MXPA06004590A

MXPA06004590A - Stable compositions of spores, bacteria and/or fungi.

Info

Publication number: MXPA06004590A
Application number: MXPA06004590A
Authority: MX
Inventors: Lisa M Sanders
Original assignee: Ecolab Inc
Priority date: 2003-10-24
Filing date: 2004-10-18
Publication date: 2006-07-05
Also published as: AU2004284445B2; AU2004284445A1

Abstract

The present invention relates to a stable cleaning composition including a borate salt and spores (bacterial or fungal), vegetative bacteria, or fungi. The composition can also include a polyol.

Description

STABLE COMPOSITIONS OF SPPORES, BACTERIA AND / OR FUNGI FIELD OF THE INVENTION The present invention relates to a stable cleaning composition that includes a salt of borate and spores (bacterial or fungal), vegetative bacteria, or fungi and methods for using the composition. The composition may also include a polyol. BACKGROUND OF THE INVENTION Spores, bacteria and fungi play an important role in cleaning compositions, particularly those used to clean drains and collectors or grease traps. The present cleaning compositions that include spores, bacteria or fungi are typically provided as a "two-part" product with a container of the biological component and a second container of the chemical cleaners. The mixing of chemical cleaners and biological components and then the storage of the mixture is not possible due to the adverse effects of chemicals on spores, bacteria or fungi. There remains a need for stable cleaning compositions (eg, "one-part" compositions) that include both chemical cleansers such as spores, bacteria or fungi. BRIEF DESCRIPTION OF THE INVENTION The present invention relates to a stable cleaning composition that includes a salt of borate and spores (bacterial or fungal), vegetative bacteria or fungi and to methods for using the composition. The composition may also include a polyols. In one embodiment, the present invention includes borate salt and an effective cleaning amount of spores, bacteria or fungi. The borate salt may include an alkanolamine borate. The borate salt and / or composition may be substantially free of sodium ions. In one embodiment, the present composition can provide a preparation that includes spores (bacterial or fungal), vegetative bacteria or fungi having adequate stability at a pH greater than or equal to 9. In one embodiment, the present composition can provide a preparation that includes spores (bacterial or fungal), vegetative bacteria or fungi having adequate stability up to about 65% by weight of water. A cleaning composition according to the present invention may also include one or more nonionic surfactants, silicone surfactants, anionic surfactant and a hydrotrope. The cleaning composition can include one or more nonionic surfactants from about 0.003 to about 35% by weight, a silicone surfactant from about 0.0005 to about 35% by weight, an anionic surfactant from about 0.003 to about 35% by weight and a hydrotrope from about 0.001 to about 20% by weight. The cleaning composition may include nonionic surfactant and silicone surfactant. The cleaning composition may include from about 0.5 to about 35% by weight of nonionic surfactant and from about 0.1 to about 35% by weight of silicone surfactant. The present method can include the application of a composition according to the present invention to a surface or object to be cleaned. The applied composition may be a microbial composition or a stabilized cleaning composition. The surface or object to be cleaned may include one or more of a floor, a drain or a floor drain. In one embodiment, the present method can include increasing the coefficient of friction of a surface. In one embodiment, the present invention may include cleaning of cements. In one embodiment, the surface or cement is a floor or floor material.

BRIEF DESCRIPTION OF THE FIGURES Figure 1 illustrates weakly obtained results for the coefficient of friction (slip resistance) measurements for mosaics in restaurant kitchens. Figures 2A and 2B illustrate that the present composition cleaned enamelled on a quarry tile floor in a restaurant kitchen. Figure 2A illustrates the floor before the application of the present composition. Figure 2B illustrates the floor after application of the present composition. Figure 3 illustrates a portion of a floor cleaned with a conventional cleaning composition (left) and a portion cleaned with a composition according to the present invention.

DETAILED DESCRIPTION OF THE INVENTION Definitions As used herein, "bacterial preparation" refers to a composition that includes bacterial spores and / or vegetative bacteria, which can be provided in a preservative. The preservative may include, for example, any of a variety of preservative compositions used in preparations of commercially supplied spores (bacterial or fungal), vegetative bacteria or fungi. Such preservatives may include, for example, a chelant, a surfactant, a buffer, water or the like. The microbial preparation, for example, can digest or degrade society such as fat, oil, mineral fat, sugar, protein, carbohydrates or the like. As used herein, percent weight (% -p), percent by weight,% by weight and the like are synonyms that refer to the concentration of a substance as the weight of that substance divided by the weight of the composition and multiplied by 100. As used herein, boric acid salt and borate salt are used interchangeably to refer to a salt such as potassium borate, monoethanolamine borate or another salt obtained by or which may be visualized as being obtained by neutralization of boric acid. The weight percent of a boric acid salt or borate salt in a composition of the present invention can be expressed either as a percentage weight of the ion containing negatively charged boron, for example, the portions of borate and / or boric acid , or as the percentage weight of the entire boric acid salt, for example, both the negatively charged portion and the positively charged portion. Preferably, the percentage weight refers to the whole salt of boric acid. The per hundred by weight of cyclic acid salts, or other acid salts, may also be expressed in these forms, preferably with reference to the entire salt of the acid. As used herein, the term "total boron compound" refers to the sum of the borate and boric acid moieties. As used herein, "basic or alkaline pH" refers to a pH greater than 7, greater than or equal to 8, from about 8 to about 9.5, from about 8 to about 11, greater than about 9, or about 9. to approximately 10.5. As used herein, substantially free of sodium ion refers to a composition that includes less than about 1% sodium ion. The embodiments of compositions according to the present invention may include less than 1% by weight of sodium ion, less than 0.75% by weight of sodium ion, less than 0.5% by weight of sodium ion, less than 0.25% by weight. weight of sodium ion, less than 0.2% by weight of sodium ion, less than 0.15% by weight of sodium ion, less than 0.1% by weight of sodium ion, less than 0.05% by weight of sodium ion. Each of these quantities can be modified by the term "approximately". As used herein, the terms "floor material" or "floor" refers to any horizontal surface on which a person may walk. A material for floor or floor can be made of an inorganic material, such as ceramic mosaic or natural stone (for example, quarry mosaic), or an organic material, such as epoxy, a polymer, a rubber or an elastic material . The material for floor or floor can be in any of a variety of environments, such as a restaurant (for example, a fast food restaurant), an establishment for processing and / or preparing food, a slaughterhouse or trail, a plant of packing, a plant for the production of organic fats, a kitchen or the like. As used herein, the phrases "coefficient of friction" and "slip resistance" can be defined with respect to any of a variety of standard publications, such as ASTM Standard D-2047, "Coefficient of Static Friction of Floor Surfaces Coated with Wax According to Measurement by James Machine" and a report by the ASTM Committee D-21 that indicated that a floor that has a static friction coefficient of not less than 0.5 as measured by this test is recognized to provide a non-hazardous walking surface. This value is rated in NBS Technical Note 895"A General Perspective of Floor Slip Resistance, with Annotated Bibliography "by Robert J. Brungraber, where it is indicated that the value of 0.5 provides a safety factor and that most people, who stride normally, would be unlikely to slip on surfaces for which the value is greater than 0.3 to 0.35 Other important and similar standards include ANSI 1264.2-2001, ASTM C1028-89, ASTM F1679-00 (which refers to the English XL Tribometer), Test Method F1677-96 of ASTM, and UL 410 ( 1992) Each of the standards in this paragraph is hereby incorporated by reference, as used herein, the term "approximately" which modifies the amount of an ingredient in the compositions of the invention or used in the methods of the invention relates to the variation that may occur in the numerical quantity, for example, by means of typical methods of measuring and handling the materials used to make the concentrates or the solutions of use in the real world; by differences in the manufacture, source or purity of the ingredients used to make the compositions or carry out the methods; and the similar ones. Modified or not by the term "approximately", the claims include equivalents of the amounts. Stabilized Microbial Preparation The present invention relates to a stabilized microbial preparation that includes a borate salt and microbes. The microbes can be in the form of spores (bacterial or fungal), vegetative bacteria or fungi. The microbial preparation may include, for example, spores or mixture of spores that can digest or degrade dirt such as fat, oils (eg, vegetable oils or animal fat), proteins, carbohydrates or the like. The microbial preparation can also produce enzymes that aid in the degradation of dirt such as mineral fat, oil, fat, proteins, carbohydrates or the like. The borate salt may include any of a variety of boric acid salts, for example, certain alkali metal salts or alkanolamine salts. The boric acid salt can provide a source of alkalinity for a cleaning composition that includes the stabilized microbial preparation. The boric acid salt can provide advantageous stability to the microbial preparation as compared to a conventional microbial preparation employed, for example, in cleaning compositions. Conventional microbial preparations that start with, for example, 104 live bacteria or spores, after four months, may contain only 103 or even only 1 O2 of living organisms. That is, they lose one or two logs of active organisms, which can decrease the amount of dirt removed, digested or degraded. In one embodiment, the stabilized microbial preparations present lose less than one or two logs, or less than one log, of activity for four months. This provides a longer shelf life for the product that contains the microbial preparation. In one embodiment, the present stabilized microbial preparation is a component of a cleaning composition.

Although not limited to the present invention, the microbial preparation can be viewed as a source of cleaning enzyme or detergent in the cleaning composition. Such a cleaning composition may also include additional enzymes, not produced by the microbial preparation in situ. The microbial preparation can produce, for example, enzymes such as proteases, lipases and / or amylases. The composition may also include other added enzymes such as, for example, proteases, lipases and / or amylases. Although not limiting to the present invention, the added enzymes can be seen as providing immediate cleaning by application of the cleaning composition and the microbial preparation can be seen as a persistent cleaning provider since the microbes remain in the article to be cleaned, even after rinsing. Most cleaners can only provide dirt removal which is really just moving the dirt from one surface or location (for example, one floor) to another (for example, a drain). In certain embodiments, the cleaning compositions included in the present stabilized microbial preparation can provide both soil removal and persistent dirt reduction by persistent enzymatic breakdown of dirt. Cleaning compositions including the present stabilized microbial preparations can be used for a variety of purposes, including as a floor cleaner, a cement cleaner, such as a floor and drain cleaner and grease degreaser / digestive in combination, as a digestive fat in grease traps, for treatment of effluents and / or waste water (for example, reduction of fats, oils and mineral fats), in the municipal water treatment, as a fat digestive in treatment plants, or for black and gray water treatment on cruise ships. Although not limiting to the present invention, it is believed that stable microbial present compositions can undo grease or oil on a surface. Breaking the grease or oil can release other dirt stuck in the grease or oil. Accordingly, the present composition can clean a surface. In one embodiment, the present invention includes a method that includes repeating the application of the present stable microbial composition. For example, the present method may include the daily application. The application for 5 to 14 days can clean a slightly dirty surface. The application for three to six weeks can clean a very dirty surface. Boric Acid Salts The present invention relates to a stable microbial cleaning composition that employs one or more boric acid salts to provide improved stability of the microbial preparation, even at basic pH. Suitable boric acid salts can provide alkalinity to the stable microbial cleaning solution. Such salts include boric acid alkali metal salts; boric acid salts of amine, preferably boronic acid alkanolamine salts; and the like; or a combination thereof. In certain embodiments, the boric acid salt includes potassium borate, monoethanolammonium borate, diethanolammonium borate, triethanolammonium borate, and the like, or a combination thereof. In one embodiment, the boric acid salt includes monoethanolamine borate. The boric acid salt, for example potassium borate or monoethanolamine, can be obtained by any of a variety of routes. For example, the commercially available boric acid salt, for example, potassium borate, can be added to the composition. Alternatively, the boric acid salt, for example potassium borate or monoethanolamine, can be obtained by neutralizing boric acid with a base, for example, a potassium-containing base such as potassium hydroxide or a base such as monoethanolamine. In certain modalities, the boric acid salt is soluble in the composition of the invention in concentrations in excess of 5 or 10% by weight, for example, in excess of 11, 12, 13, 14, 15, 16, 17, 18, 19 or 20% by weight. The boric acid salt in the present compositions can be used in a maximum concentration up to its solubility limit. In certain embodiments, the boric acid salt can be soluble in the composition of the invention in concentrations up to 35% by weight, for example, up to 25, 30 or 35% by weight. In certain embodiments, the boric acid salt may be soluble from 12 to 35% by weight, from 15 to 30% by weight, or from 20 to 25% by weight, preferably from 20 to 25% by weight. The present compositions may also include any of the amounts or ranges of boric acid salt modified by the term "about". In one embodiment, alkanolamine borates, such as monoethanolamine borate, are soluble in higher concentrations than other salts of boric acid, particularly sodium borate. Alkanolamine borates, such as monoethanolamine borate, can be employed and are soluble in cleaning compositions present in the concentrations listed above, preferably up to about 30% by weight, preferably from about 20 to about 25% by weight . In one embodiment, this high solubility can be obtained at an alkaline pH, such as pH from about 9 to about 10.5. In one embodiment, potassium borate is soluble in higher concentrations than other metal salts of boric acid, particularly other alkali metal salts of boric acid, particularly sodium borate. Potassium borate can be employed and is soluble in the present enzyme cleaning compositions in the concentrations listed above, preferably up to about 25% by weight, preferably from about 15 to about 25% by weight. In one embodiment, this high solubility can be obtained at an alkaline pH, such as a pH from about 9 to about 10.5. The boric acid salt can provide desirable increases in the stability of the microbial preparation at a basic pH compared to other buffer systems suitable for maintaining a pH above about 7, above about 8, about 8 to about 11. , or from about 9 to about 10.5. Maintaining the alkaline pH can provide greater cleaning power. The present composition with stable bacteria may be substantially free of sodium ion. Advantageously, in compositions substantially free of sodium ion, the borate salts are soluble in higher concentrations than in the presence of the sodium ion. Unfortunately, sodium ion is a common counter ion for salts. Therefore, care must be taken to provide compositions according to the present invention that are substantially free of sodium ion. For example, compositions substantially free of sodium ion in accordance with the present invention can be made from the acidic forms of reagents, which are neutralized, as appropriate, by an alkanolamine or potassium hydroxide. For example, compositions substantially free of sodium ion according to the present invention can be made from salts other than sodium salts, for example potassium or alkanolamine salts. In one embodiment, the present compositions include sodium ion at a level at which sodium borate does not precipitate from the composition. One way to achieve such low sodium levels is to exclude the sodium salts from the composition or to exclude the sodium salts except the amphoteric surfactant. Preferably, even with sodium of an amphoteric surfactant the composition of the present invention is substantially free of sodium ion. The present cleaning compositions substantially free of sodium ion may include borate salts up to concentrations of about 35% by weight, for example, from about 15 to about 30% by weight. In one embodiment, this high solubility can be obtained at an alkaline pH, such as pH from about 9 to about 10.5. Compositions including borate salts and substantially free of sodium ion can provide desirable increases in the stability of the microbial preparation at a basic pH compared to other suitable buffer systems to maintain a pH above about 7, above about 8, from about 8 to about 1, or from about 9 to about 10.5. Maintaining an alkaline pH can provide greater cleaning power. In certain embodiments, alkanolamine borate is present from about 5 to about 35% by weight, from about 10% by weight to about 30% by weight, from about 10% by weight to about 20% by weight, from about 5% by weight up to about 15% by weight, or from about 15% by weight to about 25% by weight. In certain embodiments, the alkanolamine borate is present from about 5% by weight to about 10% by weight, from about 15% by weight to about 20% by weight, from about 25% by weight to about 30% by weight of the composition. Such a formulation may be substantially free of sodium ion. The present compositions can also include any of the amounts or ranges of monoethanolamine borate not modified by the term "about". In certain embodiments, the monoethanolamine borate is present from about 10% by weight to about 20% by weight, from about 5% by weight to about 15% by weight or from about 15% by weight to about 25% by weight. In certain embodiments, the monoethanolamine borate is present from about 5% by weight to about 10% by weight, from about 15% by weight to about 20% by weight, from about 25% by weight to about 30% by weight of the composition. Such a formulation may be substantially free of sodium ion. The present compositions can also include any of the amounts or ranges of monoethanolamine borate not modified by the term "about". In certain embodiments, the boric acid salt is present from about 5 to about 35% by weight, from about 10% by weight to about 30% by weight, from about 10% by weight to about 20% by weight, from about 5% by weight. % by weight up to about 15% by weight, or from about 15% by weight to about 25% by weight. In certain embodiments, the boric acid salt is present from about 5% by weight to about 10% by weight, from about 15% by weight to about 20% by weight, from about 25% by weight to about 30% by weight of the composition. Such a formulation may be substantially free of sodium ion. The present compositions may also include any of the amounts or ranges of boric acid salt not modified by the term "about". Microbial Preparations Any of a variety of spores (bacterial or fungal), vegetative bacteria or fungi can be employed in the present stabilized bacterial compositions. For example, the present composition can include any viable microorganism or mixture thereof that can survive the formulation and environment of intended use or that can digest, degrade, or promote the degradation of lipids, proteins, carbohydrates, other organic matter, or the similar ones common to dirt or domestic, institutional and industrial effluents, or the like. Many suitable strains and species are known. Spores (of bacteria or fungi)Suitable vegetative bacteria or fungi include Bacillus, Pseudomonas, Arthrobacter, Enterobacter, Citrobacter, Corynebacter, Nitrobacter, mixtures thereof or the like; Acinetobacter, Aspergillus, Azospirillum, Burkholderia, Ceriporiopsis, Esqueria, Lactobacillus, Paenebacillus, Paracoccus, Rhodococcus, Syphingomonas, Streptococcus, Thiobacillus, Trichoderma, Xanthomonas, Lactobacillus, Nitrosomes, Alcaliaens, Klebsiella, mixtures thereof or the like; mixtures thereof or the like. Suitable Bacillus include Bacillus licheniformis, Bacillus subtilis, Bacillus polymyxa, or the like; Bacillus methanolicus, Bacillus amyloliquefaciens, Bacillus pasteurii, Bacillus laevolacticus, Bacillus megaterium, mixtures thereof or the like; mixtures thereof or the like. Suitable Pseudomonas include Pseudomonas aeruginosa, Pseudomonas alkanolytica, Pseudomonas dentrificans, mixtures thereof or the like. Suitable Arthrobacter include Arthrobacter paraffineus, Arthrobacter petroleophagus, Arthrobacter rubellus, Arthrobacter sp., Mixtures thereof or the like. Suitable Enterobacter include Enterobacter cloacae, Enterobacter sp., Mixtures thereof or the like. Suitable citrobacter include Citrobacter amalonaticus, Citrobacter freundi, mixtures thereof and the like. Suitable Corynebacterium include Corynebacterium alcanum, Corynebacterium fujiokense, Corynebacterium hydrocarbooxydane, Corynebacterium sp., Mixtures thereof and the like. Spores (of bacteria or fungi), vegetative bacteria or suitable fungi include those ATCC nos. Access 21417, 21424, 27811, 39326, 6051a, 21228, 21331, 35854, 10401, 12060, 21551, 21993, 21036, 29260, 21034, 13867, 15590, 21494, 21495, 21908, 962, 15337, 27613, 33241, 25405, 25406, 25407, 29935, 21194, 21496, 21767, 53586, 55406, 55405, 55407, 23842, 23843, 23844, 23845, 6452, 6453, 11859, 23492, mixtures thereof or the like. Suitable microorganisms that can be used in the present invention include those described in the patents of U.S. Nos. 4,655,794, 5,449,619 and 5,863,882; and the patent application publications of U.S. Nos. 20020182184, 20030126688 and 20030049832; whose descriptions are incorporated herein by reference. Spores (of bacteria or fungi), vegetative bacteria or suitable fungi are commercially available from a variety of sources (eg, Sybron Chemicals, Inc., Semco Laboratories, Inc., or Novozymes). Trademarks for such products include SPOZYME® 1B, SPOZYME® Ultra Base 2, SPOZYME® EB, SPOZYME® BCC, SPOZYME® WC Wash, SPOZYME® FE, BI-CHEM® MSB, BI-CHEM® Purta Tread, BI-CHEM® GC600L, Bl-CHEM® Bioclean, GREASE GUARD® or similar ones. In one embodiment, spores (bacterial or fungal), vegetative bacteria or fungi include Baciilus strains adapted specifically for high production of extracellular enzymes, particularly proteases, amylases and cellulases. Such strains are common in waste treatment products. This mixture may include Baciilus licheniformis, Baciilus subtilis and Baciilus polymyxa. As an additional example, Bacillus pasteurii can exhibit high levels of lipase production; Bacillus laevolacticus may exhibit a faster germination cycle; Bacillus amyloliquefaciens can exhibit high levels of protease production. Suitable concentrations for the spores (bacterial or fungal), vegetative bacteria or fungi in the formula include from about 1 × 10 3 to about 1 × 10 9 CFU / ml, from about 1 × 10 4 up to 1 × 10 8 CFU / ml, approximately 1 x 105 CFU / ml up to 1 x 107 CFU / ml, or, the like. Commercially available spore (bacterial or fungal), vegetative bacterial or fungal compositions can be employed in the present compositions in effective cleaning compositions, for example, from about 0.5 to about 10% by weight, from about 1 to about 5 (for example 4)% by weight, from about 2 to about 10% by weight, from about 1 to about 3% by weight, or about 2% by weight. The present composition may include those amounts or ranges not modified by approximately.

Modes of Stabilized Microbial Preparation In one embodiment, the present stabilized microbial preparations including the microbial preparation (e.g., bacterial preparation, such as spore mixture), boric acid salt (e.g., alkanolamine borate, such as monoethanolamine borate) ) and optional polyol (e.g., propylene glycol). In certain embodiments, the present stabilized microbial preparations include from about 2 to about 40% by weight of boric acid salt, from about 3 to about 15% by weight of boric acid salt, from about 5 to about 30% by weight of boric acid salt, from about 5 to about 25% by weight of boric acid salt, from about 5 to about 10% by weight of boric acid salt, from about 10 to about 15% by weight of boric acid salt, or from about 25 to about 30% by weight of boric acid salt. In certain embodiments, the present composition includes from about 2 to about 30% by weight of polyol, from about 2 to about 10% by weight of polyol, from about 5 to about 20% by weight of polyol, from about 5 to about 10. % by weight of polyol, or from about 10 to about 20% by weight of polyol. In certain embodiments, the present stabilized microbial preparations include from about 2 to about 40% by weight of polyol, from about 2 to about 20% by weight of polyol, from about 2 to about 15% by weight of polyol, from about 2 to about about 10% by weight of polyol, from about 3 to about 10% by weight of polyol, from about 4 to about 15% by weight of polyol, about 8% by weight of polyol or about 12% by weight of polyol. In certain embodiments, the present stabilized microbial preparations include from about 10 to about 95% by weight of water, from about 15 to about 75% by weight of water, from about 15 to about 35% by weight of water, from about 25 to about about 75% by weight of water, from about 40 to about 70% by weight of water, from about 45 to about 65% by weight of water, or up to about 50, about 55, about 60, about 65, or about 70% in weight of water. In one embodiment, the present cleaning composition includes spores, bacteria or fungi; and alkanolamine borate. In one embodiment, the composition may have a pH greater than or equal to 9, for example, of about 9 about 10.5. In one embodiment, the composition may have a pH greater than or equal to 8, for example, of about 8 about 9.5. The composition may also include a polyol. In one embodiment, the polyol may include propylene glycol. The composition may also include up to about 65% water. In one embodiment, the alkanolamine borate may include monoethanolammonium borate, diethanolammonium borate, triethanolammonium borate or a combination thereof. The composition can include from about 5 to about 35% by weight of alkanolamine borate, from about 10 to about 30% by weight of alkanolamine borate, from about 15 to about 25% by weight of alkanolamine borate. In one embodiment, the present cleaning composition includes spores, bacteria or fungi; and salt of borate, and may be substantially free of sodium ion. The composition may have a pH greater than or equal to 9, for example, of about 9 about 10.5. The composition may also include a polyol. In one embodiment, the polyol may include propylene glycol I,. The composition may also include up to about 65% water. The boric acid salt may include potassium borate. Potassium borate may include a combination of potassium hydroxide and boric acid. The composition can include from about 5 to about 35% by weight of borate salt, from about 10 to about 30% by weight of borate salt, or from about 15 to about 25% by weight of borate salt. In one embodiment, the spores or bacteria may include spores of bacteria.

Cleaning Compositions Including Stabilized Microbial Preparation The present invention also relates to cleaning compositions that include the present stabilized microbial preparation. In one embodiment, the concentrate and diluted aqueous cleaning compositions of this invention can include an effective concentration of a mixed surfactant that includes a nonionic surfactant and a silicone surfactant, plus the present stabilized microbial preparation. These compositions can also include an anionic surfactant and a hydrotrope or solubilizers, which can maintain a single-phase aqueous solution or suspension without separation. Suitable cleaning compositions in which the present stabilized microbial preparation can be included are described in U.S. Patent Nos. 6,425,959 and 6,506,261, the disclosures of which are incorporated herein by reference. In one embodiment, the compositions and methods may include a nonionic surfactant and a nonionic silicone surfactant. This composition may also include an anionic surfactant and a hydrotrope (which may be an anionic compound with little surfactant character), for example, an amine oxide material. Such a composition can be used pure, without thinner, to remove complex oily or greasy organic dirt and inorganic dirt from typically hard metal surfaces or other hard surfaces. The compositions may contain a source of alkalinity and a mixture sufficient to obtain excellent cleaning properties. In one embodiment, the cleaning compositions (concentrated or that can be diluted with liquids) of the invention can include from about 0.003 to about 70% by weight of a mixed surfactant composition containing a nonionic surfactant and a non-silicone surfactant. ionic. The nonionic surfactant may be free of a silicone portion, may be a block copolymer (EO) (PO), an alkoxylated alcohol, an alkoxylated alkylphenol, or an alkoxylated amine, wherein alkoxylate is a portion of (EO) or (PO). The weight ratio of the nonionic surfactant to the nonionic silicone surfactant can be from about 1 to about 10 parts by weight, preferably from 3 to 7 parts of the nonionic surfactant or mixture thereof for each part by weight of the surfactant of silicone or mixture thereof. Such a composition may also include from about 0.003 to about 35% by weight of one or more anionic surfactants; from about 0.001 to about 20% by weight of one or more effective hydrotropes; or mixtures thereof. The hydrotrope can be an alkyl di-methyl amine oxide. The hydrotrope can maintain the mixture of chelating agent and the surfactant in a uniform one-phase aqueous composition. In one embodiment, the concentrated compositions of the invention can include from about 1 to about 15% by weight of one or more nonionic silicone surfactants, from about 5 to about 75% by weight of one or more nonionic surfactants, from about 5 to about 75% by weight of one or more nonionic surfactants, and from about 2 to 20% by weight of one or more hydrotrope solubilizers (for example, an amine oxide material). In this embodiment, the ratio between the nonionic surfactant and the nonionic silicone surfactant can be from about 3 to about 7 parts by weight of a nonionic surfactant for each part by weight of the nonionic silicone surfactant. In one embodiment of a formulated dilute aqueous composition, the aqueous solution can include from about 0.0005 to about 35% by weight or from about 0.1 to about 10% by weight of the silicone surfactant, from about 0.0003 to 35% by weight or from about 0.3 to 30% by weight of the anionic surfactant, from about 0.003 to 35% by weight or from about 0.3 to 30% by weight of the anionic surfactant, and from about 0.001 to 20% by weight or from 0.2 to about 30% by weight of the hydrotrope solubilizers while maintaining the proportion of non-ionic silicone surfactant as discussed above. In one embodiment, the cleaning concentrate may include an aqueous base: from about 0.003 to 35% by weight or from about 0.1 to 25% by weight of a chelating agent or a sequestering agent; from about 0.003 to 35% by weight or from about 0.3 to 30% by weight of a nonionic surfactant, from about 0.0005 to 35% by weight or from about 0.01 to 10% by weight of a nonionic silicone surfactant; from about 0.003 to 30% by weight of an ammonium surfactant; and from about 0.001 to 20% by weight or from about 0.2 to 30% by weight of a hydrotrope or surfactant solubilizer (for example, an amine oxide). The cleaner concentrate can be used neat or can be diluted with service water to a sufficient ratio to obtain the active dilute aqueous cleaner discussed above. In the context of the invention, the term "pure" indicates the substantial absence of a diluent such as an aqueous medium. The resulting diluted cleaner can be applied to the dirty substrate for dirt removal. For the purpose of this patent application, the cleaning compositions may include a chelating agent, a nonionic / nonionic silicone surfactant mixture, an anionic surfactant and a hydrotrope (eg, amine oxide). Such modalities can be useful for the removal of dirt from a corrosion-resistant surface. The chelating agent can be a potassium salt. Similarly, the hydrotrope can be a potassium salt. Modalities of Cleaning Compositions In certain embodiments, the cleaning compositions of the present invention can be described by the ingredients and amounts listed in the tables below. The ingredients of the stabilized microbial composition are not listed in the tables below, but are present as described above. The quantities or ranges in these tables can also be modified by approximately. Concentrated composition Chemical Product% weight% weight Chelating Agent 0.1 to 30 0.5 to 15 Tensoactive mixture 0.5 to 70 1 to 30 Anionic Surfactant 0.1 to 70 0.5 to 35 Hydrotope of Oxide 0.1 to 20 0.5 to 15 of Amine Optional Acid Up To > pH 9 > pH 9 Chemical Product% p% p% p% p% p Non-ionic surfactant 2-16 4-16 2-8 8 4 Surfactant Silicone 0.5-6 1-6 0.5-2 3 1 Amphoteric Surfactant 1-10 2-10 1-6 5 3 Anionic Surfactant 2-16 4-6 2-8 8 4 Hydrotrope 1-20 5-20 1-16 11 3 Aqueous composition Diluted (as it is or as a formulation additive) Chemical Product PPm ppm Ppm Chelating Agent 0-150,000 600-20,000 1200-10,000 Mixture 30-175,000 3000-100,000 6000-50,000 Surfactants Surfactant 30-175,000 3000-100,000 6000-50,000 Anionic Hydrotrope 10-100,000 1000-60,000 2000-20,000 Aqueous diluent and Rest Rest Other stabilized microbial composition Chemical Product ppm ppm Chelating Agent 6-70,000 600-20,000 Mixture Surfactants 30-350,000 3000-100,000 Ammonium Surfactant 30-350,000 3000-100,000 Oxide Hydrotrope 7-80,000 700-25,000 Amine Optional Acid Up > pH 9 Up to > pH 9 Aqueous diluent and Rest Other stabilized microbial composition The above tables show compositions useful for the cleaning compositions of the present invention. The tables list the amounts of certain ingredients and the stable microbial compositions of the time also include spores, bacteria or fungi and boric acid salt. Such compositions can be used as removers of organic dirt or grease. The surfactant mixtures discussed above refer to the combination of a nonionic surfactant and a nonionic silicone surfactant in the proportions described above. In addition, chelating agents are useful, but not necessary. Chelating agents provide chelation and removal of dirt, but can contribute to corrosion or other chemical damage to certain surfaces. In one embodiment, the present cleaning composition includes spores, bacteria or fungi; and salt of borate, for example, alkanolamine borate. In certain embodiments, the composition may also include from about 0.003 to about 35% by weight of nonionic surfactant, for example, from about 0.5 to about 35% by weight of nonionic surfactant. The nonionic surfactant may include a non-ionic block copolymer comprising at least (EO) and (PO) z, wherein y and z are independently between 2 and 100; alkyl (from 6 to 24 carbon atoms) alkoxylated phenol having from 2 to 15 moles of ethylene oxide; alcohol of 6 to 24 alkoxylated carbon atoms having from 2 to 15 moles of ethylene oxide; alkoxylated amine having from 2 to 20 moles of ethylene oxide; or mixtures thereof. In certain embodiments, the composition can also include from about 0.0005 to about 35% by weight of silicone surfactant, for example, from about 0.1 to about 35% by weight of silicone surfactant. The silicone surfactant may include a silicone structure and at least one pendant alkylene oxide group having from about 2 to 100 moles of alkylene oxide. The pendant alkylene oxide group can include (EO) n wherein n is from 5 to 75. In certain embodiments, the composition can also include from about 0.003 to about 35% by weight of ammonium surfactant, for example, from about 0.5. up to about 35% by weight of anionic surfactant. The anionic surfactant may include linear alkyl benzene sulfonate; alpha olefin sulfonate; alkyl sulfonate; secondary alkane sulfonate; sulfosuccinates; or mixtures thereof. The anionic surfactant can include alkyl benzene alkanol ammonium sulfonate. The anionic surfactant can include alkyl benzene monoethanol ammonium sulfonate. In certain embodiments, the composition may also include from about 0.001 to about 20% by weight of hydrotrope, for example, from about 0.1 to about 20% by weight of hydrotrope. The hydrotrope can include alkyl (6 to 24 carbon atoms) dimethyl amine oxide; alkylated diphenyl oxide disulfonate; or mixtures thereof. The hydrotrope can include isoalkyldimethyl amine oxide surfactant. The hydrotrope can include iso-alkyl (10 to 14 carbon atoms) dimethyl amine oxide. The hydrotrope may include alkylated diphenyl disulfonic oxide acid or salts thereof. In one embodiment, the composition can also include from about 0.5 to about 35% by weight of nonionic surfactant, and from about 0.1 to about 35% by weight of silicone surfactant. In this embodiment, the nonionic surfactant may include a non-ionic block copolymer comprising at least (EO) and (PO) z; alkyl (from 6 to 24 carbon atoms) alkoxylated phenol having from 2 to 15 moles of ethylene oxide; alkoxylated alcohol (from 6 to 24 carbon atoms) having from 2 to 15 moles of ethylene oxide; alkoxylated amine having from 2 to 20 moles of ethylene oxide; or mixtures thereof. In this embodiment, the silicone surfactant may include a silicon structure and at least one pendant alkylene oxide group having from about 2 to 100 moles of alkylene oxide. In this embodiment, the weight ratio of the nonionic surfactant to the nonionic surfactant surfactant may be from about 0.1 to about 10 parts by weight of the nonionic surfactant for each part of the silicon surfactant. In one embodiment, the weight ratio of the nonionic surfactant to the nonionic surfactant surfactant may be from about 3 to about 7 parts by weight of the nonionic surfactant for each part of the silicon surfactant. In certain embodiments, the composition may also include from about 0.5 to about 35% by weight of nonionic surfactant, from about 0.1 to about 35% by weight of silicone surfactant, from about 0.5 to about 35% by weight of nonionic surfactant. , and from about 0.1 to about 20% by weight of hydrotrope. Ingredients for Stabilized Microbial Preparations The present stabilized microbial preparations and / or cleaning compositions can include any of a variety of ingredients that may be useful for cleaning or other uses. Such ingredients may include enzymes, surfactants, hydrotropes, chelating agents, divalent cations, polyol, cosmetic enhancement agent, solvents, preservatives or the like.

In certain embodiments, the composition may also include an effective amount of one or more solvents; an effective amount of one or more enzymes; an effective amount of one or more antimicrobials; an effective amount of one or more chelating agents; or mixtures thereof. The composition may include from about 0.1 to 30% by weight of chelating agent. The chelating agent may include small or polymeric compound having carboxyl groups, or mixtures thereof. The enzyme can include detergent enzyme. The detergent enzyme may include protease, amylase, lipase, cellulase, peroxidase, gluconase or mixtures thereof. The detergent enzyme may include alkaline protease, lipase or amylase or mixtures thereof. In certain embodiments, the composition may also include a source of calcium ions, polyol, abrasive, colorant or a combination or mixtures thereof. Surfactant The surfactant or mixture of surfactants of the present invention can be selected from nonionic, semi-polar nonionic, anionic, cationic, amphoteric, or zwitterionic water soluble or water dispersible surface active agents; or any combination thereof. The surfactant or mixture of surfactants in particular selected for use in the process and products of this invention may depend on the conditions of the ultimate utility, including the method of manufacture, the physical form of the product, the pH of use, the temperature of use , the control of foam and the type of dirt. The surfactants incorporated into the cleaning compositions of the present invention are preferably compatible with the enzymes, not substrates for enzymes in the composition and not inhibitors or inactivators of the enzyme. For example, when proteases and amylases are employed in the present compositions, the surfactant is preferably free of peptide and glycosidic linkages. In addition, it is known that certain cationic surfactants decrease the effectiveness of enzymes. Generally, the concentration of the surfactant or mixture of surfactants useful in the stabilized compositions of the present invention falls in the range from about 0.5% to about 40% by weight of the composition, preferably from about 2% to about 10%, preferably from about 5% to about 8%. These percentages can be referred to percentages of the commercially available surfactant composition, which may contain solvents, colorants, odorants and the like in addition to the current surfactant. In this case, the percentage of the current chemical surfactant may be lower than the percentages listed. These percentages can be referred to the percentage of the current chemical surfactant. Nonionic Surfactant The nonionic surfactants useful in the invention are generally characterized by the presence of a hydrophobic organic group and an organic hydrophilic Neo group and are typically produced by the condensation of an aliphatic, alkyl aromatic or polyoxyalkylene hydrophobic organic compound with a moiety of hydrophilic alkaline oxide which in common practice is ethylene oxide or a product of the polyhydration thereof, polyethylene glycol. Virtually any hydrophobic compound having a hydroxyl, carboxyl, amino or amido group with a reactive hydrogen atom can be condensed with ethylene oxide, or its polyhydration adducts, or mixtures thereof with alkoxylenes such as propylene oxide to form an active agent of non-ionic surface. The length of the polyoxyalkylene hydrophilic portion that is condensed with any particular hydrophobic compound can be easily adjusted to give a water-dispersible or water-soluble compound having the desired degree of balance between the hydrophilic and hydrophobic properties. Non-ionic surfactant of EOPO An example of useful non-ionic surfactants used with silicone surfactants are polyether compounds prepared from ethylene oxide, propylene oxide, in a homopolymer with grafted portion or a block or heteric copolymer. Such polyether compounds are known as polyalkylene oxide polymers, polyoxyalkylene polymers or polyalkylene glycol polymers. Such nonionic surfactants have a molecular weight in the range from about 500 to about 15,000. It has been found that certain types of nonionic surfactants of polyoxypropylene-polyoxyethylene glycol polymer are particularly useful. Surfactants that include at least one block of a polyoxypropylene and that have at least one other polyoxyethylene block attached to the polyoxypropylene block can be used. Additional blocks of polyoxyethylene or polyoxypropylene may be present in a molecule. These materials having an average molecular weight in the range from about 500 to about 15,000 are commonly available as PLURONIC (R) manufactured by BASF Corporation and available under a variety of other registered trademarks of their chemical suppliers. In addition, PLURONIC (R) R (PLURONIC reverse structure) are also useful in the compositions of the invention. Additionally, the alkylene oxide groups used with an alcohol and an alkylphenol, a fatty acid or other such group, may be useful. A useful surfactant may include a linear alcohol of 6 to 24 capped polyalkoxylated carbon atoms. The surfactants can be made with polyoxyethylene or polyoxypropylene units and can be topped with common agents that form an end ether group. A useful species of this surfactant is a linear alcohol of 12 to 14 polyethoxylated carbon atoms composed of (PO) x or benzyl ether compound; see the patent of E. U. No. 3,444,247. Particularly useful polyoxypropylene polyoxypropylene block polymers are those which include a central block of polyoxypropylene units and blocks of polyoxyethylene units on each side of the central block.

These copolymers have the formula shown below: (EO) n- (PO) m- (EO) n wherein m is an integer from 21 to 54; n is an integer from 7 to 128. Useful additional block copolymers are block polymers that have a central block of polyoxyethylene units and blocks of polyoxypropylene units on each side of the center block !. The copolymers have the formula as shown below: (PO) n- (EO) m- (PO) n where m is an integer from 14 to 164 and n is an integer from 9 to 22. A suitable nonionic surfactant for Use in the compositions of the invention includes an alkoxylated alkylphenol of the formula: wherein R 'includes an aliphatic group of 2 to 24 carbon atoms and AO represents a group of ethylene oxide, a propylene oxide group, a heteric mixed EOPO group or a block group EO-PO, PO-EO , EOPOEO OR POEOPO, and Z represents H or a (AO), benzyl or other auction. A suitable nonionic surfactant includes an ethoxylated alkylphenol of the formula: wherein R 'includes an aliphatic group of 6 to 18 carbon atoms, preferably an aliphatic group of 6 to 12 carbon atoms and n is an integer from about 2 to about 24. A principal example of such a surfactant is an ethoxylated nonylphenol which it has 2.5 to 14.5 moles of EO in the ethoxylated group. The ethoxylated group may be topped with a group (PO) x when x is from 2.5 to 12.5 or a benzyl portion. Alkoxylated amines The present compositions can include any of a variety of alkoxylated amines. In one embodiment, the alkoxylated amine has the general formula I: N (R1) (R2) (R3) (R4), in which at least one of R-i, R2 or R3 includes an alkoxylated or ether moiety. R 4 can be hydrogen, straight or branched alkyl, or straight or branched alkyl aryl. The alkoxylated amine can be a primary, secondary or tertiary amine. In one embodiment, the alkoxylated amine is a tertiary amine. In certain embodiments, each R2 and 3 includes an alkoxylated moiety, for example, one or more ethoxylated moieties, one or more propoxylated moieties, or combinations thereof, and R4 is hydrogen. For example, one of R ^ R2 or R3 may include one portion of ether and the other two may include one or more ethoxylated portions, one or more propoxylated portions or combinations thereof. By way of further example, an alkoxylated amine may be represented by the formulas lia, llb or lie general, respectively: R5- (PO) sN- (EO) tH, Ib Rs- (PO) sN- (EO) tH (EO ) uH, and lie R5-N (EO) tH; wherein R5 can be an alkyl, alkenyl or other aliphatic group, or an alkyl-aryl group from 8 to 20 or from 12 to 14 carbon atoms, EO is oxyethylene, PO is oxypropylene, s is from 1 to 20, from 2 to 12, or from 2 to 5, t is from 1 to 20, from 1 to 10, from 2 to 12, or from 2 to 5, and u is from 1 to 20, from 1 to 10, from 2 to 12 , or from 2 to 5. Other variations in the scope of these compounds can be represented by the formula lid: R5- (PO) vN [(EO) wH] [(EO) zH] in which R5 is as defined above , v is from 1 to 20 (for example, 1, 2, 3 or 4 or, in one mode, 2) and yyz are independently from 1 to 20, from 1 to 10, from 2 to 12, or from 2 to 5. In one embodiment, the alkoxylated amine is an alkoxylated amine ether. An alkoxylated amine ether may have the formula III: In formula III, R may be a straight or branched alkyl or alkyl aryl; R2 can be independently at each occurrence hydrogen or alkyl of 1 to 6 carbon atoms; R3 can independently be at each occurrence hydrogen or alkyl of 1 to 6 carbon atoms; m can average from about 1 to about 20; x and y can independently average from 1 to about 20; and x + y can average from about 2 to about 40. In one embodiment, in formula III, R 1 can be: alkyl of 8 to 24 carbon atoms, alkyl aryl and containing from about 7 to about 30 carbon atoms, or alkyl-aryl (for example, alkyl-aryl di-substituted with alkyl groups); R2 may contain 1 or 2 carbon atoms or it may be hydrogen; R3 can be hydrogen, alkyl containing 1 or 2 carbon atoms; and x + y can range from about 1 to about 3. Such ether ethoxylated amines are described in the E patents.

U. Nos. 6,060,625 and 6,063,145. In one embodiment, in formula III, R can be: alkyl of 6 to 24 carbon atoms, alkyl aryl and containing from about 7 to about 30 carbon atoms, or alkyl-aryl (for example, alkyl-aryl di- substituted with alkyl groups); R2 may contain 1 or 2 carbon atoms or it may be hydrogen; R3 can be hydrogen, alkyl containing 1 or 2 carbon atoms; and x + y can range from about 1 to about 20. In one embodiment, in formula III, m can be from 0 to about 20 and x and y can each independently average from 0 to about 20. In certain embodiments, the alkoxy moieties can be finished or finished with units of ethylene oxide, propylene oxide or butylene oxide. .

In one embodiment, in formula III, R1 may be alkyl of 6 to 20 carbon atoms or alkyl of 9 to 13 carbon atoms, for example, linear alkyl; R2 can be CH3; m may be from about 1 to about 10; R3 can be hydrogen; and x + y can range from about 5 to about 12. In one embodiment, in formula III, R can be alkyl of 6 to 14 carbon atoms or alkyl of 7 to 14 carbon atoms, for example, linear alkyl; R2 can be CH3; m may be from about 1 to about 10; R3 can be hydrogen; and x + y may range from about 2 to about 12. In one embodiment, such alkoxylated amine ether may include alkoxylated portions terminated with propylene oxide or butylene oxide units, which can provide low foaming compositions. In one embodiment, in formula III, R can be alkyl of 6 to 14 carbon atoms, for example, linear alkyl; R2 can be CH3; m may be from about 1 to about 10; R3 can be hydrogen; and x + y may range from about 2 to about 20. In one embodiment, the alkoxylated amine may be an alkoxylated propoxy amine of 12 to 14 carbon atoms in which, in formula III, R 1 may be alkyl of 12 to 14 atoms carbon, for example, linear alkyl; R2 can be CH3; m may be about 10; R3 can be hydrogen; x can be approximately 2.5 e and can be approximately 2.5. In one embodiment, the alkoxylated amine may be an alkoxylated propoxy amine of 12 to 14 carbon atoms in which, in formula III, R may be alkyl of 12 to 14 carbon atoms, for example, linear alkyl; R2 can be CH3; m may be approximately 5; R3 can be hydrogen; x can be approximately 2.5 e and can be approximately 2.5. In one embodiment, the alkoxylated amine may be an alkoxylated propoxy amine of 12 to 14 carbon atoms in which, in formula III, R 1 may be alkyl of 12 to 14 carbon atoms, for example, linear alkyl; R2 can be CH3; m may be approximately 2; R3 can be hydrogen; x can be approximately 2.5 e and can be approximately 2.5. In one embodiment, in formula III, R can be alkyl of 10 carbon atoms branched; R2 can be CH3; m can be 1; R3 can be hydrogen; and x + y may be about 5. Such an alkoxylated amine may be an alkoxylated tertiary amine known as poly (5) oxyethylene isodecyloxypropylmetal. In one embodiment, the alkoxylated amine can be an ethoxylated secondary amine which can be described by the formula: R- (PO) -N- (EO) x wherein x = 1 to 7 moles of ethylene oxide. In one embodiment, the alkoxylated amine can be a diamine which can be described by the formula: R-O-CH2CH2CH2N (H) (CH2CH2CH2NH2) in which R is, for example, alkyl of 10 carbon atoms branched.

In one embodiment, the alkoxylated amine ether of the formula III is a propoxylated ethoxylated amine ether of the Formula IV: In formula IV, R can be a straight or branched alkyl or arylaryl; a can average from about 1 to about 20; x and y can average each independently from 0 to about 10; and x + y can average from about 1 to about 20. Such an alkoxylated amine ether can be referred to as a propoxylated ethoxylated amine ether. In certain embodiments, the alkoxy moieties may be capped or terminated with units of ethylene oxide, propylene oxide or butylene oxide. In one embodiment, the alkoxylated amine can be an ethoxylated propoxy amine of 12 to 14 carbon atoms which can be described by the formula: R- (PO) 2 N [EO] 2.5-H [EO] 2.5-H. In one embodiment, the alkoxylated amine can be an ethoxylated propoxy amine of 12 to 14 carbon atoms which can be described by the formula: R- (PO) 10 N [EO] 2.5-H [EO] 2.5-H. In one embodiment, the alkoxylated amine can be an ethoxylated propoxy amine of 12 to 14 carbon atoms which can be described by the formula: R- (PO) 5N [EO] 2.5-H [EO] 2.5-H. In one embodiment, the alkoxylated amine may be an ethoxylated tertiary amine known as poly (5) oxyethylene isodecyloxypropylamine, which has a C10H2i alkyl group branched off from the ether oxygen. In one embodiment, the alkoxylated amine can be a diamine which can be described by the formula: R-0-CH2CH2CH2N (H) (CH2CH2CH2NH2) in which R is alkyl of 10 carbon atoms branched. In one embodiment, the alkoxylated amine may be an ethoxylated tertiary amine known as iso (2-h id roxieti I) isodecyloxypropylarane, which has a branched C-H 2 i alkyl group outside the oxygen of the ether. Alkoxylated ether amines are commercially available, for example, under the trademarks such as Surfonic (Hunstman Chemical) or Tomah Ether or Ethoxylated Amines. In one embodiment, the alkoxylated amine is an alkoxylated alkylamine. A suitable alkoxylated alkylamine may have the formula V: In the formula V, R can be straight or branched alkyl or alkyl aryl; R3 can independently be at each occurrence hydrogen or alkyl of 1 to 6 carbon atoms; x and y can average each independently from 0 to about 25; and x + y can average from about 1 to about 50. In one embodiment, in the formula V, x and y can each independently average from 0 to about 10; and x + y can average from about 1 to about 20. In one embodiment, the alkoxy moieties may be finished or terminated with units of ethylene oxide, propylene oxide or butylene oxide. In one embodiment, the alkoxylated alkylamine of the formula V is a propoxylated ethoxylated alkylamines of the formula VI: In formula VI, R6 may be a straight or branched alkyl or alkyl aryl (eg, alkyl of 18 carbon atoms); x and y can average each independently from 0 to about 25; and x + y can average from about 1 to about 50. In one embodiment, in formula VI, x and y can each independently average from 0 to about 10; and x + y can average from about 1 to about 20 or 40. Such alkoxylated amine ether can be referred to as a propoxylated ethoxylated amine. One such propoxylated ethoxylated alkylamine can be described by the chemical names N, N-bis-2 (omega-hydroxypolyoxyethylene / polyoxypropylene) ethyl alkylamine or N, N-bis- (polyoxyethylene / propylene) to fatty alkylamine, by the number 68213- 26-3 CAS, and / or by chemical formula C64H 3o0 8. Alkylamine alkoxylates are commercially available, for example, under trademarks such as Armoblen (Akzo Nobel). Armoblen 600 is called a propoxylated ethoxylated alkylamine. In one embodiment, the alkoxylated amine is an amine ether. The ether suitable amines may have the general formula VII: N (R) (R2) (R3), in which at least one of R-, R2, or R3 includes an ether portion. In one embodiment, R includes a portion of ether and R2 and R3 are hydrogen. Such an ether amine may have the formula VIII: R40 (R5) NH2 In the formula VIII, R4 may be aryl alkyl or alkyl of 1 to 13 carbon atoms, straight or branched chain and R5 may be alkyl of 1 to 6 carbon atoms , straight or branched chain. Ether amines are commercially available, for example, from Toman3 Products. Suitable alkoxylated amines may include amines known as ethoxylated amine, propoxylated amine, propoxylated ethoxylated amine, alkoxylated alkylamine, ethoxylated alkylamine, propoxylated alkylamine, propoxylated ethoxylated alkylamine, propoxylated ethoxylated quaternary ammonium compound, amine ether (primary, secondary or tertiary), ether alkoxylated amine, ethoxylated amine ether, propoxylated amine ether, alkoxylated amine ether, alkoxylated alkyl ether amine, alkoxylated alkyl propoxy amine, alkoxylated alkyl alkoxy ether amine, and the like. Additional Non-Ionic Surfactants Additional nonionic surfactants useful in the present invention include: Condensation products of one mole of straight or branched chain, saturated or unsaturated carboxylic acid having from about 8 to about 18 carbon atoms with from about 6 to about approximately 50 moles of ethylene oxide. The acid portion may consist of mixtures of acids in the range of carbon atoms defined above or may consist of an acid having a specific number of carbon atoms within the range. Examples of commercial compounds of this chemistry are commercially available under the trademarks Nopalcol® manufactured by Henkel Corporation and Lipopeg® manufactured by Lipo Chemicals, Inc. in addition to the ethoxylated carboxylic acids, commonly called polyethylene glycol esters, other esters of alkanoic acids formed by reaction with glycerides, glycerin and polyhydric alcohols (saccharides or sorbitan / sorbitol) have application in this invention for specialized modalities, particularly indirect applications of food additives. All these ester portions have one or more sites of reactive hydrogen in their molecule that can undergo additional acylation or addition of ethylene oxide (alkoxide) to control the hydrophilic capacity of these substances. Care should be taken when adding these fatty or acylated ester carbohydrates to compositions of the present invention which contain amylase and / or lipase enzymes due to potential incompatibility. Examples of low foaming nonionic surfactants include above-described nonionic surfactants that are modified by "capped" or "end blocking" of the terminal hydroxy group (s) (to multi-functional portions) to reduce foaming by reaction with a molecule small hydrophobic such as propylene oxide, butylene oxide, benzyl chloride; and short chain fatty acids, alcohols or alkyl halides containing from 1 to about 5 carbon atoms; and mixtures thereof. Also included are reagents such as thionyl chloride which converts the terminal hydroxy groups into a chloride group. Such modifications to the terminal hydroxy group can lead to non-ionic all-block, block-heteric, hetter-block or all-heteric. The polyhydroxy fatty acid amide surfactants suitable for use in the present compositions include those having the structural formula R2CONR1Z in which: R1 is H, hydrocarbyl group of 1 to 4 carbon atoms, 2-hydroxy ethyl, 2-hydroxy propyl , ethoxy, propoxy, or a mixture thereof; R2 is a hydrocarbyl of 5 to 31 carbon atoms, which may be straight chain; and Z is a polyhydroxy hydrocarbyl having a linear hydrocarbyl chain with at least three hydroxyls directly connected to the chain, or an alkoxylated derivative (preferably ethoxylated or propoxylated) thereof. Z can be derived from a reducing sugar in a reductive amination reaction; such as a glycityl portion. Suitable non-ionic alkyl polysaccharide surfactants, particularly for use in the present compositions include those described in U.S. Patent No. 4,565,647, Filling, issued January 21, 1986. These surfactants include a hydrophobic group containing from about 6 to about 30 carbon atoms and a polysaccharide, for example, a polyglycoside, hydrophilic group containing from about 1.3 to about 10 units of saccharide. Any reducing saccharide containing five or six carbon atoms for example, glucose galactose and portions of galactosyl can be substituted for the glucosyl portions can be used. (Optionally, the hydrophobic group is attached at positions 2-, 3-, 4-, etc. thus giving a glucose or galactose as opposed to a glycoside or galactoside). The inter-saccharide linkages can be, for example, between position 1 of the additional saccharide units and positions 2-, 3-, 4- and / or 6 in the preceding saccharide units. Suitable fatty acid amide surfactants for use in the present compositions include those having the formula: R6CON (R7) 2 wherein R6 is an alkyl group containing from 7 to 21 carbon atoms and each R7 is independently hydrogen, alkyl of 1 to 4 carbon atoms, hydroxyalkyl of 1 to 4 carbon atoms, or (C2H40) xH, wherein x is in the range of 1 to 3. The treatise Nonionic surfactants, edited by Schick, MJ, Vol. 1 of the Surfactant Science Series, Marcel Dekker, Inc., New York, 1983, is an excellent reference on the wide variety of nonionic compounds generally employed in the practice of the present invention. A typical list of non-ionic classes, and species of these surfactants, is given in U.S. Patent No. 13,929,678 issued to Laughlin and Heuring on December 30, 1975. Additional examples are given in "Active Surface Agents and Detergents" ( Vol. I and II by Schwartz, Perry and Berch). Semi-Polar Non-ionic Surfactants The semi-polar type of non-ionic surface active agents is another class of nonionic surfactant useful in the compositions of the present invention. Generally, semi-polar nonionics are high foamers and foam stabilizers, which may limit their application in CIP systems. However, in the compositional modalities of this invention designed for high foaming cleaning methodology, semi-polar non-ionics would have immediate utility. Semi-polar nonionic surfactants include amine oxides, phosphine oxides, sulfoxides and their alkoxylated derivatives. The amine oxides are tertiary amine oxides corresponding to the general formula: wherein the arrow is a conventional representation of a semi-polar junction; and R1, R2 and R3 can be aliphatic, aromatic, heterocyclic, alicyclic or combinations thereof. Generally, for amine oxides of detergent interest, R is an alkyl radical of from about 8 to about 24 carbon atoms; R2 and R3 are alkyl or hydroxyalkyl of 1 to 3 carbon atoms or a mixture thereof; R2 and R3 may be linked together, for example, through an oxygen or nitrogen atom, to form a ring structure; R 4 is an alkaline or hydroxyalkylene group containing 2 to 3 carbon atoms; and n ranges from 0 to about 20. Useful water-soluble amine oxide surfactants are selected from alkyl di- (lower alkyl) amine coconut or tallow oxides, the specific examples of which are oxides of dodecyl dimethylamine, tridecyl dimethylamine oxide, tetradecyl dimethylamine oxide, pentadecyl dimethylamine oxide, hexadecyl dimethylamine oxide, heptadecyl dimethylamine oxide, octadecyl dimethylamine oxide, dodecyl dipropylamine oxide, tetradecyl dibutylamine oxide, octadecyl dibutylamine oxide, bis (2-hydroxyethyl) dodecylamine oxide, bis (2-hydroxyethyl) -3-dodecoxy-1-hydroxypropylamine oxide, dimethyl- (2-hydroxydecyl) amine oxide, 3,6,9-trioctadecyldimethylamine oxide and 3-dodecoxy-2-hydroxypropyl di- ( 2-hydroxyethyl) amine. Useful semi-polar nonionic surfactants also include water-soluble phosphine oxides having the following structure: wherein the arrow is a conventional representation of a semi-polar junction; and R1 is an alkyl, alkenyl or hydroxyalkyl portion ranging from 10 to about 24 carbon atoms in chain length; and R2 and R3 are each alkyl portions selected separately from alkyl or hydroxyalkyl groups containing from 1 to 3 carbon atoms. Examples of useful phosphine oxides include dimethyldecylphosphine oxide, dimethyltetradecylphosphine oxide, methylethyltetradecylphosphine oxide, dimethylhexadecylphosphine oxide, diethyl-2-hydroxyocydodecylphosphine oxide, bis (2-hydroxyethyl) dodecylphosphine oxide, and bis (hydroxymethyl) tetradecylphosphine oxide. The semi-polar nonionic surfactants useful herein also include the water soluble sulfoxide compounds having the structure: wherein the arrow is a conventional representation of a semi-polar junction; and R1 is an alkyl or hydroxyalkyl portion from about 8 to about 28 carbon atoms, from 0 to about 5 ether linkages and from 0 to about 2 hydroxyl substituents; and R2 is an alkyl portion consisting of alkyl and hydroxyalkyl groups having from 1 to 3 carbon atoms.

Useful examples of these surfoxides include dodecyl methyl sulfoxide; 3-hydroxytridecylmethyl sulfoxide; and 3-hydroxy-4-dodecoxib useful methyl sulfoxide. Preferred semi-polar nonionic surfactants for the compositions of the invention include dimethylamine oxides, such as lauryl dimethylamine oxide, myristyl dimethylamine oxide, cetyl dimethylamine oxide, combinations thereof and the like. Silicone Surfactants The silicone surfactant may include a modified dialkyl, for example, a dimethyl polysiloxane. The hydrophobic polysiloxane group can be modified with one or more pendant hydrophilic polyalkylene oxide group or groups. Such surfactants can provide low surface tension, high wetting, high spray, defoaming and excellent stain removal. The silicone surfactants of the invention include a polydialkyl siloxane, for example, a polydimethyl siloxane to which polyether groups, typically polyalkylene oxide, have been grafted, through a hydrosilation reaction. The process results in a pendant alkyl copolymer (AP type), in which the polyalkylene oxide groups are attached along the siloxane structure by a series of hydrolytically stable Si-C bonds. These non-ionic polydialkyl siloxane substituted products have the following generic formula: R3Si-0- (R2SiO) x (R2SiO) y-SiR3 wherein PE represents a non-ionic group, for example, -CH2 (CH2) P- 0- (EO) m (PO) nZ, with EO representing oxide of ethylene, PO representing propylene oxide, x is a number ranging from about 0 to about 100, m, n and p are numbers ranging from about 0 to about 50, m + n > 1 and Z represents hydrogen or R wherein each R independently represents a straight or branched lower alkyl (1-6 carbon atoms). Such surfactants have a molecular weight (Mn) of about 500 to 20,000. Other nonionic silicone surfactants have the formula: | (C2H40) ¿7 (C3H6O) z, R wherein x represents a number ranging from about 0 to about 100, and represents a number ranging from about 1 to about 100, a and b represent numbers that fluctuate independently from about 0 to about 60, a + b > 1, and each R is independently H or a straight or branched lower alkyl (1-6 carbon atoms). A second class of nonionic silicone surfactants is an alkoxy with blocked ends (type AEB) that are less preferred because Si-O- bonding offers limited resistance to hydrolysis under neutral or slightly alkaline conditions, but breaks rapidly in acidic environments. Suitable surfactants are sold under the trademark SILWET®, the trademark TEGOPREN® or under the trademark ABIL® B. A useful surfactant, SILWET® L77, has the formula: CH3Si-0 (CH3) Si (R1) 0-S (CH3) 3 wherein R = -CH2CH2CH2-0- [CH2CH2CH20] 2CH3; wherein z is from 4 to 16, preferably from 4 to 12, more preferably from 7 to 9. Other useful surfactants include TEGOPREN 5840®, ABIL B-8843® and ABIL B-8863®. Ammonium surfactants Useful also in the present invention are the surface active substances which are classified as anionic because the charge in the hydrophobe is negative; or surfactants in which the hydrophobic section of the molecule carries no charge unless the pH rises to neutral or above (e.g., carboxylic acids). The carboxylate, sulfonate, sulfate and phosphate are the polar (hydrophilic) solubilization groups found in ammonium surfactants. Of the cations (against ions) associated with these polar groups, sodium, lithium and potassium impart solubility in water; the ammonium and substituted ammonium ions provide solubility in both water and oil; and calcium, barium and magnesium promote solubility in oil. The anionics are excellent detergent or cleaning surfactants and are, therefore, favored additions for heavy duty detergent compositions. Generally, however, anionics have high foam profiles that limit their use alone or at high concentration levels in cleaning systems such as CIP circuits that require strict foam control. In addition, the surface active anionic compounds can impart special chemical or physical properties different from that of detergent in the composition. Anionics can be used as gelling agents or as part of a gelation or thickening system. The anionics are excellent stabilizers and can be used to control the hydrotropic effect and haze point. Most of the high volume commercial anionic surfactants can be subdivided into five main chemical classes and additional sub-groups, which are described in the "Encyclopedia of Surfactants", Cosmetics & Toiletries, Vol. 104 (2) 71-86 (1989). The first class includes acylamino acids (and salts), such as acylglutamates, acyl peptides, sarcosinates (e.g., N-acyl sarcosinates), taurates (e.g., N-acyl taurates and fatty acid amides of methyl tauride), and the similar ones. The second class includes carboxylic acids (and salts), such as alkanoic acids (and alkanoates), esters of carboxylic acids (for example, alkyl succinates), carboxylic acid esters and the like. The fourth class includes sulfonic acids (and salts), such as isethionates (e.g., acyl isethionates), alkylaryl sulfonates, alkyl sulfonates, sulfosuccinates (e.g., monoesters and sulfosuccinate diesters), and the like. The fifth class includes sulfuric acid esters (and salts), such as alkyl ether sulfonates, alkyl sulfonates and the like. Although each of these classes of ammonium surfactants can be employed in the present compositions, it should be noted that certain of these ammonium surfactants may be incompatible with the enzymes. For example, acyl-amino acids and salts may be incompatible with proteolytic enzymes due to their peptide structure. Suitable sulfate anionic surfactants for use in the present compositions include alkyl, linear and branched, primary and secondary sulfates, alkyl ethoxy sulfates, fatty oleyl glycerol sulphates, alkylphenol ether sulphates, ethylene oxide sulfates, acyl sulphates 5 to 17 carbon atoms) -N- (alkyl of 1 to 4 carbon atoms) and -N- (hydroxyalkyl of 1 to 2 carbon atoms) glucamine and sulfates of alkyl polysaccharides such as the alkyl polyglycoside sulphates (the compounds non-sulfated nonionics described herein). Examples of suitable synthetic water-soluble anionic detergent compounds include the ammonium and substituted ammonium salts (such as mono-, di- and triethanolamine) and alkali metal salts (such as sodium, lithium and potassium) of the mononuclear aromatic sulfonates which contain from about 5 to about 18 carbon atoms in the alkyl group in a straight or branched chain, for example, the alkylbenzene sulfonate salts or alkyl toluene, xylene, eumeno and phenol sulfonates; alkyl naphthalene sulfonates, diamyl naphthalene sulfonates and dinonyl naphthalene sulfonates and alkoxylated derivatives. The carboxylate anionic surfactants suitable for use in the present compositions include the alkyl ethoxy carboxylates, the alkyl polyethoxy polycarboxylate surfactants and the soaps (eg, alkyl carboxyls). Secondary soap surfactants (eg, alkyl carboxyl surfactants) useful in the present compositions include those which contain a carboxy unit attached to a secondary carbon. The secondary carbon can be in a ring structure, for example as in p-octyl benzoic acid, or as in alkyl-substituted cyclohexyl carboxylates. Secondary soap surfactants typically do not contain ether bonds, nor ester bonds nor hydroxide groups. In addition, they typically lack nitrogen atoms in the main group (amphiphilic portion). Suitable secondary soap surfactants typically contain 11 to 13 carbon atoms in total, although more carbon atoms (eg, up to 16) may be present. Other anionic detergents suitable for use in the present compositions include olefin sulfonates, such as long chain alkene sulfonates, long chain hydroxyalkane sulfonates or mixtures of alkenesulfonates and hydroxyalkane sulfonates. Also included are alkyl sulfonates, alkyl poly (ethyleneoxy) ether sulfonates and poly (ethyleneoxy) aromatic sulfonates such as sulfonates or condensation products of ethylene oxide and nonylphenol (usually having from 1 to 6 oxyethylene groups per molecule). Also suitable are resin acids and hydrogenated resin acids, such as Greek resin or fish, and hydrogenated resin acids and resin acids present in or derived from tallow oil. The salts in particular will be selected suitably depending on the particular formulation and the needs therein. Additional examples of suitable anionic surfactants are given in "Surface Active Agents and Detergents" (Vol. I and II by Schwartz, Perry and Berch). A variety of such surfactants are also generally described in U.S. Patent No. 3,929,678, issued December 30, 1975 to Laughlin et al. In column 23, line 58 to column 29 line 23. In one embodiment, the present composition includes sulfonates or substituted sulfonates of alkyl or alkylaryl and sulfonated products. In certain embodiments, the present composition includes linear alkane sulfonates, linear alkyl benzene sulfonates, alpha-olefin sulfonates, alkyl sulfates, secondary alkane sulfates or sulphonates or sulfosuccinates. Cationic surfactants Substances with surface activity are classified as cationic if the charge on the hydrotrope portion of the molecule is positive. Surfactants in which the hydrotrope carries no charge unless the pH is lowered to near neutral or less, but which are cationic then (eg, alkylamines), are also included in this group. In theory, cationic surfactants can be synthesized from any combination of elements containing an "onium" structure RnX + Y- and could include other compounds besides nitrogen (ammonium) such as phosphorus (phosphonium) and sulfur (sulfonium). In practice, the field of the cationic surfactant is dominated by nitrogen-containing compounds, probably because the synthesis routes for cationic nitrogen are simple and correct and give high yields of the product, which makes them less expensive. Cationic surfactants preferably include, more preferably refer to, compounds that contain at least one long chain hydrophobic carbon group and at least one positively charged nitrogen. The long chain carbon group can be attached directly to the nitrogen atom by simple substitution; or more preferably indirectly by a bridging group or functional groups in the so-called alkylamines and interrupted amido amines. Such functional groups can make the molecule more hydrophilic and / or more dispersible in water, more easily solubilized in water by mixtures of co-surfactants and / or water-soluble. For increased water solubility, additional primary, secondary or tertiary amino groups may be introduced or the amino nitrogen may be quaternized with low molecular weight alkyl groups. In addition, the nitrogen may be a part of the straight or branched chain portion of varying degrees of saturation or of a saturated or unsaturated heterocyclic ring. In addition, I 03 cationic surfactants may contain complex bonds having more than one cationic nitrogen atom. The surfactant compounds classified as amine, amphoteric and zuiterion oxides are themselves typically cationic in solutions of near neutral pH or acid and may overlap surfactant classifications. The polyoxyethylated cationic surfactants generally behave as nonionic surfactants in alkaline solution and as cationic surfactants in acid solution. The simplest cationic amines, the amine salts and the quaternary ammonium compounds can be represented schematically as follows: R 'R R "_ R-N R-N-H + X" R-N-R'X wherein, R represents a long alkyl chain, R ', R "and R'" can be long alkyl chains or smaller alkyl or aryl groups or hydrogen and X represents an anion. Amine salts and quaternary ammonium compounds may be useful due to their high degree of water solubility. The majority of high volume commercial cationic surfactants can be subdivided into four major classes and additional subgroups known to those skilled in the art and described in the "Encyclopedia of Surfactants," Cosmetics & Toiletries, Vol. 104 (2) 86-96 (1989). The first class includes alkylamines and their salts. The second class includes alkyl imidazolines. The third class includes ethoxylated amines. The fourth class includes quaternary, such as alkylbenzyldimethylammonium salts, alkyl benzene salts, heterocyclic ammonium salts, tetraalkyl ammonium salts and the like. Cationic surfactants are known to have a variety of properties that may be beneficial in the present compositions. These desirable properties may include detergency in compositions at or below neutral pH. Antimicrobial efficacy, thickening or gelling in cooperation with other agents, and the like. Cationic surfactants useful in the compositions of the present invention include those having the formula R1mR2xYLZ wherein each R is an organic group containing a straight or branched alkyl or alkenyl group optionally substituted with up to three phenyl or hydroxy groups and optionally interrupted by up to four of the following structures: or an isomer or mixtures of these structures and containing from about 8 to 22 carbon atom. The R groups can additionally contain up to 12 ethoxy groups. m is a number from 1 to 3. Preferably no more than one group R in a molecule has 16 or more carbon atoms when m is 2 or more than 12 carbon atoms when m is 3. Each R 2 is an alkyl group or hydroxyalkyl containing from 1 to 4 carbon atoms or a benzyl group with not more than one R2 in a molecule that is benzyl, and x is a number from 0 to 11, preferably from 0 to 6. The remainder of any positions of atoms of carbon in the group Y is filled by hydrogens. And it can be a group that includes, but is not limited to: (C2H40) -N- (C2H40) p = about 1 to 12 - s- or a mixture of them. Preferably, L is 1 or 2, with the groups Y which are separated by a selected portion of analogs of R and R2 (preferably alkylene or alkenylene) having from 1 to about 22 carbon atoms and two free single carbon ligations when L is 2. Z is a water-soluble anion, such as a halide, sulfate, methylsulfate, hydroxide or nitrate group, with chloride, bromide, iodide, sulfate or methyl sulfate anions being particularly preferred in a number to give electrical neutrality of the cationic component. Amphoteric surfactants Amphoteric surfactants, or ampholytic surfactants, contain both an acidic and basic group and an organic hydrophobic group. These ionic entities may be any of the anionic or cationic groups described herein for other types of surfactants.

A basic nitrogen and an acidic carboxylate group are the typical functional groups employed as the basic hydrophilic and acidic groups. In some surfactants, sulfonate, sulfate, phosphonate or phosphate provide the negative charge. Amphoteric surfactants can be broadly described as derivatives of secondary and tertiary aliphatic amines, in which the aliphatic radical can be straight or branched chain and wherein one of the aliphatic substituents contains from about 8 to 18 carbon atoms and one contains a anionic group for solubilization in water, for example, carboxy, sulfo, sulfate, phosphate or phosphono. Amphoteric surfactants are subdivided into two main classes known to those of skill in the art and described in the "Encyclopedia of Surfactants", Cosmetics &; Toiletries, Vol. 104 (2) 69-71 (1989). The first class includes acyl / dialkyl ethylenediamine derivatives (eg, 2-alkyl hydroxyethyl imidazoline derivatives) and their salts. The second class includes N-alkylamino acids and their salts. Some amphoteric surfactants can be designed to accommodate both classes. Amphoteric surfactants can be synthesized by methods known to those skilled in the art. For example, 2-alkyl hydroxyethyl imidazoline is synthesized by condensation and ring closure of a long chain carboxylic acid (or derivative) with dialkyl ethylenediamine. Commercial amphoteric surfactants are derived by subsequent hydrolysis and ring opening of the imidazoline ring by alkylation - for example with chloroacetic acid or ethyl acetate. During the alkylation, one or two carboxy-alkyl groups react to form a tertiary amino and an ether linkage with different alkylating agents giving different tertiary amines. The long chain iodazole derivatives which have application in the present invention generally have the general formula: (MONO) ACETATE (DI) PROPIONATE SULFONATO ANFOTERICO Neutral pH - zuiterion where R is a hydrophobic acyclic group containing from about 8 to 18 carbon atoms and M is a cation that will neutralize the charge of the anion, usually sodium. Amphoteric commercially important imidazoline derivatives which may be employed in the present compositions include for example: cocoanfopropionate, cocoanfocarboxypropionate, cocoanfoglycinate, cocoanfocarboxyglycinate, cocoanopropyl sulfonate and cocoanfocarboxypropionic acid. Preferred amphocarboxylic acids are produced from fatty imidazolines in which the functionality of the dicarboxylic acid of the amphodicarboxylic acid is diacetic acid and / or dipropionic acid. The carboxymethylated compounds (glycinates) described hereinbefore are often called betaines. Betaines are a special class of amphotericins discussed herein below in the section entitled Zuiterionic Surfactants. The long-chain N-alkyl amino acids are easily prepared by the reaction of RNH2, wherein R = straight chain or branched alkyl of 8 to 18 carbon atoms, fatty amines with halogenated carboxylic acids. Alkylation of the primary amino groups of an amino acid leads to secondary and tertiary amines. The alkyl substituents may have additional amino groups that provide more than one nitrogen receiving center. The most commercial N-alkylamine acids are alkyl derivatives of beta-alanine or beta-N (2-carboxyethyl) alanine. Examples of commercial M-alkyl amino acid ampholytes having application in this invention include alkyl beta-amino dipropionates, RN (C2H4COOM) 2 and RNHC2H COOM. In these, R is preferably a hydrophobic acyclic group containing from about 8 to about 18 carbon atoms, and M is a cation that neutralizes the charge of the anion. Preferred amphoteric surfactants include those derived from coconut products such as coconut oil or coconut fatty acid. Most preferred of these coconut-derived surfactants include as part of their structure a portion of ethylenediamine, an alkanolamide portion, an amino acid portion, preferably glycine, or a combination thereof; and an aliphatic substituent from about 8 to 18 (preferably 12) carbon atoms. Tai surfactant can also be considered an alkyl amphipicarboxylic acid. Disodium cocoampropionate is one of the most preferred amphoteric surfactants and is commercially available under the trademark Miranol ™ FBS from Rhodia, Inc., Cranbury, N.J. Another amphoteric surfactant derived from the preferred coconut with the chemical name cocoanthus disodium diacetate is sold under the trademark Miranol ™ C2M-SF also from Rhodia, Inc., Cranbury, N.J. A typical listing of amphoteric and species classes of these surfactants is given in U.S. Patent No. 3,929,678 issued to Laughlin and Heuring on December 30, 1975. Additional examples are given in "Active Surface Agents and Detergents" (Vol. I and II by Schwartz, Perry and Berch). Zwitterionic Surfactants Zwitterionic surfactants can be thought of as a subset of amphoteric surfactants. Zwitterionic surfactants can be broadly described as derivatives of secondary and tertiary amines, derivatives of heterocyclic secondary and tertiary amines, or derivatives of quaternary ammonium, quaternary phosphonium or tertiary sulfonium compounds. Typically, a zwitterionic surfactant includes a positively charged quaternary ammonium or, in some cases, a sulfonium or phosphonium ion; a negatively charged carboxyl group; and an alkyl group. Zwitterionics generally contain cationic and ammonium groups which ionize to an almost equal degree in the isoelectric region of the molecule and which can develop a strong "internal salt" attraction between positive and negative charge centers. Examples of such synthetic zwitterionic surfactants include derivatives of quaternary ammonium compounds, aliphatic phosphonium and sulfonium, in which the aliphatic radicals can be straight or branched chain and wherein one of the aliphatic substituents contains from 8 to 18 carbon atoms and one contains an anionic group of solubilization in water, for example, carboxy , sulfonate, sulfate, phosphate or phosphonate. The betaine and sultaine surfactants are exemplary zwitterionic surfactants for use herein. A general formula for these compounds is: wherein R 1 contains an alkyl, alkenyl or hydroxyalkyl radical of from 8 to 18 carbon atoms having from 0 to 10 portions of ethylene oxide and from 0 to 1 portion of glyceryl; And it is selected from the group consisting of nitrogen, phosphorus and sulfur atoms; R2 is an alkyl or monohydroxyalkyl group containing one to three carbon atoms; x is 1 when Y is a sulfur atom and 2 when Y is a nitrogen or phosphorus atom, R3 is an alkylene or hydroxyalkylene or hydroxyalkylene of 1 to 4 carbon atoms and Z is a radical selected from the group consisting of carboxylate, sulfonate, sulfate, phosphonate and phosphate. Examples of zwitterionic surfactants having the structures listed above include: 4- [N, N-di (2-hydroxyethyl) -N-octadecylammonium] -butane-1-carboxylate; 5- [S-3-hydroxypropyl-S-hexa-d eci Is u Ifon io] -3-h idroxypen tan o-1-sulfate; 3- [P, P-diethyl-P-3,6,9-trioxa-tetracosanphosphon io] -2-h idroxpropan-1-phosphate; 3- [N, N-dipropyl-N-3-dodecoxy-2-hydroxypropyl-ammonium] -propran-1-phosphonate; 3- (N, N-dimethyl-N-hexadecylammonium) -prophan-1 -su Ifon ato; 3- (N, N-dimethyI-N-hexadecyl-ammonium) -2-hydroxy-propran-1 -su Ifon ato; 4- [N, N-di (2 (2-hydroxyethyl) -N- (2-idroxidodecyl) ammonium] -b uta n-1-carboxylate; 3- [S-ethyl-S- (3-dodecoxy) 2-hydroxypropyl) sulfonium] -propran-1-phosphate; 3- [P, P-dimethyl-P-dodecyl-phosphonium] -propran-1-phosphonate; and S [N, N-di (3-hydroxypropyl) -N -hexadecylammonium] -2-hydroxy-pentan-1-sulfate The alkyl groups contained in said detergent surfactants may be straight or branched and saturated or unsaturated The zwitterionic surfactant suitable for use in the present compositions includes a betaine of the general structure: CH2-CO2" These surfactant betaines do not typically exhibit strong cationic or anionic characters at extreme pH's or show reduced solubility in water in their isoelectric range. Unlike "external" quaternary ammonium salts, betaines are compatible with anionics. Examples of suitable betaines include coconut acylamidopropyl dimethyl betaine; hexadecyldimethyl betaine; acylamidopropyl betaine of 12 to 14 carbon atoms; acylamidohexadhexyl betaine of 8 to 14 carbon atoms; 4-acyl of 4 to 16 carbon atoms methylamidodiethylammonium-1-carboxybutane; acyl 16 to 18 carbon atoms amidodimethyl betaine; acyl of 12 to 16 carbon atoms amidopentandiethyl betaine; and acyl of 12 to 16 carbon atoms methylamidodimethyl betaine. Sultains useful in the present invention include those compounds having the formula (R (R1) 2 N + R2SOs ", in which R is a hydrocarbyl group of 6 to 18 carbon atoms, each R1 is typically independently alkyl of 1 to 4 carbon atoms. to 3 carbon atoms, for example, methyl, and R2 is a hydrocarbyl group of 1 to 6 carbon atoms, for example, an alkylene or hydroxyalkylene group of 1 to 3 carbon atoms, a listing of typical zwitterionic classes, and species of these surfactants are given in U.S. Patent No. 3,929,678 issued to Laughlin and Heuring on December 30, 1975. Additional examples are given in "Surface Active Agents and Detergents" (Vol. I and II by Schwartz, Perry and Berch.) Surfactant Compositions The surfactants described hereinbefore may be used alone or in combination in the practice and utility of the present invention, In particular, nonionics and anionics may be used in combination. Amphoteric and zwitterionic, nonionic, cationic, semi-polar surfactants can be used in combination with non-ionic or anionic surfactants. The above examples are merely specific illustrations of the numerous surfactants that may find application within the scope of this invention. The above organic surfactant compounds can be formulated in any of several forms of the commercially desirable composition of this invention which has described its utility. Said compositions include washing treatments for soiled surfaces in concentrated form which, when supplied or dissolved in water, properly diluted by a proportioning device and delivered to the target surfaces as a solution, gel or foam will provide cleaning. Said cleaning treatments consisting of a product; or that involve a system of two products where proportions of each are used. Said product is typically a liquid concentrate or emulsion. Hydrotrope A hydrotropic agent is often employed in the formulation to maintain a pure or aqueous single-phase composition. Such an agent can be used in the present invention. Hydrotropia is a property that refers to the ability of materials to improve the solubility or miscibility of a substance in liquid phases in which the substance tends to be insoluble. The substances that provide hydrotropia are called hydrotropes and are used in relatively lower concentrations than the materials to be solubilized. A hydrotrope modifies a formulation to increase the solubility of an insoluble substance or creates mixed miscellar or miscellar structures that result in a stable suspension of the insoluble substance. In this invention, hydrotropes are most useful for maintaining the components of the formulas in a uniform solution both during manufacture and when they are dispensed at the location of use. The hydrotrope solubilizer can maintain a one-phase solution having the components evenly distributed throughout the composition in an aqueous or non-aqueous form. Preferred hydrotrope solubilizers are used from about 0.1 to about 30% by weight and include, for example, small molecule ammonium surfactants and semi-polar nonionic surfactants. The most preferred range of hydrotrope solubilizers is from about 1 to about 20% by weight. Hydrotrope materials are relatively well known for exhibiting hydrotropic properties in a broad spectrum of chemical molecule types. Hydrotropes generally include ether compounds, alcohol compounds, anionic surfactants, cationic surfactants and other materials. A major hydrotrope solubilizer for use in this invention includes an amine oxide material. The small molecule anionic surfactants include aromatic or sulphonated sulfonic acid hydrotropes such as benzene sulphonic acid or substituted naphthalene sulphonic acid of 1 to 5 carbon atoms. Examples of such a hydrotrope are xylene sulfonic acid or naphthalene sulphonic acid or salts thereof. The semi-polar type of the nonionic surface active agents includes amine oxide hydrotropes such as tertiary amine oxides corresponding to the general formula: G i- (OR ¾-N ¾ where n is from 0 to 25, the arrow is a conventional representation of a semi-polar ligature; and R ,, R2 and R3 can be aliphatic, aromatic, heterocyclic, alicyclic or combinations thereof. Generally, for amine oxides of detergent interest, R1 is an aliphatic or alkyl radical, linear or branched, from about 8 to about 24 carbon atoms; R2 and R3 are selected from the group consisting of alkyl or hydroxyalkyl of 1 to 3 carbon atoms and mixtures thereof; R 4 is an alkylene or hydroxyalkylene group containing 2 to 3 carbon atoms; and n ranges from 0 to about 20. Useful water-soluble amine oxide hydrotropes are selected from alkyl di- (lower alkyl) amine oxides, specific examples of which are isoalkyl oxide of 10 to 14 carbon atoms dimethylamine, (iso-dodecyl) dimethylamine-Barlox 12i oxide, n-decyldimethylamine oxide, dodecyldimethylamine oxide, tridecyldimethiamine oxide, tetradecyldimethylamine oxide, pentadecyldimethylamine oxide, hexadecyldimethylamine oxide, heptadecyldimethylamine oxide, octadecyldimethylamine oxide, dodecyldipropylamine, tetradecyldipropylamine oxide, hexadecyldipropylamine oxide, tetradecyldibutylamine oxide, octadecyldibutylamine oxide, bis (2-hydroxyethyl) dodecylamine oxide, bis (2-hydroxyethyl) -3-dodecoxy-hydroxypropylamine oxide, d-oxide methyl- (2-hydroxydecyl) amine and 3,6,9-trioctadecyldimethylamine oxide. The most preferred of the above is sodium isodecyl dimethylamine oxide (Barlox 12i). Other hydrotropes or couplers can generally be used in compositions of the present invention to maintain the physical integrity of a phase and storage stability. For this purpose, any number of known ingredients can be used for those skilled in formulas, such as monofunctional and polyfunctional alcohols. These preferably contain from about 1 to about 6 carbon atoms and from 1 to about 6 hydroxy groups. Examples include ethanol, isopropanol, n-propanol, 1,2-propanediol, 1,2-butanediol, 2-methyl-2,4-pentanediol, mannitol and glucose. Useful also are the glycols, polyglycols, polyoxides, glycol ethers and higher propylene glycol ethers. Additional useful hydrotropes include the free salts of acids and alkali metal, of sulfonated alkyl aryls such as alkylated diphenyl oxide sulfonates, toluene, xylene, eumeno and ether sulfonates, phenol and phenol or phenol ether sulfonate or diphenyl oxide disulfonates alkoxylated (Dowfax materials), naphthalene alkyl sulfonate and alkoxylated derivatives. These sulfonate materials used as hydrotropes are not considered to be typically to be as a strong surfactant. These materials are sulfonates with an associated hydrophobic group that is designed to provide hydrotropic properties, not surfactant properties. With this in mind, it is considered that these materials are typically not surfactant compositions. Sequestrant The present cleaning composition may include a sequestrant. In general, a sequestrant is a molecule capable of coordinating (i.e., agglutinating) the metal ions commonly found in natural water to prevent metal ions from interfering with the action of the other detergent ingredients of a cleaning composition. Some chelating / sequestering agents can also function as a threshold agent when they are included in an effective amount. For an additional discussion of the chelating / sequestering agents, see the Kirk-Othmer Encyclopedia of Chemical Technology, Third Edition, volume 5, pages 339 to 366 and volume 23 pages 319 to 320. A variety of sequestrants can be used in this homogeneous cleaning composition, including, for example, organic phosphate, aminocarboxylic acid, condensed phosphate, inorganic abrasive, polymeric polycarboxylate, di- or tri-carboxylic acid, mixtures thereof or the like. Such sequestrants and abrasives are commercially available. In certain embodiments, the heterogeneous cleaning composition present includes scavenger from about 5 to about 50% by weight, from about 30 to about 50% by weight, from about 10 to about 45% by weight, or from about 20 to about 40% by weight. weight. In certain embodiments, the present heterogeneous cleaning composition includes sequestrant at about 20% by weight, about 25% by weight, about 30% by weight, about 35% by weight, or about 40% by weight. The composition may include any of these ranges or amounts unmodified by the approximately. Suitable fused phosphates include sodium potassium orthophosphate, sodium potassium pyrophosphate, potassium sodium tripolyphosphate, sodium hexametaphosphate, for example, tripolyphosphate. In one embodiment, the present cleaning composition includes a condensed phosphate, such as an abrasive, chelating or sequestering agent, such as sodium tripolyphosphate. Polycarboxylates suitable for use as a sequestrant include, for example, polyacrylic acid, maleic / olefin copolymer, acrylic / maleic copolymer, polymethacrylic acid, copolymers of acrylic acid-methacrylic acid, hydrolyzed polyacrylamide, hydrolyzed polymethacrylamide, polyamide-methacrylamide copolymers hydrolyzed, hydrolyzed polyacrylonitrile, hydrolyzed poly-methacrylonitrile, hydrolyzed acrylonitrile-methacrylonitrile copolymers, polymaleic acid, polyfumárico acid, copolymers of acrylic and itaconic acid and the like. In one embodiment, the polycarboxylate includes polyacrylate. The di- or tri-carboxylic acids include oxalic acid, citric acid or salts thereof. In one embodiment, the oxalic acid can be used to reduce iron levels in the use composition or remove iron soil from the article to be cleaned. For example, oxalic acid can be part of a souring remover by controlling iron or iron. In one embodiment, the present heterogeneous cleaning composition includes as a sequestrant or abrasive a condensed phosphate and polyacrylate, or another polymer, for example, sodium tripolyphosphate and polyacrylate. The abrasive may include an organic phosphonate, such as an organic phosphonic acid and alkali metal salts thereof. Some examples of suitable organic phosphonates include: 1-hydroxyethane-1,1-diphosphonic acid: CH 3 C (OH) [PO (OH) 2] 2; aminotri (methylene phosphonic acid): N [CH2 + PO (OH) 2] 3; sodium salt of aminotri (methylene phosphonate) 2-hydroxyethylimino bis (methylene phosphonic acid): OHCH2CH2N [CH2PO- (OH) 2] 2; diethyleneaminopenta (methylene phosphonic acid): (OH) 2POCH 2 N [CH 2 CH 2 N- [CH 2 PO (OH) 2] 2] 2; sodium salt of diethylene triaminopenta (methylene phosphonate): C9H (28-x) N3Nax015P5 (x = 7), potassium salt of hexamethylenediamine (tetramethylenephosphonate): C10H (28-x) N2KxO12P4 (x = 6); bis (hexamethylene) triamine (hexamethylene phosphonic acid): (OH 2 +) POCH 2 N [(CH 2) 6 N [CH 2 PO (OH) 2] 2] 2; and phosphorous acid: H3P03; and other similar organic phosphonates and mixtures thereof. The sequestrant may be or include an aminocarboxylic acid type sequestrant. Suitable sequestrants of the aminocarboxylic acid type include the acids or alkali metal salts thereof, for example, amino acetates and salts thereof. Some examples include the following: N-hydroxyethylamino diacetic acid; hydroxyethylene diaminotetraacetic acid, nitrilotriacetic acid (NTA); methyl dialytic acid (MGDA); Ethylenediaminetetraacetic acid (EDTA); N-hydroxyethyl-ethylene diaminotriacetic acid (HEDTA); diethylenetriaminpentaacetic acid (DTPA); and alanine-N, N-diacetic acid; imidodisuccinic acid; and the like and mixtures thereof. A useful building / chelating agent or salts itself includes a polymeric phosphinocarboxylic acid including salts thereof and derivatives thereof. Such materials can be prepared by reacting an unsaturated carboxylic acid monomer, such as acrylic acid with a hypophosphorous acid or derivatives thereof generally represented by the following formula: wherein is an OX group wherein X is hydrogen or a straight or branched alkyl group containing from 1 to 4 carbon atoms; and R3 is hydrogen, a straight or branched alkyl group of 1 to 8 carbon atoms, a cycloalkyl group of 5 to 12 carbon atoms, a phenyl group, a benzyl group or an -OX group wherein X is hydrogen or a group straight or branched alkyl of 1 to 4 carbon atoms. Polyphosphinocarboxylic acid salts can also be used as noted. A preferred embodiment of such material is Belsperse® -161. The sequestrant may be or may include a biodegradable sequestrant. Suitable biodegradable scavengers include methyl glycine diacetic acid or its salts. Such a sequestrant is ercially available, for example, under the trademark Trilon ES. Enzymes The present cleaning osition can include one or more enzymes, which can provide a desirable activity for the removal of spots based on protein, based on carbohydrates, or based on triglycerides of substrates; for cleaning, staining and pre-wetting. Although not limiting to the present invention, enzymes suitable for the present cleaning ositions can act by degrading or altering one or more types of soil debris found on a surface or textile thereby removing dirt or making dirt more removed by a surfactant or other onent of the cleaning osition. Both the degradation and the alteration of the dirt residues can improve detergency by reducing the physicochemical forces that agglutinate the dirt to the surface or the textile to be cleaned, that is, the dirt bes more soluble in water. For example, one or more proteases are used to cleave lex protein macromolecular structures present in the dirt residues in simpler short chain molecules which, by themselves, are more readily released from the surfaces, or otherwise more easily removed by detergent solutions containing said proteases. Suitable enzymes include a protease, an amylase, a lipase, a gluconase, a cellulase, a peroxidase or a mixture thereof of any suitable origin, such as of vegetable, animal, bacterial, fungal or yeast origin. Preferred selections are influenced by factors such as activity, optimum pH and / or stability, thermostability and stability to active detergents, abrasives and the like. In this regard, bacterial or mycotic enzymes, such as bacterial amylases and proteases, and fungal cellulases are preferred. Preferably, the enzyme is a protease, a lipase, an amylase or a combination thereof. As used herein, "detergent enzyme" means an enzyme that has a cleaning, stain or otherwise beneficial effect as a component of a composition for laundry, textiles, dishwashers, on-site cleaning, drains, floors, carpets , medical or dental instruments, meat cutting tools, hard surfaces, personal care or the like. Suitable detergent enzymes include a hydrolase, such as a protease, an amylase, a lipase or a combination thereof. The enzymes are normally incorporated into a composition according to the invention in a quantity sufficient to give an effective cleaning during a washing or pre-wetting process. An effective amount for cleaning refers to an amount that produces a clean, sanitary and, preferably, corrosion-free appearance to the cleaned material. An effective amount for cleaning can also refer to an amount that produces an improved effect of cleaning, stain removal, dirt removal, bleaching, deodorization or freshness on the substrates. Typically, such a cleaning effect can be achieved with amounts of enzyme from about 0.1% to about 3% by weight, preferably from about 1% to about 3% by weight, of the cleaning composition. Higher active levels may also be desirable in highly concentrated cleaning formulations. Commercial enzymes, such as alkaline proteases, can be obtained in liquid or dried form, sold as aqueous solutions of raw material or in purified, assorted, processed and compound forms and include from about 2% to about 80% by weight, of active enzyme generally in combination with stabilizers, buffers, co-factors, impurities and inert vehicles. The actual content of active enzyme depends on the manufacturing method and is not critical, assuming that the composition has the desired enzymatic activity. The particular enzyme selected for use in the process and products of this invention depends on the conditions of the ultimate utility, including the physical form of the product, the pH of use, the temperature of use and the types of soil to be digested, degraded or altered. The enzyme can be selected to provide optimal activity and stability for any given set of utility conditions. The compositions of the present invention preferably include at least one protease. It has further been found that the composition of the invention, surprisingly, not only stabilizes the protease over a shelf life substantially extended, but also significantly increases the activity of the protease for protein digestion and the increased removal of proteins. dirt. In addition, the increased activity of the protease occurs in the presence of one or more additional enzymes, such as amylase, cellulase, lipase, peroxidase, endoglucanase and mixtures thereof, preferably lipase or amylase enzymes. The enzyme can be selected for the type of dirt as a target for the cleaning composition or present at the site or the surface to be cleaned. Although not limited to the present invention, it is believed that the amylase may be advantageous for cleaning dirt containing starch, such as potato, pasta, flour, baby food, sauce, chocolate or the like. Although not limiting to the present invention, it is believed that the protease may be advantageous for cleaning dirt containing proteins, such as blood, skin flakes, mucus, fat, food (e.g., eggs, milk, spinach, meat residues, tomato sauce) or the like. While not limiting the present invention, it is believed that the lipase may be advantageous for cleaning dirt containing grease, oil, or wax, such as grease, oil or animal or vegetable wax (eg, salad dressing, butter, butter, etc.). pork, chocolate, lipstick). Although not limited to the present invention, it is believed that the cellulase can be advantageous for cleaning cellulose-containing or cellulose-containing dirt that serves as attachment points for other dirt. A valuable reference on enzymes is "Industrial Enzymes", Scott, D., in Kirk-Othmer Encyclopedie of Chemical Technology, third edition, (Editors Grayson, M. and EcKroth, D.) Vol. 9, pp. 173-224, John Wiley & amp;; Sons, New York, 1980. Protease A protease suitable for the composition of the present invention can be derived from a plant, an animal or a microorganism. Preferably, the protease is derived from a microorganism, such as a yeast, a mold or a bacterium. Preferred proteases include serine proteases active at an alkaline pH, preferably derived from a Bacillus strain such as Bacillus subtilis or Bacillus licheniformis; these preferred proteases include native and recombinant subtilisins. The protease can be purified or a component of a microbial extract, and any wild type or variant (either chemical or recombinant). A preferred protease is not inhibited by a metal chelating agent (sequestrant) or by a thiol poison nor is it activated by metal ions or reducing agents, does it have a? broad substrate specificity, is inhibited by diisopropyl fluorophosphate (DFP), is an endopeptidase, has a molecular weight in the range from about 20,000 to about 40,000 and is active at a pH from about 6 to about 12 and at temperatures in a range from about 20 ° C to about 80 ° C. Examples of proteolytic enzymes that can be employed in the composition of the invention include (with registered trademarks) Savinasa®; a protease derived from the Bacillus lentus type, such as Maxacal®, Opticlean®, Durazym® and Properasa®; a protease derived from Bacillus licheniformis, such as Alcalasa® and Maxatasa®; and a protease derived from Bacillus amiloliquefaciens, such as Primasa®. Preferred commercially available protease enzymes include those sold under the trademarks Alcalasa®, Savinasa®, Primasa®, Durazym® or Esperasa® by Novo Industries A / S (Denmark); those sold under the trademarks Maxatasa®, Maxacal® or Maxapem® by Gist-Brocades (The Netherlands); those sold under the trademarks Purafect®, Purafect OX and Properasa by Genencor International; those sold under the Opticlean® or Optimasa® trademarks by Solvay Enzymes; and the similar ones. A mixture of such proteases can also be used. For example, Purafect® is a preferred alkaline protease (a subtilisin) for use in detergent compositions of this invention that have application in lower temperature cleaning programs, from about 30 ° C to about 65 ° C; whereas, Esperasa® is an alkaline selection protease for detergent solutions at higher temperatures, from about 50 ° C to about 85 ° C. Suitable detergent proteases and described in the patent publications including: GB 1,243,784, WO 9203529 A ( enzyme / inhibitor system), WO 9318140 A, and WO 9425583 (protease as recombinant trypsin) to Novo; WO 9510591 A, WO 9507791 (a protease having decreased absorption and increased hydrolysis), WO 30010, WO 95/30011, WO 95/29979, to Procter & Gamble; WO 95/10615 (Bacillus amyloliquefaciens subtilisin) to Genencor International; EP 130,756 A (protease A); EP 303,761 A (protease B); and EP 130,765 A. A variant protease employed in the present compositions is preferably at least 80% homologous, preferably having at least 80% sequence identity, with the amino acid sequences of the proteases in these references. In preferred embodiments of this invention, the amount of commercial alkaline protease present in the composition of the invention ranges from about 0.1% by weight of detergent solution to about 3% by weight, preferably from about 1% to about 3% by weight, from about 2% by weight, of solution of the commercial enzyme product. Typical detergent enzymes commercially available include about 5 to 10% active enzyme. While the establishment of the commercial alkaline protease percentage by weight required is of practical convenience for making modalities of the present teaching, the variation in commercial protease concentrates and the additive and negative effects of the in situ environment on the protease activity require a analytical technique of more discernment for the protease assay to quantify the activity of the enzyme and establish correlations with the performance of the removal of dirt residue and for enzyme stability in the preferred embodiment; and, if it is a concentrate, for solutions of dilutions of use. The activity of the proteases for use in the present invention are rapidly expressed in terms of activity units - more specifically, Kilo-Novo Protease Units (KNPU) which are units of azocasein assay activity well known in the art. A more detailed discussion of the azocasein assay procedure can be found in the publication entitled "The Use of Azoalbumin as a Substrate in the Colorimetric Determination of Peptic and Triptycal Activity", Tomarelli, RM Charney, J., and Harding, ML, J Lab. Clin. Chem. 34, 428 (1949). In preferred embodiments of the present invention, the activity of proteases present in the use solution ranges from about 1 x 10 ~ 5 KNPU / gm in solution to about 4 x 1 O "3 KNPU / gm in solution. mixtures of different proteolytic enzymes in this invention Although several specific enzymes have been described above, it is to be understood that any protease that can confer the desired proteolytic activity to the composition can be used and this embodiment of this invention is not limited in any way by The specific selection of the proteolytic enzyme Amiiase A suitable amiiase for the composition of the present invention can be derived from a plant, an animal or a microorganism Preferably the amiaia is derived from a microorganism, such as a yeast, a mold or a bacterium Preferred amylases include those derived from a Bacülus, such as B. licheniformis, B. amylol iquefaciens, B. subtilis or B. stearothermophilus. The amiiase can be purified or a component of a microbial extract, and any wild type or variant (either chemical or recombinant), preferably a variant that is more stable under washing or prewet conditions than a wild-type amyiase. Examples of amyiase enzymes that can be employed in the composition of the invention include those sold under the trademark Rapidase by Gist-Brocades® (The Netherlands); those sold under the registered names Termamil®, Fungamil® or Duramil® by Novo; Purastar STL or Purastar OXAM by Genencor; and the similar ones. Preferred commercially available amylase enzymes include variant amylase with improved stability sold under the trade name Duramil (R) ++ by Novo. A mixture of amylases can also be used. Suitable amylases for the compositions of the present invention include: -amylases described in WO 95/26397, PCT7DK96 / 00056 and GB 1,296,839 to Novo; and amylases with improved stability described in J. Biol. Chem. 260 (11): 6518-6521 (1985); WO 9510603 A, WO 9509909 A and WO 9402597 by Novo; the references described in WO 9402597 and WO 9418314 of Genencor International. A variant α-amylase used in the present compositions can be at least 80% homologous, preferably having at least 80% sequence identity, with the amino acid sequences of the proteins of these references. Amylases suitable for use in the compositions of the present invention have improved stability compared to certain amylases, such as Termamil®. Improved stability refers to a significant or measurable improvement in one or more of: oxidation stability, for example, for hydrogen peroxide / tetraacetyl ethylenediamine in buffered solution at a pH of 9 to 10; thermal stability, for example, at common wash temperatures such as about 60 ° C; and / or alkaline stability, for example, at a pH from about 8 to about 11; each compared to a suitable control amylase, such as Termamil®. Stability can be measured by methods known to those skilled in the art. Suitable amylases with increased stability for use in the compositions of the present invention have a specific activity of at least 25% greater than the specific activity of Termamil® at a temperature in the range of 25 ° C to 55 ° C and at a pH in the range from about 8 to about 10. The activity of the amylase for such comparisons can be measured by assays known to those skilled in the art and / or commercially available., such as the Phadebas l-amylase assay (R). In one embodiment, the amount of commercial amylase present in the composition of the invention ranges from about 0.1% by weight of detergent solution to about 3% by weight, preferably from about 1% to about 3% by weight, preferably about 2% by weight. % by weight, of solution of the commercial enzyme product. Typical commercially available detergent enzymes include about 0.25 to 5% active amylase. While the establishment of the required percentage by weight of amylase is of practical convenience for manufacturing modalities of the present teaching, the variation in commercial amylase concentrates and the effects of additive and negative in situ environment on the activity of amylase requires a technique Most discriminating analytical for the amylase assay to quantify the activity of the enzyme and establish correlations with the performance of the removal of dirt residue and for enzyme stability in the preferred embodiment; and, if it is a concentrate, for solutions of dilutions of use. The activity of the amylases for use in the present invention can be expressed in known units or through known amylase assays and / or commercially available assays, such as the Phadebas® α-amylase assay. Of course, mixtures of different amylase enzymes can be incorporated in this invention. Although several specific enzymes have been described above, it should be understood that any amylase that can confer the desired amylase activity to the composition can be used and this embodiment of this invention is not limited in any way by the specific selection of the amylase enzyme. . Cellulases A cellulase suitable for the composition of the present invention can be derived from a plant, an animal or a microorganism. The cellulase can be derived from a microorganism, such as a fungus or bacteria. Suitable cellulases include those derived from a fungus, such as Humicola insolens, Humicola strain DS 1800, or a cellulase 212 that produces the fungus belonging to the genus Aeromonas and those extracted from the hepatopancreas of a marine mollusk, Dolabella Auricular Solander. The cellulase can be purified or a component of an extract, and any wild type or variant (either chemical or recombinant). Examples of cellulase enzymes that can be employed in the composition of the invention include those sold under the trade names Carezyme® or Cellusyme® from Novo, or Cellulase from Genencor; and the similar ones. A mixture of cellulases can also be used. Suitable cellulases are described in the patent documents which include: U.S. Patent No. 4,435,307, GB-A-2,075,028, GB-A-2,095,275, DE-OS-2,247,832, WO 9117243 and WO 9414951 A (Stabilized Cellulases). Novo In one embodiment, the amount of commercial cellulase present in the composition of the invention ranges from about 0.1% by weight of detergent solution to about 3% by weight, preferably from about 1% to about 3% by weight of the product's solution. commercial enzyme Typical detergent enzymes commercially available include from about 0.25 to 5% active amylase. While the establishment of the percentage by weight of cellulase required is of practical convenience for developing modalities of the present teaching, the variation in commercial cellulase concentrates and the additive and negative effects of the in situ environment on the cellulase activity may require a analytical technique of more discernment for the cellulase assay to quantify the activity of the enzyme and establish correlations with the performance of the removal of dirt residue and for stability of the enzyme in the modality; and, if it is a concentrate, for solutions of dilutions of use. The activity of the cellulases for use in the present invention can be expressed in known units or through known or commercially available cellulase assays. Of course, mixtures of different cellulase enzymes can be incorporated in this invention. Although several specific enzymes have been described above, it should be understood that any cellulase that can confer the desired cellulase activity to the composition can be used and this embodiment of this invention is not limited in any way by the specific selection of the cellulase enzyme. . Lipases A suitable lipase for the composition of the present invention can be derived from a plant, an animal or a microorganism. In one embodiment, the lipase is derived from a microorganism, such as a fungus or bacteria. Suitable lipases include those derived from a Pseudomonas, such as Pseudomonas stutzeri ATCC 19,154, or from a Humicola, such as Humicola lanuginosa (typically produced recombinantly in Aspergillus orizae). The lipase can be purified or a component of an extract, and any wild type or variant (either chemical or recombinant). Examples of lipase enzymes that can be employed in the composition of the invention include those sold under the registered names Lipase P "Amano" or "Amano P" by Amano Pharmaceutical Co. Ltd., Nagoya, Japan, or under the registered name Lipolase ® by Novo and the like. Other commercially available lipases that can be employed in the present compositions include Amano-CES, lipases derived from Chromobacter viscosum, for example Chromobacter viscosum var. Ipolyticum NRRLB 3673 from Toyo Jozo Co., Tagata, Japan; Chromobacter viscosum lipases from U.S. Biochemical Corp., E.U.A. and Disoynth Co., and lipases derived from Pseudomonas gladioli or Humicola ianuginosa. A suitable lipase is sold under the registered name Lipolase® by Novo. Suitable lipases are described in the patent documents including: WO 7414951 A (stabilized lipases) by Novo, WO 9205249, RD 94359044, GB 1,372,034, Japanese patent application 53,20487, opened on February 24, 1978 for Amano Pharmaceuticals Co. Ltd., and EP 341,947. In one embodiment, the amount of commercial lipase present in the composition of the invention ranges from about 0.1% by weight of detergent solution to about 3% by weight, preferably from about 1% to about 3% by weight of the product's solution. commercial enzyme Typical commercially available detergent enzymes include about 5 to 10% active enzyme. While the establishment of the percentage by weight of lipase required is of practical convenience for manufacturing modalities of the present teaching, the variation in commercial lipase concentrates and the effects of additive and negative of the in situ environment on the activity of the lipase requires a technique more discriminating analytical for the amylase assay to quantify the activity of the enzyme and establish correlations for the performance of the removal of dirt residue and for stability of the enzyme in the modality; and, if it is a concentrate, for solutions of dilutions of use. The activity of lipases for use in the present invention can be expressed in known units or through known or commercially available lipase assays. Of course, mixtures of different lipase enzymes can be incorporated in this invention. Although several specific enzymes have been described above, it should be understood that any lipase that can confer the desired lipase activity to the composition can be used and this embodiment of this invention is not limited in any way by the specific selection of the lipase enzyme. . Additional Enzymes Additional enzymes suitable for use in the present compositions include a cutinase, a peroxidase, a gluconase and the like. Suitable cutinase enzymes are described in WO 8809367 A of Genencor. Known peroxidases include horseradish peroxidase, ligninase, and haloperoxidases such as chloro- or bromo-peroxidase. Peroxidases suitable for the compositions are described in WO 89099813 A and WO9307260 A by Novo. Peroxidase enzymes can be used in combination with oxygen sources, for example, percarbonate, perborate, hydrogen peroxide and the like. Additional enzymes suitable for incorporation into the present composition are described in WO 9307263 A and WO 9307260 A from Genencor International, WO 8908694 A from Novo, and US Patent No. 3,553,139 to McCarty et al., US Patent No. 4,101,457 to Place and collaborators, U.S. Patent No. 4,507,219 to Hughes and U.S. Patent No. 4,261,868 to Hora et al. An additional enzyme, such as a cutinase or peroxidase, suitable for the composition of the present invention can be derived from a plant, an animal or a microorganism. Preferably, the enzyme is derived from a microorganism. The enzyme can be purified or a component of an extract, and any wild type or variant (either chemical or recombinant). In the preferred embodiments of this invention, the amount of commercial additional enzyme, such as a cutinase or peroxidase, present in the composition of the invention ranges from about 0.1% by weight of detergent solution to about 3% by weight, preferably from about 1% to about 3% by weight of the solution of the commercial enzyme product. Typical detergent enzymes commercially available include about 5 to 10% active enzyme. While the establishment of the percentage by weight of additional enzyme, such as a cutinase or a peroxidase, required is of practical convenience to manufacture modalities of the present teaching, the variation in commercial additional enzyme concentrates and the additive and negative effects of the environment in situ about its activity may require a more discerning analytical technique for the enzyme assay to quantify the activity of the enzyme and establish correlations for the performance of the removal of dirt residue and for stability of the enzyme in the modality; and, if it is a concentrate, for solutions of dilutions of use. The activity of the additional enzyme, such as a cutinase or a peroxidase, for use in the present invention can be expressed in known units or through known or commercially available assays. Naturally, mixtures of different additional enzymes can be incorporated in this invention. Although several specific enzymes have been described above, it should be understood that any additional enzymes that can confer the desired enzymatic activity to the composition can be used and this embodiment of this invention is not limited in any way by the specific selection of the enzyme. Enzyme stabilization system The present compositions may also include ingredients for stabilizing one or more enzymes. For example, the cleaning composition of the invention may include a water soluble source of calcium and / or magnesium ions. Calcium ions are generally more effective than magnesium ions and are preferred herein if only one type of cation is to be used. The compositions, especially liquids, can include from about 1 to about 30, preferably from about 2 to about 20, more preferably from about 8 to about 12 millimoles of calcium ion per liter of the finished composition, although variation is possible depending on the composition. of factors that include the multiplicity, the type and levels of enzymes incorporated. Preferably, water-soluble calcium or magnesium salts are used, including for example calcium chloride, calcium hydroxide, calcium formate, calcium malate, calcium maleate, calcium hydroxide and calcium acetate; more generally, the calcium or magnesium sulfate salts corresponding to the calcium salts listed can be used. Of course, additionally increased levels of calcium and / or magnesium may be useful, for example to promote the shearing action of certain types of surfactant. The stabilization systems of certain cleaning compositions, for example dishwasher compositions, may further include from 0 to about 10%, preferably from about 0.01% to about 6% by weight, of chlorine bleach sequestrants, aggregates to prevent The chlorine bleach species present in many water supplies attack and de-activate the enzymes, especially under alkaline conditions. Although the chlorine levels in the water may be small, typically in the range from about 0.5 ppm to about 1.75 pmm, the available chlorine in the total volume of water contacted with the enzyme, for example during dishwashing , it can be relatively large; consequently, the stability of the enzyme by the chlorine in use can be problematic. Suitable anions of the chlorine sequestrant are widely known and readily available, and if used, may be salts containing ammonium cations with sulfite, bisulfite, thiosulfite, thiosulfate, chloride, etc. Antioxidants, such as carbamate, ascorbate, etc., organic amines such as ethylene diaminetetraacetic acid (EDTA) or the alkali metal salt thereof, monoethanoiamine (MEA) and mixtures thereof can be used in a similar manner. Similarly, special enzyme inhibition systems can be incorporated so that different enzymes have maximum compatibility. Other conventional sequestrants such as bisulfate, nitrate, chloride, hydrogen peroxide sources such as sodium perborate tetrahydrate, sodium perborate monohydrate and sodium percarbonate, as well as phosphate, condensed phosphate, acetate, can be used if desired. benzoate, citrate, formate, lactate, malate, tartrate, salicylate, etc., and mixtures thereof. In general, since the function of the chlorine sequestrant can be performed by ingredients listed separately under better recognized functions, there is no requirement to add a separate chlorine sequestrant unless a compound that performs that function to the desired degree is absent from an embodiment containing enzyme of the invention; even then, the sequestrant is added only for optimal results. In addition, the formulator will exercise a normal chemical skill to avoid the use of any sequestrant or enzyme stabilizer that is unacceptably incompatible, as formulated, with other reactive ingredients. In relation to the use of the ammonium salts, such salts can be simply mixed with the composition; but they tend to absorb water and / or release ammonia during storage. Accordingly, such materials, if present, are desirably protected in a particle such as that described in U.S. Patent No. 4,652,392, Baginski et al. Divalent Ion The cleaning compositions of the invention may contain a. divalent ion, such as calcium and magnesium ions, at a level from 0.05% to 5% by weight, from 0.1% to 1% by weight, or approximately 0.25% by weight of the composition. In one embodiment, calcium ions may be included in the present compositions. The calcium ions can, for example, be added as a salt of chloride, hydroxide, oxide, formate or acetate, or nitrate, preferably chloride. Polyol The microbial preparation or stabilized cleaning composition of the invention can also include a polyol. The polyol, for example, can provide additional stability and hydrotropic properties to the composition. Suitable polyols include glycerin; glycols, such as ethylene glycol, propylene glycol or hexylene glycol; sorbitol; alkyl polyglycosides; and mixtures thereof. In one embodiment, the polyol includes propylene glycol. Suitable alkyl polyglycosides for use as polyols according to the invention include those with the formula: (G) x-0-R in which G is a portion derived from the reduction of saccharide containing 5 or 6 carbon atoms, by example, pentose or hexose, R is a fatty aliphatic group containing from 6 to 20 carbon atoms, and x is the degree of Polymerizations (DP) of the polyglycoside which represents the number of monosaccharide units repeated in the polyglycoside. Preferably, x is from about 0.5 to about 10. In one embodiment, R contains from 10 to 16 carbon atoms and x is from 0.5 to 3. In one embodiment, the present composition includes from about 2 to about 30% by weight of polyol, from about 2 to about 10% by weight of polyol, from about 5 to about 20% by weight of polyol, from about 5 to about 10% by weight of polyol, or from about 10 to about 20% by weight of polyol . In certain embodiments, the present stabilized microbial preparations include from about 2 to about 40% by weight of polyol, from about 2 to about 20% by weight of polyol, from about 2 to about 15% by weight of polyol, from about 2 to about about 10% by weight of polyol, from about 3 to about 10% by weight of polyol, from about 4 to about 15% by weight of polyol, or from about 4 to about 8% by weight of polyol, about 4% by weight of polyol, about 8% by weight of polyol or about 12% by weight of polyol. The composition can include any of these ranges or amounts unmodified by "about". Solvent or Co-solvent A solvent or co-solvent may be used to increase certain dirt removal properties of this invention. Preferred cosolvents are mono- and di-alkyl alcohols and ethers of alkylene glycols, dialkylene glycols, trialkylene glycols, etc. Alcohols that are useful as cosolvents in this invention include methanol, ethanol, propanol and isopropanol. Particularly useful in this invention are the mono and dialkyl ethers of ethylene glycol and diethylene glycol, which have acquired trivial names such as polyglots, seals and carbides. Representative examples of this kind of cosolvent include methyl seals, butyl carbitol, dibutyl carbitol, diglyme, triglyme, etc. Nonaqueous liquid solvents can be used for various compositions of the present invention. These include the higher glycols, the polyglycols, the polyoxides and the glycol ethers. Suitable substances are propylene glycol, polyethylene glycol, polypropylene glycol, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, tripropylene glycol methyl ether, propylene glycol methyl ether (MW), dipropylene glycol methyl ether (DPM), propylene glycol methyl ether acetate (PMA), dipropylene glycol methyl ether acetate (CPMA), ethylene glycol n-butyl ether and ethylene glycol n-propyl ether. Other useful solvents are ethylene oxide / propylene oxide liquid random copolymer such as the Synalox® series of solvents from Dow Chemical (eg, Synalox® 50-50B). Other suitable solvents are propylene glycol ethers such as PnB, DPnB, and TPnB (propylene glycol mono n-butyl ether, mono-n-butyl ethers of dipropylene glycol and tripropylene glycol sold by Dow Chemical under the trademark Dowanol®). Also suitable is tripropylene glycol monomethyl ether "Dowanol TP ® from Dow Chemical Suitable solvents for use with this invention include no VOCs or low VOCs including DPnB, PnB, D-limonene, n-methyl pyrrolidone, propylene glycol phenyl ether, ethylene glycol phenyl ether, tripropylene glycol methyl ether and the like Acidulants Acidifying or alkaline agents are used to maintain the pH appropriate for the cleaners of the invention Careful pH control can increase the cleanliness The acid component or acidulant used for preparing the cleaners of the invention will include an acid which can be dissolved in the aqueous system of the invention to adjust the pH downwards Preferably, common commercial inorganic weak organic and inorganic acids can be used in the invention. include phosphoric acid and sulfamic acid, weak useful organic acids they include acetic acid, hydroacetic acid, citric acid, tartaric acid and the like. Acidulants that are useful include organic and inorganic acids such as citric acid, lactic acid, acetic acid, glycolic acid, adipic acid, tartaric acid, succinic acid, propionic acid, maleic acid, alkaline sulfonic acids, as well as phosphoric acid and the similar ones or mixtures thereof. Additional Alkalinity Sources Alkaline materials that can be used for pH adjustment include both weak and strong alkaline materials. Such materials include strong bases such as sodium hydroxide, potassium hydroxide, alkali metal salts such as sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate, sodium sesquicarbonate, sodium borate, potassium borate, phosphate of sodium and potassium phosphate, organic bases such as triethanolamine, tripropanolamine, etc., alkali metal silicates, in general alkali metal salts. Additional sources of alkalinity may include potassium hydroxide or basic potassium salts such as potassium carbonate, potassium bicarbonate, potassium phosphate, etc. Thickening or Gelation Agents Suitable thickeners may include those that do not include components incompatible with food or other sensitive products in contact areas. In addition, the thickeners should not inhibit the growth of the spores of the present composition. Generally, thickeners that may be used in the present invention include natural gums such as xanthan gum, guar gum, modified guar, or other plant muscilage gums; modified gums; thickeners based on polysaccharides, such as aiginates, starches and cellulose polymers (for example, carboxymethylcellulose, hydroxyethyl cellulose and the like); polyacrylate thickeners; associative thickeners; and hydrocolloid thickeners, such as pectin. Generally, the concentration of the thickener used in the present compositions or methods will be dictated by the desired viscosity in the final composition. However, as a general guide, the viscosity of the thickener in the present composition ranges from about 0.05 wt% to about 3 wt%, from about 0.1 wt% to about 2 wt% or about 0.1 wt% to about 0.5% by weight. Colorant The composition of the invention may also include a colorant. The colorant advantageously provides visibility of the product in a package, dispenser and / or lines for the composition. A wide variety of dyes is suitable, including Acid Green 25 and Direct Blue 86. Compositions of Use The compositions and methods of the invention are suitable for removing complex organic or greasy dirt and inorganic dirt from a variety of substrates. The compositions of the invention can be pure (ie, without diluent such as an aqueous diluent) or can be diluted with water or other liquid medium to form an aqueous degreasing solution. In addition, the degreasing compositions of the invention can be used as an additive with other cleaning compositions formulated to clean substrates. The cleaning compositions of the invention can be used for organic and inorganic dirt that removes grease as an additive to remove grease for a material! of formulated cleaning. Such cleaning materials are common in the industry and include hard surface cleaners, laundry detergents, general purpose cleaners for use in domestic and institutional applications, floor cleaners, glass cleaners, etc. The compositions of the invention are used as an additive by adding them to a conventional cleaning formulation of from about 0.1 to about 20% by weight of the composition of the invention. The materials of this invention, even when diluted heavily in aqueous solution alone or in a formulation, such as a glass cleaner, a hard surface cleaner, a general purpose cleaner or a laundry detergent, can provide a grease removal exceptional that is as effective as the concentrated material. The compositions of the invention can be used with full force (pure, ie in the absence of an aqueous diluent). The compositions of the invention are applied directly to organic or greasy dirt typically on a hard surface such as glass, metal, composite, wood, etc. surfaces. The compositions combined with the organic or greasy dirt, tend to reduce any interface of dirt / hard surface that binds and reduces the tackiness of the complex dirt and reduces the viscosity of the dirt material, resulting in a relative ease of physical removal. A composition of use can include any of the amounts by weight percent of ingredients listed above divided by the amount of dilution and can be expressed as% by weight or ppm. In particular, the amounts listed above for boric acid salt and the microbial component or spores are for concentrated compositions. For example, a composition of use may include any of the amounts in% by weight listed above independently divided by 10, 20, 30, 40, 50, 60, 70, 80, 90,100, 200, 300, 400, 500, 600, 700, 800, 900, 1000, 2000, 3000, 4000, 5000, 6000, 7000, 8000, 9000 or 10,000. In one embodiment, the dilution is by a factor of 56 g of concentrate for 3,875 liters of use composition. Foaming In a modality, the present composition can be mixed with diluent to form a use composition that is used in a skimmer. The foaming application can be carried out, for example, by using a foam application device such as a tank skimmer or a wall mounted skimmer, for example, using a foaming nozzle or a trigger sprinkler. The application of foaming can be carried out by placing the composition of use in a pressure vessel for 58 liter foam application, such as a 58 liter stainless steel pressure vessel with mixing propellant. The foaming composition can then be dispensed through a trigger sprinkler for foaming. A wall-mounted frother can use air to expel the foam from a tank or line. In one embodiment, compressed air can be injected into the mixture, then applied to the object through a foam application device such as a tank skimmer or a wall mounted skimmer. Mechanical foaming heads that can be used according to the invention to provide foam generation include those heads that cause the air and the foaming composition to mix and form a foamed composition. That is, the mechanical head for foaming causes the air and the foaming composition to mix in a mixing chamber and then pass through an opening to produce a foam. Suitable foaming mechanical heads that can be used in accordance with the invention include those available from Airspray International, Inc., of Pompano Beach, Florida, and Zeller Plastik, a division of Crown Cork and Seal Co. The appropriate mechanical heads for Foamed materials that can be used in accordance with the invention are described, for example, in U.S. Patent No. D-452,822; U.S. Patent No. D-452,653; U.S. Patent No. D-456,260; and U.S. Patent No. 6,053,364. Mechanical foaming heads that can be used in accordance with the invention include those heads that are actuated or that attempt to be actuated by applying pressure from a finger to a trigger that causes the foaming composition and air to mix and produce a foam. That is, the pressure of a person's finger can cause the trigger to be depressed thereby removing the foaming composition and the air towards the head and causing the foaming composition and the air to mix and produce a foam. Methods Employing the Present Compositions In one embodiment, the cleaning composition is applied directly to a large dirt deposit, allowing it to soften and promote the removal of dirt. Once the composition has been allowed to increase the dirt removal capacity, the cleaner and the removed dirt can be easily removed with a rinsing step. In one embodiment, the method omits rinsing. That is, the present composition can be applied and the surface is not rinsed. The compositions of the invention which include a nonionic surfactant, a nonionic silicone surfactant, an ammonium surfactant and a hydrotrope can be contacted directly with the hard surface for the removal of organic, oily or greasy dirt. Depending on the substrate, such a composition may additionally include a chelating agent having a final formulation that includes a nonionic surfactant, and a nonionic silicone surfactant, an anionic surfactant, a hydrotrope solubilizer and a chelating agent. These compositions can be used on substantially non-corrosive surfaces, such as plastics, wood, coated wood, stainless steels, composite materials, fabrics, cement and others. In one embodiment, the present method includes a method for cleaning a hard surface. The method may include applying to the surface a cleaning composition that includes spores or bacteria; a borate salt; from about 0.5 to about 35% by weight of nonionic surfactant; and from about 0.1 to about 35% by weight of silicone surfactant. The method may include application of the composition to a floor, drainage or a combination thereof. In one embodiment, the present method includes a method for cleaning a floor. Such a method may include increasing the coefficient of friction of the floor. Such a method may include cleaning the cementation of a mosaic floor. The cleaning of the cement can include allowing it to show more of its natural color. The method includes applying a stabilized spore composition according to the present invention to the floor. In one embodiment, the method does not include (e.g., omit) rinsing. In one embodiment, the present method can include effectively removing from the floor covering (eg, mosaic) a film that is slippery when wet. The method may include cleaning the floor covering and increasing its coefficient of friction. In one embodiment, the present method for cleaning a hard surface may include applying the present composition to a surface of a bath, such as a wall, a floor or accessories. The surface of the bathroom can be a wall or surface of the shower. The surface of the bathroom can be a wall with mosaics. A composition for use on a vertical surface may include a thickener, a humectant or a foaming surfactant. Applying the composition to the vertical surface may include foaming the composition. In one embodiment, the present composition includes a thickener or humectant, which may assist in retention of the composition on a horizontal or vertical surface. In one embodiment, the present method can include the application of the present composition to a surface having grease or oil therein. Such surfaces include a floor, a parking lot, a department hall, a garage floor, a parking ramp floor and the like. In one embodiment, the present method includes spraying a surface with the present composition. In one embodiment, the present method includes applying the stabilized microbial composition to a surface and keeping the surface moist for an extended period, such as one to two hours to about eight to about 16 hours. Maintaining the wet surface can be done by repeated application of the composition, such as by spraying. Maintaining the wet surface can be done by contacting the surface with a sponge, wet mop with the composition for an extended period. Maintaining the wet surface can be done by applying a persistent stable microbial composition. A persistent stable microbial composition can remain on the surface and keep the surface moist. For example, a thickened composition and certain foaming compositions may remain on the surface and keep the surface moist. The extended presence of the present composition can provide a faster cleaning compared to a composition that dries or evaporates. The present invention can be better understood with reference to the following examples. These examples are intended to be representative of specific embodiments of the invention and are not intended to limit the scope of the invention. EXAMPLES Example 1 - Microbial Preparations Stabilized with Borate Salts The compositions according to the present invention were shown to stabilize the microbial preparations, specifically a spore composition that digests fat. Materials and Methods This experiment evaluated the aerobic plaque counts produced from various cleaning compositions including bacterial spores, with or without aging of the compositions. Those compositions that include viable spores produced colonies of bacteria with lipolytic activity that resulted in dark areas in coated growth medium. The dark zones resulted from the production of free fatty acids. The controls included spores or bacteria suspended in water and a conventional bacterial cleaning composition. The test method was a normal protocol of "Lipolytic Microorganisms", Compendium of Methods for the Microbiological Food Examination, third edition, 1992, p. 183. Briefly, plaques of Iipolitic agar were prepared. The plates were inoculated with the test bacterial suspensions and allowed to dry. Nutrient agar was emptied on the inoculated surface. The plates were incubated at room temperature to allow the growth of bacteria and inspected for the appearance of lipolytic colonies. The lipolytic colonies were identified by a dark blue surrounding area. The following compositions were made and tested in this example: 1 2 3 4 5 6 7 Water 26 28 28 30 54 56 56 Boric acid 10 10 10 10 Alcanol amine 19 19 19 19 2 2 2 Polio! 8 8 8 8 8 8 8 Non-ionic surfactant 8 8 8 8 8 8 8 Silicone surfactant 3 3 3 3 3 3 3 Amphoteric surfactant 5 5 5 5 5 5 5 Ammonium surfactant 8 8 8 8 8 8 8 Hydrotrope 11 11 11 11 11 11 Spore mix 2 2 2 2 Protease 2 2 2 2 All amounts in% by weight.

The control composition 8 included 2% by weight of spore mixture in water. The control composition 9 included 2% by weight of protease in water. The control composition 10 included 2% by weight of spore mixture and 2% by weight of protease in water. Each composition was diluted up to 2% by weight for bacterial growth test. Results Tables 1 to 3 report the test results of the viability of the spore mixture in the compositions described above, in control formulations and in commercially available formulations. Table 1 * = Cross contamination between samples.

Table 2 Description (formula number) Aerobic lipolytic plate count (CFU / mL) (1) Amine borate + 2% spore mixture + 1.7 x 104 2% freshly made protease (1) Amine borate + 2% spore mixture + 2.1 x 104 2% aged protease 6 days (5) Without borate + 2 % spore mixture + 2% 2.5 x 104 freshly made protease (5) Without borate + 2% spore mixture + 2% 2.0 x 103 6-day old protease 2% commercial spore mixture 5.0 x 102 contains cleaner of unknown age 2% commercial spore mix 3.6 x 103 contains 4 month old cleaner Water + 2% spore mix 3.0 x 104 Table 3 Description (formula number) Aerobic lipolytic plate count (CFU / mL) (1) Amine borate + 2% spore mixture + 2.1 x 104 2% protease aged 10 weeks Table 3 (continued) Conclusions Amine borate salts stabilize the spores of bacteria that digest fat and the bacteria themselves. Increased stability was observed for concentrated compositions including salts of amine borate and mixture of spores. For example, a six-day sample of formula 5 (without borate) lost approximately one log of bacterial activity. A sample of unknown age lost approximately two logs of bacterial activity. Unexpectedly, the amine borate salts, which may have limited solubility, were soluble in compositions with silicone surfactants. Example 2 - Borate Salt Compositions Including Microbial Preparations Stabilized with Polyol The compositions according to the present invention and including both borate salt and polyol were shown to stabilize the microbial preparations, specifically a composition of spores that digest fat. Materials and Methods Compositions were made according to the general formulas listed in Example 1, but with varying concentrations of borate counter (for example, aicanoiamine) and polyol (for example, propylene glycol). The stability of the compositions was determined by measuring lipolytic activity at various times after the composition was made. The compositions generally contained 2% by weight of spore mixture. Each composition was diluted to 2% by weight to test for bacterial growth, which was done as described in Example 1. The following compositions were made and tested in this example. 11 12 13 14 15 16 17 18 19 20 Water 50 44 38 31 48 36 58 55 49 43 Acid 2 4 6 8 4 8 2 4 6 8 boric Alcanol 5 9 14 18 9 18 5 9 14 18 amine Polyol 8 8 8 8 4 4 Tensoactive 8 8 8 8 8 8 8 8 8 8 non-ionic Surfactant 3 3 3 3 3 3 3 3 3 3 silicone Surfactant 5 5 5 5 5 5 5 5 5 5 amphoteric Surfactant 8 8 8 8 8 8 8 8 8 8 anionic Hydrotrope 11 11 11 11 11 11 11 8 8 8 Mixture of 2 2 2 2 2 2 2 2 2 2 spores Protease 1 pH 100% 9.7 10 10.3 10.1 10.1 10.5 10.1 10 10.4 10.5 pH 1% 9.2 9.3 9.5 9.3 9.3 9.5 9.5 9.4 9.4 9.5 Results Tables 4 to 8 report the results of the viability test of the spore mixture in compositions 11 to 20.

Table 4 - Undamaged Compositions Description (number of Composition Reduction Results) aerobic growth plate count (CFU / mL) (Log) (11) Boric acid 2% + 5% MEA + 4.5 x 104 NA 8% propylene glycol (12) Boric acid 4% + 9% MEA + 3.0 x 103 NA 8% propylene glycol (13) Boric acid 6% + 14% MEA 2.2 x 104 NA + 8% propylene glycol (14) Boric acid 8% + 18% MEA 2.0 x 104 NA + 8 % propylene glycol (15) Boric acid 4% + 9% MEA + 2.4 x 104 NA 4% propylene glycol (16) Boric acid 8% + 18% MEA 2.8 x 104 NA + 4% propylene glycol (17) Boric acid 2% + 5% MEA 5.4 x 104 NA (18) Boric acid 4% + 9% MEA 5.0 x 104 NA (19) Boric acid 6% + 14% MEA 2.7 x 104 NA (20) Boric acid 8% + 18% MEA 3.4 x 104 NA Table 5 - Aged Compositions 4 Weeks Description (number of Composition Reduction Results) aerobic growth plate count (CFU / mL) (Log) (11) Boric acid 2% + 5% MEA + 2.4 x 105 8% propylene glycol (12) Boric acid 4% + 9% MEA + 9.4 x 104 -8% propylene glycol (13) Boric acid 6% + 14% MEA 1.2 x 105 - + 8% propylene glycol (14) Boric acid 8% + 18% MEA 1.2 x 105 - + 8% propylene glycol (15) Boric acid 4% + 9% MEA + 3.2 x 105 -4% propylene glycol ( 16) Boric acid 8% + 18% MEA 1.0 x 105 - + 4% propylene glycol (17) Boric acid 2% + 5% MEA 1.9 x 105 - (18) Boric acid 4% + 9% MEA 2.5 x 104 0.3 (19) Boric acid 6% + 14% MEA 4.8 x 104 - (20) Boric acid 8% + 18% MEA 1.0 x 105 - Table 6 - Aged Compositions 8 Weeks Description (number of Composition Reduction Results) aerobic growth plate count (CFU / mL) (Log) (11) Boric acid 2% + 5% MEA + 2.1 x 105 0.33 8% propylene glycol (12) Boric acid 4% + 9% MEA + 3.0 x 104 8% propylene glycol (13) Boric acid 6% + 14% MEA 2.2 x 103 1.0 + 8% propylene glycol (14) Boric acid 8% + 18% MEA 3.4 x 104 - + 8% propylene glycol (15) Boric acid 4% + 9% MEA + 3.3 x 104 -4% propylene glycol (16) Boric acid 8% + 18% MEA 1.3 x 104 0.33 + 4% propylene glycol ( 17) Boric acid 2% + 5% MEA 1.8 x 104 0.48 (18) Boric acid 4% + 9% MEA 2.7 x 104 0.27 (19) Boric acid 6% + 14% MEA 5.0 x 103 0.72 (20) Boric acid 8% + 18% MEA 6.0 x 103 0.75 Table 7 - Aged Compositions 12 Weeks Description (number of Composition Reduction Results) aerobic growth plate count (CFU / mL) (Log) (11) Boric acid 2% + 5% MEA + 1.1 x 104 0.61 8% propylene glycol (12) Boric acid 4% + 9% MEA + 5.2 x 103 -8% propylene glycol (13) Boric acid 6% + 14% MEA 5.4 x 102 1.61 + 8% propylene glycol (14) Boric acid 8% + 18% MEA 1.4 x 102 2.15 + 8% propylene glycol (15) Boric acid 4% + 9% MEA + 6.8 x 103 0.55 4% propylene glycol (16) Boric acid 8% + 18% MEA 1.5 x 10 '3.27 + 4% propylene glycol (17) Boric acid 2% + 5% MEA 2.4 x 103 1.35 (18) Acid boric 4% + 9% MEA 3.2 x 103 1.19 (19) Boric acid 6% + 14% MEA 5.1 x 102 1.72 (20) Boric acid 8% + 18% MEA <1 x 101 3.53 Table 8 - Aged Compositions 16 Weeks Description (number of Composition Reduction Results) aerobic growth plate count (CFU / mL) (Log) (1) Boric acid 2% + 5% MEA + 6.2 x 103 0.86 8% propylene glycol (12) Boric acid 4% + 9% MEA + 2.0 x 103 0.18 8% propylene glycol (15) Boric acid 4% + 9% MEA + 5.8 x 102 1.62 4% propylene glycol Conclusions Only minor reductions in bacterial growth occurred as the compositions aged for up to eight weeks.

The most significant reductions in bacterial growth were observed after 12 weeks of aging. For example, bacterial growth was reduced by more than or equal to one log for composition numbers 13, 14, 16, 17, 18, 19 and 20. That means that composition numbers 11, 12, and 15 exhibited the greatest stabilization after 12 weeks of aging. These results confirm that borate salts (eg, alkanolamine borate salts) stabilize the spore mixture. Interestingly, each of the compositions lacking polyol showed a production of more than one log. This indicates that the polyol contributes to the stabilization of the spore mixture. Interestingly, the present compositions stabilized the spore mixture still at a pH above 9.5, a pH of 10, and still at a pH of 10.5. For example, composition 12 stabilized the spore mixture for up to 16 weeks at a pH of about 10. EXAMPLE 3 - Compositions with Borate Salt Stabilizing Microbial Preparations at a Basic pH The compositions according to the present invention were demonstrated and they include both borate salt and polyol stabilize the microbial preparations, specifically a composition of spores that digest fat, in a wide range of basic pH. Materials and Methods Compositions were made according to the general formulas listed in Example 1, but with variable pH. The stability of the compositions was determined by measuring the lipolytic activity at various times after the composition was made. The compositions generally contained 2% by weight of spore mixture. Each composition was diluted to 2% by weight to test for bacterial growth, which was done as described in Example 1. The following compositions were made and tested in this example.

All quantities in% by weight.

Results Tables 9 and 10 report the results of the feasibility test of the spore mixture in the compositions 21 to 25. Table 9 - Lipolytic Microbial Counts (CFU / ml) - Average of Duplicate Plates * Concentrate aged 14 weeks, diluted use composition aged 24 hours. Table 10 - Reduction in Growth After Aging (log units) Conclusions For at least about 14 weeks to age the present compositions including borate salt and polyol provided effective stability for the mixture of spores at pH from 7 to 9. Example 4 - Microbial Compositions Stabilized with Aggregated Lipase Compositions were made according to with the present invention and which include borate salt, polyol and lipase and showed to be stable and effective cleansers (compositions 26 and 27). These included lipase-containing compositions and compositions (28 to 31) containing additional lipase may include ingredients in the following amounts: 26. 27 28 29 30 31 32 33 Water 27 64 60 56 52 48 64 52 Acid 10 5 5 5 5 5 5 5 boric Alcanol 18 9 9 9 9 9 9 8 amine Polyol 8 4 8 12 16 20 4 12 Surfactant 8 4 4 4 4 4 4 4 nonionic Surfactant 3 1 1 1 1 1 1.3 1.3 sulfonium surfactant 5 3 3 3 3 3 3 3 amphoteric Surfactant 8 4 4 4 4 4 4 4 anionic Hydrotrope 11 3 3 3 3 3 5 5 Sequester 4 te Mixture 2 1 1 1 1? 1 1 spores Lipasa 2 1 1 1 1 1 1 2 Example 5 - Stabilized Microbial Compositions Increase Slip Resistance of Floors Compositions according to the present invention and including borate salt, polyol and lipase showed that they are effective to significantly increase the slip resistance of a tile floor. Materials and Methods A use solution was applied that included composition 33 (14.5 g / L or 16% concentrate) each day to a tile floor, specifically a floor of terrazzo mosaics, without rinsing. Dry and wet skid resistance measurements were taken over a period of six weeks in kitchens of five restaurants. The six weeks included two weeks for base measurements and four weeks or measurements after application of the composition 33. Before cleaning with the present composition (for example, during the base period and before), the floor was cleaned daily with a conventional floor cleaning composition commercially available. Slip resistance was measured as a coefficient of friction (COF) using an English XL Variable Incidence Tribometer in accordance with ASTM F1679-02. The protocol was as follows. 15 quarry mosaics were selected in each restaurant kitchen. In the main passage corridors and areas of interest (for example, near the frying pans) each fifth mosaic was selected. The same 15 tiles were evaluated in each restaurant for COF each week. The COF of each tile was measured four times, once in each of four directions separated by 90 °. Each tile measured as dry as wet. The 60 measurements under each condition were averaged for each restaurant, and the results were averaged for the five restaurants. Results Figure 1 illustrates the results obtained weekly for the COF (slip resistance) for the 15 tiles in each of the five restaurants. The dry mosaic COF improved from an average base value of 0.60 to 0.81 through the four week trial period. The wet mosaic COF improved from a base average value of 0.38 to 0.56 through the four week trial period. Each of these increases is significant with a confidence level that exceeds 99%. Conclusion The compositions according to the present invention significantly increase the friction coefficients for slippery surfaces, such as floors in restaurant kitchens. Example 6 - Stabilized Microbial Compositions Clean Encemented The compositions according to the present invention and including borate salt, polyol and lipase were shown to be effective in cleaning the cement between the tiles. Materials and Methods A dilution of use of composition 33 (14.5 g / L or 1.6% concentrate) was applied to the tile floor, specifically a quarry tile floor, without rinsing, as described in Example 5. The mosaic it was photographed before and after the application of the present composition. Results The photographs of Figures 2A and 2B illustrate that the present composition cleaned the cement in a quarry tile floor in a restaurant kitchen. Figure 2A illustrates the floor before the application of the present composition. Figure 2B illustrates the floor after application of the present composition. Figure 3 illustrates a portion of a floor cleaned with a conventional cleaning composition (left) and a portion cleaned with composition 33. The composition 33 cleaned the cement, the conventional composition did not. Conclusions The present compositions cleanse the mosaics more effectively than conventional compositions. Example 7 - Stabilized Microbial Compositions Clean Floors Compositions according to the present invention and including borate salt, polyol and spores proved to be effective for cleaning floors. Materials and Methods A dilution of use of composition 34 (14.5 g / L or 1.6% concentrate) was applied to a mosaic floor, specifically a floor of quarry mosaics, without rinsing. The floor was evaluated before and after the application of the present composition.

Results Composition 34 cleaned the floor. Conclusions The present compositions clean floors more effectively than conventional compositions. It should be noted that, as used in this specification and the appended claims, the singular forms of "a", "an", and "the" include plural referents unless the content clearly dictates otherwise. Thus, for example, reference to a composition containing "a compound" includes a mixture of two or more compounds. It should also be noted that the term "or" is generally used in its sense that includes "and / or" unless the content clearly dictates otherwise. All publications and patent applications in this specification are indicative of the level of ordinary skill in the art to which this invention pertains. The invention has been described with reference to several specific and preferred embodiments and techniques. However, it should be understood that many variations and modifications can be made although they remain within the spirit and scope of the invention.

Claims

CLAIMS 1. A cleaning composition comprising: spores, bacteria or fungi; and alkanolamine borate. The composition of claim 1, wherein the composition has a pH greater than or equal to 8. The composition of claim 1, further comprising polyol. 4. The composition of claim 3, wherein the polyol comprises propylene glycol. The composition of claim 1, further comprising up to about 65% by weight of water. The composition of claim 1, wherein the alkanolamine borate comprises monoethanolammonium borate, diethanolammonium borate, triethanolammonium borate or a combination thereof. The composition of claim 1, comprising from about 5 to about 35% by weight of alkanolamine borate. The composition of claim 1, wherein the spores or bacteria comprise bacterial spores. The composition of claim 1, further comprising from about 0.003 to about 35% by weight of nonionic surfactant. The composition of claim 9, wherein the nonionic surfactant comprises: a non-ionic block copolymer consisting of at least (EO) and (PO) z, wherein y and z are independently between 2 and 100; alkyl alkoxylate of 6 to 24 carbon atoms-phenol having from 2 to 15 moles of ethylene oxide; alcohol alkoxylate of 6 to 24 carbon atoms having from 2 to 15 moles of ethylene oxide; alkoxylated amine having from 2 to 20 moles of ethylene oxide; or mixtures thereof. The composition of claim 1, further comprising from about 0.0005 to about 35% by weight of silicone surfactant. 12. The composition of claim 11, wherein the silicone surfactant comprises a silicone structure and at least one pendant ethylene oxide group having from about 2 to 100 moles of alkylene oxide. The composition of claim 12, wherein the pendant alkylene oxide group comprises (EO) n wherein n is from 3 to 75. The composition of claim 1, further comprising from about 0.003 to about 35 % by weight of anionic surfactant. 15. The composition of claim 14, wherein the anionic surfactant comprises; linear alkyl benzene sulfonate; alpha olefin sulfonate; alkyl sulfonate; secondary alkane sulfonate; sulfosuccinate; or mixtures thereof. 16. The composition of claim 1, further comprising from about 0.001 to about 20% by weight of hydrotrope. 17. The composition of claim 16, comprising from about 0.1 to about 20% by weight of hydrotrope. The composition of claim 16, wherein the hydrotrope comprises: alkyl-oxide of 6 to 24 carbon atoms-dimethyl amine; alkylated diphenium oxide disulfonate; or mixtures thereof. The composition of claim 1, further comprising: from about 0.5 to about 35% by weight of nonionic surfactant; and from about 0.1 to about 35% by weight of silicone surfactant. The composition of claim 19, wherein: the nonionic surfactant comprises: nonionic block copolymer constituted by at least (EO) and (PO) z; alkyl alkoxylate of 6 to 24 carbon atoms-phenol having from 2 to 15 moles of ethylene oxide; alcohol alkoxylate of 6 to 24 carbon atoms having from 2 to 15 moles of ethylene oxide; alkoxylated amine having from 2 to 20 moles of ethylene oxide; or mixtures thereof; the silicone surfactant comprises a silicone structure and at least one pendant alkylene oxide group having from about 2 to 100 moles of alkylene oxide; and the weight ratio of the nonionic surfactant to the nonionic silicone surfactant is from about 0.1 to about 10 parts by weight of the nonionic surfactant for each part of the silicone surfactant. The composition of claim 1, further comprising: from about 0.5 to about 35% by weight of nonionic surfactant; from about 0.1 to about 35% by weight of silicone surfactant; from about 0.5 to about 35% by weight of anionic surfactant; and from about 0.1 to about 20% by weight of hydrotrope. The composition of claim 21, wherein the nonionic surfactant comprises: nonionic block polymer constituted at least (EO) and (PO) z; alkyl alkoxylate of 6 to 24 carbon atoms-phenol having from 2 to 15 moles of ethylene oxide; alcohol alkoxylate of 6 to 24 carbon atoms having from 2 to 15 moles of ethylene oxide; alkoxylated amine having from 2 to 20 moles of ethylene oxide; or mixtures thereof; the silicone surfactant comprises a silicone structure and at least one pendant alkylene oxide group having from about 2 to 100 moles of alkylene oxide; the proportion by weight of the nonionic surfactant to the nonionic silicone surfactant is from about 3 to 7 parts by weight of the nonionic surfactant for each part of the silicone surfactant; the anionic surfactant comprises alkenyl ammonium alkyl benzenesulfonate; and the hydrotrope comprises: alkyl-oxide of 6 to 24 carbon-dimethyl amine atoms; alkylated biphenyl oxide disulfonate; or mixtures thereof. composition of claim 21, further comprising: an effective amount of one or more solvents; an effective amount of one or more enzymes; an effective amount of one or more antimicrobials; an effective amount of one or more chelating agents; or mixtures thereof. 24. The composition of claim 1, further comprising detergent enzyme. The composition of claim 24, wherein the detergent enzyme comprises protease, amylase, lipase, cellulase, peroxidase, gluconase or mixtures thereof. 26. A cleaning composition comprising: spores or bacteria; and borate salt; the composition that is substantially free of sodium ion. The composition of claim 26, wherein the composition has a pH greater than or equal to 8. The composition of claim 26, further comprising p or I i or I. 29. The composition of claim 28, wherein the polyol comprises propylene glycol. 30. The composition of claim 26, further comprising up to about 65% by weight of water. The composition of claim 26, wherein the boric acid salt comprises a boric acid alkali metal salt, a boric acid salt of alkanol amine or a combination thereof. 32. The composition of claim 31, wherein the boric acid salt comprises monoethanolammonium borate, diethanolammonium borate, triethanolammonium borate or a combination thereof. 33. The composition of claim 31, wherein the boric acid salt comprises potassium borate. 34. The composition of claim 33, wherein the potassium borate comprises a combination of potassium hydroxide and boric acid. 35. The composition of claim 26, comprising from about 5 to about 35% by weight of borate-salt. 36. The composition of claim 26, further comprising: from about 0.5 to about 25% by weight of nonionic surfactant; and from about 0.1 to about 25% by weight of silicone surfactant. 37. The composition of claim 36, wherein: the nonionic surfactant comprises: nonionic block copolymer comprising at least (EO) and (PO) z; alkyl alkoxylate of 6 to 24 carbon atoms-phenol having from 2 to 15 moles of ethylene oxide; alcohol alkoxylate of 6 to 24 carbon atoms having from 2 to 15 moles of ethylene oxide; alkoxylated amine having from 2 to 20 moles of ethylene oxide; or mixtures thereof; the silicone surfactant comprises a silicone structure and at least one pendant alkylene oxide group having from about 2 to 100 moles of alkylene oxide; and the weight ratio of the nonionic surfactant to the nonionic silicone surfactant is from about 0.1 to 10 parts by weight of the nonionic surfactant for each part of the silicone surfactant. 38. The composition of claim 26, further comprising: from about 0.5 to about 35% by weight of nonionic surfactant; from about 0.1 to about 35% by weight of silicone surfactant; from about 0.5 to about 35% by weight of anionic surfactant; and from about 0.1 to about 20% by weight of hydrotrope. 39. The composition of claim 38, wherein: the nonionic surfactant comprises: nonionic block copolymer comprising at least (EO) and (PO) z; alkyl alkoxylate of 6 to 24 carbon atoms-phenol having from 2 to 15 moles of ethylene oxide; alcohol alkoxylate of 6 to 24 carbon atoms having from 2 to 15 moles of ethylene oxide; alkoxylated amine having from 2 to 20 moles of ethylene oxide; or mixtures thereof; the silicone surfactant comprises a silicone structure and at least one pendant alkylene oxide group having from about 2 to 100 moles of alkylene oxide; and the weight ratio of the nonionic surfactant to the nonionic silicone surfactant is from about 3 to 7 parts by weight of the nonionic surfactant for each part of the silicone surfactant; the anionic surfactant comprises alkyl benzene alkanol ammonium sulforide; and the hydrotrope comprises: alkyl oxide of from 6 to 24 carbon atoms-dimethyl amine; alkylated diphenyl oxide disulfonate; or mixtures thereof. 40. The composition of claim 26, further comprising detergent enzyme. 41. A method for cleaning a hard surface, comprising applying to the surface a cleaning composition comprising: spores or bacteria; borate salt; from about 0.5 to about 35% by weight of nonionic surfactant; and from about 0.1 to about 35% by weight of Siicone surfactant. 42. The method of claim 41, comprising applying the composition to a floor, a drain or a combination thereof. 43. A method for cleaning enamelling, which comprises applying to the enamel a cleaning composition comprising: spores or bacteria; borate salt; from about 0.5 to about 35% by weight of nonionic surfactant; and from about 0.1 to about 35% by weight of Siicone surfactant. 44. The method of claim 43, comprising applying the composition to a surface with mosaics. 45. The method of claim 44, comprising applying the composition to a tile floor.