MXPA01001135A - Transparent hair conditioning composition comprising breakable visible particle - Google Patents

Abstract

Disclosed is a hair conditioning composition comprising:(1) a breakable visible particle;(2) a silicone compound;and (3) an aqueous carrier;wherein the composition is transparent.

Description

TRANSPARENT HAIR CONDITIONER COMPOSITIONS COMPRISING VISIBLE AND ROMPABLE PARTICLE TECHNICAL FIELD The present relates to transparent hair conditioning compositions comprising a visible and breakable particle.

BACKGROUND OF THE INVENTION Human hair becomes dirty due to its contact with the surrounding environment and due to the sebum secreted by the scalp. When the hair is dirty it has an unpleasant and greasy feeling and an unattractive appearance. When the hair is dirty, shampoo needs to be given regularly. Shampooing the hair causes it to be cleaned by removing excess dirt and sebum. However, the shampoo can leave the hair in a wet, matted and generally unwieldy condition. Once the hair dries, it usually remains in a dry, stiff, lusterless or creped condition, due to the removal of natural hair oils and other natural conditioning and moisturizing components. The hair can also be left with very high levels of static when drying, which can interfere with the hairstyle and result P1188 Z? T * a condition commonly referred to as "hair that flies" or contributes to an undesirable "split ends" phenomenon particularly in long hair. A variety of approaches have been developed to reduce these problems after shampooing. This range of approaches ranges from the post-shampoo application of a hair conditioner, for example products to apply and not to rinse and products to eliminate by rinsing, to conditioning shampoos that try to both clean and condition the hair in a single product. Although some consumers prefer the ease and convenience of a shampoo that includes conditioners, a considerable proportion of consumers prefer more conventional conditioning formulations that are applied to the hair as a separate step to that of the shampoo, and in a manner normally subsequent to the shampoo. The conditioning formulations may be in the form of products that are removed by rinsing or in products that remain on the hair, and which may be in the form of an emulsion, cream, gel, spray and foam. These consumers who prefer conventional formulations of conditioners value the relatively superior conditioning effect or the convenience of changing the amount of conditioning depending on the conditioning depending on the condition of the hair or portion of hair. The conditioning formulations may be in the form of applied and rinsing products or products that are applied and not rinsed, ie, are deposited on the hair, and may be in the form of emulsions, creams, gels, sprays and foams. The products in the form of creams, gels and foams are suitable because the consumer can easily control the quantity of the product and its distribution. These products are particularly suitable for the products to be applied and not to be rinsed. The products to apply and not to rinse and that provide aesthetic advantages are those preferred by the consumer. Transparent or nearly transparent products that include distinctive visible particles are particularly preferred with respect to aesthetics. However, conventional products to apply and not to rinse do not provide these aesthetic effects in a totally satisfactory way that at the same time leaves the hands and hair are a feeling of being clean. Based on the above, there is still the desire to provide hair conditioning compositions, suitable for applying and non-rinsing products, which have favorable aesthetic benefits, which improve the benefits of hair conditioning, such as P1188 ÍB ™ softness, silkiness and reduction of friction, which are easy to apply to the hair and leave the hair and hands with a feeling of cleanliness. There is no antecedent that provides all the advantages and benefits of the present invention.

SUMMARY The present invention relates to a hair conditioning composition comprising: (1) a visible and breakable particle; (2) a silicone compound; and (3) an aqueous carrier; where the composition is transparent. These or other charactercs, aspects and advantages of the present invention will become apparent to those skilled in the art, from the reading of the present disclosure.

DETAILED DESCRIPTION OF THE INVENTION While the specification concludes with the claims that particularly state and dnctly claim the invention, it is believed that the present invention will be better understood from the following description. 25 All references cited are considered to be P1188 - í.M «y» ». *. »* ^ JfA i ». ' ** & * < ,, * «& £ .. their entirety are part of this, as a reference. The citation of any reference is not an acceptance with respect to any determination for its availability as a prior art to the claimed invention. In the present, "comprising" means that other steps and other ingredients may be added that do not affect the final result. This term encompasses the terms "consng of" and "consng basically of". All percentages, parts and proportions are based on the total weight of the compositions of the present invention, unless otherwise specified. All these weights insofar as they belong to the ld ingredients are based on the active level and, therefore, do not include vehicles or by-products that could be included in commercially available materials. The aspects and embodiments of the present invention set forth in this document have many advantages. For example, the hair conditioning compositions of the present invention provide favorable aesthetic benefits, which improve the benefits of hair conditioning, such as softness, silkiness and reduction of friction, which are easy to apply to the hair and which leave the hair and hair. hands with a clean feeling.

P1188 mfc VISIBLE AND ROMPABLE PARTICLE The compositions of the present invention comprise a visible and breakable particle. By definition, a breakable visible particle is a particle that can be detected in a dnctive manner as an individual particle with the naked eye, when it is comprised in the present invention, and is stable in the present composition, although when used it is liable to break. The breakable visible particle can be of any size, shape or color, in accordance with the desired charactercs of the product, as long as they are detected in a dnctive way to the naked eye as an individual particle. In general, the visible and breakable particle has an average diameter of approximately between 50μm and 3000μm, approximately between lOOμm and lOOOμm and more preferably approximately between 300μm and lOOOμm. For stable, what is meant is that the visible and breakable particles do not disintegrate, agglomerate or separate under normal conditions on the shelf. By "breakable" it is understood that the visible and breakable particles can disintegrate with application of little shearing force by the effect of the fingers, on the hand, during use. The visible and breakable particles of the present are used at levels that provide the P1188 composition a favorable aesthetic benefit, according to the desired charactercs of the product, typically found in up to about 10% by weight of the composition, preferably between about 0.01% and 5% by weight of the composition. The visible and breakable particles of the present invention comprise a structural material and, preferably, a contained material. The structural material provides some resnce to the visible particle, so that it retains its dnctly detectable structure in the composition present under the normal conditions of the shelf, while they can break and disintegrate by applying little shear with the hand and fingers, during use. The structural materials comprise components selected from the group consisting of polysaccharides and their derivatives, saccharides and their derivatives, oligosaccharides, monosaccharides and mixtures thereof. Preferably, from the previous group, components that have different solubilities in water are selected for the preparation of the structural material. More preferably, the structural material comprises components selected from the group consisting of cellulose, cellulose derivatives, saccharides and mixtures thereof. More preferably, the structural materials comprise a mixture of cellulose, cellulose derivatives and saccharides. Examples of components useful in making the structural material Visible particles useful herein include: polysaccharides and saccharide derivatives, such as crystalline cellulose, cellulose acetate, cellulose acetate butyrate, cellulose acetate phthalate, cellulose nitrate, ethyl cellulose , hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxypropylmethylcellulose phthalate, methylcellulose, sodium carboxymethylcellulose, acacia gum (gum arabic), agar, agarose, maltodextrin, calcium alginate sodium alginate, dextran starch, galactose, glucosamine, cyclodextrin, chitin, amylose, amylopectin, glycogen, laminating, lichenan, curdlan, inulin, levan, pectin, morning sugar, xylan, alginic acid, arabic acid, glucomannan, agarose, agaropectin, profirano, carrageenan, fucoidan, glycosaminoglycan, hyaluronic acid, chondroitin, peptidoglycan, lipopolysaccharide, gum guar, starch and starch derivatives; oligosaccharides such as sucrose, lactose, maltose, uronic acid, muramic acid, cellobiose, isomaltose, planteosa, melezitose, gentianose, maltotriose, stachyose, glucoside and polyglucoside; monosaccharides, such as glucose, fructose and mannose. The components that may also be included in the structural material are: synthetic polymers, such as P1188 'J & z', - ">? *" Acrylic polymers and copolymers including polyacrylamide, poly (alkyl cyanoacrylate) and poly (ethylene vinyl acetate) and carboxyvinyl polymer, polyamide, poly (methyl vinyl ether maleic anhydride) , poly (adipyl-L-lysine), polycarbonate, polyterephthalamide, polyvinyl acetate phthalate, poly (terephthaloyl-L-lysine), polyarylsulphone, poly (methylmethacrylate), poly (e-caprolactone), polyvinylpyrrolidone, polydimethylsiloxane, polyoxyethylene, polyester, polyglycolic acid, polylactic acid, polyglutamic acid, polylysine, polystyrene, poly (styrene-acrylonitrile), polyimide and polyvinyl alcohol, and other materials such as fat, fatty acid, fatty alcohol, milk solids, molasses, gelatin, gluten , albumen, shellac, caseinate, beeswax, carnauba wax, spermaceti wax, hydrogenated tallow, glycerol monopalmitate, glycerol dipalmitate, hydrogenated castor oil, glycerol monostearate, glycerol distearate , glycerol tristearate, 12-hydroxystearyl alcohol, protein and protein derivatives; and mixtures thereof. The components herein can be described in other sections as useful components of the present composition. However, the components of the present are mainly used to prepare the structure of the visible breakable particles and do not dissolve substantially in the mass of the present composition under the normal conditions of the shelf. The visible and breakable particles of the present may encompass, contain or be filled with a contained material. This contained material may be water soluble or insoluble therein and comprises components such as: vitamins, amino acids, proteins and protein derivatives, herbal extracts, pigments, dyes, antimicrobial agents, chelating agents, UV light absorbers, optical brighteners, silicone compounds, perfumes, humectants which are generally soluble in water, additional conditioning agents which are generally insoluble in water and mixtures thereof. In a preferred embodiment, water-soluble components are preferred as the material contained. In another embodiment, the components selected from the group consisting of vitamins, amino acids, protein-derived proteins, herbal extracts and mixtures thereof are the preferred content material. In another embodiment, the preferred content material are components selected from the group consisting of vitamin E, pantotenyl ethyl ether, panthenol, multiflores Polygonum extracts and mixtures thereof. The vitamins and amino acids useful as the material contained herein include: vitamins soluble in P1188 water such as vitamin Bl, B2, B6, B12, C pantothenic acid, pantotenyl ethyl ether, panthenol, biotin and its derivatives, water soluble amino acids, such as asparagine, indole alanine, glutamic acid and its salts, water-insoluble vitamins, such as vitamins A, D, E and their derivatives, water insoluble amino acids such as tyrosine, tryptamine and their salts. Pigments useful as the material contained herein include inorganic, nitrous, monoazo, disazo, carotenoid, triphenyl methane, triaryl methane, xanthene, quinoline, oxazine, azine, anthraquinone, indigoid, thionindigoid, quinacridone, phthalocyanine, botanical, natural colors that include: water-soluble components, such as those with the CI names: Acid Red 18, 26, 27, 33, 51, 52, 87, 88, 92, 94, 95, Acid Yellow 1, 3, 11, 23, 36, 40, 73, Edible Yellow 3, Edible Green 3, Edible Blue 2, Edible Red 1, 6, Acid Blue 5, 9, 74, Red Pigment 57-1, 53 (Na), Basic Violet 10, Red Solvent 49 , Acid Orange 7, 20, 24, Acid Green 1, 3, 5, 25, Green Solvent 7, Violet Acid 9, 43; Water-insoluble components, such as those having the CI names: Pigment Red 53 (Ba), 49 (Na), 49 (Ca), 49 (Ba), 49 (Sr), 57, Red Solvent 23, 24, 43 , 48, 72, 73, Orange Solvent 2, 7, Pigment Red 4, 24, 48, 63 (Ca) 3, 64, Red from Tub 1, Blue from Tub 1, 6, P1188 s? * $ ¡® & k * < .

Pigment Orange 1, 5, 13, Yellow Solvent 5, 6, 33, Pigment Yellow 1 and 12, Green Solvent 3, Violet Solvent 13, Solvent Blue 63, Pigment Blue 15, titanium dioxides, chlorophyllin copper complex, groceries, powder aluminum, bentonite, calcium carbonate, barium sulfate, bismuthine, calcium sulfate, carbon black, animal black, chromic acid, cobalt blue, gold, ferric oxides, hydrous ferric oxide, ferric ferrocyanide, magnesium carbonate, phosphate Manganous, silver and zinc oxides. Antimicrobial agents useful as a contained material include those which are useful as cosmetic biocides and anti-dandruff agents including: water-soluble components, such as pyroctone olamine, water-insoluble components, such as 3,4,4'-trichlorocarbanilide (triclosan) , triclocarban and zinc pyrithione. Chelating agents useful as contained material include: 2,2'-dipyridylamine; 1, 10-phenanthroline. { o-phenanthroline}; di-2-pyridyl ketone; 2, 3-bis (2-pyridyl) pyrazine; 2, 3-bis (2-pyridyl) -5,6-dihydropyrazine; 1,1'-carbonyldiimidazole; 2,4-bis (5,6-diphenyl-1,2,4-triazine-3-yl) pyridine; 2,4,6-tri (2-pyridyl) -1,3,5-triazine; 4,4'-dimethyl-2, 2 'dipyridyl; 2, 2'-biquinoline; di-2-pyridyl glyoxal. { 2, 2'-pyridyl}; 2- (2-pyridyl) benzimidazole; 2,2'- bipirazine; 3- (2-pyridyl) -5,6-diphenyl-1,2,4-triazine; 3. 4- P1188 phenyl-2-pyridyl) -5-phenyl-1,2,4-triazine; 3- (4-phenyl-2-pyridyl) -5,6-diphenyl-1,2,4-triazine; 2,3,5,6-tetrathra- (2'-pyridyl) -pyrazine; 2,6-pyridinedicarboxylic acid; 2,4,5-trihydroxypyrimidine; phenyl 2-pyridyl ketoxime; 3-amino-5,6-dimethyl-l, 2,4-triazine; 6-hydroxy-2-phenyl-3 (2H) -pyridazinone; 2, 4-fteridinadiol. { lumazina }; 2, 2'-dipyridyl and 2,3-dihydroxypyridine. The silicone compounds, humectants, additional conditioning agents, UV light absorbers, optical brighteners and herbal extracts useful for the material contained therein are the same as those exemplified in other portions of the specification. However, the components herein are retained primarily within visible breakable particles and practically do not dissolve in the mass of the present composition under normal shelf conditions. Visible and breakable particles commercially available and particularly useful herein are those having the trade names Unisphere and Unicerin, which can be obtained from Induchem AG (Switzerland). The Unisphere and Unicerin particles are made of microcrystalline cellulose, hydroxypropyl cellulose, lactose, vitamins, pigments and proteins. During use, the Unisphere and Unicerin particles can disintegrate with very little shear stress of the fingers of the hand P1188 practically without resistance and dissolve easily in the composition.

SILICONE COMPOSITE The compositions of the present invention may include a silicone compound. The silicone compounds useful herein include volatile, soluble or insoluble or nonvolatile, soluble or insoluble silicone conditioning agents. By solubles it is understood that the silicone conditioning agent is miscible with the carrier of the composition in order to be part of the same phase. Insoluble is understood to mean that the silicone forms a discontinuous or separate phase of the carrier, in order to form an emulsion or suspension of silicone droplets. The silicone compounds of the present invention can be made by the suitable method known in the art, such as emulsion polymerization. The silicone compounds can also be incorporated in the present invention in the form of an emulsion, which is formed by mechanical mixing, or during the synthesis step through emulsion polymerization, with or without the aid of a surfactant selected from the anionic surfactants, non-ionic surfactants, cationic surfactants and mixtures thereof. The silicone compounds that are used here P1188 will preferably have a viscosity of from about 1,000 to about 2,000,000 centistokes at 25 ° C, more preferably from about 10,000 to about 1,800,000 and still more preferably from about 100,000 to about 1,500,000. The viscosity can be measured by means of a glass capillary viscometer as indicated in the Dow Corning CTM0004 Test Method, July 20, 1970, which is incorporated herein by reference. The high molecular weight silicone compounds can be made by emulsion polymerization. Suitable silicone fluids include copolymers of polyether siloxane, polyalkylsiloxanes, polyarylsiloxanes, polyalkylaryl siloxanes and mixtures thereof. Other silicone compounds having hair conditioning properties may also be employed. The silicone compounds of the present invention are preferably used in levels by weight of the composition ranging from about 0.1% to about 60%, more preferably between about 0.1% and 40%. The silicone compounds herein also include polyalkyl or polyarylsiloxanes with the following structure (I) P1188 R 93 R 93, 93 Z8-Si -0- [-Si -0-] p-Si-Ze (I) R93 R93 R93 wherein R93 is alkyl or aryl, and p is an integer from about 7 to about 8,000. Z8 represents groups that block the ends of the silicone chains. The substituted alkyl or aryl groups on the siloxane chain (R93) or on the ends of the siloxane chains (Z8) can have any structure as long as the resulting silicone is in the fluid state at room temperature, is dispersible, is not irritating , toxic or harmful in any way when applied to hair, is compatible with other components of the composition, is chemically stable under normal use and storage conditions and is capable of being deposited on the hair to condition it. Suitable groups Z8 include hydroxy, methyl, methoxy, ethoxy, propoxy and aryloxy groups. The two R93 groups on the silicon atom may represent the same or different groups. Preferably, the two R93 groups represent the same group. Suitable R93 groups include methyl, ethyl, propyl, phenyl, methylphenyl and phenylmethyl. Preferred silicone polymers are polydimethylsiloxane, polydiethylsiloxane and polymethylphenylsiloxane. It preferred P1188 especially the polydimethylsiloxane which is also known as dimethicone. Polyalkylsiloxanes that can be used include, for example, polydimethylsiloxanes. These silicone products are available, for example, from General Electric Company in their Viscasil® and SF 96 series and from Dow Corning in their Dow Corning 200 series. Polyalkylaryl siloxane fluids can also be used and include, for example, polymethylphenylsiloxanes. These siloxanes are available, for example, from General Electric Company such as the SF 1075 Methyl Phenyl Fluid or from Dow Corning as the Cosmetic Grade Fluid 556. Also useful herein, to improve the shine characteristics of the hair, are the silicones with high degree of arylation, for example highly phenylated polyethylenesilicone having refractive indices of about 1.46 or higher, especially about 1.52 or higher. When these high refractive index silicones are used they should be mixed with a dispersing agent, for example a surfactant or a silicone resin, as described below to decrease the surface tension and improve the ability of the material to form films. The silicone compounds that can be used include, for example, a modified polydimethylsiloxane P1188 ^ ** ¡gtei ^^^^^^^^^^^^^^^^^^^^^^^ with polypropylene oxide , although ethylene oxide or mixtures of ethylene oxide and propylene oxide can also be used. The level of ethylene oxide and propylene oxide should be sufficiently low so as not to interfere with the dispersibility characteristics of the silicone. These materials are also known as dimethicone copolyols. Other silicone compounds include materials substituted with amino. Alkylamino-substituted silicone compounds include those represented by the following structure (II) wherein R94 is H, CH3 or OH, p1, p2, q1 and q2 are integers depending on the desired molecular weight, the average molecular weight is between about 5,000 and 10,000. This polymer is also known as "amodimethicone". Amino-substituted silicone fluids include those represented by formula (III). (R97) aG3-a-S? - (- OSiG2) P3 - (- OS? Gb (R97) 2-b) p4-0-SiG3-a (R97) a (III) P1188"kiA * -. $ & & amp; wherein G is selected from the group consisting of hydrogen, phenyl, OH, C? -C8 alkyl, and preferably methyl, a denotes 0 or an integer from 1 to 3 and is preferably equal to 0, b denotes 0 or 1 and preferably equal the sum p3 + p4 is a number from 1 to 2,000 and preferably from 50 to 150, p3 is able to denote a number from 0 to 1,999 and preferably from 49 to 149 and p4 is able to denote an integer from 1 to 2,000 and preferably from 1 to 10, R97 is a monovalent radical of the formula Cq3H2q3L where q3 is an integer from 2 to 8 and L is selected from the groups -N (R96) CH2-CH2-N (R96) 2 -N (R96) 2 -N (R9S) 3X '-N (R96) CH2-CH2-NR96H2X' wherein R96 is selected from the group consisting of hydrogen, phenyl, benzyl, a saturated hydrocarbon radical, preferably alkyl radical containing from 1 to 20 carbon atoms and X 'denotes a halide ion. An especially preferred amino-substituted siloxane corresponding to formula (II) is the polymer known as "ethylsilyllamodimethicone" wherein R94 is CH3. Other amino-substituted siloxanes that can be used are represented by the formula (V): wherein R98 denotes a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, preferably an alkyl or alkenyl radical such as for example methyl; R99 denotes a hydrocarbon radical, preferably C? -C? 8 alkyl radical or an alkyleneoxy radical of C? -C? 8 and more preferably C? -C8; Q "is a halide ion, preferably chloride, p5 denotes an average statistical value of 2 to 20, preferably 2 to 8, p5 denotes an average statistical value of 20 to 200 and preferably 20 to 50. A preferred polymer of this class is available from Union Carbide under the name "UCAR SILICONE ALE 56." References disclosing suitable non-volatile dispersed silicone compounds include U.S. Patent No. 2,826,551 to Geen, U.S. Pat. 3,964,500 from Drakoff, issued June 22, 1976; United States Patent No. 4,364,837 from Pader and British Patent No. 849,433 from "The Silicone Compounds" disuted by Petrarch Systems, Inc. of 1984; P1188 > ~ ¿^,? &. a -i-a fairly extensive but not exhaustive list of suitable silicone compounds. Another non-volatile dispersed silicone that can be especially useful is silicone rubber. The term "silicone gum", as used herein, refers to a polyorganosiloxane material having a viscosity at 25 ° C greater than or equal to 1,000,000 centistokes. It is recognized that the silicone gums described herein may also have some overlap with the aforementioned silicone compounds. This overlap is not intended to be a limitation of any of these materials. Silicone gums are described by Petrarch and others including U.S. Patent No. 4,152,416 by Spitzer et al., Issued May 1, 1979 and Noli, Walter, Chemistry and Technology of Silicones, New York; Academic Press 1968. Silicone gums are also described in the product data sheets of General Elec Silicone Rubber Product Data Sheets SE 30, SE 33, SE 54 and SE 76. "Silicone gums" will typically have a mass molecular weight. greater than about 200,000, generally between about 200,000 and about 1,000,000. Specific examples include polydimethylsiloxane, copolymer of poly (dimethylsiloxane methylvinylsiloxane), copolymer of poly (dimethylsiloxane diphenylsiloxane methylvinylsiloxane) and mixtures of the P1188 same. Also useful are silicone resins, which are highly cross-linked polymeric siloxane systems. Crosslinking is introduced through the incorporation of functional and tetrafunctional silanes with monofunctional or difunctional silanes, or both, during the manufacture of the silicone resin. As is well understood in this field, the degree of crosslinking that is required in order to result in a silicone resin will vary according to the specific silane entities that are incorporated in the silicone resin. In general, silicone materials having a sufficient level of trifunctional and tetrafunctional siloxane monomer units and, therefore, a sufficient level of crosslinking, so that they are dried to form a rigid or hard film, are considered as resins of silicone. The ratio of oxygen atoms to silicon atoms is indicative of the level of crosslinking in a particular silicone material. The silicone materials having at least about 1.1 oxygen atoms for each silicon atom in general will be silicone resins for the present. Preferably, the ratio between oxygen atoms: silicon is at least about 1.2: 1.0. The silanes used in the manufacture of silicone resins include monomethyl-, P1188 dimethyl-, trimethyl-, monophenyl-, diphenyl-, methylphenyl-, monovinyl- and methylvinyl-chlorosilanes and tetrachlorosilane, where the methyl-substituted silanes are the most commonly used. Preferred resins are offered by General Electric as GE SS4230 and SS4267. Commercially available silicone resins will generally be supplied in a form dissolved in a non-volatile or low-density volatile silicone fluid. The silicone resins used herein should be supplied and incorporated into the compositions herein in this dissolved form, as will be readily apparent to those skilled in the art. Without being limited by theory, it is considered that silicone resins can improve the deposition of other silicones in the hair and can improve the lustrousness of hair with high volumes of refractive index. Other useful silicone resins are silicone resin powders as the materials to which the CTFA designation of polymethylsilsequixan is provided, which is commercially available as Tospearl® from Toshiba Silicones. The method of manufacturing these silicone compounds can be found in Encyclopedia of Polymer Science and Engineering, Volume 15, Second Edition, page 204-308 of John Wiley & Sons, Inc., 1989.

P1188 The silicone materials and silicone resins can be conveniently identified according to an abbreviated nomenclature system well known to those skilled in the art, such as the "MDTQ" nomenclature. In this system, the silicone is described according to the presence of several monomeric siloxane units which form the silicone. In summary, the symbol M denotes the monofunctional unit (CH3) 3SiO0.s; D denotes the difunctional unit (CH3) 2SiO; T denotes the trifunctional unit (CH3) SÍO1.5; and Q denotes the quadri or tetrafunctional unit Si02. The prime signs in unit symbols for example, M ', D', T 'and Q' denote substituents other than methyl and must be specifically defined each time they are present. Typical alternating substituents include groups such as vinyl, phenyl, amino, hydroxyl, etc. The molar proportions of the different units, either in terms of subscripts in the symbols that indicate the total number of each type of units in the silicone or an average thereof, or as specifically indicated proportions in combination with the molecular weight, complete the description of the silicone material with the MDTQ system. The high relative molar amounts of T, Q, T 'and / or Q' relative to D, D 'M and / or M' in a silicone resin are indicative of high levels of crosslinking. However, as discussed here, the general level of P1188 crosslinking can also be indicated by the oxygen to silicon ratio. The silicone resins that are used here and are preferred are MQ, MT, MTQ, MQ and MDTQ resins. Therefore, the preferred silicone substituent is methyl. MQ resins are especially preferred wherein the M: Q ratio is between about 0.5: 1.0 and about 1.5: 1.0 and the average molecular weight of the resin is from about 1000 to about 10,000. Particularly suitable silicone compounds herein are non-volatile silicone oils having a molecular weight of between about 200,000 and 600,000, such as dimethicone and dimethiconol. These silicone compounds can be incorporated into the composition as silicone oils, the silicone oils are volatile or non-volatile. The silicone compounds commercially available and useful herein include dimethicone under the tradename DC345 of Dow Corning Corporation, dimethicone gum solutions under the trade names SE 30, SE 33, SE 54 and SE 76 of General Electric, dimethiconol with the commercial names DCQ2-1403 YDCQ2-1401 available from Dow Corning Corporation and the polymerized dimethiconol emulsion available from Toshiba Silicone, as described in application GB 2,303,857.

P1188 «• > * ^ B ^ ^ f ^ AQUEOUS CARRIER The compositions of the present invention comprise an aqueous carrier, which is present as an external phase of the composition. The level and species of the carrier are selected according to the compatibility with other components and other desired characteristics of the product. Carriers useful in the present invention include water and aqueous solutions of lower alkyl alcohols. The lower alkyl alcohols useful herein are monohydric alcohols having from 1 to 6 carbon atoms, more preferably, ethanol and isopropanol. Preferably, the aqueous carrier is practically water. Deionized water is used more preferably. Water can also be used from natural sources that include mineral cations, depending on the characteristics desired for the product. In general, the compositions of the present invention comprise from about 20% to 90%, preferably from about 40% to 98% and most preferably from about 50% to 98% water. The pH of the present composition is preferably from about 4 to 9, more preferably from about 4.5 to 7.5. To achieve pH P1188 , Faith ... • "&"., - Desirable, buffers and other pH adjusting agents may be included. The compositions of the present invention are transparent. What is understood by tansparentes is that a black substance that has the size of a square of lcm X lcm can be detected with the naked eye through a thickness of 1 cm of the present composition.

AGENT FOR GIVING VISCOSITY The compositions of the present invention may further comprise a viscosity imparting agent, which is selected from the group consisting of: anionic polymers, nonionic polymers and mixtures thereof. In a preferred embodiment, a viscosity imparting agent that is used in this invention will form a gel with a certain viscosity. In that preferred embodiment, the agent imparting the viscosity is selected so that the composition of this invention has a viscosity of between about 1,000 cps at 100,000 cps, preferably between about 2,000 cps at 50,000 cps. At present, the viscosity can be adequately measured with a Brookfield RVT viscometer at 20 rpm at 20 ° C, with spindle # 4, 5, 6 or 7, depending on the viscosity and characteristics of the composition. The agents for imparting viscosity of P1188 preference is used in levels by weight of the composition that are between about 0.001% and 5%, more preferably between about 0.05% and 3%. The viscosity imparting agents that are used in the present invention are anionic polymers such as a carboxylic acid / carboxylate copolymer. The carboxylic acid / carboxylate copolymers herein are hydrophobically modified crosslinked copolymers of carboxylic acid and alkyl carboxylate and have amphiphilic properties. These carboxylic acid / carboxylate copolymers are obtained by copolymerization of: 1) a carboxylic acid monomer, such as acrylic acid, methacrylic acid, maleic acid, maleic anhydride, itaconic acid, fumaric acid, crotonic acid or a-chloroacrylic acid, 2) a carboxylic ester having an alkyl chain of between about 1 and 30 carbons and, Preference 3) a crosslinking agent of the following formula: 52 - Y - • Y '• Y - C -R 52 II C H2 C H2 wherein R52 is a hydrogen or an alkyl group having from about 1 to 30 carbons; Y1 is, independently, oxygen, CH20, COO, OCO, P1188 wherein R53 is a hydrogen or an alkyl group having from about 1 to 30 carbons and Y2 is selected from (CH2) m », (CH2CH20) m", or (CH2CH2CH20) m .. where m "is an integer approximately between 1 and 30. The carboxylic acid / carboxylate copolymers herein are considered to provide appropriate viscosity and rheological properties to the composition and emulsify and stabilize certain conditioning agents in the composition. It is further considered that, due to the alkyl group contained in the copolymer, the carboxylic acid / carboxylate copolymers do not undesirably become sticky to the composition. Suitable carboxylic acid / carboxylate copolymers herein are copolymers of acrylic acid / alkyl acrylate having the following formula: P1188 wherein R51 is, independently, a hydrogen or an alkyl of 1 to 30 carbons, wherein at least one of R51 is a hydrogen, R52 is as defined above, n, n ', m and m' are integers, those n + n '+ m + m' is approximately between 40 and 100, n "is an integer of approximately between 1 and 30 and i is defined so that the copolymer has a molecular weight of approximately between 500,000 and 3,000,000. carboxylic acid / carboxylate copolymers commercially available and useful herein include: Crosslinked polymer with name CTFA acrylates / C10-30 alkyl acrylate having the tradenames Pemulene TR-1, Pemulene TR-2, Carbopol 1342, Carbopol 1382 and Carbopol ETD 2020, all available from BF Goodrich Company Viscosity imparting agents useful herein include other anionic polymers and nonionic polymers Vinyl polymers, such as acrylic acid polymers, are useful herein. lico crosslinked with the CTFA name Carbomer, cellulose derivatives and modified cellulose polymers such as methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose, nitro cellulose, sodium cellulose sulfate, sodium carboxymethyl cellulose, crystalline cellulose, cellulose powder, polyvinylpyrrolidone, -, pilivinyl alcohol, guar gum, hydroxypropyl guar gum, xanthan gum, gum arabic, tragacanth, galactan, locust bean gum, guar gum, cocoa gum, carrageenan, pectin, agar, quince seed (Cydonia oblonga Mili), starch ( of rice, corn, potato and wheat), algae colloids (algae extract), microbiological polymers, such as dextran, succinoglucan, polleran, starch-based polymers, such as carboxymethyl starch, methylhydroxypropyl starch, acid-based polymers alginic, such as sodium alginate, propylene glycol esters of alginic acid, acrylate polymers, such as sodium polyacrylate, polyethylacrylate, polyacrylamide, polyethylene imine and water-soluble inorganic material such as bentonite, magnesium aluminum silicate, laponite, hectonite and anhydrous silicic acid. Polyalkylene glycols having a molecular weight greater than about 1000 are useful herein. Those with the following general formula are useful: wherein R95 is selected from the group consisting of H, methyl and mixtures thereof. When R95 is H, these materials are polymers of ethylene oxide, which also P1188 are known as polyethylene oxides, polyoxyethylenes and polyethylene glycols. When R95 is methyl, these materials are polymers of propylene oxide, which are also known as polypropylene oxides, polyoxypropylene and polypropylene glycols. When R95 is methyl, it will be understood that there may also be several positional isomers of the resulting polymers. In the previous structure, x3 has an average value of approximately between 1,500 and 25,000, preferably from about 2,500 to 20,000 and more preferably from about 3,500 to 15,000. Other useful polymers include polypropylene glycols and mixed polyethylene-polypropylene glycols or polyoxyethylene-polyoxypropylene copolymer polymers. The polyethylene glycol polymers useful herein are PEG-2M, wherein R95 equals H and x3 has an average value of about 2,000 (PEG-2M is also known as Polyox WSR® N-10, which can be obtained from Union Carbide and as PEG-2,000); PEG-5M, where R95 equals H and x3 has an average value of approximately 5,000 (also known as Polyox WSR® N-35, and Polyox WSR® N-80, both can be obtained from Union Carbide and as PEG- 5, 000 and polyethylene Glycol 300,000); PEG-7M, where R95 is equal to H and x3 has an average value of about 7,000 (PEG-7M is also known as Polyox WSR® N-750, and can P1188 obtained from Union Carbide); PEG-9M, where R95 is equal to H and x3 has an average value of about 9,000 (PEG-9M is also known as Polyox WSR® N-3333, can be obtained from Union Carbide) and PEG-14M, where R95 is equal to H and x3 has an average value of approximately 14,000 (PEG-14M is also known as Polyox WSR® N-3000, can be obtained from Union Carbide). Viscosity imparting agents commercially available and useful herein include carbomers (Carbomers) under the trade names Carbopol 934, Carbopol 940, Carbopol 950, Carbopol 980 and Carbopol 981, all available from BF Goodrich Company, acrylate copolymer / methacrylate esteareth-20 under the tradename ACRYSOL 22, can be obtained from Rohm and Hass, nonoxynil hydroxyethylcellulose under the tradename AMERCELL POLIMER HM-1500 can be obtained from Amerchol, methylcellulose under the tradename BENECEL, hydroxyethyl cellulose under the tradename NATROSOL, hydroxypropyl cellulose with the trade name KLUCEL, cetyl hydroxyethyl cellulose with the trade name POLYSURF 67, all supplied by Herculus, polymers based on ethylene oxide and / or propylene oxide under the trade names CARBOWAX PEG, POLYOX WASR and UCON FLUIDS, all supplied by Amerchol. Neutralization agents can be included for P1188 neutralizes anionic polymers of the present. Non-limiting examples of these neutralizing agents include sodium hydroxide, potassium hydroxide, ammonium hydroxide, monoethanolamine, diethanolamine, triethanolamine, diisopropanolamine, aminomethylpropanol, tromethamine, tetrahydroxypropyl ethylenediamine and mixtures thereof MOISTURIZING The compositions of the present invention may further comprise a humectant. The humectants herein are selected from the group consisting of polyhydric alcohols, water-soluble alkoxylated nonionic polymers and mixtures thereof. The humectants herein are preferably used in weight levels of the composition of between about 0.1% and 20%, more preferably between about 0.5% and 5%. Polyhydric alcohols useful herein include: glycerin, sorbitol, propylene glycol, butylene glycol, hexylene glycol, ethoxylated glucose, 1,2-hexane diol, hexanetriol, dipropylene glycol, erythritol, trehalose, diglycerin, xylitol, maltitol, maltose, glucose. , fructose, sodium chondroitin sulfate, sodium hyaluronate, sodium adenosine phosphate, sodium lactate, pyrrolidone carbonate, glucosamine, cyclodextrin and mixtures thereof.

P1188 The water-soluble alkoxylated nonionic polymers useful herein include polyethylene glycols and polypropylene glycols having a molecular weight of up to about 1000, such as those having CTFA names PEG-200, PEG-400, PEG- 600, PEG-1000 and mixtures thereof. Available commercially available humectants include: glycerin with the trade names STAR and SUPEROL available from The Procter & Gamble Company, CRODEROL GA7000, available from Croda Universal Ltd., PRECERIN series, available from Unichema and the same trademark as the chemical name available from NOF; propylene glycol with trade name LEXOL PG-865/855, available from Inolex, 1, 2 -PROPYLENE GLYCOL USP, available from BASF; sorbitol with the trade names LIPONIC series, available from Lipo, SORBO, ALEX, A-625 and A-641, available from ICI and UNISWEET 70, UNISWEET CONC, available from UPI; dipropylene glycol with the same trade name available from BASF; diglycerin under the trade name DIGLYCEROL, available from Solvay GmbH, xylitol with the same trade name available from Kyowa and Eizai; maltitol under the trade name MALBIT, available from Hayashibara, sodium chondroitin sulphate with the same commercial name, available from Freeman and Bioiberica and under the trade name ATOMERGIC SODIUM CHONDROITIN SULFATE, available P1188 from Atomergic Chemetals; sodium hyaluronate with the trade names ACTIMOIST, available from Active Organics, the AVIAN SODIUM HYALURONATE series, available from Intergen, HYALURONIC ACID Na available from Ichimaru Pharcos; sodium adenosine phosphate with the same commercial available from Asahikasei, Kyowa and Daiichi Seiyaku; sodium lactate with the same trade name available from Merck, Wako and Showa Kako, cyclodextrin under the trade names CAVITRON, available from American Maize, the RHODOCAP series, available from Rhone-Poulenc, and DEXPEARL, available from Tomen; and polyethylene glycols with the trade name CARBOWAX series, available from Union Carbide.

OPTICAL POLISHER The compositions of the present invention may further comprise an optical brightener. Optical brighteners are compounds that absorb ultraviolet light and re-emit, that is, reemit, energy in the form of visible light. Specifically, the optical brighteners useful herein have an absorption, preferably a main absorption peak, between a wavelength of about lnm to about 420nm and an emission, preferably, a main emission peak, between a wavelength of about 360 nm and about 830 nm; where the P1188 »? *? - main absorption peak has a wavelength shorter than the main emission peak. More preferably, the optical brighteners herein have a main absorption peak with a wavelength between about 200 nm and about 420 nm and a main emission peak with a wavelength between about 400 nm and about 780 nm. The optical brighteners may or may not have minor absorption peaks in the visible range with a wavelength of between approximately 360 nm and approximately 830 nm. The optical brighteners can be described by other names, in this case and in other industries, such as fluorescent whitening agents, fluorescent brighteners and fluorescent dyes. When applied to hair by means of suitable vehicles, the optical brighteners of the present provide hair benefits in three areas. In the first, the optical brighteners of the present alter the hair color by emitting light in the visible range. In the second area, the optical brighteners of the present improve the shine of the hair by emitting light in the visible range. In the third, the optical brighteners of the present protect from ultraviolet light to the hair by absorbing ultraviolet light. Optical brighteners, in general, P1188 they are based on structures of aromatic and heteroaromatic systems that provide these unique characteristics. The optical brighteners useful herein may be soluble or insoluble in water and may be classified according to their base structure, according to the following. Preferred optical brighteners herein include polystyrylsilbenes, triazinestilbenes, hydrocoumarins, aminocoumarins, triazoles, pyrazolines, oxazoles, pyrenes, porphyrins and imidazoles. Preferably, the optical brighteners of the present are included in the composition at a weight level of from about 0.001% to about 10%.

Polystyrylsilbenes Polystyrylsilbenes are a class of compounds that have two or more of the following base structure: The polystyrylsilbenes useful in the present invention include those having the formulas (1), (2) and (3): P1188 wherein R101 is H, OH, S03M, COOM, OSO3M, OPO (OH) OM, wherein M is H, Na, K, Ca, Mg, ammonium, mono-, di-, tri- or tetra-alkyl-C C3-ammonium, mono-, di- or tri- hydroxyalkyl-C? -C30-ammonium or ammonium which is di- or tri-substituted by a mixture of C? -C30 alkyl groups and C? -C30 hydroxyalkyl groups or S02N (C?-C30 alkyl) 2, O- (C?-C30 alkyl), CN, Cl, C00 (C!-C30 alkyl), CON (C?-C30 alkyl) 2, or O (CH 2) 3N + ( CH2) 3X ", where X" is an anion of chloride, bromide, iodide, formate, acetate, propionate, glucoate, lactate, acrylate, methane phosphonate, phosphite, dimethyl or diethyl phosphite; CN or alkyl of 1 to 30 carbons, R102 and R103 are independently H, S03M, wherein M is as previously defined; and x is 0 or 1; wherein the compound has a trans-coplanar orientation or a cis-coplanar orientation; preferably x is 1, R101 is S03Na and R102 and R103 are H; wherein the compound has a trans-coplanar orientation; wherein R104 and R, 1-1 ^ 053, independently, are CN, COO (C -C30 alkyl), CONH alkyl C? -C4 or CON (C? -C4 alkyl) 2, P1188 wherein the compound has a trans-coplanar or cis-coplanar orientation, preferably R104 and R105 is 2-cyano, wherein the compound has a trans-coplanar orientation; Y wherein each R106, independently, is H or alkyl of 1 to 30 carbon atoms and wherein the compound has a trans-coplanar or cis-coplanar orientation, preferably a trans-coplanar orientation. Suitable polystyrylsilbenes include disodium-1,4'-bis (2-sulphotrisyl) bisphenyl (CI Fluorescent Brightener 351) under the tradename Tinopal CBS-X obtainable from Ciba Specialty Chemicals, 1,4-bis (2-cyano-styryl) benzene (CI Fluorescent Brightener 199) with trade name Ultraphor RN available from BASF.

Triazinestilbenes Triazinestilbenes are a class of compounds that have both triazine and stilbene structures in the same molecule. Triazinestilbenes useful in the present invention include those having formulas (4): P1188 wherein R107 and R108 are, independently, phenylamino, mono or disulfonated phenialamino, morpholino, N (CH2CH2OH) 2, N (CH3) (CH2CH2OH), NH2, N (alkyl? C? -C4) 2, OCH3, Cl, NH- (CH2) 1-4S03H or NH- (CH2) 1-4OH; An "is a carboxylate, sulfate, sulfonate or phosphate anion and M is as previously defined, wherein the compound has a trans-coplanar orientation or a cis-coplanar orientation, preferably R107 is 2,5-disulfophenylamino and each R108 is morpholino, or each R107 is 2, 5-disulfophenylamino and each R108 is N (C2H5) 2, or each R107 is 3-sulphophenyl and each R108 is NH (CH2CH2OH) or N (CH2CH2OH) 2, or each R107 is 4 sulphophenyl and each R108 is N (CH2CH2OH) 2, and in each case, the sulfo group is S03M, where M is sodium, wherein the compound has a trans-coplanar orientation.The suitable triazinostilbenes include 4,4'-acid bis- [(4-anilino-6-bis (2-hydroxyethyl) amino-1, 3,5-triazin-2-yl) amino] stilbene-2, 2'-disulfonic with trade name Tinopal UNPA-GX from Ciba Specialty Chemicals: 4,4 '-bis- [(4-anilino-6-morpholine-1,3,5-triazin-2-yl) amino] stilbene-2,2' -disodium sulfonate with trade name Tinopal AMS-GX from Ciba Specialty Chemicals; P1188 - * --- > - "A--. ..., ^ .. ¿^.,., ^ ¿L * ..... ...._ &., Afa ^ .... Z .. 4,4 '-bis- [(4-anilino-6- (2-hydroxyethyl) methyl amino- 1, 3,5-triazin-2-yl) amino] stilbene-2,2' -disodium sulfonate with trade name Tinopal 5BM-GX from Ciba Specialty Chemicals; 4 '4-bis- [(4,6-dianilino-1,3,5-triazin-2-yl) amino] stilbene-2,2'-disodium sulfonate; 4, 4 '-bis- [(4-anilino-6-methylamino-l, 3,5-triazin-2-yl) amino] stilbene-2, 2'-disodium; 4,4'-bis [(4-anilino-6-ethylamino-1,3,5-triazin-2-yl) amino] stilbene-2,2 '-disodium sulfonate and 4,4'-bis (4) acid phenyl-1,3,2-triazol-2-yl) stilbene-2,2'-disulfonic acid.

Hydroxycoumarins Hydroxycoumarins are a class of compounds that have the following basic structure and have at least one hydroxy portion: The hydroxycoumarins useful in the present invention include those having formulas (5): wherein R201 is H, OH, Cl, CH3, CH2COOH, CH2S03H, CH2OS03H or CH20P0 (0H) 0H; R202 is H, phenyl, COO-C? -C30 alkyl, glucose P1188 «T? IaüiÉuü áÉ tiH. or a group of the formula (6) and R203 is OH or 0-C 1 -C 30 alkyl and R 20 4 is OH or O-C 1 -C 30 alkyl, glucoside or a group of the formula (7): wherein R205 and R206 are independently, phenylamino, mono or disulfonated phenylamino, morpholino, N (CH CH2OH) 2, N (CH3) (CH2CH2OH), NH2, N (C? -C30 alkyl) 2, OCH3, Cl, NH- (CH2)? - 4S03H or NH- (CH2)? - 4OH. Suitable hydroxycoumarins include 6,7-dihydroxycoumarin available from Wako Chemicals, 4-methyl-7-hydroxycoumarin available from Wako Chemicals, 4-methyl-6,7-dihydroxycoumarin available from Wako Chemicals, esculin available from Wako Chemicals. and umbelliferone (4-hydroxycoumarin) available from Wako Chemicals.

Aminocumarins Aminocumarins are a class of compounds that have the basic structure of coumarin and that have at least one amino moiety.

P1188 Aminocumarins useful in the present invention include those having the formulas (8): wherein R207 is H, Cl, CH3, CH2C00H, CH2S03H, CH2OS03H or CH20P0 (0H) 0H, R208 IS H, phenyl or COO-C 1 -C30 alkyl, and R209 and R210 are independently H, NH2, N (C-alkyl) ? -C30) 2, NH-C 1-30 alkyl or NHCO-C? -C30 alkyl. Suitable aminocoumarins include 4-methyl-7,7'-diethylamino coumarin with trade name Calcofluor-RWP from BASF, 4-methyl-7,7'-dimethylamino coumarin with trade name Calcofluor-LD from BASF.

Triazoles Triazoles are a class of compounds that have the following base structure: - z The triazoles useful in the present invention include those having formulas (9) to (12) and (15) to (20): P1188 wherein R301 and R302 independently are H, C? -C30 alkyl, phenyl or monosulfonated phenyl; An- and M are as previously defined, wherein the compound has a trans-coplanar or cis-coplanar orientation, preferably R301 is phenyl, R302 is H and M is sodium; wherein the compound has a trans-coplanar orientation; wherein R303 is H or Cl; R304 is S03M, S02N (Cl-C30 alkyl) 2, S020-phenyl or CN; R305 is H or S03M, COOM, OS03M or OPO (OH) OM; and M is as previously defined, wherein the compound has a trans-coplanar orientation or a cis-coplanar orientation; preferably, R303 and R304 are H and R304 is S03M, wherein M is Na; wherein the compound has a trans-coplanar orientation; P1188 • wherein each Ht R306 and R312 independently represent H, a sulfonic acid group or the salts, esters or amides thereof, a carboxylic acid group or the salts, esters or amides thereof, a cyano group, a halogen atom , an unsubstituted or substituted alkylsulfonyl, arylsulfonyl, alkyl, alkoxy, aralkyl, aryl, aryloxy, aralkoxy or cycloalkyl radical, a substituted or unsubstituted heterocyclic ring containing from two to three nitrogen atoms or a nitrogen atom oxygen and 1 or 2 nitrogen atoms, or together with R307 and R313 represents a methylenedioxy, ethylenedioxy, methyleneoxymethyleneoxy, trimethylene, tetramethylene, propenylene, butenylene or butadienylene radical, each of R307 and R313 independently represents H, a sulfonic acid group or salts, esters or amides thereof, a carboxylic acid group or the salts, esters or amides thereof, a cyano group, a halogen atom an alkyl or alkoxy substituted radical gone or not replaced, or together with R 306 and R312 represent a methylenedioxy, ethylenedioxy, methyleneoxymethyleneoxy, trimethylene, tetramethylene, propenylene, butenylene or butadienylene radical; each of R308 and R314 independently represents H, a halogen atom or a substituted or unsubstituted alkyl radical, each of R309 and R311 independently represents H, a halogen atom, a cyano group, a sulfonic acid group or the P1188 .j & & J > L * A ** salts esters or amides thereof, or a carboxylic acid group or the salts, esters or amides thereof, and R310 independently represents H, a halogen atom, a cyano group, a sulfonic acid group or the salts, alkyl radicals, preferably hydroxy, alkoxy of 1 to 30 carbon atoms, cyano, halogen, carboxy, sulfonic acid groups, carbalkoxy having from 1 to 30 carbon atoms in the alkoxy, phenyl or phenoxy entity; the alkoxy radicals may be substituted by hydroxy, alkoxy of 1 to 30 carbon atoms, cyano, halogen, carboxy, carbalkoxy having from 1 to 30 carbon atoms in the alkoxy, phenyl or phenoxy moiety; the phenyl, phenylalkyl or phenoxy radicals may be substituted by halogen, cyano, carboxy, carbalkoxy having 1 to 30 carbon atoms in the alkoxy, sulfo or alkyl or alkoxy portion, each of from 1 to 30 carbon atoms, wherein the compound has a trans-coplanar or cis-coplanar orientation, preferably cycloalkyl radicals are cyclohexyl or cyclopentyl radicals which can be substituted by alkyl of 1 to 30 carbon atoms, the possible 5-membered heterocyclic rings are v-triazole, oxazole or 1,3,4-oxadiazole, which can be containing as radical substituents alkyl of 1 to 4 carbon atoms, halogen, phenyl, carboxy, carbalkoxy having 1 to 30 carbon atoms in the alkoxy entity, P1188 cyano, benzyl, alkoxy of 1 to 30 carbon atoms, phenoxy or sulfo, while two adjacent substituents of the triazole and oxazole radicals together can form a fused, substituted or unsubstituted benzene nucleus, wherein the compound has an orientation trans-coplanar; wherein Q1 denotes one of the ring systems (13) or (14); wherein R317 denotes H, alkyl of 1 to 30 carbon atoms, cyclohexyl, phenylalkyl of 1 to 30 carbon atoms in the alkyl, phenyl, alkoxy of 1 to 30 carbon atoms or Cl, or together with R318 denotes alkylene with 3 to 30 carbon atoms, R318 denotes H or alkyl with 1 to 30 carbon atoms or together with R317 denotes alkylene with 3 to 30 carbon atoms, R319 denotes H or methyl, R320 denotes H, alkyl with 1 to 30 carbon atoms. carbon, phenyl, alkoxy with 1 P1188 at 30 carbon atoms or Cl, or together with R321 denotes a fused benzene ring; R321 denotes H or Cl or together with R320 denotes a fused benzene ring; R315 denotes H, alkyl with 1 to 30 carbon atoms, alkoxy with 1 to 30 carbon atoms or Cl, R31S denotes H or Cl, Q2 denotes H, Cl alkyl of 1 to 30 carbon atoms and phenyl and Q3 denotes Cl; wherein the compound has a trans-coplanar or cis-coplanar orientation, preferably a trans-coplanar orientation. wherein R322 denotes H, Cl, methyl, phenyl, benzyl, cyclohexyl or methoxy; R323 denotes H or methyl and Z denotes O or S, wherein the compound has a trans-coplanar or cis-coplanar orientation, preferably a trans-coplanar orientation; Y P1188 wherein R324 denotes H, Cl, alkyl of 1 to 30 carbon atoms, phenylalkyl with 1 to 30 carbon atoms, phenyl or alkoxy with 1 to 30 carbon atoms or R324 together with R325 denotes a fused benzene radical, R325 denotes H or methyl or R325 together with R324 denotes a fused benzene radical, R326 denotes H, alkyl of 1 to 30 carbon atoms, alkoxy of 1 to 30 carbon atoms, Cl, carbalkoxy of 1 to 30 carbon atoms or alkylsulfonyl from 1 to 30 carbon atoms and R327 denotes H, Cl, methyl or methoxy, wherein the compound has a trans-coplanar or cis-coplanar orientation, preferably a trans-coplanar orientation. Suitable triazoles include 2- (4-styryl-3-sulfophenyl) -2H-naphtho [1,2-d] triazole (C.I.

Fluorescent 46) with trade name Tinopal RBS P1188 available from Ciba Specialty Chemicals.

Pyrazolinas Pirazolinas are a class of compounds that have the following basic structure: -o La-s pyrazolines useful in the present invention include those having formulas (21) to (23): wherein R401 is H, Cl or N (C?-C30 alkyl) 2, R402 is H, Cl, S03M, S02NH2, S02NH (C?-C30 alkyl), COO-C?-C30 alkyl, S02-C alquilo-alkyl ? -C30, S02NH (CH2)! _4N + (CH3) 3 or S02NH (CH2)? _4N + H (C-C30-alkyl) 2 An ", R403 and R404 are the same or different and each is H, phenyl or alkyl C? -C30 and R405 is H or Cl, and An "and M are as previously defined, preferably, R401 is Cl, R402 is S02CH2N + H (C-C4-alkyl) 2 An", where An "is phosphite and R403, R404 and R405 are each H, and formulas (22) and (23) are shown below.

P1188 Suitable pyrazolines include l- [4- (2-sulfoethylsulfonyl) phenyl] -3- (4-chlorophenyl) -2-pyrazoline (CI fluorescent brightener 121) under the tradename Blankophor DCB from Bayer, 1- [4- ( 2-sulfoethylsulfonyl) phenyl] -3- (4-chlorophenyl) -2-pyrazoline, 1- [4- (2-sulfoethylsulfonyl) phenyl] -3- (3,4-chloro-6-methylphenyl) -2-pyrazoline, l- < 4- . { N-3-N, N, N-trimethylammonium) propyl] -amidosulfonyl} phenyl > 3- (4-chlorophenyl) 2-pyrazoline and l- < 4- . { 2- [1-Methyl-2- (N, N-dimethylamino) ethoxy] ethylsulfonyl} phenyl > 3- (4-chlorophenyl) 2-pyrazoline.

Oxazoles Oxazoles are a class of compounds that have the following basic structure: Oxazoles useful in the present invention include those of formulas (24), (25), (26) and (27): P1188 wherein R501 and R502 are, independently, H, Cl, Cx-C3o alkyl or S02-C0-C30 alkyl, wherein the compound has a trans-coplanar or cis-coplanar orientation, preferably R 501 is 4-CH 3 and R is 2-CH 3, wherein the compound has a trans-coplanar orientation; wherein R503 is, independently, H, C (CH3) 3, C (CH3) 2-phenyl, C-C30 alkyl or COO-C- C30 alkyl, preferably H and Q4 is -CH = CH-; -CH = CH- / V_ CH = CH- // V preferably or one group R503 in each ring is 2-methyl and the other R503 is H and Q4 is -CH = CH, or one group R503 in each ring is 2-C (CH3) 3 and the other R503 is H; wherein the compound has a trans-coplanar or cis-coplanar orientation, preferably P1188 a trans-coplanar orientation; in oC? -C30 or phenyl; R505 and R506 are the atoms required to form a fused benzene ring or R506 and R508 are, independently, H or C? -C30 alkyl; and R507 is H, C? -C30 alkyl or phenyl; wherein the compound has a trans-planar or cis-coplanar orientation, preferably R504 is a 4-phenyl group and each of R505 to R508 is H, wherein the compound has a trans-coplanar orientation; Y wherein R509 denotes H, Cl, alkyl of 1 to 30 carbon atoms, cyclohexyl, phenylalkyl of 1 to 3 carbon atoms in the alkyl, phenyl or alkoxy portion with 1 to 30 carbon atoms, R510 denotes H or alkyl with 1 at 30 carbon atoms and Q5 denotes a radical; wherein R, 511 represents H, alkyl of 1 to 30 carbon atoms P1188 carbon, alkoxy of 1 to 30 carbon atoms, Cl, carbalkoxy of 1 to 30 carbon atoms, unsubstituted sulfamoyl or sulfamoyl which is monosubstituted or disubstituted with alkyl or hydroxyalkyl of 1 to 30 carbon atoms or represents alkylsulfonyl of 1 to 30 carbon atoms, wherein the compound has a trans-coplanar or cis-coplanar orientation, preferably a trans-coplanar orientation. Suitable oxazoles include 4,4'-bis (5-methylbenzoxazol-2-yl) stilbene and 2- (4-methoxycarbonylstyryl) benzoxazole.

Pyrenes Pyrenes useful in the present invention include those having the formulas (28) and (29): wherein each R601 is independently C17-C30 alkoxy, preferably methoxy; Y P1188 wherein each R602 is, independently, is H, OH or S03M, wherein M is as previously defined, sulfonated or aniline phenylamino. Suitable pyrenes include 2,4-dimethoxy-6- (1'-pyrenyl) -1,3,5-triazine (C.I.

Fluorescent 179) under the tradename Fluolite XMF, 8-hydroxy-l, 3,6-pyrnethrisulfonic acid (Green D &C No. 8)) and 3-hydroxy-5,8,1-trisulfanyl pyrene.

Porphyrins The porphyrins useful in the present invention include those having the formulas (30), (31) and (32); P1188 wherein R701 is CH3 or CHO; R702 is H or COO-C 1 -C 30 alkyl and R 703 is H or an alkyl group having from 1 to 30 carbon atoms; Y wherein each R704 is, independently, H, S03M; COOM, OS03M or 0P0 (0H) 0M, wherein M is as defined, halide or alkyl of 1 to 30 carbon atoms; and Q6 is Cu, Mg, Fe, Cr, Co or mixtures thereof with cationic charges. Suitable porphyrins include porphyrin available from Wako Chemicals and Copper Ptalocyanin II which is obtained from Wako Chemicals.

Imidazoles Imidazoles are a class of compounds that have the following base structure: P1188 Imidazoles useful in the present invention include those having the formulas (33): wherein X "is as defined above .. Suitable imidazoles include those with the trade name C.I. Fluorescence Brightener 352 or Uvtex AT from Ciba Specialty Chemical.

ADDITIONAL CONDITIONING AGENT The compositions of the present invention may further comprise an additional conditioning agent which is selected from the group consisting of amphoteric acidic polymers, high melting point compounds, cationic surfactants, high molecular weight ester oils, cationic polymers, compounds additional oily and mixtures thereof. The additional conditioning agents of the present are selected according to the compatibility with other components and according to the desired characteristics of the product. By For example, the components of cationic nature will be included in an amount that does not produce separation, in view of the components of anionic and / or amphoteric nature. The additional conditioning agents herein are used in weight levels of the composition of between about 0.01% and 10%.

Amphoteric Conditioning Polymer The amphoteric conditioning polymers useful herein are compatible with the carboxylic acid / carboxylate copolymers and provide conditioning benefits to hair. Although some of the amphoteric conditioning polymers herein may have certain hair setting or retention properties, such properties are not required for the amphoteric conditioning polymers herein. The amphoteric conditioning polymers useful herein are those which include at least one anionic monomer, the cationic monomer is quaternary ammonium, preferably dialkylammonium chloride or carboxylamidoalkyl ammonium chloride, and the anionic monomer is carboxylic acid. The amphoteric conditioning polymers herein may include nonionic monomers such as acrylamide, methacrylate or ethacrylate. In addition, the conditioning polymers useful herein do not contain P1188 xX & w Z ¡fa-A betainized monomers. Polymers suitable for the present are those having the CTFA name of Polyquaternium 22, Polyquaternium 39 and Polyquaternium 47. These polymers are, for example, copolymers consisting of dimethyldiallylammonium chloride and acrylic acid, terpolymers consisting of dimethyldiallylammonium chloride and acrylamide, and terpolymers consisting of acrylic acid, methacrylamidopropyl trimethylammonium chloride, and methyl acrylate, as those of the following formula, wherein the ratio of n6: n7: n8 is 45:45:10.

Commercially available and highly preferred amphoteric conditioning polymers herein include Polyquaternium 22 under the trade names MERQUAT 280, MERQUAT 295, Polyquaternium 39 under the trade names MERQUAT PLUS 3330, MERQUAT PLUS 3331 and Polyquaternium 47 under the trade names MERQUAT2001, MERQUAT 2001N , they are all obtained from Well Calgon Corporation. Here, non-betainized amphoteric polymers resulting from the copolymerization of a vinyl monomer carrying at least one carboxyl group, such as acrylic acid, methacrylic acid, maleic acid, itaconic acid, fumaric acid, crotonic acid or alpha-chloroacrylic acid, are useful. and a basic monomer which is a vinyl substituted compound containing at least one basic nitrogen atom, such as dialkylaminoalkyl methacrylates and acrylates and dialkylaminoalkyl methacrylamides and acrylamides. Polymers containing units derived from: i) at least one monomer selected from acrylamides or methacrylamides substituted on the nitrogen with an alkyl radical, ii) at least one acid comonomer containing one or more reactive carboxyl groups, are useful herein. and iii) at least one basic comonomer, such as esters with substituents of primary, secondary and tertiary amine and quaternary ammonium substituents, of acrylic and methacrylic acids and the product resulting from the quaternization of dimethylaminoethyl methacrylate with dimethyl or diethyl sulfate. N-substituted acrylamides or methacrylamides P1188 which are particularly preferred are groups in which the alkyl radicals contain from 2 to 12 carbon atoms, especially N-ethylacrylamide, N-tert-butylacpramide, β-tert-octylacrylamide, N-octylacrylamide, N-decylacrylamide and N-dodecyl acrylamide and also the corresponding methacrylamides. The acidic comonomers are selected more particularly from among acrylic, methacrylic, crotonic, itaconic, maleic and fumaric acids and also the alkyl monoesters of maleic acid or fumaric acid in which the alkyl has from 1 to 4 carbon atoms. The preferred basic comonomers are aminoethyl, butylaminoethyl, N, N'-dimethylaminoethyl and N-tert-butylaminoethyl methacrylates. Commercially available amphoteric conditioning polymers include octylacrylamide / acrylate / butylaminoethyl methacrylate copolymers under the tradenames AMPHOMER, AMPHOMER SH701, 7? MPH0MER 28-4910, AMPHOMER LV71 and AMPHOMER LV47 supplied by National Starch & Chemical.

Compounds with high melting point The compounds with high melting point which are used herein have a melting point of at least about 25 ° C and are selected from the group that P1188 ^ -feg * ^^^^? it consists of fatty alcohols, fatty acids, fatty alcohol derivatives, fatty acid derivatives, hydrocarbons, steroids and mixtures thereof. Those skilled in the art will understand that the compounds disclosed in this section of the specification can, in some cases, fall into more than one classification, for example, some fatty alcohol derivatives can also be classified as fatty acid derivatives. However, it is not intended that a certain classification is a limitation on that particular compound and this is done for the convenience of classification and nomenclature. In addition, those skilled in the art will understand that, depending on the number and position of the double bonds and the length and position of the branches, certain compounds having certain required carbon atoms may have a melting point less than about 25 ° C. It is not intended that these compounds with low melting point be included in this section. Non-limiting examples of high-melting compounds are found in the International Cosmetic Ingredient Dictionary, Fifth Edition, 1993, and CTFA Cosmetic Ingredient Handbook, Second Edition, 1992. These high-melting compounds are considered to cover the surface of the hair and reduce friction, resulting in this way they provide the P1188 j * ßtr, -g »-hair a soft touch and ease of combing. Fatty alcohols useful herein are those having from about 14 to about 30 carbon atoms, preferably from about 16 to about 22 carbon atoms. These fatty alcohols can be straight or branched chain alcohols and can be saturated or unsaturated. Non-limiting examples of fatty alcohols include cetyl alcohol, stearyl alcohol, behenyl alcohol and mixtures thereof. Fatty acids useful herein are those having from about 10 to about 30 carbon atoms, preferably from about 12 to about 22 carbon atoms and more preferably from about 16 to about 22 carbon atoms. These fatty acids can be straight or branched chain acids and can be saturated or unsaturated. Also included are diacids, triazides and other multiple acids that meet the requirements herein. Also included here are the salts of these fatty acids. Non-limiting examples of fatty acids include lauric acid, palmitic acid, stearic acid, behenic acid, sebacic acid and mixtures thereof. The fatty alcohol derivatives and the fatty acid derivatives useful herein include ethers of P1188 alkyl of fatty alcohols, alkoxylated fatty alcohols, alkyl ethers of alkoxylated fatty alcohols, esters of fatty alcohols, fatty acid esters of compounds having esterifiable hydroxy groups, hydroxysubstituted fatty acids and mixtures thereof. Non-limiting examples of fatty alcohol derivatives and fatty acid derivatives include materials such as methyl stearyl ether; the ceteth series of compounds such as ceteth-1 to ceteth-45, which are ethylene glycol ethers of cetyl alcohol, wherein the numeric designation indicates the number of ethylene glycol entities present; the series of steareth compounds such as steareth-1 to 10, which are ethylene glycol ethers of steareth alcohol, wherein the numeric designation indicates the number of ethylene glycol entities present; ceteareth 1 to ceteareth 10, which are ethylene glycol ethers of ceteareth alcohol, that is, a mixture of fatty alcohols containing predominantly cetyl and stearyl alcohol, wherein the numeric designation indicates the number of ethylene glycol entities present. C? -C30 alkyl ethers of the described ceteth, steareth and ceteareth compounds; polyoxyethylene ethers of behenyl alcohol; ethyl stearate, cetyl stearate, cetyl palmitate, stearyl stearate, myristyl myristate, polyoxyethylene cetyl ether stearate, ether P1188 polyoxyethylene stearyl stearate, polyoxyethylene lauryl ether stearate, ethylene glycol monostearate, polyoxyethylene monostearate, polyoxyethylene distearate, propylene glycol monostearate, propylene glycol distearate, trimethylolpropane distearate, sorbitan stearate, polyglyceryl stearate, glyceryl monostearate, distearate glyceryl, glyceryl tristearate and mixtures thereof. The hydrocarbons useful herein include compounds having at least about 20 carbons. Steroids useful herein include compounds such as cholesterol. Compounds with high melting point of a single high purity compound are preferred. Those of greatest preference are pure compounds of pure fatty alcohols selected from the group of pure cetyl alcohol, stearyl alcohol and behenyl alcohol. By the term "pure" in the present, what is meant is that the compound has a purity of at least about 90%, preferably at least about 95%. These single high purity compounds provide good rinsing properties of the hair when the consumer rinses the composition. The compounds of high melting point P1188 commercially available and useful herein include: cetyl alcohol, stearyl alcohol and behenyl alcohol, which have the trade names of the KONOL series available from New Japan Chemical (Osaka, Japan), and from the NAA series available from NOF (Tokyo, Japan); pure behenyl alcohol having the trade name 1-D0C0SAN0L available from WAKO (Osaka, Japan), several fatty acids having the trade names NEO-FAT available from Akzo (Chicago Illinois, USA), HYSTRENE available from Witco Corp. (Dublin Ohio, USA), and DERMA available from Vevy (Genova, Italy); and the cholesterol that has the commercial name of NIKKOL AGUASÓME LA available from Nikko.

Cationic Surfactant Among the cationic surfactants useful herein are those corresponding to formula (I): R71 R wherein R71, R72, R73 and R74 are independently selected from an aliphatic group of between 8 to 30 carbon atoms or a group aromatic, alkoxy, polyoxyalkylene, alkylamido, hydroxyalkyl, aryl or alkylaryl having up to about 22 carbon atoms; the rest of R71, R72, R73 and R74 are independently selected from a group Aliphatic p1188 of from 1 to about 22 carbon atoms or an aromatic, alkoxy, polyoxyalkylene, alkylamido, hydroxyalkyl, - "" aryl or alkylaryl group having up to 22 carbon atoms; and X is a salt-forming anion such as those selected from halogen (eg, chloride, bromide), acetate, citrate, lactate, glycolate, phosphate, nitrate, sulfonate, sulfate, alkyl sulfate and alkylsulfonate. The aliphatic groups may contain, in addition to carbon and hydrogen atoms, ether linkages and other groups such as amino groups. Longer chain aliphatic groups, for example those of about 12 carbon atoms or higher, may be saturated or unsaturated. It is preferred that R71, R72, R73 and R74 are independently selected from Ci alkyl at about C22. Non-limiting examples of the cationic surfactants useful in this invention include the materials having the following CTFA designations: quaternium-8, quaternium-14, quaternium-18 methosulfate, quaternium-24 and mixtures thereof. Among the cationic surfactants of the general formula (1), those which contain in the molecule at least one alkyl chain having at least 16 carbon atoms are preferred. Non-limiting examples of these preferred cationic surfactants include: available behenyl trimethyl ammonium chloride, P1188 for example, under the trade name INCROQUAT TMC-80 DE Croda and ECONOL TM22 from Sanyo Kasei; cetyl trimethyl ammonium chloride available, for example, under the tradename CA-2350 from Nikko Chemicals, alkyl trimethyl ammonium hydrogenated tallow chloride, dialkyl (14-18) dimethyl ammonium chloride, ditallow alkyl dimethyl ammonium chloride, hydrogenated ditallow alkyl dimethyl ammonium chloride, diethyallethyl dimethyl ammonium chloride, dicetyl dimethyl ammonium chloride, di (behenyl / arachidyl) dimethyl ammonium, dibenzyl dimethyl ammonium chloride, stearyl dimethyl benzyl chloride, stearyl propylene glycol phosphate dimethyl ammonium chloride, stearoyl amidopril dimethyl benzyl ammonium chloride, stearoyl amido propyl dimethyl (myristylacetate) ammonium chloride and N- (stearoyl-colamino formyl methyl) pyridinium. Also preferred are hydrophilically substituted cationic surfactants in which at least one of the substituents contains one or more aromatic, ether, ester, amido or amino entities present as substituents or as linkages in the radical chain, wherein at least one of the radicals R1-R4 contain one or more hydrophilic entities selected from alkoxy (preferably Ci-C3 alkoxy), polyoxyalkylene (preferably Cx-C3 polyoxyalkylene), alkylamido, hydroxyalkyl, alkyl ester and combinations thereof.

P1188 Preferably, the hydrophilically substituted cationic conditioning surfactant contains from 2 to about 10 non-ionic hydrophilic entities located within the aforementioned ranges. Preferred hydrophilically substituted cationic surfactants include those of formula (II) to formula (VII) below: wherein n1 is from 8 to 28, m? m2 is from 2 to about 40, Z1 is a short chain alkyl, preferably a Ci-C3 alkyl, more preferably methyl or (CH2CH0) m3H wherein m1 + m2 + m3 is up to 60, and X is a salt-forming anion as defined above; wherein n2 is from 1 to 5, one or more of R75, R76 and R77 are independently a C? -C30 alkyl, the residue CH2CH2OH, one or two of R78, R79 and R80 are independently a Ci-C30 alkyl and the remainder are CH2CH2OH and X is a salt-forming anion as mentioned above; P1188 wherein, independently of formulas (IV) and (V), Z2 is an alkyl, preferably C? -C3 alkyl, more preferably methyl, and Z3 is a short chain hydroxyalkyl, preferably hydroxymethyl or hydroxyethyl, n3 and n4 independently are integers from 2 to 4, inclusive, preferably from 2 to 3, inclusive, and more preferably 2, R81 and R82 independently are substituted or unsubstituted hydrocarbyls, preferably alkenyl or C 2 -C 20 alkyl and X is a salt-forming anion as defined above; wherein R 83 is a hydrocarbyl, preferably C 1 -C 3 alkyl, more preferably methyl, Z 4 and Z 5 are, independently, short chain hydrocarbyls, preferably alkenyl or C 2 -C 4 alkyl, more preferably ethyl, m 4 is 2 to about 40, preferably from about 7 to about 30 and X is a salt-forming anion as defined above; P1188 (VII) wherein R84 and R85 independently are C? _3 alkyl, preferably methyl, Z6 is a Ci2 to C22 hydrocarbyl, alkylcarboxy or alkylamido, and A is a protein, preferably a collagen, keratin, milk protein, silk , soy protein, wheat protein or hydrolyzed forms thereof, and X is a salt-forming anion, as defined above; wherein n5 is 2 or 3, R86 and R87, independently are C? -C3 hydrocarbyls, preferably methyl and X is a salt-forming anion as defined above. Non-limiting examples of hydrophilically substituted cationic surfactants useful in this invention include materials having the following CTFA designations: quaternium-16, quaternium-26, quaternium-27, quaternium-30, quaternium-33, quaternium-43, quaternium-52 , quaternium-53, quaternium-56, quaternium-60, quaternium-61, quaternium-62, quaternium-70, quaternium-71, quaternium-72, quaternium-75, hydrolyzed collagen quaternium-76, quaternium-77, quaternium-78 , hydrolyzed collagen quaternium-79, quaternium-79 hydrolyzed keratin, milk protein P1188 hydrolyzed quaternium-79, quaternium-79 hydrolysed silk, quaternium-79 hydrolyzed soy protein and quatern 'hydrolyzed wheat protein' mum-79, quaternium-80, quaternium-81, quaternium-82, quaternium-83, quaternium-84 and mixtures thereof. Highly preferred hydrophilically substituted cationic surfactants include dialkylamidoethyl hydroxyethylmonium salt, dialkylamidoethyl dimonium salt, dialkyloyl ethyl hydroxyethylmonium salt, dialkyloyl ethyldimonium salt and mixtures thereof. For example the following commercially available materials: VARISOFT 110, VARISOFT 222, VARIQUAT K1215 and 638 from Witco Chemical, MACKPRO KLP, MACKPRO WLW, MACKPRO MLP, MACKPRO NSP, MACKPRO NLW, MACKPRO WWP, MACKPRO NLP, MACKPRO SLP from Mclntyre, ETHOQUAD 18 / 25, ETHOQUAD 0 / 12PG, ETHOQUAD C / 25, ETHOQUAD S / 25 and ETHODUOQUAD from Akzo, DEHYQUAT SP from Henkel and ATLAS G265 from ICI Americas. Amines are suitable cationic surfactants. The primary, secondary and tertiary fatty amines are also useful. Alkyl groups of these amines preferably have from about 12 to about 22 carbon atoms. Amide tertiary amines useful herein include stearamidopropyldimethylamine, stearamidopropyldiethylamine, stearamidoethyldiethylamine, P1188 .-5 3% -. stearamidoethyldimethylamine, palmitamidopropyldimethylamine, palmitamidopropyldiethylamine, palmitamidoetildietilamina, palmitamidoethyldimethylamine, behenamidopropyldimethylamine, behenamidopropildietilamina, behenamidoetildietilamina, behenamidoetildimetilamina, arachidamidopropyldimethylamine, araquidamidopropildietilamina, arachidamidoethyldiethylamine, arachidamidoethyldimethylamine, dietilaminoetilestearamida. Also useful are dimethyl stearamine, dimethyloxyamine, soyamine, myristylamine, tridecylamine, ethylstearylamine, N-sebopropane diamine, stearylamine ethoxylate (with 5 moles of ethylene oxide), dihydroxyethylstearylamine and arachidylbehenylamine. The amines useful in the present invention are set forth in U.S. Pat. 4, 275, 055, Nachtigal, et al. These amines can also be used in combination with acids such as for example L-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, tartaric acid, citric acid, L-glutamic hydrochloride, maleic acid and mixtures thereof; more preferably L-glutamic acid, lactic acid, citric acid. The amines hereof are preferably partially neutralized with any of the acids, at a molar ratio of amine to acid of between about 1: 0.3 to about 1: 2 most preferably P1188 ^ C ^ ^ yes ^ approximately 1: 0.4 to approximately 1: 1.

High Molecular Weight Ester Oils High molecular weight ester oils are presently sterile. The high molecular weight ester oils useful herein have a molecular weight of at least 500, preferably at least 800, and are in the liquid state at 25 ° C. Useful useful high molecular weight ester oils are selected from the group consisting of pentaerythritol ester oils, trimethylol ester oils, polyalphaolefin oils, citrate ester oils, glyceryl ester oils and mixtures thereof. As used herein, the term "water insoluble" refers to the compound that is practically not soluble in water at 25 ° C; when the compound is mixed with water at a concentration by weight greater than 1.0%, preferably greater than 0.5%, the compound temporarily disperses to form an unstable colloid in water, then rapidly separates from the water to form two phases. The high molecular weight ester oil herein provides the hair when it is dry conditioning benefits such as moisturizing, softness and docile feel and does not leave the hair feeling greasy to the touch. It is believed that the materials P1188 * »£. oily insoluble in water, usually have the ability to deposit in the hair. Without being limited to the theory, it is believed that, because of its volume, the high molecular weight ester oil covers the surface of the hair, as a consequence, the high molecular weight ester oil reduces the friction in the hair to give it softness and docility. It is also believed that, because it has some hydrophilic groups, the high molecular weight ester oil provides a feeling of wetness to the touch and even because it is liquid it does not leave the hair feeling greasy to the touch. The high molecular weight ester oil is chemically stable under normal conditions of use and storage. The pentaerythritol ester oils useful herein are those having the following formula: wherein R1, R2, R3 and R4, independently, are branched, linear, saturated or unsaturated alkyl, aryl and alkylaryl groups having from 1 to about 30 carbon atoms. Preferably R1, R2, R3 and R4, independently, are branched, linear, saturated or unsaturated alkyl groups, having between P1188 approximately 8 and 22 carbon atoms. More preferably, R1, R2, R3 and R4 are defined so that the molecular weight of the compound sjaa is between about 800 and 1200. The trimethylol ester oils useful herein are those having the following formula: wherein R 11 is an alkyl group having between 1 and about 30 carbon atoms and R 12, R 13 and R 14, independently, are branched, linear, saturated or unsaturated alkyl, aryl and alkylaryl groups having from 1 to about 30 carbon atoms. carbon. Preferably R11 is ethyl and R12, R13 and R14 are independently branched, linear, saturated or unsaturated alkyl, aryl and alkylaryl groups having between about 8 and 22 carbon atoms. More preferably R11, R12, R13 and R14 are defined so that the molecular weight of the compound is between about 800 and 1200. The poly-α-olefin oils useful herein are those having the following formula and having a viscosity of between approximately 1 and P1188 about 35,000 cst, a molecular weight between about 200 and about 60,000 and a polydispersity of no more than about 3; wherein R31 is an alkyl having from about 4 to 14 carbon atoms, preferably from 4 to 10 carbon atoms. Poly-α-olefin oils having a molecular weight of at least about 800 are useful herein. These high molecular weight poly α-olefin oils are considered to provide a lasting wetting perception to the hair. Poly-α-olefin oils having a molecular weight of less than 800 are useful herein. These low molecular weight poly α-olefin oils are considered to provide softness, light and a cleansing sensation in the hair. The citrate ester oils useful herein are those which have a molecular weight of at least about 500 and have the formula: then «* & €" 79 - < * s ^ wherein R21 is OH or CH3COO and R22, R23 and R24 are, independently, straight, branched, saturated or unsaturated alkyl, aryl and alkylaryl groups having from 1 to 30 carbon atoms. Preferably, R21 is OH and R, R23 and R24 are, independently, straight, branched, saturated or unsaturated alkyl, aryl and alkylaryl groups having from about 8 to 22 carbon atoms. More preferably, R21, R22, R23 and R24 are defined so that the molecular weight of the compound is at least about 800. The glyceryl ester oils useful herein are those having a molecular weight of at least approximately 500 and have the following formula: wherein R41, R42 and R43 are, independently, branched, straight, saturated or unsaturated alkyl, aryl and alkylaryl groups, having from about 1 to 30 carbon atoms. Preferably, R41, R42 and R43 are, independently, straight, branched, saturated or unsaturated alkyl, aryl and alkylaryl groups having 8 to 22 carbon atoms, approximately. More preferably, R41, R42 and R43 are defined so that the weight Molecular P1188 of the compound is at least about 800. Pentaerythritol ester oils and particullarly trimethylol ester oils useful herein include pentaerythritol tetraisostearate, pentaerythritol tetraoleate, trimethylolpropane triisostearate, trimethylolpropane tpoleate and mixtures thereof. . These compounds are available from Kokyo Alcohol under the trade names KAKPTI, KAKTTI and Shin-nihon Rika under the trade names PTO, ENUJERUBU TP3SO. The poly-olefin oils particularly useful herein include polydecenes with the trade names PURESYN 6 with a number average molecular weight of about 500 and PURESYN 100 with a number average molecular weight of about 3000 and PURESYN 300 with a number average molecular weight of about 600, which are obtained from Mobil Chemical Co. Citrate ester oils particularly useful herein include triisocetyl citrate under the tradename CITMOL 316 from Bernel, triisostearyl citrate under the tradename PELEMOL TISC from Phoenix and trioctyldodecyl citrate with the commercial name CITMOL 320 of Bernel. The glyceryl ester oils particularly P1188 át ». useful herein include triisostearyl under the tradename SUN ESPOL G-318 of Taiyo Kagaku, triolein under the tradename CITHROL GTO OF Croda Surfactants Ltd., trilinolein under the tradename EFADERMA-F of Vevy or EFA-GLYCERIDES of Brooks.

Cationic Polymers Cationic polymers are useful herein. In the sense used herein, the term "polymers should include materials either made by the polymerization of one type of monomer or made by the polymerization of two or more types of monomers (ie copolymers). Preferably, the cationic polymer is a "cationic polymer" is a water-soluble cationic polymer "Water-soluble" means a polymer that is sufficiently soluble in water to form a solution substantially clear to the naked eye at a concentration of 0.1% in water, ie distilled or equivalent , at 25 ° C. Preferably, the polymer will be sufficiently soluble to form a substantially clear solution at a concentration of 0.5%, more preferably at a concentration of 1.0% The cationic polymers of the present will generally have an average molecular weight weighted that is P1188 of at least about 5,000, typically of at least about 10,000 and less than about 10 million. Preferably, the molecular weight is between about 100,000 and about 2 million. The cationic polymers will generally have cationic nitrogen containing entities, for example quaternary ammonium or cationic ammonium entities and mixtures thereof. Any anionic counterions "can be used for water-soluble cationic polymers as long as the water solubility criteria are met." Suitable counterions include halides (for example Cl, Br, I or F, preferably Cl, Br or I), sulfate and methylisulfate Other may also be used as it is listed is not exclusive The entities containing cationic nitrogen will generally be present as a substituent or as a fraction of the total monomeric units of cationic hair conditioning polymers. The water-soluble cationic polymer may comprise copolymers, terpolymers, etc. of cationic amine-substituted or ammonium-quaternary monomeric units and other non-cationic units referred to herein as "monomeric separating units." These polymers are known in the art and can A variety of them can be found in the CTFA Cosmetic Ingredient Dictionary, 3rd Edition, edited by Estrin, Crosley, and Haynes, (The Cosmetic, Toiletry, and Fragrance Association, Inc., Washington, D.C., 1982). The cationic amines can be primary, secondary or tertiary amines depending on the particular species and the pH of the composition. In general, secondary and tertiary amines, especially tertiary amines, are preferred. The amine-substituted vinyl monomers can be polymerized in the amine form and then optionally converted to ammonium by a quaternization reaction. Amines can also similarly quaternize subsequent to polymer formation. For example, the tertiary amine functional groups can be quaternized by reaction with a salt of the formula R88X, wherein R88 is a short chain alkyl, preferably C? -C7 alkyl, more preferably C? -C3 alkyl and X is an anion that forms a salt, as defined above. Suitable quaternary ammonium and cationic ammonium monomers that are included in the cationic polymers of the shampoo composition herein include vinyl compounds substituted with dialkylaminoalkyl acrylate, dialkylaminoalkyl as methacrylate, monoalkylaminoalkyl acrylate, monoalkylaminoalkyl methacrylate, trialkyl methacryloxyalkyl ammonium salts, trialkyl acryloxyalkyl ammonium saltsdiallyl quaternary ammonium salts and vinyl quaternary ammonium monomers having cationic cyclic rings containing nitrogen, for example pyridinium, imidazolium and quaternized pyrrolidone, for example alkyl vinyl imidazolium salts, alkyl vinyl pyridinium, alkyl vinyl pyrrolidone. The alkyl portions of these monomers are preferably lower alkyls such as for example C 1 -C 3 alkyls, more preferably Ci-C 2 alkyls. Suitable amine-substituted vinyl monomers used herein include dialkylaminoalkyl acrylate, dialkylaminoalkyl methacrylate, dialkylaminoalkyl acrylamide and dialkylaminoalkyl methacrylamide, wherein the alkyl groups are preferably C? -C7 hydrocarbyl / most preferably Ci-C3 alkyls. The cationic polymers herein may comprise mixtures of monomer units derived from compatible spacer monomers and / or monomers substituted with quaternary ammonium and / or amine. Suitable hair conditioning cationic polymers which are used in the shampoo compositions include l-vinyl-2-pyrrolidone salt copolymers P1188 and l-vinyl-3-methylimidazolium (for example, chloride salt) (referred to in the CTFA industry, as polyquaternium-16), such as those obtained commercially from BASF Wya?, Dotte Corp. (Parsippany , NH, USA) with the commercial name LUVIQUAT (for example, LUVIQUAT FC 370); copolymers of l-vinyl-2-pyrrolidone and dimethylaminoethyl methacrylate, known as polyquaternium-11, which is commercially available from Gaf Corporation (Wayne, N J, USA) under the tradename GAFQUAT (eg, GAFQUAT 755N); cationic polymers containing diallyl quaternary ammonium, including, for example, dimethyldiallylammonium chloride homopolymer and copolymers of acrylamide and dimethyldiallylammonium chloride, referred to in the CTFA industry as polyquaternium 6 and polyquaternium 7, respectively, and mineral acid salts of esters of amino-alkyl of homopolymers and copolymers of unsaturated carboxylic acids having from 3 to 5 carbon atoms, as described in U.S. Patent No. 4,009,256. Other suitable cationic polymers that can be used include polysaccharide polymers, for example cationic cellulose derivatives and cationic starch derivatives. The polymers of cationic polysaccharides that are used herein include those of the formula: P1188 I Z ^ O-d ^ -IST-R ^) R < ? l wherein Z7 is a residual group of anhydroglucose, for example a cellulose anhydroglucose residue or starch; R89 is an alkylene oxyalkylene, polyoxyalkylene or hydroxyalkylene group, or a combination thereof; R 90, R 91 and R 92 are independently alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl or alkoxyaryl, each group contains up to about 18 carbon atoms and the total number of carbon atoms of each cationic entity (i.e., the sum of the carbon atoms). carbon in R90, R91 and R92) is preferably about 20 or less; and X is an anionic counterion, as already described. Cationic cellulose is available from Amerchol Corp. (Edison, NJ, USA) in its polymer series Polymer JR® and LR®, as hydroxyethyl cellulose salts that react with epoxide substituted with trimethyl ammonium, which is referenced in the industry (CTFA) as polyquaternium 10. Another type of preferred cationic cellulose includes the polymeric quaternary ammonium salts of hydroxyethyl cellulose which are reacted with epoxide substituted with lauryl dimethyl ammonium, referred to P1188 in the CTFA industry as polyquaternium 24 and which is obtained from Amerchol Corp. (Edison, NJ, USA) under the trade name Polymer LM-200®. Other water-soluble cationic polymers that can be used include cationic guar gum derivatives, for example guar hydroxypropyltrimonium chloride. (commercially available from Celanese Corp. in its series Jaguar R). Other materials include quaternary nitrogen containing cellulose ethers as described in U.S. Patent No. 3,962,418 and etherified cellulose and starch copolymers as described in U.S. Patent No. 3,958,581. Particularly useful cationic polymers herein include Polyquaternium-7, Polyquaternium-10, Polyquaternium-24 and mixtures thereof.

Additional oily compounds Additional and useful oily compounds herein include fatty alcohols and their derivatives, fatty acids and their derivatives and hydrocarbons. The additional oily compounds may be volatile or non-volatile and may have a melting point of not more than 25 ° C. Without being limited by theory, it is considered that oily compounds can penetrate the hair to modify the hydroxy bonds of hair, which results in the hair being provided with softness and flexibility. The additional oily compounds of this section should be distinguished from the high-melting compounds described above. Non-limiting examples of oily compounds are found in the International Cosmetic Ingredient Dictionary, Fifth Edition, 1993, and CTFA Cosmetic Ingredient Handbook, Second Edition, 1992. Fatty alcohols useful herein include those having from about 10 to about 30 carbon atoms, preferably from about 12 to about 22 carbon atoms. and, more preferably from about 16 to about 22 carbon atoms. These fatty alcohols can be straight or branched chain alcohols and can be saturated or unsaturated alcohols, preferably unsaturated alcohols. Non-limiting examples of these compounds include oleyl alcohol, palmitoleyl alcohol, isostearyl alcohol, isocetyl alcohol, undecanol, octyl dodecanol, octyl decanol, octyl alcohol, caprylic alcohol, decyl alcohol and lauryl alcohol. Fatty acids useful herein include those having from about 10 to about 30 carbon atoms, preferably from about 12 to about 22 carbon atoms and P1188 more preferably from about 16 to about 22 carbon atoms. These fatty acids can be straight or branched chain acids and can be saturated or unsaturated. Suitable fatty acids include, for example, oleic acid, linoleic acid, isostearic acid, linolenic acid, ethyl linolenic acid, ethyl linolenic acid, arachidonic acid and ricinoleic acid. Hereby it is defined that the fatty acid derivatives and the fatty alcohol derivatives include, for example, fatty alcohol ethers, alkoxylated fatty alcohols, alkyl ethers of fatty alcohols, alkyl ethers of alkoxylated fatty alcohols and bulky ester oils, such as pentaerythritol ester oils, trimethylol ester oils, citrate ester oils. glyceryl ester oils and mixtures thereof. Non-limiting examples of fatty acid derivatives and fatty alcohol derivatives include, for example, methyl linoleate, ethyl linoleate, isopropyl linoleate, isodecyl oleate, isopropyl oleate, ethyl oleate, octyldodecyl oleate, oleyl oleate, decyl oleate, butyl oleate, methyl oleate, octyldodecyl stearate, octyldodecyl isostearate, octyldodecyl isopalmitate, octyl isopelargonate, octyl pelargonate, hexyl isostearate, isopropyl isostearate, isodecyl isononanoate, ethyl stearate, methyl and 01eth-2. The bulky ester oils such as pentaerythritol ester oils, trimethylol ester oils, citrate ester oils and glyceryl ester oils which are useful herein are those having a molecular weight less than about 800, preferably less than about 500. Hydrocarbons useful herein include straight chain, cyclic and branched chain hydrocarbons which may be saturated or unsaturated, as long as they have a melting point no greater than about 25 ° C. These hydrocarbons have from about 12 to about 40 carbon atoms, preferably from about 12 to about 30 carbon atoms, and more preferably from about 12 to about 22 carbon atoms. Also included herein are the polymeric hydrocarbons of the alkenyl monomers, such as the polymers of the C2-6 alkenyl monomers. These polymers can be straight or branched chain polymers. The straight chain polymers will usually have a relatively short length, which have a total number of carbon atoms as described above. The branched chain polymers may have substantially higher chain lengths. He P1188 average molecular weight in number of these materials can vary widely, but will normally be up to about 500, preferably, from about 200 to about 400, and more preferably from about 300 to about 350. Also useful herein are the various grades of mineral oils. Mineral oils are liquid mixtures of hydrocarbons that are obtained from petroleum. Specific examples of suitable hydrocarbon materials include paraffin oil, mineral oil, dodecane, isododecane, hexadecane, isohexadecane, eicosene, isoeicosene, tridecane, tetradecane, polybutene, polyisobutene and mixtures thereof. Preferred for use herein are hydrocarbons selected from the group consisting of mineral oil, poly-olefin oils, such as isododecane, isohexadecane, polybutene, polyisobutene, and mixtures thereof. Commercially available fatty alcohols and their derivatives useful herein include: oleyl alcohol with the trade name UNJECOL 90BHR available from Shin Nihon Rika, various liquid esters with the trade names of the SCHERCEMOL series, available from Scher and hexyl isostearate with the name commercial HIS and isopropyl isostearate having the trade name of ZPIS available from Kokyu Alcohol. The ester acites Bulk P1188 commercially available herein include: trilaprylate / trimethylolpropane tricaprate with the trade name MOBIL ESTER P43 from Mobil Chemical Co. Commercially available hydrocarbons useful herein include isododecane, isohexadecane and isoeicosene under trade names PERMETHYL 99A, PERMETHYL 101A and PERMETHYL 1082, available from Presperse (South Plainfield New Jersey, USA), a copolymer of isobutene and normal butene with trade names INDOPOL H-100 available from Amoco Chemicals (Chicago Illinois, USA), mineral oil with trade name BENOL available from Witco, Isoparaffin with trade name ISOPAR of Exxon Chemical Co. (Houston Texas, USA).

Additional components The compositions herein can include other additional components that are selected by the expert in this area according to the desired characteristics of the final product and which are suitable to make the composition more acceptable in its cosmetic and aesthetic aspects, or to provide other benefits of use. These other additional components include, for example: UV light absorbers, herbal extracts and other additional components.

P1188 UV ABSORBER The compositions of the present invention may contain a UV absorber (ultraviolet light). UV absorbers are particularly useful for the compositions of the present invention that are practically transparent. The UV light absorbers of the present are preferably used in levels, by weight of the composition, of between about 0.01% and 10%. The UV light absorbers useful herein may be water soluble or water insoluble, and include: p-aminobenzoic acid, its salts and derivatives (ethyl, isobutyl, glyceryl esters, p-dimethylaminobenzoic acid); anthranilates (ie, o-aminobenzoates; methyl, menthyl, phenyl, benzyl, phenylethyl, linalyl, terpinyl and cyclohexenyl esters); salicylates (amyl, phenyl, benzyl, menthyl, glyceryl and dipropylene glycol esters); cinnamic acid derivatives (menthyl and benzyl esters, phenyl cinnamonitrile, butyl cinnamoyl pyruvate, trihydroxycinnamic acid derivatives (esculetin, metilesculetin, daphnetin and glucosides, esculin and daphnin), dibenzalacetone and benzalacetophenone, naphthosulfonates (sodium salts of acids) 2-naphthol-3,6-disulfonic acid and 2-naphthol-6,8-disulfonic acid) -dihydroxynaphthoic acid and its salts, o- and p-hydroxybiphenyldisulfonates, salts of quinine (bisulfate, sulfate, chloride, oleate and P1188 tannate); quinoline derivatives (salts of 8-hydroxyquinoline, 2-phenylquinoline); hydroxy or methoxy substituted benzophenones; uric and vilouric acids; tannic acid and its derivatives (for example, hexaethyl ether); (butyl carbityl) (6-propyl piperonyl) ether; hydroquinone, benzophenones (oxybenzene, sulisobenzone, dioxybenzone, benzoresorcinol, 2, 2 ', 4, 4'-tetrahydroxybenzophenone, 2,2'-Dihydroxy-4,4'-dimethoxybenzophenone, octabenzone); 4-Isopropyldibenzoylmethane; Butylmethoxydibenzoylmethane; ethacrylene and 4-isopropyl-di-benzoylmethane. Of these, 2-ethylhexyl p-methoxycinnamate, 4,4'-t-butyl methoxydibenzoylmethane, 2-hydroxy-4-methoxybenzophenone, octyldimethyl p-aminobenzoic acid, digaloyltrioleate, 2,2-dihydroxy-4-methoxybenzophenone ethyl 4- [bis] (hydroxypropyl)] aminobenzoate, 2-ethylhexyl-2-cyano-3, 3-diphenylacrylate, 2-ethylhexylsalicylate, glyceryl p-aminobenzoate, 3,3,5-trimethylcyclohexylsalicylate, methylanthranilate, p-dimethylaminobenzoic acid or aminobenzoate, 2 - ethylhexyl p-dimethylaminobenzoate, 2-phenylbenzimidazole-5-sulfonic acid, 2- (p-dimethylaminophenyl) -5-sulfonicbenzoxazoic acid and mixtures thereof. Preferred sunscreens useful in the compositions of the present invention are 2-ethylhexyl p-methoxycinnamate, butylmethoxydibenzoylmethane, 2-hydroxy-4-methoxybenzophenone, octyldimethyl p-aminobenzoic acid and P1188 mixtures thereof HERBAL EXTRACT The compositions of the present invention may contain herbal extracts. Herbal extracts useful herein include those which are soluble in water and those which are insoluble in water. Herbal extracts useful herein include: Multi-flowered polygonse extract, extract of Houttuynia cordate, extract of Phellodendron Bark, extract of meliloto, extract of white dead nettle, extract of licorice root, extract of herbal peony, extract of saponaria, extract of scourer, extract of quina, extract of climber saxifrage, extract of Sophora angustifolia, candock extract, bitter fennel extract, primrose extract, rose extract, Rehmannia glutinosa extract, lemon extract, shikon extract, aloe extract, lily bulb extract, eucalyptus extract, extract of field equisetum, sage extract, thyme extract, tea extract, laver extract, cucumber extract, clove extract, raspberry extract, lemon balm extract, gmgseng extract, carrot extract, horse chestnut extract, peach extract, peach leaf extract, mulberry extract, cornflower extract, witch hazel extract, placenta extract, P1188 thymus extract, silk extract, algae extract, marshmallow extract, dahurica angelica extract, apple extract, apricot kernel extract, arnica extract, artemisia capillaris extract, astragalus extract, lemon balm extract, extract knob, birch bark extract, sour orange peel extract, tea plant extract, burdock root extract, pimpinela extract, rusco extract, Stephania cepharantha extract, feverfew extract, chrysanthemum flower extract , satsuma tangerine peel extract, cnidium extract, coix seed extract, chrysalis extract, comfrey leaf extract, crategus extract, evening primrose oil, gambir extract, ganoderma extract, gardenia extract, extract Gentian, Geranium Extract, Ginkgo Extract, Vine Leaf Extract, Craegus Extract, Alkane Extract, Honeysuckle Extract, Honeysuckle Flower Extract, Extra hoelen extract, hops extract, horsetail extract, hydrangea extract, hypericum extract, isodonis extract, isodonis extract, ivy extract, japanese angelica extract, japanese coptis extract, juniper extract, yuyuba extract, Lion's foot extract, lavender extract, lettuce extract, licorice extract, linden extract, lithosperm extract, loquat extract, loofah extract, P1188 malloti extract, mauve extract, calendula extract, moutan bark extract, mistletoe extract, mukurossi extract, St. John's wort extract, mulberry root extract, urticasea extract, nutmeg extract, extract orange, parsley extract, hydrolyzed concheolin protein, peony root extract, mint extract, philodendrol extract, pine pineapple extract, platycodon extract, polygonatum extract, rehmannia extract, rice bran extract, rhubarb extract, rose fruit extract, rosemary extract, royal jelly extract, safflower extract, saffron flower extract, elderberry extract, saponaria extract, Sasa albo marginata extract, saxifrage stolonifera extract, scutellaria extract root, Cortinellus shiitake extract, lytosperm extract, sophora extract, bay extract, calamus root extract, swertia extract, thyme extract, ext tiger rape, tomato extract, turmeric extract, uncaria extract, cress extract, Campeche stick extract, grape extract, lily extract, cinorrodón extract, serpol extract, witch hazel extract from Virginia, extract strudel, yeast extract, cassava extract, zanthoxylum extract and mixtures thereof Herbal extracts available in the form P1188 commercial and useful herein include polygonum extracts of multiple flowers (Polygonum multiflori) that are water soluble and obtainable from the Institute of Occupational Medicine, CAPM, China National Light Industry and Maruzen, and other herbal extracts listed above can be obtained of Maruzen.

Other additional components A wide variety of other additional ingredients can be formulated in the present compositions. These include: other conditioning agents such as collagen hydrolyzed under the tradename Peptein 2000 available from Hormel, Vitamin E under the tradename Emix-d available from Eisai, panthenol available from Roche, pantenyl ethyl ether available from Roche, hydrolyzed keratin, proteins, plant extracts and nutrients; hair fixation polymers such as amphoteric fixative polymers, cationic fixative polymers, anionic fixative polymers, nonionic fixative polymers and silicone graft copolymers; preservatives such as benzyl alcohol, methyl paraben, propyl paraben and imidazolidinyl urea; agents for adjusting the pH, such as citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; salts, in general, such as P1188 potassium acetate and sodium chloride; coloring agents, such as any of the dyes FD &C or D &C; hair oxidizing agents (bleaching agents), such as hydrogen peroxide, perborate and persulfate salts; hair reducing agents such as thioglycollates; perfumes; and, sequestering agents, such as ethylenediamine tetraacetate disodium; filters and agents absorbing ultraviolet and infrared light, such as octyl salicylate, anti-dandruff agents such as zinc pyrithione, and mixtures thereof.

EXAMPLES The following examples further describe and demonstrate the modalities that fall within the scope of the present invention. The examples are provided solely for the purpose of illustration and should not be construed as limitations of the present invention, since many variations thereof are possible, without departing from the spirit and scope of the invention. The ingredients are identified by their chemical name, CTFA or otherwise defined below.

Compositions Ex. l Ex. 2 Ex. 3 Ex. 4 Ex. 5 Ex. 6 Visible particle 1 * 1 0. 1 - - - - 0. 2 P1188 ** $.? ^ & iiSSfe «.sai ^ '^ P1188 P1188 Definitions of components * 1 Visible particles 1: Unispheres AGE-527 available from Induchem AG * 2 Visible particles 2: Unispheres YE-501 available from Induchem.AG * 3 Visible particles 3: Unicerin C-30 available from Induchem AG * 4 Visible Particles 4: Unisphers UEA-509 available from P1188 Induchem AG * 5 Vitamin E: Emix-d available from Eisai * 6 Copolymer of acrylic acid / alkyl acrylate 1: PEMULEN TR-1 available from B.F. Goodrich * 7 Acrylic acid copolymer / alkyl acrylate 2: PEMULEN TR-2 available from B.F. Goodrich * 8 Carbomer: ICarbopol 981 available from B.F. Goodrich * 9 Carbomer 2: Carbopol Ultrez 10 available from B.F.

Goodrich * 10 Acrylates / methacrylate copolymer steareth-20: Acrysol 22 available from Rohm and Hass * 11 Bentonite: Southern Clay bentonite * 12 Magnesium aluminum silicate: Gelwhite MAS-L from Southern Clay * 13 Cetyl hydroxyethylcellulose: Polysurf 67 available from Aqualon * 14 Hydroxyethylcellulose: Polymer Amercell HM-1500 available of Amerchol * 15 Alky silicone emulsion: emulsion of silicone of copolymer grafted with alkyl DC2-2845 of Dow Corning * 16 Triethanolamine: Triethanolamine available from Nippon Shokubai * 17 Dimethicone and Dimethiconol: DCQ2-1403 available from Dow Corning P1188 A¿- #fi ¿L- > * 18 Cyclomethicone / Dimethiconol: DCQ2-1401 available from Dow Corning * 19 Cyclomethicone / Dimethicone: Gum / Cyclomethicone blend available from Shin-Etsu * 20 Cyclomethicone: DC345 available from Dow Corning * 21 Panthenol: Panthenol available from Roche * 22 Emulsion alkyl silicone: alkyl-grafted polymer silicone emulsion DC2-2845 from Dow Corning * 23 Polyquaternium-39: Merquat Plus 3330 available from Calgon * 24 Polyquaternium-47: Merquat Plus 2001 available from Calgon * 25 Polyquaternium-22: Merquat 280 available of Calgon * 26 Polyquaternium-24: Polymer LM-200 available from Amerchol * 27 PEG-2M: Polyox PEG 2M available from Amerchol. * 28 Polyethylene glycol 200: Carbowax PEG200 available from Union Carbide * 29 Hexylene Glycol: Hexylene Glycol available from Mitsui Toatsu * 30 Behenyl trimethyl ammonium chloride: INCROQUAT TMC-80 available from Croda * 31 Pentaeptritol Tetraoleate: Pentaerythritol Tetraoleate available from Shinnihon Rika * 32 Aloe extract: Aloe Vera extract obtained from P1188 Ichimaru Farcos * 33 Polycorum multiflori extract: Multiflori polygonum extract obtained from Occupational Medicine, CAPM * 34 Ginseng: Ginseng available from Occupational Medicine, CAPM * 35 Benzophenone-4: Uvnul MS-40 available from BASF * 36 Octyl Methoxycinnamate: MCX parasol available from Roche * 37 2,4-dimethoxy-6- (1 'pyrene) -1,3,5-trizine: 2, 4- dimethoxy-6- (1'-pyrene) -1, 3, 5-triazine available from Ciba Geigy * 38 Porphyrin: Porphyrin available from Wako Chemicals Method of Preparation Polymeric materials such as the viscosity imparting agent, the amphoteric conditioning polymer, if present, are dispersed in water at room temperature, mixed with vigorous stirring and then heated to about 50 ° C. The obtained mixture is cooled to below 40 ° C and then the neutralizing agent is added to the mixture. A triple mixer may be used if necessary, to disperse the polymeric materials. After neutralization, the remaining components are added to the mixture. If the surfactant is included Cationic P1188 is included in the formulation, a premix is made by dissolving the s, cationic urfactant in hot water at a temperature of about 70 ° C with stirring and then cooling to below 40 ° C. The premix obtained is added to the mixture. Examples 1 to 12 are compositions for conditioning hair, of the present invention, which are particularly useful for use without requiring rinsing. These examples have many disadvantages. For example, they are transparent and show the visible and breakable particles in distinctive form. They can also provide benefits of better conditioning to the hair, such as smoothness, softness and reduction of friction, are easy to apply to the hair and leave the hair and hands with a feeling of cleanliness. It is understood that the examples and embodiments described herein are for illustrative purposes only and that, in light thereof, various modifications or changes will be suggested to a person skilled in the art, without departing from the spirit and scope of the invention.

P1188

Claims (10)

1. CLAIMS: 1. A composition for conditioning hair, comprising: (1) a visible and breakable particle; (2) a silicone compound; and (3) an aqueous carrier, wherein the composition is transparent. The composition for conditioning the hair according to claim 1, wherein the visible and breakable particle comprises structural material selected from the group consisting of cellulose, cellulose derivatives, saccharides and mixtures thereof. 3. The hair conditioning composition according to claim 1, wherein the visible and breakable particle contains an included material, which contains a water-soluble component. The composition for conditioning the hair according to claim 1, wherein the visible and breakable particle contains an included material selected from the group consisting of vitamins, amino acids, proteins, protein derivatives, herbal extracts and mixtures thereof. The composition for conditioning the hair according to claim 1, wherein the included material selected from the group consisting of vitamin E, pantotenyl ethyl ether, panthenol, Polygonum extracts P1188 multiflori and mixtures thereof. 6. The hair conditioning composition according to any of claims 1 to 5, further comprising a viscosity imparting agent. The composition for conditioning the hair according to any of claims 1 to 5, further comprising a humectant. The composition for conditioning the hair according to any of claims 1 to 5, further comprising an optical brightener. 9. The hair conditioning composition according to any of claims 1 to 5, further comprising an additional conditioning agent. A composition for conditioning hair comprising, by weight: (1) between about 0.01% and 5% of a visible and breakable particle; (2) between about 0.1% and 60% of a silicone compound; (3) between about 0.01% and 10% of a viscosity modifier; (4) between about 0.1% and 20% of a humectant; (5) and an aqueous carrier, wherein the composition is transparent. P1188