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NO20001405L - Modifisert alumoksan-katalysatoraktivator - Google Patents

Modifisert alumoksan-katalysatoraktivator

Info

Publication number
NO20001405L
NO20001405L NO20001405A NO20001405A NO20001405L NO 20001405 L NO20001405 L NO 20001405L NO 20001405 A NO20001405 A NO 20001405A NO 20001405 A NO20001405 A NO 20001405A NO 20001405 L NO20001405 L NO 20001405L
Authority
NO
Norway
Prior art keywords
group
aluminum
catalyst activator
alq1
fluoraryl
Prior art date
Application number
NO20001405A
Other languages
English (en)
Other versions
NO20001405D0 (no
Inventor
Edmund M Carnahan
Eugene Chen
Grant B Jacobsen
James C Stevens
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of NO20001405D0 publication Critical patent/NO20001405D0/no
Publication of NO20001405L publication Critical patent/NO20001405L/no

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C07F5/068—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage) preparation of alum(in)oxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

En katalysatoraktivator spesielt tilpasset for anvendelse ved aktiveringen av metallkomplekser av metaller fra gruppe 3-10 for polymerisasjon av etylenisk umettede polymeriserbare monomerer, spesielt olefiner, omfattende: et preparat omfattende en blanding av aluminiuminneholdende Lewis-syrer hvor nevnte blanding har formelen: ^-,-,-,,y ^ ... --. . [(-alQ1-0-)z (-alArf-0-)z.](Arfz-AI2Q16.z-) hvor; Q1 uavhengig ved hver forekomst er valgt fra C^o alkyl; Ar' er en fluorert aromatisk hydrokarbylgruppe med fra 6 til 30 karbonatomer; T. er et tall fra 1 til 50, fortrinnsvis fra 1,5 til 40, mer foretrukket fra 2 til 30 og gruppen (-alQ1-O-) er en cyklisk eller lineær oligomer med en gjentagende enhet på2-30;-----------------------------~----------------------------------------------=¿ z' er et tall fra 1 til 50, fortrinnsvis fra 1,5 til 40, mer foretrukket fra 2 til 30 og - gruppen (-alA^-O-) er en cykiisk eller jineær oligomer med en gjentagende enhet på 2-30; og- - ._ ::/; ;:.: ......" z" er et tall fra O til 6 og gruppen (Ar'z-AI2Q Yz-) er enten tri(fluoraryl- aluminium), trialkylaluminium eller et addukt av tri(fluorarylaluminium) med en sub-støkiometrisk til super-støkiometrisk mengde av et trialkylaluminium.
NO20001405A 1997-09-19 2000-03-17 Modifisert alumoksan-katalysatoraktivator NO20001405L (no)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US5957497P 1997-09-19 1997-09-19
US5957397P 1997-09-19 1997-09-19
US5957297P 1997-09-19 1997-09-19
PCT/US1998/019314 WO1999015534A1 (en) 1997-09-19 1998-09-16 Modified alumoxane catalyst activator

Publications (2)

Publication Number Publication Date
NO20001405D0 NO20001405D0 (no) 2000-03-17
NO20001405L true NO20001405L (no) 2000-03-17

Family

ID=27369678

Family Applications (1)

Application Number Title Priority Date Filing Date
NO20001405A NO20001405L (no) 1997-09-19 2000-03-17 Modifisert alumoksan-katalysatoraktivator

Country Status (13)

Country Link
EP (1) EP1019415A1 (no)
JP (1) JP2001517714A (no)
KR (1) KR20010024121A (no)
CN (1) CN1270595A (no)
AU (1) AU9393498A (no)
BR (1) BR9812485A (no)
CA (1) CA2302173A1 (no)
HU (1) HUP0004655A3 (no)
ID (1) ID24920A (no)
NO (1) NO20001405L (no)
PL (1) PL339339A1 (no)
TR (1) TR200000688T2 (no)
WO (1) WO1999015534A1 (no)

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Also Published As

Publication number Publication date
NO20001405D0 (no) 2000-03-17
HUP0004655A3 (en) 2003-05-28
CN1270595A (zh) 2000-10-18
ID24920A (id) 2000-08-31
TR200000688T2 (tr) 2000-08-21
CA2302173A1 (en) 1999-04-01
PL339339A1 (en) 2000-12-18
KR20010024121A (ko) 2001-03-26
WO1999015534A1 (en) 1999-04-01
BR9812485A (pt) 2000-09-19
JP2001517714A (ja) 2001-10-09
EP1019415A1 (en) 2000-07-19
HUP0004655A2 (hu) 2001-04-28
AU9393498A (en) 1999-04-12

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