ATE470500T1 - Nickel-, magnesium- und aluminiumhaltiger katalysator für das dampfreformieren, verfahren zu seiner herstellung und verfahren zur wasserstofferzeugung unter verwendung des katalysators - Google Patents
Nickel-, magnesium- und aluminiumhaltiger katalysator für das dampfreformieren, verfahren zu seiner herstellung und verfahren zur wasserstofferzeugung unter verwendung des katalysatorsInfo
- Publication number
- ATE470500T1 ATE470500T1 AT04250973T AT04250973T ATE470500T1 AT E470500 T1 ATE470500 T1 AT E470500T1 AT 04250973 T AT04250973 T AT 04250973T AT 04250973 T AT04250973 T AT 04250973T AT E470500 T1 ATE470500 T1 AT E470500T1
- Authority
- AT
- Austria
- Prior art keywords
- catalyst
- nickel
- magnesium
- aluminum
- steam reforming
- Prior art date
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title abstract 12
- 239000003054 catalyst Substances 0.000 title abstract 6
- 239000011777 magnesium Substances 0.000 title abstract 5
- 229910052759 nickel Inorganic materials 0.000 title abstract 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title abstract 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title abstract 4
- 229910052782 aluminium Inorganic materials 0.000 title abstract 4
- 229910052749 magnesium Inorganic materials 0.000 title abstract 4
- 238000000629 steam reforming Methods 0.000 title abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title 1
- 229910052739 hydrogen Inorganic materials 0.000 title 1
- 239000001257 hydrogen Substances 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 239000002245 particle Substances 0.000 abstract 6
- 238000004939 coking Methods 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical group 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
- B01J35/45—Nanoparticles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/088—Decomposition of a metal salt
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
- B01J2235/15—X-ray diffraction
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/007—Mixed salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/393—Metal or metal oxide crystallite size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003046618A JP4870900B2 (ja) | 2003-02-24 | 2003-02-24 | 炭化水素分解用触媒及びその製造方法、並びに該炭化水素分解用触媒を用いた水素製造方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE470500T1 true ATE470500T1 (de) | 2010-06-15 |
Family
ID=32733032
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT04250973T ATE470500T1 (de) | 2003-02-24 | 2004-02-23 | Nickel-, magnesium- und aluminiumhaltiger katalysator für das dampfreformieren, verfahren zu seiner herstellung und verfahren zur wasserstofferzeugung unter verwendung des katalysators |
Country Status (5)
Country | Link |
---|---|
US (1) | US7196036B2 (de) |
EP (1) | EP1449581B1 (de) |
JP (1) | JP4870900B2 (de) |
AT (1) | ATE470500T1 (de) |
DE (1) | DE602004027563D1 (de) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7408089B2 (en) * | 2004-03-19 | 2008-08-05 | Catalytic Distillation Technologies | Ni catalyst, process for making catalysts and selective hydrogenation process |
KR100719484B1 (ko) * | 2004-12-31 | 2007-05-18 | 한국에너지기술연구원 | 금속모노리스 촉매를 이용한 컴팩트형 수증기개질구조촉매 및 이를 이용한 수소의 제조방법 |
EP1879833A4 (de) * | 2005-05-02 | 2009-09-30 | Symyx Technologies Inc | Metall mit hoher oberfläche, metalloxidmaterialien und herstellungsverfahren dafür |
KR101319137B1 (ko) * | 2005-08-11 | 2013-10-17 | 도다 고교 가부시끼가이샤 | 탄화수소를 분해하는 촉매, 상기 촉매를 이용한 탄화수소의분해 방법 및 수소의 제조 방법, 및 발전 시스템 |
JP5110249B2 (ja) * | 2005-08-11 | 2012-12-26 | 戸田工業株式会社 | 炭化水素を分解する触媒、該触媒を用いた炭化水素の分解方法及び水素の製造方法、並びに発電システム |
WO2007031713A1 (en) * | 2005-09-14 | 2007-03-22 | Bp P.L.C. | Process for hydrogen production |
EP1795260A1 (de) | 2005-12-07 | 2007-06-13 | L'AIR LIQUIDE, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Katalysator enthaltend einen festen Träger, ein Oxid und eine auf das Oxid aufgebrachte, metallische, aktive Phase; Verfahren zu seiner Herstellung und Verwendung |
US20070167323A1 (en) * | 2006-01-16 | 2007-07-19 | Toda Kogya Corporation | Porous carrier for steam-reforming catalysts, steam-reforming catalyst and process for producing reactive mixed gas |
US8067332B2 (en) * | 2006-05-03 | 2011-11-29 | Samsung Sdi Co., Ltd. | Methanation catalyst, and carbon monoxide removing system, fuel processor, and fuel cell including the same |
JP2008080246A (ja) * | 2006-09-27 | 2008-04-10 | Idemitsu Kosan Co Ltd | 水素製造触媒の前処理方法および燃料電池用水素の製造方法 |
JP2008094665A (ja) | 2006-10-12 | 2008-04-24 | Idemitsu Kosan Co Ltd | 水素含有ガスの製造方法 |
JP5531615B2 (ja) * | 2007-07-19 | 2014-06-25 | 戸田工業株式会社 | 炭化水素を分解する触媒 |
EP2226308B1 (de) * | 2007-12-28 | 2018-10-17 | Toda Kogyo Corp. | Poröser formartikel, verfahren zu seiner herstellung, katalysatorträger und katalysator |
JP5812253B2 (ja) * | 2011-04-27 | 2015-11-11 | 戸田工業株式会社 | 炭化水素を分解する触媒及び燃料電池システム |
KR102035714B1 (ko) * | 2012-08-08 | 2019-10-23 | 연세대학교 원주산학협력단 | 탄화수소 개질용 니켈 촉매 |
BR102016022467B1 (pt) * | 2016-09-28 | 2022-02-01 | Petróleo Brasileiro S.A. - Petrobras | Processo para preparação de um catalisador à base de níquel, catalisador à base de níquel, e, seu uso em um processo de reforma a vapor |
CN110898839A (zh) * | 2019-12-09 | 2020-03-24 | 大连理工大学 | 一种负载型抗积碳镍基催化剂的制备方法及其应用 |
EP4377255A1 (de) * | 2021-07-26 | 2024-06-05 | Pact Fuel, LLC | Katalysatoren zur erzeugung von graphitnanofasern und kohlenmonoxidfreiem wasserstoff |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2890178A (en) * | 1953-10-14 | 1959-06-09 | Exxon Research Engineering Co | Hydrocarbon conversion catalysts |
US3432363A (en) * | 1963-11-12 | 1969-03-11 | Allis Chalmers Mfg Co | High temperature fuel cell electrolyte carrier |
US3368982A (en) * | 1964-03-09 | 1968-02-13 | United Eng & Constructors Inc | Nickel and nickel oxide catalysts on a nickel spinel base |
DE1546728C3 (de) * | 1965-09-18 | 1975-07-17 | Varta Batterie Ag, 3000 Hannover | Verfahren zur Herstellung eines silberhaltigen pulverförmiger! Katalysators für Sauerstoffelektroden |
US3932514A (en) * | 1970-09-17 | 1976-01-13 | Bayer Aktiengesellschaft | Catalyst for the preparation of cyclohexanone from phenol and process therefor |
US3825505A (en) * | 1972-01-21 | 1974-07-23 | Universal Oil Prod Co | Hydrocarbon hydroprocessing catalyst |
US3825504A (en) * | 1972-01-27 | 1974-07-23 | Universal Oil Prod Co | Hydrocarbon hydroprocessing catalyst |
JPS5550704B2 (de) | 1972-06-08 | 1980-12-19 | ||
US3849343A (en) * | 1973-02-05 | 1974-11-19 | Universal Oil Prod Co | Method of catalyst manufacture |
US4870044A (en) * | 1987-03-12 | 1989-09-26 | Phillips Petroleum Company | Treated alumina material for fixed hydrofining beds |
US4857499A (en) * | 1987-03-20 | 1989-08-15 | Kabushiki Kaisha Toshiba | High temperature combustion catalyst and method for producing the same |
US4944985A (en) * | 1988-04-11 | 1990-07-31 | Leach & Garner | Method for electroless plating of ultrafine or colloidal particles and products produced thereby |
US5399537A (en) * | 1992-12-21 | 1995-03-21 | Amoco Corporation | Method for preparing synthesis gas using nickel catalysts |
US5395406A (en) * | 1993-05-11 | 1995-03-07 | Exxon Research And Engineering Company | Structurally modified alumina supports, and heat transfer solids for high temperature fluidized bed reactions |
NL9300833A (nl) * | 1993-05-13 | 1994-12-01 | Gastec Nv | Werkwijze voor de produktie van waterstof/koolmonoxide mengsels of waterstof uit methaan. |
US6007946A (en) * | 1996-06-26 | 1999-12-28 | Sanyo Electric Co., Ltd. | Non-sintered nickel electrode for alkaline storage battery, alkaline storage battery including the same, and method for production of non-sintered nickel electrode for alkaline storage battery |
DZ2724A1 (fr) * | 1998-02-20 | 2003-09-01 | Sasol Tech Pty Ltd | Procédé pour la production d'hydrocarbures à partir d'un gaz de synthèse et leurs catalyseurs. |
JP4211900B2 (ja) * | 1998-03-31 | 2009-01-21 | 三菱重工業株式会社 | 金属微粒子担持炭化水素改質用触媒及びその製造方法 |
KR100584167B1 (ko) * | 1999-02-05 | 2006-05-26 | 토다 고교 가부시끼가이샤 | Mg-Al-기제 히드로탈사이트 유형 입자, 염소 함유수지 조성물 및 상기 입자의 제조방법 |
US6413639B1 (en) * | 1999-10-01 | 2002-07-02 | Toda Kogyo Corporation | Mg-Al based hydrotalcite-type particles, chlorine-containing resin stabilizer and process for producing the particles |
JP4098508B2 (ja) | 2001-08-20 | 2008-06-11 | 財団法人 ひろしま産業振興機構 | 炭化水素と水蒸気とを反応させるための触媒の製造方法および当該触媒を使用した炭化水素から水素を製造する方法 |
WO2003099436A1 (en) | 2002-05-29 | 2003-12-04 | L'air Liquide, Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude | Catalyst obtainable by calcining a hydrotalcite-like precursor and its use for the partial oxidation of methane |
-
2003
- 2003-02-24 JP JP2003046618A patent/JP4870900B2/ja not_active Expired - Lifetime
-
2004
- 2004-02-23 DE DE602004027563T patent/DE602004027563D1/de not_active Expired - Lifetime
- 2004-02-23 US US10/783,021 patent/US7196036B2/en not_active Expired - Fee Related
- 2004-02-23 EP EP04250973A patent/EP1449581B1/de not_active Expired - Lifetime
- 2004-02-23 AT AT04250973T patent/ATE470500T1/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
US7196036B2 (en) | 2007-03-27 |
JP2004255245A (ja) | 2004-09-16 |
DE602004027563D1 (de) | 2010-07-22 |
JP4870900B2 (ja) | 2012-02-08 |
US20040209773A1 (en) | 2004-10-21 |
EP1449581A1 (de) | 2004-08-25 |
EP1449581B1 (de) | 2010-06-09 |
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