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ATE173266T1 - SULFONATED 2,2'-BIS(DIPHENYLPHOSPHINOMETHYL)-1,1'-BINAPHTHALINES, PROCESS FOR THE PRODUCTION THEREOF AND THEIR USE IN A PROCESS FOR THE HYDROFORMYLATION OF OLEFINICALLY UNSATURATED COMPOUNDS - Google Patents

SULFONATED 2,2'-BIS(DIPHENYLPHOSPHINOMETHYL)-1,1'-BINAPHTHALINES, PROCESS FOR THE PRODUCTION THEREOF AND THEIR USE IN A PROCESS FOR THE HYDROFORMYLATION OF OLEFINICALLY UNSATURATED COMPOUNDS

Info

Publication number
ATE173266T1
ATE173266T1 AT93107701T AT93107701T ATE173266T1 AT E173266 T1 ATE173266 T1 AT E173266T1 AT 93107701 T AT93107701 T AT 93107701T AT 93107701 T AT93107701 T AT 93107701T AT E173266 T1 ATE173266 T1 AT E173266T1
Authority
AT
Austria
Prior art keywords
olefinically unsaturated
unsaturated compounds
hydroformylation
binaphthalines
diphenylphosphinomethyl
Prior art date
Application number
AT93107701T
Other languages
German (de)
Inventor
Wolfgang A Prof Dr Di Herrmann
Rainer Dr Manetsberger
Helmut Dr Dipl-Chem Bahrmann
Christian Dipl-Ch Kohlpaintner
Peter Dr Dipl-Chem Lappe
Original Assignee
Celanese Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE4217803A external-priority patent/DE4217803A1/en
Priority claimed from DE4244274A external-priority patent/DE4244274A1/en
Application filed by Celanese Gmbh filed Critical Celanese Gmbh
Application granted granted Critical
Publication of ATE173266T1 publication Critical patent/ATE173266T1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5027—Polyphosphines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C09J123/24—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having ten or more carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96—Water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Enzymes And Modification Thereof (AREA)

Abstract

The invention concerns novel sulphonated diphosphines of the general formula <IMAGE> where Ar is m-C6H4SO3M, M is hydrogen, ammonium, a monovalent metal or the equivalent of a multivalent metal, pH is phenyl, m is identical or different and has the value 1 or 2, and n is identical or different and denotes 0.1 or 2, their preparation and the hydroformylation of olefins and olefinically unsaturated compounds using these compounds as constituent of water-soluble catalyst systems for hydroformylating olefins and olefinically unsaturated compounds.
AT93107701T 1992-05-29 1993-05-12 SULFONATED 2,2'-BIS(DIPHENYLPHOSPHINOMETHYL)-1,1'-BINAPHTHALINES, PROCESS FOR THE PRODUCTION THEREOF AND THEIR USE IN A PROCESS FOR THE HYDROFORMYLATION OF OLEFINICALLY UNSATURATED COMPOUNDS ATE173266T1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4217803A DE4217803A1 (en) 1992-05-29 1992-05-29 New sulphonated 2,2'-bis:di:phenyl-phosphino-methyl-1,1-di:naphthyl cpds.
DE4244274A DE4244274A1 (en) 1992-12-28 1992-12-28 New sulphonated 2,2'-bis:di:phenyl-phosphino-methyl-1,1-di:naphthyl cpds.

Publications (1)

Publication Number Publication Date
ATE173266T1 true ATE173266T1 (en) 1998-11-15

Family

ID=25915257

Family Applications (1)

Application Number Title Priority Date Filing Date
AT93107701T ATE173266T1 (en) 1992-05-29 1993-05-12 SULFONATED 2,2'-BIS(DIPHENYLPHOSPHINOMETHYL)-1,1'-BINAPHTHALINES, PROCESS FOR THE PRODUCTION THEREOF AND THEIR USE IN A PROCESS FOR THE HYDROFORMYLATION OF OLEFINICALLY UNSATURATED COMPOUNDS

Country Status (13)

Country Link
US (3) US5347045A (en)
EP (1) EP0571819B1 (en)
JP (2) JPH0794466B2 (en)
KR (1) KR100265520B1 (en)
CN (1) CN1032538C (en)
AT (1) ATE173266T1 (en)
BR (1) BR9302013A (en)
CA (1) CA2096812C (en)
DE (1) DE59309119D1 (en)
ES (1) ES2126613T3 (en)
MX (1) MX9303004A (en)
SG (1) SG43948A1 (en)
TW (1) TW225485B (en)

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4338826A1 (en) * 1993-11-13 1995-05-18 Hoechst Ag Process for the preparation of 1,1'-binaphthylene
US5536858A (en) * 1994-02-12 1996-07-16 Hoffmann-La Roche Inc. Tetrasulfonated diphosphine compounds and metal complexes thereof for asymmetric catalytic reactions
US5736480A (en) * 1994-02-22 1998-04-07 California Institute Of Technology Supported phase chiral sulfonated BINAP catalyst solubilized in alcohol and method of asymmetric hydrogenation
US5935892A (en) 1994-02-22 1999-08-10 California Institute Of Technology Supported phase catalyst
DE4415682A1 (en) * 1994-05-04 1995-11-09 Hoechst Ag Palladium catalysts with sulfonated bisphosphines as ligands, processes for their preparation and their use for carbonylation reactions
DE4434844A1 (en) * 1994-09-29 1996-04-04 Hoechst Ag Diphosphines and process for their preparation
ZA96178B (en) * 1995-01-18 1997-06-30 Exxon Chemical Patents Inc Organic compounds and processes for their manufacture
DE19506279A1 (en) * 1995-02-23 1996-08-29 Hoechst Ag Sulfonated diphosphines and a process for their preparation
DE19619527A1 (en) * 1996-05-15 1997-11-20 Hoechst Ag Catalyst systems based on rhodium complex compounds with diphosphine ligands and their use in the production of aldehydes
CZ297891B6 (en) * 1995-07-25 2007-04-25 Archimica Gmbh Process for preparing polynucleic aromatic compounds
DE19609336C1 (en) * 1996-03-11 1997-03-13 Hoechst Ag New substd. di:phenyl-di:phosphane cpds. used e.g. as complexing agents
DE19610869A1 (en) * 1996-03-20 1997-09-25 Hoechst Ag Process for the preparation of aldehydes
US5777087A (en) * 1996-04-18 1998-07-07 Celanese International Corporation Aryl diphosphines and catalysts containing the same
US6043398A (en) * 1996-04-18 2000-03-28 Celanese International Corporation Chemical processes using aryl diphosphine containing catalysts
DE19619528A1 (en) * 1996-05-15 1997-11-20 Hoechst Ag Substituted diphosphines and a process for their preparation
US5753584A (en) * 1996-06-04 1998-05-19 Intevep, S.A. Catalyst system for selective hydrogenation of heteroaromatic sulfur-containing and nitrogen-containing compounds
US6150298A (en) * 1996-08-27 2000-11-21 Celanese Gmbh Process for telomerizing dienes
IT1286879B1 (en) * 1996-11-21 1998-07-17 Consiglio Nazionale Ricerche 1,3-DIPHOSPHINEPROPANE BINDERS AND COMPLEXES FORMED THEM WITH TRANSITION METALS, THEIR PREPARATION AND USE
DE19742305A1 (en) 1997-09-25 1999-04-01 Hoechst Ag Process for the preparation of aldehydes by hydroformylation in the presence of crown ether
US6307087B1 (en) * 1998-07-10 2001-10-23 Massachusetts Institute Of Technology Ligands for metals and improved metal-catalyzed processes based thereon
US7223879B2 (en) * 1998-07-10 2007-05-29 Massachusetts Institute Of Technology Ligands for metals and improved metal-catalyzed processes based thereon
DE19918284C1 (en) * 1999-04-22 2000-12-14 Celanese Chem Europe Gmbh Preparation of aqueous solution of sulfonated arylphosphine, useful in catalysts for hydroformylation of olefins, involves reacting arylphosphine with oleum, diluting and blowing inert gas through the solution
GR20000100460A (en) * 2000-12-27 2002-10-09 Celanese Chemicals Europe Gmbh Method for the preparation of aldehydes
DE10114868C1 (en) * 2001-03-26 2002-10-31 Oxeno Olefinchemie Gmbh Process for the preparation of diphosphines and their use
DE10352263A1 (en) * 2003-11-08 2005-06-23 Celanese Chemicals Europe Gmbh Process for the preparation of TCD-monenal
DE10352261B4 (en) * 2003-11-08 2006-08-24 Celanese Chemicals Europe Gmbh Process for the preparation of TCD-dialdehyde
US20050209469A1 (en) 2004-03-22 2005-09-22 Shutt John R Converting propylene in an oxygenate-contaminated propylene stream to non-polymerization derivative products
JP5442925B2 (en) * 2006-04-28 2014-03-19 一般財団法人電力中央研究所 Analysis method for polychlorinated biphenyls
DE102008044783B4 (en) 2008-08-28 2012-05-16 Oxea Gmbh Process for the recovery of aliphatic C3 to C10 aldehydes from high boilers by thermal treatment
DE102009004655B4 (en) 2009-01-15 2013-02-14 Oxea Gmbh Process for the preparation of aldehydes
DE102009016651B4 (en) 2009-04-07 2011-11-17 Oxea Gmbh Process for the preparation of aldehydes
DE102014002103B4 (en) 2014-02-15 2020-10-22 Oxea Gmbh Process for the regeneration of used hydroformylation catalysts
US11365357B2 (en) 2019-05-24 2022-06-21 Eastman Chemical Company Cracking C8+ fraction of pyoil
US12031091B2 (en) 2019-05-24 2024-07-09 Eastman Chemical Company Recycle content cracked effluent
CN113993977B (en) 2019-05-24 2024-09-13 伊士曼化工公司 Mixing small amount of pyrolysis oil into liquid flow processed in gas cracker
WO2021021902A1 (en) 2019-07-29 2021-02-04 Eastman Chemical Company Process for the preparation of polyesters with recycled monomers from pyrolysis and methanolysis
KR20220043165A (en) 2019-07-29 2022-04-05 이스트만 케미칼 컴파니 Recycled Cyclobutane Diol Polyester
US11945998B2 (en) 2019-10-31 2024-04-02 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
US11319262B2 (en) 2019-10-31 2022-05-03 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
WO2021092305A1 (en) 2019-11-07 2021-05-14 Eastman Chemical Company Recycle content mixed esters and solvents
WO2021092306A1 (en) 2019-11-07 2021-05-14 Eastman Chemical Company Recycle content alpha olefins and fatty alcohols

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US4248802A (en) * 1975-06-20 1981-02-03 Rhone-Poulenc Industries Catalytic hydroformylation of olefins
EP0279018B1 (en) * 1987-02-18 1992-01-29 EASTMAN KODAK COMPANY (a New Jersey corporation) Chelate ligands for low pressure hydroformylation catalyst and process employing same
CA2002598A1 (en) * 1988-11-30 1990-05-31 Thomas Allen Puckette Preparation of biaryl compounds
US5274183A (en) * 1990-12-17 1993-12-28 Hoechst Aktiengesellschaft Water-soluble sulfonated diphosphines
DE4040315A1 (en) * 1990-12-17 1992-06-25 Hoechst Ag METHOD FOR PRODUCING ALDEHYDES

Also Published As

Publication number Publication date
KR100265520B1 (en) 2000-09-15
BR9302013A (en) 1993-12-07
EP0571819B1 (en) 1998-11-11
CA2096812A1 (en) 1993-11-30
KR940005650A (en) 1994-03-22
US5565398A (en) 1996-10-15
JPH0794466B2 (en) 1995-10-11
TW225485B (en) 1994-06-21
CN1032538C (en) 1996-08-14
EP0571819A1 (en) 1993-12-01
US5481045A (en) 1996-01-02
ES2126613T3 (en) 1999-04-01
MX9303004A (en) 1993-11-01
CA2096812C (en) 1996-11-12
SG43948A1 (en) 1997-11-14
JPH06145181A (en) 1994-05-24
JPH07252279A (en) 1995-10-03
CN1080928A (en) 1994-01-19
DE59309119D1 (en) 1998-12-17
JP2680791B2 (en) 1997-11-19
US5347045A (en) 1994-09-13

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