ATE445651T1 - Verfahren zur copolymerisation von ethylen - Google Patents
Verfahren zur copolymerisation von ethylenInfo
- Publication number
- ATE445651T1 ATE445651T1 AT03793737T AT03793737T ATE445651T1 AT E445651 T1 ATE445651 T1 AT E445651T1 AT 03793737 T AT03793737 T AT 03793737T AT 03793737 T AT03793737 T AT 03793737T AT E445651 T1 ATE445651 T1 AT E445651T1
- Authority
- AT
- Austria
- Prior art keywords
- hydrocarbon group
- polyene
- olefins
- alpha
- mol
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02078739 | 2002-09-06 | ||
PCT/EP2003/009183 WO2004022613A1 (en) | 2002-09-06 | 2003-08-19 | Process for the copolymerization of ethylene |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE445651T1 true ATE445651T1 (de) | 2009-10-15 |
Family
ID=31970412
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT03793737T ATE445651T1 (de) | 2002-09-06 | 2003-08-19 | Verfahren zur copolymerisation von ethylen |
Country Status (7)
Country | Link |
---|---|
US (1) | US7615597B2 (de) |
EP (1) | EP1539843B1 (de) |
JP (1) | JP2005538198A (de) |
AT (1) | ATE445651T1 (de) |
AU (1) | AU2003260432A1 (de) |
DE (1) | DE60329691D1 (de) |
WO (1) | WO2004022613A1 (de) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1446429B1 (de) * | 2001-06-12 | 2009-10-07 | Basell Polyolefine GmbH | Verfahren zur Polymerisation von Buten-1 |
EP1549688A2 (de) * | 2002-10-10 | 2005-07-06 | Basell Polyolefine GmbH | Verfahren zur copolymerisation von ethylen |
US8058350B2 (en) * | 2003-11-06 | 2011-11-15 | Basell Poliolefine Italia, s.r.l. | Polypropylene composition |
KR101384384B1 (ko) | 2010-04-12 | 2014-04-10 | 롯데케미칼 주식회사 | 올레핀 중합용 촉매 조성물 및 이를 사용한 폴리올레핀의 제조방법 |
CN102892797A (zh) | 2010-04-12 | 2013-01-23 | 湖南石油化学株式会社 | 使用包含噻吩稠合的环戊二烯基配体的过渡金属化合物制备烯烃-二烯共聚物的方法 |
JP5546678B2 (ja) | 2010-04-12 | 2014-07-09 | ロッテ ケミカル コーポレーション | チオフェン−縮合環シクロペンタジエニルリガンドを含む遷移金属化合物を使用したポリプロピレンの製造方法 |
CN102858808B (zh) | 2010-04-12 | 2015-04-01 | 乐天化学株式会社 | 用于烯烃聚合的负载型催化剂以及利用该催化剂的聚烯烃的制备方法 |
KR100986301B1 (ko) | 2010-04-12 | 2010-10-07 | 아주대학교산학협력단 | 테트라하이드로퀴놀린 유도체로부터 유래한 티오펜-축합고리 싸이클로펜타디에닐 4족 금속 화합물 및 이를 이용한 올레핀 중합 |
US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
WO2015009472A1 (en) | 2013-07-17 | 2015-01-22 | Exxonmobil Chemcal Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
EP3022235B1 (de) | 2013-07-17 | 2020-04-08 | ExxonMobil Chemical Patents Inc. | Metallocene und katalysatorzusammensetzungen daraus |
SG11201510461SA (en) | 2013-07-17 | 2016-01-28 | Exxonmobil Chem Patents Inc | Substituted metallocene catalysts |
SG11201508750SA (en) | 2013-07-17 | 2015-11-27 | Exxonmobil Chem Patents Inc | Cyclopropyl substituted metallocene catalysts |
EP3848401A1 (de) | 2013-07-17 | 2021-07-14 | ExxonMobil Chemical Patents Inc. | Isotaktische propylenpolymere |
US10329360B2 (en) | 2015-06-05 | 2019-06-25 | Exxonmobil Chemical Patents Inc. | Catalyst system comprising supported alumoxane and unsupported alumoxane particles |
CN107690441A (zh) | 2015-06-05 | 2018-02-13 | 埃克森美孚化学专利公司 | 聚合物在气相或淤浆相中的单反应器制备 |
EP3303422B1 (de) | 2015-06-05 | 2021-03-17 | ExxonMobil Chemical Patents Inc. | Herstellung von heterophasischen polymeren in gas- oder schlämmephase |
US9809664B2 (en) | 2015-06-05 | 2017-11-07 | Exxonmobil Chemical Patents Inc. | Bimodal propylene polymers and sequential polymerization |
US10294316B2 (en) | 2015-06-05 | 2019-05-21 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
US10723821B2 (en) | 2015-06-05 | 2020-07-28 | Exxonmobil Chemical Patents Inc. | Supported metallocene catalyst systems for polymerization |
US10280235B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers |
US10919994B2 (en) * | 2016-03-04 | 2021-02-16 | Japan Polyethylene Corporation | Metallocene compound, catalyst component for olefin polymerization and catalyst for olefin polymerization containing the same, and method for producing olefin polymer using catalyst for olefin polymerization |
EP3464390A1 (de) | 2016-05-27 | 2019-04-10 | ExxonMobil Chemical Patents Inc. | Metallocenkatalysatorzusammensetzungen und und polymerisationsverfahren damit |
US11472828B2 (en) | 2019-10-11 | 2022-10-18 | Exxonmobil Chemical Patents Inc. | Indacene based metallocene catalysts useful in the production of propylene polymers |
CN116410238A (zh) * | 2021-12-31 | 2023-07-11 | 中国石油天然气股份有限公司 | 含硫手性桥联茂金属化合物及其制备和应用 |
Family Cites Families (62)
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ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
EP0172961B1 (de) | 1984-08-30 | 1988-10-19 | Mitsui Petrochemical Industries, Ltd. | Buten-1-Polymer und seine Verwendung |
JPH0816133B2 (ja) | 1987-03-14 | 1996-02-21 | 出光石油化学株式会社 | ブテン−1共重合体 |
WO1991002012A1 (en) | 1989-08-03 | 1991-02-21 | Exxon Chemical Patents Inc. | Very high molecular weight polyethylene |
JPH03126704A (ja) | 1989-10-11 | 1991-05-29 | Idemitsu Petrochem Co Ltd | パイプ用ポリブテン‐1および樹脂パイプ |
US5280074A (en) * | 1989-12-21 | 1994-01-18 | Hoechst Ag | Process for the preparation of a polypropylene molding composition |
EP0672689A1 (de) | 1990-06-22 | 1995-09-20 | Exxon Chemical Patents Inc. | Aluminiumfreie Monocyclopentadienyl-Metallocenkatalysatoren für Olefinpolymerisation |
DE59104869D1 (de) * | 1990-11-12 | 1995-04-13 | Hoechst Ag | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation. |
US5830821A (en) * | 1991-11-30 | 1998-11-03 | Targor Gmbh | Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands |
TW294669B (de) * | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
JPH0626804A (ja) | 1992-07-07 | 1994-02-04 | Yaskawa Electric Corp | ギャップセンサの励磁方法 |
DE4317655A1 (de) * | 1993-05-27 | 1994-12-01 | Basf Ag | Mehrphasige Blockcopolymerisate des Propylens |
IT1264680B1 (it) | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori supportati per la polimerizzazione delle olefine |
IT1269931B (it) * | 1994-03-29 | 1997-04-16 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
JP4026846B2 (ja) * | 1994-04-11 | 2007-12-26 | 三井化学株式会社 | プロピレン系重合体組成物の製造方法およびプロピレン系重合体組成物 |
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IT1269837B (it) | 1994-05-26 | 1997-04-15 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione delle olefine |
JP3338190B2 (ja) | 1994-08-17 | 2002-10-28 | 三菱化学株式会社 | α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法 |
US5869723A (en) | 1995-06-08 | 1999-02-09 | Showa Denko K.K. | Ionic compound and olefin polymerization catalyst containing the same |
TR199901635T2 (xx) * | 1996-11-15 | 2000-02-21 | Montell Technology Company Bv | Heterosiklik metalosenler ve polimerizasyon kataliz�rleri. |
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US6559252B1 (en) | 1997-10-29 | 2003-05-06 | Basell Technology Company Bv | Catalysts and processes for the polymerization of olefins |
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DE19804970A1 (de) | 1998-02-07 | 1999-08-12 | Aventis Res & Tech Gmbh & Co | Katalysatorsystem |
KR100598444B1 (ko) * | 1998-03-05 | 2006-07-10 | 바셀 테크놀로지 캄파니 비이브이 | 폴리부텐-1 (공)중합체 및 그것의 제조방법 |
IT1301990B1 (it) * | 1998-08-03 | 2000-07-20 | Licio Zambon | Catalizzatori per la polimerizzazione delle olefine. |
DE19903306A1 (de) | 1999-01-28 | 2000-08-03 | Targor Gmbh | Organometallverbindung, Katalysatorsystem enthaltend diese Organometallverbindung und seine Verwendung |
BE1012364A3 (fr) * | 1998-12-22 | 2000-10-03 | Solvay | Procede pour la preparation d'une composition catalytique pour la polymerisation des alpha-olefines, composition catalytique obtenue et procede de polymerisation utilisant une telle composition catalytique |
DE19917985A1 (de) | 1999-04-21 | 2000-10-26 | Targor Gmbh | Katalysatorsystem |
EP1074557A3 (de) * | 1999-07-31 | 2003-02-26 | Basell Polyolefine GmbH | Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen |
CN1374973A (zh) | 1999-09-22 | 2002-10-16 | 巴塞尔技术有限公司 | 用于烯烃聚合的催化剂体系及方法 |
US6444833B1 (en) * | 1999-12-15 | 2002-09-03 | Basell Technology Company Bv | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
AU3014401A (en) * | 1999-12-16 | 2001-06-25 | Basell Technology Company B.V. | Process and apparatus for making supported catalyst systems for olefin polymerisation |
EP1252202B1 (de) * | 1999-12-21 | 2006-02-22 | Basell Polyolefine GmbH | Teilkristalline propylenpolymerisat-zusammensetzung zur herstellung von biaxial gereckten polypropylenfolien |
DE60015090T2 (de) * | 1999-12-22 | 2006-03-02 | Basell Poliolefine Italia S.P.A. | Alpha-olefin enthaltendes polymerisationskatalysatorsystem, das ein aromatisches silan enthält |
DE19962910A1 (de) | 1999-12-23 | 2001-07-05 | Targor Gmbh | Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen |
CN1590422A (zh) * | 1999-12-23 | 2005-03-09 | 巴塞尔聚烯烃有限公司 | 过渡金属化合物,配体体系,催化剂体系及其在烯烃的聚合反应和共聚反应中的用途 |
DE19962814A1 (de) * | 1999-12-23 | 2001-06-28 | Targor Gmbh | Neues Katalysatorsystem und dessen Verwendung |
US6492465B1 (en) * | 2000-02-08 | 2002-12-10 | Exxonmobil Chemical Patents, Inc. | Propylene impact copolymers |
EP1173445B1 (de) * | 2000-02-24 | 2004-06-09 | Basell Polyolefine GmbH | Organometallische verbindung die als cokatalysator bei der polymerisation von olefinen verwendbar ist |
US7122498B2 (en) * | 2000-06-30 | 2006-10-17 | Exxonmobil Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
US6870016B1 (en) * | 2000-06-30 | 2005-03-22 | Exxonmobil Chemical Patents Inc. | Polymerization process and polymer composition |
CN1519263A (zh) | 2000-07-03 | 2004-08-11 | 三井化学株式会社 | 固体钛催化剂、制备α-烯烃聚合物或共聚物的方法和由此制得的聚合物或共聚物 |
US20020107344A1 (en) * | 2000-12-07 | 2002-08-08 | Peterson Thomas Henry | Supprt materials for use with polymerization catalysts |
EP1355958A2 (de) * | 2000-12-22 | 2003-10-29 | Basell Poliolefine Italia S.p.A. | Verfahren zur herstellung von porösen polymeren und dadurch erhältliche polymere |
ATE394407T1 (de) | 2001-04-10 | 2008-05-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung von mono oder bis halogensubstituierten metallozenverbindungen |
EP1446429B1 (de) * | 2001-06-12 | 2009-10-07 | Basell Polyolefine GmbH | Verfahren zur Polymerisation von Buten-1 |
WO2002100908A1 (en) * | 2001-06-12 | 2002-12-19 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
ATE315559T1 (de) | 2001-08-01 | 2006-02-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung von heterocyclischen pentalen derivaten |
US7019157B2 (en) * | 2001-08-06 | 2006-03-28 | Chisso Corporation | Metallocene compounds, production process for olefin polymers using catalysts containing them and olefin polymers produced by the production process |
EP1448624A1 (de) * | 2001-11-27 | 2004-08-25 | Basell Polyolefine GmbH | Verfahren zur herstellung von polymerzusammensetzungen |
DE60213452T2 (de) * | 2001-11-30 | 2007-08-23 | Basell Polyolefine Gmbh | Metallocene und verfahren zur herstellung von propylenpolymeren |
DE10158656A1 (de) * | 2001-11-30 | 2003-06-26 | Basell Polyolefine Gmbh | Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
US7569648B2 (en) | 2002-02-25 | 2009-08-04 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
CN100532400C (zh) | 2002-07-09 | 2009-08-26 | 巴塞尔聚烯烃股份有限公司 | 用于烯烃聚合的催化剂体系 |
EP1549688A2 (de) | 2002-10-10 | 2005-07-06 | Basell Polyolefine GmbH | Verfahren zur copolymerisation von ethylen |
WO2004106351A1 (en) * | 2003-05-28 | 2004-12-09 | Basell Polyolefine Gmbh | Bisindenyl zirconium complexes for use in the polymerisation of olefins |
WO2005023889A1 (en) * | 2003-09-11 | 2005-03-17 | Basell Polyolefine Gmbh | Multistep process for preparing heterophasic propylene copolymers |
US20060287436A1 (en) * | 2003-09-11 | 2006-12-21 | Anteo Pelliconi | Multistep process for preparing heterophasic propylene copolymers |
CN1849350A (zh) * | 2003-09-11 | 2006-10-18 | 巴塞尔聚烯烃股份有限公司 | 制备多相丙烯共聚物的多步方法 |
JP2007505175A (ja) * | 2003-09-11 | 2007-03-08 | バセル ポリオレフィン ジーエムビーエイチ | ヘテロ相プロピレンコポリマーを製造するための多段方法 |
-
2003
- 2003-08-19 AU AU2003260432A patent/AU2003260432A1/en not_active Abandoned
- 2003-08-19 DE DE60329691T patent/DE60329691D1/de not_active Expired - Lifetime
- 2003-08-19 EP EP03793737A patent/EP1539843B1/de not_active Expired - Lifetime
- 2003-08-19 JP JP2004533372A patent/JP2005538198A/ja active Pending
- 2003-08-19 AT AT03793737T patent/ATE445651T1/de not_active IP Right Cessation
- 2003-08-19 US US10/526,656 patent/US7615597B2/en not_active Expired - Fee Related
- 2003-08-19 WO PCT/EP2003/009183 patent/WO2004022613A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
DE60329691D1 (de) | 2009-11-26 |
JP2005538198A (ja) | 2005-12-15 |
WO2004022613A1 (en) | 2004-03-18 |
US20050234204A1 (en) | 2005-10-20 |
EP1539843B1 (de) | 2009-10-14 |
EP1539843A1 (de) | 2005-06-15 |
US7615597B2 (en) | 2009-11-10 |
AU2003260432A1 (en) | 2004-03-29 |
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