NL2031590B1

NL2031590B1 - High-Index Silicoborate and Borosilicate Glasses

Info

Publication number: NL2031590B1
Application number: NL2031590A
Authority: NL
Inventors: I Priven Alexander; Marie Joseph Lepicard Antoine; Luo Jian
Original assignee: Corning Inc
Priority date: 2022-03-25
Filing date: 2022-04-14
Publication date: 2023-10-06

Abstract

Glass compositions include titania (TiOz), lanthanum oxide (Lagos) and boron oxide (3203) as essential components and may optionally include silica (SÍOz), niobia (szOs), zirconia (ZrOZ), yttria (Yzoa), bismuth oxide (BÍan), tungsten oxide (W03), zinc oxide (ZnO) and other components. The glasses may be characterized by high refractive index at 587.56 nm at comparably low density at room temperature.

Description

High-Index Silicoborate and Borosilicate Glasses

FIELD

[0001] The present disclosure generally relates to borate and silicoborate glasses having a high refractive index and low density.

BACKGROUND

[0002] Glass is used in a variety of optical devices, examples of which include augmented reality devices, virtual reality devices, mixed reality devices, eye wear, etc. Desirable properties for this type of glass often include a high refractive index and a low density. Additional desirable properties may include high transmission in the visible and near-uitraviolet (near-UV) range of the electromagnetic spectrum and/or low optical dispersion. it can be challenging to find glasses having the desired combination of these properties and which can be formed from compositions having good glass-forming ability. For example, generally speaking, as the refractive index of a glass increases, the density also tends to increase. Species such as TiO, and Nb:0; are often added to increase the refractive index of a glass without increasing the density of the glass. However, these materials often absorb blue and UV light, which can undesirably decrease the transmittance of light in this region of the spectrum by the glass.

Often, attempts to increase the refractive index of a glass while maintaining a low density, and without decreasing transmittance in the blue and UV region of the spectrum, can result in a decrease in the glass-forming ability of the material. For example, crystallization and/or liquid-liquid phase separation can occur during cooling of the glass melt at cooling rates that are generally acceptable in the industry.

Typically, the decrease in glass-forming ability appears as the amount of certain species, such as ZrO,

Y203, Sc:03, BeO, etc. increases.

[0003] Low density, high refractive index glasses often belong to one of two types of chemical systems, based on the glass formers used: (a) silicoborate or borosilicate glasses in which SiO; and/or B20: are used as the main glass formers and (b) phosphate glasses in which P,0s is used as a main glass former.

Glasses which rely on other oxides as main glass formers, such as GeO, Te, Bi203, and V20s, can be challenging to use due to cost, glass-forming ability, optical properties, and/or production requirements.

[0004] Phosphate glasses can be characterized by a high refractive index and low density, however, phosphate glasses can be challenging to produce due to volatilization of P2Os from the melts and/or risks of platinum incompatibility. In addition, phosphate glasses are often highly colored and may require an extra bleaching step to provide a glass having the desired transmittance characteristic.

Furthermore, phosphate glasses exhibiting a high refractive index also tend to have an increase in optical dispersion.

[0005] Silicoborate and borate glasses are typically easier to produce and can exhibit a high transmittance without a bleaching step. However, silicoborate and borosilicate glasses typically exhibit an increase in density at increasing refractive indices, compared to phosphate glasses.

[0006] in view of these considerations, there is a need for borate and silicoborate glasses having a high refractive index, a low density, and a high transmittance to blue light.

SUMMARY

[0007] According to an embodiment of the present disclosure, a glass comprises a plurality of components, the glass having a composition of the components comprising greater than or equal to 12.0 mol.% and less than or equal to 35.0 mol.% TiO,, greater than or equal to 2.5 mol.% and less than or equal to 20.0 mol.% ZrO,, greater than or equal to 0.5 mol.% and less than or equal to 40.0 mol.%

B:03, greater than or equal to 0.5 mol.% and less than or equal to 30.0 mol.% Nb:0s, greater than or equal to 0.0 mol.% and less than or equal to 20.0 mol.% Bi203, greater than or equal to 0.0 mol.% and less than or equal to 15.0 mol.% P,0s, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% AlO3, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Gd:03, greater than or equal to 0.0 mol.% and less than or equal to 8.0 mol.% WO:3, greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.% PbO, greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.% V20;, greater than or equal to 0.0 mol.% and less than or equal to 1.5 mol.% ZnO, greater than or equal to 95.0 mol.% RmO,, greater than or equal to 0.5 mol.% and less than or equal to 35.0 mol.%

RE„O,, a sum of SiO; + B20: + P2Os greater than or equal to 10.0 mol.% and a sum of TiO2 + Nb2Os greater than or equal to 0.0 mol.% and less than or equal to 42.0 mol.%, wherein the composition of the components satisfies the condition: SiO; + B20:3 - P20s [mol.%] = 0.000, and the glass satisfies the condition: P, - (1.765 + 0.057 * Py) > 0.000, where P, is a parameter predicting a value of a refractive index at 587.56 nm, na, calculated from the glass composition in terms of mol.% of the components according to the Formula (1):

P= 1.844 + 0.0054162 * La,0; + 0.0031113 * TiO, - 0.004212 * B203 - 0.0035692 * SiO, + 0.0027887 * ZrO, + 0.0078026 * Nb,0s - 0.00012928 * CaO + 0.00076566 * BaO + 0.0043601 * Y203 +0.00067408 * ZnO + 0.0068029 * Gd,0; - 0.0025106 * Na,O + 0.0039937 * WO: - 0.0043208 *

Al,O3 - 0.0011666 * Li,O + 0.0051727 * PbO + 0.012958 * Bi203 - 0.0018753 * GeO, - 0.0014084 * 0

TeO; + 0.0086647 * Er;03 + 0.0097345 * Yb203 - 0.0038734 * K,0 - 0.00041776 * SrO - 0.0017294 *

MgO, and P4 is a parameter predicting a value of density at room temperature, der, calculated from the glass composition in terms of mol.% of the components according to the Formula (11):

Ps = 4.688 + 0.047868 * L3203 - 0.0065829 * TiO, - 0.027601 * B203 - 0.022365 * SiO; + 0.016475 *

ZrO; - 0.0052977 * Nb,Os - 0.0030466 * CaO + 0.014971 * BaO + 0.019511 * Y,0; + 0.0076377 *

ZnO + 0.066160 * Gd203 - 0.016932 * Na20 + 0.025764 * WO; - 0.035116 * Al,03 - 0.0094315 * Li20 (li) +0.047388 * PbO + 0.080813 * Bi,03- 0.0088118 * GeO, + 0.072296 * Er,03 + 0.078888 * Yb20: - 0.026242 * K,0 + 0.010351 * SrO - 0.0030424 * MgO, where RmO, is a total sum of all oxides, REO, is a total sum of rare earth metal oxides, and an asterisk (*} means multiplication.

[0008] According to another embodiment of the present disclosure, a glass comprises a plurality of components, the glass having a composition of the components comprising greater than or equal to 1.0 mol.% and less than or equal to 13.5 mol.% ZrQO;, greater than or equal to 0.3 mol.% and less than or equal to 35.0 mol.% TiO, greater than or equal to 0.3 mol.% and less than or equal to 29.5 mol.% B203, greater than or equal to 0.0 mol.% and less than or equal to 9.0 mol.% WOs, greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.% PbO, greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% Gd:0;3, greater than or equal to 0.0 at.% and less than or equal to 2.0 at.% F, a sum of

TiO; + Nb,Os + La203 greater than or equal to 10.0 mol.% and less than or equal to 70.0 mol.%, a sum of

SiO2 + B203 + P05 greater than or equal to 10.0 mol.%, a sum of REMO, + WO: + ZrO; greater than or equal to 5.0 mol.%, a sum of SiO; + Y203 + Gd20: greater than or equal to 0.3 mol.%, a sum of V20; +

MoO: greater than or equal to 0.0 mol.% and less than or equal to 3.0 mol.% and may optionally contain one or more components selected from Bi203, CaO, BaO, ZnO, Na20, Al,03, Li20, GeO;, TeO,, KO, SrO and MgO, wherein the composition of the components satisfies the conditions: TiO, / (TiO2 + Nb20s +

WO; + Bi203) [mol.%4] > 0.050, SiO: + B20:3 - P2Os [mol.%] > 1.0 and La20: / TiO, [mol.%4] < 1.5, and the glass satisfies the condition: P, - (1.99 + 0.083 * (TiO2 / (TiO; + Nb20; + WO; + Biz0s))) > 0.000, where Pa is a parameter predicting a refractive index at 587.56 nm, ng, calculated from the glass composition in terms of mol.% of the components according to the Formula (1):

P,= 1.844 + 0.0054162 * La203 + 0.0031113 * TiO, - 0.004212 * B,0; - 0.0035692 * SiO, + 0.0027887 * ZrO, + 0.0078026 * Nb,0s - 0.00012928 * CaO + 0.00076566 * BaO + 0.0043601 * Y203 +0.00067408 * ZnO + 0.0068029 * Gd203 - 0.0025106 * Na20 + 0.0039937 * WO; - 0.0043208 *

TeO; + 0.0086647 * Er;03 + 0.0097345 * Yb,0s - 0.0038734 * K,0 - 0.00041776 * SrO - 0.0017294 *

MgO, where REO, is a total sum of rare earth metal oxides, and an asterisk (*)} means multiplication.

[0009] According to one more embodiment of the present disclosure, a glass comprises a plurality of components, the glass having a composition of the components comprising greater than or equal to 0.5 mol.% and less than or equal to 45.0 mol.% B,0s, greater than or equal to 0.1 mol.% and less than or equal to 25.0 mol.% Bi203, greater than or equal to 0.0 mol.% and less than or equal to 8.0 mol.% WO3, a sum of SiO; + B203 + P20; is greater than or equal to 10.0 mol.%, a sum of TiO, + Nb,Os greater than or equal to 8.5 mol.%, a sum of REO, + WO; + ZrO; greater than or equal to 4.5 mol.% and may optionally contain one or more components selected from CaO, BaO, ZnO, Na20, Al:03, Li20, PbO, GeO:, TeOa, K:0,

SrO and MgO, wherein the composition of the components satisfies the condition: SiOz + B20: - P205 [mol.%] > 0.100, and the glass satisfies the condition: P, > 2.045, where P, is a parameter predicting a refractive index at 587.56 nm, na, calculated from the glass composition in terms of mol.% of the components according to the Formula (1):

P,= 1.844 +0.0054162 * La203 + 0.0031113 * TiO, - 0.004212 * B203 - 0.0035692 * SiO, + 0.0027887 * ZrO, + 0.0078026 * Nb,Os - 0.00012928 * CaO + 0.00076566 * BaO + 0.0043601 * Y203 + 0.00067408 * ZnO + 0.0068029 * Gd.0; - 0.0025106 * Na20 + 0.0039937 * WO; - 0.0043208 *

AlO3 - 0.0011666 * Li,O + 0.0051727 * PhO + 0.012958 * Bi203 - 0.0018753 * GeO; - 0.0014084 * 0

TeO, + 0.0086647 * Er,0; + 0.0097345 * Yb203 - 0.0038734 * KO - 0.00041776 * SrO - 0.0017294 *

MgO, where REO, is a total sum of rare earth metal oxides, and an asterisk (*) means multiplication.

[0010] These and other aspects, objects, and features of the present disclosure will be understood and appreciated by those skilled in the art upon studying the following specification, claims, and appended drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

[0011] FIG. 1 is a plot illustrating the relationship between the refractive index na and the refractive index parameter P, calculated by formula {I} for some Comparative Glasses and some Exemplary Glasses according to an embodiment of the present disclosure.

[0012] FIG. 2 is a plot illustrating the relationship between the density dez and the density parameter Py calculated by formula (ll) for some Comparative Glasses and some Exemplary Glasses according to an embodiment of the present disclosure.

[0013] FIG. 3 is a plot of an exemplary cooling schedule according to a "15 min test” condition and a “2.5 min test” condition for some Exemplary Glasses according to an embodiment of the present disclosure.

[0014] FIG. 4 is a plot illustrating the relationship between the density parameter Py and the refractive index parameter P, for some Comparative Glasses and some Exemplary Glasses according to an embodiment of the present disclosure.

[0015] FIG. 5 is a plot illustrating the relationship between the density at room temperature dgr and the 5 refractive index at 587.56 nm ny for some Comparative Glasses and some Exemplary Glasses according to an embodiment of the present disclosure.

[0016] FIG. 6 is a plot illustrating the relationship between the ratio TiO2 / (TiO2 + NbOs + WO; + Bi203) and the refractive index parameter P, for some Comparative Glasses and some Exemplary Glasses according to an embodiment of the present disclosure.

[0017] FIG. 7 is a plot illustrating the relationship between the ratio TiO, / (TiO2 + Nb20s + WO; + Bi203) and the refractive index at 587.56 nm ng for some Comparative Glasses and some Exemplary Glasses according to an embodiment of the present disclosure.

DETAILED DESCRIPTION

[0018] In the following detailed description, for purposes of explanation and not limitation, example embodiments disclosing specific details are set forth to provide a thorough understanding of various principles of the present disclosure. However, it will be apparent to one having ordinary skill in the art, having had the benefit of the present disclosure, that the present disclosure may be practiced in other embodiments that depart from the specific details disclosed herein. Moreover, descriptions of well- known devices, methods and materials may be omitted so as not to obscure the description of various principles of the present disclosure. Finally, wherever applicable, like reference numerals refer to like elements.

[0019] Unless otherwise expressly stated, it is in no way intended that any method set forth herein be construed as requiring that its steps be performed in a specific order. Accordingly, where a method claim does not actually recite an order to be followed by its steps, or it is not otherwise specifically stated in the claims or descriptions that the steps are to be limited to a specific order, it is in no way intended that an order be inferred, in any respect. This holds for any possible non-express basis for interpretation, including, without limitation, matters of logic with respect to arrangement of steps or operational flow; plain meaning derived from grammatical organization or punctuation; the number or type of embodiments described in the specification.

[0020] As used herein, the term "and/or," when used in a list of two or more items, means that any one of the listed items can be employed by itself, or any combination of two or more of the listed items can be employed. For example, if a composition is described as containing components A, B, and/or C, the composition can contain A alone; B alone; C alone; A and B in combination; A and C in combination; B and C in combination; or A, B, and C in combination.

[0021] Modifications of the disclosure will occur to those skilled in the art and to those who make or use the disclosure. Therefore, it is understood that the embodiments shown in the drawings and described above are merely for illustrative purposes and not intended to limit the scope of the disclosure, which is defined by the following claims, as interpreted according to the principles of patent law, including the doctrine of equivalents.

[0022] As used herein, the term "about" means that amounts, sizes, formulations, parameters, and other quantities and characteristics are not and need not be exact, but may be approximate and/or larger or smaller, as desired, reflecting tolerances, conversion factors, rounding off, measurement error and the like, and other factors known to those skilled in the art. When the term "about" is used in describing a value or an end-point of a range, the disclosure should be understood to include the specific value or end-point referred to. Whether or not a numerical value or end-point of a range in the specification recites "about," the numerical value or end-point of a range is intended to include two embodiments: one modified by “about,” and one not modified by “about.” it will be further understood that the end-points of each of the ranges are significant both in relation to the other end-point, and independently of the other end-point.

[0023] The term “component” refers to a material or compound included in a batch composition from which a glass is formed. Components include oxides, including but not limited to those expressed in

Formulas (1), and (li), and the claims. Representative components include B203, P205, Al203, CuO, Cu:0,

RO, R20, Sn0:, MnO:;, REO, SiO2, Ta:0s, ZnO, WO3, Nb20s, TiO2, Zr0;, Bi203, TeO;, etc. Other representative components include halogens (e.g. F, Br, Cl). Whenever a component is included as a term in a mathematical expression or formula, it is understood that the component refers to the amount of the component in units of mol.% in the batch composition of the glass. For example, the expression “B,0s + P20s” refers to the sum of the amount of B20:3 in units of mol.% and the amount of

P2Os5 in units of mol.% in the batch composition of the glass. A mathematical expression or formula is any expression or formula that includes a mathematical operator such as “+”, <p “min”, or “max”.

[0024] Unless otherwise specified, the amount or content of a component in a glass composition is expressed herein in units of mol.% {mole percent).

[0025] The term "formed from" can mean one or more of comprises, consists essentially of, or consists of. For example, a component that is formed from a particular material can comprise the particular material, consist essentially of the particular material, or consist of the particular material.

[0026] The terms "free" and “substantially free" are used interchangeably herein to refer to an amount and/or an absence of a particular component in a glass composition that is not intentionally added to the glass composition. It is understood that the glass composition may contain traces of a particular constituent component as a contaminant or a tramp in an amount of less than 0.10 mol.%.

[0027] As used herein, the term "tramp", when used to describe a particular constituent component in a glass composition, refers to a constituent component that is not intentionally added to the glass composition and is present in an amount of less than 0.10 mol.%. Tramp components may be unintentionally added to the glass composition as an impurity in another constituent component and/or through migration of the tramp component into the composition during processing of the glass composition.

[0028] Unless otherwise specified, the term “glass” is used to refer to a glass made from a glass composition disclosed herein.

[0029] The symbol " * “ means multiplication when used in any formula herein.

[0030] The term “log” means logarithm in base 10.

[0031] Temperature is expressed herein in units of °C (degrees Celsius).

[0032] Density is expressed herein in units of g/cm.

[0033] Viscosity is expressed herein in units of P (Poise).

[0034] The term "glass former" is used herein to refer to a component that, being solely present in the glass composition (i.e, without other components, except for tramps), is able to form a glass when cooling the melt at a rate of not greater than about 300 °C/min.

[0035] The term "modifier", as used herein, refers to the oxides of monovalent or divalent metals, i.e.,

RO or RO, where "R"” stands for a cation. Modifiers can be added to a glass composition to change the atomic structure of the melt and the resulting glass. In some embodiments, the modifier may change the coordination numbers of cations present in the glass formers (e.g., boron in B203}, which may result in forming a more polymerized atomic network and, as a result, may provide better glass formation.

[0036] As used herein, the term "RO" refers to a total content of divalent metal oxides, the term "R,0" refers to a total content of monovalent metal oxides, and the term ”Alk;O" refers to a total content of alkali metal oxides. The term R;0 encompasses alkali metal oxides (Alk20}, in addition to other monovalent metal oxides, such as Ag,0, Tl,0, and Hg,0, for example. As discussed below, in the present disclosure, a rare earth metal oxide is referred to herein by its normalized formula (RE203)} in which the rare earth metal RE has the redox state "+3," and thus rare earth metal oxides are not encompassed by thetermRO.

[0037] As used herein, the term "rare earth metals" refers to the metals listed in the Lanthanide Series of the IUPAC Periodic Table, plus yttrium and scandium. As used herein, the term "rare earth metal oxides,” is used to refer to the oxides of rare earth metals in different redox states, such as "+3" for fanthanum in La203, "+4" for cerium in CeQ,, "+2" for europium in EuQ, etc. In general, the redox states of rare earth metals in oxide glasses may vary and, in particular, the redox state may change during melting, based on the batch composition and/or the redox conditions in the furnace where the glass is melted and/or heat-treated (e.g., annealed). Unless otherwise specified, a rare earth metal oxide is referred to herein by its normalized formula in which the rare earth metal has the redox state "+3."

Accordingly, in the case in which a rare earth metal having a redox state other than "+3" is added to the glass composition batch, the glass compositions are recalculated by adding or removing some oxygen to maintain the stoichiometry. For example, when CeO: (with cerium in redox state "+4") is used as a batch component, the resulting as-batched composition is recalculated assuming that two moles of CeO: is equivalent to one mole of Ce:03, and the resulting as-batched composition is expressed in terms of

Ce,0s. As used herein, the term "REO," is used to refer to the total content of rare earth metal oxides in all redox states present, and the term "RE,03" is used to refer to the total content of rare earth metal oxides in the "+3" redox state, also specified as "trivalent equivalent”.

[0038] Unless otherwise specified, all compositions are expressed in terms of as-batched mole percent (mol%). As will be understood by those having ordinary skill in the art, various melt constituents (e.g., fluorine, alkali metals, boron, etc.} may be subject to different levels of volatilization (e.g., as a function of vapor pressure, melt time and/or melt temperature) during melting of the constituents. As such, the term “about,” in relation to such constituents, is intended to encompass values within about 0.2 mol% when measuring final articles as compared to the as-batched compositions provided herein. With the forgoing in mind, substantial compositional equivalence between final articles and as-batched compositions is expected.

[0039] in the case when fluorine or other halogen (chlorine, bromine, and/or iodine} is added to or is present in an oxide glass, the molecular representation of the resulting glass composition may be expressed in different ways. In the present disclosure, the content of fluorine as a single term, when present, is expressed in terms of atomic percent (at.%), which is determined based on the fraction of fluorine in a total sum of all atoms in a glass composition multiplied by a factor of 100.

[0040] in the present disclosure, the following method of representation of fluorine-containing compositions and concentration ranges is used. The concentration limits for all oxides (e.g. SiO, B20;,

Na;0, etc.) are presented under the assumption that the respective cations (such as, for example, silicon [Sis"], boron [B3*]|, sodium [Na], etc.) are initially presented in the form of the corresponding oxides.

When fluorine is present, for the purposes of calculating the concentration of components of the composition, some part of the oxygen in the oxide is equivalently replaced with fluorine (i.e. one atom of oxygen is replaced with two atoms of fluorine). The fluorine is assumed to be present in the form of silicon fluoride (SiF4); accordingly, the total sum of all oxides plus SiF, is assumed to be 100 mole percent in all compositions.

[0041] The measured density values for the glasses reported herein were measured at room temperature in units of g/cm? by Archimedes method in water with an error of 0.001 g/cm}?. As used herein, density measurements at room temperature (specified as der) are indicated as being measured at 20 °C or 25 °C, and encompass measurements obtained at temperatures that may range from 20 °C to 25 °C. itis understood that room temperature may vary between about 20 °C to about 25 °C, however, for the purposes of the present disclosure, the variation in density within the temperature range of 20 °C to 25 °C is expected to be less than the error of 0.001 g/cm?, and thus is not expected to impact the room temperature density measurements reported herein.

[0042] As used herein, good glass forming ability refers to a resistance of the melt to devitrification as the material cools. Glass forming ability can be measured by determining the critical cooling rate of the melt. The terms "critical cooling rate” or "v" are used herein to refer to the minimum cooling rate at which a melt of a given composition forms a glass free of crystals visible under an optical microscope under magnification of 500x. The critical cooling rate can be used to measure the glass-forming ability of a composition, i.e., the ability of the melt of a given glass composition to form glass when cooling.

Generally speaking, the lower the critical cooling rate, the better the glass-forming ability.

[0043] The term "liquidus temperature" (Tig) is used herein to refer to a temperature above which the glass composition is completely liquid with no crystallization of constituent components of the glass. The liquidus temperature values reported herein were obtained by measuring samples using either DSC or by isothermal hold of samples wrapped in platinum foil. For samples measured using DSC, powdered samples were heated at 10 K/min to 1250°C. The end of the endothermal event corresponding to the melting of crystals was taken as the liquidus temperature. For the second technique (isothermal hold), a glass block (about 1 cm?) was wrapped in platinum foil, to avoid volatilization, and placed in a furnace at a given temperature for 17 hours. The glass block was then observed under an optical microscope to check for crystals.

[0044] The refractive index values reported herein were measured at room temperature, unless otherwise specified. The refractive index values for a glass sample were measured using a Metricon

Model 2010 prism coupler refractometer with an error of about + 0.0002. Using the Metricon, the refractive index of a glass sample was measured at two or more wavelengths of about 406 nm, 473 nm, 532 nm, 633 nm, 828 nm, and 1064 nm. The measured dependence characterizes the dispersion and was then fitted with a Cauchy's law equation or Sellmeier equation to allow for calculation of the refractive index of the sample at a given wavelength of interest between the measured wavelengths.

The term "refractive index na" is used herein to refer to a refractive index calculated as described above at a wavelength of 587.56 nm, which corresponds to the helium d-line wavelength. The term "refractive index nc” is used herein to refer to a refractive index calculated as described above at a wavelength of

656.3 nm. The term "refractive index ne" is used herein to refer to a refractive index calculated as described above at a wavelength of 486.1 nm. The term "refractive index ng" is used herein to refer to a refractive index calculated as described above at a wavelength of 435.8 nm.

[0045] As used herein, the terms "high refractive index" or "high index” refer to a refractive index value of a glass that is greater than or equal to at least 1.80, unless otherwise indicated. Where indicated, embodiments of the terms "high refractive index" or "high index” refer to a refractive index value of a glass that is greater than or equal to at least 1.85, greater than or equal to 1.90, or greater than or equal to 1.95, or greater than or equal to 2.00.

[0046] The glass transition temperature (Tg) is measured by differential scanning calorimeter (DSC) at the heating rate of 10 K/min after cooling in air.

[0047] Glass composition may include boron oxide (B203}. According to some embodiments of the present disclosure, boron oxide may play a role of a glass former. As a glass former, B203 may increase the liquidus viscosity and, therefore, inhibit crystallization. However, adding B20: to a glass composition may cause liquid-liquid phase separation, which may cause devitrification and/or a reduction in the visible transmittance of the glass. Also, adding B20:3 to the high-index glasses reduces the refractive index. Accordingly, the amount of boron oxide is limited, or glasses may be substantially free of B203. In embodiments, the glass composition may contain boron oxide (B20:3} in an amount from greater than or equal to 0.3 mol.% to less than or equal to 45.0 mol.% and all ranges and sub-ranges between the foregoing values. In some embodiments, the glass composition may contain BOs in an amount greater than or equal to 0.3 mol.%, greater than or equal to 5.0 mol.%, greater than or equal to 10.0 mol.%, greater than or equal to 14.0 mol.%, greater than or equal to 15.0 mol.%, greater than or equal to 16.0 mol.%, greater than or equal to 16.4 mol.%, greater than or equal to 16.9 mol.%, greater than or equal to 25.0 mol.%, greater than or equal to 30.0 mol.%, greater than or equal to 35.0 mol.%, or greater than or equal to 40.0 mol.%. In some other embodiments, the glass composition may contain B,O; in an amount less than or equal to 45.0 mol.%, less than or equal to 40.0 mol.%, less than or equal to 35.0 mol.%, less than or equal to 30.0 mol.%, less than or equal to 29.5 mol.%, less than or equal to 25.0 mol.%, less than or equal to 24.0 mol.%, less than or equal to 22.5 mol.%, less than or equal to 20.4 mol.%, less than or equal to 20.0 mol.%, or less than or equal to 10.0 mol.%. in some more embodiments, the glass composition may contain B20: in an amount greater than or equal to 0.3 mol.% and less than or equal to 29.5 mol.%, greater than or equal to 0.5 mol.% and less than or equal to 45.0 mol.%, greater than or equal to 0.5 mol.% and less than or equal to 40.0 mol.%, greater than or equal to 10.0 mol.% and less than or equal to 35.0 mol.%, greater than or equal to 13.67 mol.% and less than or equal to 24.41 mol.%, greater than or equal to 15.0 mol.% and less than or equal to 22.5 mol.%, greater than or equal to 16.0 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 16.4 mol.%

and less than or equal to 20.4 mol.%, greater than or equal to 16.9 mol.% and less than or equal to 20.4 mol.%, greater than or equal to 0.3 mol.% and less than or equal to 45.0 mol.%, greater than or equal to 0.3 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 45.0 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 10.0 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 14.0 mol.% and less than or equal to 45.0 mol.%, greater than or equal to 14.0 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 15.0 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 16.4 mol.% and less than or equal to 20.0 mol.%.

[0048] Glass composition may include silica (SiO). Silica may play a role of glass-former. Silica, as well as B:03, may help to increase the liquidus viscosity (viscosity at the liquidus temperature) and, therefore, inhibit crystallization. However, adding SiO, to a glass composition may cause liquid-liquid phase separation, which may cause devitrification and/or a reduction in the transmittance of the glass.

Also, SiO; is a low-index component and makes it difficult to achieve high index. Accordingly, the content of SiO is limited, or glasses may be substantially free of Si0,. in embodiments, the glass composition may contain silica (SiO2} in an amount from greater than or equal to 0.0 mol.% to less than or equal to 22.1 mol.% and all ranges and sub-ranges between the foregoing values. in some embodiments, the glass composition may contain SiO, in an amount greater than or equal to 0.0 mol.%, greater than or equal to 4.7 mol.%, greater than or equal to 5.0 mol.%, greater than or equal to 10.0 mol.%, greater than or equal to 11.0 mol.%, or greater than or equal to 20.0 mol.%. In some other embodiments, the glass composition may contain SiO; in an amount less than or equal to 22.1 mol.%, less than or equal to 20.0 mol.%, less than or equal to 17.5 mol.%, less than or equal to 16.5 mol.%, less than or equal to 15.0 mol.%, less than or equal to 13.4 mol.%, or less than or equal to 10.0 mol.%. In some more embodiments, the glass composition may contain SiO; in an amount greater than or equal to 0.0 mol.% and less than or equal to 15.0 mol.%, greater than or equal to 4.68 mol.% and less than or equal to 13.4 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 10.0 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 10.0 mol.% and less than or equal to 17.5 mol.%, greater than or equal to 11.0 mol.% and less than or equal to 16.5 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 22.1 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 4.7 mol.% and less than or equal to 22.1 mol.%, greater than or equal to 4.7 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 22.1 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 10.0 mol.% and less than or equal to 22.1 mol.%, greater than or equal to 10.0 mol.% and less than or equal to 13.4 mol.%, greater than or equal to 11.0 mol.% and less than or equal to 22.1 mol.%, greater than or equal to 11.0 mol.% and less than or equal to 13.4 mol.%.

[0049] Glass composition may include phosphorus oxide (P205) as an additional glass former. Greater amounts of P20; may increase the melt viscosity at a given temperature, which may inhibit crystallization from the melt when cooling and, therefore, may improve the glass-forming ability of the melt (i.e. lower the critical cooling rate of the melt). However, P2Os significantly decreases the refractive index. Also, in some cases P,0s may stimulate liquid-liquid phase separation, which may cause crystallization of glass forming melts when cooling and/or loss of transmittance. Additionally, P20O; can increase the liquidus temperature of a given composition due to the low solubility of refractory phosphate phases, such as rare earth phosphates and zirconia phosphate. Accordingly, the content of

P2Os in high-index glasses is limited, or glasses may be free of P20O.. in embodiments, the glass composition may contain phosphorus oxide (P.0s) in an amount from greater than or equal to 0.0 mol.% to less than or equal to 15.0 mol.% and all ranges and sub-ranges between the foregoing values. In some embodiments, the glass composition may contain P,0s in an amount greater than or equal to 0.0 mol.%, greater than or equal to 5.0 mol.%, greater than or equal to 9.0 mol.%, greater than or equal to 10.0 mol.%, greater than or equal to 11.0 mol.%, or greater than or equal to 13.0 mol.%. In some other embodiments, the glass composition may contain P,0s in an amount less than or equal to 15.0 mol.%, less than or equal to 13.0 mol.%, less than or equal to 11.0 mol.%, less than or equal to 10.0 mol.%, less than or equal to 9.0 mol.%, or less than or equal to 5.0 mol.%. In some more embodiments, the glass composition may contain P.Os in an amount greater than or equal to 0.0 mol.% and less than or equal to 15.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 15.0 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 9.0 mol.%, greater than or equal to 9.0 mol.% and less than or equal to 15.0 mol.%, greater than or equal to 9.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 10.0 mol.% and less than or equal to 15.0 mol.%, greater than or equal to 10.0 mol.% and less than or equal to 11.0 mol.%, greater than or equal to 11.0 mol.% and less than or equal to 15.0 mol.%, greater than or equal to 11.0 mol.% and less than or equal to 13.0 mol.%.

[0050] Glass composition may have limitations for the amount of all oxides. When a glass composition completely or mostly consists of oxides, containing zero or a small amount of non-oxide components (such as halides, chalcogenides and others), it may become easier to melt and preserve from crystallization, phase separation, volatilization of components and other undesirable effects.

Accordingly, in some embodiments of the present disclosure, the glass composition may be required to contain high amount of oxide components, or not to contain non-oxide components in remarkable amounts.

[0051] in some embodiments, the glass composition may contain a sum of all oxides RmO, in an amount greater than or equal to 95.0 mol.%.

[0052] Glass composition may have limitations for the amount of rare earth metal oxides. In some embodiments, the glass composition may contain rare earth metal oxides REO, in an amount greater than or equal to 0.5 mol.%, or greater than or equal to 20.0 mol.%. In some other embodiments, the glass composition may contain rare earth metal oxides REmO, in an amount less than or equal to 35.0 mol.% or less than or equal to 20.0 mol.%. In some more embodiments, the glass composition may contain RE»„O, in an amount greater than or equal to 0.5 mol.% and less than or equal to 35.0 mol.%, or greater than or equal to 0.5 mol.% and less than or equal to 20.0 mol.%.

[0053] Glass composition may include lanthanum oxide (La,0s). Lanthanum oxide is a high-index component that has little effect on transmittance in the visible range. Also, addition of La203 may inhibit phase separation. However, La,0; provides higher density relative to other high-index components, such as, for example, TiO2, Nb205 or WO. Also, when added in high amount, it may cause crystallization of refractory species, like lanthanum disilicate (La25i207}, lanthanum zirconate (La2ZrOs} and others, and, accordingly, reduce glass forming ability. For this reason, the content of La20: should be limited. in embodiments, the glass composition may contain lanthanum oxide (La203} in an amount from greater than or equal to 0.0 mol.% to less than or equal to 70.0 mol.% and all ranges and sub-ranges between the foregoing values. In some embodiments, the glass composition may contain La203 in an amount greater than or equal to 0.0 mol.%, greater than or equal to 5.0 mol.%, greater than or equal to 10.0 mol.%, greater than or equal to 15.0 mol.%, greater than or equal to 20.0 mol.%, greater than or equal to 21.0 mol.%, greater than or equal to 22.0 mol.%, greater than or equal to 40.0 mol.%, greater than or equal to 50.0 mol.%, or greater than or equal to 60.0 mol.%. In some other embodiments, the glass composition may contain La20:3 in an amount less than or equal to 70.0 mol.%, less than or equal to 60.0 mol.%, less than or equal to 50.0 mol.%, less than or equal to 40.0 mol.%, less than or equal to 30.0 mol.%, less than or equal to 27.5 mol.%, less than or equal to 26.25 mol.%, less than or equal to 24.0 mol.%, or less than or equal to 10.0 mol.%. In some more embodiments, the glass composition may contain La;0s in an amount greater than or equal to 15.0 mol.% and less than or equal to 30.0 mol.%, greater than or equal to 20.0 mol.% and less than or equal to 30.0 mol.%, greater than or equal to 20.0 mol.% and less than or equal to 27.5 mol.%, greater than or equal to 21.0 mol.% and less than or equal to 26.25 mol.%, greater than or equal to 21.83 mol.% and less than or equal to 24.03 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 70.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 10.0 mol.% and less than or equal to 70.0 mol.%, greater than or equal to 10.0 mol.% and less than or equal to 24.0 mol.%, greater than or equal to 15.0 mol.% and less than or equal to 24.0 mol.%, greater than or equal to 20.0 mol.% and less than or equal to 70.0 mol.%, greater than or equal to 20.0 mol.% and less than or equal to 24.0 mol.%.

[0054] Glass composition may include yttria (Y20s). Yttria behaves like lanthanum oxide, but may provide a given refractive index at a lower density, while still not providing undesirable coloring.

However, adding Y20: in high amounts to the glass compositions may adversely cause crystallization of the glass melts when cooling. Accordingly, in some embodiments, the content of Y203 may be limited. In embodiments, the glass composition may contain yttria (Y20s) in an amount from greater than or equal to 0.0 mol.% to less than or equal to 10.0 mol.% and all ranges and sub-ranges between the foregoing values. In some embodiments, the glass composition may contain Y,0s in an amount greater than or equal to 0.0 mol.%, greater than or equal to 0.5 mol.%, greater than or equal to 0.75 mol.%, greater than or equal to 3.0 mol.%, or greater than or equal to 5.0 mol.%. In some other embodiments, the glass composition may contain Y203 in an amount less than or equal to 10.0 mol.%, less than or equal to 8.0 mol.%, less than or equal to 6.25 mol.%, less than or equal to 6.0 mol.%, less than or equal to 5.5 mol.%, or less than or equal to 5.0 mol.%. In some more embodiments, the glass composition may contain Y203 in an amount greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 8.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 6.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.%, greater than or equal to 0.5 mol.% and less than or equal to 6.25 mol.%, greater than or equal to 0.75 mol.% and less than or equal to 5.5 mol.%, greater than or equal to 2.54 mol.% and less than or equal to 5.28 mol.%, greater than or equal to 0.5 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 0.5 mol.% and less than or equal to 5.0 mol.%, greater than or equal to 0.75 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 0.75 mol.% and less than or equal to 5.0 mol.%, greater than or equal to 3.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 3.0 mol.% and less than or equal to 5.0 mol.%.

[0055] Glass composition may include gadolinium oxide (Gd.03). Gadolinium oxide behaves like lanthanum oxide, providing high refractive index without compromising visible transmittance, but adversely increasing the density of glass. Also, gadolinium oxide is more expensive than other rare earth metal oxides, such as La203 and Y,0s. Accordingly, in some embodiments, the content of Gd,0s in a glass composition is limited, or a glass composition may be substantially free of Gd.0s. In embodiments, the glass composition may contain gadolinium oxide (Gd203) in an amount from greater than or equal to 0.0 mol.% to less than or equal to 10.0 mol.% and all ranges and sub-ranges between the foregoing values.

In some embodiments, the glass composition may contain Gd.0s; in an amount greater than or equal to 0.0 mol.%, greater than or equal to 5.0 mol.%, greater than or equal to 7.0 mol.%, greater than or equal to 8.0 mol.%, or greater than or equal to 9.0 mol.%. In some other embodiments, the glass composition may contain Gd20:3 in an amount less than or equal to 10.0 mol.%, less than or equal to 9.0 mol.%, less than or equal to 8.0 mol.%, less than or equal to 7.0 mol.%, less than or equal to 5.0 mol.%, less than or equal to 2.0 mol.%, less than or equal to 1.35 mol.%, or less than or equal to 1.2 mol.%. In some more embodiments, the glass composition may contain Gd,0s in an amount greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 1.35 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 1.2 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 7.0 mol. %.

[0056] Glass composition may include alumina (AlO3). Alumina may increase the viscosity of glass forming melts at high temperature, which may reduce the critical cooling rate and improve the glass forming ability. However, addition of Al,O; may cause crystallization of refractory minerals, such as aluminum titanate (Al,TiOs), aluminum niobate (AINbOa) and others, in the melt when cooling, or may lower the solubility of ZrO, in the liquid, causing a drastic increase on the liquidus temperature or necessitating a lower ZrO» content of a composition. Accordingly, the amount of ALO; is limited, or glasses may be substantially free of Al,Os. In embodiments, the glass composition may contain alumina (Al203} in an amount from greater than or equal to 0.0 mol.% to less than or equal to 10.0 mol.% and all ranges and sub-ranges between the foregoing values. In some embodiments, the glass composition may contain Al,Os in an amount greater than or equal to 0.0 mol.%, greater than or equal to 5.0 mol.%, greater than or equal to 7.0 mol.%, greater than or equal to 8.0 mol.%, or greater than or equal to 9.0 mol.%. In some other embodiments, the glass composition may contain Al20:3 in an amount less than or equal to 10.0 mol.%, less than or equal to 9.0 mol.%, less than or equal to 8.0 mol.%, less than or equal to 7.0 mol.%, or less than or equal to 5.0 mol.%. In some more embodiments, the glass composition may contain Al203 in an amount greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 7.0 mol.%, greater than or equal to 7.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 7.0 mol.% and less than or equal to 8.0 mol.%, greater than or equal to 8.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 8.0 mol.% and less than or equal to 9.0 mol.%.

[0057] Glass composition may include vanadia (V20s). Vanadia provides the highest ratio of the refractive index to density among all oxides. However, vanadia may cause undesirable dark coloring and may also raise environmental concerns. For these reasons, the content of vanadia in the glasses is limited, or glass compositions may be free of V,0s. In embodiments, the glass composition may contain vanadia (V.0s)} in an amount from greater than or equal to 0.0 mol.% to less than or equal to 10.0 mol.% and all ranges and sub-ranges between the foregoing values. In some embodiments, the glass composition may contain V,0s in an amount greater than or equal to 0.0 mol.%, greater than or equal to 5.0 mol.%, greater than or equal to 7.0 mol.%, greater than or equal to 8.0 mol.%, or greater than or equal to 9.0 mol.%. In some other embodiments, the glass composition may contain V2Os in an amount less than or equal to 10.0 mol.%, less than or equal to 9.0 mol.%, less than or equal to 8.0 mol.%, tess than or equal to 7.0 mol.%, less than or equal to 5.0 mol.%, less than or equal to 3.0 mol.%, or less than or equal to 0.1 mol.%. In some more embodiments, the glass composition may contain V20s in an amount greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 0.1 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 7.0 mol.%, greater than or equal to 7.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 7.0 mol.% and less than or equal to 8.0 mol.%, greater than or equal to 8.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 8.0 mol.% and less than or equal to 9.0 mol.%.

[0058] Glass composition may include lead oxide (PbO). Adding lead oxide to a glass composition may increase the refractive index without causing crystallization or phase separation of the glass forming melt and not compromising the visible transmittance. However, adding PbO may adversely increase the density of glass. Also, PbO raises environmental concerns. Accordingly, in some embodiments of the present disclosure the content of PbO in glass composition is limited, or, preferably, a glass composition can be substantially free of PbO. In embodiments, the glass composition may contain lead oxide (PbO) in an amount from greater than or equal to 0.0 mol.% to less than or equal to 10.0 mol.% and all ranges and sub-ranges between the foregoing values. In some embodiments, the glass composition may contain PbO in an amount greater than or equal to 0.0 mol.%, greater than or equal to 5.0 mol.%, greater than or equal to 7.0 mol.%, greater than or equal to 8.0 mol.%, or greater than or equal to 9.0 mol.%. In some other embodiments, the glass composition may contain PbO in an amount less than or equal to 10.0 mol.%, less than or equal to 9.0 mol.%, less than or equal to 8.0 mol.%, less than or equal to 7.0 mol.%, less than or equal to 5.0 mol.%, or less than or equal to 0.5 mol.%. In some more embodiments, the glass composition may contain PbO in an amount greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 0.5 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 7.0 mol.%, greater than or equal to 7.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 7.0 mol.% and less than or equal to 8.0 mol.%, greater than or equal to 8.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 8.0 mol.% and less than or equal to 9.0 mol.%.

[0059] Glass composition may include zinc oxide (ZnO). Zinc oxide provides a high ratio of refractive index to density and may increase the solubility of titania, which indirectly increases the refractive index of glasses. However, in some embodiments, at high concentrations of ZnO, the glass-forming ability of the melt may decrease and the melt may tend to crystallize during cooling. In embodiments, the glass composition may contain zinc oxide (ZnO) in an amount from greater than or equal to 0.0 mol.% to less than or equal to 10.0 mol.% and all ranges and sub-ranges between the foregoing values. in some embodiments, the glass composition may contain ZnO in an amount greater than or equal to 0.0 mol.%, greater than or equal to 5.0 mol.%, greater than or equal to 7.0 mol.%, greater than or equal to 8.0 mol.%, or greater than or equal to 9.0 mol.%. In some other embodiments, the glass composition may contain ZnO in an amount less than or equal to 10.0 mol.%, less than or equal to 9.0 mol.%, less than or equal to 8.0 mol.%, less than or equal to 7.0 mol.%, less than or equal to 5.0 mol.%, less than or equal to 4.0 mol.%, less than or equal to 3.0 mol.%, less than or equal to 2.7 mol.%, less than or equal to 1.5 mol.%, or less than or equal to 0.1 mol.%. In some more embodiments, the glass composition may contain ZnO in an amount greater than or equal to 0.0 mol.% and less than or equal to 4.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 3.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 2.7 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 1.5 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 0.1 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 7.0 mol.% and less than or equal to 8.0 mol.%.

[0060] Glass composition may include tungsten oxide (WO:s). WO; provides high refractive index without significantly increasing density or causing undesirable coloring. Also, addition of WO; to glass composition may decrease the liquidus temperature, which allows melting such glasses at lower temperatures, that, in turn, may increase the transmittance of such glasses. Also, addition of WO: may decrease the glass transition temperature T,, which allows glass formation at lower temperatures. At high concentrations of WQs, the liquidus temperature tends to increase, and the viscosity at the liquidus temperature drops, making it difficult to avoid crystallization of melts when cooling. Accordingly, the content of WO: should be limited, or glass compositions may be free of WO:. In embodiments, the glass composition may contain tungsten oxide (WO:s} in an amount from greater than or equal to 0.0 mol.% to less than or equal to 9.0 mol.% and all ranges and sub-ranges between the foregoing values. In some embodiments, the glass composition may contain WO; in an amount greater than or equal to 0.0 mol.%, greater than or equal to 2.0 mol.%, greater than or equal to 5.0 mol.%, greater than or equal to 6.0 mol.%, greater than or equal to 7.0 mol.%, or greater than or equal to 8.0 mol.%. In some other embodiments, the glass composition may contain WO: in an amount less than or equal to 9.0 mol.%, less than or equal to 8.0 mol.%, less than or equal to 7.0 mol.%, less than or equal to 6.0 mol.%, less than or equal to 5.0 mol.%, less than or equal to 2.0 mol.%, less than or equal to 1.8 mol.%, or less than or equal to 1.6 mol.%. In some more embodiments, the glass composition may contain WO; in an amount greater than or equal to 0.0 mol.% and less than or equal to 9.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 8.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 6.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 1.8 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 1.6 mol.%, greater than or equal to 1.97 mol.% and less than or equal to 5.91 mol.%, greater than or equal to 2.0 mol.% and less than or equal to 5.0 mol.%, greater than or equal to 6.0 mol.% and less than or equal to 7.0 mol.%, greater than or equal to 7.0 mol.% and less than or equal to 8.0 mol.%.

[0061] Glass composition may include zirconia (ZrQ;). Zirconia can increase the refractive index while maintaining low density. ZrO; can also increase the viscosity of the melt, which may help to inhibit crystallization from the melt. ZrO, does not introduce coloring in the glass in the visible and near-UV ranges, which may help to maintain a high transmittance of the glass. However, high concentrations of zirconia may cause crystallization of refractory minerals, such as zirconia (ZrO2}, zircon (ZrSiOa4}, calcium zirconate (CaZrO3) and others, which may decrease the glass forming ability of the melt. In embodiments, the glass composition may contain zirconia (ZrO:} in an amount from greater than or equal to 0.0 mol.% to less than or equal to 20.0 mol.% and all ranges and sub-ranges between the foregoing values. In some embodiments, the glass composition may contain ZrO; in an amount greater than or equal to 0.0 mol.%, greater than or equal to 1.0 mol.%, greater than or equal to 2.5 mol.%, greater than or equal to 4.0 mol.%, greater than or equal to 5.0 mol.%, greater than or equal to 5.3 mol.%, greater than or equal to 5.6 mol.%, greater than or equal to 6.5 mol.%, greater than or equal to 6.8 mol.%, greater than or equal to 10.0 mol.%, greater than or equal to 14.0 mol.%, greater than or equal to 16.0 mol.%, or greater than or equal to 18.0 mol.%. In some other embodiments, the glass composition may contain ZrO; in an amount less than or equal to 20.0 mol.%, less than or equal to 18.0 mol.%, less than or equal to 16.0 mol.%, less than or equal to 14.0 mol.%, less than or equal to 13.5 mol.%, less than or equal to 10.0 mol.%, less than or equal to 9.0 mol.%, less than or equal to 8.1 mol.%, less than or equal to 8.0 mol.%, less than or equal to 7.8 mol.%, or less than or equal to 5.0 mol.%. In some more embodiments, the glass composition may contain ZrO; in an amount greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 1.0 mol.% and less than or equal to 13.5 mol.%, greater than or equal to 2.5 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 4.0 mol.% and less than or equal to 9.0 mol.%, greater than or equal to 5.3 mol.% and less than or equal to 8.1 mol.%, greater than or equal to 5.6 mol.% and less than or equal to 8.0 mol.%, greater than or equal to 6.5 mol.% and less than or equal to 8.0 mol.%, greater than or equal to 6.8 mol.% and less than or equal to 7.79 mol.%, greater than or equal to 0.0 mol.% and less than or equal to

20.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.%, greater than or equal to 1.0 mol.% and less than or equal to 5.0 mol.%, greater than or equal to 2.5 mol.% and less than or equal to 5.0 mol.%, greater than or equal to 4.0 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 4.0 mol. % and less than or equal to 5.0 mol.%, greater than or equal to 5.6 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 5.6 mol.% and less than or equal to 7.8 mol.%.

[0062] Glass composition may include niobia (Nb.0Os). Niobia can be used to increase the refractive index of glass while maintaining a low density. However, niobia can introduce a yellow coloring to the glass that cannot be bleached in the same manner as titania, which can result in a loss of transmittance in the blue and UV range. Niobia may cause crystallization and/or phase separation of the melt. in some embodiments, the glasses may be substantially free of NbzOs. In embodiments, the glass composition may contain niobia (Nb2Os) in an amount from greater than or equal to 0.0 mol.% to less than or equal to 70.0 mol.% and all ranges and sub-ranges between the foregoing values. In some embodiments, the glass composition may contain Nb.Os in an amount greater than or equal to 0.0 mol.%, greater than or equal to 0.5 mol.%, greater than or equal to 2.5 mol.%, greater than or equal to 4.5 mol.%, greater than or equal to 5.0 mol.%, greater than or equal to 6.79 mol.%, greater than or equal to 10.0 mol.%, greater than or equal to 40.0 mol.%, greater than or equal to 50.0 mol.%, or greater than or equal to 60.0 mol.%. In some other embodiments, the glass composition may contain Nb,Os in an amount less than or equal to 70.0 mol.%, less than or equal to 60.0 mol.%, less than or equal to 50.0 mol.%, less than or equal to 40.0 mol.%, less than or equal to 30.0 mol.%, less than or equal to 10.0 mol.%, less than or equal to 9.25 mol.%, less than or equal to 8.6 mol.%, less than or equal to 7.7 mol.%, or less than or equal to 6.7 mol.%. In some more embodiments, the glass composition may contain Nb,Os in an amount greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 0.5 mol.% and less than or equal to 30.0 mol.%, greater than or equal to 2.5 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 4.5 mol.% and less than or equal to 9.25 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 6.7 mol.%, greater than or equal to 5.1 mol.% and less than or equal to 8.6 mol.%, greater than or equal to 6.79 mol.% and less than or equal to 7.7 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 70.0 mol.%, greater than or equal to 2.5 mol.% and less than or equal to 70.0 mol.%, greater than or equal to 2.5 mol.% and less than or equal to 6.7 mol.%, greater than or equal to 4.5 mol.% and less than or equal to 6.7 mol.%, greater than or equal to 6.79 mol.% and less than or equal to 70.0 mol.%, greater than or equal to 10.0 mol.% and less than or equal to 30.0 mol.%.

[0063] Glass composition may include bismuth oxide (Bi;Os). Bi,03 provides very high refractive index but leads to increase in density. it may also decrease the viscosity of melts at high temperatures, which may cause crystallization of the melts when cooling. Accordingly, the content of bismuth oxide should be limited, or glass compositions may be free of Bi203. In embodiments, the glass composition may contain bismuth oxide (Bi203) in an amount from greater than or equal to 0.0 mol.% to less than or equal to 25.0 mol.% and all ranges and sub-ranges between the foregoing values. In some embodiments, the glass composition may contain Bi203 in an amount greater than or equal to 0.0 mol.%, greater than or equal to 0.1 mol.%, greater than or equal to 5.0 mol.%, greater than or equal to 10.0 mol.%, greater than or equal to 19.0 mol.%, greater than or equal to 20.0 mol.%, greater than or equal to 21.0 mol.%, or greater than or equal to 23.0 mol.%. In some other embodiments, the glass composition may contain

Bi20: in an amount less than or equal to 25.0 mol.%, less than or equal to 23.0 mol.%, less than or equal to 21.0 mol.%, less than or equal to 20.0 mol.%, less than or equal to 19.0 mol.%, less than or equal to 10.0 mol.%, less than or equal to 9.2 mol.%, or less than or equal to 5.0 mol.%. In some more embodiments, the glass composition may contain Bi203 in an amount greater than or equal to 0.0 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 0.1 mol.% and less than or equal to 25.0 mol.%, greater than or equal to 0.12 mol.% and less than or equal to 9.15 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 25.0 mol.%, greater than or equal to 0.1 mol.% and less than or equal to 5.0 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 9.2 mol.%, greater than or equal to 19.0 mol.% and less than or equal to 20.0 mol.%.

[0064] Glass composition may include titania (TiO). The levels of TiO; and/or Nb20; that are typically used in glasses to increase refractive index tend to decrease the transmittance in the near-UV region and shift the UV cut-off to higher wavelengths. Accordingly, the amount of TiO; is limited. In embodiments, the glass composition may contain titania (TiO) in an amount from greater than or equal to 0.0 mol.% to less than or equal to 39.1 mol.% and all ranges and sub-ranges between the foregoing values. In some embodiments, the glass composition may contain TiO, in an amount greater than or equal to 0.0 mol.%, greater than or equal to 0.3 mol.%, greater than or equal to 5.0 mol.%, greater than or equal to 12.0 mol.%, greater than or equal to 15.0 mol.%, greater than or equal to 20.0 mol.%, greater than or equal to 20.25 mol.%, greater than or equal to 22.0 mol.%, greater than or equal to 23.7 mol.%, greater than or equal to 24.1 mol.%, greater than or equal to 29.1 mol.%, or greater than or equal to 34.1 mol.%. In some other embodiments, the glass composition may contain TiO: in an amount less than or equal to 39.1 mol.%, less than or equal to 35.0 mol.%, less than or equal to 34.1 mol.%, less than or equal to 31.4 mol.%, less than or equal to 29.1 mol.%, less than or equal to 27.5 mol.%, less than or equal to 26.0 mol.%, less than or equal to 25.5 mol.%, less than or equal to 25.0 mol.%, less than or equal to 24.1 mol.%, less than or equal to 20.0 mol.%, or less than or equal to 5.0 mol.%. In some more embodiments, the glass composition may contain TiO2 in an amount greater than or equal to 0.3 mol.% and less than or equal to 35.0 mol.%, greater than or equal to 12.0 mol.% and less than or equal to 35.0 mol.%, greater than or equal to 15.0 mol.% and less than or equal to 35.0 mol.%, greater than or equal to 20.0 mol.% and less than or equal to 27.5 mol.%, greater than or equal to 20.25 mol.% and less than or equal to 26.0 mol.%, greater than or equal to 20.25 mol.% and less than or equal to 25.5 mol.%, greater than or equal to 22.0 mol.% and less than or equal to 25.0 mol.%, greater than or equal to 23.7 mol.% and less than or equal to 31.35 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 39.1 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.%, greater than or equal to 0.3 mol.% and less than or equal to 5.0 mol.%, greater than or equal to 12.0 mol.% and less than or equal to 39.1 mol.%, greater than or equal to 12.0 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 15.0 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 20.0 mol.% and less than or equal to 24.1 mol.%, greater than or equal to 20.25 mol.% and less than or equal to 24.1 mol.%.

[0065] Glass composition may include fluorine (F). Adding fluorine to a glass composition is known to provide lower optical dispersion, which may improve the image quality. Also, fluorine can in some cases decrease the liquidus temperature, preventing a glass article from crystallization when cooling the melt.

However, fluorine may raise ecological concerns. For that reason, the content of fluorine is limited, or glasses are free of fluorine. In embodiments, the glass composition may contain fluorine (F} in an amount from greater than or equal to 0.0 at.% to less than or equal to 2.0 at.% and all ranges and sub- ranges between the foregoing values. In some other embodiments, the glass composition may contain F in an amount less than or equal to 2.0 at.%, less than or equal to 1.0 at.%, or less than or equal to 0.1 at.%. In some more embodiments, the glass composition may contain F in an amount greater than or equal to 0.0 at.% and less than or equal to 2.0 at.%, greater than or equal to 0.0 at.% and less than or equal to 0.1 at.%.

[0066] In some embodiments, the glass composition may have a sum of La203 +Ti0; +B20:3 +502 +ZrO2 +Nb20s greater than or equal to 97.0 mol.%, greater than or equal to 98.0 mol.%, or greater than or equal to 99.0 mol.%. In some more embodiments, the glass composition may have a sum of La203 +T1O2 +B,03 +Si02 +ZrO: +ND20s greater than or equal to 97.0 mol.% and less than or equal to 100 mol.%.

[0067] In some embodiments, the glass composition may have a sum of La203 +Ti0; +B20:3 +502 +ZrO2 +Nb20s; +Ba0 +Y203 +Ca0 +Ga203 +Gd203 +Zn0 +WO3 +CeO: +SrO +Na20 +Ta20s +Al20:3 greater than or equal to 99.0 mol.%, or greater than or equal to 99.5 mol.%. In some more embodiments, the glass composition may have a sum of La;03 +Ti0; +B20:3 +Si0; +ZrO: +Nb20; +Ba0 +Y203 +Ca0 +Ga203 +Gd:0; +Zn0 +WO0; +Ce0; +5rO +Na 0 +Ta20s +Al;0:3 greater than or equal to 99.0 mol.% and less than or equal to 100 mol.%.

[0068] In some embodiments, the glass composition may have a sum of La203 +Y203 +Gd20: +TiO; +B20: +Si02 +ZrO: +ND20s greater than or equal to 99.0 mol.%, or greater than or equal to 99.5 mol.%. In some more embodiments, the glass composition may have a sum of La203 +Y203 +Gd;03 +TiO02 +B,0; +5i0; +ZrO2 +Nb20s greater than or equal to 99.0 mol.% and less than or equal to 100 mol.%.

[0069] In some embodiments, the glass composition may have a sum of La203 +Y203 +Gd20: +702 +B,0; +5i0; +ZrO2 +Nb,0s +Ca0 +Ba0 greater than or equal to 99.0 mol.%, or greater than or equal to 99.5 mol.%. In some more embodiments, the glass composition may have a sum of La20:3 +Y20:3 +Gd203 +TiO2 +B203 +Si0; +ZrO2 +Nb2Os +Ca0 +Ba0 greater than or equal to 99.0 mol.% and less than or equal to 100 mol.%.

[0070] In some embodiments, the glass composition may have a sum of R20+RO greater than or equal to 0.0 mol.%, greater than or equal to 2.5 mol.%, or greater than or equal to 5.0 mol.%. in some other embodiments, the glass composition may have a sum of R20+RO less than or equal to 6.0 mol.%, less than or equal to 5.0 mol.%, less than or equal to 2.5 mol.%, or less than or equal to 1.0 mol.%. in some more embodiments, the glass composition may have a sum of R20+RO greater than or equal to 0.0 mol.% and less than or equal to 6.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 1.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 2.5 mol.%, greater than or equal to 2.5 mol.% and less than or equal to 6.0 mol.%, or greater than or equal to 2.5 mol.% and less than or equal to 5.0 mol.%.

[0071] In some embodiments, the glass composition may have a sum of RE,O,+WQO3+ZrQ, greater than or equal to 0.0 mol.%, greater than or equal to 4.5 mol.%, greater than or equal to 5.0 mol.%, greater than or equal to 20.0 mol.%, or greater than or equal to 32.0 mol.%. In some other embodiments, the glass composition may have a sum of RE; 0,+WO3+Zr0; less than or equal to 36.0 mol.% or less than or equal to 20.0 mol.%. In some more embodiments, the glass composition may have a sum of

REnO,+WO3+Zr0; greater than or equal to 0.0 mol.% and less than or equal to 36.0 mol.%, or greater than or equal to 0.0 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 4.5 mol.% and less than or equal to 36.0 mol.%, or greater than or equal to 4.5 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 5.0 mol.% and less than or equal to 36.0 mol.%, or greater than or equal to 5.0 mol.% and less than or equal to 20.0 mol.%.

[0072] in some embodiments, the glass composition may have a sum of Si0,+B;0; greater than or equal to 0.0 mol.%, or greater than or equal to 10.0 mol.%.

[0073] In some embodiments, the glass composition may have a sum of SiO02+Y203+Gd:0: greater than or equal to 0.0 mol.%, greater than or equal to 0.3 mol.%, greater than or equal to 8.7 mol.%, or greater than or equal to 10.0 mol.%. In some other embodiments, the glass composition may have a sum of

SiO2+Y203+Gd:0;3 less than or equal to 15.9 mol.% or less than or equal to 10.0 mol.%. In some more embodiments, the glass composition may have a sum of SiO:+Y203+Gd20: greater than or equal to 0.0 mol.% and less than or equal to 15.9 mol.%, or greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 0.3 mol.% and less than or equal to 15.9 mol.%, or greater than or equal to 0.3 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 8.7 mol.% and less than or equal to 15.9 mol.%.

[0074] In some embodiments, the glass composition may have a sum of TiO2+Nb20Os greater than or equal to 0.0 mol.%, greater than or equal to 8.5 mol.%, greater than or equal to 20.0 mol.%, greater than or equal to 25.0 mol.%, or greater than or equal to 40.0 mol.%. In some other embodiments, the glass composition may have a sum of TiO2+Nb;Os less than or equal to 42.0 mol.%, less than or equal to 40.0 mol.%, less than or equal to 38.0 mol.%, or less than or equal to 20.0 mol.%. In some more embodiments, the glass composition may have a sum of TiO2+Nb20s greater than or equal to 0.0 mol. % and less than or equal to 42.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 40.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 38.0 mol.%, or greater than or equal to 0.0 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 8.5 mol.% and less than or equal to 42.0 mol.%, greater than or equal to 8.5 mol.% and less than or equal to 40.0 mol.%, greater than or equal to 8.5 mol.% and less than or equal to 38.0 mol.%, or greater than or equal to 8.5 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 20.0 mol.% and less than or equal to 42.0 mol.%, greater than or equal to 20.0 mol.% and less than or equal to 40.0 mol.%, or greater than or equal to 20.0 mol.% and less than or equal to 38.0 mol.%, greater than or equal to 25.0 mol.% and less than or equal to 42.0 mol.%, greater than or equal to 25.0 mol.% and less than or equal to 40.0 mol.%, or greater than or equal to 25.0 mol.% and less than or equal to 38.0 mol.%.

[0075] In some embodiments, the glass composition may have a sum of TiO:+Nb20s+La203 greater than or equal to 0.0 mol.%, greater than or equal to 10.0 mol.%, greater than or equal to 45.0 mol.%, or greater than or equal to 50.0 mol.%. In some other embodiments, the glass composition may have a sum of TiO2+Nb20s5+La20: less than or equal to 70.0 mol.%, less than or equal to 63.0 mol.%, or less than or equal to 50.0 mol.%. In some more embodiments, the glass composition may have a sum of

TiO:+Nb20;5+La203 greater than or equal to 10.0 mol.% and less than or equal to 70.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 70.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 63.0 mol.%, or greater than or equal to 0.0 mol.% and less than or equal to 50.0 mol.%, greater than or equal to 10.0 mol.% and less than or equal to 63.0 mol.%, or greater than or equal to 10.0 mol.% and less than or equal to 50.0 mol.%, greater than or equal to 45.0 mol.% and less than or equal to 70.0 mol.%, greater than or equal to 45.0 mol.% and less than or equal to 63.0 mol.%, or greater than or equal to 45.0 mol.% and less than or equal to 50.0 mol.%.

[0076] In some other embodiments, the glass composition may have a sum of V20:;+Mo0O: less than or equal to 3.0 mol.%, less than or equal to 2.0 mol.%, or less than or equal to 1.0 mol.%. In some more embodiments, the glass composition may have a sum of V,0s+MoQs; greater than or equal to 0.0 mol.%

and less than or equal to 3.0 mol.%, greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.%, or greater than or equal to 0.0 mol.% and less than or equal to 1.0 mol. %.

[0077] in some embodiments, the glass composition may have a sum of WO3+Bi203 greater than or equal to 0.0 mol.%, or greater than or equal to 5.0 mol.%. In some other embodiments, the glass composition may have a sum of WO3+Bi20: less than or equal to 7.0 mol.% or less than or equal to 5.0 mol.%. In some more embodiments, the glass composition may have a sum of WO3+Bi203 greater than or equal to 0.0 mol.% and less than or equal to 7.0 mol.%, or greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.%.

[0078] In some embodiments, the glass composition may have a sum of ZrO+HfO, greater than or equal to 0.0 mol.%, or greater than or equal to 1.0 mol.%.

[0079] In some embodiments, the glass composition may have a sum of 5i02+B203+P20; greater than or equal to 10.0 mol.%, greater than or equal to 20.0 mol.%, greater than or equal to 26.0 mol.%, or greater than or equal to 30.0 mol.%. In some other embodiments, the glass composition may have a sum of Si02+B203+P2O; less than or equal to 31.0 mol.%, less than or equal to 30.0 mol.%, or less than or equal to 20.0 mol.%. In some more embodiments, the glass composition may have a sum of

Si02+B203+P20; greater than or equal to 10.0 mol.% and less than or equal to 31.0 mol.%, greater than or equal to 10.0 mol.% and less than or equal to 30.0 mol.%, or greater than or equal to 10.0 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 20.0 mol.% and less than or equal to 31.0 mol.%, or greater than or equal to 20.0 mol.% and less than or equal to 30.0 mol.%, greater than or equal to 26.0 mol.% and less than or equal to 31.0 mol.%, or greater than or equal to 26.0 mol.% and less than or equal to 30.0 mol.%.

[0080] In some embodiments, glass composition may have limitations for SiO02+B20:-P20s. The difference (SiO:+B203-P20s) indicates the primary glass formers. If this difference is positive, BO; and/or

SiO2 may be used as primary glassformer(s); if the difference is negative then the primary glass former may be P,0s. In preferred embodiments of the present disclosure, the difference (SiO02+B203-P20s) is zero or positive. In some embodiments, the glass may have a difference Si02+B203-P20; greater than or equal to 0 mol.%, greater than or equal to 0.1 mol.%, greater than or equal to 1.0 mol.%, greater than or equal to 10.0 mol.%, greater than or equal to 20.0 mol.%, greater than or equal to 26.0 mol.%, or greater than or equal to 30.0 mol.%. In some other embodiments, the glass may have a difference

SiO2+B20:-P20s less than or equal to 31.0 mol.%, less than or equal to 30.0 mol.%, less than or equal to 20.0 mol.%, or less than or equal to 10.0 mol.%. In some more embodiments, the glass may have a difference SiO2+B20:3-P20s; greater than or equal to 0 mol.% and less than or equal to 31.0 mol.%, greater than or equal to 0 mol.% and less than or equal to 30.0 mol.%, greater than or equal to O mol.% and less than or equal to 20.0 mol.%, or greater than or equal to 0 mol.% and less than or equal to 10.0 mol.%,

greater than or equal to 0.1 mol.% and less than or equal to 31.0 mol.%, greater than or equal to 0.1 mol.% and less than or equal to 30.0 mol.%, greater than or equal to 0.1 mol.% and less than or equal to 20.0 mol.%, or greater than or equal to 0.1 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 1.0 mol.% and less than or equal to 31.0 mol.%, greater than or equal to 1.0 mol.% and less than or equal to 30.0 mol.%, greater than or equal to 1.0 mol.% and less than or equal to 20.0 mol.%, or greater than or equal to 1.0 mol.% and less than or equal to 10.0 mol.%, greater than or equal to 10.0 mol.% and less than or equal to 31.0 mol.%, greater than or equal to 10.0 mol.% and less than or equal to 30.0 mol.%, or greater than or equal to 10.0 mol.% and less than or equal to 20.0 mol.%, greater than or equal to 20.0 mol.% and less than or equal to 31.0 mol.%, or greater than or equal to 20.0 mol.% and less than or equal to 30.0 mol.%.

[0081] in some embodiments, glass composition may have limitations for a ratio SiO02/(Si02+B20:3). It has been empirically found that SiO; and B,03, when being presented together in a glass composition, may improve the glass forming ability of a melt and protect it from the liquid-liquid phase separation.

Higher values of the ratio SiO2/(Si02+B20:) may help to improve the chemical durability, whereas lower values of this ratio may improve the solubility of the high index components. In some embodiments, the glass may have a ratio SiO2/{Si02+B203}mol.% greater than or equal to 0.0, greater than or equal to 0.38, or greater than or equal to 0.5. In some other embodiments, the glass may have a ratio

SiO2/{Si0:+B203}mol.% less than or equal to 0.75, less than or equal to 0.5, or less than or equal to 0.4.

In some more embodiments, the glass may have a ratio SiO0>/{(Si02+B20:}mol.% greater than or equal to 0.0 and less than or equal to 0.4, greater than or equal to 0.38 and less than or equal to 0.75, greater than or equal to 0.0 and less than or equal to 0.75, greater than or equal to 0.0 and less than or equal to 0.5, greater than or equal to 0.38 and less than or equal to 0.5, or greater than or equal to 0.38 and less than or equal to 0.4.

[0082] In some embodiments, glass composition may have limitations for a ratio

Ti0;/(Ti02+Nb20:+WO3+Bi203}). The ratio TiO2/(Ti0;+Nb:0s+WO:+Bi203} determines the mole fraction of

TiO; in a total sum of components that provide highest refractive indexes. When the ratio

TiO2/(TiO02+Nb20:+WO3+Bi203) is too low, it may be difficult to reach low density at high refractive index.

When the ratio TiO2/(TiO2+Nb20:+WO3+Bi203) is too high, the glass melt may tend to phase separation or crystallization when cooling, or provide undesirable coloring that may decrease blue transmittance.

Typically, a higher ratio TiO2/(TiO02+Nb;0:+WO2+Bi,03} indicates a potentially higher refractive index at a given density, but lower blue transmittance. Accordingly, in some embodiments of the present disclosure it may be desirable to reach higher refractive indexes at a given ratio

TiO2/(TiO02+Nb20:+WO3+Bi203). In some embodiments, the glass may have a ratio

TiO2/{TiO:+Nb205+WO:+Bi203}mol.% greater than or equal to 0.05, or greater than or equal to 0.5. In some other embodiments, the glass may have a ratio TiO2/(TiO72+Nb205+WO3+Bi203}mol.% less than or equal to 0.8 or less than or equal to 0.5. In some more embodiments, the glass may have a ratio

TiO2/(TiO2+Nb205+WO;3+Bi20:}mol.% greater than or equal to 0.05 and less than or equal to 0.8, or greater than or equal to 0.05 and less than or equal to 0.5.

[0083] in some embodiments, glass composition may have limitations for a ratio La203/Ti02. The

La203/TiO2 ratio refers to two primary high index components, TiO; and La203. When the ratio

La203/TiO02 is low, the glass may have lower density, but also lower blue transmittance. When the ratio

La203/TiO2 is high, the glass may have higher blue transmittance, but also higher density. Also, if the ratio La,03/TiO; is very high or very low, in some cases the glass melt may tend to phase separation.

Accordingly, in some embodiments of the present disclosure, the ratio La203/TiO02 may be limited. In some embodiments, the glass may have a ratio La20s/TiO, greater than or equal to 0.75 mol.%, or greater than or equal to 1.2 mol.%. In some other embodiments, the glass may have a ratio La203/Ti02 less than or equal to 1.5 mol.%, less than or equal to 1.2 mol.%, or less than or equal to 0.94 mol.%. In some more embodiments, the glass may have a ratio La203/TiO; greater than or equal to 0.75 mol.% and less than or equal to 1.5 mol.%, greater than or equal to 0.75 mol.% and less than or equal to 1.2 mol.%, or greater than or equal to 0.75 mol.% and less than or equal to 0.94 mol.%.

[0084] In some embodiments, the glass may have a refractive index at 587.56 nm nq from greater than or equal to 1.950 to less than or equal to 2.150 and all ranges and sub-ranges between the foregoing values. In some embodiments, the glass may have a refractive index at 587.56 nm ng greater than or equal to 1.950, greater than or equal to 2.000, greater than or equal to 2.025, greater than or equal to 2.045, greater than or equal to 2.050, greater than or equal to 2.058, greater than or equal to 2.100, greater than or equal to 2.120, or greater than or equal to 2.140. In some other embodiments, the glass may have a refractive index at 587.56 nm ná less than or equal to 2.150, less than or equal to 2.140, less than or equal to 2.120, less than or equal to 2.100, less than or equal to 2.070, less than or equal to 2.050, or less than or equal to 2.000. In some more embodiments, the glass may have a refractive index at 587.56 nm na greater than or equal to 1.950 and less than or equal to 2.070, greater than or equal to 1.950 and less than or equal to 2.150, greater than or equal to 1.950 and less than or equal to 2.000, greater than or equal to 2.000 and less than or equal to 2.050, greater than or equal to 2.025 and less than or equal to 2.050, greater than or equal to 2.050 and less than or equal to 2.070, greater than or equal to 2.058 and less than or equal to 2.070.

[0085] in some embodiments, the glass may have a density at room temperature dx from greater than or equal to 4.50 g/cm? to less than or equal to 5.50 g/cm? and all ranges and sub-ranges between the foregoing values. In some embodiments, the glass may have a density at room temperature dgr greater than or equal to 4.50 g/cm}3, greater than or equal to 4.90 g/cm?, greater than or equal to 5.20 g/cm},

greater than or equal to 5.30 g/cm?, or greater than or equal to 5.40 g/cm?. In some other embodiments, the glass may have a density at room temperature dr less than or equal to 5.50 g/cm}, less than or equal to 5.40 g/cm}, less than or equal to 5.30 g/cm, less than or equal to 5.20 g/cm}3, or less than or equal to 4.90 g/cm3. In some more embodiments, the glass may have a density at room temperature dr: greater than or equal to 4.50 g/cm? and less than or equal to 5.50 g/cm?, greater than or equal to 4.50 g/cm? and less than or equal to 4.90 g/cm’, greater than or equal to 4.90 g/cm? and less than or equal to 5.50 g/cm?, greater than or equal to 4.90 g/cm? and less than or equal to 5.20 g/cm?3, greater than or equal to 5.20 g/cm? and less than or equal to 5.50 g/cm}, greater than or equal to 5.20 g/cm? and less than or equal to 5.30 g/cm}, greater than or equal to 5.30 g/cm? and less than or equal to 5.50 g/cm’, greater than or equal to 5.30 g/cm? and less than or equal to 5.40 g/cm.

[0086] In some embodiments, the glass may have a liquidus temperature Ty, less than or equal to 1260 °C.

[0087] in some embodiments, the glass may have a transmittance at a wavelength of 460 nm TXas0 nm, % greater than or equal to 70.

[0088] in some embodiments, the glass may have a quantity na - (1.765 + 0.057 * dg} greater than or equal to 0.000.

[0089] In some embodiments, the glass may have a quantity nq - (1.99 + 0.083 * (TiO, / (TiO2 + Nb205 +

WO; + Bi203}}} greater than or equal to 0.000.

[0090] In some embodiments, the glass may have a quantity nq - (2.005 + 0.083 * (TiO / (TiO2 + Nb20s +

WO; + Bi0s))) greater than or equal to 0.000.

[0091] Refractive index n4 and density der are properties of glass that can be predicted from the glass composition. A linear regression analysis of the Exemplary Glasses of the present disclosure in the

EXAMPLES section below and other glass compositions reported in the literature was performed to determine equations that can predict the composition dependences of the refractive index ng and the density der.

[0092] The training dataset of glass compositions satisfying the compositional limitations specified in

Table 1 below and having measured values of the properties of interest (ng and dr), about 100 glass compositions for each property (nq and der), were randomly selected from literature data presented in the publicly available SciGlass Information System database and from the Exemplary Glasses from the embodiments presented herein. The linear regression analysis on the above-specified dataset, with the exclusion of outliers, was used to determine the formulas (1) and (1!) presented in Table 2 below for predictive parameters P, and Pq that predict n4 and dsr, respectively. Another subset of glass compositions satisfying the compositional limitations of Table 1 was used as a validation set to evaluate the ability to interpolate within the compositional limitations of Table 1 and was used to establish to the standard deviations specified in the Table 2 for the predictive parameters P, and P4. An external dataset of prior art glass compositions, also randomly selected from the SciGlass Information System database, was used to evaluate the ability to predict the properties (ng and drt) outside of the compositional limits of Table 1 with reasonable accuracy. Multiple iterations of this process were performed in order to determine the best formula for each property (nq and der}. Formulas (I) and (1!) in Table 2 are the result of the analysis.

[0093] The data for the Comparative Glass compositions used in the linear regression modeling, including the training dataset, validation dataset and external dataset were obtained from the publically available SciGlass Information System database. Formulas (1) and (ll) below were obtained from the linear regression analysis:

Pa= 1.844 + 0.0054162 * La203 + 0.0031113 * TiO, - 0.004212 * B,03 - 0.0035692 * SiO, + 0.0027887 * ZrO, + 0.0078026 * Nb20; - 0.00012928 * CaO + 0.00076566 * BaO + 0.0043601 * Y203 + 0.00067408 * ZnO + 0.0068029 * Gd,0s - 0.0025106 * Na20 + 0.0039937 * WO; - 0.0043208 *

Al203 - 0.0011666 * Li;O + 0.0051727 * PbO + 0.012958 * Bi;0s - 0.0018753 * GeO; - 0.0014084 * 0

MgO,

Pa = 4.688 + 0.047868 * La203 - 0.0065829 * TiO, - 0.027601 * B203 - 0.022365 * SiO, + 0.016475 *

Zr0; - 0.0052977 * Nb20s - 0.0030466 * CaO + 0.014971 * BaO + 0.019511 * Y203 + 0.0076377 *

ZnO + 0.066160 * Gd;03 - 0.016932 * Na 0 + 0.025764 * WO; - 0.035116 * ALO; - 0.0094315 * Li,O (11) + 0.047388 * PbO + 0.080813 * Bi,03- 0.0088118 * GeO; + 0.072296 * Er,0; + 0.078888 * Yb,03 - 0.026242 * K;0 + 0.010351 * SrO - 0.0030424 * MgO.

[0094] in Formulas (1) and (11) and Tables 1 and 2, P, is a predictive parameter that predicts the refractive index at 587.56 nm, ng, calculated from the components of the glass composition expressed in mol.%, and Py is a predictive parameter that predicts the density at room temperature, der, calculated from the components of the glass composition expressed in mol.%.

[0095] In Formulas (1) and (Il), each component of the glass composition is listed in terms of its chemical formula, where the chemical formula refers to the concentration of the component expressed in mol.%. For example, for purposes of Formulas {I} and (i), La2O:3 refers to the concentration of La,0s, expressed in mol.%, in the glass composition. it is understood that not all components listed in Formulas (1) and (11) are necessarily present in a particular glass composition and that Formulas (1) and (lf) are equally valid for glass compositions that contain less than all of the components listed in the formulas. It is further understood that Formulas (I) and (lf) are also valid for glass compositions within the scope and claims of the present disclosure that contain components in addition to the components listed in the formulas. if a component listed in Formulas {1} and (11) is absent in a particular glass composition, the concentration of the component in the glass composition is 0 mol.% and the contribution of the component to the value calculated from the formulas is zero.

Table 1. Composition Space Used for Modeling

Property Nd dr, g/cm?

Component limits Max, mol.% Max, mol.% : ae aa ea we ww ww

Cee |e [ow |e ow era ee {a err ara

Na20 0 10

FE a

ALO; 0 10 0 10

Ea

F 0 0.5 [at.%] 0 2 [at.%]

Other species 0 Not limited 0 Not limited 5

Table 2. Property prediction models

Property Abbreviation | Unit Predicting Regression Composition Standard

Refractive index Ny Pn Formula (1) Mol.% 0.017

EE a

Density at room drt g/cm? Formula (i) Mol.% 0.076

EEE I I a

[0096] FIG. 1 is a plot of the parameter P, calculated by Formula (1) as a function of measured refractive index ng for some Comparative Glasses {"Comp. Glasses") taken from the literature and some Exemplary

Glasses ("Ex. Glasses"). As illustrated by the data in FIG. 1, the compositional dependence of the parameter P, had a standard deviation within a range of + 0.017 unit of the measured n4 for the majority of glasses, which corresponds to the standard error specified in Table 2.

[0097] FIG. 2 is a plot of the parameter Pq calculated by Formula (if) as a function of measured density drr for some Literature Glasses ("Comp. Glasses") and some Exemplary Glasses ("Ex. Glasses"). As illustrated by the data in FIG. 2, the compositional dependence of the parameter P4 had a standard deviation within a range of + 0.076 unit of the measured dhr for the majority of glasses, which corresponds to the standard deviation specified in Table 2.

[0098] Table 3 identifies the combination of components and their respective amounts according to some embodiments of the present disclosure. The Exemplary Glasses A in Table 3 may include additional components according to any aspects of the present disclosure as described herein. in Table 3, RmO, is a total sum of all oxides.

Table 3: Exemplary Glasses A

B203 0.5 to 40.0 mol.%

ALO; 0.0 to 10.0 mol.%

V20s5 0.0 to 5.0 mol.%

[0099] Exemplary Glasses A according to embodiments of the present disclosure may satisfy the following condition:

SiO:+B203-P20Os [mol.%] > 0.000, where chemical formulas refer to the amounts of components in glass, expressed in mol.%.

[00100] According to some embodiments of the present disclosure, Exemplary Glasses A may also satisfy the following condition: ng - {1.765 + 0.057 * dar) > 0.000, where ny is a refractive index at 587.56 nm, and dr is a density at room temperature.

[00101] Table 4 identifies the combination of components and their respective amounts according to some embodiments of the present disclosure. The Exemplary Glasses B in Table 4 may include additional components according to any aspects of the present disclosure as described herein. In

Tables 4 and 5, REmO, is a total sum of all rare earth oxides

Table 4: Exemplary Glasses B 0,3 to 29.5 mol.% 0.0 to 9.0 mol.%

[00102] Exemplary Glasses B according to embodiments of the present disclosure may optionally fluorine (F} in an amount 0.0 to 2.0 at. %.

[00103] According to some embodiments of the present disclosure, Exemplary Glasses B may also satisfy the following condition:

TiO2/{Ti0;+Nb20:+WO:+Bi203) [mol.%] = 0.050, where chemical formulas refer to the amounts of components in glass, expressed in mol.%.

[00104] According to some embodiments of the present disclosure, Exemplary Glasses B may also satisfy the following condition:

SiO2+B203-P20Os [mol.%] > 1.0, where chemical formulas refer to the amounts of components in glass, expressed in mol.%.

[00105] According to some embodiments of the present disclosure, Exemplary Glasses B may also satisfy the following condition:

La203/TiO2 fmol.%} < 1.5, where chemical formulas refer to the amounts of components in glass, expressed in mol.%.

[00106] According to some embodiments of the present disclosure, Exemplary Glasses B may also satisfy the following condition: na - (1.99 + 0.083 * (TiO: / (TiO2 + Nb20s + WO; + Bi203))) > 0.000, where nq is a refractive index at 587.56 nm.

[00107] According to some embodiments of the present disclosure, Exemplary Glasses B may also satisfy the following condition: ne - (2.005 + 0.083 * (TiO / (TiO2 + Nb0s + WO:3 + Biz03))) > 0.000, where nq is a refractive index at 587.56 nm.

[00108] Table 5 identifies the combination of components and their respective amounts according to some embodiments of the present disclosure. The Exemplary Glasses C in Table 5 may include additional components according to any aspects of the present disclosure as described herein.

Table 5: Exemplary Glasses C

[00109] Exemplary Glasses C according to embodiments of the present disclosure may satisfy the following condition:

SiO:+B203-P20s [mol.%4] > 0.100, where chemical formulas refer to the amounts of components in glass, expressed in mol.%.

[00110] According to some embodiments of the present disclosure, Exemplary Glasses C may also have a refractive index at 587.56 nm nq of greater than or equal to 2.045.

EXAMPLES

[00111] The following examples describe various features and advantages provided by the disclosure, and are in no way intended to limit the invention and appended claims.

[00112] To prepare the glass samples for some exemplary glasses of the present disclosure, about 15 grams of each sample (content of intended components in the as-batched compositions was more than 99.99 wt %) was melted from batch raw materials at a temperature of about 1300 °C in platinum or platinum-rhodium crucibles (Pt:Rh=80:20} for 1 hour. One of two controlled cooling conditions were applied. In the first condition (referred to as "15 min test” or "15 min devit test"}, the cooling conditions were controlled so that it took about 15 min for the samples to cool from 1100 °C to 500 °C in air inside a furnace. In the second condition (referred to as "2.5 min test" or "2.5 min devit test"), the cooling conditions were controlled so that it took about 2.5 min for the samples to cool from 1100 °C to 500 °C in air inside a furnace. Temperature readings were obtained by direct reading of the furnace temperature or using an IR camera reading with calibration scaling. The first condition (15 min test) approximately corresponds to a cooling rate of up to 300 °C/min at a temperature of 1000°C and the second test approximately corresponds to a cooling rate of up to 600 °C/min at 1000 °C. The temperature of 1000 °C corresponds approximately to the temperature at which the cooling rate was expected to approach a maximum. When the temperature is lower, the cooling rate also decreases significantly. Typical schedules of the first and second cooling regimes are shown in FIG. 3. For these samples, observations referred to as ”15-min devit test” and "2.5-min devit test", are specified in Table 6 below; the observation "1" is used to denote that a glass composition passed the indicated devit test, where a composition is deemed to have passed the indicated devit test if a melt of the composition forms a glass free of crystals visible under an optical microscope under magnification from 100x to 500x.

The observation "0" is used to denote that a glass composition failed the indicated devit test.

[00113] To prepare other glass samples for exemplary glasses of the present disclosure, unless otherwise specified, a one kilogram batch of the components was prepared in a pure platinum crucible.

The crucible was placed in a furnace set at a temperature of 1250°C, the temperature in the furnace was then raised to 1300°C and held at 1300°C for 2 hours. The furnace temperature was then reduced to 1250°C and the glass was allowed to equilibrate at this temperature for an hour before being poured on a steel table and annealed at Tg for an hour.

[00114] Some sample melts were also melted in a "one liter" platinum crucible heated by the

Joule effect. In this process, approximately 3700 g of raw materials (components as batched) was used.

The crucible was filled with the batch components in 1.5 hours at 1250°C. The temperature was then raised to 1300°C and held for one hour. During this step, the glass melt was continuously stirred at 60 rpm. The temperature was then decreased to 1200°C where the melt was allowed to equilibrate for 30 minutes and the stirring was continued at a rate of 20 rpm. A delivery tube was heated at 1225°C and the glass melt was cast on a cooled graphite table to form the glass. The glass was formed into a bar of approximately 25 mm in thickness, 50 mm in width, and 90 cm in length. The bars were inspected under an optical microscope to check for crystallization and were all crystal free. The glass quality observed under the optical microscope was good with the bars being free of striae and bubbles. The glass was placed at about Tg in a lehr oven for 1 hour for a rough annealing. The bars were then annealed in a static furnace for one hour at about Tg and the temperature was then lowered at 1°C/min,

[00115] Some of samples were bleached after melting to improve the transmittance. The bleaching process was performed at the temperatures between 500°C and Ty, the crystallization onset temperature. When the bleaching temperature is less than about 500°C, the rate of bleaching is slow and time required for bleaching is too long to be practical. When the bleaching temperature exceeds Ty, the glass may crystallize when heat treating. The higher the bleaching temperature, the faster the rate of the bleaching process, but lower transmittance is typically observed when bleaching at fast rates.

Accordingly, the temperature and time of bleaching was selected to come to an acceptable transmittance within a reasonable time, such as less than or equal to 24 hours, or less than or equal to 48 hours, or less than or equal to 96 hours, or like. Before bleaching, the glasses were heated from room temperature to the bleaching temperature at a rate from 3 to 5 °C/min, After bleaching, the glasses were cooled from the bleaching temperature to the room temperature at a rate from 1 to 3 °C/min.

[00116] No chemical analysis of the tested samples was performed because chemical analysis was performed for similar samples prepared in independent meltings by XRF (X-ray fluorescence - for all oxides, except for B203 and Li20)}, by ICP-OES (inductively coupled plasma optical emission spectroscopy - for B20:3) and by FES (flame emission spectroscopy - for Li20). These analyses gave deviations from the batched compositions within £2.0 mass %.

[00117] Some Exemplary Glasses were exposed to Nanostrip 2X cleaning solution. Dried glass samples were submerged in 600 ml of Nanostrip 2X solution (Capitol Scientific, 85% H.S0 and <1%

H202} for 50 min at 70°C while stirring at 400 rpm. The ratio of surface area to volume of the glass samples used in this test was 0.08 cm’. After 50 minutes, the samples were quenched in deionized water and rinsed in 18 MQ water, and then dried by high-pure nitrogen gas and placed in a desiccator overnight. Weight loss normalized to surface area (mg/cm?) and weight loss percentage (wt%) were calculated.

[00118] in Tables 6 and 7, the abbreviation "n" with a subscript refers to the refractive index at a corresponding wavelength in nm; for example, n632.8 nm refers to the refractive index at wavelengths of 632.8 nm.

Table 6. Exemplary Glass Compositions

TiO: / (TiO: + Nb20s + WO: + mol.% | 0.8242 | 0.8242 | 0.8149 | 0.8149 | 0.8242 | 0.8243 | 0.8243 0.8241 aay TE [pw pes TTT

Predicted and calculated properties [Ferns EE [ous [on ows [nek [so [own

Py - (1.765 + 0.057 * Po) 0.0086 | 0.0099 | 0.0082 | 0.0089 | 0.0157 | 0.0188 | 8.800E- | 3.300E- rn | LE

Pa - (1.99 + 0.083 * (TiO2 / (TiO: 0.0088 | 0.0112 | 0.0165 | 0.0179 | 0.0211 | 0.0262 | -0.0019 | 0.0028 wooo

Pa - (2.005 + 0.083 * (TiO: / (TiO2 0.0062 | -0.0038 | 0.0015 | 0.0029 | 0.0061 | 0.0112 | -0.0169 | 0.0122 moronen

Table 6 Continued

Composition - mol.% owl EEE

TiO: / (TiO2 + Nb20s + WO; | mol.% | 0.7835 0.7763 0.7245 | 0.6728 0.7259 | 0.7745 | 0.8146 0.7982 a, OO ee] ae sw

Gan | |]

Predicted and calculated properties

Pu - (1.765 + 0.057 * Pg) -6.500E~ | -8.900E~ | -0.0029 | 0.0049 0.0204 | 0.0107 | 3.400E- | 0.0082

EF Fo

Pa - (1.99 + 0.083 * (TiO2 / 5.800E- 0.0037 0.0097 | 0.0156 0.0440 | 0.0203 | 0.0013 0.0079 (Ti02 + Nb20s + WO: + 04

Bi20:)))

Pa - (2.005 + 0,083 * (T102/ -0.0144 -0.0113 -0.0053 | 5.700E- | 0.0290 | 0.0053 | -0.0138 -0.0071 (TiO2 + Nb20; + WO: + 04

Bi203)}))

Table 6 Continued

SiO2 + Y20: + Gd20; mol. % 7718 | 6.125 | 8.000

TiO2 / (TiO2 + Nb2Os + WO23 + | mol% | 0.5085 | 0.4888 | 0.4692 | 0.4995 0.4609 | 0.4932 | 0.4537 | 0.4858 vo le i er

Measured properties

Ein nL Bs ss

Gee [me

PoE ORR | ok | GO | ON | BOER OURS |Our | ee

Pa - (1.99 + 0.083 * (TiO: / 0.0137 | 0.0272 | 0.0190 | 0.0147 0.0233 | 0.0401 | 0.0514 | 0.07253 (TiO2 + Nb20s + WO: +

B03)

Pa - (2.005 + 0.083 * (TiO, / -0.0013 | 0.0122 | 0.0040 | -3.300E- | 0.0083 | 0.0251 | 0.0364 | 0.0375 (TiO2 + Nb:0: + WO: + 04

Bi203))

Table 6 Continued

Exemplary Glass 25 27 31 | 32

Composition - mol.%

ACI CN A CN I CO LI

57

En LC |v Jowu [vow omy [ows oe ow

TiO: / (TiO2 + Nb20s + WO: + mol.% | 0.4883 | 0.5404 | 0.7982 | 0.7148 | 0.8105 | 0.8160 | 0.8062 | 0.8179 oy aes 1 TT] TT 1

Predicted and calculated properties

Pa - (1.99 + 0.083 * (TiO2 / (TiO2 0.0068 | 0.0039 | 0.0079 | 0.0192 | 0.0050 | 0.0039 | 0.0056 | 0.0034 oen

Pn - (2.005 + 0.083 * (TiO: / (TiO -0.0082 | -0.0111 | -0.0071 | 0.0043 | -0.0100 | -0.0111 | -0.0094 | -0,0116

Table 6 Continued

Composition - mol.%

Wo fwwp poo mp [vv

TiO: / (TIO: + Nb20s + WO; + mol% | 0.8216 | 0.8335 | 0.8241 | 0.7600 | 0.7187 | 0.7232 | 0.7848 | 0.7746 oy Oe mol% | 0.7618 | 0.7769 0.7920

Be [sw TT

Ewen | | | rr

NC CA OO RE [ i | il ial

Pa - (1.99 + 0.083 * (TiO / (TiO: 0.0023 | 8.300E- | -0.0051 | 0.0172 | 0.0228 | 0.0265 | 0.0103 | 0.0129

Swoon | fo

Py - (2.005 + 0.083 * (Ti0: / (TiO2 20.0127 | 0.0149 | -0.0201 | 0.0022 | 0.0078 | 0.0115 | 0.0047 | 0.0021 aeron

Table 6 Continued

Composition - mol.%

Go wv vo Jv fom Jo Joy Jue ee Jo Jv Jv Jo Jer Jon fom

Composition constraints

TiO: / (TiO2 + Nb2Os + WO: + mol.% | 0.8069 | 0.7955 | 0.7874 | (0.7955 | 0.7994 | 0.8010 | 0.8013

Ll

Measured properties oen TT Tr TT TTT]

FJ [we em ww [ew [eww]

Fe | [ows [own [uv Joo | ower [owe won | ours

Pa - (1.99 + 0.083 * (TiO2 / (Ti0O2 0.0047 | 0.0088 | 0.0107 | 0.0088 | 0.0071 | 0.0038 | 0.0047 | 0.0054

JE ll

Pa - (2.005 + 0.083 * (TiO2/ -0.0103 | -0.0062 | -0.0043 | -0.0062 | -0.0079 | 0.0112 | 0.0103 | -0.0096 momorwmen

Table 6 Continued

Composition - mol.% io ooo foro Ti

Go 7 U vo jor [0 Jom |v Jue

Composition constraints

TiO: / (TiO2 + Nb2Os + WO: + mol.% | 0.8014 | 0.7995 | 0.8035 | 0.8035 | 0.8011 | 0.8014 | 0.7995 a

Measured properties pes de Ee ae ase lL

Eat Ci ET CTO Cn hn windeteson | fr pr pL ce ey rr ro pe me fw yr rr oe pee ee we]

Predicted and calculated properties esse | wo Tie [a fom ows

Pa - (1.99 + 0.083 * (T102/ (TiO: 0.0046 | 0.0051 | 0.0015 | 0.0026 | 0.0038 | 0.0046 | 0.0051 | 0.0054 aon

Exemplary Glass 6

Pa - (2.005 + 0.083 * (TiO2 / -0.0104 | ~0.0099 | ~0.0135 | ~0.0124 | 0.0112 | -0.0104 | -0.0099 | -0,0096 (TiO2 + Nb20: + WO; + Bi20s)))

Table 6 Continued

Composition - mol.% ome or fer fff

Composition constraints

TiO: / (TiO2 + Nb2Os + WO: + mol.% | 0.7998 | 0.7978 | 0.7993 | 0.7977 | 0.7955 | 0.6773 | 0.6286 | 0.8113 vo KH

Measured properties nn]

TC: Teme emery | [Tr rr z IE

Predicted and calculated properties

LT EE glen’ | 5.1167 | 3.1211 3.1281 5.1348

Pa - (1.765 + 0.057 * Py) 0.0057 | 0.0061 | 0.0064 | 0.0069 | 0.0073 | 0.0300 | 0.0398 | 4.000E-

Hd

Pa - (1.99 + 0.083 * (T102/ (TiO: 0.0060 | 0.0068 | 0.0071 | 0.0080 | 0.0088 | 0.0675 | 0.0914 | 7.400E- oenen

Pu - (2.005 + 0,083 * (TiO: / 0.0091 | ~0.0082 | ~0.0080 | ~0.0070 | ~0.0062 | 0.0525 | 0.0764 | 0.0143

I

Table 6 Continued @

Composition - mol.%

Lax Os mol.% | 24.03 22.70

Nb20s mol % | 6.79 5.00

We me

EE EC I EE EO x [= =

FORT | aw [aw aon

EO won oy anes [F008 05 C0 0: WO Bio | | eet | eet | wars

[00119] Table 7 below lists the glass compositions and properties for Comparative Glasses C1-

C32.

Table 7. Compositions and Properties of Comparative Example Glasses =] ALI LH al Li 212] {1] [2]

Composition - mol.%

c

Gow [i foo vv [oo Ju]

Ao wer a 0 [9 Jo JoJo] eo [mins oe 9 fo Jo [v0 co [aes jee [ojo ou] ae | sw | fe

Te || ww] Jem

ELL [| [meme |] oe [| [ee | an [ee

Fei To [om as [os Tver [ows aw [oo

Table 7 Continued

Kies | [A [A [a [an [A [A

Composition - mol.% oan [ea fv fo |v |v]

[Gowan fon [in Joa fo Jo sw [ow =p fo [ws Jo fos fo vv]

I A CC LA LE

[Tow [rows oe [0 EEE [| fe wow | won won mn | an

To [P| | me ew Pa [ope [ven | soo zo]

ET ee EE | To [7097 7003 [700 [200 281 == [ewe Lc ea ee Ei El EA ae a

Table 7 Continued

Kes | [HL [IE a

TiO; 2608 | 2608 | 1645 | 23.52 21.96

SiO: 2104 2104 | 4.48 3.89 1.66 eo [wa joo EE

Wo ww vivo Teo

Wo wm [or Jo Jo Jv |v Jv [we

REE A CC ae

Measured properties net ee 19729 | 1.9729 | 2.000 | L911 CC 2.0023 ee |e vee noe po gms mom |] [less 1986 2092] 120142 | 206043 nen) 19647 | 1.9647 | 1.9920 CC] 1.9951 | 2.0429

Predicted and calculated properties

Pa {for der] 4184 | 4184 | 4412 5715 | 5281 | 4.959

Table 7 Continued

Ks [A [Bn [Ml [ET me]

Ge [ae [oF [0 Jo Jv s ee a ee [se =p ee a [Eee a|n mor [wr]

Fw [www an a ww me [even || TOR | SUR [iE | | Saar | BRE

Predicted and calculated properties [Fifa | a [To [3 [a [To [so [Go [ao

[00120] The reference key for each of the Comparative Glasses listed in Table 7 is as follows: [1]

CN111320384A; [2] JP2020169116A; [3] JP6943995, [4] US20220073410A1; [5] U.S. Patent Application

Serial No. 17/683,527 (filed March 1, 2022); [6] US4584279A; [7] US9169152B2; {8] US9302930B2; [9]

US9643880B2; [10] WO2019131123A1; [11] JP2021102549A; [12] US8852745B2; [13] wO2014057584A1; [14] WO2021171950A1; [15] JPHO9278480; [16] US20220073410A1; [17]

TW202012333; [18] US5747397A; [19] JP2006151758A; [20] JPS6033229; [21] US9487432B2.

[00121] FIG. 4 is a plot showing the relationship between the parameter Pa that predicts density at room temperature and the parameter P, that predicts refractive index at 587.56 nm for some of the

Exemplary Glasses and some of the Comparative Glasses. The Exemplary Glasses (filled circles) are the

Examples 1 to 4, 7, 8, 13 to 16, 27 to 34 and 51 to 66 from Table 6. The Comparative Glasses (open circles) are the Examples C1 to C10 from Table 7. The parameter P4 that predicts density at room temperature was determined according to Formula {lt}. The parameter P, that predicts refractive index at 587.56 nm was determined according to Formula (1). All of the Exemplary Glasses and Comparative

Glasses shown in FIG. 4 have the features specified in Table 8. in Table 8, the specification "Not limited" refers to a limitation that was not considered when selecting the compositions.

Table 8. Limitations for glass compositions shown in FIGS 4 and 5

Component Unit | Min :

B203 mol.% | 0.5 40 : oma >

Al, Os mol.% 10 nfs io va ew ease ease 5

DE es I ee [3 [ed [Gree [| © [rio

[00122] The Comparative Glasses of FIG. 4 were selected as having the highest value of the parameter P, over the range of values of the parameter Py shown in FIG. 4 among the known glasses that have the features specified in Table 8.

[00123] The line corresponding to the formula y = 1.765 + 0.057 * x shown in FIG. 4 provides a visual representation of the differences between the Comparative Glasses having the features specified in Table 8 and the Exemplary Glasses 1 to 4, 7, 8, 13 to 16, 27 to 34 and 51 to 66. As can be seen in FIG. 4, the mentioned Exemplary Glasses (filled circles) and none of the Comparative Glasses (open circles)

represented in FIG. 4 fall above the line y = 1.765 + 0.057 * x, where y corresponds to the parameter P, that predicts refractive index at 587.56 nm and x corresponds to the parameter P« that that predicts density at room temperature. In other words, some of the Exemplary Glasses and none of the

Comparative Glasses represented in FIG. 4 satisfy the following formula (IH):

Pn - (1.765 + 0.057 * Pg) > 0.00 (li)

[00124] The Exemplary Examples represented in FIG. 4 are, by prediction, superior in terms of the combination of Pa and P, to the best known Comparative Glasses that have the features specified in

Table 8.

[00125] FIG. 5 is a plot showing the relationship between the density at room temperature dgr and the refractive index at 587.56 nm nq for some of the Exemplary Glasses and some of the

Comparative Glasses. The Exemplary Glass (filled circle) is Example 2 from Table 6. The Comparative

Glasses (open circles) are the Examples C10 to C19 from Table 7. All of the Exemplary Glasses and

Comparative Glasses shown in FIG. 5 have the features specified in Table 8.

[00126] The Comparative Glasses of FIG. 5 were selected as having the highest measured values of the refractive index at 587.56 nm ng over the range of measured density at room temperature dgr shown in FIG. 5 among the known glasses that have the mentioned features specified in Table 8.

[00127] The line corresponding to the formula y = 1.765 + 0.057 * x shown in FIG. 5 provides a visual representation of the differences between the Comparative Glasses having the features specified in Table 8 and the Exemplary Glass 2. As can be seen in FIG. 5, the mentioned Exemplary Glass (filled circles) and none of the Comparative Glasses (open circles) represented in FIG. 5 fall above the liney = 1.765 + 0.057 * x, where y corresponds to ng and x corresponds to dz. In other words, some of the

Exemplary Glasses and none of the Comparative Glasses represented in FIG. 5 satisfy the following formula (IV): ng - (1.765 + 0.057 * dry) > 0.00 (IV)

[00128] This means that, under the conditions specified in Table 8 above, some of the Exemplary

Glasses have higher measured values of the refractive index at 587.56 nm n4 at comparable measured values of the density at room temperature dr than the best of the Comparative Glasses satisfying the same conditions. This can be interpreted as these Exemplary Glasses, according to measurements, have higher values of ny at comparable values of drr among the glasses, i.e. they are, according to measurement, superior in terms of a combination of dg and ne (i.e. lower dr for a given nq or higher ng for a given der) to the best known Comparative Glasses that have the features specified in Table 8.

[00129] The values of all attributes specified in Table 8 and Formulas (iil) and (IV) for the

Comparative Glasses C1 to C19 plotted in FIGS 4 and 5 are presented in Table 9 below. Full compositions of the Comparative Glasses are presented in Table 7. Full compositions and attributes of the Exemplary

Glasses are presented in Table 6.

Table 9. Attributes of Comparative Example Glasses Having the Features Specified in

Table 8

For off

Wo wee ze oo Jo Jv oo] ;

Sow [fof wo wees [ov ov ojo Jv

AC 2 CH CN CB LC I U

JL ee TT cs

Predicted and calculated properties

Table 9 Continued

EE]

TT

Ee eee ee owas CO OO io ane Be CA KO LN

Ge [en [ow [a [sw [a [sm [oa] mew [ww eet Jon sew oes Jaw ng - (1.765 + 0.057 * der) 0.037 — Predicted and calculated properties

Table 9 Continued

ILC 2) CN CO LI

Measured properties na - (1.765 + 0.057 * der) 0.0198 | -0.0297

Predicted and calculated properties

Pa- (1.765 + 0.057 * Pg) 0.0622

[00130] As follows from FIG. 4 and 5, both predicted and measured property data confirms that some of the Exemplary Glasses have a better combination of density at room temperature dar and refractive index at 587.56 nm n4 than the best of the Comparative Glasses that have the features specified in Table 8.

[00131] TiO, provides high refractive index at a lower density than Nb20;, WO; and Bi203, but may adversely decrease the blue transmittance of glass. That is why in some embodiments of the present disclosure it is desirable to reach high refractive indexes, adding lower amount of TiO» comparing to other high index components. Accordingly, reaching higher refractive indexes at comparable values of the molar ratio TiO2/{TiO2+Nb20:5+WO:+Bi203) indirectly indicates a potential advantage in terms of blue transmittance in combination with high refractive index and low density.

[00132] FIG. 6 is a plot showing the relationship between the ratio TiO / (TiO2 + Nb20s + WO3 +

Bi203} and the predictive parameter P, for some of the Exemplary Glasses and some of the Comparative

Glasses. The Exemplary Glasses (filled circles) are the Examples 1 to 6, 8 to 19, 23, 25, 27 to 34 and 51 to 67 from Table 6. The Comparative Glasses (open circles) are the Examples C3, C7, C8 and C20 to C26 from Table 7. The parameter P, that predicts refractive index at 587.56 nm was determined according to

Formula (1). All of the Exemplary Glasses and Comparative Glasses shown in FIG. 6 have the features specified in Table 10. In Table 10, the specification "Not limited" refers to a limitation that was not considered when selecting the compositions.

Table 10. Limitations for glass compositions shown in FIGS. 6 and 7 wm few wv er ee 7 wea wees Jw 0 3 a Jw] 0 [www 0 i 0 [m0 wad

[00133] The Comparative Glasses shown in FIG. 6 were selected as having the highest value of the parameter P, that predicts refractive index at 587.56 nm over the range of the ratio TiO, / (TiO2 +

Nb2Os + WO; + Bi>03) shown in FIG. 6 among the known glasses that have the features specified in Table 10.

[00134] The line corresponding to the formula y = 1.99 + 0.083 * x shown in FIG. 6 provides a visual representation of the differences between the Comparative Glasses having the features specified in Table 10 and the Exemplary Glasses 1 to 6, 8 to 19, 23, 25, 27 to 34 and 51 to 67. As can be seen in

FIG. 6, the mentioned Exemplary Glasses (filled circles) and none of the Comparative Glasses (open circles) represented in FIG. 6 fall above the line y = 1.99 + 0.083 * x, where y corresponds to the parameter P, that predicts refractive index at 587.56 nm and x corresponds to the ratio TiO; / (TiO2 +

Nb20s + WO: + Bi203). In other words, some of the Exemplary Glasses and none of the Comparative

Glasses represented in FIG. 6 satisfy the following formula (V}{a):

Pa - (1.99 + 0.083 * TiO, / (TiO2 + Nb205 + WO; + Bi203)) > 0.00 (V)(a)

[00135] As can also be seen in FIG. 6, some of Exemplary Glasses and none of the Comparative

Glasses represented in FIG. 6 fall above the line y = 2.005 + 0.083 * x, where y corresponds to the parameter P, that predicts refractive index at 587.56 nm and x corresponds to the ratio TiO, / (TiO, +

Nb20Os + WO: + Bi203). In other words, some of the Exemplary Glasses and none of the Comparative

Glasses represented in FIG. 6 satisfy the following formula (V)(b):

Pn - (2.005 + 0.083 * TiO2 / (TiOz + Nb205 + WO; + Bi203)} > 0.00 (V){b)

[00136] The Exemplary Examples represented in FIG. 6 are, by prediction, superior in terms of the combination of the ratio TiO, / (TiO; + Nb2Os + WO: + Bi>03) and the predictive parameter P‚ (i.e. lower ratio for a given P, or higher P, for a given ratio) to the best known Comparative Glasses that have the features specified in Table 10.

[00137] FIG. 7 is a plot showing the relationship between the ratio TiO2 / (TiO; + Nb20s + WO3 +

Bi203) and the measured refractive index at 587.56 nm ny for some of the Exemplary Glasses and some of the Comparative Glasses. The Exemplary Glasses (filled circles) are the Examples 2, 3, 13, 14, 23, 65 and 66 from Table 6. The Comparative Glasses (open circles) are the Examples C7, C8, C13, C20 and C27 to C32 from Table 7. All of the Exemplary Glasses and Comparative Glasses shown in FIG. 7 have the features specified in Table 10. In Table 10, the specification "Not limited", if appears, refers to a limitation that was not considered when selecting the compositions.

[00138] The Comparative Glasses of FIG. 7 were selected as having the highest measured values of the refractive index at 587.56 nm n4 over the range of values of the ratio TiO; / (TiO2 + NbOs + WO3 +

Bi203} shown in FIG. 7 among the known glasses that have the mentioned features specified in Table 10.

[00139] The line corresponding to the formula y = 1.99 + 0.083 * x shown in FIG. 7 provides a visual representation of the differences between the Comparative Glasses having the features specified in Table 10 and the Exemplary Glasses 2, 3, 13, 14, 23, 65 and 66. As can be seen in FIG. 7, the mentioned Exemplary Glasses (filled circles) and none of the Comparative Glasses (open circles)

represented in FIG. 7 fall above the line y = 1.99 + 0.083 * x, where y corresponds to ng and x corresponds to the ratio TiO; / (TiO; + Nb;Os + WO; + Bi203}. In other words, some of the Exemplary

Glasses and none of the Comparative Glasses represented in FIG. 7 satisfy the following formula (Vi}(a):

Ng - (1.99 + 0.083 * TiO, / (TiO, + Nb,Os + WO; + Bi203)} > 0.00 (VI)(a)

[00140] As can also be seen in FIG. 7, some of Exemplary Glasses and none of the Comparative

Glasses represented in FIG. 7 fall above the line y = 2.005 + 0.083 * x, where y corresponds to ng and x corresponds to the ratio TiO; / (TiO; + NbOs + WO; + Biz 03). In other words, some of the Exemplary

Glasses and none of the Comparative Glasses represented in FIG. 7 satisfy the following formula (Vi)(b): ng - (2.005 + 0.083 * TiO, / (TiO2 + Nb205 + WO; + Bi203}} > 0.00 (Vi)(b)

[00141] The Exemplary Examples represented in FIG. 7 that satisfy the formula (Vi)(b) are characterized by the highest values of ng at comparable values of the ratio TiO; / (TiO, + Nb2Os + WO; +

Bi203) among the glasses that have the features specified in Table 10.

[00142] This means that, under the conditions specified in Table 10 above, some of the

Exemplary Glasses have higher measured values of the refractive index at 587.56 nm ny at comparable measured values of the ratio TiO, / (TiO2 + Nb:Os + WO: + Bi203) than the best of the Comparative

Glasses satisfying the same conditions. This can be interpreted as these Exemplary Glasses, according to measurements, have higher values of ng at comparable values of TiO; / (TiO2 + Nb20s + WO; + Bi203) among the glasses, i.e. they are, according to measurement, superior in terms of a combination of TiO, / (TiO2 + Nb20:s + WO:3 + Bi203} and ng to the best known Comparative Glasses that have the features specified in Table 10.

[00143] The values of all attributes specified in Table 10 and Formulas (V)(a), (V)(b), (VI)(a) and (Vi)(b) for the Comparative Glasses C3, C7, C8, C13 and C20 to C32 plotted in FIGS 6 and 7 are presented in Table 11 below. Full compositions of comparative example glasses are presented in Table 7. Full compositions and attributes of the Exemplary Glasses are presented in Table 6.

Table 11. Attributes of Comparative Example Glasses Having the Features Specified in Table 10

Composition i foo fe

Te]

Dz wee [vo KK CA CC

Wome [a ow Job ow Jo |v w |v _

TiO2 / (TiO: + Nb20s + WO: + mol% | 0.8373 | 0.8342 | 0.8342 | 0.8373 | 0.4688 | 1000 | 0.5050 | 0.7692

RE

Measured properties

TT Te Te Te TT] ng - (1.99 + 0.083 * TiOz / (TiO: 0.0092 | 0.0092 | -0.0085 | 0.0289 more 1g - (2.005 + 0.083 * TiO2 / (TIO: 0.0242 | -0.0242 | -0.0235 | -0.0439 een

Pa - (1.99 +0.083 * TiO2 / (TiO» 0.0019 | -0.0088 | -0.0100 | -0.0022 | -0.0330 | -0.0354 | -0.0022 | -0.0041 mm |e oe ee

Pa - (2.005 + 0.083 * TiO2 / (TiO: 0.0169 | -0.0238 | 0.0250 | -0.0172 | -0.0480 | -0.0504 | -0.0172 | -0.0191 mama

Table 11 Continued

Composition sf of fo fee eee] oT

Woo wilco Jojo Jo Jo Jo Jv Jv

TiO2 / (TiO: +Nb:Os + | mol.% | 0.8670 | 0.8676 | 0.8669 | 0.9344 | 0.8671 | 0.8672 | 0.8677 | 0.6636 | 0.8694 voor

Measured properties ne - (1.99 + 0.083 * 0.0317 | -0.008 | -0.008 | -0.008 | 0.0171 | 0.0197

TiO: / (TIO: + Nb20s +

ES ng - (2.005 +0.083 * 0.0467 | 0.023 | 0.023 | 0.023 | -0.0321 | -0.0347

TiO: / (TiO2 + Nb20s +

WO: + BOs)

Predicted and calculated properties

Py - (1.99 + 0.083 * 0.0099 | -0.0100 | -0.0100 | -0.0431 | -0.0359 | 0.0361 | 0.0360 | 0.0746 | -0.0467

TiOz / (TiO2 + Nb20s + wml

Pa - (2.005 + 0.083 * 40.0249 | -0.0250 | -0.0250 | 0.0381 | 0.0509 | 0.0511 | -0.0510 | -0.0896 | -0.0617

TiO2 / (Ti02 + Nb20s +

Fre

[00144] As follows from FIG. 6 and 7, both predicted and measured property data confirms that some of the Exemplary Glasses have better combination of refractive index at 587.56 nm ng and the ratio TiO, / [TiO; + Nb:Os + WO: + Bi,03) than the best of the Comparative Glasses that have the features specified in Table 10.

[00145] The following non-limiting aspects are encompassed by the present disclosure. To the extent not already described, any one of the features of the first through the sixty-eighth aspect may be combined in part or in whole with features of any one or more of the other aspects of the present disclosure to form additional aspects, even if such a combination is not explicitly described.

[00146] According to a first aspect, the glass comprises a plurality of components, the glass having a composition of the components comprising greater than or equal to 12.0 mol.% and less than or equal to 35.0 mol.% TiO, greater than or equal to 2.5 mol.% and less than or equal to 20.0 mol.%

Zr0,, greater than or equal to 0.5 mol.% and less than or equal to 40.0 mol.% B203, greater than or equal to 0.5 mol.% and less than or equal to 30.0 mol.% Nb.Os, greater than or equal to 0.0 mol.% and less than or equal to 20.0 mol.% Bi; 0s, greater than or equal to 0.0 mol.% and less than or equal to 15.0 mol.% P,0Os, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Al: Os, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Gd.0s, greater than or equal to 0.0 mol.% and less than or equal to 8.0 mol.% WO;3, greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.% PbO, greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.% V.0s, greater than or equal to 0.0 mol.% and less than or equal to 1.5 mol.% ZnO, greater than or equal to 95.0 mol.%

RmO,, greater than or equal to 0.5 mol.% and less than or equal to 35.0 mol.% REmOs, a sum of SiO; +

B20:3 + P2Os greater than or equal to 10.0 mol.% and a sum of TiO; + Nb20; greater than or equal to 0.0 mol.% and less than or equal to 42.0 mol.%, wherein the composition of the components satisfies the condition: SiO; + B203 - P2Os [mol.%)] = 0.000, and the glass satisfies the condition: P, - (1.765 + 0.057 *

Pg) > 0.000, where P, is a parameter predicting a refractive index at 587.56 nm, ng, calculated from the glass composition in terms of mol.% of the components according to the Formula (I):

P,= 1.844 +0.0054162 * La203 + 0.0031113 * TiO, - 0.004212 * B203 - 0.0035692 * SiO, + 0.0027887 * ZrO, + 0.0078026 * Nb20; - 0.00012928 * CaO + 0.00076566 * BaO + 0.0043601 * Y,0, + 0.00067408 * ZnO + 0.0068029 * Gd.0; - 0.0025106 * Na20 + 0.0039937 * WO; - 0.0043208 *

ALO; - 0.0011666 * Li,O + 0.0051727 * PbO + 0.012958 * Bi203 - 0.0018753 * GeO, - 0.0014084 * 0

TeO; + 0.0086647 * Er;03 + 0.0097345 * Yb,0; - 0.0038734 * K;0 - 0.00041776 * SrO - 0.0017294 *

MgO, and Pg is a parameter predicting a density at room temperature, dry, calculated from the glass composition in terms of mol.% of the components according to the Formula (11):

ZnO + 0.066160 * Gd;03 - 0.016932 * Na 0 + 0.025764 * WO; - 0.035116 * ALO; - 0.0094315 * Li,O (11) + 0.047388 * PbO + 0.080813 * Bi,03- 0.0088118 * GeO; + 0.072296 * Er,0; + 0.078888 * Yb,03 - 0.026242 * K,0 + 0.010351 * SrO - 0.0030424 * MgO, where RO, is a total sum of all oxides, REmO, is a total sum of rare earth metal oxides, and an asterisk (*} means multiplication.

[00147] According to a second aspect, the glass of the first aspect, wherein the glass satisfies the condition: ng - (1.765 + 0.057 * dg) > 0.000, where nq is a refractive index at 587.56 nm and der [g/cm] is a density at room temperature.

[00148] According to a third aspect, the glass of any one of aspects 1-2, wherein the composition of the components comprises greater than or equal to 20.0 mol.% and less than or equal to 27.5 mol.% TiO,, greater than or equal to 15.0 mol.% and less than or equal to 30.0 mol.% La20;, greater than or equal to 15.0 mol.% and less than or equal to 22.5 mol.% B203, greater than or equal to 5.0 mol.% and less than or equal to 20.0 mol.% SiO, greater than or equal to 4.0 mol.% and less than or equal to 9.0 mol.% Zr0,, greater than or equal to 2.5 mol.% and less than or equal to 10.0 mol.% Nb20;, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% BaO, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% CaO, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Ga.0s, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Y203 and greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% WO:.

[00149] According to a fourth aspect, the glass of any one of aspects 1-3, wherein the composition of the components comprises one or more of the following components: greater than or equal to 20.25 mol.% and less than or equal to 26.00 mol.% TiO,, greater than or equal to 20.0 mol.% and less than or equal to 27.5 mol.% La203, greater than or equal to 16.4 mol.% and less than or equal to 20.4 mol.% B203, greater than or equal to 10.0 mol.% and less than or equal to 17.5 mol.% SiO,, greater than or equal to 5.3 mol. % and less than or equal to 8.1 mol.% ZrQ,, greater than or equal to 4.5 mol.% and less than or equal to 9.3 mol.% Nb,Os, greater than or equal to 0.5 mol.% and less than or equal to 6.3 mol.% Y203, greater than or equal to 0.0 mol.% and less than or equal to 9.0 mol.% CaO, greater than or equal to 0.0 mol.% and less than or equal to 8.0 mol.% Ga203, greater than or equal to 0.0 mol.% and less than or equal to 6.5 mol.% BaO, greater than or equal to 0.0 mol.% and less than or equal to 1.8 mol.% WO:3, greater than or equal to 0 mol.% and less than or equal to 1.35 mol.% Gd;03, greater than or equal to 0.0 mol.% and less than or equal to 0.9 mol.% SrO and greater than or equal to 0.0 mol.% and less than or equal to 0.9 mol.% Yb, 0s.

[00150] According to a fifth aspect, the glass of any one of aspects 1-4, wherein the composition of the components comprises greater than or equal to 21.0 mol.% and less than or equal to 26.3 mol.%

La203, greater than or equal to 20.25 mol.% and less than or equal to 25.50 mol.% TiQ,, greater than or equal to 16.9 mol.% and less than or equal to 20.4 mol.% B:03, greater than or equal to 11.0 mol.% and less than or equal to 16.5 mol.% SiO, greater than or equal to 5.6 mol.% and less than or equal to 8.0 mol.% Zr0,, greater than or equal to 5.1 mol.% and less than or equal to 8.6 mol.% Nb20;, greater than or equal to 0.75 mol.% and less than or equal to 5.50 mol.% Y203, greater than or equal to 0.0 mol.% and less than or equal to 8.0 mol.% CaO, greater than or equal to 0.0 mol.% and less than or equal to 7.5 mol.% Ga203, greater than or equal to 0.0 mol.% and less than or equal to 5.5 mol.% BaO, greater than or equal to 0.0 mol.% and less than or equal to 1.6 mol.% WO3, greater than or equal to 0.0 mol.% and less than or equal to 1.2 mol.% Gd,0s, greater than or equal to 0.0 mol.% and less than or equal to 0.8 mol.% SrO and greater than or equal to 0.0 mol.% and less than or equal to 0.8 mol.% Yb,0s.

[00151] According to a sixth aspect, the glass of any one of aspects 1-5, wherein the composition of the components satisfy one or more of the following conditions: a sum of La;0s + TiO; + B203 + SiOz +

ZrO; + Nb,Os + BaO + Y203 + CaO + Ga20:3 + Gd203 + ZnO + WO3 + CeO + SrO + Na 0 + Ta20; + Al;03 greater than or equal to 99.0 mol.%, a sum of La203 + Y203 + Gd20;3 + TiOz + B203 + SiO2 + ZrO; + Nb205 greater than or equal to 99.0 mol.%, a sum of La203 + Y203 + Gd203 + TiO; + B203 + SiO2 + ZrO; + Nb20s +

CaO + BaO greater than or equal to 99.0 mol.% and a sum of La203 + TiO2 + B203 + SiO, + ZrO; + Nb20s greater than or equal to 97.0 mol.%.

[00152] According to a seventh aspect, the glass of any one of aspects 1-6, wherein the composition of the components comprises greater than or equal to 5.0 mol.% B203, greater than or equal to 5.0 mol.% La:03, greater than or equal to 5.0 mol.% Nb:0;, greater than or equal to 5.0 mol.%

SiO2 and a sum of ZrO, + HfO, greater than or equal to 1.0 mol.%.

[00153] According to an eighth aspect, the glass of any one of aspects 1-7, wherein the composition of the components comprises a sum of R20 + RO greater than or equal to 0.0 mol.% and less than or equal to 6.0 mol.%, where R20 is a total sum of monovalent metal oxides, and RO is a total sum of divalent metal oxides.

[00154] According to a ninth aspect, the glass of the eighth aspect, wherein the composition of the components comprises a sum of R20 + RO greater than or equal to 0.0 mol.% and less than or equal to 1.0 mol.%, where R20 is a total sum of monovalent metal oxides, and RO is a total sum of divalent metal oxides.

[00155] According to a tenth aspect, the glass of any one of aspects 1-9, wherein the composition of the components satisfies the condition: 0.00 < SiO; / (SiO2 + B03) [mol.%] < 0.40.

[00156] According to an eleventh aspect, the glass of any one of aspects 1-9, wherein the composition of the components satisfies the condition: 0.38 < SiQ; / (SiO; + B203) [mol.%] < 0.75.

[00157] According to a twelfth aspect, the glass of any one of aspects 1-11, wherein the composition of the components comprises greater than or equal to 0.0 mol.% and less than or equal to 6.5 mol.% CaO and greater than or equal to 0.0 mol.% and less than or equal to 5.5 mol.% BaO and wherein the composition of the components is substantially free of ZnO.

[00158] According to a thirteenth aspect, the glass of any one of aspects 1-12, wherein the composition of the components comprises a sum of WO: + Bi203 greater than or equal to 0.0 mol.% and less than or equal to 7.0 mol.%.

[00159] According to a fourteenth aspect, the glass of any one of aspects 1-13, wherein the composition of the components comprises greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.% Y203, greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% Ta20s, greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% TeQ,, greater than or equal to 0.0 mol.% and less than or equal to 0.5 mol.% GeO,, greater than or equal to 0.0 mol.% and less than or equal to 0.5 mol.% PbO, greater than or equal to 0.0 mol.% and less than or equal to 0.2 mol.% As20;3 and greater than or equal to 0.0 mol.% and less than or equal to 0.2 mol.% Sb:0;, wherein the composition of the components is substantially free of fluorine and substantially free of V20s.

[00160] According to a fifteenth aspect, the glass of any one of aspects 1-3 and 6-14, wherein the composition of the components comprises greater than or equal to 22.0 mol.% and less than or equal to 25.0 mol.% TiO,, greater than or equal to 20.0 mol.% and less than or equal to 30.0 mol.%

La:0;, greater than or equal to 16.0 mol.% and less than or equal to 20.0 mol.% B,0s, greater than or equal to 10.0 mol.% and less than or equal to 20.0 mol.% SiO2, greater than or equal to 6.5 mol.% and less than or equal to 8.0 mol.% ZrO, greater than or equal to 5.0 mol.% and less than or equal to 6.7 mol.% Nb:0;5, greater than or equal to 0.0 mol.% and less than or equal to 6.0 mol. % Y203, greater than or equal to 0.0 mol.% and less than or equal to 3.0 mol.% BaO and greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% Gd:0:3 and greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% of all other components in total.

[00161] According to a sixteenth aspect, the glass of any one of aspects 1-15, wherein the glass satisfies the conditions: 4.5 < P4 < 5.5 and 1.95<P,<2.07.

[00182] According to a seventeenth aspect, the glass of any one of aspects 1-16, wherein the glass has a density at room temperature, dr, that is greater than or equal to 4.5 g/cm? and less than or equal to 5.5 g/cm? and a refractive index at 587.56 nm, na, that is greater than or equal to 1.95 and less than or equal to 2.07.

[00163] According to an eighteenth aspect, the glass of any one of aspects 1-17, wherein the glass has a liquidus temperature, Ti, that is less than or equal to 1260 °C.

[00164] According to a nineteenth aspect, the glass of any one of aspects 1-18, wherein when cooled in air from 1100°C to 500 °C in 2.5 minutes, the glass does not crystallize.

[00165] According to a twentieth aspect, the glass of any one of aspects 1-19, wherein the glass has a transmittance at a wavelength of 460 nm, TX4s0 nm, that is greater than or equal to 70%.

[00166] According to a twenty-first aspect, a method for manufacturing an optical element, the method comprising processing a glass, wherein the glass is the glass of any one of aspects 1-20.

[00167] According to a twenty-second aspect, an optical element comprising a glass, wherein the glass is the glass of any one of aspects 1-21.

[00168] According to a twenty-third aspect, the glass comprises a plurality of components, the glass having a composition of the components comprising greater than or equal to 1.0 mol.% and less than or equal to 13.5 mol.% Zr0,, greater than or equal to 0.3 mol.% and less than or equal to 35.0 mol.% TiO,, greater than or equal to 0.3 mol.% and less than or equal to 29.5 mol.% B,0s, greater than or equal to 0.0 mol.% and less than or equal to 9.0 mol.% WO;, greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.% PbO, greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% Gd:03, greater than or equal to 0.0 at.% and less than or equal to 2.0 at.% F, a sum of TiO, +

Nb2Os + La,0; greater than or equal to 10.0 mol.% and less than or equal to 70.0 mol.%, a sum of SiO, +

B20:; + P;Os greater than or equal to 10.0 mol.%, a sum of REO, + WO: + ZrO; greater than or equal to 5.0 mol.%, a sum of SiO; + Y203 + Gd;0:; greater than or equal to 0.3 mol.%, a sum of V20s + MoO; greater than or equal to 0.0 mol.% and less than or equal to 3.0 mol.% and may optionally contain one or more components selected from Bi203, CaO, BaO, ZnO, Na:0, Al:03, LiO, GeO, TeO,, K20, SrO and

MgO, wherein the composition of the components satisfies the conditions: TiO, / (TiO2 + Nb205 + WO; +

Bi203) [mol.%] = 0.050, SiO; + B20; - P20s [mol.%] = 1.0 and La203 / TiO; [mol.%] < 1.5, and the glass satisfies the condition: P, - (1.99 + 0.083 * (TiO2 / (TiO2 + Nb20s + WO; + Biz03}}} > 0.000, where P, is a parameter predicting a refractive index at 587.56 nm, ng, calculated from the glass composition in terms of mol.% of the components according to the Formula (I):

P‚= 1.844 + 0.0054162 * La20:3 + 0.0031113 * TiO; - 0.004212 * B203 - 0.0035692 * SiO, + 0.0027887 * ZrO, + 0.0078026 * Nb.Os - 0.00012928 * CaO + 0.00076566 * BaO + 0.0043601 * Y,0s +0.00067408 * ZnO + 0.0068029 * Gd,0s - 0.0025106 * Na20 + 0.0039937 * WO; - 0.0043208 *

Al203 - 0.0011666 * Li,O + 0.0051727 * PbO + 0.012958 * Bi203 - 0.0018753 * GeO; - 0.0014084 * 0

TeO; + 0.0086647 * Er,03 + 0.0097345 * Yb203 - 0.0038734 * K,0 - 0.00041776 * SrO - 0.0017294 *

MgO, where REO, is a total sum of rare earth metal oxides, and an asterisk {(*} means multiplication.

[00169] According to a twenty-fourth aspect, the glass of the twenty-third aspect, wherein the glass satisfies the condition: ng - (1.99 + 0.083 * (TiO, / {TiO + Nb20Os + WO: + Bi203}}} > 0.000, where ng is a refractive index at 587.56 nm.

[00170] According to a twenty-fifth aspect, the glass of any one of aspects 23-24, wherein the glass satisfies the condition: na - (2.005 + 0.083 * (TiO2 / (TiO2 + Nb205 + WO; + Biz0s))) > 0.000, where nq is a refractive index at 587.56 nm.

[00171] According to a twenty-sixth aspect, the glass of any one of aspects 23-25, wherein the glass satisfies the condition: P, - (2.005 + 0.083 * (TiO, / (TiO, + Nb2Os + WO: + Bi203)}} > 0.000.

[00172] According to a twenty-seventh aspect, the glass of any one of aspects 23-26, wherein the composition of the components comprises greater than or equal to 20.0 mol.% and less than or equal to 27.5 mol.% Ti0O,, greater than or equal to 15.0 mol.% and less than or equal to 30.0 mol.%

La203, greater than or equal to 15.0 mol.% and less than or equal to 22.5 mol.% B203, greater than or equal to 5.0 mol.% and less than or equal to 20.0 mol.% SiO,, greater than or equal to 4.0 mol.% and less than or equal to 9.0 mol.% ZrO:, greater than or equal to 2.5 mol.% and less than or equal to 10.0 mol.%

Nb,Os, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% BaO, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% CaO, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Ga:03, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Y203, greater than or equal to 0.0 mol.% and less than or equal to 4.0 mol.% ZnO and greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% WO.

[00173] According to a twenty-eighth aspect, the glass of any one of aspects 23-27, wherein the composition of the components comprises one or more of the following components: greater than or equal to 20.25 mol.% and less than or equal to 26.00 mol.% TiO, greater than or equal to 20.0 mol.% and less than or equal to 27.5 mol.% La203, greater than or equal to 16.4 mol.% and less than or equal to 20.4 mol.% B;0;, greater than or equal to 10.0 mol.% and less than or equal to 17.5 mol.% SiO, greater than or equal to 5.3 mol.% and less than or equal to 8.1 mol.% ZrO,, greater than or equal to 4.5 mol.% and less than or equal to 9.3 mol.% Nb20s, greater than or equal to 0.5 mol.% and less than or equal to 6.3 mol.% Y,0s3, greater than or equal to 0.0 mol.% and less than or equal to 9.0 mol.% CaO, greater than or equal to 0.0 mol.% and less than or equal to 8.0 mol.% Ga,0s, greater than or equal to 0.0 mol.% and less than or equal to 6.5 mol.% BaO, greater than or equal to 0.0 mol.% and less than or equal to 3.0 mol.% ZnO, greater than or equal to 0.0 mol.% and less than or equal to 1.8 mol.% WOQs3, greater than or equal to 0 mol.% and less than or equal to 1.35 mol.% Gd,0s, greater than or equal to 0.0 mol.% and less than or equal to 0.9 mol.% SrO and greater than or equal to 0.0 mol.% and less than or equal to 0.9 mol.% Yb,0s.

[00174] According to a twenty-ninth aspect, the glass of any one of aspects 23-28, wherein the composition of the components comprises greater than or equal to 21.0 mol.% and less than or equal to 26.3 mol.% La203, greater than or equal to 20.25 mol.% and less than or equal to 25.50 mol.% TiO,, greater than or equal to 16.9 mol.% and less than or equal to 20.4 mol.% B203, greater than or equal to 11.0 mol.% and less than or equal to 16.5 mol.% SiO2, greater than or equal to 5.6 mol.% and less than or equal to 8.0 mol.% ZrQ,, greater than or equal to 5.1 mol.% and less than or equal to 8.6 mol.%

Nb,Os, greater than or equal to 0.75 mol.% and less than or equal to 5.50 mol.% Y203, greater than or equal to 0.0 mol.% and less than or equal to 8.0 mol.% CaO, greater than or equal to 0.0 mol.% and less than or equal to 7.5 mol.% Ga20;3, greater than or equal to 0.0 mol.% and less than or equal to 5.5 mol.%

BaO, greater than or equal to 0.0 mol.% and less than or equal to 2.7 mol.% ZnO, greater than or equal to 0.0 mol.% and less than or equal to 1.6 mol.% WOs, greater than or equal to 0.0 mol.% and less than or equal to 1.2 mol.% Gd,0s, greater than or equal to 0.0 mol.% and less than or equal to 0.8 mol.% SrO and greater than or equal to 0.0 mol.% and less than or equal to 0.8 mol.% Yb20:.

[00175] According to a thirtieth aspect, the glass of any one of aspects 23-29, wherein the composition of the components satisfy one or more of the following conditions: a sum of La203 + TiO, +

B203 + SiO2 + ZrO; + Nb;Os + BaO + Y203 + CaO + Ga203 + Gd203 + ZnO + WO3 + CeO; + SrO + Na20 +

Ta20; + ALO; greater than or equal to 99.0 mol.%, a sum of La203 + Y203 + Gd203 + TÎO2 + B203 + Si02 +

ZrO; + NbyOs greater than or equal to 99.0 mol.%, a sum of La;0s + Y203 + Gd203 + TiO; + B203 + SiO; +

ZrO, + Nb,0s + CaO + BaO greater than or equal to 99.0 mol.% and a sum of La203 + TiO; + B203 + SiO, +

ZrO, + Nb,Os greater than or equal to 97.0 mol.%.

[00176] According to a thirty-first aspect, the glass of any one of aspects 23-26 and 29-30, wherein the composition of the components comprises greater than or equal to 5.0 mol.% B203, greater than or equal to 5.0 mol.% Nb.Qs, greater than or equal to 5.0 mol.% SiO», greater than or equal to 5.0 mol.% TiO; and a sum of ZrO, + HfO: greater than or equal to 1.0 mol.%.

[00177] According to a thirty-second aspect, the glass of any one of aspects 23-31, wherein the composition of the components comprises a sum of R2O + RO greater than or equal to 0.0 mol.% and less than or equal to 6.0 mol.%, where R20 is a total sum of monovalent metal oxides, and RO is a total sum of divalent metal oxides.

[00178] According to a thirty-third aspect, the glass of the thirty-second aspect, wherein the composition of the components comprises a sum of R,0 + RO greater than or equal to 0.0 mol.% and less than or equal to 1.0 mol.%.

[00179] According to a thirty-fourth aspect, the glass of any one of aspects 23-33, wherein the composition of the components satisfies the condition: 0.00 < SiO; / (SiO2 + B03) [mol.%] < 0.40.

[00180] According to a thirty-fifth aspect, the glass of any one of aspects 23-33, wherein the composition of the components satisfies the condition: 0.38 < SiQ; / (SiO; + B203) [mol.%] < 0.75.

[00181] According to a thirty-sixth aspect, the glass of any one of aspects 23-35, wherein the composition of the components comprises greater than or equal to 0.0 mol.% and less than or equal to 6.5 mol.% CaO and greater than or equal to 0.0 mol.% and less than or equal to 5.5 mol.% BaO and wherein the composition of the components is substantially free of ZnO.

[00182] According to a thirty-seventh aspect, the glass of any one of aspects 23-36, wherein the composition of the components comprises a sum of WO: + Bi203 greater than or equal to 0.0 mol.% and less than or equal to 7.0 mol.%.

[00183] According to a thirty-eighth aspect, the glass of any one of aspects 23-37, wherein the composition of the components comprises greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.% Y,0s, greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% Ta20s, greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% TeO,, greater than or equal to 0.0 mol.% and less than or equal to 0.5 mol.% GeO,, greater than or equal to 0.0 mol.% and less than or equal to 0.5 mol.% PbO, greater than or equal to 0.0 mol.% and less than or equal to 0.2 mol.% As203 and greater than or equal to 0.0 mol.% and less than or equal to 0.2 mol.% Sb:0;, wherein the composition of the components is substantially free of fluorine and substantially free of V,0s.

[00184] According to a thirty-ninth aspect, the glass of any one of aspects 23-27 and 30-38, wherein the composition of the components comprises greater than or equal to 22.0 mol.% and less than or equal to 25.0 mol. % TiO, greater than or equal to 20.0 mol.% and less than or equal to 30.0 mol.% La203, greater than or equal to 16.0 mol.% and less than or equal to 20.0 mol.% B203, greater than or equal to 10.0 mol.% and less than or equal to 20.0 mol.% SiO», greater than or equal to 6.5 mol.% and less than or equal to 8.0 mol.% ZrO2, greater than or equal to 5.0 mol.% and less than or equal to 6.7 mol.% Nb:0;, greater than or equal to 0.0 mol.% and less than or equal to 6.0 mol.% Y203 and greater than or equal to 0.0 mol.% and less than or equal to 3.0 mol.% BaO and greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% of all other components in total.

[00185] According to a fortieth aspect, the glass of any one of aspects 23-39, wherein the glass satisfies the conditions: 4.5 < P4 <5.5 and 1.95 <P, < 2.07.where Pa is a parameter predicting a density at room temperature, der, calculated from the glass composition in terms of mol.% of the components according to the Formula (ll):

ZnO + 0.066160 * Gd;03 - 0.016932 * Na20 + 0.025764 * WO: - 0.035116 * Al,O; - 0.0094315 * (tn).

Li2O + 0.047388 * PbO + 0.080813 * Bi,0s - 0.0088118 * GeO, + 0.072296 * Er,03 + 0.078888 *

Yb,0s - 0.026242 * K,0 + 0.010351 * SrO - 0.0030424 * MgO,

[00186] According to a forty-first aspect, the glass of any one of aspects 23-40, wherein the glass has a density at room temperature, der, that is greater than or equal to 4.5 g/cm? and less than or equal to 5.5 g/cm? and a refractive index at 587.56 nm, ng, that is greater than or equal to 1.95 and less than or equal to 2.07.

[00187] According to a forty-second aspect, the glass of any one of aspects 23-41, wherein the glass has a liquidus temperature, Tug, that is less than or equal to 1260 °C.

[00188] According to a forty-third aspect, the glass of any one of aspects 23-42, wherein when cooled in air from 1100 °C to 500 °C in 2.5 minutes, the glass does not crystallize.

[00189] According to a forty-fourth aspect, the glass of any one of aspects 23-43, wherein the glass has a transmittance at a wavelength of 460 nm, TX4s0 nm, that is greater than or equal to 70%.

[00190] According to a forty-fifth aspect, a method for manufacturing an optical element, the method comprising processing a glass, wherein the glass is the glass of any one of aspects 23-44.

[00191] According to a forty-sixth aspect, an optical element comprising a glass, wherein the glass is the glass of any one of aspects 23-45.

[00192] According to a forty-seventh aspect, the glass comprises a plurality of components, the glass having a composition of the components comprising greater than or equal to 0.5 mol.% and less than or equal to 45.0 mol.% B203, greater than or equal to 0.1 mol.% and less than or equal to 25.0 mol.% Bi203, greater than or equal to 0.0 mol.% and less than or equal to 8.0 mol.% WO3, a sum of SiO, +

B20: + P2Os greater than or equal to 10.0 mol.%, a sum of TiO, + Nb2Os greater than or equal to 8.5 mol.%, a sum of REmOn + WO: + ZrO; greater than or equal to 4.5 mol.% and may optionally contain one or more components selected from CaO, BaO, ZnO, Na20, Al203, Li20, PbO, GeO2, Te, K20, SrO and

MgO, wherein the composition of the components satisfies the conditions: SiO2 + B203 - P20Os [mol.%] > 0.100, and the glass satisfies the condition: P, > 2.045, where P, is a parameter predicting a refractive index at 587.56 nm, ng, calculated from the glass composition in terms of mol.% of the components according to the Formula (1):

Pa= 1.844 + 0.0054162 * La,0; + 0.0031113 * TiO, - 0.004212 * B,0s - 0.0035692 * SiO, + 0.0027887 * ZrO, + 0.0078026 * Nb»Os - 0.00012928 * CaO + 0.00076566 * BaO + 0.0043601 * Y,0; +0.00067408 * ZnO + 0,0068029 * Gd203 - 0.0025106 * Na;O + 0.0039937 * WO; - 0.0043208 *

MgO, where REnO, is a total sum of rare earth metal oxides, and an asterisk (*} means multiplication.

[00193] According to a forty-eighth aspect, the glass of the forty-seventh aspect, wherein the glass has a refractive index at 587.56 nm, na, that is greater than or equal to 2.045.

[00194] According to a forty-ninth aspect, the glass of any one of aspects 47-48, wherein the composition of the components comprises greater than or equal to 20.0 mol.% and less than or equal to 27.5 mol.% TiO2, greater than or equal to 15.0 mol.% and less than or equal to 30.0 mol.% La203, greater than or equal to 15.0 mol.% and less than or equal to 22.5 mol.% B:03, greater than or equal to 5.0 mol.% and less than or equal to 20.0 mol.% SiO2, greater than or equal to 4.0 mol.% and less than or equal to 9.0 mol.% ZrO:, greater than or equal to 2.5 mol.% and less than or equal to 10.0 mol.% Nb,Os, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% BaO, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% CaO, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Ga,0s, greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Y,0;, greater than or equal to 0.0 mol.% and less than or equal to 4.0 mol.% ZnO and greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% WOs.

[00195] According to a fiftieth aspect, the glass of any one of aspects 47-49, wherein the composition of the components comprises one or more of the following components: greater than or equal to 20.25 mol.% and less than or equal to 26.00 mol.% TiO,, greater than or equal to 20.0 mol.% and less than or equal to 27.5 mol.% La203, greater than or equal to 16.4 mol.% and less than or equal to 20.4 mol.% B203, greater than or equal to 10.0 mol.% and less than or equal to 17.5 mol.% SiO;, greater than or equal to 5.3 mol.% and less than or equal to 8.1 mol.% ZrO,, greater than or equal to 4.5 mol.% and less than or equal to 9.3 mol.% Nb.Os, greater than or equal to 0.5 mol.% and less than or equal to 6.3 mol.% Y203, greater than or equal to 0.0 mol.% and less than or equal to 9.0 mol.% CaO, greater than or equal to 0.0 mol.% and less than or equal to 8.0 mol.% Ga203, greater than or equal to 0.0 mol.% and less than or equal to 6.5 mol.% BaO, greater than or equal to 0.0 mol.% and less than or equal to 3.0 mol.% ZnO, greater than or equal to 0.0 mol.% and less than or equal to 1.8 mol.% WO:3, greater than or equal to 0 mol.% and less than or equal to 1.35 mol.% Gd203, greater than or equal to 0.0 mol.% and less than or equal to 0.9 mol.% SrO and greater than or equal to 0.0 mol.% and less than or equal to 0.9 mol.% Yb20:3.

[00196] According to a fifty-first aspect, the glass of any one of aspects 47-50, wherein the composition of the components comprises greater than or equal to 21.0 mol.% and less than or equal to 26.3 mol.% La203, greater than or equal to 20.25 mol.% and less than or equal to 25.50 mol.% TiO,, greater than or equal to 16.9 mol.% and less than or equal to 20.4 mol.% B203, greater than or equal to 11.0 mol.% and less than or equal to 16.5 mol.% SiO2, greater than or equal to 5.6 mol.% and less than or equal to 8.0 mol.% ZrQ,, greater than or equal to 5.1 mol.% and less than or equal to 8.6 mol.%

Nb,Os, greater than or equal to 0.75 mol.% and less than or equal to 5.50 mol.% Y203, greater than or equal to 0.0 mol.% and less than or equal to 8.0 mol.% CaO, greater than or equal to 0.0 mol.% and less than or equal to 7.5 mol.% Ga:0;3, greater than or equal to 0.0 mol.% and less than or equal to 5.5 mol.%

BaO, greater than or equal to 0.0 mol.% and less than or equal to 2.7 mol.% ZnO, greater than or equal to 0.0 mol.% and less than or equal to 1.6 mol.% WOs, greater than or equal to 0.0 mol.% and less than or equal to 1.2 mol.% Gd,0s, greater than or equal to 0.0 mol.% and less than or equal to 0.8 mol.% SrO and greater than or equal to 0.0 mol.% and less than or equal to 0.8 mol.% Yb20:3.

[00197] According to a fifty-second aspect, the glass of any one of aspects 47-51, wherein the composition of the components satisfy one or more of the following conditions: a sum of La203 + TiO, +

B203 + SiO; + ZrO2 + Nb2Os + BaO + Y203 + CaO + Ga203 + Gdy0s + ZnO + WO: + CeO, + SrO + Na20 +

Ta,0s + Al2O3 greater than or equal to 99.0 mol.%, a sum of La203 + Y203 + Gd20: + TiO, + B203 + SiOz +

ZrO; + Nb,Os greater than or equal to 99.0 mol.%, a sum of La;0s + Y203 + Gd203 + TiO, + B203 + SiO; +

ZrO, + Nb,0s + CaO + BaO greater than or equal to 99.0 mol.% and a sum of La,0s + TiO; + B03 + SiO2 +

ZrO; + NbyOs greater than or equal to 97.0 mol.%.

[00198] According to a fifty-third aspect, the glass of any one of aspects 47-48 and 51-52, wherein the composition of the components comprises greater than or equal to 5.0 mol.% B203, greater than or equal to 5.0 mol.% La203, greater than or equal to 5.0 mol.% Nb,Os, greater than or equal to 5.0 mol.% Si0,, greater than or equal to 5.0 mol.% TiO; and a sum of ZrO; + HfO: greater than or equal to 1.0 mol.%.

[00199] According to a fifty-fourth aspect, the glass of any one of aspects 47-53, wherein the composition of the components comprises a sum of R20 + RO greater than or equal to 0.0 mol.% and less than or equal to 6.0 mol.%, where R20 is a total sum of monovalent metal oxides and RO is a total sum of divalent metal oxides.

[00200] According to a fifty-fifth aspect, the glass of the fifty-fourth aspect, wherein the composition of the components comprises a sum of R20 + RO greater than or equal to 0.0 mol.% and less than or equal to 1.0 mol.%..

[00201] According to a fifty-sixth aspect, the glass of any one of aspects 47-55, wherein the composition of the components satisfies the condition: 0.00 < SiQ; / (SiO; + B203) [mol.%] < 0.40.

[00202] According to a fifty-seventh aspect, the glass of any one of aspects 47-55, wherein the composition of the components satisfies the condition: 0.38 < SiO; / (SiO2 + B203} [mol.%] < 0.75.

[00203] According to a fifty-eighth aspect, the glass of any one of aspects 47-57, wherein the composition of the components comprises greater than or equal to 0.0 mol.% and less than or equal to 6.5 mol.% CaO and greater than or equal to 0.0 mol.% and less than or equal to 5.5 mol.% BaO and wherein the composition of the components is substantially free of ZnO.

[00204] According to a fifty-ninth aspect, the glass of any one of aspects 47-58, wherein the composition of the components comprises a sum of WO; + Bi,O; greater than or equal to 0.0 mol.% and less than or equal to 7.0 mol.%.

[00205] According to a sixtieth aspect, the glass of any one of aspects 47-59, wherein the composition of the components comprises greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.% Y,0s, greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% Ta20;, greater than or equal to 0.0 mol.% and fess than or equal to 2.0 mol.% TeO,, greater than or equal to 0.0 mol.% and less than or equal to 0.5 mol.% GeQ,, greater than or equal to 0.0 mol.% and less than or equal to 0.5 mol.% PbO, greater than or equal to 0.0 mol.% and less than or equal to 0.2 mol.% As203 and greater than or equal to 0.0 mol.% and less than or equal to 0.2 mol.% Sb203, wherein the composition of the components is substantially free of fluorine and substantially free of V,0s.

[00206] According to a sixty-first aspect, the glass of any one of aspects 47-49 and 52-60, wherein the composition of the components comprises greater than or equal to 22.0 mol.% and less than or equal to 25.0 mol.% TiQ,, greater than or equal to 20.0 mol.% and less than or equal to 30.0 mol.% La» 0s, greater than or equal to 16.0 mol.% and less than or equal to 20.0 mol.% B20;, greater than or equal to 10.0 mol.% and less than or equal to 20.0 mol.% SiO, greater than or equal to 6.5 mol.% and less than or equal to 8.0 mol.% ZrO,, greater than or equal to 5.0 mol.% and less than or equal to 6.7 mol.% Nb:0;, greater than or equal to 0.0 mol.% and less than or equal to 6.0 mol.% Y,0;, greater than or equal to 0.0 mol.% and less than or equal to 3.0 mol.% BaO and greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% Gd20: and greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% of all other components in total.

[00207] According to a sixty-second aspect, the glass of any one of aspects 47-61, wherein the glass satisfies the conditions: 4.5 < Py < 5.5 and 2.045 <P, < 2.07, where Pa is a parameter predicting a density at room temperature, dry, calculated from the glass composition in terms of mol.% of the components according to the Formula (lH):

ZnO + 0.066160 * Gd;03 - 0.016932 * Na20 + 0.025764 * WO: - 0.035116 * Al,O; - 0.0094315 * (1).

Yb,0s - 0.026242 * K,0 + 0.010351 * SrO - 0.0030424 * MgO,

[00208] According to a sixty-third aspect, the glass of any one of aspects 47-62, wherein the glass has a density at room temperature, dry, that is greater than or equal to 4.5 g/cm? and less than or equal to 5.5 g/cm? and a refractive index at 587.56 nm, ng, that is greater than or equal to 2.045 and less than or equal to 2.07.

[00209] According to a sixty-fourth aspect, the glass of any one of aspects 47-63, wherein the glass has a liquidus temperature, Tug, that is less than or equal to 1260 °C.

[00210] According to a sixty-fifth aspect, the glass of any one of aspects 47-64, wherein when cooled in air from 1100 °C to 500 °C in 2.5 minutes, the glass does not crystallize.

[00211] According to a sixty-sixth aspect, the glass of any one of aspects 47-65, wherein the glass has a transmittance at a wavelength of 460 nm, TX4s0 nm, that is greater than or equal to 70%.

[00212] According to a sixty-seventh aspect, a method for manufacturing an optical element, the method comprising processing a glass, wherein the glass is the glass of any one of aspects 47-66.

[00213] According to a sixty-eighth aspect, an optical element comprising a glass, wherein the glass is the glass of any one of aspects 47-67.

[00214] Many variations and modifications may be made to the above-described embodiments of the disclosure without departing substantially from the spirit and various principles of the disclosure.

All such modifications and variations are intended to be included herein within the scope of this disclosure and protected by the following claims.

[00215] To the extent not already described, the different features of the various aspects of the present disclosure may be used in combination with each other as desired. That a particular feature is not explicitly illustrated or described with respect to each aspect of the present disclosure is not meant to be construed that it cannot be, but it is done for the sake of brevity and conciseness of the description. Thus, the various features of the different aspects may be mixed and matched as desired to form new aspects, whether or not the new aspects are expressly disclosed.

[00216] The disclosure also includes the following clauses, which clauses correspond exactly in

English to the appended Dutch language 'Conclusies’.

CLAUSES: 1. A glass comprising a plurality of components, the glass having a composition of the components comprising: e greater than or equal to 12.0 mol.% and less than or equal to 35.0 mol.% TiO,, s greater than or equal to 2.5 mol.% and less than or equal to 20.0 mol.% ZrO,, e greater than or equal to 0.5 mol.% and less than or equal to 40.0 mol.% B20:3, e greater than or equal to 0.5 mol.% and less than or equal to 30.0 mol.% Nb20;, e greater than or equal to 0.0 mol.% and less than or equal to 20.0 mol.% Bi203, e greater than or equal to 0.0 mol.% and less than or equal to 15.0 mol.% P20;, e greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Al203, e greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Gd:03, e greater than or equal to 0.0 mol.% and less than or equal to 8.0 mol.% WO;3, e greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.% PbO, e greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.% V.0s, e greater than or equal to 0.0 mol.% and less than or equal to 1.5 mol.% ZnO, e greater than or equal to 95.0 mol.% RmOs, e greater than or equal to 0.5 mol.% and less than or equal to 35.0 mol.% REmOn, e asum of SiO; + B20:3 + P,0s greater than or equal to 10.0 mol.% and e asum of TO; + Nb,Os greater than or equal to 0.0 mol.% and less than or equal to 42.0 mol.%, wherein the composition of the components satisfies the condition: e SiOz + B203- P20Os [mol.%] > 0.000, and wherein the glass satisfies the condition: e P,-(1.765 + 0.057 * Py) > 0.000, where es Pisa parameter predicting a refractive index at 587.56 nm, ng, calculated from the glass composition in terms of mol.% of the components according to the Formula (1):

P= 1.844 + 0.0054162 * La,0; + 0.0031113 * TiO, - 0.004212 * B203 - 0.0035692 * SiO, + 0.0027887 * ZrO, + 0.0078026 * Nb,0s - 0.00012928 * CaO + 0.00076566 * BaO + 0.0043601 * Y,0; +0.00067408 * ZnO + 0.0068029 * Gd203 - 0.0025106 * Na,O + 0.0039937 * WO: - 0.0043208 *

MgO,

e and Py is a parameter predicting a density at room temperature, dar, calculated from the glass composition in terms of mol.% of the components according to the Formula (li):

Pa = 4.688 + 0.047868 * La30: - 0.0065829 * TiO, - 0.027601 * B01 - 0.022365 * Si0; + 0.016475 *

ZrO, - 0.0052977 * Nb,Os - 0.0030466 * CaO + 0.014971 * BaO + 0.019511 * Y,05 + 0.0076377 *

ZnO + 0.066160 * Gd:03 - 0.016932 * Na 0 + 0.025764 * WO3 - 0.035116 * Al;03 - 0.0094315 * Li2O (Il) + 0.047388 * PbO + 0.080813 * Bi,03 - 0.0088118 * GeO, + 0.072296 * Er,0; + 0.078888 * Yh,0; - 0.026242 * K;O + 0.010351 * SrO - 0.0030424 * MgO, where RmOh is a total sum of all oxides, REmO, is a total sum of rare earth metal oxides, and an asterisk (*} means multiplication. 2. The glass of clause 1, wherein the glass satisfies the condition: e ng- (1.765 + 0.057 * dr) > 0.000, where * ngis a refractive index at 587.56 nm, e drr[g/cm’?] is a density at room temperature. 3. The glass of any one of clauses 1-2, wherein the composition of the components comprises: e greater than or equal to 20.0 mol.% and less than or equal to 27.5 mol.% TiO, e greater than or equal to 15.0 mol.% and less than or equal to 30.0 mol.% La:0;, e greater than or equal to 15.0 mol.% and less than or equal to 22.5 mol.% B:03, e greater than or equal to 5.0 mol.% and less than or equal to 20.0 mol.% SiO, e greater than or equal to 4.0 mol.% and less than or equal to 9.0 mol.% ZrO, e greater than or equal to 2.5 mol.% and less than or equal to 10.0 mol.% Nb.Os, e greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Ba0, e greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% CaO, e greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Ga20;, e greater than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Y,03 and e greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% WO:. 4. The glass of any one of clauses 1-3, wherein the composition of the components comprises: e greater than or equal to 22.0 mol.% and less than or equal to 25.0 mol.% TiO,, e greater than or equal to 20.0 mol.% and less than or equal to 30.0 mol.% La203, e greater than or equal to 16.0 mol.% and less than or equal to 20.0 mol.% B,0s,

e greater than or equal to 10.0 mol.% and less than or equal to 20.0 mol.% SiO», e greater than or equal to 6.5 mol.% and less than or equal to 8.0 mol.% ZrO, e greater than or equal to 5.0 mol.% and less than or equal to 6.7 mol.% Nb20;, e greater than or equal to 0.0 mol.% and less than or equal to 6.0 mol.% Y20;3, se greater than or equal to 0.0 mol.% and less than or equal to 3.0 mol.% BaO and e greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% Gd:03 and e greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% of alt other components in total. 5. The glass of any one of clauses 1-4, wherein the glass satisfies the conditions: e 45<Py<55and e 195<P,<207. 6. The glass of any one of clauses 1-5, wherein when cooled in air from 1100 °C to 500 °C in 2.5 minutes, the glass does not crystallize. 7. A glass comprising a plurality of components, the glass having a composition of the components comprising: e greater than or equal to 1.0 mol.% and less than or equal to 13.5 mol.% ZrO,, e greater than or equal to 0.3 mol.% and less than or equal to 35.0 mol.% TiO, e greater than or equal to 0.3 mol.% and less than or equal to 29.5 mol.% B,0s, e greater than or equal to 0.0 mol.% and less than or equal to 9.0 mol.% WO:;, e greater than or equal to 0.0 mol.% and less than or equal to 5.0 mol.% PbO, e greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% Gd:03, e greater than or equal to 0.0 at.% and less than or equal to 2.0 at.% F, e asum of TiO2 + Nb,Os + La20: greater than or equal to 10.0 mol.% and less than or equal to 70.0 mol.%, e asum of Si0: + B203 + P,0s greater than or equal to 10.0 mol.%, es asum of RExOa + WO; + ZrO, greater than or equal to 5.0 mol.%, eo asum of SiO; + Y203 + Gd20: greater than or equal to 0.3 mol.%, e asum of V20s + MoO; greater than or equal to 0.0 mol.% and less than or equal to 3.0 mol.% and + optionally comprising one or more components selected from Bi203, CaO, BaO, ZnO, Na20,

Al203, Li2O, GeO;, Te, K20, SrO and MEO,

wherein the composition of the components satisfies the conditions: e TiO, / (TiO; + NbyOs + WO; + Bi203) [mol.%] > 0.050, e SiO2 + B;0; - P20; [mol.%] > 1.0 and e 1a203/TiO0: [mol.%] < 1.5, and wherein the glass satisfies the condition: e P‚-{(1.99 + 0.083 * (TiO: / (TiO2 + Nb20s + WO: + Bi203)}} > 0.000, where e P‚isa parameter predicting a refractive index at 587.56 nm, na, calculated from the glass composition in terms of mol.% of the components according to the Formula (1):

Pa= 1.844 + 0.0054162 * La203 + 0.0031113 * TiO, -0.004212 * B,0:3 - 0.0035692 * SiO2 + 0.0027887 * ZrO + 0.0078026 * Nb;0; - 0.00012928 * CaO + 0.00076566 * BaO + 0.0043601 * Y203 + 0.00067408 * ZnO + 0.0068029 * Gd,0s - 0.0025106 * Na20 + 0.0039937 * WO; - 0.0043208 *

Al203 - 0.0011666 * Li;O + 0.0051727 * PbO + 0.012958 * Bi20: - 0.0018753 * GeO; - 0.0014084 * 0

MgO, where REnO, is a total sum of rare earth metal oxides, and an asterisk (*) means multiplication. 8. The glass of clause 7, wherein the glass satisfies the condition: * ng-(1.99+ 0.083 * (TiO, / (TiO; + Nb,Os + WO: + Bi203)}) > 0.000, where e nd is a refractive index at 587.56 nm. 9. The glass of any one of clauses 7-8, wherein the composition of the components satisfies the condition: e 0.38 <Si0; / (SiO2 + B203} [mol.%] < 0.75. 10. The glass of any one of clauses 7-9, wherein the composition of the components comprises: e greater than or equal to 22.0 mol.% and less than or equal to 25.0 mol.% TiO, e greater than or equal to 20.0 mol.% and less than or equal to 30.0 mol.% La203, e greater than or equal to 16.0 mol.% and less than or equal to 20.0 mol.% B:20;3, e greater than or equal to 10.0 mol.% and less than or equal to 20.0 mol.% SiO, oe greater than or equal to 6.5 mol.% and less than or equal to 8.0 mol.% ZrO, e greater than or equal to 5.0 mol.% and less than or equal to 6.7 mol.% Nb,Os,

e greater than or equal to 0.0 mol.% and less than or equal to 6.0 mol.% Y203 and e greater than or equal to 0.0 mol.% and less than or equal to 3.0 mol.% BaO and e greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% of all other components in total. 11. The glass of any one of clauses 7-10, wherein the glass satisfies the conditions: e 45<Py<55and e 195<P,<2.07, where e Paisa parameter predicting a density at room temperature, dar, calculated from the glass composition in terms of mol.% of the components according to the Formula (li):

Pa = 4.688 + 0.047868 * La203 - 0.0065829 * TiO; - 0.027601 * B20:3 - 0.022365 * SiO, + 0.016475 *

ZrO, - 0.0052977 * Nb,Os - 0.0030466 * CaO + 0.014971 * BaO + 0.019511 * Y;0: + 0.0076377 *

ZnO + 0.066160 * Gd,0s5 - 0.016932 * Na,O + 0.025764 * WO; - 0.035116 * Al;0: - 0.0094315 * (1).

Li»O + 0.047388 * PbO + 0.080813 * Bi;03 - 0.0088118 * GeO, + 0.072296 * Er,0; + 0.078888 *

Yb,03 - 0.026242 * K,0 + 0.010351 * SrO - 0.0030424 * MgO, 12. The glass of any one of clauses 7-11, wherein when cooled in air from 1100 °C to 500 °C in 2.5 minutes, the glass does not crystallize. 13. A glass comprising a plurality of components, the glass having a composition of the components comprising: e greater than or equal to 0.5 mol.% and less than or equal to 45.0 mol.% B,0;, e greater than or equal to 0.1 mol.% and less than or equal to 25.0 mol.% Bi203, e greater than or equal to 0.0 mol.% and less than or equal to 8.0 mol.% WO;, e asum of SiO; + B203 + P2O; greater than or equal to 10.0 mol. %, e asum of TiO, + Nb,Os greater than or equal to 8.5 mol.%, e asum of REnO, + WO; + ZrO; greater than or equal to 4.5 mol.% and » optionally comprising one or more components selected from CaO, BaO, ZnO, Na20, AkO3, Li,O,

PbO, GeO, TeO:, KO, SrO and MgO, wherein the composition of the components satisfies the condition: e SiO; + B,0s - P;Os [mol.%] > 0.100, and the glass satisfies the condition:

oe P,>2.045, where e P,is a parameter predicting a refractive index at 587.56 nm, ng, calculated from the glass composition in terms of mol.% of the components according to the Formula (1):

P,= 1.844 + 0.0054162 * La203 + 0.0031113 * TiO, - 0.004212 * B,0; - 0.0035692 * SiO, + 0.0027887 * ZrO, + 0.0078026 * Nb,0s - 0.00012928 * CaO + 0.00076566 * BaO + 0.0043601 * Y,0; +0.00067408 * ZnO + 0.0068029 * Gd203 - 0.0025106 * Na,O + 0.0039937 * WO: - 0.0043208 *

MgO, where REO, is a total sum of rare earth metal oxides and an asterisk (*) means multiplication. 14. The glass of clause 13, wherein the glass has + arefractive index at 587.56 nm, nq that is greater than or equal to 2.045. 15. The glass of any one of clauses 13-14, wherein the composition of the components satisfies the condition: e 0.38 <Si0; / (SiO; + B03) [mol.%] < 0.75. 16. The glass of any one of clauses 13-15, wherein the composition of the components comprises: s greater than or equal to 22.0 mol.% and less than or equal to 25.0 mol. % TiO, e greater than or equal to 20.0 mol.% and less than or equal to 30.0 mol.% La, 0s, e greater than or equal to 16.0 mol.% and less than or equal to 20.0 mol.% B203, e greater than or equal to 10.0 mol.% and less than or equal to 20.0 mol.% SiO, e greater than or equal to 6.5 mol.% and less than or equal to 8.0 mol.% ZrO, oe greater than or equal to 5.0 mol.% and less than or equal to 6.7 mol.% Nb, Os, e greater than or equal to 0.0 mol.% and less than or equal to 6.0 mol.% Y,0;, e greater than or equal to 0.0 mol.% and less than or equal to 3.0 mol.% BaO and e greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% Gd,0; and e greater than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% of all other components in total. 17. The glass of any one of clauses 13-16, wherein the glass satisfies the conditions:

e 45<Py<55and e 2045<P, 52.07, where e Pgis a parameter predicting a density at room temperature, der, calculated from the glass composition in terms of mol.% of the components according to the Formula (i):

Ps = 4.688 + 0.047868 * La203 - 0.0065829 * TiO, - 0.027601 * B,03 - 0.022365 * SiO, + 0.016475 *

ZrO; - 0.0052977 * Nb,Os - 0.0030466 * CaO + 0.014971 * BaO + 0.019511 * Y;0: + 0.0076377 *

ZnO + 0.066160 * Gd203 - 0.016932 * Na20 + 0.025764 * WO; - 0.035116 * Al,03 - 0.0094315 * (1).

LiO + 0.047388 * PbO + 0.080813 * Bi203 - 0.0088118 * GeO; + 0.072296 * Er203 + 0.078838 *

Yb,0; - 0.026242 * K,0 + 0.010351 * SrO - 0.0030424 * MgO, 18. The glass of any one of clauses 13-17, wherein when cooled in air from 1100 °C to 500 °C in 2.5 minutes, the glass does not crystallize.

Claims

CONCLUSIONS

1. Glass comprising a plurality of components, wherein the glass comprises a composition of the components, wherein the composition comprises: e more than or equal to 12.0 mol.% and less than or equal to 35.0 mol.% TiO, es more than or equal to 2.5 mol.% and less than or equal to 20.0 mol.% Zr0,, e more than or equal to 0.5 mol.% and less than or equal to 40.0 mol.% B203, e more than or equal to 0.5 mol. % and less than or equal to 30.0 mol.% Nb20,;, e more than or equal to 0.0 mol.% and less than or equal to 20.0 mol.% Bi203, e more than or equal to 0.0 mol.% and less than or equal to 15.0 mol.% P:0s, es more than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Al:03, e more than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Gd:0;, e more than or equal to 0.0 mol.% and less than or equal to 8.0 mol.% WO;, e more than or equal to 0.0 mol.% and less than or equal to 5.0 mol.% PbO, e more than or equal to 0.0 mol.% and less than or equal to 5.0 mol.% V2O;, es more than or equal to 0.0 mol.% and less than or equal to 1.5 mol.% ZnO, e more than or equal to 95.0 mol.% RmO,, e more than or equal to 0.5 mol.% and less than or equal to 35.0 mol.% REO, e a sum of SiO; + B20:3 + PO; that is more than or equal to 10.0 mol.% and e is a sum of TiO, + Nb20s that is more than or equal to 0.0 mol.% and less than or equal to 42.0 mol.%, where the composition of the components meet the conditions: 9 SiO; + B03 - P2Os [mol.%] > 0.000, and where the glass meets the condition: e P,-(1.765 + 0.057 * Py) > 0.000, where e P, is a parameter that predicts a refractive index at 587.56 nm, ny, which is calculated from the glass composition expressed in mol% of the components according to formula (1):

Po = 1.844 + 0.0054162 * La203 + 0.0031113 * TiO, - 0.004212 * B,0:3 - 0.0035692 * SiO2 +

0.0027887 * ZrO, + 0.0078026 * Nb»Os - 0.00012928 * CaO + 0.00076566 * BaO + 0.0043601 * Y,0;

+0.00067408 * ZnO + 0.0068029 * Gd:03 - 0.0025106 * Na20 + 0.0039937 * WO; - 0.0043208 * ALO; - 0.0011666 * Li,O + 0.0051727 * PbO + 0.012958 * Bi203 - 0.0018753 * GeO, - 0.0014084 * 0 TeO; + 0.0086647 * Er.03 + 0.0097345 * Yb203 - 0.0038734 * K.0 - 0.00041776 * SrO - 0.0017294 * MgO, e and Py is a parameter that predicts a room temperature density, dr, which is calculated from the glass composition expressed in moles .% of the components according to formula (11): Ps = 4.688 + 0.047868 * La203 - 0.0065829 * TiO, - 0.027601 * B.03 - 0.022365 * SiO, + 0.016475 * ZrO; - 0.0052977 * Nb,Os - 0.0030466 * CaO + 0.014971 * BaO + 0.019511 * Y203 + 0.0076377 * ZnO + 0.066160 * Gd:03 - 0.016932 * Na20 + 0.025764 * WO; - 0.035116 * ALO; - 0.0094315 * Li,O (HH)

+0.047388 * PbO + 0.080813 * Bi»0; - 0.0088118 * GeO, + 0.072296 * Er,03 + 0.078888 * Yb,0; -

0.026242 * K,0 + 0.010351 * SrO - 0.0030424 * MgO, where RO, is a total sum of all oxides, REO, is a total sum of rare earth oxides and an asterisk (*} means multiplication.

2. Glass according to claim 1, wherein the glass meets the condition: eng- (1.765 + 0.057 * dr) > 0.000, where eng is a refractive index at 587.56 nm, ehr [g/cm] is a density at room temperature .

3. Glass according to any one of claims 1-2, wherein the composition of the components comprises: e more than or equal to 20.0 mol.% and less than or equal to 27.5 mol.% TiO2, e more than or equal to 15.0 mol. .% and less than or equal to 30.0 mol.% La203, e more than or equal to 15.0 mol.% and less than or equal to 22.5 mol.% B203, e more than or equal to 5.0 mol.% and less than or equal to 20.0 mol.% SiO, e more than or equal to 4.0 mol.% and less than or equal to 9.0 mol.% ZrO, e more than or equal to 2.5 mol.% and less than or equal to 10.0 mol.% Nb:0;, e more than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% BaO, e more than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% CaO, e more than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Ga:0;3, e more than or equal to 0.0 mol.% and less than or equal to 10.0 mol.% Y,0; and e more than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% WO:.

Glass according to any one of claims 1-2, wherein the composition of the components comprises: es more than or equal to 22.0 mol.% and less than or equal to 25.0 mol.% TiO,, e more than or equal to 20.0 mol.% and less than or equal to 30.0 mol.% La2O;, e more than or equal to 16.0 mol.% and less than or equal to 20.0 mol.% B203, e more than or equal to 10.0 mol.% and less than or equal to 20.0 mol.% SiO, e more than or equal to 6.5 mol.% and less than or equal to 8.0 mol.% ZrO,, es more than or equal to 5.0 mol.% and less than or equal to 6.7 mol.% NbOs, e more than or equal to 0.0 mol.% and less than or equal to 6.0 mol.% Y20;, e more than or equal to 0.0 mol.% and less than or equal to 3.0 mol.% BaO and e more than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% Gd,0; and e more than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% of all other components in total.

5. Glass according to any one of claims 1-4, wherein the glass meets the conditions: e 45<Py<55 and e 195<P,<2.07.

Glass according to any one of claims 1 to 5, wherein the glass does not crystallize when cooled in air from 1100°C to 500°C in 2.5 minutes.

7. Glass comprising a plurality of components, wherein the glass comprises a composition of the components, wherein the composition comprises: es more than or equal to 1.0 mol.% and less than or equal to 13.5 mol.% Zr0,, e more than or equal to 0.3 mol.% and less than or equal to 35.0 mol.% TiO2, e more than or equal to 0.3 mol.% and less than or equal to 29.5 mol.% B203, es more than or equal to 0.0 mol .% and less than or equal to 9.0 mol.% WQs, e more than or equal to 0.0 mol.% and less than or equal to 5.0 mol.% PbO, es more than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% Gd:03, e more than or equal to 0.0 at.% and less than or equal to 2.0 at.% F, e a sum of TiO; + Nb20;s + La,0; which is more than or equal to 10.0 mol.% and less than or equal to 70.0 mol.%,

e a sum of SiO; + B203 + P2Os which is more than or equal to 10.0 mol.%, e a sum of REnO, + WO; + ZrQ; which is more than or equal to 5.0 mol.%, e sum of SiO: + Y2 O3 + Gd,0; which is more than or equal to 0.3 mol.%, e a sum of V,0s + MoO; which is more than or equal to 0.0 mol.% and less than or equal to 3.0 mol.% and optionally one or more components selected from Bi2O3, CaO, BaO, ZnO, Na:0, Al;0 ;, Li2O0, GeO;, TeO,, K20, SrO and MgO, where the composition of the components meets the conditions: e TiO, / (TiO; + NbyOs + WO: + Bi203) [mol.%] > 0.050, ash SiO:+B203-P:0; [mol.%] > 10 and e 1a203/TiO0: [mol.%] < 1.5, and where the glass meets the condition: e P‚-{1.99 +0.083 * (TiO / (TIO; + Nb2Os + WO: + Bi203))) > 0.000, where e P, is a parameter predicting a refractive index at 587.56 nm, ny, calculated from the glass composition expressed in mol% of the components according to formula (I): Pa= 1.844 + 0.0054162 * La203 + 0.0031113 * TiO; -0.004212 * B.03 - 0.0035692 * SiO, +

0.0027887 * ZrO, + 0.0078026 * Nb.Os - 0.00012928 * CaO + 0.00076566 * BaO + 0.0043601 * Y203

+ 0.00067408 * ZnO + 0.0068029 * Gd,0s - 0.0025106 * Na20 + 0.0039937 * WO; - 0.0043208 * Al203 - 0.0011666 * Li;O + 0.0051727 * PbO + 0.012958 * Bi;0s - 0.0018753 * GeO; - 0.0014084 * 0 TeO; + 0.0086647 * Er.03 + 0.0097345 * Yb203 - 0.0038734 * K.0 - 0.00041776 * SrO - 0.0017294 * MgO, where REO, is a total sum of rare earth oxides and an asterisk {*) means multiplication.

8. Glass according to claim 7, wherein the glass meets the condition: e ng- (1.99 + 0.083 * (TiO: / (TiO; + Nb20s + WO; + Bi20:)}) > 0.000, where e ng is a refractive index at is 587.56 nm.

8. Glass according to any one of claims 7-8, wherein the composition of the components meets the condition:

e 0.38 <SiO0; / (SiOz + B203} [mol.%] < 0.75.

Glass according to any one of claims 7-9, wherein the composition of the components comprises: e more than or equal to 22.0 mol% and less than or equal to 25.0 mol% TiO, e more than or equal to 20.0 mol.% and less than or equal to 30.0 mol.% La,0;, es more than or equal to 16.0 mol.% and less than or equal to 20.0 mol.% B203, e more than or equal to 10.0 mol.% and less than or equal to 20.0 mol.% SiO,, es more than or equal to 6.5 mol.% and less than or equal to 8.0 mol.% ZrO;, e more than or equal to 5.0 mol.% and less than or equal to 6.7 mol.% Nb20;s, e more than or equal to 0.0 mol.% and less than or equal to 6.0 mol.% Y203 and e more than or equal to 0.0 mol.% and less than or equal to 3.0 mol .% BaO and e more than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% of all other components in total.

11. Glass according to any one of claims 7-10, wherein the glass meets the conditions: e 45<Py<55 and e 195<P,<2.07, where e P is not a parameter that predicts a density at room temperature, der, which is calculated from the glass composition expressed in mol.% of the components according to formula (II): Pa = 4.688 + 0.047868 * La203 - 0.0065829 * TiO, - 0.027601 * B203 - 0.022365 * SiO, + 0.016475 * Zr0; - 0.0052977 * Nb20s - 0.0030466 * CaO + 0.014971 * BaO + 0.019511 * Y203 + 0.0076377 * ZnO + 0.066160 * Gd;03 - 0.016932 * Na20 + 0.025764 * WO: - 0.0 35116 * Al,O; - 0.0094315 * (1). Li2o + 0.047388 * PBO + 0.080813 * BI, 0s - 0.008118 * Geo, + 0.072296 * Er, 03 + 0.07888 * YB20: - 0.026242 * K; O + 0.010351 * MGO,

Glass according to any one of claims 7-11, wherein the glass does not crystallize when cooled in air from 1100°C to 500°C in 2.5 minutes.

13. Glass comprising a plurality of components, wherein the glass comprises a composition of the components, wherein the composition comprises: e more than or equal to 0.5 mol.% and less than or equal to 45.0 mol.% B,0;, e more than or equal to 0.1 mol.% and less than or equal to 25.0 mol.% Bi203, es more than or equal to 0.0 mol.% and less than or equal to 8.0 mol.% WO;3,

e a sum of SiO; + B203 + P2Os which is more than or equal to 10.0 mol.%, e a sum of TiO; + Nb,Os which is more than or equal to 8.5 mol.%, e a sum of REmOn + WO: + ZrO; which is more than or equal to 4.5 mol.% and optionally one or more components selected from CaO, BaO, ZnO, Na2O, Al;O3, Li2O, PbO, Ge0:, Te0,, K20, SrO and MgO , where the composition of the components meets the condition: 9 SiO; + B203 - P2Os [mol.%] > 0.100, and the glass meets the condition: e P> 2.045, where e is a Peen parameter predicting a refractive index at 587.56 nm, na, which is calculated from the glass composition expressed in mol.% of the components according to formula {I}: Pa= 1.844 + 0.0054162 * La203 + 0.0031113 * TiO, -0.004212 * B,0:3 - 0.0035692 * SiO2 +

0.0027887 * ZrO, + 0.0078026 * Nb2Os - 0.00012928 * CaO + 0.00076566 * BaO + 0.0043601 * Y203

+0.00067408 * ZnO + 0.0068029 * Gd:03 - 0.0025106 * Na20 + 0.0039937 * WO; - 0.0043208 * Al203 - 0.0011666 * Li,O + 0.0051727 * PbO + 0.012958 * Bi,0: - 0.0018753 * GeO, - 0.0014084 * 0 TeO2 + 0.0086647 * Er,03 + 0.0097345 * Y b203 - 0.0038734 * KO - 0.00041776 * SrO - 0.0017294 * MgO, where REO, is a total sum of rare earth oxides and an asterisk (*) means multiplication.

The glass of claim 13, wherein the glass has: * a refractive index at 587.56 nm, ng, that is greater than or equal to 2.045.

15. Glass according to any one of claims 13-14, wherein the composition of the components meets the condition:

e 0.38 <Si0, / (SiO; + B03) [mol.%] < 0.75.

16. Glass according to any one of claims 13-15, wherein the composition of the components comprises: e more than or equal to 22.0 mol.% and less than or equal to 25.0 mol.% TiO, e more than or equal to 20.0 mol. .% and less than or equal to 30.0 mol.% La2O;, e more than or equal to 16.0 mol.% and less than or equal to 20.0 mol.% B203, e more than or equal to 10.0 mol.% and less than or equal to 20.0 mol.% SiO,

e more than or equal to 6.5 mol.% and less than or equal to 8.0 mol.% ZrO, e more than or equal to 5.0 mol.% and less than or equal to 6.7 mol.% Nb,0s, e more than or equal to 0.0 mol.% and less than or equal to 6.0 mol.% Y203, e more than or equal to 0.0 mol.% and less than or equal to 3.0 mol.% BaO and es more than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% Gd.0; and e more than or equal to 0.0 mol.% and less than or equal to 2.0 mol.% of all other components in total.

17. Glass according to any one of claims 13-16, wherein the glass meets the conditions: s 45<Py<55 and eo 2.045<P,<2.07, where e P4 is a parameter that predicts a density at room temperature, dar, which is calculated from the glass composition expressed in mol.% of the components according to formula (li): Pa = 4.688 + 0.047868 * La203 - 0.0065829 * TiO, - 0.027601 * B.03 - 0.022365 * SiO, +0.016475 * ZrO, - 0.0052977 * Nb,Os - 0.0030466 * CaO + 0.014971 * BaO + 0.019511 * Y,03 + 0.0076377 * ZnO + 0.066160 * Gd, 0; - 0.016932 * Na,0 + 0.025764 * WO: - 0.035116 * ALO; - 0.0094315 * (1. Li2O + 0.047388 * PbO + 0.080813 * Bi, 0; - 0.0088118 * GeO, + 0.072296 * Er,0; + 0.078888 * Yb,0s - 0.026242 * K,0 + 0.010351 * SrO - 0.0030424 * MgO ,

Glass according to any one of claims 13-17, wherein the glass does not crystallize when cooled in air from 1100°C to 500°C in 2.5 minutes.