NZ625675A - Process and system for generating synthesis gas - Google Patents
Process and system for generating synthesis gas Download PDFInfo
- Publication number
- NZ625675A NZ625675A NZ625675A NZ62567512A NZ625675A NZ 625675 A NZ625675 A NZ 625675A NZ 625675 A NZ625675 A NZ 625675A NZ 62567512 A NZ62567512 A NZ 62567512A NZ 625675 A NZ625675 A NZ 625675A
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- NZ
- New Zealand
- Prior art keywords
- synthesis gas
- carbon
- converter
- hydrogen
- decomposing
- Prior art date
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- 230000015572 biosynthetic process Effects 0.000 title claims abstract 45
- 238000003786 synthesis reaction Methods 0.000 title claims abstract 45
- 238000000034 method Methods 0.000 title claims abstract 44
- 239000007789 gas Substances 0.000 claims abstract 49
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract 40
- 229910052799 carbon Inorganic materials 0.000 claims abstract 40
- 229930195733 hydrocarbon Natural products 0.000 claims abstract 32
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract 32
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 30
- 239000001257 hydrogen Substances 0.000 claims abstract 30
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract 25
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 21
- 239000012530 fluid Substances 0.000 claims abstract 14
- 230000009466 transformation Effects 0.000 claims 8
- 238000000926 separation method Methods 0.000 claims 6
- 239000003054 catalyst Substances 0.000 claims 5
- 150000002431 hydrogen Chemical class 0.000 claims 5
- 230000001105 regulatory effect Effects 0.000 claims 3
- 230000001131 transforming effect Effects 0.000 claims 3
- 239000000443 aerosol Substances 0.000 claims 2
- 230000001276 controlling effect Effects 0.000 claims 2
- 230000005611 electricity Effects 0.000 claims 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 1
- 239000000295 fuel oil Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000006227 byproduct Substances 0.000 abstract 1
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/40—Carbon monoxide
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
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- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/126—Microwaves
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- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
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- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
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- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
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- C01B32/00—Carbon; Compounds thereof
- C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0405—Apparatus
- C07C1/041—Reactors
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- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0485—Set-up of reactors or accessories; Multi-step processes
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
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- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
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- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
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- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/06—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by mixing with gases
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/0894—Processes carried out in the presence of a plasma
- B01J2219/0898—Hot plasma
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0255—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a non-catalytic partial oxidation step
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- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
- C01B2203/0272—Processes for making hydrogen or synthesis gas containing a decomposition step containing a non-catalytic decomposition step
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- C01B2203/06—Integration with other chemical processes
- C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
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- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0833—Heating by indirect heat exchange with hot fluids, other than combustion gases, product gases or non-combustive exothermic reaction product gases
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- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0861—Methods of heating the process for making hydrogen or synthesis gas by plasma
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/08—Jet fuel
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- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/094—Char
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- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0943—Coke
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- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0973—Water
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- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1656—Conversion of synthesis gas to chemicals
- C10J2300/1659—Conversion of synthesis gas to chemicals to liquid hydrocarbons
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- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas
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- Carbon And Carbon Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
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- Crystals, And After-Treatments Of Crystals (AREA)
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Abstract
A method and an apparatus for generating synthesis gas using hydrocarbons and water are described. In further embodiments of the method and the apparatus, synthesis gases having any desired CO/hydrogen ratio and/or synthetic functionalised and/or non-functionalised hydrocarbons are generated. With this method, a hydrocarbon containing fluid may be transformed into a synthesis gas having variable hydrogen content without generating significant amounts of CO2. Further, hydrogen and different forms of carbon may be obtained as by-products.
Claims (37)
1. A method for generating synthesis gas comprising the following steps: decomposing a hydrocarbon ning fluid into carbon and hydrogen by means of introduction of energy, the energy at least partially being provided by heat, n the carbon and the hydrogen have a temperature of at least 200°C after the decomposing step; bringing water into contact with at least a portion of the carbon generated by the decomposing step at a temperature between 800 and 1700°C, wherein upon ng the carbon into contact with water, the carbon obtained by the decomposing step has cooled down by no more than 50% in °C with respect to its ature after the decomposing step; transforming at least a portion of the water and the carbon obtained by the decomposing step into synthesis gas; wherein the carbon obtained by the decomposing step and the hydrogen obtained by the decomposing step are jointly brought into contact with the water.
A method for generating synthesis gas comprising the ing steps: decomposing a arbon containing fluid into carbon and hydrogen by means of introduction of energy, the energy at least partially being provided by heat, wherein the carbon and the hydrogen have a temperature of at least 200°C after the decomposing step; bringing water into contact with at least a portion of the carbon generated by the decomposing step at a temperature between 800 and , wherein upon bringing the carbon into contact with water, the carbon obtained by the decomposing step has cooled down by no more than 50% in °C with respect to its temperature after the decomposing step; transforming at least a portion of the water and the carbon obtained by the decomposing step into sis gas; wherein the carbon obtained by the decomposing step is separated at least partially from the hydrogen ed by the decomposing step prior to the step of bringing the carbon into contact with the water, and wherein at least a portion of the separated hydrogen is added to the synthesis gas generated by the transformation.
The method for generating synthesis gas ing to claim 1 or 2, wherein the osing step takes place at a temperature above 1000°C; and wherein the carbon is brought into contact with the water at a temperature of at least 1000°C.
The method for generating synthesis gas according to claim 3, wherein the carbon is brought into contact with the water at a temperature between 1000°C and 1200°C
The method for generating synthesis gas according to any one of the preceding , wherein the heat required to reach the temperature of between 800 and 1700°C for the transformation originates essentially completely from the heat that is provided for decomposing the hydrocarbon containing fluid.
The method for generating synthesis gas according to any one of the preceding claims, wherein at least a portion of the heat of at least a portion of the carbon obtained by the decomposing step and/or a n of the hydrogen obtained by the osing step is used to heat the water prior to bringing the water in contact with carbon and/or is used to heat the process r, in which the water is brought into contact with the carbon.
The method for generating synthesis gas according to any one of the ing , wherein the synthesis gas has a temperature of 800 to 1700°C after transformation; and wherein at least a portion of its heat is used to preheat the water and/or other media used for the process.
The method for generating synthesis gas according to any one of the preceding claims, wherein at least a n of the heat of at least a portion of the carbon ed by the decomposing step and/or a portion of the en obtained by the decomposing step and/or a portion of the synthesis gas is used for generating electricity, wherein the electricity may be provided as energy carrier for introducing energy for decomposing the arbon containing fluid.
The method for generating synthesis gas according to any one of the preceding claims, wherein the energy for decomposing the hydrocarbon ning fluid is primarily introduced by means of a plasma.
10. The method for generating synthesis gas according to any one of the preceding claims, wherein the decomposing step is performed in a Kvaerner reactor.
11. The method for generating synthesis gas according to claim 9 or 10, wherein the carbon generated by decomposing and the hydrogen generated by decomposing are brought into contact with water in form of an aerosol.
12. The method for generating synthesis gas according to claim 2, wherein at least one of additional hydrogen or additional carbon monoxide is added to sis gas, and wherein at least a portion of the additional hydrogen is generated by decomposing a hydrocarbon ning fluid at a ature below 1000°C by means of a microwave plasma.
13. The method for generating synthesis gas according to claim 12, wherein the temperature is below 600°C.
14. The method for generating synthesis gas according to any one of claims 2 to 13, wherein the ratio of CO to hydrogen of the synthesis gas has a value of 1:1 to 1:3.
15. The method for generating synthesis gas according to claim 14, wherein the ratio of CO to hydrogen of the synthesis gas has a value of 122.1.
16. A method for generating synthetic functionalised and/or non-functionalised hydrocarbons, wherein at first a synthesis gas is generated according to the method of any one of claims 1 to 15, and wherein the synthesis gas is brought into contact with a suitable catalyst in order to cause the transformation of the synthesis gas to synthetic functionalised and/or non- functionalised hydrocarbons, n the temperature of the catalyst and/or the synthesis gas is open-loop controlled or close-loop regulated to a predetermined range of temperatures.
17. The method for generating synthetic functionalised and/or non-functionalised hydrocarbons according to claim 16, wherein the transformation of the synthesis gas is carried out by means of a Fischer—Tropsch process.
18. The method for generating synthetic functionalised and/or non—functionalised hydrocarbons according to claim 16, wherein the Fischer-Tropsch process is a Shell Middle Distillate Synthesis (SMDS) process.
19. The method for generating synthetic onalised and/or non—functionalised arbons according to claim 16, n the transformation of the sis gas is carried out by means of a Bergius-Pier process, a Pier process or a combination of a Pier process and a Methanol-to—Liquid (MtL) process.
20. The method according to any one of the ing claims, wherein the hydrocarbon containing fluid to be decomposed is l gas, methane, wet gases, heavy oil or a mixture thereof.
21. An apparatus for generating synthesis gas comprising: a hydrocarbon converter for decomposing a hydrocarbon containing fluid into carbon and hydrogen, wherein the hydrocarbon converter comprises at least one process chamber having at least one inlet for a hydrocarbon containing fluid and at least one outlet for carbon and/or hydrogen and at least one unit for introducing energy into the process chamber, the energy consisting at least partially of heat; a C converter for transformation of water and carbon, the C converter comprising at least one further process chamber having at least one inlet for water, at least one inlet for at least carbon and at least one outlet, wherein the inlet for at least carbon is directly connected to the at least one outlet of the hydrocarbon converter; wherein the hydrocarbon converter, the at least one outlet of the arbon converter, the C converter and the at least one inlet of the C converter are adapted to concurrently direct said carbon and said hydrogen produced in the hydrocarbon converter into the C converter.
22. An apparatus for generating synthesis gas comprising: a hydrocarbon converter for osing a arbon containing fluid into carbon and hydrogen, n the hydrocarbon converter comprises at least one process chamber having at least one inlet for a hydrocarbon containing fluid and at least one outlet for carbon and/or hydrogen and at least one unit for introducing energy into the s chamber, the energy consisting at least partially of heat; a C converter for transformation of water and carbon, the C converter comprising at least one further s chamber having at least one inlet for water, at least one inlet for at least carbon and at least one , wherein the inlet for at least carbon is directly ted to the at least one outlet of the hydrocarbon converter; wherein a separation unit is provided for separating the carbon obtained by decomposing and the hydrogen obtained by decomposing, the separation unit having separate outlets for the separated materials coming from the separation unit, wherein the outlet for carbon is ted to the C converter, wherein a separate inlet pipe for the hydrogen coming from the separation unit is provided, the inlet pipe for hydrogen leading into the C converter or into a mixing chamber located ream.
23. The apparatus for generating synthesis gas according to claim 21, wherein the at least one unit for introducing energy into the process chamber is designed in such a way that it can generate, at least locally, temperatures above 1000° C.
24. The apparatus for generating synthesis gas according to any one of claims 21 to 23, wherein the at least one unit for introducing energy into the process chamber comprises a plasma unit.
25. The apparatus for ting synthesis gas according to claim 24, wherein the plasma unit is a microwave plasma unit.
26. The apparatus for generating synthesis gas according to any one of the claims 21 to 25, wherein the process chamber of the C converter is formed by an outlet pipe of the hydrocarbon converter, wherein the outlet pipe is connected to an inlet for water.
27. The apparatus for generating synthesis gas according to any one of claims 21 to 26, wherein the hydrocarbon converter comprises a Kvaerner reactor.
28. The tus for generating synthesis gas according to any one of claims 24, 25 or 27, wherein the hydrocarbon converter is further adapted to produce an aerosol comprising carbon and hydrogen.
29. The apparatus for generating synthesis gas according to any one of claims 21 to 28 having at least one additional hydrocarbon converter for decomposing a hydrocarbon ning fluid into carbon and hydrogen, the additional hydrocarbon converter comprising: at least one process chamber having at least one inlet for the hydrocarbon containing fluid; at least one unit for introducing energy into the s chamber, the energy at least partially consisting of heat; a separation unit for separating the carbon obtained by decomposing and the hydrogen obtained by decomposing, with separation unit having separate outlets for carbon and hydrogen, wherein the outlet for hydrogen is ted to the separate inlet pipe for hydrogen.
30. The apparatus for generating synthesis gas according to claim 29, n the at least one additional hydrocarbon converter is of a type carrying out osing at temperatures below 1000°C by means of a microwave plasma.
31. The apparatus for generating synthesis gas according to claim 30, wherein the temperature is below 600°C.
32. An apparatus for transforming sis gas into synthetic onalised and/or non- functionalised hydrocarbons comprising: an apparatus ing to any one of claims 21 to 31; and a CO converter having a process chamber, in which a catalyst is located, and means for ng the synthesis gas in contact with the catalyst, and a control unit for the oop controlling or closed—loop regulating the temperature of the catalyst and/or the synthesis gas to a predetermined temperature.
33. The apparatus according to claim 32, wherein the CO ter comprises a Fischer- Tropsch converter.
34. The apparatus according to claim 33, wherein the ter is a SMDS converter.
35. The apparatus according to claim 32, wherein the CO converter comprises a Bergius-Pier converter, 8 Pier converter or a combination of a Pier converter with a MtL converter.
36. The apparatus according to any one of claims 31 to 34 further comprising a control unit for open-loop controlling or closed-loop regulating the pressure of the synthesis gas in the CO converter.
37. The method according to any one of claims 1 to 20, ntially as herein described with reference to any one of the Examples and/or
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102011122562 | 2011-12-20 | ||
| DE102011122562.9 | 2011-12-20 | ||
| DE102012008933.3 | 2012-05-04 | ||
| DE102012008933 | 2012-05-04 | ||
| DE102012010542.8 | 2012-05-29 | ||
| DE102012010542A DE102012010542A1 (en) | 2011-12-20 | 2012-05-29 | METHOD AND APPARATUS FOR GENERATING SYNTHESEGAS |
| PCT/EP2012/005310 WO2013091879A1 (en) | 2011-12-20 | 2012-12-20 | Process and system for generating synthesis gas |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NZ625675A true NZ625675A (en) | 2016-05-27 |
| NZ625675B2 NZ625675B2 (en) | 2016-08-30 |
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