ATE206713T1 - Metallkomplexe, kondensierte indenylderivate enthaltend, und polymerisationsverfahren - Google Patents
Metallkomplexe, kondensierte indenylderivate enthaltend, und polymerisationsverfahrenInfo
- Publication number
- ATE206713T1 ATE206713T1 AT97950689T AT97950689T ATE206713T1 AT E206713 T1 ATE206713 T1 AT E206713T1 AT 97950689 T AT97950689 T AT 97950689T AT 97950689 T AT97950689 T AT 97950689T AT E206713 T1 ATE206713 T1 AT E206713T1
- Authority
- AT
- Austria
- Prior art keywords
- metal complexes
- polymerization processes
- complexes containing
- containing condensed
- indenyl derivatives
- Prior art date
Links
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 title 1
- -1 INDENYL Chemical class 0.000 title 1
- 239000002184 metal Substances 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US3481796P | 1996-12-19 | 1996-12-19 | |
US08/949,505 US5965756A (en) | 1996-12-19 | 1997-10-14 | Fused ring substituted indenyl metal complexes and polymerization process |
PCT/US1997/021585 WO1998027103A1 (en) | 1996-12-19 | 1997-11-21 | Fused ring substituted indenyl metal complexes and polymerization process |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE206713T1 true ATE206713T1 (de) | 2001-10-15 |
Family
ID=26711411
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT97950689T ATE206713T1 (de) | 1996-12-19 | 1997-11-21 | Metallkomplexe, kondensierte indenylderivate enthaltend, und polymerisationsverfahren |
Country Status (18)
Country | Link |
---|---|
US (2) | US5965756A (de) |
EP (1) | EP0946575B1 (de) |
JP (1) | JP3427302B2 (de) |
KR (1) | KR100500093B1 (de) |
CN (1) | CN1093543C (de) |
AR (1) | AR010799A1 (de) |
AT (1) | ATE206713T1 (de) |
AU (1) | AU726100B2 (de) |
BR (1) | BR9714571B1 (de) |
CA (1) | CA2268440C (de) |
DE (1) | DE69707306T2 (de) |
ES (1) | ES2162339T3 (de) |
ID (1) | ID22003A (de) |
MY (1) | MY117028A (de) |
NO (1) | NO324380B1 (de) |
TR (1) | TR199901403T2 (de) |
TW (1) | TW513448B (de) |
WO (1) | WO1998027103A1 (de) |
Families Citing this family (105)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6420507B1 (en) * | 1997-05-01 | 2002-07-16 | The Dow Chemical Company | Olefin polymers prepared with substituted indenyl containing metal complexes |
EP1522553B1 (de) | 1998-07-01 | 2007-04-11 | ExxonMobil Chemical Patents Inc. | Elastische Mischung mit Kristallpolymeren und kristallisierbaren Polymeren des Propens |
US6680361B1 (en) * | 1998-11-02 | 2004-01-20 | Dupont Dow Elastomers Llc | Shear thinning ethylene/α-olefin interpolymers and their preparation |
KR100623106B1 (ko) * | 1998-11-02 | 2006-09-13 | 다우 글로벌 테크놀로지스 인크. | 전단시닝 에틸렌/α―올레핀 인터폴리머 및 그의 제조 방법 |
EP1010709A1 (de) * | 1998-12-14 | 2000-06-21 | Fina Research S.A. | Metallocenverbindung und ihre Verwendung für die Herstellung von Polyolefinen |
AU765658B2 (en) * | 1999-02-05 | 2003-09-25 | Boulder Scientific Company | Silylated and N-silylated compound synthesis |
US6369176B1 (en) * | 1999-08-19 | 2002-04-09 | Dupont Dow Elastomers Llc | Process for preparing in a single reactor polymer blends having a broad molecular weight distribution |
CN1409729A (zh) * | 1999-12-10 | 2003-04-09 | 陶氏环球技术公司 | 取代的第4族金属配合物,催化剂和烯烃聚合方法 |
US6825295B2 (en) * | 1999-12-10 | 2004-11-30 | Dow Global Technologies Inc. | Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process |
DE10003581A1 (de) * | 2000-01-28 | 2001-08-02 | Bayer Ag | Metallorganische Verbindungen mit anellierten Indenyl Liganden |
US6723675B1 (en) * | 2000-05-25 | 2004-04-20 | Univation Technologies, Llc | Catalyst for the production of olefin polymers |
JP2002206006A (ja) * | 2000-11-13 | 2002-07-26 | Basell Technology Co Bv | オレフィンポリマーの製造方法 |
MY131000A (en) | 2001-03-16 | 2007-07-31 | Dow Global Technologies Inc | High melt strength polymers and method of making same |
KR20030085575A (ko) * | 2001-03-27 | 2003-11-05 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 코포레이션 | 4족 금속 착물 촉매의 첨가에 의한 기체상 중합 방법 |
DE60238049D1 (de) | 2001-04-12 | 2010-12-02 | Exxonmobil Chem Patents Inc | Verfahren zur Polymerisation von Propylen und Ethylen in Lösung |
CA2446116A1 (en) * | 2001-05-14 | 2002-11-21 | Dow Global Technologies Inc. | 3-aryl-substituted cyclopentadienyl metal complexes and polymerization process |
US6946531B2 (en) * | 2001-05-14 | 2005-09-20 | Dow Global Technologies Inc. | Low molecular weight ethylene interpolymers and polymerization process |
WO2002100908A1 (en) * | 2001-06-12 | 2002-12-19 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
SG147306A1 (en) | 2001-11-06 | 2008-11-28 | Dow Global Technologies Inc | Isotactic propylene copolymers, their preparation and use |
US6906160B2 (en) | 2001-11-06 | 2005-06-14 | Dow Global Technologies Inc. | Isotactic propylene copolymer fibers, their preparation and use |
US6960635B2 (en) * | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
US6927256B2 (en) | 2001-11-06 | 2005-08-09 | Dow Global Technologies Inc. | Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent |
US6943215B2 (en) | 2001-11-06 | 2005-09-13 | Dow Global Technologies Inc. | Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers |
AU2003216477A1 (en) * | 2002-03-14 | 2003-09-29 | Dow Global Technologies Inc. | Polycyclic, fused heteroring compounds, metal complexes and polymerization process |
AU2003216476A1 (en) * | 2002-03-14 | 2003-09-29 | Dow Global Technologies Inc. | Substituted indenyl metal complexes and polymerization process |
US20040034169A1 (en) * | 2002-06-04 | 2004-02-19 | Union Carbide Chemicals & Plastics Technology Corporation | Polymer compositions and method of making pipes |
DE60321920D1 (de) * | 2002-08-02 | 2008-08-14 | Dow Global Technologies Inc | Metallkomplexe der gruppe 4 des pse, die 4-aryl substituierte, tricyclische indenylderivate enthalten |
US8008412B2 (en) * | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
US20080153997A1 (en) * | 2006-12-20 | 2008-06-26 | Exxonmobil Research And Engineering | Polymer production at supercritical conditions |
US8058371B2 (en) * | 2002-09-20 | 2011-11-15 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization |
AU2003299143A1 (en) * | 2002-10-02 | 2004-04-23 | Dow Global Technologies Inc. | Liquid and gel-like low molecular weight ethylene polymers |
EP1964884A1 (de) | 2002-10-17 | 2008-09-03 | Dow Global Technologies Inc. | Hoch gefüllte Polymerzusammensetzungen |
US7144934B2 (en) * | 2002-10-24 | 2006-12-05 | Dow Global Technologies Inc. | Charge dissipation modifiers for olefinic interpolymer compositions |
US7579407B2 (en) * | 2002-11-05 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
US7589160B2 (en) * | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
DE60329523D1 (de) * | 2002-12-04 | 2009-11-12 | Basell Polyolefine Gmbh | 1-Buten-Copolymere und Herstellungsverfahren dafür |
WO2004055067A1 (en) | 2002-12-13 | 2004-07-01 | Dow Global Technologies Inc. | Olefin polymerization catalyst composition comprising group 13 amide derivatives |
JP4742221B2 (ja) | 2003-03-21 | 2011-08-10 | ダウ グローバル テクノロジーズ エルエルシー | モルホロジー制御オレフィン重合プロセス |
EP3112385B1 (de) | 2003-07-09 | 2020-01-08 | Arlanxeo Netherlands B.V. | Verfahren zur herstellung eines polymers mit monomereinheiten aus ethylen, einem olefin und einem vinyl-norbornen |
DE602004025303D1 (de) | 2003-08-19 | 2010-03-11 | Dow Global Technologies Inc | Interpolymere zur Verwendung für Schmelzklebstoffe und Verfahren zu ihrer Herstellung |
ES2321632T3 (es) * | 2004-03-16 | 2009-06-09 | UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY LLC | Oligomerizacion de etileno con cataklizadores de amida de metal del grupo 6 soportados sobre fosfato de aluminio. |
SG183748A1 (en) | 2004-03-17 | 2012-09-27 | Dow Global Technologies Llc | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
EP2327727B1 (de) | 2004-03-17 | 2015-07-22 | Dow Global Technologies LLC | Katalysatorzusammensetzung mit Transportwirkstoff zur Formierung von Ethylen-Copolymeren |
EP2357203B1 (de) | 2004-03-17 | 2017-05-24 | Dow Global Technologies LLC | Katalysatorzusammensetzung mit Kettenübertragungsreagenz zur Bildung von Multiblock-Olefin-Copolymeren |
CN106977786A (zh) * | 2004-03-19 | 2017-07-25 | 陶氏环球技术有限责任公司 | 由聚合物配方制成的薄膜层 |
EP2345677A3 (de) | 2004-06-16 | 2014-04-16 | Dow Global Technologies LLC | Verfahren zur Auswahl von Polymerisationsmodifikatoren |
JP4988568B2 (ja) * | 2004-07-08 | 2012-08-01 | エクソンモービル・ケミカル・パテンツ・インク | オレフィン重合触媒系およびその使用方法 |
WO2006049857A1 (en) | 2004-10-28 | 2006-05-11 | Dow Global Technologies Inc. | Method of controlling a polymerization reactor |
EP2894176B1 (de) | 2005-03-17 | 2022-06-01 | Dow Global Technologies LLC | Katalysatorzusammensetzung mit reversiblem Kettenübertragungsreagenz für die regio-irreguläre Multiblock-Copolymer-Synthese |
US9410009B2 (en) | 2005-03-17 | 2016-08-09 | Dow Global Technologies Llc | Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation |
EP1861439B1 (de) | 2005-03-17 | 2013-01-30 | Dow Global Technologies LLC | Katalysatorzusammensetzung mit transportwirkstoff zur taktischen/ataktischen multiblock-copolymer-formierung |
ES2526056T3 (es) * | 2005-09-15 | 2015-01-05 | Dow Global Technologies Llc | Copolímeros de bloque de olefinas catalíticos por medio de agente de transporte polimerizable |
KR20080055838A (ko) * | 2005-09-15 | 2008-06-19 | 다우 글로벌 테크놀로지스 인크. | 다중심 셔틀링제를 통한 중합체 구성 및 분자량 분포의제어 |
US8242237B2 (en) | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
ITMI20070877A1 (it) | 2007-05-02 | 2008-11-03 | Dow Global Technologies Inc | Processo per la produzione di copolimeri a blocchi multipli con l'utilizzo di solventi polari |
ITMI20070878A1 (it) | 2007-05-02 | 2008-11-03 | Dow Global Technologies Inc | Processo per la polimerizzazine di polimeri tattici con l'uso di catalizzatori chirali |
US8247587B2 (en) * | 2007-12-19 | 2012-08-21 | Basell Polyolefine Gmbh | Mono-hydroindacenyl complexes |
US8318875B2 (en) * | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
EP2459597B1 (de) | 2009-07-29 | 2013-10-23 | Dow Global Technologies LLC | Multifunktions-kettentransportwirkstoffe |
US20110054122A1 (en) * | 2009-08-31 | 2011-03-03 | Jerzy Klosin | Catalyst and process for polymerizing an olefin and polyolefin prepared thereby |
KR101854480B1 (ko) | 2010-02-19 | 2018-05-03 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 단량체의 중합 방법 및 이를 위한 촉매 |
ES2691727T3 (es) | 2010-02-19 | 2018-11-28 | Dow Global Technologies Llc | Complejos metal-ligando y catalizadores |
WO2012103080A1 (en) | 2011-01-26 | 2012-08-02 | Dow Global Technologies Llc | Process for making a polyolefin-polysiloxane block copolymer |
WO2012155022A1 (en) | 2011-05-12 | 2012-11-15 | Dow Global Technologies Llc | Non-cyclopentadienyl-based chromium catalysts for olefin polymerization |
KR101248423B1 (ko) * | 2011-06-09 | 2013-04-02 | 에스케이종합화학 주식회사 | 에틸렌 - α-올레핀 - 디엔 공중합체의 제조방법 |
JP5600219B2 (ja) | 2011-10-24 | 2014-10-01 | 三菱化学株式会社 | 熱可塑性エラストマー組成物及びその製造方法 |
US9382361B2 (en) | 2014-03-21 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Process to produce ethylene propylene copolymers |
US9796795B2 (en) | 2015-01-14 | 2017-10-24 | Exxonmobil Chemical Patents Inc. | Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof |
CN114685703A (zh) | 2015-04-20 | 2022-07-01 | 埃克森美孚化学专利公司 | 包含氟化物化的载体的催化剂组合物及其使用方法 |
US10640583B2 (en) | 2015-04-20 | 2020-05-05 | Exxonmobil Chemical Patents, Inc. | Catalyst composition comprising fluorided support and processes for use thereof |
EP3356374A1 (de) | 2015-09-30 | 2018-08-08 | Dow Global Technologies LLC | Mehr- oder doppelköpfige zusammensetzungen für kettenübertragung und verfahren zur herstellung davon |
US9803037B1 (en) | 2016-05-03 | 2017-10-31 | Exxonmobil Chemical Patents Inc. | Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof |
CN109312015B (zh) | 2016-05-03 | 2021-10-26 | 埃克森美孚化学专利公司 | 四氢引达省基催化剂组合物、催化剂体系及其使用方法 |
WO2018063898A1 (en) | 2016-09-29 | 2018-04-05 | Dow Global Technologies Llc | Modified ziegler-natta (pro)catalyst and system |
CN109790246A (zh) | 2016-09-29 | 2019-05-21 | 陶氏环球技术有限责任公司 | 聚合烯烃的方法 |
KR102449474B1 (ko) | 2016-09-29 | 2022-10-11 | 다우 글로벌 테크놀로지스 엘엘씨 | 마그네슘 할라이드-담지 티탄 (전)촉매 |
BR112019006150B1 (pt) | 2016-09-30 | 2023-02-28 | Dow Global Technologies Llc | Composição e processo para preparar a composição |
JP7123040B2 (ja) | 2016-09-30 | 2022-08-22 | ダウ グローバル テクノロジーズ エルエルシー | 連鎖シャトリングに有用な多頭または二頭組成物の調製方法 |
TW201840572A (zh) | 2016-09-30 | 2018-11-16 | 美商陶氏全球科技有限責任公司 | 適用於鏈梭移之多頭或雙頭組合物及其製備方法 |
US11123726B2 (en) | 2016-10-27 | 2021-09-21 | Univation Technologies, Lle | Method of preparing a molecular catalyst |
KR101846412B1 (ko) * | 2016-12-06 | 2018-05-18 | 한화케미칼 주식회사 | 올레핀 중합 촉매용 전이금속 화합물, 이를 포함하는 올레핀 중합 촉매 및 이를 이용하여 중합된 폴리올레핀 |
US10807998B2 (en) | 2017-01-13 | 2020-10-20 | Exxonmobil Chemical Patents Inc. | Bridged bis(indenyl) transitional metal complexes, production, and use thereof |
CN110603274B (zh) | 2017-03-15 | 2022-09-30 | 陶氏环球技术有限责任公司 | 用于形成多嵌段共聚物的催化剂体系 |
EP3596142B1 (de) | 2017-03-15 | 2023-05-24 | Dow Global Technologies LLC | Katalysatorsystem für mehrblockcopolymerbildung |
EP3596143B1 (de) | 2017-03-15 | 2023-04-26 | Dow Global Technologies LLC | Katalysatorsystem für mehrblockcopolymerbildung |
WO2018170208A1 (en) | 2017-03-15 | 2018-09-20 | Dow Global Technologies Llc | Catalyst system for multi-block copolymer formation |
CN110582518B (zh) | 2017-03-15 | 2022-08-09 | 陶氏环球技术有限责任公司 | 用于形成多嵌段共聚物的催化剂体系 |
JP7381449B2 (ja) | 2017-08-24 | 2023-11-15 | ダウ グローバル テクノロジーズ エルエルシー | エチレン/c5-c10アルファ-オレフィン/ポリエチレンインターポリマー |
US10703838B2 (en) | 2017-10-31 | 2020-07-07 | Exxonmobil Chemical Patents Inc. | Mixed catalyst systems with four metallocenes on a single support |
US20210002308A1 (en) | 2018-03-19 | 2021-01-07 | Dow Global Technologies Llc | Silicon-terminated organo-metal compounds and processes for preparing the same |
US10899853B2 (en) | 2018-03-19 | 2021-01-26 | Exxonmobil Chemical Patents Inc. | Processes for producing high propylene content PEDM using tetrahydroindacenyl catalyst systems |
EP3768740A4 (de) * | 2018-03-19 | 2021-12-29 | ExxonMobil Chemical Patents Inc. | Verfahren zur herstellung von pedm mit hohem propylengehalt unter verwendung von tetrahydroindacenylkatalysatorsystemen |
EP3775003A4 (de) | 2018-04-06 | 2022-01-19 | ExxonMobil Chemical Patents Inc. | Thermoplastische vulkanisierungszusammensetzungen |
US11939411B2 (en) | 2018-09-28 | 2024-03-26 | Dow Global Technologies Llc | Tetra-functional long-chain branched ethylene-based polymers |
US11912799B2 (en) | 2018-09-28 | 2024-02-27 | Dow Global Technologies Llc | Tetra-functional long-chain branched ethylene-based polymers |
SG11202102949TA (en) | 2018-09-28 | 2021-04-29 | Dow Global Technologies Llc | Process of polymerizing tetra-functional long-chain branched polyolefin resins |
KR20210068075A (ko) | 2018-09-28 | 2021-06-08 | 다우 글로벌 테크놀로지스 엘엘씨 | 4작용성 장쇄 분지형 에틸렌계 중합체 |
JP2022528531A (ja) | 2019-03-29 | 2022-06-14 | ダウ グローバル テクノロジーズ エルエルシー | 三官能性長鎖分岐オレフィンを重合させるプロセス |
US12065523B2 (en) | 2019-03-29 | 2024-08-20 | Dow Global Technologies Llc | Tri-functional long-chain branched polyolefin |
US20220213246A1 (en) | 2019-03-29 | 2022-07-07 | Dow Global Technologies Llc | Process of polymerizing tri-functional long-chain branched olefin |
JP7430774B2 (ja) | 2019-07-17 | 2024-02-13 | エクソンモービル・ケミカル・パテンツ・インク | 低ガラス転移温度を有する高プロピレン含有量ep |
US11472828B2 (en) | 2019-10-11 | 2022-10-18 | Exxonmobil Chemical Patents Inc. | Indacene based metallocene catalysts useful in the production of propylene polymers |
WO2021173361A1 (en) | 2020-02-24 | 2021-09-02 | Exxonmobil Chemical Patents Inc. | Ansa-bis(inden-2-yl) catalysts for producing vinylidene-terminated polyalphaolefins |
BR112023000641A2 (pt) | 2020-07-17 | 2023-01-31 | Dow Global Technologies Llc | Processo de polimerização de monômeros de olefina |
EP4424722A1 (de) | 2021-10-26 | 2024-09-04 | China Petroleum & Chemical Corporation | Verfahren zur förderung der phasentrennung einer polymerlösung und verfahren zur herstellung eines olefinpolymers |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5621126A (en) * | 1987-01-30 | 1997-04-15 | Exxon Chemical Patents Inc. | Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts |
US5264405A (en) * | 1989-09-13 | 1993-11-23 | Exxon Chemical Patents Inc. | Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts |
US5096867A (en) * | 1990-06-04 | 1992-03-17 | Exxon Chemical Patents Inc. | Monocyclopentadienyl transition metal olefin polymerization catalysts |
US5055438A (en) * | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
US5057475A (en) * | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
US5064802A (en) * | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
US5721185A (en) * | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
DE59206948D1 (de) * | 1991-11-30 | 1996-09-26 | Hoechst Ag | Metallocene mit benzokondensierten Indenylderivaten als Liganden, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
US5374696A (en) * | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
HUT74312A (en) * | 1993-06-24 | 1996-12-30 | Dow Chemical Co | Titanium or zirconium complexes, process for producing thereof, polymerization catalysts containing thereof and polymerization process |
US5470993A (en) * | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
JP3795072B2 (ja) * | 1993-11-18 | 2006-07-12 | 出光興産株式会社 | 遷移金属化合物,オレフィン重合用触媒,該触媒を用いたオレフィン系重合体の製造方法 |
DE4416876A1 (de) * | 1994-05-13 | 1995-11-16 | Basf Ag | Verfahren zur Herstellung von verbrückten Halbsandwichkomplexen |
US5486632A (en) * | 1994-06-28 | 1996-01-23 | The Dow Chemical Company | Group 4 metal diene complexes and addition polymerization catalysts therefrom |
RU2175325C2 (ru) * | 1995-10-27 | 2001-10-27 | Дзе Дау Кемикал Компани | Металлокомплексы, содержащие замещенный инденил, и способ полимеризации олефинов |
US5688880A (en) * | 1995-12-11 | 1997-11-18 | The Dow Chemical Company | Readily supportable metal complexes |
-
1997
- 1997-10-14 US US08/949,505 patent/US5965756A/en not_active Expired - Lifetime
- 1997-11-21 KR KR10-1999-7005558A patent/KR100500093B1/ko not_active IP Right Cessation
- 1997-11-21 DE DE69707306T patent/DE69707306T2/de not_active Expired - Lifetime
- 1997-11-21 BR BRPI9714571-8A patent/BR9714571B1/pt not_active IP Right Cessation
- 1997-11-21 AU AU53626/98A patent/AU726100B2/en not_active Ceased
- 1997-11-21 CN CN97199909A patent/CN1093543C/zh not_active Expired - Lifetime
- 1997-11-21 ID IDW990543A patent/ID22003A/id unknown
- 1997-11-21 CA CA002268440A patent/CA2268440C/en not_active Expired - Fee Related
- 1997-11-21 ES ES97950689T patent/ES2162339T3/es not_active Expired - Lifetime
- 1997-11-21 TR TR1999/01403T patent/TR199901403T2/xx unknown
- 1997-11-21 WO PCT/US1997/021585 patent/WO1998027103A1/en active IP Right Grant
- 1997-11-21 EP EP97950689A patent/EP0946575B1/de not_active Expired - Lifetime
- 1997-11-21 JP JP52771998A patent/JP3427302B2/ja not_active Expired - Lifetime
- 1997-11-21 AT AT97950689T patent/ATE206713T1/de not_active IP Right Cessation
- 1997-12-17 MY MYPI97006079A patent/MY117028A/en unknown
- 1997-12-18 AR ARP970105965A patent/AR010799A1/es active IP Right Grant
- 1997-12-18 TW TW086119201A patent/TW513448B/zh active
-
1999
- 1999-06-03 US US09/325,049 patent/US6034022A/en not_active Expired - Lifetime
- 1999-06-18 NO NO19992993A patent/NO324380B1/no not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
NO992993L (no) | 1999-06-18 |
NO992993D0 (no) | 1999-06-18 |
WO1998027103A1 (en) | 1998-06-25 |
DE69707306T2 (de) | 2002-06-27 |
EP0946575B1 (de) | 2001-10-10 |
MY117028A (en) | 2004-04-30 |
JP2000507959A (ja) | 2000-06-27 |
KR20000069586A (ko) | 2000-11-25 |
CN1093543C (zh) | 2002-10-30 |
KR100500093B1 (ko) | 2005-07-11 |
ES2162339T3 (es) | 2001-12-16 |
TR199901403T2 (xx) | 1999-08-23 |
CA2268440A1 (en) | 1998-06-25 |
JP3427302B2 (ja) | 2003-07-14 |
TW513448B (en) | 2002-12-11 |
AU5362698A (en) | 1998-07-15 |
DE69707306D1 (de) | 2001-11-15 |
ID22003A (id) | 1999-08-19 |
CA2268440C (en) | 2007-04-17 |
US6034022A (en) | 2000-03-07 |
EP0946575A1 (de) | 1999-10-06 |
US5965756A (en) | 1999-10-12 |
BR9714571B1 (pt) | 2009-01-13 |
NO324380B1 (no) | 2007-10-01 |
AR010799A1 (es) | 2000-07-12 |
CN1237976A (zh) | 1999-12-08 |
BR9714571A (pt) | 2000-03-28 |
AU726100B2 (en) | 2000-11-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ATE206713T1 (de) | Metallkomplexe, kondensierte indenylderivate enthaltend, und polymerisationsverfahren | |
ATE213250T1 (de) | Metallkomplexe enthaltend in position 3 arylsubstituierte indenylderivate, und polymerisationsverfahren | |
ATE234851T1 (de) | Cyclopentaphenanthrenyl-titan-komplexe und polymerisationsverfahren | |
NO990545L (no) | 3-heteroatom substituerte cyklopentadienyl-inneholdende metallkomplekser og olefin polymerisasjons-prosess | |
ATE227729T1 (de) | Substituierte indenyl enthaltende metallkomplexe und olefinpolymerisierungsverfahren. | |
NL300248I1 (nl) | Gesubstitueerde 3,5-difenyl-1,2,4-triazolen en de toepassing daarvan als farmaceutische metaal chelatoren. | |
ATE547437T1 (de) | Substituierte gruppe-4-metallkomplexe, katalysatoren und olefinpolymerisationsverfahren | |
DE69431222D1 (de) | Übergangsmetallverbindung, und diese enthaltender Polymerisationkatalysator | |
NO985329D0 (no) | FremgangsmÕte for Õ fremstille koplymerer og blandinger inneholdende det samme | |
DE60005185D1 (de) | Übergangsmetallkomplexe und olefin-polymerisationsverfahren | |
ZA976998B (en) | 3-Heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process | |
DE69732397D1 (de) | Beschichtungsverfahren, beschichtungsmittel und damit beschichtete artikel | |
FI20020195A (fi) | Metallikomplekseja, jotka sisältävät 2,6-diasyylipyridiiniligandin, ja niiden käyttö eteenin polymerointiin | |
DE59711118D1 (de) | Spickeln, Zunehmen und Mindern | |
DE59812192D1 (de) | Bleichaktive Metall-Komplexe | |
BR9507510A (pt) | Heterociclos de n-cianoaril nitrogênio | |
DE69713471D1 (de) | Substituierte benzoldithiol-metallkomplexe | |
DE69713751D1 (de) | Heterocyclische metallkomplexe und olefinpolymerisationsverfahren | |
AU3902300A (en) | Bis(n,n-dihydrocarbylamino)- substituted cyclopentadienes and metal complexes thereof | |
DE69810492D1 (de) | Mehrzähnige imine und ihre metalkomplexe | |
ID18764A (id) | Degradasi pati menggunakan komplek koordinasi berdasarkan logam | |
EP0671452A3 (de) | Rauchgasarme, temperaturbeständige Binde- und Beschichtungsmittel und deren Verwendung. | |
DE69100297D1 (de) | Katalytische Zusammensetzungen und Polymerisationsverfahren, Hexakiphosphin- und Hexahalid-Verbindungen. | |
ZA9711382B (en) | Fused ring substituted indenyl metal complexes and polymerization process | |
ES1035618Y (es) | Base alargacamas perfeccionado. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
UEP | Publication of translation of european patent specification | ||
REN | Ceased due to non-payment of the annual fee |