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AU652663B2 - Process for the manufacture of membrane-covered fertilizer granules - Google Patents

Process for the manufacture of membrane-covered fertilizer granules Download PDF

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Publication number
AU652663B2
AU652663B2 AU24399/92A AU2439992A AU652663B2 AU 652663 B2 AU652663 B2 AU 652663B2 AU 24399/92 A AU24399/92 A AU 24399/92A AU 2439992 A AU2439992 A AU 2439992A AU 652663 B2 AU652663 B2 AU 652663B2
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AU
Australia
Prior art keywords
fertilizer granules
membrane
coating
granules
release
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU24399/92A
Other versions
AU2439992A (en
Inventor
Horst Burger
Michael Jaschkowitz
Bernhard Kloth
Wilhelm Kohl
Holger Wegener
Peter Wehr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aglukon Spezialduenger GmbH
Original Assignee
Aglukon Spezialduenger GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Publication of AU2439992A publication Critical patent/AU2439992A/en
Application granted granted Critical
Publication of AU652663B2 publication Critical patent/AU652663B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/30Layered or coated, e.g. dust-preventing coatings
    • C05G5/37Layered or coated, e.g. dust-preventing coatings layered or coated with a polymer

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  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Fertilizers (AREA)
  • Medicinal Preparation (AREA)

Abstract

Described is a process for the manufacture of membrane-covered fertilizer granules by coating the granules with films of a mixture of a polyisocyanate and a polyol, the coating compound being applied in proportions such that each film has a thickness of 10 to 30 $g(m)m, preferably 15 to 20 $g(m)m. The granular fertilizer manufactured in this way has the advantage that it initially emphasizes nitrogen release and subsequently potassium release.

Description

OPI DATE 16/03/93 A03' DATE 27/05/93 APPLN. ID 24399/92 111111IlD II~ PCT NUMBER PCT/0E92/00697 ~I AU9224399 (51) Internationale Patentklassifikation 5 (11) Internationale Veri'ntlichungsnummer: WO 93/04017 3/00 Al (43) Internationales Verdiffentlichungsdatum: 4. Milrz 1993 (04.03,93) (21) Internationales Aktenzeichen: PCT/DE92/00697 (74) Anwalt: SCHERING AKTIENGESELLSCHAFT; Gewerblicher Rechtsschutz, Postfach 65 03 11, Mtlllerstras- (22) Internationales Anmeldedatum: 18. August 1992 (18.08.92) se 170-178, D-1000 Berlin 65 (DE).
Priori tfitsdaten: (81) Bestimmungsstaatcn: AU, CA, CS, Fl, HU, JP, NO, PL, P 4127 459.8 20. August 1991 (20.08.91) DE RU, US, europ~lisches Patent (AT, BE, CH, DE, DK, ES, FR, GB, GR, IE, IT, LU, MC, NL, SE).
(71) Arimelder (Itir alle Bestirnungsmtaten ausser US): AGLU- KON SPEZIALDtJNGER GMBH [DE/DE]; Postfach Veriiffentlicht 190 343, Heerdter Landstrasse 199, D-4000 Dflsseldorf Mit internationalein Reclwrclwnbericzt.
I1I (DE).
(72) Erfinder; mid
M
Erfinder/Aninelder (hur fir US) BORGER, Horst [DE/ DE]; In der Schindskaule 9, D-5000 K6ln 90 (DE).
4154 OWTZ Micshr a eKlOTrhr [DE/DE]; 6 5hnsr 0a -2 6 41A4SCHKsOsITZ MichEl KDE/DH Bentr. 20a, D- Schirmerstr. 29, D-5000 Ki6ln 30 KOHL, Wilhelm [DE/DE]; Neusserstr. 74, D-4047 Dorinagen I11 (DE).
WEGENER, Holger [DE/DE]; Matthiasstr. 16, D-4040 Neuss 1 WEHR, Peter [DE/DE]; Eupenerstr. D-4000 Dilsseldorf I11 (DE).
(54)TitleL. PROCESS FOR THE MANUFACTURE OF MEMBRANE-COVERED FERTILIZER GRANULES (54) Bezeichnung: VERFAHREN ZUR HERSTELLUNG VON MEMBRANUMHOLLTEN DONGEMiTfELGRANULA-
TEN
(57) Abstract Described is a process for the manufacture of membrane-covered fertilizer granules by coating the granules with films of a mixture of a polyisocyanate and a polyol, the coating compound being applied in proportions such that each film has a thickness of 10 to 30 lim, preferably 15 to 20 g.m. The granular fertilizer manufactured in this way has the advantage that it initially emphasizes nitrogen release and subsequently potassium release.
(57) Zusammenfassung Es wird emn Verfahren zur Herstellung von membranumhillten Dungemittelgranulaten durch schichtweises Aufbringen eines Gemisches von Polyisocyanat und Polyol beschrieben, bel dem die Beschichtungsmasse in Anteilen so appliziert wird, dag die Schichten jeweils eine Schichtdicke von 10-30 gim, vorzugsweise von 15-20 im haben. Die so hergestellten Dtlngemittelgranulate haben den Vorteil einer anfflnglichen Stickstoffbetonung und einer spflteren Kaliumbetonung.
b r Pr~ocess for the preparation of membrane-coated fertilizer granules The invention relates to a process for the preparation of membrane-coated fertilizer granules for demand-related plant feeding.
Nowadays, modern, environmentally acceptable and demand-related plant feeding is based to an increasing extent on long-acting fertilizers which are characterised by chemical modification of the nutrients or by coating soluble.fertilizer granules.
Coated long-acting fertilizers are described in numerous patents.
Urea formaldehyde resins, PE, PP, alkyd resins, epoxy resins and recently polyurethane resins, amongst others, are used as coating agents DE 3 544 451, US 3 264 088, GB 1 011 463, EP 0 276 179, DE 2 834 513, US 3 223 518, NL patent 129 279). With the systems mentioned, it has proved more or less possible to modify the nutrient releases over time so that release periods can be achieved for fairly short or fairly long growing times.
A disadvantage of the well known methods is that, until now, parameters for demand-related plant feeding, homogeneity of the individual particle coating, physical resilience, frost resistance, could be solved only incompletely, if at all. In particular, it has not been possible hitherto to control the release of individual nutrients from special salt mixtures in such as way that the release of potassium is delayed to a greater extent compared with nitrogen.
The aim of the invention is to overcome the well known disadvantages. An economic, industrial production process has now been found which, with sufficient homogeneity of the individual particle coating, makes it possible to produce physically resilient, frost-resistant granulated material from which the controlled, delayed release of nutrients takes place as defined by Fick's laws of diffusion.
An important prerequisite for obtaining high mechanical resilience is the selection of a highly resilient coating i V' material which, when it is applied to the fertilizer granules, shows its mechanical properties to their best advantage.
A solvent-free two-component polyurethane resin system that can be processed at room temperature and which can be cured by amine catalysis within very short periods (compare DE 3544 451) has proved to be suitable for coating according to the invention.
The coating process according to the invention is carried out in a drum which is provided with special attachments. On the one hand, specially shaped mixing blades ensure the homogeneity of the mixture, and on the other hand air channels lead into the bed of granulated material so as to be able to aerate said bed intensively. The reaction takes place in a closed system.
The granules for said coating process must be largely spherical, low-dust, attrition-resistant, break-proof and the nutrients contained therein must be largely water-soluble. A narrow particle size distribution of the granules is advantageous, the factor 3 between the smallest and the largest particles of granulated material being sufficient.
A coating process is described in DE 35 44 451 in which, with a planned granulated material coating of 15% by wt. coating, based on the end product, the coating compound composed of polyisocyanate and polyol is deposited 3 times in 5% portions with simultaneous permanent catalyst gassing with amine-saturated nitrogen gas at 20 The outcome of such a coating leads to an initial release of up to 18% after 24 hours (example 1).
The release of electrolytes from plastics-coated fertilizers in an aqueous solution is determined by measuring the conductivity.
To this end, 10.0 g of the sample to be tested are added to 800 ml of water with a conductivity of less than 0.5 s/cm. The water is stirred for t days at a constant rate of rotation of 300 rpm at 25 IC. The change in the salt content of the solution 7 3~i~~
''C
L #j 4 after t days is determined by conductimetry.
In--order to draw up a calibration curve, the -ondu'tivity is measured in solutions with 0.2; 0.4; 0.6; 0.8; 1.0; 2.0; 8.0 and 10.0 g of dissolved sample in 800 ml of water, the conductivity being measured in mS/cm.
The rate of release R is then determined on the basis of the calibration curve, the mean rate of release per day RP being determined by R Ru/t2 tl where R, rate of release after tl days and R, rate of release after t2 days.
Although the basic flow characteristic curve reveals a delay in nutrient release, it does not give all the indications of the presence of a true membrane. The following are to be regarded as indices of membrane-controlled diffusion (membrane function): a) a measurable membrane activation time and b) the applicability of Fick's law of diffusion according to the following differential equation: Jr''"L t: i li 4C~15~ dmi Kx 1 x Aci x F x T dt n(T) f (ri) D mi molar concentration of the substance i t time K constant: R/(6 T N) R: gas constant N: Avogadro's constant n(T) Viscosity membrane/solution (substance property of the coating if well executed) Aci(T) Concentration gradient of the substance i (substance property of the core composition) f(ri) Velocity factor of the particle i with the radius r (substance property of the core composition) F Membrane surface area (particle size distribution and surface structure of the granules) D Membrane thickness (effective thickness of coating deposited) T Temperature in OKelvin The release of the nutrients in the time unit is dependent not only on the total membrane surface, the membrane thickness and "'the"-temperature but also essentially 'on the concentration difference between the individual dissolved substances inside the coated granules and the solution surrounding the granules.
Surprisingly, it has now been found that if the process is carried out in a particular way it is possible to produce granules which, in terms of their release characteristics, exhibit all the typical features of membrane-controlled diffusion. With the process according to the invention, coated granules were obtained which have a measurable characteristic membrane activation- time. The subsequent nutrient release likewise confirms the active separation of the reserve of active substances from the surrounding solution.
In order to produce this complete membrane as a diffusion regulator, the coating material to be applied *consisting of polyisocyanate and polyol is metered in such a way that layer thicknesses of 10 to 30 mn, preferably 15 to 25 gm are not exceeded. In the case of a granulated material in the particle size range of 2 to 4 mm and a median value of 3.0 mm, this means a partial quantity of approx. 1 to 3% to be deposited, particularly less than 2% by mass, based on the mass of granules to be coated.
After a defined distribution and spreading time, this proportion of coating compound is caused to react spontaneously by means of a highly concentrated amine mist as catalyst. The highly concentrated amine mist is produced directly from undiluted amine under airless conditions with a pressure of 2 to 10 bar, preferably 3 to 5 bar, with a volume flow of 10 to 30 ml/s.
In contrast to gassing with only a dilute amine-air mixture, the highly concentrated amine mist makes it possible to' create, on all the reaction sites simultaneously, such a high catalyst potential on the entire coating compound deposited that simultaneous spontaneous curing takes place on each individual particle.. As a result, the extremely sensitive gel stage which represets the transition.bet-ween-free-flowing- res-in mixture and tack-free coating surface will pass through extremely rapidly without destruction of the resin coating that is just in the process of forming.
After the tack-free state has been reached, the amine is removed to such an extent by aeration and degassing prior to the next application of coating compound that premature initiation of the reaction before the next distribution and spreading stage is prevented. This separation of the individual reaction stages according to the invention is important for the dense structure of the individual particle membrane. Intermediate bonding of individual particles to each other would lead to cracking when the particles separate and hence damage to the surface formed thus far, and would reduce substantially the quality of the coating.
The temperature in the reaction bed affects both the distribution and spreading of the coating and the reaction time. It was found that in a temperature range of 25 to 50 OC, preferably in the region of 30 to 40 1C, spreading and distribution are accelerated sufficiently by a lowering of the viscosity without the reaction time being reduced to the same extent. The amount of catalyst is adjusted i.e. reduced, to the increased temperature whilst maintaining the catalyst potential. Temperature control is achieved by varying the inflow air temperature depending on the process heat released.
After introduction of the amine mist and an appropriate reaction time, aeration is carried out preferably by introducing air directly into the inside of the bed of granulated material. As a result of the rapid gaseous exchange thereby made possible, amine is removed from the bed of granulated material which is thus prepared in an optimum time for the subsequent application of coating compound.
i r 8 In order to develop the desired membrane thickness, the coating process described is repeated several times. It has become SapparJent..in_-so doing that at-a. granulated -materiwl temperature of 30 oC at the beginning of the first coating cycle, e.g. by heating with air to an inflow air temperature of about 80 OC, after the third coating application the temperature can be kept in the optimum temperature range of 30 to 40 OC by cooling with inflow air at ambient temperature. At the same time, the amount of amine is reduced in stages. In this way, 2 5% by mass based on the coating compound applied, is deposited with dimethylisopropylamine in the first coating process. This can then be reduced to 0.5% by mass in the further coating stages.
A reproducible production process is ensured in a suitable manner by process control and regulation by SPC (stored program control).
Example 1 Preparation of membrane-coated fertilizer granules with a nutrient release time of 8 months.
450kg of a spherical granulated material NPK 16-10-20 are placed in a sealable drum and heated to a granulated material temperature of 30 OC by passing through a stream of air preheated to 80 OC. Whilst the drum is rotating, 8.8 kg of a polyolpolyisocyanate mixture are applied dropwise to the granules in the first stage and mixed for a total of 2 mins.
Subsequently, without any further inflow of air and the drum being closed, dimethylisopropylamine is applied under airless conditions via two wide-jet nozzles, diameter 0.4 mm, with a pressure of about 4 bar and a volume flow of 18.7 ml/s. After a reaction time of 1 minute, the amine concentration in the bed of granulated material is reduced to below 250 ppm within a further 4 minutes by connecting up inflow air and off-gas in a controlled manner.
L -1 The sequence of stages resin application, mixing time, amine application, reaction time and aeration is passed through six times, .as .can be -seen f.rom-'the--table belbow' Table Stage Resin Catalyst Temperature of inflow air ranules 1. 8.8 kg 0.24 kg 80 2. 8.8 kg 0.20 kg 80 33 3. 8.8 kg 0.18 kg 80 4. 8.8 kg 0.16 kg 80 38 8.8 kg 0.14 kg 20 38 6. 8.8 kg 0.14 kg 20 36 Total 52.8 kg 1.06 kg The coating process with the parameters inflow air and granulated material temperature and catalyst concentration is shown again by way of a graph in figure 1.
The resin membrane produced in this way fulfils the conditions of the Fick diffusion equation given above.
Above all, a measurable membrane activation can be observed which becomes particularly noticeable at low temperatures by a marked delay in the onset of nutrient release, as can be seen from figure 2. The temperature dependence of cumulative nutrient release from the granulated material prepared according to example 1 to be expected from Fick's law of diffusion is shown in this figure.
Figure 3 shows the rate of diffusion as a function of the thickness of the coating surrounding the granules. The granules measured in this figure were prepared with different quantities of resin, as in example 1.
T u- 1^ <^s ^'Lfi Figure 4 shows the characteristic dissolution behaviour of an NPK 16-10-20 fertilizer on the basis of the individual nutrient Isolubil.it.ies in a closed, system with simulation-of water ingress and nutrient release, as would be expected in the ideally coated fertilizer core.
Figure 5 shows the actual ratios of nutrient release of the fertilizer granules prepared according to the invention according to example 1.
The change in the NPK ratios during the period of nutrient release of the fertilizer granules coated according to example 1 (figure 5) corresponds to the theoretical expectation (Figure This analytical finding shows that the saturated solution present in the interior of the individual coated particle leads to the same nutrient ratios after membrane penetration into the outside solution.
Figure 6 shows the high degree of homogeneity of the product from the production process according to the invention (similar to example 1 with 4 coating stages) in a comparison between the individual particle measurements of the granulated material A according to the invention and a comparative product B (OsmocoteR, Sierra, Heerlen NL).
In the application of coated long-acting fertilizers which are to be used for supplying substrates, mechanical mixing, storage stability of substrates already supplied in general but also unforeseeable frost effects are important critical factors under practical conditions.
In figure 7 it is shown how the granulated material prepared according to the invention behaves in comparison with other coated products (OsmocoteR, Sierra, Heerlen NL) during storage with and without intermittent frost action. Whilst the comparative product has completely lost its property of delayed nutrient release after frost action, this property is only 0^
A
11 slightly impaired with the granulated material prepared according to the invention.
.It is shown in figure 8 how the granulated material prepared according to the invention behaves in comparison with other coated products (comparative product as above) in terms of their mechanical resilience during substrate preparation. The nutrient release behaviour of granules produced according to the invention is increased only slightly even with vigorous repeated mechanical mixing, whereas the comparative product exhibits an unacceptable direct salt release from destroyed granules.

Claims (1)

12- THE CLAIMS DEFINING THE INVENTION ARE AS FOLLOWS: 1. Process for the preparation of membrane-coated fertilizer granules by deposition in layers of a mixture of polyisocyanate and polyol and separate curing of the layers in each case with amine in the form of a liquid mist, characterised in that the mixture is applied in proportions such that the layers each have a thickness of 10 30 ym and that after each layer curing, the amine concentration is lowered to a non-catalytically active level before the next layer is applied. 2. Process according to claim 1, characterised in that the coating is carried out in a temperature range of 25 to 50 0 C. 3. Use of fertilizer granules prepared according to claim 1 or 2 for specific plant feeding from uniform fertilizer granules with initial nitrogen emphasis and subsequent potassium emphasis from the available nutrient ratio. 4. Use of fertilizer granules prepared according to claim 1 or 2 in combination with othjr or similar fertilizers as mixed products. S: 25 5. Processes for the pre -'ration of membrane-coated fertilizer granules or uses o, fertilizer granules prepared by said processes, substantially as hereinbefore described with reference to the Example and/or drawings. SDATED this 24th day of June, 1994 Aglukon Spzeialdnger GmbH 35 By Its Patent Attorneys DAVIES COLLISON CAVE 940624,p.\opci\dab,24399.spe, 12
AU24399/92A 1991-08-20 1992-08-18 Process for the manufacture of membrane-covered fertilizer granules Ceased AU652663B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4127459 1991-08-20
DE4127459A DE4127459A1 (en) 1991-08-20 1991-08-20 METHOD FOR PRODUCING MEMBRANE-COATED DETERGENT GRANULES
PCT/DE1992/000697 WO1993004017A1 (en) 1991-08-20 1992-08-18 Process for the manufacture of membrane-covered fertilizer granules

Publications (2)

Publication Number Publication Date
AU2439992A AU2439992A (en) 1993-03-16
AU652663B2 true AU652663B2 (en) 1994-09-01

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Country Status (19)

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EP (1) EP0599927B1 (en)
JP (1) JPH07500560A (en)
AT (1) ATE154341T1 (en)
AU (1) AU652663B2 (en)
CA (1) CA2115998C (en)
CZ (1) CZ282958B6 (en)
DE (2) DE4127459A1 (en)
DK (1) DK0599927T3 (en)
ES (1) ES2104939T3 (en)
FI (1) FI114703B (en)
GR (1) GR3024189T3 (en)
HU (1) HU218166B (en)
IL (1) IL102868A (en)
NO (1) NO303908B1 (en)
NZ (1) NZ244013A (en)
PT (1) PT100787B (en)
RU (1) RU2091357C1 (en)
WO (1) WO1993004017A1 (en)
ZA (1) ZA926284B (en)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU652900B2 (en) * 1991-02-14 1994-09-08 O.M. Scott & Sons Company, The Abrasion resistant coatings for fertilizers
JP3291077B2 (en) * 1993-07-21 2002-06-10 旭化成株式会社 Multi-layer coated granular fertilizer consisting of coating materials with different decomposition rates
US5599374A (en) * 1994-09-23 1997-02-04 Rlc Technologies, L.L.C. Process for producing improved sulfur-coated urea slow release fertilizers
GB9504875D0 (en) * 1995-03-10 1995-04-26 Sherritt Inc A polymerically coated fertilizer
JPH09202683A (en) * 1996-01-23 1997-08-05 Sumitomo Chem Co Ltd Production of coated fertilizer
TW349082B (en) * 1996-02-08 1999-01-01 Sumitomo Chemical Co Coated fertilizer
US6503288B1 (en) * 1996-12-30 2003-01-07 Bayer Corporation Process for the production of biodegradable encapsulated fertilizers
MY120571A (en) 1998-05-22 2005-11-30 Sumitomo Chemical Co Granular coated fertilizer and method for producing the same
US6841515B2 (en) * 2001-01-22 2005-01-11 Unified Enviromental Services Group, L.L.C. Production and use of biosolid granules
WO2006091645A2 (en) 2005-02-23 2006-08-31 Blue Water Investments Manufacturing of bioorganic-augmented high nitrogen-containing inorganic fertilizer
US8192519B2 (en) 2005-03-09 2012-06-05 Vitag Corporation Beneficiated, heat-dried biosolid pellets
WO2007035513A2 (en) 2005-09-15 2007-03-29 Vitag Llc Organic containing sludge to fertilizer alkaline conversion process
US9695092B2 (en) 2006-02-23 2017-07-04 Anuvia Plant Nutrients Corporation Process for treating sludge and manufacturing bioorganically-augmented high nitrogen-containing inorganic fertilizer
EP2118042B1 (en) 2007-02-16 2020-02-12 Anuvia Plant Nutrients Holdings LLC Process for treating sludge and manufacturing bioorganically-augmented high nitrogen-containing inorganic fertilizer
JP5760357B2 (en) 2009-10-06 2015-08-12 セントラル硝子株式会社 Method for producing coated water-soluble granular material
IN2012DN06560A (en) 2009-12-30 2015-10-23 Vitag Holdings Llc
CN103476249B (en) * 2011-02-09 2016-04-20 Oms投资有限公司 The method and system of coated particulate substrates
MX356057B (en) 2011-03-28 2018-05-10 Anuvia Plant Nutrients Holdings Llc High value organic-enhanced inorganic fertilizers.
US10870609B2 (en) 2018-08-16 2020-12-22 Anuvia Plant Nutrients Corporation Reactive inorganic coatings for agricultural fertilizers
JP2022507494A (en) 2018-11-14 2022-01-18 アヌビア・プラント・ニュートリエンツ・ホールディングス・インコーポレイテッド Delivery of bioactive molecules in organically fortified inorganic fertilizer coatings or surface layers

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4772490A (en) * 1985-12-16 1988-09-20 Ashland Oil, Inc. Method for producing a water-permeable covering on granular water-soluble substances

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3223518A (en) * 1961-08-18 1965-12-14 Archer Daniels Midland Granular fertilizer having a plurality of coatings and the process of making
NL292143A (en) * 1962-05-01
US3264088A (en) * 1965-12-08 1966-08-02 Archer Daniels Midland Co Slow release fertilizer granule having a plurality of epoxy resin coatings
US3264089A (en) * 1965-12-10 1966-08-02 Archer Daniels Midland Co Slow release fertilizer granule having a plurality of urethane resin coatings
JPS603040B2 (en) * 1978-01-09 1985-01-25 チツソ旭肥料株式会社 Coated fertilizer and its manufacturing method
US4711659A (en) * 1986-08-18 1987-12-08 Moore William P Attrition resistant controlled release fertilizers
IL81311A (en) * 1987-01-20 1990-11-29 Haifa Chemicals Ltd Method for the manufacture of slow release fertilizers

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4772490A (en) * 1985-12-16 1988-09-20 Ashland Oil, Inc. Method for producing a water-permeable covering on granular water-soluble substances

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Publication number Publication date
WO1993004017A1 (en) 1993-03-04
FI940776A0 (en) 1994-02-18
CA2115998A1 (en) 1993-03-04
FI940776A (en) 1994-02-18
PT100787A (en) 1993-09-30
DE59208613D1 (en) 1997-07-17
HU218166B (en) 2000-06-28
JPH07500560A (en) 1995-01-19
EP0599927B1 (en) 1997-06-11
DE4127459C2 (en) 1993-07-29
NZ244013A (en) 1995-02-24
IL102868A (en) 1995-10-31
ES2104939T3 (en) 1997-10-16
RU2091357C1 (en) 1997-09-27
EP0599927A1 (en) 1994-06-08
DK0599927T3 (en) 1997-12-29
ATE154341T1 (en) 1997-06-15
GR3024189T3 (en) 1997-10-31
ZA926284B (en) 1993-05-18
HU9400479D0 (en) 1994-06-28
RU94015604A (en) 1996-04-10
IL102868A0 (en) 1993-01-31
NO940386L (en) 1994-02-07
NO303908B1 (en) 1998-09-21
AU2439992A (en) 1993-03-16
PT100787B (en) 1999-07-30
CZ36794A3 (en) 1994-07-13
FI114703B (en) 2004-12-15
HUT70289A (en) 1995-09-28
DE4127459A1 (en) 1993-02-25
CA2115998C (en) 2003-07-29
CZ282958B6 (en) 1997-11-12
NO940386D0 (en) 1994-02-07

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