BR112020020409B1 - COMPOSITIONS WITH INTENSIFIED DEPOSITION OF ANTI-DANDDRESS AGENTS SOLUBLE IN SURFACTANT - Google Patents

Abstract

COMPOSITIONS WITH INTENSIFIED DEPOSITION OF ANTI-DANDDRESS AGENTS SOLUBLE IN SURFACTANT. The present invention relates to a hair treatment composition directed at 8 to 16% of one or more surfactants; 0.01% to 10% of one or more surfactant-soluble antidandruff agents; 0.01 to 5% of one or more cationic polymers having a molecular weight (MW) of about 250,000 to about 2,600,000 g/mol and a charge density (CD) of about 0.25 to about 7 .0 meq/g; where CD + 8x10 -7*MW - 1.5 = 0 and where the composition has a deposition efficiency of about 1.4X to about 3X that of a control composition, where the control composition comprises 14 % SLE1S, no polymeric constituents, 1% surfactant soluble anti-dandruff at a pH of about 6.

Description

FIELD OF THE INVENTION

[0001] The present invention relates to hair care compositions containing lower levels of surfactant in combination with one or more cationic polymers of a given molecular weight and charge density, providing a soluble agent deposition benefit.

BACKGROUND OF THE INVENTION

[0002]For years, anti-dandruff shampoos have been widely used for treating dandruff and cleaning the hair and scalp, but there still remains a need for optimized anti-dandruff shampoos. In general, anti-dandruff shampoos are formulated with anti-dandruff agents in combination with surfactants and aqueous systems that are designed to deposit the anti-dandruff agents on the scalp. Anti-dandruff agents can be insoluble particulates such as zinc pyrithione and/or surfactant-soluble substances such as climbazole or octopirox. Many anti-dandruff shampoos use cationic polymers with anionic surfactants to form coacervates that aid in the deposition of insoluble particulate agents such as silicone droplets or zinc pyrithione. Most often, the coacervate is formed upon dilution of the shampoo, and as it forms, it traps the insoluble particulate agents. As the coacervate deposits on the hair and scalp, the trapped insoluble particulate agents, in turn, are also deposited.

[0003] However, it was thought that coacervates did not affect the deposition of soluble agents, as soluble agents are soluble within the continuous surfactant phase of the shampoo, making it difficult to become trapped in coacervates as they form upon dilution of the shampoo. shampoo. Therefore, it can be difficult to deposit much more than the 1 to 2% of the soluble agents present in anti-dandruff shampoos on the scalp while the remaining 98 to 99% of the soluble agents in the formulas are rinsed off. Since many of the anti-dandruff agents can be relatively expensive, allowing >97% of the soluble agents to be rinsed out is equivalent to throwing money away, and thus there is a need for a shampoo that can more efficiently deposit soluble anti-dandruff agents. Furthermore, as consumers continue to desire a shampoo that offers superior anti-dandruff efficacy and lower deposition of the anti-dandruff agent results in inferior anti-dandruff efficacy, there remains a need for a shampoo that can deposit a higher percentage of soluble agents present on the scalp. in anti-dandruff shampoos.

[0004] It has surprisingly been found that a hair care composition containing lower levels of surfactant in combination with one or more cationic polymers having a molecular weight of from about 250,000 to about 2,500,000 g/mol, and a charge density of about 0.25 to about 7.0 meq/g, and where the polymeric charge density plus 8x10-7 times the molecular weight minus 1.5 is greater than or equal to zero, provides a benefit of soluble agent deposition.

SUMMARY OF THE INVENTION

[0005] A hair treatment composition directed at 8 to 16% of one or more surfactants; 0.01% to 10% of one or more surfactant-soluble antidandruff agents; 0.01 to 5% of one or more cationic polymers having a molecular weight (MW) of about 250,000 to about 2,600,000 g/mol and a charge density (CD) of about 0.25 to about 7 .0 meq/g; where CD + 8x10-7*MW - 1.5 > 0 and where the composition has a deposition efficiency of about 1.4X to about 3X that of a control composition, where the control composition comprises 14 % SLE1S, no polymeric constituents, 1% surfactant soluble anti-dandruff at a pH of about 6.

DETAILED DESCRIPTION OF THE EMBODIMENTS OF THE INVENTION

[0006]All percentages and ratios used in this document are expressed in weight of the total composition, except where otherwise indicated. All measurements are understood to be taken under ambient conditions, where "ambient conditions" means conditions at about 25°C, under about one atmosphere of pressure and about 50% relative humidity, unless otherwise indicated. All numerical ranges include narrower ranges; the delineated upper and lower swath boundaries are combinable to create additional swaths not explicitly delineated.

[0007] The compositions of the present invention may comprise, consist essentially of, or consist of essential ingredients as well as optional ingredients described herein. For use in the present invention, the expression "consists essentially of" means that the composition or component may contain additional ingredients, but only if these do not substantially alter the basic and novel characteristics of the claimed compositions or methods.

[0008] "Applying" or "application" as used in reference to a composition means applying or spreading the compositions of the present invention onto a keratinous tissue such as hair.

[0009] "Dermatologically acceptable" means that the compositions or components described are suitable for use in contact with human skin tissue without undue toxicity, incompatibility, instability or allergic response, and the like.

[0010] "Safe and effective amount" means an amount of a compound or composition sufficient to significantly elicit a positive benefit.

[0011] Although the specification ends with claims that specifically point out and distinctly claim the invention, it is believed that the present invention will be better understood from the following description.

[0012] As used herein, the term "fluid" includes liquids and gels.

[0013] For use in the present invention, articles including "a" and "an", when used in a claim, are understood to mean one or more of what is claimed or described.

[0014] As used herein, "comprising" means that other steps and other ingredients that do not affect the final result can be added. This term encompasses the terms "consisting of" and "consisting essentially of".

[0015] For use in the present invention, the term "blends" is intended to include a unique combination of materials and any compounds that may result from such a combination.

[0016] As used herein, "molecular weight" or "MW", refers to weight average molecular weight, unless otherwise specified. Molecular weight is measured using the industry standard method, gel permeation chromatography ("GPC").

[0017] Where ranges of amounts are given, these should be understood as being the total amount of said ingredient in the composition or, where more than one species falls within the scope of the ingredient definition, as the total amount of all ingredients present in the composition. composition matching that definition.

[0018] For example, if the composition comprises 1% to 5% fatty alcohol, then a composition comprising 2% stearyl alcohol and 1% cetyl alcohol and no other fatty alcohol would fall within the scope.

[0019] The amount of each specific ingredient or mixtures thereof, described later in this document, may account for up to 100% (or 100%) of the total amount of ingredient(s) in the hair care composition.

[0020]As used herein, "personal care compositions" includes products such as shampoos, shower gels, liquid hand cleansing creams, hair dyes, facial cleansing creams and other liquid surfactant-based compositions

[0021]As used herein, the terms "include", "includes" and "including" are intended to be non-limiting and are understood to mean "comprises", "comprises" and "comprising", respectively.

[0022] All percentages, parts and ratios are based on the total weight of the compositions of the present invention, except where otherwise specified. All these weights, provided they pertain to listed ingredients, are based on active content and therefore do not include vehicles or by-products that may be included in commercially available materials.

[0023] Except where otherwise specified, all component or composition contents refer to the active portion of that component or that composition and exclude impurities, for example, residual solvents or by-products, which may be present in commercially available sources of such components or compositions.

[0024] It should be understood that each upper numerical limit presented throughout this descriptive report includes each of the lower numerical limits, as if such lower numerical limits were expressly written in this document. Each lower numerical limit presented throughout the specification includes each of the upper numerical limits, as if such upper numerical limits were expressly written in this document. Each numerical range presented in this specification includes each narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were expressly written herein.

Soluble Anti-Dandruff Agent

[0025]The anti-dandruff agent can be a material or a mixture selected from the group consisting of: azoles, such as climbazole, ketoconazole, itraconazole, econazole and elubiol; hydroxypyridones, such as octopirox (piroctone olamine), ciclopirox, rilopirox and MEA-Hydroxyoctyloxypyridinone; keratolytic agents such as salicylic acid and other hydroxy acids; strobilurins such as azoxystrobin and metal chelating agents such as 1,10-phenanthroline.

[0026] In the present invention, the azole antimicrobials may be an imidazole selected from the group consisting of benzimidazole, benzothiazole, bifonazole, butaconazole nitrate, climbazole, clotrimazole, croconazole, eberconazole, econazole, elubiol, fenticonazole, fluconazole, flutimazole, isoconazole , ketoconazole, lanoconazole, metronidazole, miconazole, neticonazole, omoconazole, oxyconazole nitrate, sertaconazole, sulconazole nitrate, tioconazole, thiazole and mixtures thereof, or the azole antimicrobial agents is a triazole selected from the group consisting of: terconazole, itraconazole and mixtures thereof. The azole antimicrobial agent may be ketoconazole. Additionally, the sole antimicrobial agent may be ketoconazole.

[0027] The soluble anti-dandruff agent may be present in an amount from about 0.01% to about 10%, from about 0.1% to about 9%, from about 0.25% to about 8 %, and from about 0.5% to 6%. The soluble anti-dandruff agent may be surfactant soluble and thus surfactant-soluble anti-dandruff agents.

A. DETERSIVE SURFACTANT

[0028] The hair care composition can comprise more than about 8% by weight of a surfactant system that provides cleaning performance to the composition, or can comprise more than 10% by weight of a surfactant system that provides cleaning performance. composition cleaning. The surfactant system contains an anionic surfactant and/or a combination of anionic surfactants and/or a combination of anionic surfactants and cosurfactants selected from the group consisting of amphoteric, zwitterionic, nonionic surfactants and mixtures thereof. Various examples and descriptions of detersive surfactants are provided in US Patent No. 8,440,605; in US Patent Application Publication No. 2009/155383; and US Patent Application Publication No. 2009/0221463, which are incorporated herein by reference in their entirety.

[0029] The hair care composition may comprise from about 8% to about 16%, from about 11% to about 16% and/or from about 12% to about 16%, by weight, of one or more surfactants.

[0030] Anionic surfactants suitable for use in compositions are alkyl and alkyl ether sulfates. Other suitable anionic surfactants are the water-soluble salts of organic sulfuric acid reaction products. Additional suitable anionic surfactants are the reaction products of fatty acids esterified with isethionic acid and neutralized with sodium hydroxide. Other similar anionic surfactants are described in US Patent Nos. 2,486,921; 2,486,922; and 2,396,278, which are incorporated herein by reference in their entirety.

[0031] Examples of anionic surfactants for use in hair care compositions include ammonium lauryl sulfate, ammonium lauret sulfate, ammonium paret C10-15 sulfate, ammonium C10-15 alkyl sulfate, ammonium C11-15 alkyl sulfate, decyl ammonium sulfate, ammonium decet sulfate, ammonium undecyl sulfate, ammonium undecet sulfate, triethylamine lauryl sulfate, triethylamine lauret sulfate, triethanolamine lauryl sulfate, triethanolamine laureth sulfate, monoethanolamine lauryl sulfate, monoethanolamine lauret sulfate, Diethanolamine, Diethanolamine Laureth Sulfate, Sodium Lauric Monoglyceride Sulfate, Sodium Lauryl Sulfate, Sodium Laureth Sulfate, Sodium Paret C10-15 Sulfate, Sodium C10-15 Alkyl Sulfate, Sodium C11-15 Alkyl Sulfate, Sodium Decyl Sulfate sodium, sodium decet sulfate, sodium undecyl sulfate, sodium undecet sulfate, potassium lauryl sulfate, potassium lauret sulfate, potassium paret C10-15 sulfate, potassium C10-15 alkyl sulfate, potassium C11-15 alkyl sulfate , potassium decyl sulfate, potassium decet sulfate, potassium undecyl sulfate, potassium undecet sulfate, sodium lauryl sarcosinate, sodium lauroyl sarcosinate, lauryl sarcosine, cocoyl sarcosine, cocoyl ammonium sulfate, ammonium lauroyl sulfate, cocoyl sulfate sodium, sodium lauroyl sulfate, potassium cocoyl sulfate, potassium lauryl sulfate, triethanolamine lauryl sulfate, triethanolamine lauryl sulfate, monoethanolamine cocoyl sulfate, monoethanolamine lauryl sulfate, sodium tridecyl benzene sulfonate, sodium dodecyl benzene sulfonate, cocoyl sodium isethionate and combinations thereof. The anionic surfactant can be sodium lauryl sulfate and sodium laureth sulfate.

[0032] The composition of the present invention may also include anionic surfactants selected from the group consisting of: a) R1 O(CH2CHR3O)y SO3M; b) CH3 (CH2)z CHR2 CH2 O (CH2 CHR3O)y SO3M; and c) mixtures thereof, in which R1 represents CH3 (CH2)10, R2 represents H or a hydrocarbon radical comprising from 1 to 4 carbon atoms such that the sum of the carbon atoms in z and R2 is 8, R3 is H or CH3 , y is 0 to 7, the average value of y is about 1 when y is not (0), and M is a positively charged monovalent or divalent cation.

[0033] Suitable anionic alkyl sulfates and alkyl ether sulfate surfactants include, but are not limited to, those having branched alkyl chains, which are synthesized from C8 to C18 branched alcohols that may be selected from the group consisting of: Guerbet alcohols, alcohols derived from aldol condensation, oxo alcohols, oxo F-T and mixtures thereof. Some non-limiting examples of branched alcohols include 2-alkyl oxo alcohols such as 2-methyl-1-undecanol, 2-ethyl-1-decanol, 2-propyl-1-nonanol, 2-butyl 1-octanol, 2-methyl-1 -dodecanol, 2-ethyl-1-undecanol, 2-propyl-1-decanol, 2-butyl-1-nonanol, 2-pentyl-1-octanol, 2-pentyl-1-heptanol, and those sold under the trade names LIAL® (Sasol), ISALCHEM® (Sasol), and NEODOL® (Shell), and alcohols derived from Guerbet and aldol condensation derivatives such as 2-ethyl-1-hexanol, 2-propyl-1-butanol, 2-butyl- 1-octanol, 2-butyl-1-decanol, 2-pentyl-1-nonanol, 2-hexyl-1-octanol, 2-hexyl-1-decanol, and those sold under the trade name ISOFOL® (Sasol) or sold as alcohol ethoxylates and alkoxylates under the trade names LUTENSOL XP® (BASF) and LUTENSOL XL® (BASF).

[0034] Anionic alkyl sulfates and alkyl ether sulfates may also include those synthesized from C8 to C18 branched alcohols derived from butylene or propylene that are sold under the trade names EXXAL™ (Exxon) and Marlipal® (Sasol). These include anionic surfactants of the tridecet-n sulfate subclass (STnS), where n is between about 0.5 and about 3.5. Examples of surfactants in this subclass are sodium tridecet-2 sulfate and sodium tridecet-3 sulfate. The composition of the present invention may also include sodium tridecyl sulfate.

[0035] The composition of the present invention may also include anionic alkyl and alkyl ether sulfosuccinates and/or dialkyl ether and dialkyl sulfosuccinates and mixtures thereof. The dialkyl and dialkyl ether sulfosuccinates may be linear or branched C6-15 dialkyl and dialkyl ether sulfosuccinates. The alkyl moieties can be symmetrical (ie, the same alkyl moieties) or asymmetrical (ie, different alkyl moieties). Some non-limiting examples include: disodium lauryl sulfosuccinate, disodium laureth sulfosuccinate, sodium bistridecyl sulfosuccinate, sodium dioctyl sulfosuccinate, sodium dihexyl sulfosuccinate, sodium dicyclohexyl sulfosuccinate, sodium diamyl sulfosuccinate, sodium diisobutyl sulfosuccinate sodium, linear bis(tridecyl) sulfosuccinate and mixtures thereof.

[0036] The hair treatment composition may comprise a co-surfactant. The co-surfactant may be selected from the group consisting of amphoteric surfactant, zwitterionic surfactant, nonionic surfactant and mixtures thereof. The cosurfactant may include, but is not limited to, lauramido propyl betaine, cocoamido propyl betaine, lauryl hydroxy sultaine, sodium lauroamphoacetate, disodium cocoamphodiacetate, cocamide and mixtures thereof.

[0037] The hair care composition may further comprise from about 0.25% to about 15%, from about 1% to about 14%, from about 2% to about 13% by weight of a or more amphoteric, zwitterionic, nonionic cosurfactants, or a mixture thereof.

[0038] Amphoteric or zwitterionic surfactants suitable for use in the hair care composition of the present invention include those known for their use in shampoo or other hair care and hygiene products. Non-limiting examples of suitable zwitterionic or amphoteric surfactants are described in US Patent Nos. 5,104,646 and 5,106,609, which are incorporated herein by reference in their entirety.

[0039] Amphoteric cosurfactants suitable for use in the composition include those surfactants described as derived from secondary and tertiary aliphatic amines, in which the aliphatic radical can be a straight or branched chain and in which one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains an anionic group such as carboxy, sulfonate, sulfate, phosphate or phosphonate. Suitable amphoteric surfactants include, but are not limited to, those selected from the group consisting of: sodium cocaminopropionate, sodium cocaminodipropionate, sodium cocoamphoacetate, sodium cocoamphodiacetate, sodium cocoamphohydroxypropylsulfonate, sodium cocoamphopropionate, sodium cornamphopropionate, sodium lauraminopropionate, sodium lauroamphoacetate, sodium lauroamphoacetate, sodium lauroamphohydroxypropylsulfonate, sodium lauroamphopropionate, sodium cornamphopropionate, sodium laurimino dipropionate, ammonium cocaminopropionate, ammonium cocaminodipropionate, ammonium cocoamphoacetate, ammonium cocoamphodiacetate, cocoampho- ammonium hydroxypropylsulfonate, ammonium cocoamphopropionate, ammonium cornamphopropionate, ammonium lauraminopropionate, ammonium lauroamphoacetate, ammonium lauroampho-hydroxypropylsulfonate, ammonium lauroamphopropionate, ammonium cornanphopropionate, ammonium lauriminodipropionate, triethanolamine cocaminopropionate, triethanolamine cocaminodipropionate , triethanolamine cocoamphoacetate, Triethanolamine cocoampho-hydroxypropylsulfonate, triethanolamine cocoamphopropionate, triethanolamine cornamphopropionate, triethanolamine lauraminopropionate, triethanolamine lauroampho-acetate, triethanolamine lauroampho-hydroxypropylsulfonate, triethanolamine lauroamphopropionate, triethanolamine cornamphopropionate, triethanolamine laurimino-dipropionate, cocoanpho acid dipropionic, disodium caproamphodiacetate, disodium caproamphoadipropionate , disodium capryloamphodiacetate, disodium capryloamphodipriopionate, disodium cocoamphocarboxyethylhydroxypropylsulfonate, disodium cocoamphodiacetate, disodium cocoamphodipropionate, disodium dicarboxyethylcocopropylenediamine, disodium lauret-5 carboxyamphodiacetate, disodium lauriminodipropionate, disodium lauroamphodiacetate, disodium lauroamphodipropionate, disodium oleoamphodipropionate, Disodium PPG-2-isodecyl-7 carboxyanphodiacetate, lauraminopropionic acid, lauroamphodipropionic acid, lauryl aminopropylglycine, lauryl diethylenediamineglycine and mixtures thereof.

[0040] The composition may comprise a zwitterionic cosurfactant, wherein the zwitterionic cosurfactant is a derivative of aliphatic quaternary ammonium, phosphonium and sulfonium compounds, wherein the aliphatic radicals may be straight-chain or branched, and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains an anionic group such as carboxy, sulfonate, sulfate, phosphate or phosphonate. The zwitterionic surfactant may be selected from the group consisting of: cocamido ethyl betaine, cocamido propylamine oxide, cocamido propyl betaine, collagen hydrolyzed with cocamido propyl dimethylaminohydroxypropyl, collagen hydrolyzed with cocamido propyl dimonium hydroxy propyl, cocamido propyl hydroxy sultaine, cocobetaine starch amphopropionate, coco betaine, coco hydroxy sultaine, coco/oleamidopropyl betaine, coco sultaine, lauramido propyl betaine, lauryl betaine, lauryl hydroxy sultaine, lauryl sultaine and mixtures thereof.

[0041] Non-ionic surfactants suitable for use in the present invention include those described in McCutcheon's Detergents and Emulsifiers, US Edition (1986), by Allured Publishing Corp., and in Functional Materials ( "Functional materials"), by McCutcheon, North American edition (1992). Non-ionic surfactants suitable for use in the personal care compositions of the present invention include, but are not limited to, polyoxyethylene alkyl phenols, polyoxyethylene alcohols, polyoxyethylene polyoxypropylene glycols, glyceryl esters of alkanoic acids, polyglyceryl esters of alkanoic acids, esters propylene glycol alkanoic acids, sorbitol esters of alkanoic acids, polyoxyethylene sorbitol esters of alkanoic acids, polyoxyethylene glycol esters of alkanoic acids, polyoxyethylene alkanoic acids, alkanolamides, N-alkyl pyrrolidones, alkyl glycosides, alkyl polyglycosides, oxides of alkylamine and polyoxyethylene silicones.

[0042] The co-surfactant may be a non-ionic surfactant selected from the group including alkanolamides: Cocamide, cocamide methyl MEA, cocamide DEA, cocamide MEA, cocamide MIPA, lauramide DEA, lauramide MEA, lauramide MIPA, myristamide DEA, myristamide MEA, MEA PEG-20 cocamide, PEG-2 cocamide, PEG-3 cocamide, PEG-4 cocamide, PEG-5 cocamide, PEG-6 cocamide, PEG-7 cocamide, PEG-3 lauramide, PEG-5 lauramide, PEG-3 oleamide, PPG-2 cocamide, PPG-2 hydroxyethyl cocamide, PPG-2 hydroxyethyl isostearamide and mixtures thereof.

[0043] Representative polyoxyethylene alcohols include alkyl chains in the C9-C16 range and having from about 1 to about 110 alkoxy groups including, but not limited to, 3-laurel, 23-laurel, 10-ketete, stearet -10, stearet-100, stearet-10, all commercially available from Shell Chemicals, Houston, Texas, USA, under the tradenames Neodol® 91, Neodol® 23, Neodol® 25, Neodol® 45, Neodol® 135, Neodo ®l 67, Neodol® PC 100, Neodol® PC 200, Neodol® PC 600, and mixtures thereof.

[0044] Polyoxy ethylene fatty ethers are also commercially available, commercially available under the trade name Brij®, from Uniqema, Wilmington, Delaware, USA, including, but not limited to, Brij® 30, Brij® 35, Brij® 52, Brij® 56, Brij® 58, Brij® 72, Brij® 76, Brij® 78, Brij® 93, Brij® 97, Brij® 98, Brij® 721 and mixtures thereof.

[0045] Suitable alkyl glycosides and alkyl polyglycosides can be represented by the formula (S)n-O-R wherein S is a sugar moiety such as glucose, fructose, mannose, galactose and the like; n is an integer equal to about 1 to about 1000, and R is a C8C30 alkyl group. Examples of long chain alcohols from which the alkyl group can be derived include decyl alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol and the like. Examples of such surfactants include alkyl polyglycosides wherein S is a glucose moiety, R is a C8-20 alkyl group, and n is an integer from about 1 to about 9. Commercially available examples of such surfactants include decyl polyglycoside and lauryl polyglycoside, available under the trade names APG® 325 CS, APG® 600 CS and APG® 625 CS), from Cognis, of Ambler, Pa, USA. Also useful for the present invention are sucrose ester-based surfactants such as sucrose cocoate and sucrose laurate as well as alkyl polyglycosides, available under the tradenames Triton™ BG-10 and Triton™ CG-110 from the Dow Chemical Company of Houston, TX, USA.

[0046] Other non-ionic surfactants suitable for use in the present invention are glyceryl esters and polyglyceryl esters, including, but not limited to, C12 glyceryl monoesters, glyceryl monoesters of -22 saturated, unsaturated and long chain fatty acids branched chain such as glyceryl oleate, glyceryl monostearate, glyceryl monopalmitate, glyceryl C12 monobehenate and mixtures thereof, and polyglyceryl esters of -22 saturated, unsaturated and branched chain fatty acids such as polyglyceryl-4 isostearate, polyglyceryl-3 oleate, polyglyceryl-2 sesquioleate, triglyceryl diisostearate, diglyceryl monooleate, tetraglyceryl monooleate and mixtures thereof.

[0047] Sorbitan esters can also be used here as non-ionic surfactants. C12 sorbitan esters of -22 saturated, unsaturated and branched chain fatty acids are useful in the present invention. Such sorbitan esters generally comprise mixtures of mono-, di-, triesters, etc. Representative examples of suitable sorbitan esters include sorbitan monolaurate (SPAN® 20), sorbitan monopalmitate (SPAN® 40), sorbitan monostearate (SPAN® 60), sorbitan tristearate (SPAN® 65), sorbitan monooleate (SPAN® 80), sorbitan trioleate (SPAN® 85) and sorbitan isostearate.

[0048] Also suitable for use in the present invention are alkoxylated derivatives of sorbitan esters including, but not limited to, polyoxy ethylene (20) sorbitan monolaurate (Tween® 20), polyoxy ethylene (20) sorbitan monopalmitate (Tween® 40), polyoxy ethylene (20) sorbitan monostearate (Tween® 60), polyoxy ethylene (20) sorbitan monooleate (Tween® 80), polyoxy ethylene (4) sorbitan monolaurate (Tween® 21), polyoxy ethylene (4) monostearate ethylene (4) sorbitan (Tween® 61), polyoxy ethylene (5) sorbitan monooleate (Tween® 81) and blends thereof, all available from Uniqema.

[0049] Also suitable for use in the present invention are alkyl phenol ethoxylates including, but not limited to, nonylphenol ethoxylates (Tergitol™ NP-4, NP-6, NP-7, NP-8, NP-9, NP-10 , NP-11, NP-12, NP-13, NP-15, NP-30, NP-40, NP-50, NP-55, NP-70 available from The Dow Chemical Company, Houston, TX, USA) and octyl phenol ethoxylates (Triton™ X-15, X-35, X-45, X-114, X-100, X-102, X165, X-305, X-405, X-705 available from The Dow Chemical Company, Houston, TX, USA).

[0050] Also suitable for use herein are tertiary alkylamine oxides, including lauramine oxide and cocamine oxide.

[0051] Some non-limiting examples of other anionic, zwitterionic, amphoteric or nonionic surfactants suitable for use in the hair care composition are described in McCutcheon's, Emulsifiers and Detergents, 1989 Annual, published by M. C. Publishing Co., and in the US patents Nos. 3,929,678 and 2,658,072; 2,438,091; 2,528,378, which are incorporated herein by reference in their entirety.

[0052] Suitable surfactant combinations comprise a weight average % of alkyl branching from about 0.5% to about 30%, alternatively from about 1% to about 25%, alternatively from about 2 % to about 20%.

[0053] The combination of surfactants can have a weight average cumulative % of C8 to C12 alkyl chain lengths of from about 7.5% to about 25%, alternatively from about 10% to about 22.5 %, alternatively from about 10% to about 20%.

[0054] The combination of surfactants may have an average C8-C12/C13-C18 alkyl chain ratio of from about 3 to about 200, alternatively from about 25 to about 175.5, alternatively from about 50 to about 150, alternatively about 75 to about 125.

B. CATION POLYMERS

[0055] The hair care composition also comprises a cationic polymer. Such cationic polymers can include at least one of (a) a cationic guar gum polymer, (b) a cationic non-guar galactomannan polymer, (c) a cationic tapioca polymer, (d) a cationic copolymer of acrylamide monomers and cationic monomers, and/or (e) synthetic non-crosslinked cationic polymer, which may or may not form lyotropic liquid crystals in combination with the detersive surfactant (f) a cationic cellulose polymer. Additionally, the cationic polymer can be a mixture of cationic polymers.

[0056] The hair care composition may comprise a polymer of cationic guar gum, which is a derivative of cationically substituted galactomannan (guar) gum. Guar gum for use in preparing these guar gum derivatives is typically obtained as a naturally occurring material from the seeds of the guar plant. The guar gum molecule itself is a straight-chain mannan, which is branched at regular intervals with single-membered galactose units on alternative mannose units. The mannose units are linked to each other via β(1-4) glycosidic bonds. The branching of galactose is via an a(1-6) bond. The cationic derivatives of guar gums are obtained through the reaction between the hydroxyl groups of polygalactomannan and reactive quaternary ammonium compounds. The degree of substitution of the cationic groups on the guar gum structure needs to be sufficient to provide the necessary cationic charge density described above.

[0057] In the present invention, the cationic polymer can be, including, but not limited to, a cationic guar polymer, have an average molecular weight of less than 2.2 million g/mol, or from about 150 thousand to about 2.2 million g/mol, or from about 200 thousand to about 2.2 million g/mol, or from about 250 thousand to about 2.5 million g/mol, or from about 300 thousand to about from 1.2 million g/mol, or from about 700,000 to about 1 million g/mol. Additionally, the cationic guar polymer can have a charge density of from about 0.2 to about 2.2 meq/g or from about 0.3 to about 2.0 meq/g or from about 0. 4 at about 1.8 meq/g; or from about 0.5 meq/g to about 1.8 meq/g.

[0058] The cationic polymer of guar gum can have a weight average molecular weight of less than about 1.5 million g/mol and has a charge density of about 0.1 meq/g to about 2.5 meq/g . The cationic guar gum polymer can have a weight average molecular weight of less than 900 thousand g/mol or from about 150 thousand to about 800 thousand g/mol or from about 200 thousand to about 700 thousand g/mol or from from about 300 thousand to about 700 thousand g/mol or from about 400 thousand to about 600 thousand g/mol, from about 150 thousand to about 800 thousand g/mol or from about 200 thousand to about 700 thousand g/mol or from about 300 thousand to about 700 thousand g/mol or from about 400 thousand to about 600 thousand g/mol. The cationic guar gum polymer can have a charge density of from about 0.2 to about 2.2 meq/g or from about 0.3 to about 2.0 meq/g or from about 0.4 to about 1.8 meq/g; or from about 0.5 meq/g to about 1.5 meq/g.

[0059] The cationic guar gum polymer can be formed from quaternary ammonium compounds. The quaternary ammonium compounds for the formation of the cationic polymer of guar gum conform to the general formula 1: wherein R3, R4 and R5 are methyl or ethyl groups; R6 is either an epoxy alkyl group with the following general formula 2: or R6 is a halohydrin group of general formula wherein R7 is a C1 to C3 alkylene; X is chlorine or bromine and Z is an anion such as Cl-, Br-, I- or HSO4-.

[0060] The cationic polymer of guar gum fits the general formula 4: wherein R8 is guar gum; and wherein R4, R5, R6 and R7 are as defined above; and wherein Z is a halogen. Guar gum cationic polymer can conform to Formula 5:

[0061]Other suitable cationic guar polymers include cationic guar derivatives such as hydroxy propyl triammonium guar chloride. The cationic guar polymer may be hydroxy propyl triammonium chloride. Specific examples of hydroxypropyltrimonium chlorides of guar include the Jaguar® series commercially available from Solvay, for example, Jaguar® C-500, commercially available from Solvay. Jaguar® C-500 has a charge density of 0.8 meq/g and a molecular weight of 500,000 g/mol. Another suitable hydroxy propyltrimonium guar chloride is: hydroxy propyltrimonium guar chloride which has a charge density of about 1.3 meq/g and a molecular weight of about 500,000 g/mol and is available from Solvay as Jaguar® Great. Another suitable hydroxy propyl trimonium guar chloride is: hydroxy propyl trimonium guar chloride which has a charge density of about 0.7 meq/g and a molecular weight of about 1,500,000 g/mol and is available from Solvay as Jaguar® Excel. Another suitable hydroxy propyl trimonium guar chloride is: hydroxy propyl trimonium guar chloride which has a charge density of about 1.1 meq/g and a molecular weight of about 500,000 g/mol and is available from ASI, a density loading of about 1.5 meq/g and a molecular weight of about 500,000 g/mol is available from ASI. Other hydroxypropyltrimonium chlorides of guar are suitable: Hi-Care 1000, which has a charge density of about 0.7 meq/g and a molecular weight of about 600,000 g/mol and is available from Solvay; N-Hance 3269 and N-Hance 3270, which have a charge density of about 0.7 meq/g and a molecular weight of about 425,000 g/mol and are available from ASI; Hi-Care 3196, which has a charge density of about 0.8 meq/g and a molecular weight of about 1,100,000 g/mol and is available from ASI. AquaCat CG518 has a charge density of about 0.9 meq/g and a molecular weight of about 50,000 g/mol and is arranged close to the ASI. BF-13, which is a borate (boron)-free guar with a charge density of about 1.1 meq/g and a molecular weight of about 800,000, and BF-17, which is a borate (boron)-free guar with a specific gravity loading of about 1.5 meq/g and molecular weight of about 800,000, both available from ASI.

[0062] The hair care compositions of the present invention may comprise a galactomannan polymer derivative having a mannose to galactose ratio greater than 2:1 on a monomer to monomer basis; the galactomannan polymer derivative selected from the group consisting of a cationic galactomannan polymer derivative and an amphoteric galactomannan polymer derivative having a net positive charge. For use in the present invention, the term "cationic galactomannan" refers to a polymer of galactomannan to which a cationic group is added. The term "amphoteric galactomannan" refers to a galactomannan polymer to which both a cationic group and an anionic group are added so that the polymer has a net positive charge.

[0063] Galactomannan polymers are present in the endosperm of seeds of the Leguminosae family. Galactomannan polymers are created from a combination of mannose monomers and galactose monomers. The galactomannan molecule is a straight-chain mannan branched at regular intervals with single-membered galactose units on specific mannose units. The mannose units are linked to each other via β(1-4) glycosidic bonds. The branching of galactose is via an α (1-6) bond. The ratio of mannose monomers to galactose monomers varies according to plant species and is also affected by climate. The non-guar galactomannan polymer derivatives of the present invention have a mannose to galactose ratio greater than 2:1 on a monomer to monomer basis. Suitable ratios of mannose to galactose can be greater than about 3:1 and the ratio of mannose to galactose can be greater than about 4:1. Analysis of mannose to galactose ratios is well known in the art and is typically based on measurement of galactose content.

[0064] The gum for use in the preparation of non-guar galactomannan polymer derivatives is typically obtained in the form of a naturally occurring material such as seeds or grains from plants. Examples of various non-guar galactomannan polymers include, but are not limited to, tara gum (3 parts mannose/1 part galactose), carob or locust bean gum (4 parts mannose/1 part galactose), and cassia gum (5 parts parts mannose/1 part galactose).

[0065] Non-guar galactomannan polymer derivatives may have a molecular weight of from about 1,000 to about 10,000,000 and/or from about 5,000 to about 3,000,000.

[0066] The hair care compositions of the invention may also include galactomannan polymer derivatives having a cationic charge density of about 0.5 meq/g to about 7 meq/g. Galactomannan polymer derivatives can have a cationic charge density of about 1 meq/g to about 5 meq/g. The degree of substitution of the cationic groups on the galactomannan structure needs to be sufficient to provide the cationic charge density described above.

[0067] The galactomannan polymer derivative may be a cationic derivative of the non-guar galactomannan polymer, which is obtained through the reaction between the hydroxyl groups of the polygalactomannan polymer and the reactive quaternary ammonium compounds. Quaternary ammonium compounds suitable for use in forming the cationic galactomannan polymer derivatives include those according to general formulas 1 to 5 as defined above.

[0068] The cationic non-guar galactomannan polymer derivatives formed from the reagents described above are represented by the general formula 6: where R is the gum. The cationic galactomannan derivative can be a hydroxy propyl trimethyl ammonium chloride gum, which can be more specifically represented by the general formula 7:

[0069] Alternatively, the galactomannan polymer derivative may be an amphoteric galactomannan polymer derivative having a net positive charge, obtained when the cationic galactomannan polymer derivative further comprises an anionic group.

[0070] Cationic non-guar galactomannan may have a mannose to galactose ratio greater than about 4:1, a molecular weight of about 1,000 g/mol to about 10,000,000 g/mol, and/or about 50,000 g/mol to about 1,000,000 g/mol, and/or from about 100,000 g/mol to about 900,000 g/mol, and/or from about 150,000 g/mol to 400,000 g/mol and about a cationic charge density of from about 1 meq/g to 5 meq/g, from about and/or from about 2 meq/g to 4 meq/g, and may be derived from a cassia plant.

[0071] The hair care compositions may comprise water-soluble cationically modified starch polymers. For use in the present invention, the term "cationically modified starch" refers to a starch to which a cationic group is added prior to degradation of the starch to a lower molecular weight, or to which a cationic group is added after modification of the starch to to obtain a desired molecular weight. The definition of the term "cationically modified starch" also includes amphoterically modified starches. The term "amphoterically modified starch" refers to a hydrolyzed starch to which a cationic group and an anionic group are added.

[0072] The cationically modified starch polymers disclosed in the present invention have a percentage of bound nitrogen from about 0.5% to about 4%.

[0073] Cationically modified starch polymers for use in hair care compositions can have a molecular weight of about 850,000 g/mol to about 1,500,000 g/mol and/or from about 900,000 g/mol to about of 1,500,000 g/mol.

[0074] Hair care compositions can include cationically modified starch polymers having a charge density of from about 0.2 meq/g to about 5 meq/g and/or from about 0.2 meq/g to about 2 meq/g. Chemical modification to obtain such a charge density includes, but is not limited to, the addition of amino groups and/or ammonium groups to the starch molecules. Some non-limiting examples of these ammonium groups may include substituents such as trimethyl hydroxy propyl ammonium chloride, trimethyl hydroxy propyl ammonium chloride, dimethyl stearyl hydroxy propyl ammonium chloride, and dimethyl dodecyl hydroxy propyl ammonium chloride. See Solarek, D.B., Cationic Starches in Modified Starches: Properties and Uses, Wurzburg, O.B., Ed., CRC Press, Inc., Boca Raton, Florida, USA, 1986, pages 113 to 125. Cationic groups can be added to starch before degradation to a lower molecular weight or may be added after such modification.

[0075] Cationically modified starch polymers generally have a degree of substitution of a cationic group of about 0.2 to about 2.5. For use in the present invention, the "degree of substitution" of cationically modified starch polymers is the average number of hydroxyl groups on each anhydroglucose unit that is derivatized by substituent groups. Since each anhydroglucose unit has three hydroxyl groups potentially available for substitution, the maximum possible degree of substitution is 3. The degree of substitution is expressed as the number of moles of substituent groups per mole of anhydroglucose units, on a molar average basis . The degree of substitution can be determined using proton nuclear magnetic resonance (".sup.1H NMR") spectroscopy methods well known in the art. Suitable .sup.1H NMR techniques include those described in "Observation on NMR Spectra of Starches in Dimethyl Sulfoxide, Iodine-Complexing, and Solvating in Water-Dimethyl Sulfoxide", Qin-Ji Peng and Arthur S. Perlin, Carbohydrate Research, 160 (1987), 57-72; and "An Approach to the Structural Analysis of Oligosaccharides by NMR Spectroscopy", J. Howard Bradbury and J. Grant Collins, Carbohydrate Research, 71, (1979), 15-25.

[0076] The source of starch before chemical modification can be chosen from a variety, such as tubers, legumes, cereals and grains. Some non-limiting examples of these sources may include corn starch, wheat starch, rice starch, waxy corn starch, oat starch, cassava starch, waxy barley, waxy rice starch, glutenous rice starch, rice starch sweet, amioca, potato starch, tapioca starch, oat starch, sago starch, rice pudding or mixtures of these items.

[0077] Cationically modified starch polymers can be selected from degraded cationic corn starch, cationic tapioca, cationic potato starch and mixtures thereof. Alternatively, cationically modified starch polymers are cationic corn starch and cationic tapioca.

[0078] The starch, before degradation or after modification to a lower molecular weight, may comprise one or more additional modifications. For example, these modifications can include cross-linking, stabilization reactions, phosphorylations and hydrolyzations. Stabilization reactions can include alkylation and esterification.

[0079] The cationically modified starch polymers can be incorporated into the composition in the form of hydrolyzed starch (for example, acid, enzyme, or alkaline degradation), oxidized starch (for example, peroxide, peracid, hypochlorite, alkaline, or any other oxidizing agent), physically or mechanically degraded starch (e.g., through thermomechanical energy input from processing equipment), or combinations thereof.

[0080] An optimal form of starch is one that is readily soluble in water, and forms a substantially clear solution (% transmittance about 80 to 600 nm) in water. The transparency of the composition is measured by ultraviolet/visible (UV/VIS) spectrophotometry, which determines the absorption or transmission of UV/VIS light by a sample, using a Gretag Macbeth Color i 5 colorimeter, according to the related instructions. A light wavelength of 600 nm proved to be suitable for characterizing the degree of clarity of cosmetic compositions.

[0081] Cationically modified starch suitable for use in hair care compositions is available from known starch suppliers. Also suitable for use in the hair care compositions is nonionic modified starch which can be further derivatized to a cationically modified starch as is known in the art. Other suitable modified starch starting materials can be quaternized, as is known in the art, to produce cationically modified starch polymer suitable for use in hair care compositions.

[0082]Starch Degradation Procedure: An aqueous starch paste can be prepared by mixing granular starch in water. The temperature is raised to about 35°C. An aqueous solution of potassium permanganate is then added at a concentration of about 50 ppm, based on the amount of starch. The pH is raised to about 11.5 with sodium hydroxide, and the aqueous slurry stirred enough to prevent the starch from settling out. Next, a solution of hydrogen peroxide diluted to about 30% in water is added to a content of about 1% peroxide based on the amount of starch. The pH of about 11.5 is then restored by adding additional sodium hydroxide. The reaction is complete after a period of from about 1 to about 20 hours. The mixture is then neutralized with dilute hydrochloric acid. The degraded starch is recovered by filtration followed by washing and drying.

[0083] The hair care composition may comprise a cationic copolymer of an acrylamide monomer and a cationic monomer, the copolymer having a charge density of about 1.0 meq/g to about 3.0 meq/g . The cationic copolymer can be a synthetic cationic copolymer of acrylamide monomers and cationic monomers.

[0084] The cationic copolymer may comprise: (i) an acrylamide monomer of the following AM formula: wherein R9 is H or C1-4 alkyl; and R10 and R11 are independently selected from the group consisting of H, C1-4 alkyl, CH2OCH3, CH2OCH2CH(CH3)2 and phenyl, or together are C3-6 cycloalkyl; and (ii) a cationic monomer according to formula CM: where k =1, each of v, v' and v'' is independently an integer from 1 to 6, w is zero or an integer from 1 to 10, and X- is an anion.

[0085] The cationic monomer can be according to the CM formula and where k = 1, v = 3 and w = 0, z = 1 and X- is Cl- to form the following structure:

[0086]The above structure can diquaternary. Alternatively, the cationic monomer can be according to formula CM e where v and v'' are each 3, v' = 1, w =1, y = 1 and X- is Cl-, as:

[0087] The above structure can be called a triquaternary.

[0088]Suitable acrylamide monomer includes, but is not limited to, acrylamide or methacrylamide.

[0089] The cationic copolymer (b) can be AM:TRIQUAT which is a copolymer of acrylamide and 1,3-propanediamine, N-[2-[[[dimethyl[3-[(2-methyl-1-oxo-2) - propenyl)amino]propyl]ammonium]acetyl]amino]ethyl]2-hydroxy-N,N,N',N',N'-pentamethyl-, trichloride. AM:TRIQUAT is also known as polyquaternium 76 (PQ76). AM:TRIQUAT can have a charge density of 1.6 meq/g and a molecular weight of 1.1 million g/mol.

[0090] Additionally, the cationic copolymer may be of an acrylamide monomer and a cationic monomer, the cationic monomer being selected from the group consisting of: dimethylaminoethyl (meth)acrylate, dimethylaminopropyl (meth)acrylate, ( ditert-thiobutylaminoethyl meth)acrylate, dimethylaminomethyl(meth)acrylamide, dimethylaminopropyl(meth)acrylamide; ethylenimine, vinylamine, 2-vinylpyridine, 4-vinylpyridine; trimethyl ammonium ethyl (meth)acrylate chloride, trimethyl ammonium ethyl (meth)acrylate methyl sulfate, benzyl dimethyl ammonium ethyl (meth)acrylate chloride, 4-benzoylbenzyl dimethyl ammonium ethyl acrylate chloride, ethyl ( trimethyl ammonium meth)acrylamido, trimethyl ammonium propyl (meth)acrylamido chloride, vinylbenzyl trimethyl ammonium chloride, diallyl dimethyl ammonium chloride and mixtures thereof.

[0091] The cationic copolymer may comprise a cationic monomer selected from the group consisting of: cationic monomers include trimethyl ammonium ethyl (meth)acrylate chloride, trimethylammonium ethyl (meth)acrylate methyl sulfate, ethyl (meth) benzyl chloride dimethylammonium acrylate, 4-benzoylbenzyl dimethylammonium ethyl acrylate chloride, trimethylammonium ethyl (meth)acrylamido chloride, trimethylammonium propyl (meth)acrylamido chloride, vinylbenzyl trimethylammonium chloride and mixtures thereof.

[0092]The cationic copolymer can be soluble in water. The cationic copolymer is formed from (1) copolymers of (meth)acrylamide and cationic monomers based on (meth)acrylamide and/or hydrolysis stable cationic monomers, (2) terpolymers of (meth)acrylamide, monomers based on cationic esters of (meth)acrylic acid and monomers based on (meth)acrylamide and/or cationic monomers with stable hydrolysis. The monomers based on cationic (meth)acrylic acid esters can be cationized esters of (meth)acrylic acid containing a quaternized N atom. Cationized esters of (meth)acrylic acid containing a quaternized N atom can be quaternized dialkyl amino alkyl (meth)acrylates with C1 to C3 alkyl and alkylene groups. Suitable cationized esters of (meth)acrylic acid containing a quaternized N atom may be selected from the group consisting of: ammonium salts of dimethylamino methyl (meth)acrylate, dimethyl amino ethyl (meth)acrylate, dimethylaminopropyl, diethylamino methyl (meth)acrylate, diethylamino ethyl (meth)acrylate; and diethylaminopropyl (meth)acrylate quaternized with methyl chloride. Cationized esters of (meth)acrylic acid containing a quaternized N atom can be dimethylamino ethyl acrylate, which is quaternized with an alkyl halide, or with methyl chloride or benzyl chloride or dimethyl sulfate (ADAME-Quat). The cationic monomer when based on (meth)acrylamides can be dialkylamino alkyl(meth)acrylamides quaternized with C1 to C3 alkyl and alkylene groups, or dimethylamino propylacrylamide, which is quaternized with an alkyl halide or methyl chloride or benzyl chloride or dimethyl sulfate.

[0093] Suitable cationic monomer based on a (meth)acrylamide includes dialkylamino alkyl(meth)acrylamide quaternized with C1 to C3 alkyl and alkylene groups. The cationic monomer based on a (meth)acrylamide can be dimethylaminopropylacrylamide, which is quaternized with an alkyl halide, specifically methyl chloride or benzyl chloride or dimethyl sulfate.

[0094] The cationic monomer can be a cationic monomer with stable hydrolysis. Cationic monomers with stable hydrolysis may be, in addition to dialkyl amino alkyl(meth)acrylamide, all monomers which can be observed to be stable to the OECD hydrolysis test. The cationic monomer may be hydrolysis-stable, and the hydrolysis-stable cationic monomer may be selected from the group consisting of: diallyl dimethylammonium chloride and cationic styrene derivatives, soluble in water.

[0095] The cationic copolymer is a terpolymer of acrylamide, 2-dimethylammoniomethyl (meth)acrylate quaternized with methyl chloride (ADAME-Q) and 3-dimethylammoniopropyl(meth)acrylamide quaternized with methyl chloride (DIMAPA-Q). The cationic copolymer can be formed from acrylamide and acrylamidopropyltrimethylammonium chloride, acrylamidopropyltrimethylammonium chloride having a charge density of about 1.0 meq/g to about 3.0 meq/g.

[0096] The cationic copolymer can have a charge density of about 1.1 meq/g to about 2.5 meq/g or from about 1.1 meq/g to about 2.3 meq/g or about from about 1.2 meq/g to about 2.2 meq/g or from about 1.2 meq/g to about 2.1 meq/g or from about 1.3 meq/g to about 2.0 meq/g g or from about 1.3 meq/g to about 1.9 meq/g.

[0097] The cationic copolymer can have a molecular weight of about 100 thousand g/mol to about 1.5 million g/mol or from about 300 thousand g/mol to about 1.5 million g/mol or from from about 500 thousand g/mol to about 1.5 million g/mol or from about 700 thousand g/mol to about 1.0 million g/mol or from about 900 thousand g/mol to about 1. 2 million g/mol.

[0098] The cationic copolymer may be a trimethylammoniopropylmethacrylamide chloride-N-acrylamide copolymer, which is also known as AM:MAPTAC. AM:MAPTAC can have a charge density of about 1.3 meq/g and a molecular weight of about 1.1 million g/mol. The cationic copolymer can be AM:ATPAC. AM:ATPAC can have a charge density of about 1.8 meq/g and a molecular weight of about 1.1 million g/mol. (a) Synthetic Cationic Polymers

[0099] The hair care composition can comprise a synthetic polymer that can be formed from i) one or more cationic monomeric units and, optionally, ii) one or more monomeric units that have a negative charge and/or iii) a nonionic monomer, where the subsequent charge on the copolymer is positive. The ratio between the three types of monomers is given by "m", "p" and "q", where "m" is the number of cationic monomers, "p" is the number of monomers that have a negative charge and "q " is the number of non-ionic monomers.

[0100] Cationic polymers may be water-soluble or water-dispersible, non-crosslinked, and synthetic cationic polymers having the following structure: where A, can be one or more of the cationic: where @ = starch, alkyl starch, ester, ether, alkyl or alkylaryl; where Y = C1-C22 alkyl, alkoxy, alkylidene, alkyl or aryloxy; where ^ = C1-C22 alkyl, alkyloxy, alkylaryl or alkylaryloxy;. where Z = C1-C22 alkyl, alkyloxy, aryl or aryloxy; where R1 = H, linear or branched C1-C4 alkyl; where s = 0 or 1, n = 0 or >1; where T and R7 = C1-C22 alkyl; and where X- = halogen, hydroxide, alkoxide, sulfate or alkyl sulfate.

[0101] Where the monomer that has a negative charge is defined by R2' = H, linear or branched alkyl C1-C4 and R3 as: where D = O, N or S; where Q = NH2 or O; where u = 1-6; where t = 0-1; and where J = oxygenated functional group containing the following elements P, S, C.

[0102] Where the non-ionic monomer is defined by R2'' = H, C1-C4 linear or branched alkyl, R6 = linear or branched alkyl, alkyl aryl, aryloxy, alkyloxy, alkyl aryloxy and β is defined as where G' and G'' are, independently of one another, O, S or N-H and L = 0 or 1.

[0103] Examples of cationic monomers include aminoalkyl (meth)acrylates, (meth)aminoalkyl (meth)acrylamides; monomers comprising at least one secondary, tertiary or quaternary amine function, or a heterocyclic group containing a nitrogen, vinyl amine or ethylenimine atom; diallyl dialkyl ammonium salts; their mixtures, their salts, and macromonomers derived from them.

[0104] Additional examples of cationic monomers include dimethyl amino ethyl (meth)acrylate, dimethyl amino propyl (meth)acrylate, diterthiobutylaminoethyl (meth)acrylate, dimethylamino methyl (meth)acrylamide, dimethyl amino propyl (meth)acrylamide, ethylenimine , vinyl amine, 2-vinylpyridine, 4-vinylpyridine, trimethyl ammonium ethyl (meth)acrylate chloride, trimethyl ammonium ethyl (meth)acrylate methyl sulfate, dimethyl ammonium ethyl (meth)acrylate benzyl chloride, 4-benzoylbenzyl dimethyl chloride ethyl ammonium acrylate, ethyl trimethyl ammonium (meth)acrylamido chloride, propyl (meth)acrylamido trimethyl ammonium chloride, vinylbenzyl trimethyl ammonium chloride, diallyl dimethyl ammonium chloride.

[0105] Cationic monomers include those comprising a quaternary ammonium group of the formula - NR3+, where R, which is identical or different, represents a hydrogen atom, an alkyl group comprising 1 to 10 carbon atoms or a benzyl group , optionally carrying a hydroxyl group, and comprise an anion (counterion). Examples of anions are halides such as chlorides, bromides, sulfates, hydrosulfates, alkyl sulfates (for example, comprising 1 to 6 carbon atoms), phosphates, citrates, formates and acetates.

[0106] Preferred cationic monomers include trimethyl ammonium ethyl (meth)acrylate chloride, trimethyl ammonium ethyl (meth)acrylate sulfate, dimethyl ammonium ethyl (meth)acrylate benzyl chloride, 4- ethyl acrylate chloride benzoylbenzyl dimethyl ammonium, ethyl (meth)acrylamido trimethyl ammonium chloride, propyl (meth)acrylamido trimethyl ammonium chloride, vinylbenzyl trimethyl ammonium chloride.

[0107] Additional suitable cationic monomers include trimethyl ammonium propyl (meth)acrylamido chloride.

[0108] Examples of monomers with a negative charge include alpha ethylenically unsaturated monomers comprising a phosphate or phosphonate group, alpha ethylenically unsaturated monocarboxylic acids, monoalkylesters of alpha ethylenically unsaturated dicarboxylic acids, monoalkylamides of alpha ethylenically unsaturated dicarboxylic acids, alpha ethylenically unsaturated compounds that comprise a sulfonic acid group, and salts of alpha ethylenically unsaturated compounds comprising a sulfonic acid group.

[0109] Suitable monomers with a negative charge include acrylic acid, methacrylic acid, vinyl sulfonic acid, vinyl sulfonic acid salts, vinylbenzene sulfonic acid, vinylbenzene sulfonic acid salts, alpha-acrylamidomethyl propanesulfonic acid, alpha-acrylamidomethyl propanesulfonic acid salts , 2-sulfoethyl methacrylate, 2-sulfoethyl methacrylate salts, acrylamido-2-methylpropanesulfonic acid (AMPS), acrylamido-2-methylpropanesulfonic acid salts and styrene sulfonate (SS).

[0110] Examples of non-ionic monomers include vinyl acetate, amides of alpha ethylenically unsaturated carboxylic acids, esters of alpha ethylenically unsaturated monocarboxylic acids with a hydrogenated or fluorinated alcohol, polyethylene oxide (meth)acrylate (i.e. acid ( polyethoxylated meth)acrylic), monoalkyl esters of alpha ethylenically unsaturated dicarboxylic acids, monoalkyl amides of alpha ethylenically unsaturated dicarboxylic acids, vinyl nitriles, vinyl amine amides, vinyl alcohol, vinyl pyrrolidone and vinyl aromatics.

[0111] Suitable non-ionic monomers include styrene, acrylamide, methacrylamide, acrylonitrile, methyl acrylate, ethyl acrylate, n-propylacrylate, n-butyl acrylate, methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, n-butyl methacrylate , 2-ethyl hexyl acrylate, 2-ethyl hexyl methacrylate, 2-hydroxy ethyl acrylate and 2-hydroxy ethyl methacrylate.

[0112] The anionic counterion (X-) in association with the synthetic cationic polymers can be any known counterion, as long as the polymers remain soluble or dispersible in water, in the hair care composition, or in a coacervate phase of the treatment composition of the hair, and provided that the counterions are physically and chemically compatible with the essential components of the hair care composition or otherwise do not unduly impair the performance, stability or aesthetics of the product. Some non-limiting examples of these counterions include halides (eg, chlorine, fluorine, bromine, iodine), sulfate, and methylsulfate.

[0113] The cationic polymer described in the present invention can help provide damaged hair, particularly chemically treated hair, with a replacement hydrophobic F-layer. The microscopically thin F-layer provides natural weather resistance while helping to retain moisture and prevent further damage. Chemical-based treatments damage the hair cuticle and remove its protective F-layer. As the F layer is removed, the hair becomes increasingly hydrophilic. It has been found that when lyotropic liquid crystals are applied to chemically treated hair, the hair becomes more hydrophobic and younger in both appearance and feel. Without sticking to any particular theory, it is believed that the lyotropic liquid crystal complex creates a hydrophobic layer or film that coats the hair fibers and protects it, much like the natural F-layer does. The hydrophobic layer restores the hair to a generally new and healthier looking state. Lyotropic liquid crystals are formed by combining the synthetic cationic polymers described herein with the aforementioned anionic detersive surfactant component of the hair care composition. The synthetic cationic polymer has a relatively high charge density. It should be noted that some synthetic polymers that have a relatively high cationic charge density do not form lyotropic liquid crystals, primarily because of their abnormal linear charge densities. Such synthetic cationic polymers are described in WO 94/06403 to Reich et al. The synthetic polymers described herein can be formulated into a stable hair care composition that provides optimal conditioning performance for damaged hair.

[0114] Cationic synthetic polymers that can form lyotropic liquid crystals can have a cationic charge density of about 2 meq/g to about 7 meq/g and/or from about 3 meq/g to about 7 meq/g and/or from about 4 meq/g to about 7 meq/g. The cationic charge density can be about 6.2 meq/gm. The cationic polymers also have a molecular weight of from about 1,000 to about 5,000,000 and/or from about 10,000 to about 1,500,000 and/or from about 100,000 to about 1,500,000.

[0115] Synthetic cationic polymers that provide better conditioning and deposition of beneficial agents, but do not necessarily form lyotropic liquid crystals, may have a cationic charge density of about 0.7 meq/g to about 7 meq/gm and/ or from about 0.8 meq/gm to about 5 meq/gm and/or from about 1.0 meq/gm to about 3 meq/gm. The polymers also have a molecular weight of from about 1,000 to about 1,500,000, from about 10,000 to about 1,500,000, and from about 100,000 to about 1,500,000.

[0116] Suitable cationic cellulose polymers are hydroxy ethyl cellulose salts reacted with substituted trimethyl ammonium epoxide, referred to in the industry (CTFA) as polyquaternium 10 and available from Dow/Amerchol Corp. (Edison, N.J., USA) in their Polymer LR, JR, and KG series of polymers. Non-limiting examples include: JR-400, JR-125, JR-30M, KG-30M, JP, LR-400 and mixtures thereof. Other suitable types of cationic cellulose include the polymeric quaternary ammonium salts of hydroxy ethyl cellulose reacted with epoxide substituted lauryl dimethyl ammonium, referred to in the industry (CTFA) as Polyquaternium 24. These materials are available from Dow/Amerchol Corp. under the trade name Polymer LM-200. Other suitable types of cationic cellulose include the polymeric quaternary ammonium salts of hydroxy ethyl cellulose reacted with lauryl dimethyl ammonium substituted epoxide and trimethyl ammonium substituted epoxide, referred to in the industry (CTFA) as Polyquaternium 67. These materials are available from Dow/ Amerchal Corp. under the trade names SoftCAT Polymer SL-5, SoftCAT Polymer SL-30, Polymer SL-60, Polymer SL-100, Polymer SK-L, Polymer SK-M, Polymer SK-MH and Polymer SK-H.

[0117] Suitable cationic cellulose polymers can have a cationic charge density of about 0.5 meq/g to about 2.5 meq/g, and/or from about 0.6 meq/g to about 2, 2 meq/g and/or from about 0.6 meq/g to about 2.0 meq/g. Additionally, the cationic charge density can be about 1.9 meq/g. The polymers can also have a molecular weight of from about 200,000 to about 3,000,000, and/or from about 300,000 to about 2,200,000, from about 1,000,000 to about 2,200,000 and/or about from 300,000 to about 1,500,000. The cationic cellulose polymer can have a cationic charge density of about 1.7 to about 2.1 meq/g and a molecular weight of about 1,000,000 to about 2,000,000.

[0118] The concentration of cationic polymers is in the range of about 0.01% to about 5%, from about 0.08% to about 3%, from about 0.1% to about 2 % and from about 0.2% to about 1% by weight of the hair care composition.

thickening polymer

[0119] The hair care composition may comprise a thickening polymer to increase the viscosity of the composition. Suitable thickening polymers can be used. The hair care composition may comprise from about 0.25% to about 10% of a thickening polymer, from about 0.5% to about 8% of a thickening polymer, from about 1.0 % to about 5% of a thickening polymer, and from about 1% to about 4% of a thickening polymer. Modifier thickening polymer can be polyacrylate, polyacrylamide thickeners. The thickening polymer may be an anionic thickening polymer.

[0120] The hair care composition may comprise thickening polymers which are homopolymers based on acrylic acid, methacrylic acid or other related derivatives; non-limiting examples include polyacrylate, polymethacrylate, polyethyl acrylate and polyacrylamide.

[0121] The thickening polymers can be hydrophobically modified alkali expandable and alkali expandable alkaline acrylic copolymers or methacrylate copolymers; non-limiting examples include acrylic acid/acrylonitrogen copolymer, acrylate itaconate/steareth-20 copolymer, acrylate itaconate/cetet-20 copolymer, acrylate itaconate/aminoacrylate/C10 to 30 alkyl PEG-20 copolymer, acrylates/aminoacrylates, acrylates/stearet-20 methacrylate copolymer, acrylates/beenet-25 methacrylate copolymer, acrylates/stearet-20 methacrylate crosspolymer, acrylates/beenet-25 methacrylate/HEMA crosspolymer, acrylates/vinyl crosspolymer neodecanoate, acrylates/vinyl isodecanoate cross polymer, acrylates/palmet-25 acrylate copolymer, acrylic acid/acrylamidomethyl propane sulfonic acid copolymer, and acrylates/C10 to C30 alkyl acrylate cross polymer.

[0122] The thickening polymers can be soluble cross-linked acrylic polymers; a non-limiting example includes carbomers.

[0123] The thickening polymers can be an associative polymeric thickeners; non-limiting examples include: hydrophobically modified alkali swellable emulsions; non-limiting examples include hydrophobically modified polypolyacrylates; hydrophobically modified polyacrylic acids and hydrophobically modified polyacrylamides; hydrophobically modified polyethers wherein these materials may have a hydrophobe which may be selected from cetyl, stearyl, oleayl and combinations thereof.

[0124] The thickening polymers can be used in combination with polyvinyl pyrrolidone, cross-linked polyvinyl pyrrolidone and derivatives. Thickening polymers can be combined with polyvinyl alcohol and derivatives. Thickening polymers can be combined with polyethylene imine and its derivatives.

[0125] Thickening polymers can be combined with alginic acid-based materials; non-limiting examples include sodium alginate and propylene glycol esters of alginic acid.

[0126] Thickening polymers can be used in combination with polyurethane polymers; non-limiting examples include: hydrophobically modified alkoxylated urethane polymers; non-limiting examples include PEG-150/decyl alcohol/SMDI copolymer, PEG-150/stearyl alcohol/SMDI copolymer, polyurethane-39.

[0127] Thickening polymers can be combined with associative polymeric thickeners; non-limiting examples include: hydrophobically modified cellulose derivatives; and a hydrophilic moiety of repeating ethylene oxide groups with repeating units from about 10 to about 300, from about 30 to about 200, from about 40 to about 150. Non-limiting examples of this class include PEG- Methylglucose 120-dioleate, PEG-(40 or 60) sorbitan tetraoleate, PEG-150 pentaerythrityl tetrastearate, PEG-55 propylene glycol oleate, PEG-150 distearate.

[0128] Thickening polymers can be combined with cellulose and derivatives; non-limiting examples include microcrystalline cellulose, carboxymethylcelluloses, hydroxyethylcellulose, hydroxypropyl cellulose, hydroxypropyl methylcellulose, methylcellulose, ethylcellulose; nitro cellulose; cellulose sulfate; cellulose powder; hydrophobically modified celluloses.

[0129] The thickening polymers can be combined with guar gum and guar gum derivatives; non-limiting examples include hydroxypropyl guar hydroxypropyl guar and hydroxypropyl guar hydroxypropyl trimonium chloride.

[0130] Thickening polymers can be combined with polyethylene oxide; polypropylene oxide; and POE-PPO copolymers.

[0131] Thickening polymers can be combined with polyalkylene glycols characterized by the general formula: where R is hydrogen, methyl or mixtures thereof, and further hydrogen, and n is an integer having a mean of 2,000 to 180,000 or 7,000 to 90,000 or 7,000 to 45,000. Non-limiting examples of this class include PEG-7M, PEG-14M, PEG-23M, PEG-25M, PEG-45M, PEG-90M or PEG-100M.

[0132] Thickening polymers can be combined with silicas; non-limiting examples include pyrolyzed silica, precipitated silica, and silicone surface treated silica.

[0133] Thickening polymers can be combined with water-swellable clays; non-limiting examples include laponite, bentolite, montmorillonite, smectite, and hectonite.

[0134] The thickening polymers can be combined with gums; non-limiting examples include xanthan gum, guar gum, hydroxy propyl guar gum, gum arabic, tragacanth, galactan, locust bean gum, karaya gum and locust bean gum.

[0135] The thickening polymers can be combined with dibenzylidene sorbitol, karaggenan, pectin, agar, quince seed (Cydonia oblonga Mill), starch (from rice, corn, potato, wheat, etc.), starch derivatives (for example , carboxy methyl starch, methyl hydroxypropyl starch), seaweed extracts, dextran, succinoglucan and puleran.

[0136] Non-limiting examples of thickening polymers include acrylamide/ammonium acrylate copolymer (and) polyisobutene (and) polysorbate 20; acrylamide/acryloyl dimethyl sodium taurate/isohexadecane/polysorbate 80 copolymer, ammonium acryloyl dimethyl taurate/VP copolymer, sodium acrylate/sodium acryloyl dimethyl taurate copolymer, cross-polymer 4 of acrylates, cross-polymer-3 of acrylates, acrylates/beenet-25 methacrylate copolymer, acrylates/C10 to C30 alkyl acrylate crosspolymer, acrylates/stearet-20 itaconate copolymer, ammonium polyacrylate/isohexadecane/castor oil PEG-40; carbomer, sodium carbomer, cross-linked polyvinyl pyrrolidone (PVP), polyacrylamide/isoparaffin C13 to C14/lauret-7, polyacrylate 13/polyisobutene/polysorbate 20, polyacrylate cross-polymer-6, polyamide-3, polyquaternium-37 (and ) hydrogenated polydecene (and) tridecet-6, acrylamide/acryloyl dimethyl taurate sodium/acrylic acid copolymer, sodium acrylate/acryloyl dimethyl taurate/dimethylacrylamide, cross polymer (and) isohexadecane (and) polysorbate 60, sodium polyacrylate . Exemplary commercially available thickening polymers include ACULYN™ 28, ACULYN™ 33, ACULYN™ 88, ACULYN™ 22, ACULYN™ Excel, Carbopol® Aqua SF-1, Carbopol® ETD 2020, Carbopol® Ultrez 20, Carbopol® Ultrez 21, Carbopol® Ultrez 10, Carbopol® Ultrez 30, Carbopol® 1342, Carbopol® Aqua SF-2 Polymer, Sepigel™ 305, Simulgel™ 600, Sepimax Zen, Carbopol® SMART 1000, Rheocare® TTA, Rheomer® SC-Plus, STRUCTURE® PLUS, Aristoflex® AVC, Stabylen 30 and combinations thereof. Gel Net

[0137] In the present invention, a gel network may be present. The gel network component of the present invention comprises at least one fatty amphiphile. For use in the present invention, "fatty amphiphile" refers to a compound having a hydrophobic tail group as defined as an alkyl, alkenyl (containing up to 3 double bonds), aromatic alkyl or branched alkyl group of length C12 to C70 and group hydrophilic headstock which does not make the compound water soluble, the compound also having a net neutrality at the pH of the shampoo composition.

[0138] The shampoo compositions of the present invention comprise fatty amphiphile as part of the preformed dispersed gel network phase, in an amount of from about 0.05% to about 14%, preferably from about 0.5 % to about 10%, and from about 1% to about 8%, by weight of the shampoo composition.

[0139] According to the present invention, suitable fatty amphiphiles, or suitable mixtures of two or more fatty amphiphiles, have a melting point of at least about 27°C. The melting point of surfactants used in accordance with the present invention can be measured by a standard melting point method as described in US Pharmacopeia, USP-NF, General Chapter <741> "Melting range or temperature". The melting point of a mixture of two or more materials is determined by mixing two or more materials at a temperature above their respective melting points and then allowing the mixture to cool. If the resulting composite is a homogeneous solid below about 27°C, then the mixture has a suitable melting point for use in the present invention. A mixture of two or more fatty amphiphiles, in which the mixture comprises at least one fatty amphiphile having an individual melting point of less than about 27°C, is still suitable for use in the present invention provided that the composite melting point of the mixture be at least about 27°C.

[0140] Suitable fatty amphiphiles of the present invention include fatty alcohols, alkoxylated fatty alcohols, fatty phenols, alkoxylated fatty phenols, fatty amides, alkyloxylated fatty amides, fatty amines, fatty alkyl starch alkylamines, alkyloxylated fatty amines, fatty carbamates, fatty amine oxides, fatty acids, alkyloxylated fatty acids, fatty diesters, fatty sorbitan esters, fatty sugar esters, methyl glycoside esters, fatty glycol esters, mono, di and triglycerides, polyglycerin fatty esters, glyceryl alkyl ethers, propylene glycol fatty acid esters, cholesterol, ceramides, fatty silicone waxes, fatty amides glucose, phospholipids and combinations thereof.

[0141] The shampoo composition may comprise fatty alcohol gel nets. These gel networks are formed by combining fatty alcohols and surfactants in a ratio of from about 1:1 to about 40:1, from about 2:1 to about 20:1, and/or from about 3:1 to about 10:1. Formation of a gel network involves heating a dispersion of the fatty alcohol in water with the surfactant to a temperature above the melting point of the fatty alcohol. During the blending process, the fatty alcohol melts, allowing the surfactant to partition into fatty alcohol droplets. The surfactant carries water along with it into the fatty alcohol. This transforms isotropic fatty alcohol droplets into liquid crystalline phase droplets. When the mixture is cooled below the melting temperature of the chain, the liquid crystalline phase is converted into a solid crystalline gel network. The gel network contributes a stabilizing benefit to cosmetic creams and hair conditioners. Additionally, it provides the benefits of conditioning feel to hair conditioners.

[0142] The fatty alcohol can be included in the fatty alcohol gel network in a content, by weight, of about 0.05% by weight to about 14% by weight. For example, the fatty alcohol can be present in an amount in the range of from about 1% by weight to about 10% by weight and/or from about 6% by weight to about 8% by weight.

[0143]Useful fatty alcohols herein include those having from about 10 to about 40 carbon atoms, from about 12 to about 22 carbon atoms, from about 16 to about 22 carbon atoms, and/or from about 16 to about 18 carbon atoms. These fatty alcohols can be straight or branched chain, and can be saturated or unsaturated. Some non-limiting examples of fatty alcohols include cetyl alcohol, stearyl alcohol, behenyl alcohol and mixtures of these substances. Mixtures of cetyl and stearyl alcohols in ratios of about 20:80 to about 80:20 are suitable.

[0144] Preparation of the gel network: A vessel is filled with water and the water is heated to approximately 74 °C. Cetyl alcohol, stearyl alcohol, and SLES surfactant are added to the heated water. After incorporation, the resulting mixture is passed through a heat exchanger so that the mixture is cooled to about 35 °C. After cooling, the fatty alcohols and surfactant are crystallized to form a crystalline gel network. Table 1 provides the components and their respective amounts for the composition of the gel network.

1. WATER-MISCIBLE SOLVENTS

[0145] The carrier useful in the hair care composition may include water and water solutions of lower alkyl alcohols, polyhydric alcohols, ketones having 3 to 4 carbon atoms, C1 to C6 esters of C1 to C6 alcohols, sulfoxides , amides, carbonate esters, and C1 to C10 ethoxylated and propoxylated alcohols, lactones, pyrrolidones, and mixtures thereof. Examples of non-limiting lower alkyl alcohols are monohydric alcohols having from 1 to 6 carbons, such as ethanol and isopropanol. Some non-limiting examples of polyhydric alcohols useful in the present invention include propylene glycol, dipropylene glycol, butylene glycols, hexylene glycol, glycerin, propanediols and mixtures thereof.

[0146] The hair care composition may comprise a hydrotrope/viscosity modifier which is an alkali metal or ammonium salt of a lower alkylbenzene sulfonate such as sodium xylene sulfonate, sodium cumene sulfonate or sodium toluene sulfonate .

[0147] The hair care composition may comprise silicone/PEG-8 silicone/PEG-9 silicone/PEG-n silicone/silicone ether (n could be another integer), non-limiting examples include PEG8-dimethicone A208 ) PM 855, PEG8-dimethicone D208 PM 2706.

C. PROPELLENT OR EXPANSION AGENT

[0148] The hair care composition described herein may comprise from about 1% to about 10% propellant or blowing agent, alternatively from about 2% to about 8% propellant, by weight of the hair care composition. hair treatment.

[0149] The propellant or blowing agent may comprise one or more volatile materials which, in a gaseous state, may carry the other components of the hair care composition in particulate or droplet form or as a foam. The propellant or blowing agent may have a boiling point within the range of about -45°C to about 5°C. The propellant or blowing agent can be liquefied when packaged in conventional aerosol cans under pressure. The rapid boiling of the propellant or blowing agent as it exits the foam aerosol dispenser can aid in the atomization or foaming of the other components of the hair care composition.

[0150] Aerosol propellants or blowing agents that can be used in the aerosol composition may include chemically inert hydrocarbons such as propane, n-butane, isobutane, cyclopropane and mixtures thereof, as well as halogenated hydrocarbons such as dichlorodifluoromethane, 1,1- dichloro-1,1,2,2-tetrafluoroethane, 1-chloro-1,1-difluoro-2,2-trifluoethane, 1-chloro-1,1-difluoroethylene, 1,1-difluoroethane, dimethyl ether, monochlorodifluoromethane, trans -1,3,3,3-tetrafluoropropene and mixtures thereof. The propellant or blowing agent can comprise hydrocarbons such as isobutane, propane and butane - these materials can be used for their low reactivity to ozone and can be used as individual components where their vapor pressures at 21.1°C are in the range range from about 1.17 bar to about 7.45 bar alternatively from about 1.17 bar to about 4.83 bar and alternatively from about 2.14 bar to about 3.79 bar .

D. SCALP HEALTH AGENTS

[0151] In the present invention, one or more scalp health agents can be added to provide benefits to the scalp in addition to the anti-dandruff/fungicidal efficacy provided by the surfactant-soluble anti-dandruff agents. This group of materials is varied and provides a wide range of benefits including hydration, barrier enhancement, fungicide, antimicrobial and antioxidant, anti-itch and sensory elements and additional anti-dandruff agents such as polyvalent metal salts of pyrithione; non-limiting examples include zinc pyrithione (ZPT) and copper pyrithione, sulfur or selenium sulfide. Such scalp health agents include, but are not limited to: vitamins E and F, salicylic acid, niacinamide, caffeine, panthenol, zinc oxide, zinc carbonate, basic zinc carbonate, glycols, glycolic acid, PCA, PEGs , erythritol, glycerin, triclosan, lactates, hyaluronates, allantoin and other ureas, betaines, sorbitol, glutamates, xylitols, menthol, menthyl lactate, isocyclomonone, benzyl alcohol, a compound comprising the following structure: R1 is selected from H, alkyl, amino alkyl, alkoxy; Q = H2, O, -OR1, -N(R1)2, -OPO(OR1)x, -PO(OR1)x, -P(OR1)x, where x = 1-2; V = NR1, O, -OPO(OR1)x, -PO(OR1)x, -P(OR1)x, where x = 1-2; W = H2,O; X, Y = independently selected from H, aryl, naphthyl, for n=0; X, Y = aliphatic CH2 or aromatic CH for n > 1 and Z is selected from aliphatic CH2, aromatic CH2, or heteroatom; A = lower alkoxy, lower alkylthio, aryl, substituted aryl or fused aryl; and stereochemistry is variable at positions marked with *. and natural extracts/oils including spearmint, peppermint, argan, jojoba and aloe.

E. OPTIONAL INGREDIENTS

[0152] In the present invention, the hair care composition may further contain one or more optional ingredients, including suitable beneficial agents include beneficial agents, but are not limited to conditioning agents, cationic silicone polymers, anti-dandruff agents, gel nets, chelating agents, and natural oils such as sunflower oil or castor oil. Other suitable optional ingredients include, but are not limited to, perfumes, perfume microcapsules, colorants, particles, antimicrobials, defoamers, antistatic agents, rheology modifiers and thickeners, suspending materials and builders, pH adjusting agents and buffers , preservatives, pearlizing agents, solvents, diluents, antioxidants, vitamins and combinations thereof. The composition can be from about 0.5% to about 7% of a perfume.

[0153] Such optional ingredients must be physically and chemically compatible with the components of the composition and must not otherwise unduly impair the stability, aesthetics, or performance of the product. The CTFA Cosmetic Ingredient Handbook, 10th Edition (published by the Cosmetic, Toiletry, and Fragrance Association, Inc., Washington, D.C., USA) (2004) (hereinafter "CTFA"), describes a wide variety of non-limiting materials that can be added to the composition of the present composition.

1. Conditioning Agents

[0154] The conditioning agent of the hair care compositions may be a silicone-based conditioning agent. The silicone-based conditioning agent can comprise volatile silicone, non-volatile silicone, or combinations of these substances. The concentration of the silicone-based conditioning agent is typically in the range of from about 0.01% to about 10% by weight of the composition, from about 0.1% to about 8%, from about from 0.1% to about 5% and/or from about 0.2% to about 3%. Some non-limiting examples of suitable silicone-based conditioning agents, and optional silicone suspending agents, are described in Reissued U.S. Patent No. 34,584 and U.S. Patent No. 5,104,646 and U.S. Patent No. 5,106,609, which descriptions are here incorporated by reference.

[0155] Silicone-based conditioning agents for use in the compositions of the present invention can have a viscosity, as measured at 25°C, from about 20 to about 2,000,000 centistokes ("cSt"), from about 1,000 to about 1,800,000 cSt, from about 10,000 to about 1,500,000 cSt, and from about 20,000 to about 1,500,000 cSt.

[0156] The dispersed particles of silicone-based conditioning agent typically have an average diameter value in the range of about 0.01 micrometers to about 60 micrometers. For application of small particles to hair, volume average particle diameters are typically in the range from about 0.01 micrometers to about 4 micrometers, from about 0.01 micrometers to about 2 micrometers, from about 0 .01 micrometers to about 0.5 micrometers.

[0157] Additional material on silicones including sections discussing silicone fluids, gums, and resins, as well as their manufacture, can be found in Encyclopedia of Polymer Science and Engineering, vol. 15, 2a. ed., pgs. 204-308, John Wiley & Sons, Inc. (1989), incorporated herein by reference.

[0158] Silicone emulsions suitable for use in the present invention include, but are not limited to, insoluble polysiloxane emulsions. These can be prepared by emulsion polymerization, in accordance with the descriptions given in U.S. Patent No. 6,316,541 or U.S. Patent No. 4,476,282 or U.S. Patent Application Publication No. 2007/0276087, or they can be emulsified after polymerization is complete, by various emulsification methods as described in U.S. Patent 9,255,184B2 or U.S. Patent 7,683,119 or Emulsions and Emulsion Stability, edited by Johan Sjoblom, CRC Press, 2005. These references can be consulted for a non-limiting list of suitable emulsifiers and emulsifier blends based on the functionality of the silicone used, the method of emulsification and the desired emulsion particle size. Accordingly, suitable insoluble polysiloxanes include polysiloxanes such as alpha-, omega-hydroxy-terminated polysiloxanes or alpha-, omega-alkoxy-terminated polysiloxanes that have an internal phase viscosity of about 5 cSt to about 500,000 cSt. For example, the insoluble polysiloxane can have an internal phase viscosity of less than 400,000 csk; less than 200,000 csk; from around 10,000 csk to around 180,000 csk. The insoluble polysiloxane can have an average particle size within the range of about 10 nm to about 10 microns. The average particle size can range from about 15 nm to about 5 microns, from about 20 nm to about 1 micron, or from about 25 nm to about 550 nm, or from about 1 to 10 microns. The concentration of silicone dispersed in the emulsion can range from about 5 to 90 percent, or from 20 to 85 percent, or from 30 to 80 percent by weight of the emulsion composition.

[0159] The average molecular weight of the insoluble polysiloxane, the viscosity of the internal phase of the insoluble polysiloxane, the viscosity of the silicone emulsion and the size of the particle comprising the insoluble polysiloxane are determined by methods commonly used by those skilled in the art, such as the methods of present invention disclosed in Smith, A.L. The Analytical Chemistry of Silicones, John Wiley & Sons, Inc.: New York, 1991. For example, the viscosity of the silicone emulsion can be measured at 30°C with a Brookfield viscometer with 6 a spindle 2.5 rpm. The silicone emulsion may also contain an additional emulsifier together with the anionic surfactant,

[0160] Other classes of silicones suitable for use in the compositions of the present invention include, but are not limited to: i) silicone fluids, including, but not limited to, silicone oils, which are flowable materials having a viscosity of less than about 1,000. 000 cSt measured at 25 °C; ii) aminosilicones, which contain at least one primary, secondary or tertiary amine; iii) cationic silicones, which contain at least one quaternary ammonium functional group; iv) silicone gums; which include materials having a viscosity greater than or equal to 1,000,000 cSt measured at 25°C; v) silicone resins, which include highly cross-linked polymeric siloxane systems; vi) silicones with a high refractive index, having a refractive index of at least 1.46, and vii) mixtures thereof.

[0161] The conditioning agent of the hair care compositions of the present invention may also comprise at least one organic conditioning material such as oil or wax, either alone or in combination with other conditioning agents, such as the silicones described above. The organic material can be non-polymeric, oligomeric or polymeric. It can be in oil or wax form and can be added in neat composition or in a pre-emulsified form. Some non-limiting examples of organic conditioning materials include, but are not limited to: i) hydrocarbon oils; ii) polyolefins, iii) fatty esters, iv) fluorinated conditioning compounds, v) fatty alcohols, vi) alkyl glycosides and alkyl glycoside derivatives; vii) hydrophobic quaternary ammonium compounds; viii) polyethylene glycols and polypropylene glycols having a molecular weight of up to about 2,000,000, such as those whose CTFA names are PEG-200, PEG-400, PEG-600, PEG-1000, PEG-2M, PEG-7M, PEG-14M , PEG-45M, and mixtures thereof.

2. Emulsifiers

[0162] Various anionic and non-ionic surfactants can be used in the compositions of the present invention. Anionic and nonionic emulsifiers can be monomeric or polymeric in nature. Monomeric examples include, by way of illustration and not limitation, alkyl ethoxylates, alkyl sulfates, soaps, derivatives thereof, and acids and esters. Polymeric examples include, by way of illustration and not limitation, polyacrylates, polyethylene glycols, block copolymers and derivatives thereof. Naturally occurring emulsifiers such as lanolins, lecithin and lignin and their derivatives are also some non-limiting examples of useful emulsifiers.

3. Chelating agents

[0163] The hair treatment composition may also contain a chelating agent. Suitable chelators include those mentioned in A E Martell & R M Smith, Critical Stability Constants, Vol. 1, Plenum Press, New York & London (1974) and A E Martell & R D Hancock, Metal Complexes in Aqueous Solution, Plenum Press, New York & London (1996) both incorporated herein by reference. When referring to chelants, the term "salts and derivatives thereof" means those salts and derivatives which comprise the same functional structure (e.g. the same chemical structure) as the chelator to which they refer and which have similar or better chelating properties. This term includes alkali metal, alkaline earth, ammonium, substituted ammonium salts (i.e. monoethanol ammonium, diethanol ammonium, triethanol ammonium), esters of chelators with an acid moiety, and mixtures thereof, in particular, all sodium salts , potassium or ammonium. The term "derivatives" also includes "chelating surfactant" compounds, such as those exemplified in U.S. Patent No. 5,284,972, and large molecules comprising one or more chelating groups that have the same functional structure as the original chelating agents, such as polymeric EDDS (ethylenediamine disuccinic acid ), described in US Patent No. 5,747,440.

[0164] The chelating agents can be incorporated into the compositions of the present invention in amounts ranging from 0.001% to 10.0% by weight of the total composition. from about 0.01% to 2.0%.

[0165] The classes of non-limiting chelating agents include carboxylic acids, amino carboxylic acids, including amino acids, phosphoric acids, phosphonic acids, polyphosphonic acids, polyethylene imines, polyfunctionally substituted aromatics, their derivatives and salts.

[0166] Non-limiting chelating agents include the following materials and their salts. Ethylenediaminetetraacetic acid (EDTA), ethylenediamine triacetic acid, ethylenediamine-N,N'-disuccinic acid (EDDS), ethylenediamine-N,N'-diglutaric acid (EDDG), salicylic acid, aspartic acid, glutamic acid, glycine, malonic acid, histidine, diethylenetriaminepentacetate (DTPA), N-hydroxyethylethylenediaminetriacetate, nitrilotriacetate, ethylenediaminetetrapropionate, tritylenetetraaminohexacetate, ethanoldiglycine, propylenediaminetetraacetic acid (PDTA), methylglycinediacetic acid (MODA), diethylenetriaminepentaacetic acid, methylglycinediacetic acid (MGDA) , N-acyl-N,N',N'-ethylenediaminetriacetic acid, nitrilotriacetic acid, ethylenediaminediglutaric acid (EDGA), 2-hydroxypropylenediamine disuccinic acid (HPDS), glycinamido-N,N'-disuccinic acid (GADS), 2- hydroxypropylenediamine-N-N'-disuccinic acid (HPDDS), N-2-hydroxyethyl-N,N-diacetic acid, glyceryliminodiacetic acid, iminodiacetic acid-N-2-hydroxypropyl sulfonic acid, aspartic acid N-carboxymethyl-N-2-acid hydroxypropyl-3-sulfonic acid, alanine-N,N'-diacetic acid, aspartic acid-N,N'-diaceic acid, aspartic acid N-monoacetic acid, iminodisuccinic acid, diamino-N,N'-dipolyacid, monoamide-N, N'-dipoly acid, diaminoalkyldi(sulfosuccinic acid) (DDS), ethylenediamine-N-N'-bis(orthohydroxyphenyl acetic acid)), N,N'-bis(2-hydroxybenzyl)ethylenediamine-N,N'- acid diacetic acid, ethylenediaminetetrapropionate, triethylenetetraaminohexacetate, diethylenetriaminepentacetate, dipicolinic acid, ethylenedicysteic acid (EDC), ethylenediamine-N,N'-bis(2-hydroxyphenylacetic acid) (EDDHA), glutamic acid diacetic acid (GLDA), hexadentate aminocarboxylate (HBED), polyethyleneimine, 1-hydroxydiphosphonate, aminotri(methylenephosphonate) (ATMP), nitrilotrimethylenephosphonate (NTP), ethylenediaminetetramethylenephosphonate, diethylenetriaminepentamethylenephosphonate (DTPMP), ethane-1-hydroxydiphosphonate (HEDP), 2-phosphonobutane-1,2,4-acid tricarboxylic acid, polyphosphoric acid, sodium tripolyphosphate, tetrasodium diphosphate, hexametaphosphoric acid, sodium metaphosphate, phosphonic acid and derivatives, aminoalkylene-poly(alkylenephosphonic acid), aminotri(1-ethylphosphonic acid), ethylenediaminetetra(1-ethylphosphonic) acid, aminotri(1-propylphosphonic acid), aminotri(isopropylphosphonic acid), ethylenediaminetetra(methylenephosphonic acid) (EDTMP), 1,2-dihydroxy-3,5-disulfobenzene. Aqueous Carrier Vehicle

[0167] Hair treatment compositions may be in the form of pourable liquids (under ambient conditions). Such compositions will therefore typically comprise a carrier, which is present in a content of from about 40% to about 85%, alternatively, from about 45% to about 80%, alternatively, from about 50% to about 75% by weight of the hair care composition. The vehicle may contain water or a miscible mixture of water and organic solvent, and, in one aspect, may comprise water with little or no significant concentration of organic solvent, except when consequently incorporated into the composition, as minor ingredients of other essential or optional components. .

[0168] The carrier which may be useful in the hair care compositions of the present invention may include water and aqueous solutions of lower alkyl alcohols and polyhydric alcohols. Lower alkyl alcohols useful in the present invention are monohydric alcohols having from 1 to 6 carbons, in one aspect, ethanol and isopropanol. Exemplary polyhydric alcohols useful in the present invention include propylene glycol, hexylene glycol, glycerin and propanediol.

G. FOAM DISPENSER

[0169] The hair care composition described herein can be supplied in a foam dispenser. The foam dispenser may be an aerosol foam dispenser. The aerosol foam dispenser may comprise a reservoir for holding the hair care composition. The reservoir may be made of any suitable material selected from the group consisting of plastic, metal, alloy, laminate and combinations thereof. The reservoir can be used only once. The reservoir can be removed from the aerosol foam dispenser. Alternatively, the reservoir can be integrated into the aerosol foam dispenser. And there can be two or more reservoirs.

[0170] The foam can also be a mechanical foam dispenser. The described mechanical foam dispenser may be selected from the group consisting of compressible foam dispensers, pump foam dispensers, other mechanical foam dispensers, and combinations thereof. The mechanical foam dispenser can be a squeeze foam dispenser. Non-limiting examples of suitable pump dispensers include those described in WO 2004/078903, WO 2004/078901 and WO 2005/078063 and can be supplied by Albea (60 Electric Ave., Thomaston, CT 06787, USA) or Rieke Packaging Systems (500 West Seventh St., Auburn, Indiana 46706).

[0171] The mechanical foam dispenser may comprise a reservoir for containing the hair care composition. The reservoir may be made of any suitable material selected from the group consisting of plastic, metal, alloy, laminate and combinations thereof. The reservoir may be a refillable reservoir such as a pour-on or screw-on reservoir, or the reservoir may be for single use. The reservoir may also be removable from the mechanical foam dispenser. Alternatively, the reservoir can be integrated into the mechanical foam dispenser. And there can be two or more reservoirs.

[0172] The reservoir may be comprised of a material selected from the group consisting of rigid materials, flexible materials and combinations thereof. The reservoir may be comprised of a rigid material so as not to flatten under external atmospheric pressure when subjected to an internal partial vacuum.

H. PRODUCT FORM

[0173] The hair treatment compositions of the present invention can be presented in typical hair treatment formulations. They can be in the form of solutions, dispersions, emulsions, powders, talcs, encapsulates, beads, sponges, solid dosage forms, foams and other delivery mechanisms. The compositions of the present invention can be hair tonics, leave-in hair products such as treatment and styling products, rinse-off hair products such as shampoos and personal care products and treatment products; and any other form that can be applied to the hair.

I. APPLICATOR

[0174] In the present invention, the hair care composition can be dispensed from an applicator for dispensing directly onto the scalp area. Direct dispensing onto the scalp, via targeted application from an applicator, allows the deposition of undiluted cleaning agents directly where cleaning needs are greatest. This also minimizes the risk of eye contact with the cleaning solution.

[0175] The applicator is attached or can be attached to a bottle containing the hair care cleaning composition. The applicator may consist of a base that retains or extends to a single tip or a plurality of tips. The ends have openings which may be located at the end, or anywhere between the end and the base. These openings allow the product to be dispensed from the bottle directly onto the hair and/or scalp.

[0176] Alternatively, the applicator may also consist of fixed or brush-shaped bristles or extending from a base. In this case, the product can be dispensed from the base and the bristles can allow the distribution of the product through the combing or brushing movement.

[0177] The design of the applicator and the tip and the materials can also be optimized to allow massage of the scalp. In this case, it may be beneficial for the geometry of the tip or the bristles at the ends to be more rounded similar to the ball applicator used for eye creams. It may also be beneficial for materials to be smoother and softer; for example, metallic or metal-like finishes, "rubbery materials". Measurement of Deposition of Soluble Agent in Surfactant

[0178] Deposition of the surfactant-soluble agent in vivo on the scalp can be determined by ethanol extraction of the agent after the scalp has been treated with a cleansing composition containing surfactant-soluble agent and rinsed. The agent concentration in the ethanol extraction solvent is measured by HPLC. Quantification is done by reference to a standard curve. The concentration detected by HPLC is converted to a collected amount using the concentration in grams multiplied by volume.

[0179] The percentage of deposited agent can be calculated using the following equation:

[0180] Sample calculation by % depositive piroctone olamine, where: Grams of deposited Agent = 1.7x10-6 g Extracted scalp area = 1 cm2 % by weight of piroctone olamine in shampoo = 1.0% Grams of applied shampoo = 5 g Treated scalp area = 300 cm2 % deposited piroctone olamine = 1.02%

[0181] The deposition efficiency can be calculated using the following equation:

[0182] Calculation sample for deposition efficiency, where: % of piroctone olamine deposited by the example formula = 1.92% % of piroctone olamine deposited by the control formula = 1.02%

Preparation of Shampoo Compositions

[0183] Shampoo compositions are prepared by adding surfactants, anti-dandruff agents, perfumes, viscosity modifiers, cationic polymers, and the rest of the water with extensive stirring to ensure a homogeneous mixture. The mixture can be heated to 50 to 75°C to accelerate the solubilization of soluble agents, then cooled. Product pH can be adjusted as necessary to provide shampoo compositions of the present invention that are suitable for application to human hair and scalp, and can range from about pH 4 to 9 or from about pH 4 to 6 or about pH 4.5 to 5.5, based on the selection of specific detersive surfactants and/or other components.

Non-limiting examples

[0184] The compositions illustrated in the Examples below are prepared using conventional formulating and mixing methods. All exemplified amounts are quoted as percent by weight on an active basis and exclude minor materials such as diluents, preservatives, color solutions, imaging ingredient, botanicals, and so on, unless otherwise specified. All percentages are based on weight unless otherwise specified. Discussion of Results for Examples 1 to 6

[0185] Example 2 is a comparative example that demonstrates that decreasing only the surfactant level increases the deposition efficiency only to 1.3X that of the control (Example 1). Examples 4 and 6 are comparative examples showing that the combination of lower surfactant contents with a cationic polymer whose molecular weight (MW) and charge density (CD) do not satisfy the equation CD + 8x10-7*MW - 1, 5 > 0 increases the deposition efficiency only to 1.3X that of their respective controls (Examples 3 and 5). Discussion of the Results of Examples 7 to 20

[0186]Examples 7, 10, 13, 16 and 19 are controls. The remaining examples in this set (Examples 7 to 20) are representative compositions of the present invention that contain lower levels of surfactant in combination with cationic polymers with CD and MW that satisfy the equation CD + 8x10 -7*MW -1.5 ^ 0 and, in turn, demonstrate increased deposition efficiencies of 1.4X to 2.2X over those of the respective controls. These deposition efficiencies are higher than those observed in Examples 2, 4 and 6, where only the surfactant content is reduced or where a lower surfactant content is combined with CD & MW cationic polymers that do not satisfy the CD + equation 8x10-7*MW - 1.5 > 0.

[0187] The examples presented below are intended to illustrate, but not to limit, the present invention: Additional Examples/Combinations A. A hair care composition comprising: a) 8 to 16% of one or more surfactants b) 0.01% to 10% of one or more surfactant-soluble antidandruff agents; c) 0.01 to 5% of one or more cationic polymers having a molecular weight (MW) from about 250,000 to about 2,600,000 g/mol and a charge density (CD) from about 0.25 to about from 7.0 meq/g; where CD + 8x10-7*MW - 1.5 > 0 and where the composition has a deposition efficiency of about 1.4X to about 3X that of a control composition, where the control composition comprises 14 % SLE1S, no polymeric constituents, 1% surfactant soluble anti-dandruff agent at a pH of about 6. B. A hair treatment composition according to paragraph A, wherein the one or more cationic polymers have a charge density (CD) from about 1.0 to about 7.0 meq/g. C. A hair care composition according to paragraphs A to B, wherein the one or more cationic polymers have a charge density (CD) of from about 1.0 to about 3.0 meq/g . D. A hair care composition in accordance with Paragraphs A to C, the one or more cationic polymers having a molecular weight (MW) of from about 300,000 to about 2,600,000 g/mol. E. A hair care composition according to paragraphs A to D, the one or more cationic polymers having a molecular weight (MW) of from about 700,000 to about 2,600,000 g/mol. F. A hair care composition in accordance with paragraphs A to E, wherein the composition has a deposition efficiency of about 1.5X to about 2.5X that of a control composition, wherein the composition control comprises 14% SLE1S, no polymeric constituents, 1% surfactant soluble anti-dandruff agent at a pH of about 6. G. A hair care composition in accordance with Paragraphs A to F, the composition having a deposition efficiency of about 1.6X to about 2.3X that of a control composition, wherein the control composition comprises 14% SLE1S, no polymeric constituents, 1% surfactant-soluble anti-dandruff agent at a pH of about 6. H. A hair care composition according to paragraphs A to G, the one or more cationic polymers having a molecular weight (MW) of from about 700,000 to about 1,500,000 g/mol and a charge density (CD) of from about 0.8 to about 1.6 meq/g. I. A hair care composition according to paragraphs A to H, the one or more cationic polymers having a molecular weight (MW) of from about 1,000,000 to about 2,600,000 g/mol and a density loading (CD) from about 0.7 to about 1.0 meq/g. J. A hair care composition according to paragraphs A to I, the one or more cationic polymers having a molecular weight (MW) of from about 1,000,000 to about 2,200,000 g/mol and a density loading (CD) from about 1.2 to about 2.2 meq/g. K. A hair care composition according to paragraphs A to J, the one or more cationic polymers having a molecular weight (MW) of from about 1,000,000 to about 2,200,000 g/mol and a density loading (CD) from about 1.7 to about 2.2 meq/g. L. A hair care composition according to paragraphs A to K, the surfactant being an anionic surfactant or combinations of anionic surfactants. M. A hair care composition according to paragraphs A to L, wherein the surfactant is an anionic surfactant selected from the group consisting of anionic alkyl sulfates and alkyl ether sulfates having straight or branched alkyl chains and mixtures of the same. N. A hair care composition according to paragraphs A to M, wherein the surfactant is a surfactant or a combination of surfactants selected from the group consisting of sodium lauryl sulfate, sodium laureth-n sulfate, wherein n is from about 0.5 to about 3.5, C10 to 15 alkyl sodium sulfate, where the alkyl chain may be straight or branched, paret-n C10 to 15 sodium sulfate, where n is between about 0.5 and about 3.5 and the alkyl chain can be straight or branched, sodium decyl sulfate, sodium decet-n sulfate where n is between about 0.5 and about 3.5, sodium undecyl sulfate, sodium undecet-n sulfate where n is between 0.5 and about 3.5, sodium tridecyl sulfate, sodium tridecet-n sulfate where n is located if between about 0.5 and about 3.5, an anionic surfactant selected from the group consisting of: a) R1 O(CH2CHR3O)y SO3M; b) CH3 (CH2)z CHR2 CH2 O (CH2 CHR3O)y SO3M; and c) their mixtures, in which R1 represents CH3 (CH2)10, R2 represents H or a hydrocarbon radical comprising from 1 to 4 carbon atoms such that the sum of carbon atoms in z and R2 is 8, R3 is H or CH3 , y is 0 to 7, the average value of y is about 1 when y is not zero (0), and M is a positively charged monovalent or divalent cation. O. A hair care composition in accordance with Paragraphs A to N, wherein one or more surfactants are present from about 8% to about 14%. P. A hair care composition in accordance with Paragraphs A to O, wherein one or more surfactants are present from about 10% to about 14%. Q. A hair care composition in accordance with Paragraphs A to P, further comprising from about 0.25% to about 15% of one or more amphoteric, nonionic or zwitterionic cosurfactants. A. A hair care composition according to Paragraphs A to Q, the one or more cationic polymers being selected from the group consisting of a cationic polymer of guar, a cationic polymer of non-guar galactomannan, a cationic tapioca polymer, a cationic copolymer of acrylamide monomers and cationic monomers, a non-crosslinked synthetic cationic polymer, which may or may not form lyotropic liquid crystals upon combination with the detersive surfactant, a cationic cellulose polymer and mixtures thereof. S. A hair care composition in accordance with Paragraphs A to R, the one or more cationic polymers being selected from the group consisting of hydroxy propyl triammonium guar chloride, epoxide-reacted hydroxy ethyl cellulose salts substituted by trimethylammonium, a cationic copolymer of acrylamide monomers and cationic monomers, a non-crosslinked synthetic cationic polymer, which may or may not form lyotropic liquid crystals upon combination with the detersive surfactant. T. A hair care composition according to Paragraphs A to S, wherein the one or more cationic polymers are present from about 0.08% to about 3%. U. A hair care composition in accordance with Paragraphs A to T, wherein the one or more cationic polymers are present at from about 0.1% to about 2%. V. A hair care composition according to Paragraphs A to U, wherein the one or more cationic polymers are present at from about 0.2% to about 1%. W. A hair care composition according to paragraphs A to V, further comprising 0.1% to about 10% of one or more of a thickening polymer. X. A hair care composition according to paragraphs A to W, the one or more thickening polymers being selected from the group consisting of homopolymers based on acrylic acid, methacrylic acid or other related derivatives, alkali swellable and expandable hydrophobically modified alkali acrylic copolymers or methacrylic copolymers, soluble crosslinked acrylic polymers, associative polymeric thickeners and mixtures thereof. Y. A hair care composition according to Paragraphs A to X, the surfactant soluble agent being a pyridone hydroxyl. Z. A hair care composition according to paragraphs A to Y, the hydroxyl pyridone being piroctone olamine. AA. Z. A hair care composition according to Paragraphs A to Z, the surfactant-soluble agent being an azole. BB. A hair care composition according to paragraphs A to AA, the azole being climbazole. CC. A hair care composition according to Paragraphs A to BB further comprising one or more scalp health agents. DD. A hair care composition in accordance with Paragraphs A to CC, the one or more scalp health agents selected from the group consisting of pyridinothione salts, selenium sulfide, particulate sulfur, salicylic acid, menthol , menthyl lactate and mixtures thereof. AND IS. A hair care composition according to Paragraphs A to DD, wherein the one or more scalp health agents are polyvalent metal salts of pyrithione. FF. A hair care composition according to paragraphs A to EE, the one or more scalp health agents being zinc pyrithione. GG. A hair care composition in accordance with paragraphs A to FF, wherein the one or more scalp health agents are present at about 0.1% to 9%. HH. A hair care composition in accordance with Paragraphs A to GG, wherein the one or more scalp health agents are present at about 0.25% to 8%. II. A hair care composition according to paragraphs A to HH, the pH of the composition being between about 4 and about 9. JJ. A hair care composition according to Paragraphs A to II, the pH of the composition being between about 4 and about 6. KK. A hair care composition according to paragraphs A to JJ, the pH of the composition being between about 4.5 to about 5.5.

[0188] The dimensions and values disclosed herein should not be understood as being strictly limited to the exact numerical values mentioned. Rather, unless otherwise specified, each of these dimensions is intended to mean both the stated value and a range of functionally equivalent values surrounding that value. For example, a dimension revealed as "40mm" would mean "about 40mm".

[0189] Each document cited in the present invention, including any patent or patent application in cross-reference or related reference, and any patent or patent application in which the present application claims priority or benefit thereof, is hereby fully incorporated herein by reference , except where expressly excluded or otherwise limited. Mention of any document is not an admission that it is prior art in relation to any invention disclosed or claimed herein, nor that it, by itself or in any combination with any other reference or references, teaches, suggests or discloses such an invention. In addition, if there is a conflict between any meaning or definition of a term mentioned in this document and any meaning or definition of the same term in a document incorporated by reference, the meaning or definition given to that term in this document will take precedence.

[0190] While specific embodiments of the present invention have been illustrated and described, it will be apparent to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is intended, therefore, to cover in the appended claims all such changes and modifications that fall within the scope of the present invention.

Claims (10)

1. Composition for hair treatment, characterized by comprising: a. from 8 to 16% of at least one surfactant, by weight of the hair care composition, wherein said surfactant is an anionic surfactant or combinations of anionic surfactants, wherein the surfactant is an anionic surfactant selected from the group consisting of anionic sulfates alkyl and alkyl ether sulfates having straight or branched alkyl chains and mixtures thereof; B. from 0.01 to 10% of at least one surfactant-soluble antidandruff agent, by weight of the hair care composition, wherein the surfactant-soluble agent is a hydroxylpyridone, wherein the total amount of surfactant-soluble antidandruff agents ranges from 0 .01 to 10% by weight of the hair care composition; w. from 0.01 to 5% of at least one cationic polymer having a charge density (DC) of 1.5 to 2.2 meq/g by weight of the hair care composition, wherein the total amount of the cationic polymer having a molecular weight (MW) from 250,000 to 2,600,000 g/mol and a charge density (CD) from 0.25 to 7.0 meq/g ranges from 0.01 to 5% by weight of the hair care composition; where CD + (8 x 10-7)*MW - 1.5 > 0 and where the composition has a deposition efficiency of 1.4X to 3X relative to a control composition, where the control composition comprises: 14% sodium laureth-1 sulfate, SLE1S, (sodium laureth-1 sulfate), is free of polymeric constituents and 1% surfactant-soluble anti-dandruff agent at pH = 6. 2. Composition for hair treatment, according to claim 1, characterized in that it has a deposition efficiency of 1.5X to 2.5X compared to a control composition, in which the control composition comprises 14% of SLE1S, is free of polymeric constituent and 1% surfactant soluble anti-dandruff agent at a pH = 6, preferably a deposition efficiency of 1.6X to 2.3X over a control composition, wherein the control composition comprises 14% of SLE1S, free of polymeric constituents, and 1% of anti-dandruff agent soluble in surfactant at pH = 6. 3. Composition for hair treatment, according to any one of the preceding claims, characterized in that the surfactant is a surfactant or combination of surfactants selected from the group consisting of sodium lauryl sulfate, sodium laureth-n sulfate, in which n is between 0.5 to 3.5, sodium C10-15 alkyl sulfate, where the alkyl chain may be straight or branched, paret-n sodium C10-15 sulfate, where n is between 0.5 to 3.5 and the alkyl chain can be straight or branched, sodium decyl sulfate, sodium decet-n sulfate where n is between 0.5 to 3.5, sodium undecyl sulfate, sodium undecet-n sulfate where n is between 0.5 to 3.5, sodium tridecyl sulfate, sodium tridecet-n sulfate where n is between 0.5 to 3.5, an anionic surfactant selected from the group consisting of: a. R1O(CH2CHR3O)ySO3M; B. CH3(CH2)zCHR2CH2O(CH2CHR3O)ySO3M; and c. mixtures thereof, wherein R1 represents CH3(CH2)10, R2 represents H or a hydrocarbon radical including from 1 to 4 carbon atoms such that the sum of carbon atoms in z and R2 is 8, R3 is H or CH3, y is 0 to 7, the average value of y is 1 when y is not zero (0), and M is a positively charged monovalent or divalent cation. 4. Hair treatment composition, according to any one of the preceding claims, characterized in that at least one surfactant is present from 8% to 14% by weight of the hair treatment composition, preferably from 10% to 14%. 5. Composition for hair treatment, according to any one of the preceding claims, characterized in that it includes from 0.25% to 15% of at least one amphoteric, nonionic or zwitterionic co-surfactant, by weight of the composition for hair treatment. 6. Composition for hair treatment, according to any one of the previous claims, characterized in that at least one cationic polymer is from 0.08% to 3% by weight of the composition for hair treatment, in which at least one cationic polymer is, preferably , from 0.1% to 2%, preferably from 0.2% to 1%, selected from the group consisting of a cationic polymer of guar, a cationic polymer of non-guar galactomannan, a cationic polymer of tapioca, a cationic copolymer of acrylamide monomers and cationic monomers, a synthetic non-crosslinked cationic polymer, which may or may not form lyotropic liquid crystals upon combination with the detersive surfactant, a cationic cellulose polymer and mixtures thereof, preferably from the group consisting of guar hydroxypropyltriammonium chloride, trimethylammonium epoxide-reacted hydroxyethylcellulose salts, a cationic copolymer of acrylamide monomers and cationic monomers, a synthetic non-crosslinked cationic polymer, which may or may not form lyotropic liquid crystals upon combination with the detersive surfactant. 7. Composition for hair treatment, according to any one of the preceding claims, characterized in that it includes from 0.1% to 10% of at least one thickening polymer, by weight of the composition for hair treatment, in which at least one thickener polymer is selected from the group consisting of homopolymers based on acrylic acid, methacrylic acid or other related derivatives, expandable alkali and hydrophobically modified alkali expandable acrylic copolymers or methacrylate copolymers, soluble crosslinked acrylic polymers, associative polymeric thickeners and mixtures thereof. 8. Composition for hair treatment, according to any one of the preceding claims, characterized by the fact that hydroxylpyridone is piroctone olamine. 9. Composition for hair treatment, according to any one of the preceding claims, characterized in that it includes from 0.1% to 9%, preferably from 0.25% to 8% of at least one scalp health agent , by weight of the hair care composition, preferably wherein at least one scalp health agent is sulfur, salicylic acid, menthol, menthyl lactate and mixtures thereof, preferably wherein at least one scalp health agent is salt pyrithione polyvalent metal, preferably wherein at least one scalp health agent is pyrithione zinc. 10. Composition for hair treatment, according to any one of the preceding claims, characterized in that the pH of the composition is in the range of 4 to 9, preferably 4 to 6, preferably 4.5 to 5.5.