CA2081813A1 - Process for the preparation of 1,1,1,2,3,3,3-heptafluoropropane (r 227) - Google Patents
Process for the preparation of 1,1,1,2,3,3,3-heptafluoropropane (r 227)Info
- Publication number
- CA2081813A1 CA2081813A1 CA002081813A CA2081813A CA2081813A1 CA 2081813 A1 CA2081813 A1 CA 2081813A1 CA 002081813 A CA002081813 A CA 002081813A CA 2081813 A CA2081813 A CA 2081813A CA 2081813 A1 CA2081813 A1 CA 2081813A1
- Authority
- CA
- Canada
- Prior art keywords
- heptafluoropropane
- preparation
- chloroheptafluoropropane
- ladium
- pal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- YFMFNYKEUDLDTL-UHFFFAOYSA-N 1,1,1,2,3,3,3-heptafluoropropane Chemical compound FC(F)(F)C(F)C(F)(F)F YFMFNYKEUDLDTL-UHFFFAOYSA-N 0.000 title abstract 2
- KJGXPVLCSICDQG-UHFFFAOYSA-N 2-chloro-1,1,1,2,3,3,3-heptafluoropropane Chemical compound FC(F)(F)C(F)(Cl)C(F)(F)F KJGXPVLCSICDQG-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/23—Preparation of halogenated hydrocarbons by dehalogenation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
The invention relates to a process for the preparation of 1,1,1,2,3,3,3-heptafluoropropane, which comprises react-ing 2-chloroheptafluoropropane with hydrogen in a molar ratio of from 1:1 to 1:10 in the gas phase on a pal-ladium-, platinum-, ruthenium-, rhodium-, nickel- or copper-containing supported catalyst at temperatures of from 100 to 400°C and pressures of from 1 to 50 bar.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4136054.0 | 1991-11-01 | ||
DE4136054 | 1991-11-01 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2081813A1 true CA2081813A1 (en) | 1993-05-02 |
CA2081813C CA2081813C (en) | 2004-01-13 |
Family
ID=6443903
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002081813A Expired - Fee Related CA2081813C (en) | 1991-11-01 | 1992-10-30 | Process for the preparation of 1,1,1,2,3,3,3-heptafluoropropane (r 227) |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0539989B1 (en) |
JP (1) | JP3249202B2 (en) |
CA (1) | CA2081813C (en) |
DE (1) | DE59208629D1 (en) |
ES (1) | ES2104790T3 (en) |
SG (1) | SG44743A1 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5780691A (en) * | 1996-12-23 | 1998-07-14 | Allied Signal Inc. | Process for producing 1,1,1,2,3,3,3,-heptafluoroprane |
US6291729B1 (en) | 1994-12-08 | 2001-09-18 | E. I. Du Pont De Nemours And Company | Halofluorocarbon hydrogenolysis |
US7151197B2 (en) | 2001-09-28 | 2006-12-19 | Great Lakes Chemical Corporation | Processes for purifying chlorofluorinated compounds and processes for purifying CF3CFHCF3 |
US7216722B2 (en) | 2003-04-17 | 2007-05-15 | Great Lakes Chemical Corporation | Fire extinguishing mixtures, methods and systems |
US7368089B2 (en) | 2003-08-13 | 2008-05-06 | Great Lakes Chemical Corporation | Systems and methods for producing fluorocarbons |
US8367879B2 (en) | 2007-11-09 | 2013-02-05 | Mexichem Amanco Holding S.A. De C.V. | Method for the preparation of 2 chloro 1,1,1,2,3,3,3 heptafluoropropane |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993024433A1 (en) * | 1992-06-03 | 1993-12-09 | Allied-Signal Inc. | Process producing a hydrofluorocarbon having at least one trifluoro group |
DE69414403T2 (en) * | 1993-07-29 | 1999-05-06 | Alliedsignal Inc., Morristown, N.J. | METHOD FOR PRODUCING 1,1,1,3,3 PENTAFLUORPROPANE |
JP3500617B2 (en) * | 1993-08-27 | 2004-02-23 | ダイキン工業株式会社 | Method for producing hexafluorocyclobutane |
US5315048A (en) * | 1993-09-30 | 1994-05-24 | Alliedsignal Inc. | Preparation of 1,1,1,2,3-pentafluoropropane by reduction of 1,2,3-trichloropentafluropropane |
US5880317A (en) * | 1993-09-30 | 1999-03-09 | Alliedsignal Inc. | Preparation of 1,1,2,3,3-pentafluoropropane |
BE1007822A5 (en) * | 1993-12-10 | 1995-10-31 | Solvay | SUPPORT FOR CATALYST hydrogenate ION SYSTEM INCLUDING THE CATALYST SUPPORT AND METHOD OF hydrodechlorination chlorofluorocarbons. |
FR2764883B1 (en) * | 1997-06-18 | 1999-07-16 | Atochem Elf Sa | PROCESS FOR THE MANUFACTURE OF HYDROFLUOROALCANES |
AU3377999A (en) * | 1998-04-03 | 1999-10-25 | E.I. Du Pont De Nemours And Company | Processes for the purification and use of 2-chloro-1,1,1,2,3,3,3-heptafluoropropane and azeotropes thereof with hf |
US6281395B1 (en) | 1998-04-03 | 2001-08-28 | E. I. Du Pont De Nemours And Company | 1,1,1,2,3,3,3-heptafluoropropane manufacturing process |
DE69910995T2 (en) * | 1998-04-03 | 2004-07-22 | E.I. Du Pont De Nemours And Co., Wilmington | METHOD FOR PRODUCING FLUOROCOLATES |
IT1301758B1 (en) | 1998-06-19 | 2000-07-07 | Ausimont Spa | 227 PREPARATION PROCESS |
DK1059092T3 (en) | 1999-06-08 | 2006-03-27 | Gentium Spa | Use of complexes of cationic liposomes and polydeoxyribonucleotides as drugs |
US6235950B1 (en) * | 1999-12-22 | 2001-05-22 | Honeywell International | Method of making hydrofluorocarbons |
US7375728B2 (en) | 2001-10-01 | 2008-05-20 | University Of Minnesota | Virtual mirror |
US20050020863A1 (en) * | 2003-07-25 | 2005-01-27 | Honeywell International Inc. | Method of making fluorinated propanes |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE571509A (en) | 1957-09-26 | 1900-01-01 | ||
GB902590A (en) | 1960-03-22 | 1962-08-01 | Allied Chem | Production of heptafluoropropane |
GB8828544D0 (en) * | 1988-12-07 | 1989-01-11 | Ici Plc | Chemical process |
RU2068835C1 (en) * | 1989-10-10 | 1996-11-10 | Е.И.Дюпон Де Немур Энд Компани | Method for hydrogenolysis of halogenated hydrocarbons |
-
1992
- 1992-10-29 ES ES92118515T patent/ES2104790T3/en not_active Expired - Lifetime
- 1992-10-29 DE DE59208629T patent/DE59208629D1/en not_active Expired - Fee Related
- 1992-10-29 EP EP92118515A patent/EP0539989B1/en not_active Expired - Lifetime
- 1992-10-29 SG SG1996006724A patent/SG44743A1/en unknown
- 1992-10-30 JP JP29338392A patent/JP3249202B2/en not_active Expired - Fee Related
- 1992-10-30 CA CA002081813A patent/CA2081813C/en not_active Expired - Fee Related
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6291729B1 (en) | 1994-12-08 | 2001-09-18 | E. I. Du Pont De Nemours And Company | Halofluorocarbon hydrogenolysis |
US5780691A (en) * | 1996-12-23 | 1998-07-14 | Allied Signal Inc. | Process for producing 1,1,1,2,3,3,3,-heptafluoroprane |
US7151197B2 (en) | 2001-09-28 | 2006-12-19 | Great Lakes Chemical Corporation | Processes for purifying chlorofluorinated compounds and processes for purifying CF3CFHCF3 |
US7329786B2 (en) | 2001-09-28 | 2008-02-12 | Great Lakes Chemical Corporation | Processes for producing CF3CFHCF3 |
US7332635B2 (en) | 2001-09-28 | 2008-02-19 | Great Lakes Chemical Corporation | Processes for purifying chlorofluorinated compounds |
US7335805B2 (en) | 2001-09-28 | 2008-02-26 | Great Lakes Chemical Corporation | Processes for purifying reaction products and processes for separating chlorofluorinated compounds |
US7348461B2 (en) | 2001-09-28 | 2008-03-25 | Great Lakes Chemical Corporation | Processes for halogenating compounds |
US7216722B2 (en) | 2003-04-17 | 2007-05-15 | Great Lakes Chemical Corporation | Fire extinguishing mixtures, methods and systems |
US7223351B2 (en) | 2003-04-17 | 2007-05-29 | Great Lakes Chemical Corporation | Fire extinguishing mixtures, methods and systems |
US7368089B2 (en) | 2003-08-13 | 2008-05-06 | Great Lakes Chemical Corporation | Systems and methods for producing fluorocarbons |
US8367879B2 (en) | 2007-11-09 | 2013-02-05 | Mexichem Amanco Holding S.A. De C.V. | Method for the preparation of 2 chloro 1,1,1,2,3,3,3 heptafluoropropane |
Also Published As
Publication number | Publication date |
---|---|
EP0539989A1 (en) | 1993-05-05 |
JP3249202B2 (en) | 2002-01-21 |
EP0539989B1 (en) | 1997-06-18 |
DE59208629D1 (en) | 1997-07-24 |
SG44743A1 (en) | 1997-12-19 |
CA2081813C (en) | 2004-01-13 |
JPH05221894A (en) | 1993-08-31 |
ES2104790T3 (en) | 1997-10-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |