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CA1081641A - Process and apparatus for heating and deaerating raw bituminous froth - Google Patents

Process and apparatus for heating and deaerating raw bituminous froth

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Publication number
CA1081641A
CA1081641A CA270,082A CA270082A CA1081641A CA 1081641 A CA1081641 A CA 1081641A CA 270082 A CA270082 A CA 270082A CA 1081641 A CA1081641 A CA 1081641A
Authority
CA
Canada
Prior art keywords
froth
zone
conduit
deaeration
inlet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA270,082A
Other languages
French (fr)
Inventor
Thomas C. A. Hann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suncor Energy Inc
Original Assignee
Suncor Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suncor Inc filed Critical Suncor Inc
Priority to CA270,082A priority Critical patent/CA1081641A/en
Application granted granted Critical
Publication of CA1081641A publication Critical patent/CA1081641A/en
Expired legal-status Critical Current

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Abstract

PROCESS AND APPARATUS FOR HEATING AND
DEAERATING RAW BITUMINOUS FROTH

ABSTRACT OF THE DISCLOSURE
In order to collect, heat and deaerate raw bituminous froth prior to upgrading that froth to synthetic crude oil, a central collection zone is provided for collecting the raw froth which is transferred therefrom to a deaeration zone by means of a conduit having a plurality of steam injection means disposed therein and oriented to urge the froth toward the deaeratior zone. The deaeration zone may include a plurality of baffles across which the heated froth is distributed in order to facilitate the release of gases as the froth spills over the baffles. An outlet in a lower portion of the deaeration zone permits transfer by pumping or other means for further treatment of the froth.

Description

-`-`` 10~31641 BACKG~OUND OF THE INVENTION

The present invention is re].ated to apparatus suitable for collecting, heating and deaerating raw bituminous froth prior to upgrading that froth to synthetic crude oil.
Tar sands, which are also known as oil and bituminous sands, are siliceous materials which are impregnated with a heavy petroleum. The largest and most important deposits of the sands are the Athabasca sands, found in northern Alberta, Canada. These sands underlay more than 13,000 square miles at a depth of O to 2,000 feet. Total recoverable reserves after extraction and processing are estimated at more than 300 billion barrels. Tar sands are primarily silica, having close-ly associated therewith an oil film which varies from about 5 to 21% by weight, with a typical content of 13 weight percent of the sand. The oil is quite viscous -- G to 10 API gravity ---~i and contains typically 4.5% sulfur and 38% aromatics. In addition to the oil and sand components, tar sands contain clay :
and silt in quantities of 1 to 10% by weight, in the form of a film around the sand grains.
Several basic extraction methods have been known for many years for the separation of oil from the sands. In the so-called "cold water" method, the separation is accomplished by mixing the sands with a solvent capable of dissolving the bitumen constituent. The mixture is then introduced into a large volume of water, water with a surface agent added, or a -: solution of a neutral salt in water, which salt is capable of acting as an electrolyte. The combined mass is then subjected to a pressure or gravity separation.

In the hot water method, as disclosed in Canadian Patent No. 841,581 issued May 12, 1970, the bituminous sands : .
~' ` 1~8~641 are jetted with steam and mulled wlth a minor amount of hot water at temperatures of 170 to 190F, and the resulting pulp is then dropped into a turbulent stream of circulating hot water and carried to a separation cell maintained at a temper-ature of about 185F. In the separation cell, sand settles to the bottom as tailings and oil rises to the top in the form of a froth. An aqueous middlings layer comprising clay and silt and some oil is formed between these layers. This basic pro-cess may be combined with a scavenger step for further treat-ment of the middlings layer obtained from the primary separationstep to recover additional amounts of oil therefrom.
The bituminous froth produced by this process is recov-ered at a temperature in the range of about 140 to 180 F and normally has a specific gravity in the range of 0.85 to 0.95.
Generally the froth contains 30 to 70 volume percent air.
In recovering bituminous froth utilizing the process disclosed in Canadian Patent 841,581 and the hot water separa-tion cell disclosed in Canadian Patent No. 882,667 issued October 5, 1971, the froth is recovered in overflow launders disposed on the upper edge of the extrac-tion cell. Thereafter, the froth flows by gravity into a collection vessel located near the separation cell below the level of the froth collection launders. Often, one collection vessel serves four or more separation cells at the same time to provide a central collec-tion means for recovered froth. Froth from secondary scavenger steps as disclosed in the above-noted hot water process can also be collected in this same vessel. Thereafter, the froth is heated and transferred to a centrifuge zone or other means of demineralizing and dehydration. Normally, the froth is 30 diluted with a liquid hydrocarbon before the demineralization and dehydration steps. Methods of accomplishing water and ~`
.

:' mineral removal from the froth are disclosed in Canadian Patent No~s. 910,271 issued September 19, 1972 and 918,091 issued January 2, 1973.
Raw bituminous froth as recovered from the hot water extraction cell resembles a liquid foam containing minerals, water and air and having poor flow characteristics. The froth is difficult to pump and therefore must be treated to improve its liquid flow characteristics if it is to be processed in a reasonable manner. Canadian Patent No. 630,710 issued November 7, 1961 discloses that bituminous froth can be col-lected and transferred to a deaeration zone where it is heated with steam at subatmospheric pressures to remove air bubbles-from the froth. This end can be accomplished by adding the froth to a steam heated oil bath maintained at subatmospheric pressure. The froth is therein diluted with oil and agitated to aid in freeing air bubbles from the froth. Although this method improves the froth, transferring the froth to the treat-ment apparatus disclosed renders the process cumbersome. By the method of the present invention the processing of bituminous froth is improved.

DESCRIPTION OF THE INVENTION

The present invention relates to a method and apparatus for processing bituminous froth recovered via the hot water ex-traction of bitumen from tar sands. Specifically, the present invention provides a method and apparatus for heating and de-, aerating raw bituminous froth to provide a product suitable for processing to obtain synthetic crude oil.
Raw bituminous froth normally contains 30 to 70 volumepercent air and is reasonably viscous at the temperature at 10816~1 which it is normally recovered, i.e., 120 to 180F. There-fore, it is very difficult to transfer froth by ordinary methods such as pumping. However, if the froth is heated, and deaerated and diluted with a less viscous hydrocarbon liquid prior to transferring the froth from the recovery area, the treated froth is substantially easier to upgrade to syn-thetic crude oil. The present inventi.on includes a method - and apparatus to provide a heated deaerated bitumen froth pro-duct.
Specifically, the apparatus of the present invention comprises a central collection zone for collecting the raw bituminous froth obtained by the hot water extraction of tar :
sands; a conduit which communicates with the collection zone and a deaeration zone; and finally a deaeration zone wherein the heated froth is deaerated and admixed with a hydrocarbon diluent.
The collection zone can comprise a tank preferably with inlet means at or near the top of the tank and an outlet means at or near the bottom of the tank to utilize gravity as an aid in transferring froth from the tank.
The heating conduit provides a means of transferring the froth from the collection zone while concurrently heating the froth to aid in collapsing the air pockets in the froth and releasing entrapped air therefrom. The conduit can be a pipe or tube having one end, the inlet end, communicating with the outlet of the collection zone and the opposite end, the outlet, communicating with the inlet of the deaeration zone. The con-duit contains steam injection means disposed within the conduit by which steam under pressure is injected into the froth in a manner so that the force of the steam propels the froth in the conduit in the direction of the outlet o-f the conduit. Con-currently the froth is heated while being transferred in the conduit.
The deaeration zone can comprise a vertical tank having an inlet in the upper end thereof communicating with the out-let of the heating conduit. The deaeration zone can have an open top or a top with a means for venting gases from the tank. Also, the deaeration zone contains a means for adding liquid hydrocarbon diluent and a means for withdrawing diluted froth. An essential feature of the deaeration zone is a dis-tributor means located adjacent to the inlet in the top of the tank. The distribution means provides for the distribution o e the heated froth over a majority of the cross section of the de-aeration zone to facilitate release of gases from the froth.
Located below the distribution means in the deaeration zone are baffles which aid in froth deaeration also.
As a means for providing a more detailed description of one mode of the apparatus of the present invention, the figure in the drawing is presented. Referring to the figure, bitumin-ous froth contain:ing 30 to 70% by volume O:e air is -transferred from hot water extraction separation cells 10 to collection zone 12 via lines 11 and 14 respectively. The froth is quite viscous at 150F having a viscosity of about 2000 centipoise.
The froth flows by gravity to collection zone 12. Froth collection zone 12 can be any vessel suitable for storing liquids which has an inlet and an outlet for the addition and withdrawal of liquids. Preferably the inlet 27 is located in the upper part of zone 12 and the outlet 26 is located in the lower section thereof. By this arrangement withdrawal of liquids from the zone can be aided by gravity.

8:1641 Communicating with the outlet 26 or zone 12 is conduit 13 wherein the froth is heated and transferred to deaeration zone 20. Conduit 13 can be a pipe or tube suitable for trans-porting liquids. Disposed within conduit 13 are steam in-jection means 18 which can be any nozzle suitable for providing steam under pressure into conduit 13. Steam injection means 18 are positioned in conduit 13 to provide steam under pressure directed towards the outlet end of the conduit thereby pro-pelling the froth through the conduit while concurrently heating the froth. Steam is supplied by injection means 18 via lines 15, 16 and 17 respectively.
As noted above, the inlet end of conduit 13 communicates with the outlet 26 of zone 12. The outlet of conduit 13 com-municates with the inlet means of deaeration zone 20 at inlet 25. Conduit 13 can be parallel to the plane of the horizontal axis or can be disposed at an angle of up to 10 from the horiz-ontal axis with the outlet of the conduit being above the inlet thereof. When a liquid such as bituminous froth is heated in conduit 13 the entrapped air rises to the upper section in the conduit and tends to migrate to the highest level in the con-duit. Thus, preferably the conduit has its outlet raised higherthan the inlet to promote flow of gas pockets in the direction of the outlet rather than in the inlet direction.
Deaeration zone 20 can be any tank or other facility suitable for storing liquids having an inlet means 25 in the upper end thereof and a liquid withdrawal means 22 at the lower :
end thereof. Also zone 20 can be an open top tank or have a top with a vent 19 as illustrated in the figure. Disposed in the upper end of deaeration zone 20 is distributor means 23, which serves to disperse the froth preferably over the entire cross section of deaeration zone 20 thereby permitting the .

108~641 froth to cascade down over baffles 21 into the lower section of deaeration zone 20. Distribution means 23 can be any of the various structures such as a box with a perforated bottom or a series of channels having weirs whereby the froth overflows the weir onto the baffles 21 therebelow.
Air bubbles formed in the froth as a result of the steam injection are released from the froth as it cascades over the baffles in zone 20. The heated deaerated froth thereafter collects in the lower section of zone 20 wherein it can be admixed with a liquid hydrocarbon diluent from line 24 and thereafter transferred by pumping or other means for further processing via exit line 22.
Thus, the present invention comprises an apparatus for transferring, heating and deaerating bituminous froth recovered from the hot water extraction of bitumen from tar sands com-prising in combination:
a) a froth collection zone comprising a tank having an inlet and an outlet;
b) a froth deaeration zone comprising a tank having an inlet means in the upper section thereof and an outlet means in the lower section thereof; a distribution means located in the upper section of said tank and communicating with said inlet means whereby incoming froth is distributed over the cross section of the tank; a plurality of de-flecting baffles located below said distribution means and above said outlet means; and c) a conduit for heating and transferring bituminous froth comprising a tube having an inlet communicating with the outlet of said froth collection zone and .

``.. ` ~0~1641 an outlet communicating with the inlet of said froth deaeration zone said conduit having steam injecting means disposed therein, the outlet of said steam injection means being disposed to direct steam to the outlet end of said conduit to thereby concurrently heat and pump froth in said conduit from the inlet to the outlet end thereof.
The improvement realized in the apparatus and method of the present invention substantially lies in the transfer of -~
the froth via injected steam propulsion from the collection zone to the deaeration zone through the novel heating transfer conduit. Also, the deaeration zone provides efficient release of entrapped gases from the froth by the cascading effect achieved through the distribution means within the deaeration zone. The distribution means within the deaeration can be any arrangement which disperses the heated froth over the cross section of the deaeration zone. Various arrangements on struc-tural configurations of baffles within the deaeration zone can be employed within the concept of the present invention.
The present invention also comprises that in a method for heating and deaerating bituminous froth containing up to 70 volume percent occluded air, said method comprising collec-ting the froth in a collection zone and subsequently deaerating the froth in a deaeration zone, the improvement which comprises transferring the froth from the collection zone to the deaeration zone through a conduit wherein the froth is contacted with steam directionally provided to cause the froth to flow from the collection zone to the deaeration zone, said steam concurrently heating the froth to cause formation of gas pockets therein, thereby effecting improved deaeration in said deaeration zone.

~08~64~

The present invention also provides that in an apparatus for processing bituminous froth containing a froth collection zone and a deaeration zone, the improvement which comprises a conduit having one end co~lmunicating with said collection zone and the opposite end communicating with said deaeration zone, said conduit having disposed therein steam injection means positioned to inject steam under pressure into said conduit - in the direction of said deaeration zone to cause fluid materials in said conduit to flow from said collection zone to said de-aeration zone.

Claims (3)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. In a method for heating and deaerating bitum-inous froth containing up to 70 volume percent occluded air, said method comprising collecting the froth in a collection zone and subsequently deaerating the froth in a deaeration zone, the improvement which comprises trans-ferring the froth from the collection zone to the de-aeration zone through a conduit wherein the froth is contacted with st?eam directionally provided to cause the froth to flow from the collection zone to the deaera-tion zone, said steam concurrently heating the froth to cause formation of gas pockets therein, thereby effect-ing improved deaeration in said deaeration zone.
2. An apparatus for processing bituminous froth recovered from the hot water extraction of bitumen from tar sands comprising in combination:
a. a froth collection zone comprising a tank having an inlet and an outlet;
b. a froth deaeration zone comprising a tank having an inlet means in the upper section thereof and an outlet means in the lower section thereof, a distribution means loca-ted in the upper section of said tank and communicating with said inlet means whereby incoming froth is distributed over the cross section of the upper section of the tank; a plurality of deflecting baffles located below said distribution means and above said out-let means; and c. a conduit for heating and transferring bituminous froth from said collection zone to said deaeration zone comprising a tube having an inlet communicating with the outlet of said froth collection zone and an outlet communicating with the inlet of said froth deaeration zone said conduit having steam injection means disposed there-in, the outlets of said steam injection means being disposed to direct steam to-ward the outlet end of said conduit to thereby concurrently heat and pump froth in said conduit from the inlet to the out-let end thereof.
3. In an apparatus for processing bituminous froth containing a froth collection zone and a deaeration zone, the improvement which comprises a conduit having one end communicating with said collection zone and the opposite end communicating with said deaeration zone, said conduit having disposed therein steam injection means positioned to inject steam under pressure into said conduit in the direction of said deaeration zone to cause fluid materials in said conduit to flow from said collection zone to said deaeration zone.
CA270,082A 1977-01-20 1977-01-20 Process and apparatus for heating and deaerating raw bituminous froth Expired CA1081641A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA270,082A CA1081641A (en) 1977-01-20 1977-01-20 Process and apparatus for heating and deaerating raw bituminous froth

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA270,082A CA1081641A (en) 1977-01-20 1977-01-20 Process and apparatus for heating and deaerating raw bituminous froth

Publications (1)

Publication Number Publication Date
CA1081641A true CA1081641A (en) 1980-07-15

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5223148A (en) * 1991-11-08 1993-06-29 Oslo Alberta Limited Process for increasing the bitumen content of oil sands froth
US6800116B2 (en) 2002-05-23 2004-10-05 Suncor Energy Inc. Static deaeration conditioner for processing of bitumen froth
US7914670B2 (en) 2004-01-09 2011-03-29 Suncor Energy Inc. Bituminous froth inline steam injection processing
WO2012126113A1 (en) * 2011-03-22 2012-09-27 Fort Hills Energy L.P. Process for direct steam injection heating of oil sands slurry streams such as bitumen froth
US9676684B2 (en) 2011-03-01 2017-06-13 Fort Hills Energy L.P. Process and unit for solvent recovery from solvent diluted tailings derived from bitumen froth treatment
US10041005B2 (en) 2011-03-04 2018-08-07 Fort Hills Energy L.P. Process and system for solvent addition to bitumen froth
US10125325B2 (en) 2011-02-25 2018-11-13 Fort Hills Energy L.P. Process for treating high paraffin diluted bitumen
US10226717B2 (en) 2011-04-28 2019-03-12 Fort Hills Energy L.P. Method of recovering solvent from tailings by flashing under choked flow conditions
US10954448B2 (en) 2017-08-18 2021-03-23 Canadian Natural Resources Limited High temperature paraffinic froth treatment process
US11261383B2 (en) 2011-05-18 2022-03-01 Fort Hills Energy L.P. Enhanced temperature control of bitumen froth treatment process

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5223148A (en) * 1991-11-08 1993-06-29 Oslo Alberta Limited Process for increasing the bitumen content of oil sands froth
US6800116B2 (en) 2002-05-23 2004-10-05 Suncor Energy Inc. Static deaeration conditioner for processing of bitumen froth
US7914670B2 (en) 2004-01-09 2011-03-29 Suncor Energy Inc. Bituminous froth inline steam injection processing
US8685210B2 (en) 2004-01-09 2014-04-01 Suncor Energy Inc. Bituminous froth inline steam injection processing
US10125325B2 (en) 2011-02-25 2018-11-13 Fort Hills Energy L.P. Process for treating high paraffin diluted bitumen
US9676684B2 (en) 2011-03-01 2017-06-13 Fort Hills Energy L.P. Process and unit for solvent recovery from solvent diluted tailings derived from bitumen froth treatment
US10988695B2 (en) 2011-03-04 2021-04-27 Fort Hills Energy L.P. Process and system for solvent addition to bitumen froth
US10041005B2 (en) 2011-03-04 2018-08-07 Fort Hills Energy L.P. Process and system for solvent addition to bitumen froth
US9791170B2 (en) 2011-03-22 2017-10-17 Fort Hills Energy L.P. Process for direct steam injection heating of oil sands slurry streams such as bitumen froth
WO2012126113A1 (en) * 2011-03-22 2012-09-27 Fort Hills Energy L.P. Process for direct steam injection heating of oil sands slurry streams such as bitumen froth
US10226717B2 (en) 2011-04-28 2019-03-12 Fort Hills Energy L.P. Method of recovering solvent from tailings by flashing under choked flow conditions
US11261383B2 (en) 2011-05-18 2022-03-01 Fort Hills Energy L.P. Enhanced temperature control of bitumen froth treatment process
US10954448B2 (en) 2017-08-18 2021-03-23 Canadian Natural Resources Limited High temperature paraffinic froth treatment process

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