AR084143A1 - Procesos para preparar composiciones de polimeros a base de etileno - Google Patents
Procesos para preparar composiciones de polimeros a base de etilenoInfo
- Publication number
- AR084143A1 AR084143A1 ARP110104523A ARP110104523A AR084143A1 AR 084143 A1 AR084143 A1 AR 084143A1 AR P110104523 A ARP110104523 A AR P110104523A AR P110104523 A ARP110104523 A AR P110104523A AR 084143 A1 AR084143 A1 AR 084143A1
- Authority
- AR
- Argentina
- Prior art keywords
- ethylene
- based polymers
- processes
- prepare compositions
- polymerize
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
- C08F4/34—Per-compounds with one peroxy-radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/60003—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/60168—Tetra- or multi-dentate ligand
- C08F4/60186—Dianionic ligand
- C08F4/60193—OOOO
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/62003—Refractory metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/62168—Tetra- or multi-dentate ligand
- C08F4/62186—Dianionic ligand
- C08F4/62193—OOOO
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/04—Philipps catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/903—Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
Abstract
La presente provee un proceso para formar una composición de polímeros basados en etileno, comprendiendo el proceso por lo menos lo siguiente: paso 1: polimerizar un primer polímero basado en etileno en la presencia de por lo menos un catalizador molecular y de un agente de transferencia de cadenas de hidrocarburos, y bajo una presión de polimerización de por lo menos 14.000 psi; paso 2: polimerizar un segundo polímero basado en etileno.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US41956010P | 2010-12-03 | 2010-12-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
AR084143A1 true AR084143A1 (es) | 2013-04-24 |
Family
ID=45218882
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP110104523A AR084143A1 (es) | 2010-12-03 | 2011-12-02 | Procesos para preparar composiciones de polimeros a base de etileno |
Country Status (11)
Country | Link |
---|---|
US (1) | US9045628B2 (es) |
EP (2) | EP2813545A1 (es) |
JP (1) | JP6031042B2 (es) |
KR (1) | KR101869997B1 (es) |
CN (1) | CN103339186B (es) |
AR (1) | AR084143A1 (es) |
BR (1) | BR112013013634B1 (es) |
CA (1) | CA2819467C (es) |
ES (1) | ES2524430T3 (es) |
SG (1) | SG190985A1 (es) |
WO (1) | WO2012074812A1 (es) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9000113B2 (en) * | 2010-05-28 | 2015-04-07 | Basell Polyolefine Gmbh | Polyethylene composition and method for obtaining same |
CN103781806B (zh) | 2011-07-05 | 2017-06-23 | 陶氏环球技术有限责任公司 | 基于乙烯的聚合物和制备它的方法 |
WO2013169359A1 (en) * | 2012-05-09 | 2013-11-14 | Dow Global Technologies Llc | Polyolefin polymerization process, semi-crystalline ethylene-based polymer made therefrom, and articles made from the polymer |
JP6180517B2 (ja) * | 2012-06-01 | 2017-08-16 | ダウ グローバル テクノロジーズ エルエルシー | アルキル化フェノールを使用してエチレン系ポリマーを作製するためのフリーラジカルプロセス |
WO2014105415A1 (en) | 2012-12-27 | 2014-07-03 | Dow Global Technologies Llc | A polymerization process for producing ethylene based polymers |
US9751998B2 (en) | 2012-12-27 | 2017-09-05 | Dow Global Technologies Llc | Catalyst systems for olefin polymerization |
SG11201505073SA (en) * | 2012-12-27 | 2015-07-30 | Dow Global Technologies Llc | A polymerization process for producing ethylene based polymers |
WO2014210333A1 (en) | 2013-06-28 | 2014-12-31 | Dow Global Technologies Llc | Molecular weight control of polyolefins using halogenated bis-phenylphenoxy catalysts |
ES2728677T3 (es) | 2013-12-19 | 2019-10-28 | Dow Global Technologies Llc | Procedimiento para reducir la viscosidad de polímeros a base de propileno con iniciadores de C-C |
WO2015172009A1 (en) | 2014-05-09 | 2015-11-12 | Dow Global Technologies Llc | Process for making ethylene-based polymers using hydrocarbon initiators |
US10336893B2 (en) | 2014-12-23 | 2019-07-02 | Dow Global Technologies Llc | Process for preparing a modified ethylene-based polymer using a hydrocarbon initiator |
KR101679515B1 (ko) * | 2015-02-12 | 2016-11-24 | 주식회사 엘지화학 | 올리고머화 촉매계의 제조방법 및 이에 의해 제조된 올리고머화 촉매계 |
EP3310818B1 (en) | 2015-06-22 | 2020-01-22 | Dow Global Technologies LLC | Process for making ethylene-based polymers using carbon-carbon free radical initiators |
ES2785628T3 (es) | 2015-06-30 | 2020-10-07 | Dow Global Technologies Llc | Un proceso de polimerización para producir polímeros basados en etileno |
BR112017027521B1 (pt) | 2015-06-30 | 2022-01-04 | Dow Global Technologies Llc | Processo de polimerização para produzir polímeros à base de etileno |
BR112018006183B1 (pt) | 2015-09-30 | 2022-06-14 | Dow Global Technologies Llc | Pró-catalisador e processo de polimerização |
WO2017058858A1 (en) | 2015-09-30 | 2017-04-06 | Dow Global Technologies Llc | A polymerization process for producing ethylene based polymers |
KR20180103950A (ko) | 2016-01-28 | 2018-09-19 | 다우 글로벌 테크놀로지스 엘엘씨 | 겔 함량이 낮은 작용화된 에틸렌계 폴리머의 제조방법 |
ES2970349T3 (es) * | 2016-10-18 | 2024-05-28 | Dow Global Technologies Llc | Composiciones y estructuras de fundas extensibles multicapa |
KR102590976B1 (ko) | 2017-09-29 | 2023-10-19 | 다우 글로벌 테크놀로지스 엘엘씨 | 개선된 용해도를 위한 금속 상에 메틸렌트리알킬규소 리간드를 갖는 비스-페닐-페녹시 폴리올레핀 촉매 |
WO2019067280A1 (en) | 2017-09-29 | 2019-04-04 | Dow Global Technologies Llc | BIS-PHENYL-PHENOXY-POLYOLEFIN CATALYSTS HAVING ALKOXY OR AMIDO-TYPE LIGAND ON METAL FOR ENHANCED SOLUBILITY |
SG11202002720WA (en) | 2017-09-29 | 2020-04-29 | Dow Global Technologies Llc | Bis-phenyl-phenoxy polyolefin catalysts having two methylenetrialkylsilicon ligands on the metal for improved solubility |
CN115515991A (zh) * | 2020-05-29 | 2022-12-23 | 陶氏环球技术有限责任公司 | 减弱的后茂金属催化剂 |
Family Cites Families (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1205635A (en) * | 1967-05-12 | 1970-09-16 | Ici Ltd | Polymerisation of ethylene |
FR2519007B1 (fr) * | 1981-12-24 | 1985-12-27 | Charbonnages Ste Chimique | Copolymeres modifies de l'ethylene et d'au moins une a-olefine et procede pour leur preparation |
JPS5922910A (ja) * | 1982-07-29 | 1984-02-06 | Sumitomo Chem Co Ltd | エチレン重合体またはエチレン共重合体の製造方法 |
US5084534A (en) | 1987-06-04 | 1992-01-28 | Exxon Chemical Patents, Inc. | High pressure, high temperature polymerization of ethylene |
US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
GB9103527D0 (en) * | 1991-02-20 | 1991-04-10 | Exxon Chemical Patents Inc | Hp catalyst killer |
US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
JP3157163B2 (ja) | 1991-12-30 | 2001-04-16 | ザ・ダウ・ケミカル・カンパニー | エチレンインターポリマーの重合 |
JP2986547B2 (ja) | 1993-01-29 | 1999-12-06 | ザ・ダウ・ケミカル・カンパニー | エチレン共重合 |
US6448341B1 (en) | 1993-01-29 | 2002-09-10 | The Dow Chemical Company | Ethylene interpolymer blend compositions |
GB9319340D0 (en) * | 1993-09-17 | 1993-11-03 | Exxon Chemical Patents Inc | Olefin polymersisation process |
US5972822A (en) * | 1994-08-02 | 1999-10-26 | The Dow Chemical Company | Biscyclopentadienyldiene complex containing addition polymerization catalysts |
IT1275777B1 (it) | 1995-07-06 | 1997-10-17 | Enichem Spa | Catalizzatore metallocenico per la (co)polimerizzazione delle olefine |
US5869575A (en) | 1995-08-02 | 1999-02-09 | The Dow Chemical Company | Ethylene interpolymerizations |
WO1999045042A1 (en) * | 1998-03-04 | 1999-09-10 | Exxon Chemical Patents Inc. | Noncoordinating anions for olefin polymerization |
US6869904B2 (en) | 2002-04-24 | 2005-03-22 | Symyx Technologies, Inc. | Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom |
JP4158424B2 (ja) * | 2002-06-04 | 2008-10-01 | 東ソー株式会社 | エチレン系重合体およびその製造方法 |
ATE534676T1 (de) * | 2004-11-02 | 2011-12-15 | Dow Global Technologies Llc | Verfahren zur herstellung von polyethylenzusammensetzungen mit niedriger dichte und damit hergestellte polymere |
EP1973655B1 (en) * | 2005-12-16 | 2013-03-20 | Dow Global Technologies LLC | Polydentate heteroatom ligand containing metal complexes, catalysts and methods of making and using the same |
EP2787013A1 (en) * | 2006-05-17 | 2014-10-08 | Dow Global Technologies LLC | Polyolefin solution polymerization process and polymer |
KR101141494B1 (ko) * | 2007-09-05 | 2012-05-03 | 에스케이이노베이션 주식회사 | 다봉 분자량 분포를 갖는 에틸렌 공중합체 및 이의제조방법 |
KR101576697B1 (ko) * | 2008-03-13 | 2015-12-10 | 다우 글로벌 테크놀로지스 엘엘씨 | 다른 중합체와 조합된 에틸렌의 장쇄 분지화 (lcb) 블록 또는 상호연결된 공중합체 |
CA2761318A1 (en) | 2009-06-05 | 2010-12-09 | Dow Global Technologies Llc | Process to make long chain branched (lcb), block, or interconnected copolymers of ethylene |
US8722817B2 (en) * | 2009-06-05 | 2014-05-13 | Dow Global Technologies Llc | Process to make long chain branched (LCB), block, or interconnected copolymers of ethylene |
EP2478022B1 (en) | 2009-09-14 | 2021-01-13 | Dow Global Technologies LLC | Polymers comprising units derived from ethylene and polyalkene |
ES2711958T3 (es) | 2009-09-14 | 2019-05-08 | Dow Global Technologies Llc | Polímeros que comprenden unidades derivadas de etileno y siloxano |
SG179052A1 (en) | 2009-09-14 | 2012-04-27 | Dow Global Technologies Llc | Polymers comprising units derived from ethylene and poly(alkoxide) |
US8440772B2 (en) * | 2011-04-28 | 2013-05-14 | Chevron Phillips Chemical Company Lp | Methods for terminating olefin polymerizations |
-
2011
- 2011-11-21 JP JP2013542049A patent/JP6031042B2/ja not_active Expired - Fee Related
- 2011-11-21 EP EP14180705.7A patent/EP2813545A1/en not_active Withdrawn
- 2011-11-21 ES ES11793922.3T patent/ES2524430T3/es active Active
- 2011-11-21 US US13/990,061 patent/US9045628B2/en active Active
- 2011-11-21 SG SG2013042882A patent/SG190985A1/en unknown
- 2011-11-21 KR KR1020137017253A patent/KR101869997B1/ko active IP Right Grant
- 2011-11-21 BR BR112013013634-0A patent/BR112013013634B1/pt not_active IP Right Cessation
- 2011-11-21 CA CA2819467A patent/CA2819467C/en active Active
- 2011-11-21 WO PCT/US2011/061622 patent/WO2012074812A1/en active Application Filing
- 2011-11-21 EP EP11793922.3A patent/EP2646508B1/en active Active
- 2011-11-21 CN CN201180066451.XA patent/CN103339186B/zh not_active Expired - Fee Related
- 2011-12-02 AR ARP110104523A patent/AR084143A1/es not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
SG190985A1 (en) | 2013-07-31 |
BR112013013634B1 (pt) | 2020-11-10 |
EP2813545A1 (en) | 2014-12-17 |
ES2524430T3 (es) | 2014-12-09 |
CN103339186A (zh) | 2013-10-02 |
EP2646508A1 (en) | 2013-10-09 |
CN103339186B (zh) | 2016-03-30 |
KR20130122960A (ko) | 2013-11-11 |
JP2013544940A (ja) | 2013-12-19 |
CA2819467A1 (en) | 2012-06-07 |
BR112013013634A2 (pt) | 2016-09-13 |
CA2819467C (en) | 2019-06-18 |
JP6031042B2 (ja) | 2016-11-24 |
US9045628B2 (en) | 2015-06-02 |
US20130253126A1 (en) | 2013-09-26 |
WO2012074812A1 (en) | 2012-06-07 |
KR101869997B1 (ko) | 2018-06-22 |
EP2646508B1 (en) | 2014-10-01 |
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