CA1152671A - Alkaline resistant organic coatings for corrosion susceptible substrates ii - Google Patents

Abstract

ALKALINE RESISTANT ORGANIC COATINGS
FOR CORROSION SUSCEPTIBLE SUBSTRATES II
ABSTRACT OF THE DISCLOSURE
Crosslinking compositions comprising (a) reaction product, optionally at least partially neutralized of certain di- or poly epoxy and hydroxy amines and (b) amino resin crosslinkers cure into alkaline resistant coatings that protect against corrosion even in absence of inhibiting pigments such as chromates. The crosslinking compositions may be formulated into a variety of primers including sol-vent and water base primers that cure within conventional schedules.

Description

~lSZ~i71 This invention relates to preventing corrosion of susceptible substrates as ferrous metals and includes, in particular, resins that retard corrosion of such substrates even when formulated in primer compositions that are free of such inhibiting pigments as chromates.
The corrosion of steel immersed in an aqueous environment can often be slowed to an acceptable rate by the introduction of corrosion inhibitors soluble in the aqueous medium. In the case of steel structures subjected intermittently to a corrosive environment, or under conditions which preclude effective incorporation of a corrosion inhibitor into the corrosive medium, protective organic coatings are often used. One of the major functions of these coatings is to act as a reservoir for sparingly soluble inorganic corrosion inhibitors which act to slow the rate of corrosion at coating defects and other incipient anodic corrosion sites. Among the most effective inhibitors are inorganic chromates whose safety has been questioned by some. While the elimination of these pigments may therefore be desirable, it is found that in the absence of effective corrosion inhibiting pigments extensive adhesion failure adjacent to coating defects and flaws can take place, resulting ultimately in the uncontrolled spread of corrosion.
The principal cause of corrosion-induced adhesion failure is generally thought to be displacement and/or degradation of the coating resin by cathodically produced hydroxide ion.
Corrosion inhibitors suppress this effect by slowing the overall rate of corrosion, limiting the amount of alkali produced. In the absence of corrosion inhibitors it is therefore necessary that the coating resin be exceptionally resistant to displacement and/or degradation by corrosion-produced hydroxide.
The present invention provides resins suitable for use in organic coatings and which additionally are highly resistant to alkali degradation. The organic coating formulations of the invention enable fexrous substrates, especially automotive steel substrates, to be protected from corrosion without the incorporation of possibly dele-terious corrosion inhibitive pigments with application and . . . ,~
, ~

~152671 handling characteristics, including shelf stability, which are compatible with conventional commercial paint operations and practices.
In accordance with the present invention, there is provided in a solvent based primer composition that retards corrosion in substantial absence of chromate corrosion inhibiting pigments which comprises an intimate admixture of film forming ingredients consisting essentially of: (A) a substantially gel free epoxy and amine reaction product which contains no ester linkages and which is made by reacting in non-aqueous medium reactants consisting essentially of: 1. a non-ester linked epoxy reactant that contains an average of at least about two terminal epoxy groups per molecule and is a bis-phenol-A reaction product having an epoxide equivalent of at least about 875; 2. an amine reactant selected from the group consisting of secondary monoamines having a total of up to about 20 carbons, and comprising at least about 75 mole percent hydroxy amine containing one or more hydroxy groups removed at least one carbon from the amino nitrogen in an equivalent amount such that the reaction product (A) comprises tertiary amino and primary and secondary hydroxy groups and is substatia]ly free of unreacted epoxy groups; (B) optionally, a di- or polyhydroxy compound; and (C) an amino aldehyde resin crosslinking agent at about 5 to 35%
by weight of the combined weight (A) and (B).
Surprisingly such compositions may be cured within commercially acceptable curing schedules without volatilization of the amine to provide coatings that are exceptionally resistant to degradation/displacement under corrosive conditions and may advantageously be cured at even lower temperatures in the presence of catalyst. The processes exhibit corrosion resistance considerably in excess of certain conventional primers.

~15Z671 The discovery that corrosion prevention may be accomplished in the absence of inhibiting pigments provides an alternative means of preventing corrosion that is believed to utilize a mechanism different than when inhibiting pigments as chromates are included. More particularly, available evidence indicates that cured coatings, as described more fully herein, rather than slowing the overall rate of corrosion by retarding anodic dissolution of iron as a means to retard corrosion, provide an adherent cross-linked network which is exceptionally resistant to degradation/displacement by cathodically produced hydroxide and thus limit the total area over which the corrosion reactions can occur.
The essential components of cross-linking composi-tions used in this invention include certain epoxy compounds, hydroxy amines and amino resin cross-linking agent. The components are combined in a fashion that forms the cross-linking composition useful in solvent-base and water-base primer coating compositions.
Compositional Ingredients (A) EPOXY-AMINE REACTION PRODUCT
The epoxy amine reaction product is formed in non-aqueous medium by reacting a di or polyepoxide (that is preferably free of carboxy ester moieties linking the epoxide groups) with certain amines.
1. Epoxy Reactant - The epoxy reactant essen-tially should contain at least about two, on the average, epoxy groups per molecule and may contain three or more with a molecular weight preferably above about 300 (number average) and up to about 10,00 or more, depending on factors as desired viscosity and solids content.
One class of suitable epoxy compounds for the epoxy reactant include reaction products of di or poly-hydric, mono, di or polycyclic compounds with epihalohydrins O
of the formula X-CH2-CY-CH2 wherein X is halogen as chloro and Y is hydrogen or lower alkyl such as methyl or ethyl which epihalohydrin reaction products are exemplified by such straight chain epoxy terminated compounds containing ~52f~7i ~;~c~>~l- 4 c~y~ ether groups as bis-phenol A-epichlorohydrin reaction C
products that are commercially available as, for example, Epon 828, 1001 or 1004 (marketed by Shell Chemical Company).
Such products contain aromatic groups as benzene nuclei at a preferred average of at least about one, more prefer-ably for this invention at least about two, on the average, for each terminal epoxy group. Especially suitable are bis-phenol A-epichlorohydrin reaction products comprising in major amounts up to 10 or more bis-phenol moieties within the epichlorohydrin reaction product backbone, e.g. molecular weights in a range of up to about 3000, preferably 700-6000, on a number average basis.
Other examples of epoxy compounds for the epoxy reactant include polyepoxy compounds (averaging more than about two epoxy groups per molecule) which are also commer-cially available. In this group of epoxy compounds are the Novolac* epoxy resins, e.g. Epon* 152 and 154 (marketed by Shell Chemical Company). These polyepoxy ~esins include epoxidized products of phenol formaldehyde resins that contain terminal glycidyl ether groups from aromatic moieties.
Aliphatic including cycloaliphatic epoxy compounds having, on the average, at least about two epoxy groups per molcule may also be employed. Such aliphatic epoxy compounds include epihalohydrin and aliphatic di or polyols such as glycols reaction products, epoxidized polybutadienes, vinylcyclohexenedioxide and dipentene dioxide. Still further, hydrogenated bis-phenol A epichlorohydrin products may also be employed.
Compatible mixtures of any of these epoxy compounds are also suitable.
In one preferred embodiment, the epoxy reactant * Trademarks .~

~152671 comprises relati~ely high molecular weight (e.g. number average above about 700) epoxy compound that have hydrophobic groups (as epihalohydrin reaction products of a diol, e.g. bis phenol-A) for these have been found to advantageously Curther 5 provide enhanced moisture resistance to the cured coatings as compared to lower molecular weight epoxy compounds made in this way. Alternatively, as will be more fully described hereinafter, certain lower molecular weight epoxy compounds may be reacted with primary and secondary alkanol amines to lO provide epoxy amine reaction products that similarly provide more desirable moisture resistance. Preferably, however, the epoxy reactant comprises higher molecular weight epoxy compounds as those bis-phenol A-epichlorohydrin reaction products that have at least about 25 mole percent (more 15 preferably at least about 75 mole percent) of compounds that have two or more, e.g. about 3-10 aromatic groups per epoxy group.

2. Amine Reactant - The amine reactant preferably comprises secondary or primary and secondary amine desira~ly 20 having a total of up to about 2~ carbons per amino nitrogen and with at least about 75 mole percent of the amine reactant comprising at least one hydroxy amine having one or more (preferably two) primary hydroxy groups on carbon atoms that are not adjacent to any amino nitrogen. Secondary amines 25 are typically suitable with higher molecular weight epoxy compounds whereas combinations of primary and secondary amines are advantageous with lo~er molecular weight epoxy compounds as the epoxy reactant so as to increase the molec-ular weight of the epoxy amine reaction product. Secondary 30 mono-amines are normally employed wi h polyepoxide having three or more epoxy groups per molecule.
Hydroxy of the hydroxy amine serves as a moiety th~t is believed to chemically react with at least a portion of the amino resin crosslinking agent during curing so as to 35 provide a crosslinked coating; it is preferred that the hydroxy amine have primary hydroxy attached to aliphatic carbon. Also, at least one amino nitrogen of the hydroxy amine is preferably substituted only by aliphatic carbon, ~152671 i.e. hydroxy aliphatic amine, although the aliphatic carbon chain may be interrupted or substituted as with non-interfer-ring heteroatoms as oxygen or aromatic as aryl or tertiary amine.
Hydroxy aliphatic secondary amines and, particu-larly hydroxy alkyl secondary monoamines are advantageous for the amine reactant in many instances, and especially desirable are hydroxy alkyl amines wherein the alkyl group is preferably lower alkyl e.g., up to 7 carbon atoms. In one preferred em~odiment, the amine reactant comprises all or nearly all (e.g. 90 mole percent or greater~ secondary amine that is amino alcohol and especially amino alcohol bearing two hydroxy alkyl substituents as, for example, diethanol amine.
A class of preferred hydroxy amines are illustrated according to the following formula:
H
~ -N-R' wherein R and R' are independently hydrogen or straight or 20branched chain aliphatic of up to about 10 carbons each providing that (a) at least one of R and Rl is not hydrogen and (b) at least one of R and ~' is substituted by hydroxy on a primary carbon atom that is not adjacent to any amino nitrogen. R and R' can also form part of a ring compound as 25a six membered ring. More preferably, R and ~' are indepen-dently alkyl and desirably up to 7 carbons each and especially for water-base formulations hydroxy (primary) alkyl up to 4 carbons each.
A variety of amines, however, may be suitably 30employed together as, for example, primary and secondary amines which are mixtures of alkyl amines and hydroxy alkyl amines. The important criterion is that there be suf~icient hydroxy functionality, especially primary hydroxy, in the reaction product of the amine reactant and epoxy reactant to 35insure adequate reaction with the amino resin crosslinking agent.
Preferably, howeYer, about 90 or more mole percen' of the amine reactant comprises amino alcohols with primary l~S267~
,_ hydroxy and especially hydroxy al~yl monoamine preferably bearing a primary hydroxy on both alkyl groups.
. Reaction Conditions for Product of Epoxy R actant and Amine Reactant The epoxy and amine reactants are reacted at conditions that allow opening of the epoxy ring by amino nitrogen and provide a gell free reaction product. With secondary amines, this generally results in tertiary amino groups whereas primary amines provide secondary amino groups which may undergo further reaction with an unreacted epoxy of the same or more probably of another molecule epoxy reactant resulting in chain extension.
The reaction medium comprises preferably non-aqueous medium that may be of diverse but preferably polar character and serves to maintain contact of reactants, con-trol reaction speed, maintain desirable viscosity and other functions well known in the art. Thus, suitable solvents and diluents for the reaction medium include aromatic and ali-phatic hydrocarbons, halides, ethers, alcohols, ketones such as methylamyl ~etone, n-amyl ether, xylene, butanol, oxygenated solvents such as propylene glycol monopropyl ether, cellosolves as 2-methoxy ethanol, 2-butoxy ethanol, carbitols as ethoxy butoxy ethanol, and the like including mixtures of these. Moreo~er, di- and polyhydroxy compounds, as hereinafter disclosed, may also serve as reaction medium or part thereof.
Elevated reaction temperatures may ~e employed to facilitate reaction between the epoxy reactant and amine reactant and the reaction may be conducted stepwise. The reaction is complete when the product is substantially free of unreacted epoxy groups as nearly equivalent amounts ~e.g. about 0.9-1.0 amine equivalents per l to 1.1 epoxy equivalent wherein an amine equivalent is one for a mole of secondary monoamine and two for a mole of primary mono-amine and mole of diepoxide compound, for example, has twoequivalents) are preferred. Thus, the reaction product of the epoxy reactant and amine reactant should contain less than 20~ of the original unreacted epoxy groups, more 1~5267~

desirably less than 10% as ~ or less unreacted epoxy groups, based on the number originally present.
(B) AMINO RESIN CROSSLINKING AGENT
The amino resin crosslinking agent may be admixed with the above reaction product (A) at levels of about 5-30 weight percent of the combined weight of (A) and optional ingredient (C) as hereinafter described. Preferred amino resin crosslinking agent includes well known and commercially available materials that are principally condensation products of amino or amido compounds with aldehydes which may be modified by monohydric alcohols of normally up to about four carbons.
Especially preferred amino resin crosslinking agents are partially alkylated melamines (melamine formalde-hyde resins modified by alcohols) e.g. partially methylatedmelamines and butylated melamines. Another preferred cross-linking agent is urea formaldehyde condensate modified by alcohol as butylated urea resin. Mixtures of crosslinkers as mixtures of alkylated melamines and alkylated urea are found especially suitable as, for instance, in solvent base primers using butylated types at weight ratios of (a) buty-lated melamine resin to (b) butylated urea resin of a:b of between 1:1 to 10:1.
Other suitable crosslinkers that are amino resir.s include glycol uril resins and benzoguanimine resin.
(C) OPTIONAL INGREDIENTS
Di- and polyhydroxy compounds of diverse character may be employed to modify film properties as well as acting as solvent including reactive solvent for solubilizing ~ the crosslinking compositions. These compounds can also impart increased flexibility as well as reducing cratering in spray primers formulated with (A) and (B3 above.
A preferred class of hydroxy compounds include aliphatic di hydroxy compounds, especially glycols and glycol ethers of the formula HO~Ca~2aO ~ Cb~2b)yH wherein a, b, x and y are independent integers and a and b are from 2 to 6 and x and y are from 0-10 with the sum of x and y being 10. Examples include ethylene glycol, dipropylene glycol, and 1,6 hexanediol. Another class of glycols include 115;~67~
g hydroxy terminated polybutadienes, hydrogenated bis-phenol-A, such hydroxy compounds being of generally hydrophobic character and molecular weights of about preferably 100-5000, number average. Higher boiling solvents (e.g.
boiling point above about 180C as 190-250) that are of polar character tend to interact with the crosslinking composition and thereby allow higher solids content.
Pigments may be used in the primer compositions of this invention in accordance with usual techni~ue except, if desired, chromate pigments need not be included to get good corrosion resistance. Exemplary pigments include titanium dioxide, silica, carbon black, and barytes and are employed at pigment: binder (i.e. sum of (A) and (B) above) weight ratios of about 40:60-60:40. Other ingredients as solvents, diluents, surfactants, catalysts and the like may also be included for their respective functions.
Catalysts and especially acid catalysts may be used to accelerate cure of the primer compositions herein as by lowering cure temperatures required to effect crosslinking within a 15-30 minute bake cycle from about 180C to 140 or even less. Acid catalyst include protic or Lewis acid materials preferably at about 0.5-5.0~ by weight of the primer composition and typical acids include strong acids such as phosphoric acid, paratoluene sulfonic acid, and substituted boron compounds as trialkoxy boron compounds, although, however, certain of these materials may result in films which exhibit less than desired moisture resistance.
An especially preferred catalyst for crosslinking compositions herein comprises reactive hydroxy (preferably aliphatic) phosphate esters made by reacting P2O5 and di or triol. This catalyst, employed preferably between about 0.1-5% by weight of the combined weight of (h) epoxy amine reaction product a~d (B) amino resin crosslinking agent provides not only reduced cure temperature but also, as distinguished from other usual strong catalysts advantageous-ly does not increase moisture sensitivity in certain formula-tions, particularly solvent based primers and can also lead to improved corrosion resistance in water base primers as spray primers. The reactive phosphate comprises a hydroxy -LQ-functional organophosphate which is present ~n the compo-sition as a mono- or diester or as a mixture of such mono-and diesters. The hydroxy functional organophosphate esters useful in the composition of the invention include those having the formula:
o (R-O)n P (OH)3-n wherein n = 1 to 2 and R is hydroxy substituted hydrocarbon, preferably selected from the group consisting of mono- or dihydroxy alkyl, cycloalkyl, or aryl radicals. Preferably the alkyl, cycloaIkyl, or aryl radicals contain 3 to 10 carbon atoms, and especially desirable are aliphatic or cycloaliphates radicals substituted by hydroxy, optionally interrupted by heteroatoms as oxy as ~ell as aryl.
Among the numerous suitable mono- or dihydroxy functional radicals are: 2-ethyl-3-hydroxyhexyl; 4-methylol-cyclohexylmethyl; 2,2 diethyl-3-hydroxypropyl; 8-hydroxy-octyl; 6-hydroxyhexyl; 2,2-dimethyl-3-hydroxy-propyl;
2-ethyl-2-methyl-3-hydroxypropyl; 7-hydroxyheptyl; S-hydroxypentyl; 4-methylolbenzyl; 3-hydroxyphenyl; 2,3 dihydroxypropyl; 5,6 aihydroxyhexyl; 2-(3-hydroxycyclohexyl) -2-hydroxy ethyl; and 2-(3-hydroxypentyl)-2-hydroxyethyl.
The abo~e radicals are intended to be only exemplary and numerous other radicals falling within the defined scope of the organophosphate esters useful in the compositions of the invention will be apparent to those skilled in the art. Among the most preferred radicals are mono- or dihydroxy functional alkyl radicals containing

3 to 10 car~on atoms.
A preferred method for preparing the hydroxy func-3~ tional organophosphate esters useful in the compositionsof the invention is by an esterification reaction between an excess of an alkyl, cycloalkyl or aryl diol or triol or mixture thereof and phosphorus pentoxiae. When a triol is used as a reactant, preferably at least one of the hydroxyl groups should be secondary. The reaction between the diol or triol and the phosphorus pentoxide is generally carried out by adding phosphorus pentoxide portionwise to an excess of diol or triol in a liquid state or in solution in a ~15267:~

suitable solvent. A preferred temperature for carrying out the reaction is between about 50C and about 60C. Due to the multiple hydroxy functionality of the diol or triol reactant, minor amounts of polymeric acid phosphate as well as certain cyclophosphates are also generated during the reaction. ~hese polymeric and cyclic materials also serve as a reactive catalyst and, therefore, need not-be separated from the hydroxyphosphate esters described a~ove. It is advantageous in preferred embodiments of the invention to employ all reaction products, i.e., the hydroxy functional organophosphate esters and the minor amount of polymeric acid phosphate cyclophosphates, as well as excess diol or triol in the crosslinking compositions. Excess diol or triol may serve in those compositions as all or a portion of the optional hydroxy functional additive. Reacti~e cata-lysts prepared by the above preferred method will generally include about a l to 1 ratio of the mono- and diester organ-ophosphate.
Still another preferred method of preparing the hydroxy functional organophosphate esters useful in composi-tions of the invention is by an esterification reaction be-tween phosphoric acid and an alkyl, cycloalkyl or arylmono-epoxide. This reaction is carried out by adding between about 1 and about 2 moles, preferably between about l and about 1.5 moles, of the monoepoxy material to l mole of phosphoric acid or its solution in a suitable solvent.
During the esterification reaction which occurs, a hydroxyl group is formed. If a dihydroxy radical is desired in the organophosphate ester, a monoepoxide bearing hydroxy func-tionality may be used as a reactant. Preferred monoepoxidematerials useful in this method are well known monoepoxides selected from monoepoxy ethers, monoepoxy esters and alkylene oxides. Exemplary of preferred monoepoxides for use in this esterification reaction are: propylene oxide, butylene oxide, cyclohexene oxide, styrene oxide, n-butylglycidyl ether and ethylglycidyl ether. As will be understood by those skilled in the art, the proportion of monoester and diester formed by the reaction will vary with the selected molar ratio of the monoepoxide and the phosphoric acid.

llSZ67~

When 1 mole of monoepoxide is used, per mole of phosphoric acid primarily monoester is formed while a molar ratio of 2 to 1 results in primarily diester. A molar ratio of 1.5 to 1 will result in an approximately 1 to 1 mixture o~ mono-S and diesters. In all cases a minor amount of the triesterwill be formed. While this triester obviously will not serve as a reactive catalyst, it will crosslink with the amino crosslinking agent of the composition and, thus, may be safely included.
The hydroxy functional organophosphate ester component of the crosslinking composition of the in~ention is a reactive catalyst which allows the composition to cure rapidly at a low temperature. The acid functionality of the mono- or diester or mixture of such esters reacts with the hydroxy reactive functionality e.g., amino resin crosslinking agent so as to include the reactive phosphate in the cross-linked network thereby not deleteriously effecting moisture resistance and, in some cases, improving corrosion resistance.

Primer Formulation The crossli~king compositions comprising epoxy reactant and amine reactant reaction product, amino resin crosslinking agent and optionally di or polyhydroxy compound may be formulated into a variety of primer formulations including those based on non-aqueous medium and water base medium. Such primers may be used as coatings for bare and treated steels (conversion coated with phosphates) as well as guide coats over previously deposited primers applied as by electrodeposition. Conventional modifying ingredients may be used in the primer formulations including, for example, flow control agents, pigment dispersants, thixotropes, anti-cratering aids, photostabilizers and the like.
1. Solvent Base Primers Solvent base primers exhibit good thermal and 3S shelf sta~ility and may be applied to metal substra~es according to usual techniques as by spray, curtain, dip and other such coating methods.

~ 1~2671 2. Water Base Primers -Water base primers are formulated from the cross-linking compositions as hereinbefore and hereinafter described. These water-based primers are made with at least partially neutralized epoxy amine reaction products.
The amino resin cross-linking agent is selected from water soluble and dispersible agents as also described and employed at similar levels. The water-based primers may be applied as spray primers and also can be electrodeposited. (See U.S. Patent No. 4,192,929 in the name of Robert Wingfield and assigned to Ford Motor Company).
Water-based spray primers are advantageously prepared in water compatible solvents and diluents as ethylene glycols and alkylated glycols, e.g. oxygenated solvents as Cellosolves*and Carbitols*and thereafter at least partially neutralized by acid, particularly weak organic acid as formic, acetic or butyric acid. Coupling agents may be advantageously employed.
Water-based spray primers can be formulated with high levels of water e.g., greater than 10~ as about 30-50% by weight and yet cure within conventional conditions as 180C for 20-30 minutes and even less with certain catalyst as reactive hydroxy phosphate catalyst as herebefore and hereinafter described.
It is found that particularly advantageous water-base spray primers may be formulated as stable emulsions when epoxy and amine reactants are reacted in water miscible solvent and the amine reactant comprises one or more water soluble amino alcohol up about 20 carbons, especially water soluble hydroxy alkyl amines, particularly secondary amines containing at least two primary hydroxy groups as diethanol amine and dipropanolamine.
Especially suitable water miscible solvents (water miscible as used herein means the solvent forms at 25C
a continuous phase with water when at 20% by weight of water or more) include as examples monohydroxy ethers as Cl-C6 etherified glycols as R(OCx ~ OH wherein R is alkyl from 1-8 * Trademarks carbons and x is 2-4 and y is 1-10 and particularly those which have boiling points below about 180C, e.g., 2-methoxy ethanol, 2-ethoxy ethanol, and propylene glycol monopropyl ether. Other suitable sol~ents include ethanol, propanol, isopropanol and the like. Higher boiling e.g.
above about 180C glycols may also be used as co-reactive solvents.
In a convenient method of making, a concentrate is made from reacting epoxy reactant and amine reactant in water miscible solvent and thereafter at least partially neutra-lizing with weak organic acid of up to 4 carbons as formic, acetic or oxalic acid in the presence of amino resin cross-linking agent to form a concentrate that may be thereafter readily dispersed in water for spraying.
Moreover, partially methylated or butylated melamine resins are preferred. Con~entional pigment dis-persants and other additives including silanes and organo-titanates may also be employed.
3. Alternative Embodiment - Multicomponent Coat-2~ ing Composition The epoxy and amine reactants along with the aminoresin crosslinking agent and, preferably, di or polyhydroxy compound, all as above described, may alternatively be reacted together on the substrate to be coated. Thus, in this embodiment the epoxy and amine reactants and desirably di or polyhydroxy compound (preferably having boiling points in excess of about 2005C) are intimately admixed and applied to the substrate to be coated and cured thereon. In this embodiment, however, the amine reactant can also comprise solely primary amine that is a hydroxy amine. The primary amine, however, is normally employed with di-epoxides.
Preferred primary amine, for this embodiment, that contain primary hydroxy are hydroxy lower al~yl amines as ethanol amine, propanolamine, pentanol amine and the like. If secondary amines that are hydroxy amines are employed, then such amines are preferably also lower hydroxy aliphatic amlnes as dialkanol amines containing up to 7 carbon atoms, e.g. diethanolamine or as lower alkyl hydroxy ~152671 aIkyl amines as 2-(methylamino)-ethanol.
In this embodiment, it is important for corrosion resistance properties that primer formulations are admixed shortly, e.g. within less than a few hours of but desirably greater than one half hour before application and cure.
Advantageously, uncatalyzed multicomponent crosslinking compositions may be cured within conventional curing sched-ules and, if desired, be accelerated by catalyst. On the other hand, it is important that the amino resin crosslink-ing agent and epoxy reactant not be permitted to stand for anundue length of time ~e.g. several weeks) prior to formu-lation with the amine reactant comprising primary amine and application to the substrate. Preferably, the multi-component system is applied to substrates between about 30-600 minutes after mixing.
As mentioned, this alternative multicomponent embodiment preferably also utilizes di- or polyhydroxy compound such that,~for example, the di- or polyhydroxy compound advantageously serves as reactive solvent which allows crosslinking compositions and ultimate coating compo-sitions as primers which have high solids content. Moreover, film properties as flexibility may be enhanced through incorporation o~ the di- or polyhydroxy compound. In this regard, glycols of the formula HO~CaH2aO~X-tCbH2bO~yH
wherein a and b are independently 2-6 and x and y are independently 2-10 wherein the sum of x and y is 2-10 are preferably employed.
The alternative multicomponent coating composition advantageously may be formulated into solvent base primer which may be applied in a variety of ways to the sub-strate as, for example, through dip, spray, curtain and li~e coatings.
The following examples are intended as illustrating some of the more preferred aspects and, accordingly, should not be considered 2S necessarily limiting the scope of invention. All degrees are in degrees Celsius and parts in parts by weight unless specified otherwise.

:L152671 EXAMPLE I
A heat curable coating composition suitable for automotive application is prepared from a bis-phenol A-epichlorohydrin epoxy resin, alkanolamine, and an amino resin cross-linking agent in the manner hereinafter set forth:
Part A Preparation of epoxy-alkanolamine resin Materials Parts by Weight Epon 1004(1) 625 Diethanolamine 70 Methyl amyl ketone 625 Butanol 200 Reactor Charge Diethanolamine 70 Methyl amyl ketone 625 (1) A product of Shell Chemical Company, which is a reaction product of epichlorohydrin and bis phenol-A and described such as being a solid with melting point 95-105C; Gardner-Holdt viscosity at 25C of Q-U(40% w soln in butyl Dioxitol(R)) Epoxide Equivalent 875-1000 (grams resin per gram-equivalent of ep~xide); Equivalent Weight (grams resin to esterify one mole acid) 175. (Data Sheet SC:69-58).
The reactor charge is heated to 70-80C in a reaction vessel equipped with a stirrer, reflux condenser, and thermometer. The Epon 1004 is added over a four hour period. The temperature is maintained at 70-~0C throughout the addition of the epoxy resin and for four hours there-after. The epoxy-alkanolamine resin so formed is then cooled to 50C and diluted with butanol. The resin is then cooled to room temperature, filtered and formulated into a primer as hereinafter described.
Part 3 Formulation of Primer Materials Parts by Weiqht Butylated melamine resin (RN 602*)(2) 46 Urea resin (RN 512*)(3) 6.7 Titanium dioxide pigment 15 Carbon black pigment 15 Silica pigment 11 8arytes pigment 102 * Trademarks Xylene 50 Epoxy-alkanolamine resin from part A 39~
An unpigmented primer is prepared by dissolving the epoxyalkanolamine resin, the butylated melamine and the urea resin in xylene and butanol. A mill base is then prepared using one-third of the unpismented resin and the pigments shown above. ~he remaining unpigmented primer is then added and thoroughly dispersed with the mill base.
The resulting fully formulated primer is filtered, applied to cold rolled, unphosphated steel panels by spraying and cured at 180C for 20 minutes. The cured coating displays excellent corrosion resistance in salt spray, good solvent resistance to xylene and good flexibility and hardness.
(2) Product of Mobil Chemical Company that is described as being butylated melamine formaldehyde resin with viscosity of V-X; 58% non-volatiles; Acid number 2 maximum; solvent n-butanol.
(3) Product of Mobil Chemical Company that is described as being butylated urea formaldehyde resin; viscosity W-Y; non-volatiles 50~ + 2~; ~cid number 3.5-4.5; Color Gardner~
max.; Solvent 80~ n-~utanol and 20~ ethyl-benzene.

EXA~PLE II
The procedures of Example I are repeated with the following difference: Epon 1001(1) replaces Epon 1004.
All other materials used in preparing the epoxy-alkanolamine resin and the fully formulated primer are the same in kind and quantity as in Example I.
Materials Parts by Wei~ht Epon 1001(1) 334 (1) Product of Shell Chemical Company which is described as a solid and having ~iscosity (Gardner Holdt) D-G, l.Q-1.7 poises (AS~MD-445) in 40% w soln. butyl Dioxitol( ); and Epoxide e~ui~alent 450-550.
Unphosphated steel panels coated with the fully formulated primer display excellent corrosion resistance to salt spray, good xylene solvent resistance, flexibility and hardness.

EXAMPLE III
The procedures of Example I are repeated with the following difference: Epon 828 replaces Epon 1004. All other materials used in preparing the epoxy-alkanolamine resin and the fully,formulated primer are the same in kind and quantity as in Example I.
Materials Parts by Weight Epon 828(1) 126 (1) Product of Shell Chemical Company which is described as a liquid and having a viscosity (ASTM D-445) 110-150;
Epoxide equi~alent 185-192; Gardner Color 3 max; lbs./gal.
(68C) 9.7.
Unphosphated steel panels coated with the fully formulated primer display excellent corrosion resistance to salt spray, good xylene sol~ent resistance, flexibility and hardness. Some sensiti~ity to condensing humidity is al80 observed.

EX~LE IV
The procedures of Example I are repeated with the following difference: Diethanolamine is replaced by 2-(methylamino) ethanol. All other materials used in preparing the epoxy-alkanolamine resin and the fully formulated primer are the same in ~ind and ~uantity as in Example I.
Materials Parts bv Weiqht -2-(methylamino) ethanol 49 Unphosphated steel panels coated with the full ~ormulated primer display excellent corrosion resistance to salt spray, good xylene solvent resistance, flexibility and hardness.

EXAMPLE V
A heat cura~le coating composition suitable for automotive application is prepared from an epoxy-al~anolamine resin, and an amino resin crosslinking agent. The epoxy-alkanolamine resin in this case is the condensation product between lowex molecular weight bis phenol A epichlorohydrin 3S epoxy resins and mixtures of ~rimary and secondary alkanoala-~152671 mines. ~esin preparation and primer formulation proceeds in the manner hereinafter set forth:
Part A Preparation of epoxy-alkanolamine resin MaterialsParts by Weight Epon 828'1) 190 Diethanolamine 52 Ethanolamine lS
Methyl amyl ketone200 Butanol 75 Reactor Charqe Diethanolamine 52 Ethanol~ln; ne 5 Methyl amyl ketone200 The reactor charge is heated to 70-80C in a 15 reaction vessel equipped wi'ch a stirrer, reflux condenser and thermometer. The Epon 828 is added over a one hour period. The temperature is maintained at 70-80C throughout the addition of the epoxy resin and for one hour thereafter.
I~e remaining portion of ethanol amine is then added and the 20 reaction is maintained at 70-80C for an additional one hour.
The epoxy-alkanolamine resin so formed is cooled to 50C
and then diluted with butanol. The resin is cooled to room temperature, filtered and formulated into a primer a3 hereinafter described.
25 Part B Formulation of Primer Materials Parts bY Weiqht ~poxy-alkanolamine resin from part A 532 Butylated melamine resin (RN602) (2) 69 Urea resin (~N512) (3) 10 Titanium dioxide pigment 23 Carbon b lack pigment 23 Silica 16 9arytes 153 Xylene 75 Butanol 113 The procedure for the pigmentation of the primer is the identical to the one employed in Example IB.

67~

(1) A product of Shell Chemical Company, see Example III.
(2), (3) Products of Mobil Chemical Company, see Example I.

EXAMPLE VI
A heat curable coating composition suitable for automotive application is prepared from a bis phenol A-epichlorohydrin epoxy resin, an alkanolamine, an amino resin crosslinking agent and glycol in the manner herein-after set forth:
Primer Formulation Materials Parts by Weight Epoxy-alkanolamine resin from 399 Example Ia Butylated melamine resin (RN602)(1) 80 15 Urea resin (~NS12)(~ 10 $riethylene glycol 40 Methyl amyl ketone 100 Butanol 100 Titanium dioxide pigment 15 20 Carbon black pigment 15 Silica pigment 11 Barytes pigment 102 The unpigmented primer is prepared by dissolving the epoxyalkanolamine resin, the butylated melamine resin, the urea resin and the triethylene glycol in xylene and butanol. The primer is pigmented in the manner described in Example Ib. The fully formulated primer is filtered, applied to cold rolled, unphosphated steel panels and cured at 180C for 20 minutes. The coating displays satisfactory corrosion resistance in salt spray.
(1~ See Example I, product of Mobil Chemical Company.
(2) See Example I, product of Mobil Chemical Company.

EXAMP~E VII
The proc~dures of Example VI are repeated with the following difference: hydrogenated bis phenol A is sub-stituted for the triethylene glycol. All other materials ;71 in preparing the fully formulated primer are the same in kind and quantity as in Example VI.
Materials Parts by Weight Hydrogenated bis-phenol A 20 Unphosphated steel panels coated with the fully formulated primer display excellent corrosion resistance, flexibility and hardness.
EXAMPLE VIII
The procedures of Example VI are repeated with the following difference: Poly bd R-45HT*, a hydroxy termin-ated poly butadiene resin, is substituted for the triethylene glycol. All other materials used in preparing the fully formulated primer are the same in kind and quantity as in Example VI.
r 15 Materials Parts by Weight C Poly bd R-45~ (1) 20 (1) a product of ARCO/Chemical Company, division of Atlantic Richfield Company.
Unphosphated steel panels coated with the fully formulated primer display excellent corrosion resistance, flexibility and hardness.
EXAMPLE IX
(a) Heat curable coating compositions suitable for automotive application are prepared in the manner discussed in Examples I-VIII with the exception that from 2.5% by weight of phosphoric acid is added to the primer. The inclusion of small amounts of acid catalyst lowers the cure temperatue.
(b) A heat curable coating composition suitable for automotive application is prepared from a bis-phenol-A-epichlorohydrin epoxy resin, alkanolamine, and an amino resin cross-linking agent in the manner hereinafter set forth:
Part A Preparation of Epoxy-alkanolamine Resin * Trademark r~

~15267~

Materials Parts by Weight Epon 1004(l) 625 Diethanolamine 70 Methylamyl ketone 625 Butanol 200 Reactor Charge Diethanolamine 70 Methyl amyl ketone 625 (1) Product of Shell Chemical Company, see Example I.
The reactor charge is heated to ~-80C in a reaction vessel equipped with a stir~er, reflux condenser, and thermometer. The Epon 1004 is added over a four hour period. The temperature is maintained at 7~-80~C throughout the addition of the epoxy resin and for four hours thereafter.
The epoxy-alkanolamine resin so formed is then cooled to 50C and diluted with butanol. The resin is then cooled to room temperature, filtered and formulated into a primer as hereinafter described.
Part B Formulation of Primer Materials Parts bY Weight Epoxy-alkanolamine resin from part A 39.9 Butylated melamine resin (RN602)(2) 4.6 Urea resin (RN512~(3) 0.67 Titanium dioxide pigment 15 25 C-Black pigment 15 Silica pigment 11 Barytes pigment 102 Xylene 50 Butanol 75 30 Reaction product of 2-ethyl-1,3-hexandi~)with P205 (1~ based on resin 0.23 An unpigmented primer is prepared by dissolving the epoxy-alkanolamine resin, the butylated melamine, the urea resin, and the reaction product of 2-ethy}-1,3-hexanediol with P2a5, in the butanol and xylene. A mill base is then prepared using one-third of the unpigmented primer and the pigments shown above. The remaining clear primer is then added and thoroughly dispersed with the mill ;7i base. The resulting fully formulated primer is filtered, applied to cold rolled, unphosphated steel panels by spraying and cured at 140C for 20 min. The cured coating displays excellent corrosion resistance in salt spray, good xylene solvent resistance, flexibility and hardness. (2), (3) Products of Mobil Chemical Company, see Example I. (4) Prepared as follows:
In a three-necked round bottom flask equipped with a stirrer dropping funnel and a thermometer are placed 2500 grams of dry (dried over molecular sieves) 2-ethyl-1,3-hexanediol. Phosphorus pentox-ide (450 grams) is added portionwise with continuous stirring and an exothermic reaction occurs. The addition of phosphorus pentoxide is regulated to maintain the temperature at 50C. After the addition is complete, the reaction mixture is stirred at 50C for one more hour and then filtered.
The acid equivalent weight by titration with medium hydroxide solution is found to be 357.
EXAMPLE X
This example illustrates that epoxy resins con-taining ester functionality should be avoided in preparing epoxy alkanolamine resins. In this example poor corrosion resistance of a primer coating is observed when Araldite Cy 179 is incorporated into the formulation.
Part A Preparation of epoxy-alkanolamine resin Materials Parts by Weight Araldite* Cyl79*(1) 126 Diethanolamine 105 Butanol 130 Reactor Charge Diethanolamine 105 Butanol 100 The reactor charge is heated to 70-80C in a reaction vessel equipped with a stirrer, reflux condenser * Trademarks 11526~

and thermometer. A solution of ~e Araldite Cyl79 in 30 parts of butanol is added dropwise. The temperature is maintained at 70-80C during the addition and for 20 hours thereafter. The resin is then cooled and formulated into a primer as hereinafter described.
Primer Formulation Materials Parts by Weight Epoxy-aIkanolamine resin from 67 X, Part A
Butylated melamine resin (RN602)(2) 3 Triethylene glycol 19 Ferric oxide pigment 4 Titanium dioxide pigment 4 15 Silica 3 Barytes 29 Butyl Acetate 15 Xylene 15 The unpigmented primer is prepared by dissol~ing the epoxyalXanolamine resin, the butylated melamine and the triethylene glycol in butyl acetate and xylene. The primer is pigmented in the manner described in Example Ia. The fully formulated primer is filtered, applied to cold-rolled, unphosphated steel and cured at 180C for 20 minutes.
Coatings obtained from this primer display very poor corro-sion resistance.
(1) A product of Ciba-Geigy Corp., an ester-linked diepoxide.
(2) See Example I, a product of Mabil Chemical Company.
Table of Results Set forth below in the Table are results obtained relative to certain of the above Examples. The tests con-ducted ase standard laboratory tests that are intended to determine properties of primer coatings. The test procedures are as follows: 24 hour salt spray test ASTMB 117-62, 64 Salt Spray Test; 10 day salt spray ASTMB 117-62, 64 Salt Spray Test for 240 hours; condensing humidity test com~ined ASTMD 2246 and 2247 com~ined humidity testing under continu-ous condensing humidity; cathodic alkaline resistance test ~5267~

as described by A. G. Smith and R. A. Dickie, Ind. Eng.
Chem., Prod. Res. Dev., 17(1), 45 (1978), a test in which the resistance of the coating to displacement/degradation by cathodically produced hydroxide is evaluated.
Epoxy Ester Primer Test (1) Ex. I Ex. II Ex. III Ex. IV Ex. VII Ex. X
A 3(2) 10 10 10 7(2) 10 o(2) B _ 9 8 NA(3) 9 C 10 9 7 2 NA(3) 8 9 D 3 10 10 10 9 lC 0 A is 24 ~our Salt Spray Test.
B is 10 Day Salt Spray Test.
C is Condensing Humidity (10 day exposure).
D is Cathodic Alkaline Resistance (8 hour exposure).
0-2 - Total delamination or swelling of coating 3-5 - Significant loss from the scribe line, or serious ~lushing or blistering of coating 6-8 - Little or no adhesion loss from the scribe line, but some minor amount of non-scribe failure; also slight blushing 9-10 - No or very slight adhesion loss (1) Tall oil modified, epon 828 epoxy ester primer which has been crosslinked with a melamine formaldehyde resin.
(2) Test discontinued at this point.
(3) Not available.
EXAMPLE XI
A multicomponent, heat curable coating composition suitable for automotive application is prepared from a bis phenol A-epichlorohydrin epoxy resin, alkanolamine, a glycol, and an amino resin crosslinking agent in the manner hereinafter set forth:
Part A Preparation of Unpigmented Primer Formulation Materials Parts by Weiqht Epon 828 (1) 34 Ethanolamine 12.2 Triethylene Glycol 19.4 Butylated melamine resin (2) 39 40 Xylene 30 ~1~267~

An unpigmented primer is prepared by dissolving the epoxy resin, the ethanolamine, the triethylene glycol and the butylated melamine resin is xylene. The mixture is thoroughly stirred for 45 min. during which time a slight temperature increase is observed. The primer is then applied to cold rolled, unphosphated steel panels by spray-ing and cured at 180C for 20 minutes. The cured coating displays excellent corrosion resistance in salt spray, good solvent resistance to xylene and good flexibility and hard-ness.
(1) See Example III, a product of Shell Chemical Company (2) See Example I, a product of Mobil Chemical Company Part B Preparation of FU11Y Formulated Primer Materials Parts bv Weiqht 15 Unpigmented primer formulation from 134.6 Part A
Titanium Dioxide pigment 4.1 Ferric Oxide pigment 4.1 Silica pigment 2.7 20 Barytes pigment 28.6 The freshly prepared unpigmented primer solution from part A is immediately combined with the titanium diox-ide, the ferric oxide, the silica, the barytes. The pigment is dispersed; the fully formulated primer is then filtered, and immediately applied to cold rolled, unphosphated steel panels by spraying. After curing at 180C for 20 minutes, the coating displays excellent corrosion resistance in salt spray and good solvent resistance.

EXAMPLE XII
The procedures of Example XI are repeated with the following difference: 2-(methyl amino)-ethanol replaces the ethanolamine. All other materials used in preparing the unpigmented primer and the fully formulated primer are the same in kind and quantity as in Example XI.
Materials Parts ~y Weight 2-(methyl amino)-ethanol 15 l~Z671 Unphosphated steel panels coated with the fully formulated primer display excellent corrosion resistance good xylene solvent resistance and flexibility.

EXAMPLE XIII
The procedures of Example XI are repeated with the following difference: 3-amino propanol replaces the ethanol ~;ne. All other materials used in preparing the unpigmented primer and the fully formulated primer are the same in kind and quantity as in Example XI.
Materials Parts by Weight 3-amino propanol 7.5 Unphosphated steel panels coated with the fully formulated primer display excellent corrosion resistance good xylene solvent resistance and flexibility.

EXAMPLE XI~
The procedures of Example XI are repeated with the following difference: Epon 1001 replaces Epon 828. All other materials used in preparing the unpigmented primer and the fully formulated primer are the same in kind and quantity as in Example XI.
Materials Parts bv Weiqht Epon 1001 (1) 50 Unphosphated steel panels coated with the fully formulated primer display excellent corrosion resistance, good xylene solvent resistance and flexibility.
(1) See Example II, a product of Shell Chemical Company.

EXAMPLE XV
This example illustrates that high levels of alkanol amines are re~uired for good coating properties for the multicomponent system. In this example poor corrosion resistance of a primer coating is o~served when ~oo high a le~el of a secondary alkyl amine is incorporated into the primer formulation.
Part A Preparation of UnPigmented Primer ~1~2671 MaterialsParts by Weight Epon 828 tl) 34 Triethylene Glycol 19.4 Ethanolamine 6.1 Diethylamine 7.3 Butylated Melamine resin (RN602) 39 (2) Xylene 30 The unpigmented primer is prepared by combining the epoxy resin, the triethylene glycol, the ethanolamine, the diethylamine and butylated melamine in xylene. Once homogeneous, the material in part A above is pigmented in the manner described in Example XIB. The fully formulated primer is applied to cold rolled, unphosphated steel panels and baked at 180C for 20 minutes. The coating which resulted was not satisfactorily cured.
(1) See Example III, a product of Shell Chemical Company.
(2) See Example I, a product of Mobil Chemical Company.

EXAMPLE XVI
This example illustrates that primers with poor corrosion resistance are obtained if the epoxy resin is reacted with only primary alkanolamine and glycol prior to formulation of the primer.
Materials Parts b~ Weiqht Epon 828 (1) 34 Triethylene glycol 19.4 Ethanolamine 12.2 Butylated melamine resin (RN602) 39 (2) Xylene 30 Methyl ethyl ketone 25 Butanol 40 eactor Charge Epon 828 ~1) 34 Triethylene glycol 19.4 Ethanol amine 12.2 Methyl ethyl ketone 12 ~15267~

The reactor charge is stirred in a reaction vessel equipped with a stirrer, reflux condenser and thermometer.
The solution is initially clear and of low viscosity. With-in 5-10 minutes of stirring, an exothermic reaction begins, and after 1 1/2 hours the temperature rises spontaneously to 60C. After cooling to room temperature the reactor charge consists of a very viscous material which is sub-se~uently diluted with butanol and xylene. The butylated melamine is added and the material is pigmented in the manner described in Example XIB. The fully formulated primer is applied to steel panels and cured in the manner previously described. The resulting coating has very poor corrosion resistance.
(1) See Example III, a product of Shell Chemical Company.
(2) See Example I, a product of Mobil Chemical Company.

EXAMPLE XVII
This example illustrates that the multicomponent primer should be aged for a csrtain period of time prior to application to metal panels. This example describes a variation of Example XI which affords coatings with poor corrosion resistance.
Part A Preparation of Pigmented ComPonent Materials Parts by Weight Epon 828 (1) 34 Triethylene Glycol 19.4 Butylated melamine resin (2) 39 Pigments from Example IB 39.S
Xylene 10 A pigmented component is prepared by thoroughly dispersing the pigments in the epoxy resin, triethylene glycol and the melamine. This pigmented component is stable for three months at room temperature.
Part B Two Component Primer System Materials Parts bv ~eight 35 Pigmented Component from Part A 141.9 Ethanolamine 12.2 A sprayable primer is obtained ~y thoroughly mixing the pigmented component from part A with the ethanolamine.

iZ671 The resulting primer is sprayed within 10 minutes and cured at 180 for 20 minutes. The resulting coating has poor corrosion resistance.
(1) See Example III, a product of Shell Chemical Company.
~2) See Example I, a product of Mobil Chemical Company.
EXAMPLE XVIII
The procedures of Example XVII are followed except thatafter addition of the ethanol amine the primer formulation is vigorously stirred for 45 minutes and then applied by spraying and cured at 180C for 20 minutes. The coating exhibits good corrosion resistance.
EXAMPLE XIX
The procedures of Example XI are followed except that hydrogenated bis-phenol A is used in place of the 15 triethylene glycol and satisfactory primer compositions are obtained.
EXAMPLE XX
The procedures of Example XI and XII are followed except that the following amino resin cross-linking agent is employed in place of the butylated melamine to form two other primer compositions: a glycol uril resin that is Cymel* 1170 (a product of American Cyanamid). In each case a satisfactory primer composition is obtained upon inclusion of an equivalent amount of the identified amino cross-linking agent.
EXAMPLE XXI
A heat curable water-based coating composition suitable for automotive application is prepared from epoxy-amine reaction product and amino resin cross-linking agent in the manner as hereinafter set forth:
Part A Preparation of ePoxy alkanol amine reaction product * Trademark ~l~Z671 Materials Parts bY Weight Epon 1004 (1) 405.27 Diethanol amine 45.41 Propasol P (2) 299.31 Reactor Charge Diethanol amine 45.41 Propasol P (2) 299.31 (1) See Example I, a product of Shell Chemical Company.
(2) A product of Union Car~ide Corporation - propylene glycol monopropylether.
The reactor charge is heated to 80-85C in a reaction vessel e~uipped with a stirrer, reflux condenser and thermometer. The Epon 1004 is added over a 2 hDur period. The temperature is maintained at 80-85C through-out the addition and for 16 hours th~reafter. The epoxy alkanol amine reaction product so formed is then cooled to room temperature and formulated into a water-~ased primer as hereinafter described:
Part B Preparation of Millbase Materials Parts by Weiqht Epoxy alkanol amine reaction product 160.00 from Part A
Propasol P 4t.04 Barytes pigment 115.64 25 Titanium dloxide pigment 15.84 Iron oxide 15.84 Silica 11.08 To 160 parts or the epoxy alkanol amine reaction product is added, 41.04 parts of Propasol P is added and then shaken for 30 minutes. A homogeneous solution is obtained. To this then the pigments as shown above are added and then shaken for 6 hoursO A ~egmann gauge reading of 6 to 7 is obtained. This is then used for preparation of fully formulated pigmented primer.
3; Fully Formulated Water-~ased ~rimer - Materials - Parts by Weight Mill~ase from Part B 79.6 Butylated melamine resin (RN602)(1) 2.4 Acetic acid 1.04 KR-55* (2) 0.40 Water (distilled) 69.30 The mill base is weighed into a stainless steel container. To this millbase is added the melamine resin and stirred well using a disperator. Then the Kr-55 coupling agent is added and mixed well. The acetic acid is weighed into 10 parts of water in a glass container and then added to the millbase, melamine resin and KR-55 mixture under stirring. The balance of water is then added in 10-15 minutes under vigorous stirring. The whole mixing is accom-plished in 15-20 minutes. The resulting fully formulated primer is filtered, applied to cold rolled, unphosphated steel panels by spraying and cured at 180C for 20 minutes.
The cured coating displays excellent corrosion resistance in salt spray, good solvent resistance to xylene and good flexibility and hardness.
(1) See Example I, a product of Mobil Chemical Company.
C (2) Ken-React TTMDTP-55~titanate coupling agent that is said to be tetra (2,2-diallyloxymethyl-1-butoxy) titanium di (di-tridecyl) phosphite, a product of Kenrich Petro-chemicals, N.J.
EXAMPLE XXIl The procedures of Example XXI are repeated except for the following difference: The KR-55 coupling agent is replaced by coupling agent KR-238S*(l) at an equal weight level with all other materials being the same in kind and quantity.
~nphosphated sheet panels coated with the pigmented primer of this example display excellent corrosion resistance to salt spray, good xylene solvent resistance, flexibility and hardness.
(1) di (dioctyl pyrophosphate) ethylene titanate, a product of Kenrich Petrochemicals, N.J.
EXAMPLE XXIII
The procedures of Example XXI are repeated except for the following difference: The titanate coupling agent * Trademarks ~1~i;2~71 KR-55 is replaced by the hydroxy phosphate of Example IX
(b) and the level of melamine resin is increased to 4.8 parts by weight. All other materials are the same in kind and quantity in Example XXI.
Unphosphated steel panels coated with the fully pigmented primer display excellent corrosion resistance, good xylene resistance, flexibility and hardness.
EXAMPLE XXIV
The procedures for Example XXI are repeated with the following differences: The millbase is prepared with 30.5 parts of Propasol P instead of 41.04 parts and the fully pigmented primer contained higher level of water.
The ingredients remain the same in kind.
Part B Preparation of Millbase Materials Parts by Weight Epoxy-alkanol amine reaction product 160.00 from Part A, Example XXI
Propasol* P (1) 30.50 Barytes 115.64 20 Titanium dioxide 15.84 Iron oxide ~15.84 Silica 11.08 It is mixed as in Part B, Example XXI.
Fully Formulated Primer Materials Parts by Weight Millbase from Part B 87.2 Melamine resin (RN602) (2) 2.4 Acetic acid 1.39 KR-55 (3) 0.40 Water 94.40 Unphosphated steel panels coated with the fully pigmented primer display excellent corrosion resistance to salt spary, good xylene solvent resistance, flexibility and hardness.
(1) See Example XXI, a product of Union Carbide Corporation.
(2) See Example I, a product of Mobil Oil Chemical Company.
(3) See Example XXI, Titanate coupling agent.

,~ * Trademark ,~

~i2671 EXAMPLE XXV
The procedures for Example XXIV are repeated with the following difference: Titanate coupling agent is replaced by titanate coupling agent KR-238S (Ken-React a product of Kenrich Petrochemicals and is said to be di-(dioctylpyrophosphato) ethylenetitanate). All other materialsused ir. preparing the epoxy alkanol amine resin and the fully formulated primer are same in kind and quantity as in Example XXIV.
Materials Parts by Weight KR-238S (1) 0.4 Unphosphated steel panels combed with the fully pigmented primer display excellent corrosion resistance to salt spray, good xylene solvent resistance, flexibility and hardness.

EXAMPLE XXVT
The procedures of Example XXIV are repeated with the following difference: Titanate coupling agent K~-55 is replaced by hydroxy phosphate and the level of the melamine resin is increased. All other materials used in preparing the epoxy-al~anol amine resin and the fully formulated primer are the same in kind and ~uantity as in Example XXI.
Materials Parts by Weight Hydroxy phosphate tl) 0.24 ~utylated melamine resin (~602) 4.80 (2) Unphosphated steel panels coated wi~ the fully pigmented primer display excellent corrosion resistance to salt spray, good xylene solvent resistance, flexi~ility and hardness.
(1) Made in accordance with Example IX(b).
(2) A product of Mobil Chemical Company, see Example I.

EXAMPLE XXVII
(a) A heat curable water based coating composition suitable for automotive application is prepared from a ~L:15Z~à71 bis-phenol A epichlorohydrin epoxy resin, alkanol amine and an amino resin crosslinking agent in the manner herein-af~er set forth:
Part A Preparation of epoxy alkanol amine resin Materials Parts bY Weight Epon 1004(1) 312.34 Diethanolamine 35.00 Propasol P (2) 230.68 (1) See Example I, a product of Shell Chemical Company.
(2) See Example XXI, a product of Union Carbide Corporation.
To the mixture of diethanol amine and Propasol P
in a 3-necked flask equipped with reflux condenser and thermometer, Epon 1004 was added in small portions over a period of 2 hours at a reflux temperature of 95-100C. It was then refluxed for another 18 hours at that temperature.
Part B Formulation of Primer Materials Parts by Weight Epoxy-alkanol amine resin from Part A 40.00 Melamine resin (RN602) 4.80 Propasol P 16.30 Titanium dioxide pigment 4.40 Iron oxide pigment 4.40 Silica pigment 3.08 25 Barytes pigment 32.40 Glacial acetic acid 1.04 Distilled water 73.94 Preparation of the Millbase To one-third ~13.3 parts) of the epoxy alkanol amine resin is added, one-third (1.6~ parts) o~ the melamine resin followed by all of (16.30 parts) of Propasol P; pig-ments are dispersed in this mixture by ball milling.
Preparation of the Complete Primer To the millbase is added the balance ~2~.7 parts) of the epoxy alkanol amine resin is added followed by the balance ~3.2 parts) of the butylated melamine resin. Then 1.04 parts of glacial acetic acid, the amount re~uired to achieve 75% neutralizat_on of the epoxy alkanol amine resin, ~iZ671 in 10 parts of distilled water is added slowly with stirring.
The balance of the water is then added gradually under vigorous stirring over a period of 5 minutes. The resulting fully formulated primer is filtered, applied to cold rolled, unphosphated steel panels by spraying and cured at 180C
for 20 minutes. The cured coating displays excellent corrosion resistance in salt spray, good solvent resistance to xylene and good flexibility and hardness.
(b) Following the procedures of Examples XXVII(a), the melamine resin (RN602) is replaced by the same parts by weight of LTX-127* (a product of Monsanto which is a partially methylated melamine) and equivalent film proper-ties are achieved and the fully formulated primer exhibits superior dispersion stability as compared to the primer of (a).
(c) Following the procedures of Example XXVII(a), the melamine resin (RN602) is replaced by equal parts by weight of Cymel 1141 (a product of American Cyanamid) and equivalent film properties are obtained and the fully formu-lated primer exhibits superior dispersion stability ascompared to the primer of (a).

* Trademark

Claims (5)

The embodiments of the present invention in which an exclusive property or privilege is claimed are defined as follows:

1. A solvent based primer composition that retards corrosion in substantial absence of chromate corrosion inhibiting pigments which comprises an intimate admixture of film forming ingredients consisting essentially of:
(A) a substantially gel free epoxy and amine reaction product which contains no ester linkages and which is made by reacting in non-aqueous medium reactants consisting essentially of:
(1) a non-ester linked epoxy reactant that contains an average of at least about two terminal epoxy groups per molecule and is a bis-phenol-A reaction product having an epoxide equivalent of at least about 875;
(2) an amine reactant selected from the group consisting of secondary monoamines having a total of up to about 20 carbons, and comprising at least about 75 mole percent hydroxy amine containing one or more hydroxy groups removed at least one carbon from the amino nitrogen In an equivalent amount such that the reaction product (A) comprises tertiary amino and primary and secondary hydroxy groups and is substantially free of unreacted epoxy groups;
(B) optionally, a di- or polyhydroxy compound;
and (C) an amino aldehyde resin crosslinking agent at about 5 to 35% by weight of the combined weight (A) and (B).

2. The primer composition of claim 1, wherein the amine reactant is a dialkanol amine.

3. The composition of Claim 1 or 2, wherein the amino resin crosslinking agent comprises alkylated melamine or urea resin or both.

4. The composition of Claim 1, wherein (B) is present and comprises glycol.

5. The composition of Claim 2, wherein secondary amine comprises a di-lower alkanol amine having a total of up to about 7 carbons.