NZ234405A

NZ234405A - Beta zeolites having low aluminium content

Info

Publication number: NZ234405A
Application number: NZ234405A
Authority: NZ
Inventors: Stacey I Zones; Dennis L Holtermann; Lawrence W Jossens; Donald S Santilli; Andrew Rainis; James N Ziemer
Original assignee: Chevron Res & Tech
Priority date: 1989-07-07
Filing date: 1990-07-06
Publication date: 1992-05-26
Also published as: AU6052190A; EP0592392A1; JPH05500650A; BR9007515A; WO1991000777A1; CA2062947A1; ZA905369B; KR920703201A; EP0592392A4

Description

<div id="description" class="application article clearfix"> New Zealand Paient Spedficaiion for Paient Number £34405 23 4 4 0 5 Priority Daio(&j: .Til .7. . - ££j ,"or-"'RpecUicifcJon Filed: C - : (S)...CO.(/3.33./3>/4r.f " ; 1 — ■ , . . .©o J. X .XrQ. (ak,.v,c.\Ci.&. .3,5..[ C£j5f ? .C..LQ.&. 0"' —~ ZEALAN'D | P.O. JouiViif?, 'W£>:• I : — EAIta4^A<?T^95.3- - No.: Date: NO DRAWINGS N®W ZEALAND PATENT OFFICE -6 JUL 1990 ft&esiveD COMPLETE SPECIFICATION "LOW-ALUMINIUM BORON BETA ZEOLITE" XKftWe, CHEVRON RESEARCH AND TECHNOLOGY COMPANY, a corporation duly organised under the laws of the State of Delaware, United States of America, of 100 West Tenth Street, Wilmington, Delaware, United States of America, and having a place of business at 555 Market Street, San Francisco, California, United States of America. h'r-reby declare the. invention for which ixkwe pray that a patent may be granted toXKKX'us, and the method by which it is to be performed, to be particularly described in and by the following statement: - ~ 1 ~ (followed by page la) 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 23 4 4 LOW-ALUMINUM BORON BETA ZEOLITE BACKGROUND OF THE INVENTION Natural and synthetic zeolitic crystalline aluminosilicates are useful as catalysts and adsorbents. These aluminosilicates have distinct crystal structures which are demonstrated by X-ray diffraction. The crystal structure defines cavities and pores which are characteristic of the different species. The adsorptive and catalytic properties of each crystalline aluminosilicate are determined in part by the dimensions of its pores and cavities. Thus, the utility of a particular zeolite in a particular application depends at least partly on its crystal structure. Because of their unique molecular sieving characteristics, as well as their catalytic properties, crystalline aluminosilicates are especially useful in such applications as gas drying and separation and hydrocarbon conversion. Although many different crystalline aluminosilicates and silicates have been disclosed, there is a continuing need for new zeolites and silicates with desirable properties for gas separation and drying, hydrocarbon and chemical conversions, and other applications. Crystalline aluminosilicates are usually prepared from aqueous reaction mixtures containing alkali or alkaline earth metal oxides, silica, and alumina. "Nitrogenous zeolites" have been prepared from reaction mixtures containing an organic templating agent, usually a nitrogen-containing organic cation. By varying the synthesis conditions and the composition of the reaction mixture, different zeolites can be formed using the same -l<ar* 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 23 4 4 0 templating agent. Use of N,N,N-trimethyl cyclopentyl-ammonium iodide in the preparation of Zeolite SSZ-15 molecular sieve is disclosed in U.S. Patent No. 4,610,854; use of 1-azoniaspiro [4.4] nonyl bromide and N,N,N-trimethyl neopentylammonium iodide in the preparation of a molecular sieve termed "Losod" is disclosed in Helv. Chim. Acta (1974); Vol. 57, p. 1533 (W. Sieber and W. M. Meier); use of quinuclidinium compounds to prepare a zeolite termed "NU-3" is disclosed in European Patent Publication No. 40016; use of 1,4-di(1-Azonia bicyclo[2.2.2]octane) lower alkyl compounds in the preparation of Zeolite SSZ-16 molecular sieve is disclosed in U.S. Patent No. 4,508,837; use of N,N,N-trialkyl-l-adamantamine in the preparation of Zeolite SSZ-13 molecular sieve is disclosed in U.S. Patent No. 4,544,538, and for SSZ-24 in U.S. Patent No. 4,665,110. Beta zeolite is a known synthetic crystalline aluminosilicate originally described in U.S. Patents Nos. 3,308,069 and Re 28,341 to which reference is made for further details of this zeolite, its preparation and properties. Synthetic zeolitic crystalline borosilicates are useful as catalysts. Methods for preparing high silica content zeolites that contain framework boron are known and disclosed in U.S. Patent No. 4,269,813. The amount of boron contained in the zeolite usually may be made to vary by incorporating different amounts of borate ion in the zeolite forming solution. U.S. Patent No. 4,788,169 describes a method for preparing beta zeolite containing boron. This boron beta zeolite contains 7000 parts per million of aluminum according to the analyses given therein. -2- 23 4 4 01 European Patent Application No. 188,913 claims compositions 02 for various intermediate pore boron-containing zeolites with 03 an aluminum content of less than 0.05% by weight. 04 05 SUMMARY OF THE INVENTION 06 07 We have prepared a family of crystalline borosilicate "N . . 08 molecular sieves with unique properties, referred to herein 09 as "Low-Aluminum Boron Beta Zeolite" or simply "(B)Beta". 10 Thus, according to the present invention, a zeolite 11 composition, (B)Beta, is provided. Also, advantageous uses 12 have been discovered. 13 14 (B)Beta has a mole ratio of an oxide selected from silicon 15 oxide, germanium oxide, and mixtures thereof to an oxide 16 selected from boron oxide or mixtures of boron oxide with 17 aluminum, gallium, or iron oxide, greater than about 10:1 18 and wherein the amount of aluminum is less than 0.10% by 19 weight and having the X-ray diffraction lines of Table 1(a) 20 below. An aluminum-free boron beta zeolite can also be made 21 using the novel method disclosed herein. The amount of vj>) 22 aluminum contained in the zeolite depends simply upon the 23 aluminum impurity present in the silica source. 24 25 This zeolite further has a composition, as synthesized and 26 in the anhydrous state, in terms of mole ratios of oxides as 27 follows: (1.0 to 5.0)Q2°:(0.1 to 2.0^£0s^O^:(greater than 28 10)YO2 wherein M is an alkali metal cation, W is selected 29 from boron, Y is selected from silicon, germanium and 30 mixtures thereof, and Q is a diquaternary ammonium ion, or 31 mixtures of diquarternary ammonium cation, and 32 tetraethylammonium cation. 33 34 -3- 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 234 AOS (B)Beta zeolites preferably have a silica:boria ratio typically in the range of 10:1 to about 100:1. Higher mole ratios can be obtained by treating the zeolite with chelating agents or acids to extract boron from the zeolite lattice. The silica:boria mole ratio can also be increased by using silicon and carbon halides and other similar compounds. The boron in the crystalline network may also be replaced by aluminum, gallium or iron. Procedures for incorporating aluminum are described in U.S. Patent Nos. 4,559,315 and 4,550,092 which are hereby incorporated by refe rence. A method for preparing boron beta zeolite is described in U.S. Patent No. 4,788,169. A tetraethyl ammonium template is used to make this zeolite which contains 7000 parts per million of aluminum. The method described in U.S. Patent No. 4,788,169, however, cannot be used to make boron beta zeolite containing less than 1000 parts per million aluminum. Additionally, a low-aluminum boron beta zeolite cannot be made by replacing the aluminum with boron in the synthesized boron beta zeolite structure. Successful preparation of the low-aluminum boron beta zeolite requires using a new synthesis method described herein. According to one embodiment of the present invention, a method is provided for making (B)beta zeolites, comprising preparing an aqueous mixture containing sources of a diquaternary ammonium ion, an oxide selected from boron oxide, and an oxide selected from silicon oxide, germanium oxide, and mixtures thereof, and having a composition, in terms of mole ratios of oxides, falling within the following ranges: 10:1 to 100:1; wherein Y is selected from silicon, germanium, and mixtures thereof, W is selected from -4- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 234405 boron, and Q is a diquaternary ammonium ion; maintaining the mixture at a temperature of at least 100°C until the crystals of said zeolite are formed; and recovering said crystals. Among other factors, the present invention is based on our finding that low-aluminum boron beta zeolite can be made using a diquaternary ammonium template. The structure of this zeolite is the same as the boron beta zeolite structure synthesized using the tetraethyl ammonium template in U.S. Patent No. 4,788,169. Surprisingly, we have found that the amount of aluminum incorporated into this structure can be decreased by using a different template than the tetraethyl ammonium template used in U.S. Patent No. 4,788,169. We have also found that this zeolite has unexpectedly outstanding hydrocarbon conversion properties, particularly including reforming properties with high sulfur tolerance. DETAILED DESCRIPTION OF THE INVENTION (B)Beta zeolites, as synthesized, have a crystalline structure whose. X-ray powder diffraction pattern shows the following characteristic lines: -5- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 23 4 4 TABLE 1(a) 2 9 d/n 100 x i/i Shape 7.7 11.5 25 Broad 18.40 4.82 8 Very Broad 21.44 4.14 18 22.53 3.95 100 27.50 3.24 10 28.92 3.10 8 Broad 29.90 2.97 9 Typical (B)Beta borosilicate and boroaluminosilicate zeolites have the X-ray diffraction pattern of Tables 2 and 4 below. The d-spacings are shown in Table 8 and demonstrate framework substitution. Calcined (B)Beta has a typical pattern as shown in Table 1(b). TABLE 1(b) 2 e d/n 100 x I/I Shape 7.7 13.58 14.87 18.50 21.83 22.87 27.38 29.30 30.08 11 6 5 52. 5.96 4.80 4.07 3.89 3 3 26 05 2.97 85 9 12 3 15 100 10 6 8 Broad Broad Very Broad Broad Broad -6- 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 234405 The X-ray powder diffraction patterns were determined by standard techniques. The radiation was the K-alpha/doublet of copper and a scintillation counter spectrometer with a strip-chart pen recorder was used. The peak heights I and the positions, as a function of 2 9 where 0 is the Bragg angle, were read from the spectrometer chart. From these measured values, the relative intensities, 100l/lo, where I is the intensity (peak height) of the strongest peak, and d/n, related to interplanar spacings in Angstroms corresponding to the recorded peaks, can be calculated. The X-ray diffraction pattern of Table 1(a) is characteristic of (B)Beta zeolites. The zeolite produced by exchanging the metal or other cations present in the zeolite with various other cations yields substantially the same diffraction pattern although there can be minor shifts in interplanar spacing and minor variations in relative intensity. Minor variations in the diffraction pattern can also result from variations in the organic compound used in the preparation and from variations in the silica-to-boria mole ratio from sample to sample. Calcination can also cause minor shifts in the X-ray diffraction pattern. Notwithstanding these minor perturbations, the basic crystal lattice structure remains unchanged. (B)Beta zeolites can be suitably prepared from an aqueous solution containing sources of an alkali metal borate, a bis(1-Azonia, bicyclo[2.2.2] octane-a, w alkane diquaternary ammonium ion, and an oxide of silicon or germanium, or mixture of the two. The reaction mixture should have a composition in terms of mole ratios falling within the following ranges: -7- 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 234405 Broad Preferred Y02/W2°3 10-200 30-100 oh/yo2 q/yo2 m+/yo2 h2°/y°2 Q/Q+M+ 0.10-1.0 0.05-0.50 0.05-0.30 0.25-0.50 0.25-0.35 0.05-0.10 15-300 0.30-0.90 25-60 0.60-0.80 wherein Q is a diquaternary ammonium ion, or mixture with tetramethylammonium cation, y is silicon, germanium or both, and W is boron. M is an alkali metal, preferably sodium. The organic compound which acts as a source of the quaternary ammonium ion employed can provide hydroxide ion. When using the quaternary ammonium hydroxide compound as a template, it has also been found that purer forms of (B)Beta are prepared when there is an excess of compound present relative to the amount of alkali metal hydroxide. The bis(l-Azonia bicyclo[2.2.2]octane) a' w alkane diquaternary ammonium ion component Q, of the crystallization mixture, is derived from the quaternary ammonium compound. Preferably, the diquaternary ammonium ion is derived from a compound of the formula: The quaternary ammonium compounds are prepared by methods known in the art, an example of which can be found in U.S. No. 4,508,837. -8- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 234405 The reaction mixture is prepared using standard zeolitic preparation techniques. Sources of boron for the reaction mixture include borosilicate glasses and most particularly, other reactive borates and borate esters. Typical sources of silicon oxide include silicates, silica hydrogel, silicic acid, colloidal silica, tetra-alkyl orthosilicates, and silica hydroxides. The reaction mixture is maintained at an elevated temperature until the crystals of the zeolite are formed. The temperatures during the hydrothermal crystallization step are typically maintained from about 140°C to about 200°C, preferably from about 150°C to about 170°C and most preferably from about 135°C to about 165°C. The crystallization period is typically greater than one day and preferably from about three days to about seven days. The hydrothermal crystallization is conducted under pressure and usually in an autoclave so that the reaction mixture is subject to autogenous pressure. The reaction mixture can be stirred during crystallization. Once the zeolite crystals have formed, the solid product is separated from the reaction mixture by standard mechanical separation techniques such as filtration. The crystals are water-washed and then dried, e.g., at 90°C to 150°C from 8 to 24 hours, to obtain the as synthesized, (B)Beta zeolite crystals. The drying step can be performed at atmospheric or subatmospheric pressures. During the hydrothermal crystallization step, the (B)Beta crystals can be allowed to nucleate spontaneously from the reaction mixture. The reaction mixture can also be seeded with (B)Beta crystals both to direct, and accelerate the -9- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 2 3 4 40 crystallization, as well as to minimize the formation of undesired aluminosilicate contaminants. The synthetic (B)Beta zeolites can be used as synthesized or can be thermally treated (calcined). Usually, it is desirable to remove the alkali metal cation by ion exchange and replace it with hydrogen, ammonium, or any desired metal ion. The zeolite can be leached with chelating agents, e.g., EDTA or dilute acid solutions, to increase the silica:boria mole ratio. The zeolite can be used in intimate combination with hydrogenating components, such as tungsten, vanadium, molybdenum, rhenium, nickel, cobalt, chromium, manganese, or a noble metal, such as palladium or platinum, for those applications in which a hydrogenation-dehydrogenation function is desired. Typical replacing cations can include metal cations, e.g., rare earth, Group IIA and Group VIII metals, as well as their mixtures. Of the replacing metallic cations, cations of metals such as rare earth, Mn, Ca, Mg, Zn, Cd, Pt, Pd, Ni, Co, Ti, Al, Sn, Fe, and Co are particularly preferred. The hydrogen, ammonium, and metal components can be exchanged into the zeolite. The zeolite can also be impregnated with the metals, or, the metals can be physically intimately admixed with the zeolite using standard methods known to the art. And, the metals can be occluded in the crystal lattice by having the desired metals present as ions in the reaction mixture from which the (B)Beta zeolite is prepared. Typical ion exchange techniques involve contacting the synthetic zeolite with a solution containing a salt of the desired replacing cation or cations. Although a wide variety of salts can be employed, chlorides and other -10- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 2 3 4 4 Q 5 halides, nitrates, and sulfates are particularly preferred. Representative ion exchange techniques are disclosed in a wide variety of patents including U.S. Nos. 3,140,249; 3,140,251; and 3,140,253. Following contact with the salt solution of the desired replacing cation, the zeolite is typically washed with water and dried at temperatures ranging from 650°c to about 315°c. After washing, the zeolite can be calcined in air or inert gas at temperatures ranging from about 200°c to 820°c for periods of time ranging from 1 to 48 hours, or more, to produce a catalytically active product especially useful in hydrocarbon conversion processes. Regardless of the cations present in the synthesized form of the zeolite, the spatial arrangement of the atoms which form the basic crystal lattice of the zeolite remains essentially unchanged. The exchange of cations has little, if any, effect on the zeolite lattice structures. The Beta borosilicate and subsequent metalloborosilicate can be formed into a wide variety of physical shapes. Generally speaking, the zeolite can be in the form of a powder, a granule, or a molded product, such as extrudate having particle size sufficient to pass through a 2-mesh (Tyler) screen and be retained on a 400-mesh (Tyler) screen. In cases where the catalyst is molded, such as by extrusion with an organic binder, the borosilicate can be extruded before drying, or, dried or partially dried and then extruded. The zeolite can be composited with other materials resistant to the temperatures and other conditions employed in organic conversion processes. Such matrix materials include active and inactive materials and synthetic or naturally occurring zeolites as well as -11- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 234405 inorganic materials such as clays, silica and metal oxides. The latter may occur naturally or may be in the form of gelatinous precipitates, sols, or gels, including mixtures of silica and metal oxides. Use of an active material in conjunction with the synthetic zeolite, i.e., combined with it, tends to improve the conversion and selectivity of the catalyst in certain organic conversion processes. Inactive materials can suitably serve as diluents to control the amount of conversion in a given process so that products can be obtained economically without using other means for controlling the rate of reaction. Frequently, zeolite materials have been incorporated into naturally occurring clays, e.g., bentonite and kaolin. These materials, i.e., clays, oxides, etc., function, in part, as binders for the catalyst. It is desirable to provide a catalyst having good crush strength, because in petroleum refining the catalyst is often subjected to rough handling. This tends to break the catalyst down into powders which cause problems in processing. Naturally occurring clays which can be composited with the synthetic zeolites of this invention include the montmorillonite and kaolin families, which families include the sub-bentonites and the kaolins commonly known as Dixie, McNamee, Georgia, and Florida clays or others in which the main mineral constituent is halloysite, kaolinite, dickite, nacrite, or anauxite. Fibrous clays such as sepiolite and attapulgite can also be used as supports. Such clays can be used in the raw state as originally mined or can be initially subjected to calcination, acid treatment or chemical modification. -12- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 234405 In addition to the foregoing materials, the (B)Beta zeolites can be composited with porous matrix materials and mixtures of matrix materials such as silica, alumina, titania, magnesia, silica:alumina, silica-magnesia, silica-zirconia, silica-thoria, silica-beryllia, silica-titania, titania-zirconia as well as ternary compositions such as silica-alumina-thoria, silica-alumina-zirconia, silica-alumina-magnesia, and silica-magnesia-zirconia. The matrix can be in the form of a cogel. The (B)Beta zeolites can also be composited with other zeolites such as synthetic and natural faujasites (e.g., X and Y), erionites, and mordenites. They can also be composited with purely synthetic zeolites such as those of the ZSM series. The combination of zeolites can also be composited in a porous inorganic matrix. (B)Beta zeolites are useful in hydrocarbon conversion reactions. Hydrocarbon conversion reactions are chemical and catalytic processes in which carbon-containing compounds are changed to different carbon-containing compounds. Examples of hydrocarbon conversion reactions include catalytic cracking, hydrocracking, and olefin and aromatics formation reactions. The catalysts are useful in other petroleum refining and hydrocarbon conversion reactions such as isomerizing n-paraffins and naphthenes, polymerizing and oligomerizing olefinic or acetylenic compounds such as isobutylene and butene-1, reforming, alkylating, isomerizing polyalkyl substituted aromatics (e.g., ortho xylene), and disproportionating aromatics (e.g., toluene) to provide mixtures of benzene, xylenes, and higher methylbenzenes. The (B)Beta catalysts have high selectivity, and under hydrocarbon conversion conditions can provide a high percentage of desired products relative to total products. -13- 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 234405 (B)Beta zeolites can be used in processing hydrocarbonaceous feedstocks. Hydrocarbonaceous feedstocks contain carbon compounds and can be from many different sources, such as virgin petroleum fractions, recycle petroleum fractions, shale oil, liquefied coal, tar sand oil, and in general, can be any carbon containing fluid susceptible to zeolitic catalytic reactions. Depending on the type of processing, the hydrocarbonaceous feed is to undergo, the feed can contain metal or be free of metals, it can also have high or low nitrogen or sulfur impurities. It can be appreciated, however, that in general processing will be more efficient (and the catalyst more active) the lower the metal, nitrogen, and sulfur content of the feedstock. Using a (B)Beta zeolite catalyst which contains boron and/or aluminum framework substitution and a hydrogenation promoter, heavy petroleum residual feedstocks, cyclic stocks, and other hydrocrackate charge stocks can be hydrocracked at hydrocracking conditions including a temperature in the range of from 175°C to 485°C, molar ratios of hydrogen to hydrocarbon charge from 1 to 100, a pressure in the range of from 0.5 to 350 bar, and a liquid hourly space velocity (LHSV) in the range of from 0.1 to 30. The hydrocracking catalysts contain an effective amount of at least one hydrogenation catalyst (component) of the type commonly employed in hydrocracking catalysts. The hydrogenation component is generally selected from the group of hydrogenation catalysts consisting of one or more metals of Group VIB and Group VIII, including the salts, complexes, and solutions containing such. The hydrogenation catalyst is preferably selected from the group of metals, salts, and complexes thereof of the group consisting of at least one of platinum, palladium, rhodium, iridium, and mixtures thereof -14- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 2 3 4 4 or the group consisting of at least one of nickel, molybdenum, cobalt, tungsten, titanium, chromium, and mixtures thereof. Reference to the catalytically active metal or metals is intended to encompass such metal or metals in the elemental state or in some form such as an oxide, sulfide, halide, carboxylate, and the like. The hydrogenation catalyst is present in an effective amount to provide the hydrogenation function of the hydrocracking catalyst and preferably in the range of from 0.05% to 25% by weight. The catalyst may be employed in conjunction with traditional hydrocracking catalysts, e.g., any aluminosilicate heretofore employed as a component in hydrocracking catalysts. Representative of the zeolitic aluminosilicates disclosed heretofore as employable as component parts of hydrocracking catalysts are Zeolite Y (including steam stabilized, e.g., ultra-stable Y), Zeolite X, Zeolite beta (U.S. Patent No. 3,308,069), Zeolite ZK-20 (U.S. Patent No. 3,445,727), Zeolite ZSM-3 (U.S. Patent No. 3,415,736), faujasite, LZ-10 (U.K. Patent 2,014,970, June 9, 1982), ZSM-5-type zeolites, e.g., ZSM-5, ZSM-11, ZSM-12, ZSM-23, ZSM-35, ZSM-38, ZSM-48, crystalline silicates such as silicalite (U.S. Patent No. 4,061,724), erionite, mordenite, offretite, chabazite, FU-l-type zeolite, NU-type zeolites, LZ-210-type zeolite, and mixtures thereof. Traditional hydrocracking catalysts containing amounts of Na20 less than about one percent by weight are generally preferred. The relative amounts of the (B)Beta component and traditional hydrocracking component, if any, will depend at least in part, on the selected hydrocarbon feedstock and on the desired product distribution to be obtained therefrom, but in all instances an effective amount of (B)Beta is employed. -15- 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 234405 The hydrocracking catalysts are typically employed with an inorganic oxide matrix component which may be any of the inorganic oxide matrix components which have been employed heretofore in the formulation of hydrocracking catalysts including: amorphous catalytic inorganic oxides, e.g., catalytically active silica-aluminas, clays, silicas, aluminas, silica-aluminas, silica-zirconias, silica-magnesias, alumina-borias, alumina-titanias, and the like and mixtures thereof. The traditional hydrocracking catalyst component (TC) and (B)Beta may be mixed separately with the matrix component and then mixed or the TC component and (B)Beta may be mixed and then formed with the matrix component. (B)Beta can be used to dewax hydrocarbonaceous feeds by selectively removing or transforming straight chain paraffins. The catalytic dewaxing conditions are dependent in large measure on the feed used and upon the desired pour point. Generally, the temperature will be between about 200°C and about 475°C, preferably between about 250°C and about 450°C. The pressure is typically between about 15 psig and about 3000 psig, preferably between about 200 psig and 3000 psig. The LHSV preferably will be from 0.1 to 20, preferably between about 0.2 and about 10. Hydrogen is preferably present in the reaction zone during the catalytic dewaxing process. The hydrogen to feed ratio is typically between about 500 and about 30,000 SCF/bbl (standard cubic feet per barrel), preferably about 1,000 to about 20,000 SCF/bbl. Generally, hydrogen will be separated from the product and recycled to the reaction zone. Typical feedstocks include light gas-oil, heavy gas-oils, and reduced crudes boiling about 350°F. -16- 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 23 4 4 The (B)Beta hydrodewaxing catalyst may optionally contain a hydrogenation component of the type commonly employed in dewaxing catalysts. The hydrogenation component may be selected from the group of hydrogenation catalysts consisting of one or more metals of Group VIB and Group VIII, including the salts, complexes and solutions containing such metals. The preferred hydrogenation catalyst is at least one of the group of metals, salts, and complexes selected from the group consisting of at least one of platinum, palladium, rhodium, iridium, and mixtures thereof or at least one from the group consisting of nickel, molybdenum, cobalt, tungsten, titanium, chromium, and mixtures thereof. Reference to the catalytically active metal or metals is intended to encompass such metal or metals in the elemental state or in some form such as an oxide, sulfide, halide, carboxylate, and the like. The hydrogenation component is present in an effective amount to provide an effective hydrodewaxing catalyst preferably in the range of from about 0.05 to 5% by weight. (B)Beta can be used to convert straight run naphthas and similar mixtures to highly aromatic mixtures. Thus, normal and slightly branched chained hydrocarbons, preferably having a boiling range above about 40°C and less than about 200°C, can be converted to products having a substantial aromatics content by contacting the hydrocarbon feed with the zeolite at a temperature in the range of from about 400°C to 600°C, preferably 480°C-550°C at pressures ranging from atmospheric to 10 bar, and LHSV ranging from 0.1 to 15. The hydrogen to hydrocarbon ratio will range between 1 and 10. (B)Beta can be used in a fixed, fluid or moving bed reforme r. -17- 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 2 3 4 4 The conversion catalyst preferably contain a Group VIII metal compound to have sufficient activity for commercial use. By Group VIII metal compound as used herein is meant the metal itself or a compound thereof. The Group VIII noble metals and their compounds, platinum, palladium, and iridium, or combinations thereof can be used. The most preferred metal is platinum. The amount of Group VIII metal present in the conversion catalyst should be within the normal range of use in reforming catalysts, from about 0.05 to 2.0 wt. %, preferably 0.2 to 0.8 wt. %. The performance of the noble metal in (B)Beta may be further enhanced by the presence of other metals as promotors for aromatization selectivity. The zeolite/Group VIII metal conversion catalyst can be used without a binder or matrix. The preferred inorganic matrix, where one is used, is a silica-based binder such as Cab-O-Sil or Ludox. Other matrices such as magnesia and titania can be used. The preferred inorganic matrix is nonacidic. It is critical to the selective production of aromatics in useful quantities that the conversion catalyst be substantially free of acidity, for example, by poisoning the zeolite with a basic metal, e.g., alkali metal, compound. The zeolite is usually prepared from mixtures containing alkali metal hydroxides and thus, have alkali metal contents of about 1-2 wt. %. These high levels of alkali metal, usually sodium or potassium, are unacceptable for most catalytic applications because they greatly deactivate the catalyst for cracking reactions. Usually, the alkali metal is removed to low levels by ion exchange with hydrogen or ammonium ions. By alkali metal compound as used herein is meant elemental or ionic alkali metals or their basic -18- 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 234405 compounds. Surprisingly, unless the zeolite itself is substantially free of acidity, the basic compound is required in the present process to direct the synthetic reactions to aromatics production. In the case of (B)Beta the intrinsic cracking acidity is quite low and neutralisation is not usually required. We have also found that (B)Beta is advantageously used to catalytically crack hydrocarbon feedstocks in the absence of hydrogen. Preferred conditions involve a fluidized catalytic cracking process which consists of contacting a hydrocarbon feedstock with a catalyst in a reaction zone in the absence of added hydrogen at average catalyst temperatures ranging from 800°f to 1500°f, separating the catalyst from the product effluent, introducing the catalyst into a steam-stripping zone, and subsequently into a regeneration zone in the presence of steam and free oxygen containing gas where reaction coke deposited on the catalyst is burned off at elevated temperatures ranging from 1000°f to 1550°f, and then recycling the reactivated catalyst to the reaction zone. For this purpose, the (B)Beta can be employed in conjunction with traditional cracking catalysts either as an incorporated constituent component or as a separate additive particle. The catalyst may be employed in conjunction with traditional cracking catalysts, comprising any aluminosilicate heretofore employed as a component in cracking catalysts. Representative of the zeolitic aluminosilicates disclosed heretofore as employable as component parts of cracking catalysts are Zeolite Y (including steam stabilized Y, rare earth Y, chemically modified Y, ultra-stable Y or -19- ■ |V A t i i w ? 3 4 405 01 combinations thereof), Zeolite X, Zeolite beta (U.S. Patent *2 No. 3,308, 069), Zeolite ZK-20 (U.S. Patent No. 3, 445,727 ), 03 Zeolite ZSM-3 (U.S. Patent No. 3,415,736), faujasite, LZ-10 04 (U.K. Patent 2,014,970, June 9, 1982), zSM-5-Type Zeolites, 05 e.g., ZSM-5, ZSM-11, ZSM-12, ZSM-23, ZSM-35, ZSM-38, ZSM-48, 06 crystalline silicates such as silicalite (U.S. Patent No. 07 4,061,724), erionite, mordenite, offretite, chabazite, 08 FU-l-type zeolite, NU-type zeolite, LZY-210 type zeolite or I 09 other dealuminated zeolite of 24.5A unit cell size or lower, | 10 or zeolite grown "in-situ" in matrix materials (U.S. Patent | Nos. 3,647,718 and 4,493,902), and the mixtures thereof. ! 12 The term "zeolite" as used herein contemplates not only i:j aluminosilicates but substances in which the aluminum is I ! 14 replaced by gallium or boron and substances in which silicon j 15 is replaced by germanium. Other representative acidic * j 15 aluminosilicates also deemmed employable as component parts I 17 are amorphous silica-alumina catalysts, synthetic I 18 mica-montmorillonite catalysts (as defined in U.S. Patent i jj 19 No. 3,252,889), cross-linked or pillared clays (as defined I 20 in u-s- Patent Nos. 4,176,090; 4,248,739; 4,238,364 and }: 21 4,216,188), and acid activated clays — bentonite, | 22 hectorite, saponite. The traditional cracking catalyst is preferably 1 . a large pore size crystalline aluminosilicate, which preferably has a I pore size greater than 8.0 Angstroms | J 24 Traditional cracking catalysts containing amounts of Na20 t \ 25 less than about one percent by weight are generally 26 preferred. The relative amounts of the (B)Beta component 27 and traditional cracking component (TC), if any, will depend 2Q at least in part, on the selected hydrocarbon feedstock and 29 on the desired product distribution to be obtained 30 therefrom, but in all instances, an effective amount of 31 (B)Beta is employed. When a TC component is employed, the 32 relative weight ratio of the TC to the (B)Beta is generally 33 between about 1:10 and about 500:1, desirably between about 34 j -20- // fy •j 335 y <*3 APR 19^2 *'1 £ (V 234405 01 1:10 and about 200:1, preferably between about 1:2 and about 02 50:1, and most preferably is between about 1:1 and about " ' 03 20:1. 04 05 The cracking catalysts are typically employed with an 06 inorganic oxide matrix component which may be any of the 07 inorganic oxide matrix components which have been employed ■ 08 heretofore in the formulation of FCC catalysts including: 09 amorphous catalytic inorganic oxides, e.g., catalytically 10 active silica-aluminas, clays, synthetic or acid activated 11 clays, silicas, aluminas, silica-aluminas, silica-zirconias, 12 silica-magnesias, alumina-borias, alumina-titanias, pillared 13 or cross-linked clays, and the like and mixtures thereof. 14 The TC component and (B)Beta may be mixed separately with 15 their respective matrix component and then mixed together or 16 the TC component and (B)Beta may be mixed together and then 17 formed with the matrix component. 18 19 The mixture of a traditional cracking catalyst and (B)Beta 20 may be carried out in any manner which results in the 21 coincident presence of such in contact with the crude oil 0 22 feedstock under catalytic cracking conditions. For example, 23 a catalyst may be employed containing the traditional 24 cracking catalyst component and (B)Beta in single catalyst 25 particles or (B)Beta with or without a matrix component may 26 be added as a discrete component to a traditional cracking 27 catalyst provided its particle has appropriate density and 28 particle size distribution. 29 30 (B)Beta can also be used to oligomerize straight and 31 branched chain olefins having from about 2-21 and preferably 32 2-5 carbon atoms. The oligomers which are the products of 33 34 -21- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 23 4 4 05 the process are medium to heavy olefins which are useful for both fuels, i.e., gasoline or a gasoline blending stock and chemicals. The oligomerization process comprises contacting the olefin feedstock in the gaseous state phase with (B)Beta at a temperature of from about 450°F to about 1200°F, a WHSV of from about 0.2 to about 50 and a hydrocarbon partial pressure of from about 0.1 to about 50 atmospheres. Also, temperatures below about 450°F may be used to oligomerize the feedstock, when the feedstock is in the liquid phase when contacting the zeolite catalyst. Thus, when the olefin feedstock contacts the zeolite catalyst in the liquid phase, temperatures of from about 50°F to about 450°F, and preferably from 80-400°F may be used and a WHSV of from about 0.05 to 20 and preferably 0.1 to 10. It will be appreciated that the pressures employed must be sufficient to maintain the system in the liquid phase. As is known in the art, the pressure will be a function of the number of carbon atoms of the feed olefin and the temperature. Suitable pressures include from about 0 psig to about 3000 psig. The zeolite can have the original cations associated therewith replaced by a wide variety of other cations according to techniques well known in the art. Typical cations would include hydrogen, ammonium, and metal cations including mixtures of the same. Of the replacing metallic cations, particular preference is given to cations of metals such as rare earth metals, manganese, calcium, as well as metals of Group II of the Periodic Table, e.g., zinc, and Group VIII of the Periodic Table, e.g., nickel. One of the prime requisites is that the zeolite have a fairly low -22- 2 3 4 4 0 5 r 01 aromatization activity, i.e., in which the amount of m* 02 aromatics produced is not more than about 20 wt. %. This is f' ** 03 accomplished by using a zeolite with controlled acid 04 activity [alpha value] of from about 0.1 to about 120, 05 preferably from about 0.1 to about 100, as measured by its 06 ability to crack n-hexane. 07 08 Alpha values are defined by a standard test known in the 09 art, e.g., as shown in U.S. Patent No. 3,960,978 which is 10 incorporated totally herein by reference. If required, such 11 zeolites may be obtained by steaming, by use in a conversion 12 process or by any other method which may occur to one 13 skilled in this art. 14 15 (B)Beta can be used to convert light gas C2-Cg paraffins 16 and/or olefins to higher molecular weight hydrocarbons 17 including aromatic compounds. Operating temperatures of 18 100-700°C, operating pressures of 0-1000 psig and space — 1 19 velocities of 0.5-40 hr WHSV can be used to convert the 20 C2-C6 Paraffin and/or olefins to aromatic compounds. 21 Preferably, the zeolite will contain a catalyst metal or ; 22 metal oxide wherein said metal is selected from the group 23 consisting of Group IB, IIB, VIII, and IIIA of the Periodic 24 Table, and most preferably, gallium or zinc and in the range 25 of from about 0.05-5 wt. %. 26 27 (B)Beta can be used to condense lower aliphatic alcohols 28 having 1-10 carbon atoms to a gasoline boiling point 29 hydrocarbon product comprising mixed aliphatic and aromatic 30 hydrocarbon. The condensation reaction proceeds at a 31 temperature of about 500-1000°F, a pressure of about 32 0.5-1000 psig and a space velocity of about 0.5-50 WHSV. 33 The process disclosed in U.S. Patent No. 3,984,107 more 34 -23- 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 2 3 4 4 0 5 specifically describes the process conditions used in this process, which patent is incorporated totally herein by reference. The catalyst may be in the hydrogen form or may be base exchanged or impregnated to contain amonium or a metal cation complement, preferably in the range of from about 0.05-5 wt. %. The metal cations that may be present include any of the metals of the Groups I-VIII of the Periodic Table. However, in the case of Group IA metals, the cation content should in no case be so large as to effectively inactivate the catalyst. The catalyst can be made highly active and highly selective for isomerizing to hydrocarbons. The activity means that the catalyst can operate at relatively low temperatures which thermodynamically favors highly branched paraffins. Consequently, the catalyst can produce a high octane product. The high selectivity means that a relatively high liquid yield can be achieved when the catalyst is run at a high octane. The present process comprises contacting the isomerization catalyst with a hydrocarbon feed under isomerization conditions. The feed is preferably a light straight run fraction, boiling within the range of 30-250°F and preferably from 60-200°F. Preferably, the hydrocarbon feed for the process comprises a substantial amount of C^ to C-j normal and slightly branched low octane hydrocarbons, more preferably Cg and Cg hydrocarbons. The pressure in the process is preferably between 50-1000 psig, more preferably between 100-500 psig. The LHSV is preferably between about 1 to about 10 with a value in the -24- 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 234405 range of about 1 to about 4 being more preferred. It is also preferable to carry out the isomerization reaction in the presence of hydrogen. Preferably, hydrogen is added to give a hydrogen to hydrocarbon ratio (I^/HC) of between 0.5 and 10 H2/HC, more preferably between 1 and 8 I^/HC. The temperature is preferably between about 200°F and about 1000°F, more preferably between 400-600°F. As is well known to those skilled in the isomerization art, the initial selection of the temperature within this broad range is made primarily as a function of the desired conversion level considering the characteristics of the feed and of the catalyst. Thereafter, to provide a relatively constant value for conversion, the temperature may have to be slowly increased during the run to compensate for any deactivation that occurs. A low sulfur feed is especially preferred in the present process. The feed preferably contains less than 10 ppm, more preferably less than 1 ppm, and most preferably less than 0.1 ppm sulfur. In the case of a feed which is not already low in sulfur, acceptable levels can be reached by hydrogenating the feed in a presaturation zone with a hydrogenating catalyst which is resistant to sulfur poisoning. An example of a suitable catalyst for this hydrodesulfurization process is an alumina-containing support and a minor catalytic proportion of molybdenum oxide, cobalt oxide and/or nickel oxide. A platinum on alumina hydrogenating catalyst can also work. In which case, a sulfur sorber is preferably placed downstream of the hydrogenating catalyst, but upstream of the present isomerization catalyst. Examples of sulfur sorbers are alkali or alkaline earth metals on porous refractory -25- 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 234405 inorganic oxides, zinc, etc. Hydrodesulfurization is typically conducted at 315-455°c, at 200-2000 psig, and at a LHSV of 1-5. It is preferable to limit the nitrogen level and the water content of the feed. Catalysts and processes which are suitable for these purposes are known to those skilled in the art. After a period of operation, the catalyst can become deactivated by coke. Coke can be removed by contacting the catalyst with an oxygen-containing gas at an elevated temperature. The isomerization catalyst preferably contains a Group VIII metal compound to have sufficient activity for commercial use. By Group VIII metal compound as used herein is meant the metal itself or a compound thereof. The Group VIII noble metals and their compounds, platinum, palladium, and iridium, or combinations thereof can be used. Rhenium and tin may also be usd in conjunction with the noble metal. The most preferred metal is the amount of Group VIII metal present in the conversion catalyst should be within the normal range of use in isomerizing catalysts, from about 0.05-2.0 wt. %. (B)Beta can be converted to a catalyst for use in a process for the alkylation or transalkylation of an aromatic hydrocarbon. The process comprises contacting the aromatic hydrocarbon with a C2 to C2Q olefin alkylating agent or a polyalkyl aromatic hydrocarbon transalkylating agent, under at least partial liquid phase conditions, and in the presence of a catalyst comprising (B)Beta. -26- 234405 01 For high catalytic activity, the (B)Beta zeolite should be 02 predominantly in its hydrogen ion form. Generally, the 03 zeolite is converted to its hydrogen form by ammonium 04 exchange followed by calcination. If the zeolite is 05 synthesized with a high enough ratio of organonitrogen 06 cation to sodium ion, calcination alone may be sufficient. 07 It is preferred that, after calcination, at least 80% of the 08 cation sites are occupied by hydrogen ions and/or rare earth 09 ions. 10 11 The pure (B)Beta zeolite may be used as a catalyst, but 12 generally, it is preferred to mix the zeolite powder with an 13 inorganic oxide binder such as alumina, silica, 14 silica/alumina, or naturally occurring clays and form the 15 mixture into tablets or extrudates. The final catalyst may 16 contain from 1-99 wt. % (B)Beta zeolite. Usually the 17 zeolite content will range form 10-90 wt. %, and more 18 typically from 60-80 wt. %. The preferred inorganic binder 19 is alumina. The mixture may be formed into tablets or 20 extrudates having the desired shape by methods well known in 21 the art. 22 23 Examples of suitable aromatic hydrocarbon feedstocks which 24 may be alkylated or transalkylated by the process of the 25 invention include aromatic compounds such as benzene, 26 toluene, and xylene. The preferred aromatic hydrocarbon is 27 benzene. Mixtures of aromatic hydrocarbons may also be 28 employed. 29 30 Suitable olefins for the alkylation of the aromatic 31 hydrocarbon are those containing 2-20 carbon atoms, such as 32 ethylene, propylene, butene-1, transbutene-2, and 33 cis-butene-2, and higher olefins or mixtures thereof. The 34 preferred olefin is propylene. These olefins may be present -27- 234405 01 in admixture with the corresponding C2 to C2g paraffins, but 02 it is preferable to remove any dienes, acetylenes, sulfur 03 compounds or nitrogen compounds which may be present in the 04 olefin feedstock stream to prevent rapid catalyst 05 deactivation. 06 07 When transalkylation is desired, the transalkylating agent 08 is a polyalkyl aromatic hydrocarbon containing two or more 09 alkyl groups that each may have from two to about four 10 carbon atoms. For example, suitable polyalkyl aromatic 11 hydrocarbons include di-, tri-, and tetra-alkyl aromatic 12 hydrocarbons, such as diethylbenzene, triethylbenzene, 13 diethylmethylbenzene (diethyltoluene), di-isopropylbenzene, 14 di-isopropyltoluene, dibutylbenzene, and the like. 15 Preferred polyalkyl aromatic hydrocarbons are the dialkyl 16 benzenes. A particularly preferred polyalkyl aromatic 17 hydrocarbon is di-isopropylbenzene. 18 19 Reaction products which may be obtained include ethylbenzene 20 from the reaction of benzene with either ethylene or 21 polyethylbenzenes, cumene from the reaction of benzene with 22 propylene or polyisopropylbenzenes, ethyltoluene from the 23 reaction of toluene with ethylene or polyethyltoluenes, 24 cymenes from the reaction of toluene with propylene or 25 polyisopropyltoluenes, and secbutylbenzene from the reaction 26 of benzene and n-butenes or polybutylbenzenes. The j 21 production of cumene from the alkylation of benzene with 28 propylene or the transalkylation of benzene with 29 di-isopropylbenzene is especially preferred. 30 31 When alkylation is the process conducted, reaction 32 conditions are as follows. The aromatic hydrocarbon feed 33 should be present in stoichiometric excess. It is preferred 34 that molar ratio of aromatics to olefins be greater than -28- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 23 4 4 05 four-to-one to prevent rapid catalyst fouling. The reaction temperature may range from 100-600°F, preferably, 250-450°F. The reaction pressure should be sufficient to maintain at least a partial liquid phase in order to retard catalyst fouling. This is typically 50-1000 psig depending on the feedstock and reaction temperature. Contact time may range from 10 seconds to 10 hours, but is usually from five minutes to an hour. The WHSV in terms of grams (pounds) of aromatic hydrocarbon and olefin per gram (pound) of catalyst per hour, is generally within the range of about 0.5 to 50. When transalkylation is the process conducted, the molar ratio of aromatic hydrocarbon will generally range from about 1:1 to 25:1, and preferably from about 2:1 to 20:1. The reaction temperature may range from about 100-600°F, but it is preferably about 250-450°F. The reaction pressure should be sufficient to maintain at least a partial liquid phase, typically in the range of about 50-1000 psig, preferably 300-600 psig. The WHSV will range from about 0.1-10. The conversion of hydrocarbonaceous feeds can take place in any convenient mode, for example, in fluidized bed, moving bed, or fixed bed reactors depending on the types of process desired. The formulation of the catalyst particles will vary depending on the conversion process and method of operation. Other reactions which can be performed using the catalyst of this invention containing a metal, e.g., platinum, include hydrogenation-dehydrogenation reactions, denitrogenation, and desulfurization reactions. -29- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 234405 Some hydrocarbon conversions can be carried out on (B)Beta zeolites utilizing the large pore shape-selective behavior. For example, the substituted (B)Beta zeolite may be used in preparing cumene or other alkylbenzenes in processes utilizing propylene to alkylate aromatics. (B)Beta can be used in hydrocarbon conversion reactions with active or inactive supports, with organic or inorganic binders, and with and without added metals. These reactions are well known to the art, as are the reaction conditions. (B)Beta can also be used as ah adsorbent, as a filler in paper, paint, and toothpastes, and as a water-softening agent in detergents. The following examples illustrate the preparation and use of (B)Beta. EXAMPLES Example 1 Synthesis of an Effective Diquaternary Ammonium Compound Boron Beta Crystallization 48 grams of DABCO (1,4 Diazabicyclo [2.2.2] octane) is stirred into 800 ml of Ethyl Acetate. 42 grams of 1,4 Diiodobutane is added dropwise and slowly while the reaction is stirred. Allowing the reaction to run for a few days at room temperature produces a high yield of the precipitated -30- 2 3 4 4 01 diquaternary compound, pm, 02 03 04 05 /T\. N N-(CH2)^N ,N 21 w w 07 08 09 The product is washed with THF and then ether and then 10 vacuum dried. Melting point = 255°C. ! li 1 12 The crystalline salt is conveniently converted to the | 13 hydroxide form by stirring overnight in water with AGI-X8 j 14 hydroxide ion exchange resin to achieve a solution ranging i 1 15 from 0.25-1.5 molar. S 16 i 17 Example 2 f I 18 I 19 10.85 g of a 0.90M solution of the template from Example 1 1 . 20 i-s diluted with 3.95 ml f^O. 0.23 g of Na^^O^" 18H20 are 21 dissolved in this solution and then 1.97 g of Cabosil M5 are I [ '•sj? 22 blended in last. The reaction mixture is heated in a Parr | 23 4745 reactor at 150°C and rotated at 43 rpm on a spit in a | 24 Blue M oven over a 9-day period. The solid component of the y""i 25 reaction is filtered, washed repeatedly, dried at 115°C and j 26 analyzed by X-ray diffraction. The product is identified as | l'Sw) 27 (B)Beta. | 28 f 29 Example 3 j 30 | ' 31 The same experiment is set up as in Example 2 except the J 32 diquat in Example 2 is replaced by an equivalent amount of I 33 TEAOH. The experiment is run under analogous conditions 34 -31- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 23 4 4 although this time the crystallization is complete in 6 days. The product is ZSM-5 by XRD. This shows that TEAOH doesn't have enough selectivity for Beta in the borosilicate system. TEAOH is the template used in the prior art for synthesis of Beta. 202 g of a 0.84M solution of the template from Example 1 is mixed with 55 g of I^O, and 4.03 g of Na2B^O^'lOl^O. 35 g of Cabosil M5 is blended in last and the reaction is run in a Parr 600-cc stirred autoclave with liner for 6 days at 150°C and stirred at 50 rpm. The product is well-crystallized Boron Beta. The pattern is tabulated in Table 2. Example 4 TABLE 2 2 9 d/n Int. 7.7 18.40 21.44 22.53 25.50 26.08 27.50 28.92 29.90 30.57 31.15 33.62 11.5 4.82 28 B 8 VB 4.14 3.95 3.49 3.42 3.24 3.10 2.97 2.93 2.86 2.67 22 120 7 3 B 11 9 B 10 3 2 VB 6 -32- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 23 4 4 TABLE 2 (Cont.) 2 9 d/n Int. 35.17 36.32 2.55 2.47 2 2 B = Broad VB = Very Broad Examples 5-10 are given in Table 3, demonstrating the utility of the method of the invention. Examples 5-7 show that (B)Beta can be made at very low Si02/B20g values and that higher values eventually lead to some ZSM-12 formation as well. Example 8 shows that the desired product can be obtained using Ludox AS-30 as silica source. Now the aluminum impurity has risen to 530 ppm. Examples 9 and 10 show that providing the diquat as a salt to supplement TEAOH can insure formation of pure Boron Beta. Example 9 shows that is the case even without seeding. Table 4 shows the XRD data for the product of Example 5 and Table 5 is of Example 6, both in the as-synthesized form. -33- c \ . \ O ■-J I U) £» I 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 TABLE 3 Example Template No. (Exam. 1) ;(a) :(a) ,(b) ,(a) 10 (a) (b) (b) 5.60 g (0.70 m) 5.60 g 7(a) 5.60 g 107 g (0.467 m) 1.6 g Salt(c) TEAOH H20 Na2B4°7"10H20 S:0, 0.30 g 0.16 0.30 g 0.10 0.30 g 0.035 1.15 g 402 = 3.16 g 9.38 g 150°C, 11 days, 0 rpm. 150°C, 6 days, 50 rprn. 0.20 28.5 g(c) 40% = 364 g 616 g 22.6 g Cabosil 0.79 g Cabosil 0.79 g Cabosil 0.79 g Seeded SiO^I^O^ Product Cabosil 1.75 g Yes Yes Yes Ludox AS-30 = Yes 33.3 g No Ludox AS-30 = No 660 g /c\ _ v 'Diquat provided as salt first prepared in Example 1 and not OH exchanged. 15 25 75 30 30 30 Beta Beta Beta + ZSM-12 Beta Beta Beta r>o CM O Of 23 4 4 01 TABLE 4 02 ' ' 03 2 8 d/n Int. . 04 ; 05 7-7 11.5 28 B ! 06 18.55 4.78 8 VB 07 21.55 4.12 22 | ..... 08 22.60 3.93 110 ! 09 25.60 3.48 4 j 10 26.00 3.43 3 B " J 11 27.58 3.24 8 ] 12 29.00 3.08 6 B ■j 13 29.98 2.98 6 'I 14 30.65 2.92 2 ■| 15 31.15 2.87 1 VB | 16 33.67 2.66 4 B j 17 35.27 2.55 2 5 18 36.50 2.47 2 B 19 20 B Broad ^21 VB = Very Broad 22 23 24 J, 25 26 O • 27 28 29 30 31 32 33 I 34 -35- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 234405 TABLE 5 2 9 d/n Int. 7.7 11.5 27 B 18.45 4.82 5 VB 21.47 4.14 18 22.56 3.94 128 25.53 3.49 6 26.00 3.43 3 B 27.52 3.24 9 28.97 3.09 7 B 29.92 2.99 8 30.60 2.92 2 31.20 2.83 2 VB 33.66 2.66 5 35.17 2.55 2 36.35 2.47 2 B B = Broad VB = Very Broad XRD patterns for the calcined products of Examples 5 and 6 appear in Tables 6 and 7, respectively. The presence of the boron in the framework of beta zeolite can be indicated by changes in d-spacings. Table 8 compares the d-spacings before and after calcination for some of the sharper peaks of the products of Examples 4, 5 and 6. Also shown are the values for an aluminum beta zeolite prepared by the prior art reference (Re 28,341). It can be seen that the Boron Betas show d-spacings consistently smaller than the aluminum Beta. -36- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 2 e 7.7 13. 58 14.88 18.60 21.85 22.89 25.80 27.38 29.35 30.10 31.15 34.00 36.90 TABLE 6 d/n 11.5 6.53 5.97 4.77 4.06 3.88 3.45 3.26 3.05 2.97 2.87 2.64 2.44 Int. 34 B 3 5 B 2 VB 10 B 42 5 B 5 2 B 3 1 VB 1 VB 1 VB B = Broad VB = Very Broad TABLE 7 2 6 d/n Int. 7.7 11.5 38 B 13.52 6.55 4 14.85 5.95 5 B 18.50 4.82 2 VB 21.80 4.08 5 B 22.82 3.90 50 25.75 3.46 6 B 27.35 3.26 5 234405 -37- / { 18 f ,/ i, 23 4 4 0 01 TABLE 7 (Cont.) s 02 f 03 2 6 d/n Int. 04 05 29.27 3.05 2 B 06 30.00 2.98 4 07 31.00 2.88 2 VB 08 33.90 2.64 2 VB 09 36.80 2.44 1 VB 10 11 B = Broad 12 VB = Very Broad 13 \ i i j 1 14 TABLE 8 ! , t 15 16 Uncalcined Calcined 17 d/n d/n d/n d/n d/n d/n 19 Al-B 3.97 3.30 3.03 3.97 3.30 3.03 20 21 Ex 4 0.07 B-B 3.95 3.24 2.99 3.89 3.26 2.97 22 Ex 6 0.10 B-B 3.94 3.24 2.99 3.90 3.26 2.98 23 Ex 5 0.13 B-B 3.93 3.24 2.98 3.88 3.26 2.97 24 25 Note: d/n spacings for B-Betas are consistently less than 26 those for Al-Betas. 27 28 Example 11 29 30 The product of Example 4 was calcined as follows. The 31 sample was heated in a muffle furnace in nitrogen from room 32 temperature up to 540°C at a steadily increasing rate over a 33 7-hour period. The sample was maintained at 540°C for four 34 more hours and then taken up to 600°C for an additional four -38- f) 234405 01 hours. Nitrogen was passed over the zeolite at a rate of 20 02 standard cfra during heating. The calcined product had the 8 03 X-ray diffraction lines indicated in Table 9 below. 04 05 TABLE 9 06 ^ 07 2 9 d/n Int. J 08 09 7.7 11.5 58 B 10 13.58 6.52 6 11 14.87 5.96 8B 12 18.50 4.80 2 VB 13 21.83 4.07 10 B 14 22.87 3.89 70 15 25.75 3.46 7 16 27.38 3.26 7 17 29.30 3.05 4B 18 30.08 2.97 5 31.00 2.88 3 B 33.95 2.64 2 VB 19 20 21 22 B Broad 23 VB = Very Broad 24 25 Example 12 26 27 Ion exchange of the calcined material from Example 4 was 28 carried out using NH^NOg to convert the zeolites from Na 29 form to NH^. Typically the same mass of NH^NOj as zeolite 30 was slurried into H^O at ratio of 50:1 l^O zeolite. The 31 exchange solution was heated at 100°C for two hours and then 32 filtered. This process was repeated two times. Finally, 33 after the last exchange, the zeolite was washed several 34 times with 1^0 and dried. -39- •/ •* i ■I 23 4 4 0 22 01 Example 13 02 03 Constraint Index Determination 04 05 0.50 g of the hydrogen form of the zeolite of Example 4 06 (after treatment according to Examples 11 and 12 was packed 07 into a 3/8-inch stainless steel tube with alundum on both 08 sides of the zeolite bed. A Lindburg furnace was used to 09 heat the reactor tube. Helium was introduced into the 10 reactor tube at 10 cc/minute and atmospheric pressure. The 11 reactor was taken to 250°F for 40 minutes and then raised to 12 800°F. Once temperature equilibration was achieved a 50/50, 13 w/w feed of n-hexane and 3-methylpentane was introduced into 14 the reactor at a rate of 0.62 cc/hour. Feed delivery was 15 made via syringe pump. Direct sampling onto a gas 16 chromatograph was begun after 10 minutes of feed 17 introduction. Constraint Index values were calculated from 18 gas chromatographic data using methods known in the art. 19 20 Example Conversion 21 No. C.I, at 10 Min. Temp., °F 13 — 0 800 23 24 25 Example 14 26 \ 27 The product of Example 4 after treatment as in Examples 11 28 and 12 is refluxed overnight with Al (NO^ ) 3 ' 9^0 with the 29 latter being the same mass as the zeolite and using the same 30 dilution as in the ion exchange of Example 12. The product 31 is filtered, washed, and calcined to 540°C. After 32 pelletizing the zeolite powder and retaining the 20-40 mesh 33 fraction, the catalyst is tested as in Example 13. Data for 34 -40- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 234 the reaction is given in Table 10 along with a variety of catalysts made from analogous treatments with other metal salts. Examples 15-22 Please refer to Table 10 and Table 11. TABLE 10 Constraint Index Determination For Metal-Treated (B)Beta Example Metal Conversion, % Temp., No. Salt C.I. (10 Min.) °F 13 None — 0 800 14 A1(N03)3 1.0 35.0 600 15 Ga(N03)3 0.25 83.0 800 16 Sn(AC)2 0.70 1.0 800 17 MgCL2"6H20 2.0 0.2 800 18 Co(N03)2*6H20 1.0 5.0 800 Table 11 shows the data for the treatment of the product of Examples 4, 11, 12 with various quantities of Zn(Ac)2'2H20. -41- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 234405 TABLE 11 Example (B)Beta Zn(AC)2'2H20 Wt. % zn after exch./calc. No. 19 4.5 g 2.20 g 3.12 20 4.5 g 1.10 g 1.95 21 4.5 g 0.55 g 1.38 22 4.5 g 0.25 g 0.76 Example 20 gave 5% conversion at 800°F for C.I. test and CI = 0.30. Example 23 The borosilicate version of (B)Beta was evaluated as a reforming catalyst. The zeolite powder was impregnated with Pt(NH^)^'2N03 to give 0.8 wt. % Pt. The material was calcined up to 550°F in air and maintained at this temperature for three hours. The powder was pelletized on a Carver press at 1000 psi and broken and meshed to 24-40. The catalyst was evaluated at 900°F in hydrogen under the following conditions: psig = 200 H2/HC = 6.4 WHSV = 6 Temperature = 900°F The feed was an iC? mixture (Philips Petroleum Company). Table 12 gives data at 800 and 900°F and 50 and 200 psig. -42- 234405 * \ * 01 TABLE 12(a^ 02 03 Temperature 800° F 800 °F 900 0 F 04 Pressure(H2) 200 50 200 05 Conversion % CO CO 8 77 .0 100 06 Aromatization Selectivity % 25. 4 54 .5 25 .3 07 Product Toluene wt. % 19. 1 39 .3 16 .9 08 % Toluene in Cg Aromatics CO 9 93 .7 67 .8 09 C^+ yield wt. % 46. 9 77 .4 30 .2 10 C5-C8 RON 00 5 90 .6 104 .3 | 11 | 12 ^The Catalyst is quite stable and the values are averaged f 13 over at least 20 hours of run time. f 1 14 | 15 Example 24 \ 16 | 17 The product of Example 18 now contained a second metal due i I 18 to cobalt incorporation. The catalyst was calcined to | 19 1000°F. Next, a reforming catalyst was prepared as in I 20 Example 23. The catalyst was evaluated under the following | 21 conditions: ! f'l I W 22 | 23 Psig = 100, 200 I 24 H2/HC = 6.4 4 25 WHSV = 12 26 Temperature = 800°F , U « i" 28 T^e feed has an iC7 mixture (Philips Petroleum Company). >! ' !; 29 The data for the run is given in Table 13. After 23 hours i | 30 onstream, the pressure was dropped to 100 psig and this data | 31 also appears in the table. By comparison with Example 23, [ 32 the incorporation of cobalt into the zeolite gives a more I 33 C5+ selective reforming catalyst. The catalyst has good | 34 stability at 800°F. -43- -A I 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 23 4 4 0 5 TABLE 13 Temperature 800°F 800°F Pressure H2 200 100 Conversion % 83.3 86 Aromatization Selectivity % 27 37 Product Toluene, wt. % 18.8 27.3 % Toluene in Cg+ Aromatics 83.3 85.9 Cg+ yield, % 59.8 63.7 C5-Cg RON 85.3 90.3 Example 25 A product was prepared as in Example 12. Next, the catalyst was dried at 600°F, cooled in a closed system, and then vacuum impregnated with an aqueous solution of Pd(NH^)^'2NO^ to give 0.5 wt. % loading of palladium. The catalyst was then calcined slowly, up to 900°F in air and held there for three hours. Table 14 gives run conditions and product data for the hydrocracking of hexadecane. The catalyst is quite stable at the temperatures given. TABLE 14 Temperature, °F WHSV psig Conversion Isom. Select. Crack. Select. C5+/C4 C5+C6//C5+ 625 637 1.55 1.55 1200 1200 85.1 97.8 94.5 69.9 5.6 30.1 10.8 11.5 17.8 17.1 -44- 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 234405 The data shows that the catalyst has good isomerization selectivity and that the liquid yield is high compared with the gas make. The hydrogen form of (B)Beta can be used in typical fluidized catalytic cracking (FCC). (B)Beta, as prepared in Examples 2, 11, 12 and refluxed with Al (NO^ ) 3 ' 91^0 as in Example 14, was formulated into a spray dried FCC catalytic octane additive and tested in a fixed fluidized cyclic reactor. For this example, the FCC catalytic octane additive contained nominally 25% by weight (B)Beta, 32.5% Kaolin and 42.5% silica/alumina matrix. Fixed fluidized cyclic testing was conducted at 7 cat/oil ratio, with a 1100°F initial catalyst temperature. A subsequent gas chromatographic analysis of the liquid product was made to determine calculated octanes. The catalyst inventory during the fixed fluidized cyclic testing of the (B)Beta FCC catalytic octane additive contained 90% steamed rare earth FCC catalyst and 10% of calcined (B)Beta FCC catalytic octane additive. Feed properties of the gas oil used during fixed fluidized cyclic testing are given in Table 15. Example 26 TABLE 15 API Gravity Aniline Point Total Nitrogen 27.43 187.3 1040 ppm Simulated Distillation ST 5 Vol % 10% 30% 160 °C 256°C 287°C 362°C -45- </div>

Claims

<div id="claims" class="application article clearfix printTableText"> 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 23 4 4 TABLE 15 (Cont.) 50% 430°C 70% 499 °C 90% 595°C 95% 630 °C EP 654 °C Table 16 shows calculated research and motor octane numbers from the fixed fluidized cyclic tests. TABLE 16 Reference 25% (B)Beta Plus Catalyst Reference Catalyst cg-250 RON 85.6 87.8 MON 75.9 76.8 cg-340 RON 85.3 87.5 MON 7 5.6 76.9 -46- -J I \s-'l J ^ u 23 4 4 0 01 02 WRAvT4fAT. CLAIM IS. 03 1. A zeolite having a mole ratio of an oxide selected from. 04 silicon oxide, germanium oxide, and mixtures thereof to 05 an oxide selected from boron oxide, or mixtures of 06 boron oxide with aluminum oxide, gallium oxide or iron . 07 oxide, greater than 10:1 and wherein the amount of j 08 aluminum is less than 0.10% by weight and having the ! 09 X-ray diffraction lines of Table 1(b). ; "> 10 i 11 2. A zeolite having a composition, as synthesized and in ) j 12 the anhydrous state, in terms of mole ratios of oxides | 13 as follows: (1.0 to 5)C>20:(0.1 to 2.0 )M20:W203 j 14 (greater than 10) Y02 wherein M is an alkali metal j 15 cation, W is selected from boron, Y is selected from | 16 silicon, germanium, and mixtures thereof, Q is a | 17 diquaternary ammonium ion and having the X-ray ! 18 diffraction lines of Table 1(a). I | 19 | 20 3. A zeolite in accordance with Claim 1 having a mole | 21 ratio of an oxide selected from silicon oxide to boron | 1 22 oxide greater than 100:1. f ! 23 24 4. A zeolite in accordance with Claim 1 wherein a portion 25 of the boron in said zeolite is replaced by a first row | 26 transition metal or a Group IIIA metal. tj ! 27 t I , 28 5. A zeolite in accordance with Claim 4 wherein the 29 replacing metal is aluminum, gallium, iron, silicon, 30 zinc and mixtures thereof. 31 AJE&S 32 A zeolite prepared by thermally treating the zeolite of 33 Claim 3 at a temperature from ■abou-fe 200°C to 820°C. 34 -47- ■ {' ■ I, 23 4 4 A zeolite in accordance with Claim 2 wherein the diquaternary ammonium ion is derived from a compound of the formula: A zeolite in accordance with Claim 1 or 2 which has undergone ion exchange with hydrogen, ammonium, rare earth metal, Group IIA metal, or Group VIII metal ions. A zeolite in accordance with Claim 1 or 2 wherein rare earth metals, Group IIA metals, or Group VIII metals are occluded in the zeolite. A zeolite composition, comprising the zeolite of Claim 1 or 2 and an inorganic matrix. A method for preparing the zeolite of Claim 1, comprising: (a) preparing an aqueous mixture containing sources of a diquaternary ammonium ion, an oxide selected from boron oxide, and an oxide selected from silicon oxide, germanium oxide, and mixtures thereof; (b) maintaining the mixture at a temperature of at least 140°C until the crystals of said zeolite form; and (c) recovering said crystals. A N I* v_y n±(ch2)^ or 2OH -48- 234405 01 12. A method in accordance with Claim 11 wherein the 02 aqueous mixture has a composition in terms of mole 03 ratios of oxides falling in the ranges: YC>2/W203' 04 greater than 10? Q/YC^, 0.05:1 to 0.50:1; wherein Y is 05 selected from silicon, germanium, and mixtures thereof, 06 W is selected from boron, and Q is a bis (1-Azonia 07 bicyclo[2.2.2] octane) a, go alkane compound. ^ 08 09 13. A method in accordance with Claims 11 and 12 wherein 10 the diquaternary ammonium ion is derived from a 11 compound of the formula: 12 13 14 /^t r~\ - N N-(CH2)gN^ N 21 or 20H W ' 4 W 16 17 18 14. A process for converting hydrocarbons comprising 19 contacting a hydrocarbonaceous feed at hydrocarbon 20 converting conditions with the zeolite of Claim 1 or 2. 21 22 15. The process in accordance with Claim 14 which is a 23 hydrocracking process comprising contacting the 24 hydrocarbon feedstock under hydrocracking conditions 25 with the zeolite of Claim 1. 26 27 16. The process in accordance with Claim 14 which is a 28 catalytic reforming process comprising contacting a 29 hydrocarbonaceous feedstream under catalytic reforming 30 conditions with the zeolite of Claim 1. 31 32 17. The process in accordance with Claim 14 which is a 33 process for preparing a product having an increased 34 aromatics content comprising: -49- ,'/v -U °34P^/992 4 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 ? 3 4 4 0 5 (a) contacting a hydrocarbonaceous feed, which comprises normal and slightly branched hydrocarbons having a boiling range above 40°C and less than 200°C under aromatic conversion conditions with the zeolite of Claim 1, wherein said zeolite is substantially free of acidity; and (b) recovering an aromatic-containing effluent. 18. The process in accordance with Claim 17 wherein the zeolite contains a Group VIII metal component. 19. The process in accordance with Claim 14 which is a hydrocracking process comprising contacting the hydrocarbon feedstock under hydrocracking conditions with the zeolite of Claim 1. 20. The process in accordance with Claim 14 which is a catalytic cracking process comprising the step of contacting the hydrocarbon feedstock in a reaction zone under catalytic cracking conditions in the absence of added hydrogen with a catalyst comprising the zeolite of Claim 1. 21. A process in accordance with Claim 20 with a catalyst composition comprising a component which is the zeolite of Claim 1 and a large pore size crystalline aliminosilicate cracking component. 22. A process as defined in Claim 21 wherein the crystalline aluminosilicate cracking component has a pore size greater than 8.0 angstroms. / ( -50- 234405 , oi 23. A process in accordance with Claim 21 wherein the » 02 catalyst compositions comprise a physical mixture of 03 the two components. 04 Q 05 24. A process in accordance with Claim 21 wherein one of 06 the components is the zeolite of Claim 1 incorporated 07 in an inorganic oxide such as silica, alumina, 08 amorphous silica-alumina, silica-magnesia, silica 09 zirconia, alumina-boria, alumina-titanate, a synthetic .""""h io clay such as synthetic mica-montmorillonite, natural 11 clays such as kaolin, halloysite, montmorillonite, 12 attapulgite, sepiolite, and saponite, acid activated 13 clays, pillared or cross-linked clays, and mixtures 14 thereof. 15 16 25. A process in accordance with Claim 21 wherein the two 17 catalyst components are incorporated in an inorganic 18 matrix comprised of the inorganic oxide of Claim 24. 19 20 26. The process in accordance with Claim 14 which is an 21 isomerizing process for isomerizing C^ to C? 22 hydrocarbons, comprising contacting a catalyst, 23 comprising at least one Group VIII metal and the 24 zeolite of Claim 1, with a feed having normal and 25 slightly branched C^ to C? hydrocarbons under 26 isomerization conditions. 27 28 27. A process in accordance with Claim 26 wherein the 29 catalyst has been calcined in a steam/air mixture at an elevated temperature after impregnation of the Group VIII metal. 30 31 32 33 28. A process in accordance with Claim 26 wherein Group 34 VIII metal is platinum. -51- 234405 01 29. 02 03 04 05 06 07 08 O 09 30 • 10 11 12 13 31. 14 15 16 17 18 32. 19 20 21 22 O 23 24 25 26 33. 27 , ; 28 w 29 30 31 34. 32 33 34 The process in accordance with Claim 14 which is a process for alkylating an aromatic hydrocarbon which comprises contacting under alkylating conditions at least a mole excess of an aromatic hydrocarbon with a C2 to C2q olefin under at least partial liquid phase conditions and in the presence of a zeolite according to Claim 1. The process in accordance with Claim 29 wherein the aromatic hydrocarbon and olefin are present in a molar ratio of 4:1 to 20:1, respectively. The process in accordance with Claim 29 wherein the aromatic hydrocarbon is a member selected from the group consisting of benzene, toluene and xylene, or mixtures thereof. The process in accordance with Claim 14 which is a process for transalkylating an aromatic hydrocarbon which comprises contacting under transalkylating conditions an aromatic hydrocarbon with a polyalkyl aromatic hydrocarbon under at least partial liquid phase conditions and in the presence of a zeolite according to Claim 1. The process in accordance with Claim 32 wherein said aromatic hydrocarbon and said polyalkyl aromatic hydrocarbons are present in a molar ratio of 1:1 to 25:1, respectively. The process in accordance with Claim 32 wherein the aromatic hydrocarbon is a member selected from the group consisting of benzene, toluene and xylene, or mixtures thereof. s, 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 23 4 4 0 35. The process in accordance with Claim 32 wherein the polyalkyl aromatic hydrocarbon is dialkylbenzene. 36. The process in accordance with Claim 14 which is an oligomerization process comprising contacting an olefin feed under oligomerization conditions with the zeolite of Claim 1. 37. A zeolite as claimed in any one of claims 1 to 10 substantially as hereinbefore described with reference to any example thereof. 38. A method as claimed in any one of claims 11 to 13 when performed substantially as hereinbefore described with reference to"any example thereof. 39. A zeolite prepared by: a method as claimed in any one of claims 11 to 13 and 38. 40. A process as claimed in any one of claims 14 to 36 when performed substantially as hereinbefore described. .41. A converted hydrocarbon produced resulting from the use of a process as claimed in any one of claims 14 to 36 and 40. NEW ZEALAND PATENT OFFICE -6JUL1990 </div>