberg
Ludwig Bohm
Jurgen Rohrmann
Hartmut Luker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6381117&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2017190(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of CA2017190A1 publication Critical patent/CA2017190A1/en
Application granted granted Critical
Publication of CA2017190C publication Critical patent/CA2017190C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

Process for the preparation of ethylene polymers The preparation of polyethylene and ethylene-1-olefin copolymers in the suspension or gas phase process with the aid of metallocene/aluminoxane catalysts whose metallocene component is a bridged biscyclopentadienyl complex offers particular advantages.
Depending on the structure of the complex, the use of these complexes gives, with high activity, products in a very broad molecular-weight range and permits the production of very varied grain morphologies of the products, such as high and low bulk density, extremely small and extremely large mean grain diameters and various grain shapes. The variety of grain morphologies which can be achieved opens up various possibilities for the use of such polyethylene powders in sintering processes.
CA002017190A 1989-05-20 1990-05-18 Process for the preparation of ethylene polymers Expired - Lifetime CA2017190C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3916555A DE3916555A1 (en) 1989-05-20 1989-05-20 PROCESS FOR THE PRODUCTION OF ETHYLENE POLYMERS
DEP3916555.8 1989-05-20

Publications (2)

Publication Number Publication Date
CA2017190A1 true CA2017190A1 (en) 1990-11-20
CA2017190C CA2017190C (en) 2001-01-30

Family

ID=6381117

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002017190A Expired - Lifetime CA2017190C (en) 1989-05-20 1990-05-18 Process for the preparation of ethylene polymers

Country Status (7)

Country Link
EP (2) EP0399348B1 (en)
JP (1) JP2904301B2 (en)
AU (1) AU630451B2 (en)
CA (1) CA2017190C (en)
DE (3) DE3916555A1 (en)
ES (2) ES2144089T3 (en)
ZA (1) ZA903831B (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5350817A (en) * 1991-05-27 1994-09-27 Hoechst Ag Process for the preparation of polyolefins having a broad molecular weight distribution
US5360921A (en) * 1993-03-22 1994-11-01 Mitsui Petrochemical Industries, Ltd. Process for preparing cyclopentadienyl group-containing silicon compound or cyclopentadienyl group-containing germanium compound
US5504232A (en) * 1992-08-03 1996-04-02 Hoechst Aktiengesellschaft Process for the preparation of an olefin polymer using specific metallocenes
US5696045A (en) * 1993-09-29 1997-12-09 Winter; Andreas Process for the preparation of polyolefins
US5710224A (en) * 1991-07-23 1998-01-20 Phillips Petroleum Company Method for producing polymer of ethylene
US5852143A (en) * 1995-05-16 1998-12-22 Union Carbide Chemicals & Plastics Technology Corporation Production of polyethylene using stereoisomeric metallocenes
WO1999002569A1 (en) * 1997-07-14 1999-01-21 The Board Of Trustees Of The Leland Stanford, Jr. University CATALYSTS AND PROCESSES FOR THE SYNTHESIS OF ALTERNATING ETHYLENE/α-OLEFIN COPOLYMERS, AND ISOTACTIC COPOLYMERS THEREOF
US5962359A (en) * 1994-12-28 1999-10-05 Targor Gmbh Metallocene compound and its use as catalyst component
WO1999055748A1 (en) * 1998-04-27 1999-11-04 Fina Research S.A. Polyolefin production
US6218488B1 (en) 1998-03-04 2001-04-17 Exxon Mobil Chemical Patents Inc. Polymerization process for olefin copolymers using bridged hafnocene compounds
US6818585B2 (en) 1998-12-30 2004-11-16 Univation Technologies, Llc Catalyst compounds, catalyst systems thereof and their use in a polymerization process
US8822611B2 (en) 2004-11-19 2014-09-02 Total Research & Technology Feluy Solid state properties of polyethylene prepared with tetrahydroindenyl-based catalyst system

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4032266A1 (en) * 1990-10-11 1992-04-16 Hoechst Ag METHOD FOR PRODUCING A POLYOLEFIN
US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
DE4121368A1 (en) * 1991-06-28 1993-01-07 Hoechst Ag CATALYST AND METHOD FOR THE PRODUCTION OF HIGH-MOLECULAR POLYOLEFINES
TW300901B (en) * 1991-08-26 1997-03-21 Hoechst Ag
DE4130352A1 (en) * 1991-09-12 1993-03-18 Basf Ag DISABLED AND REACTIVATED METALLOCENE CATALYST SYSTEMS
DE4139261A1 (en) * 1991-11-29 1993-06-03 Basf Ag LOW DENSITY ETHYLENE COPOLYMERISATE
GB9125934D0 (en) 1991-12-05 1992-02-05 Exxon Chemical Patents Inc Process for polymerising olefinic feeds under pressure
US5302733A (en) * 1992-03-30 1994-04-12 Ethyl Corporation Preparation of metallocenes
JP2007146183A (en) * 1992-12-07 2007-06-14 Mitsubishi Chemicals Corp Resin composition for extrusion-molded article
IT1270253B (en) 1994-06-20 1997-04-29 Spherilene Srl ETHYLENE COPOLYMERS AND PROCEDURE FOR THE PREPARATION OF ETHYLENE POLYMERS
DE4436113A1 (en) 1994-10-10 1996-04-11 Hoechst Ag Metallocene compound
CN1111173C (en) * 1994-12-20 2003-06-11 三井化学株式会社 Process for the preparation of ethylene polymer and ethylene polymer
UA47394C2 (en) * 1995-05-16 2002-07-15 Юнівейшн Текнолоджіз, Ллс Ethylene polymer with improved processability and an article containing the ethylene polymer
DE19637669A1 (en) * 1996-09-16 1998-03-19 Hoechst Ag Process for the preparation of a methylene-bridged biscyclopentadienyl compound
GB9718073D0 (en) * 1997-08-28 1997-10-29 Zeneca Ltd Organometallic compounds,their preparation and use
US6448350B1 (en) 1998-04-21 2002-09-10 Basell Technology Company Bv Process for the preparation of copolymers of ethylene with alpha-olefins
CA2317485A1 (en) 1998-11-20 2000-06-02 Montell Technology Company B.V. Bridged metallocenes, preparation, use in catalytic systems
US6339134B1 (en) 1999-05-06 2002-01-15 Univation Technologies, Llc Polymerization process for producing easier processing polymers
EP1059332A1 (en) 1999-06-10 2000-12-13 Fina Research S.A. Polypropylene with high melt strength and drawability
JP3798694B2 (en) * 1999-12-01 2006-07-19 エクソンモービル・ケミカル・パテンツ・インク Catalyst compounds, catalyst systems containing them and their use in polymerization processes
AU3016401A (en) 1999-12-28 2001-07-09 Basell Technology Company B.V. Process for the preparation of ethylene polymers
DE60102805T2 (en) * 2000-02-08 2005-04-21 Exxonmobil Chem Patents Inc PROCESS FOR PREPARING GROUP 14 BURGLED BISCYCLOPENTADIENYL LIGANDS
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
WO2004046214A2 (en) 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
KR100833561B1 (en) * 2004-08-16 2008-05-30 미쓰이 가가쿠 가부시키가이샤 Ethylene polymer and use thereof
US7795194B2 (en) 2004-11-26 2010-09-14 Mitsui Chemicals, Inc. Synthetic lubricating oil and lubricating oil composition
DE602004019667D1 (en) * 2004-12-03 2009-04-09 Repsol Quimica Sa Catalyst compositions for the polymerization and copolymerization of alpha-olefins
JP2010536905A (en) * 2007-08-27 2010-12-02 ボレアリス テクノロジー オイ catalyst
US8445609B2 (en) 2009-04-21 2013-05-21 Mitsui Chemicals, Inc. Method for producing olefin polymer
US20120135903A1 (en) 2010-05-11 2012-05-31 Mitsui Chemicals, Inc. Lubricating oil composition
US8796409B2 (en) 2011-10-04 2014-08-05 Exxonmobil Chemical Patents Inc. Use of temperature and ethylene partial pressure to introduce long chain branching in high density polyethylene
JP6290796B2 (en) 2013-02-08 2018-03-07 三井化学株式会社 Solid polyaluminoxane composition, catalyst for olefin polymerization, method for producing olefin polymer, and method for producing solid polyaluminoxane composition
CN107428863B (en) 2015-03-31 2020-03-06 日本聚乙烯株式会社 Polyethylene for pipe and joint, and molded body thereof
JP6651938B2 (en) 2016-03-28 2020-02-19 日本ポリエチレン株式会社 Polyethylene and its molded body

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3127133A1 (en) 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt METHOD FOR PRODUCING POLYOLEFINS AND THEIR COPOLYMERISATS
DE3424697C2 (en) 1984-07-05 1999-07-08 Targor Gmbh Process for the polymerization of ethylene or of mixtures of ethylene with other 1-olefins
DE3443087A1 (en) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt METHOD FOR PRODUCING POLYOLEFINES
CA1268754A (en) 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
EP0260999A1 (en) * 1986-09-19 1988-03-23 Exxon Chemical Patents Inc. High pressure, high temperature polymerization of ethylene
DE3640924A1 (en) * 1986-11-29 1988-06-01 Hoechst Ag 1-OLEFIN STEREOBLOCK POLYMER AND METHOD FOR THE PRODUCTION THEREOF
JP2538588B2 (en) 1987-04-03 1996-09-25 三井石油化学工業株式会社 Method for producing solid catalyst for olefin polymerization
JP2538595B2 (en) 1987-05-13 1996-09-25 三井石油化学工業株式会社 Solid catalyst for olefin polymerization
DE3726067A1 (en) * 1987-08-06 1989-02-16 Hoechst Ag METHOD FOR PRODUCING 1-OLEFIN POLYMERS
IT1221653B (en) * 1987-11-27 1990-07-12 Ausimonti Spa PROPYLENE CRYSTALLINE COPOLYMERS
DE3743321A1 (en) * 1987-12-21 1989-06-29 Hoechst Ag 1-OLEFIN POLYMER WAX AND METHOD FOR THE PRODUCTION THEREOF
US4871705A (en) * 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
DE3825814A1 (en) * 1988-07-29 1990-02-01 Hoechst Ag METHOD FOR PRODUCING L-OLEFIN POLYMERS
DE3826075A1 (en) * 1988-07-30 1990-02-01 Hoechst Ag 1-OLEFIN ISO BLOCK POLYMER AND METHOD FOR THE PRODUCTION THEREOF
EP0426645B1 (en) * 1989-10-30 1996-07-03 Fina Research S.A. Process for producing syndiotactic copolymers of propylene and olefins

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5350817A (en) * 1991-05-27 1994-09-27 Hoechst Ag Process for the preparation of polyolefins having a broad molecular weight distribution
US5714427A (en) * 1991-05-27 1998-02-03 Hoechst Aktiengesellschaft Catalyst system comprising two zirconocenes and aluminoxane
US5710224A (en) * 1991-07-23 1998-01-20 Phillips Petroleum Company Method for producing polymer of ethylene
US5504232A (en) * 1992-08-03 1996-04-02 Hoechst Aktiengesellschaft Process for the preparation of an olefin polymer using specific metallocenes
US5763542A (en) * 1992-08-03 1998-06-09 Targor Gmbh Process for the preparation of an olefin polymer using specific metallocenes
US6087292A (en) * 1992-08-03 2000-07-11 Tangor Gmbh Metallocene catalysts comprising indenyl ligands substituted with electronegative groups
US5360921A (en) * 1993-03-22 1994-11-01 Mitsui Petrochemical Industries, Ltd. Process for preparing cyclopentadienyl group-containing silicon compound or cyclopentadienyl group-containing germanium compound
US5696045A (en) * 1993-09-29 1997-12-09 Winter; Andreas Process for the preparation of polyolefins
US5700886A (en) * 1993-09-29 1997-12-23 Hoechst Aktiengesellschaft Process for the preparation of polyolefins
US6150481A (en) * 1993-09-29 2000-11-21 Targor Gmbh Process for the preparation of polyolefins
US5962359A (en) * 1994-12-28 1999-10-05 Targor Gmbh Metallocene compound and its use as catalyst component
US6114556A (en) * 1994-12-28 2000-09-05 Targor Gmbh Metallocene compound and its use as catalyst component
US5852143A (en) * 1995-05-16 1998-12-22 Union Carbide Chemicals & Plastics Technology Corporation Production of polyethylene using stereoisomeric metallocenes
WO1999002569A1 (en) * 1997-07-14 1999-01-21 The Board Of Trustees Of The Leland Stanford, Jr. University CATALYSTS AND PROCESSES FOR THE SYNTHESIS OF ALTERNATING ETHYLENE/α-OLEFIN COPOLYMERS, AND ISOTACTIC COPOLYMERS THEREOF
US6218488B1 (en) 1998-03-04 2001-04-17 Exxon Mobil Chemical Patents Inc. Polymerization process for olefin copolymers using bridged hafnocene compounds
US6262202B1 (en) 1998-03-04 2001-07-17 Univation Technologies, Llc Noncoordinating anions for olefin polymerization
US6291609B1 (en) 1998-03-04 2001-09-18 Exxonmobil Chemical Patents Inc. High temperature olefin polymerization process
WO1999055748A1 (en) * 1998-04-27 1999-11-04 Fina Research S.A. Polyolefin production
US6818585B2 (en) 1998-12-30 2004-11-16 Univation Technologies, Llc Catalyst compounds, catalyst systems thereof and their use in a polymerization process
US7446073B2 (en) 1998-12-30 2008-11-04 Exxonmobil Chemical Patents Inc. Catalyst compounds, catalyst systems thereof and their use in a polymerization process
US8822611B2 (en) 2004-11-19 2014-09-02 Total Research & Technology Feluy Solid state properties of polyethylene prepared with tetrahydroindenyl-based catalyst system

Also Published As

Publication number Publication date
EP0399348B1 (en) 1998-05-20
EP0700937A3 (en) 1997-02-19
JP2904301B2 (en) 1999-06-14
ZA903831B (en) 1991-02-27
JPH0321607A (en) 1991-01-30
DE59010821D1 (en) 1998-06-25
EP0399348A2 (en) 1990-11-28
EP0700937B1 (en) 2000-02-16
DE59010898D1 (en) 2000-03-23
DE3916555A1 (en) 1990-11-22
AU630451B2 (en) 1992-10-29
ES2116263T3 (en) 1998-07-16
AU5577190A (en) 1991-01-10
EP0399348A3 (en) 1992-08-12
CA2017190C (en) 2001-01-30
EP0700937A2 (en) 1996-03-13
ES2144089T3 (en) 2000-06-01

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