MX2021011425A - Copolimeros de lldpe de doble componente con resistencia al impacto y al desgarro mejoradas y metodos para su preparacion. - Google Patents
Copolimeros de lldpe de doble componente con resistencia al impacto y al desgarro mejoradas y metodos para su preparacion.Info
- Publication number
- MX2021011425A MX2021011425A MX2021011425A MX2021011425A MX2021011425A MX 2021011425 A MX2021011425 A MX 2021011425A MX 2021011425 A MX2021011425 A MX 2021011425A MX 2021011425 A MX2021011425 A MX 2021011425A MX 2021011425 A MX2021011425 A MX 2021011425A
- Authority
- MX
- Mexico
- Prior art keywords
- tear strength
- ethylene polymer
- methods
- double
- preparation
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
- B29K2023/06—PE, i.e. polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/0063—Density
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2007/00—Flat articles, e.g. films or sheets
- B29L2007/008—Wide strips, e.g. films, webs
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Se describen composiciones de polímero de etileno que contienen un primer componente de polímero de etileno ramificado homogéneamente y 15-35 % en peso de un segundo componente de polímero de etileno ramificado homogéneamente de mayor densidad que el primer componente de polímero de etileno. La composición de polímero de etileno puede caracterizarse por una densidad de 0.912 a 0.925 g/cm3, un cociente de Mw/Mn de 2 a 5, un índice de fluidez menor que 2 g/10 min y un parámetro CY-a a 190 °C de 0.35 a 0.7. Estas composiciones de polímero tienen la resistencia al impacto de dardo y las propiedades ópticas excelentes de un LLDPE catalizado con metaloceno, pero con resistencia al desgarro en la dirección de la máquina mejorada, y se pueden usar en película soplada y otras aplicaciones de uso final. Además, también se describen métodos para mejorar la resistencia al desgarro Elmendorf de la película.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US16/363,221 US11427703B2 (en) | 2019-03-25 | 2019-03-25 | Dual component LLDPE copolymers with improved impact and tear resistance, and methods of their preparation |
PCT/US2020/022901 WO2020197811A1 (en) | 2019-03-25 | 2020-03-16 | Dual component lldpe copolymers with improved impact and tear resistance, and methods of their preparation |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2021011425A true MX2021011425A (es) | 2021-10-13 |
Family
ID=70277490
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2021011425A MX2021011425A (es) | 2019-03-25 | 2020-03-16 | Copolimeros de lldpe de doble componente con resistencia al impacto y al desgarro mejoradas y metodos para su preparacion. |
Country Status (8)
Country | Link |
---|---|
US (3) | US11427703B2 (es) |
EP (1) | EP3947551B1 (es) |
CN (1) | CN113272381B (es) |
BR (1) | BR112021018985A2 (es) |
CA (1) | CA3134034A1 (es) |
ES (1) | ES2993872T3 (es) |
MX (1) | MX2021011425A (es) |
WO (1) | WO2020197811A1 (es) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11028258B2 (en) | 2019-08-19 | 2021-06-08 | Chevron Phillips Chemical Company Lp | Metallocene catalyst system for producing LLDPE copolymers with tear resistance and low haze |
US11339279B2 (en) * | 2020-04-01 | 2022-05-24 | Chevron Phillips Chemical Company Lp | Dual catalyst system for producing LLDPE and MDPE copolymers with long chain branching for film applications |
CN120051525A (zh) * | 2022-11-03 | 2025-05-27 | 陶氏环球技术有限责任公司 | 聚乙烯组合物 |
CN120112593A (zh) * | 2022-11-03 | 2025-06-06 | 陶氏环球技术有限责任公司 | 聚乙烯组合物 |
Family Cites Families (41)
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WO1994025523A1 (en) | 1993-04-28 | 1994-11-10 | The Dow Chemical Company | Fabricated articles made from ethylene polymer blends |
JPH09309926A (ja) | 1996-05-17 | 1997-12-02 | Dow Chem Co:The | エチレン共重合体の製造方法 |
WO1998021276A1 (en) | 1996-11-13 | 1998-05-22 | The Dow Chemical Company | Shrink film having balanced properties or improved toughness and methods of making the same |
ES2146563T3 (es) | 1997-06-20 | 2003-09-01 | Dow Chemical Co | Composiciones de polimero de etileno y articulo fabricado a partir de las mismas. |
KR20010024063A (ko) * | 1997-09-19 | 2001-03-26 | 그래햄 이. 테일러 | 좁은 분자량 분포도 및 최적화된 조성을 갖는 에틸렌상호중합체 조성물, 이의 제조 방법 및 이로부터 제조된제품 |
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US6632680B1 (en) * | 2000-09-22 | 2003-10-14 | Deslauriers Paul J. | Measurement of short chain branching in olefin copolymers using chemometric analysis |
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KR20100040848A (ko) * | 2007-06-13 | 2010-04-21 | 다우 글로벌 테크놀로지스 인크. | 폴리에틸렌 조성물, 그의 제조 방법 및 그로부터 제조된 물품 |
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US10000594B2 (en) * | 2016-11-08 | 2018-06-19 | Chevron Phillips Chemical Company Lp | Dual catalyst system for producing LLDPE copolymers with a narrow molecular weight distribution and improved processability |
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US10435527B2 (en) | 2017-09-26 | 2019-10-08 | Chevron Phillips Chemical Company Lp | Dual component LLDPE copolymers with improved impact and tear resistance |
US10358506B2 (en) * | 2017-10-03 | 2019-07-23 | Chevron Phillips Chemical Company Lp | Dual catalyst system for producing LLDPE copolymers with improved processability |
-
2019
- 2019-03-25 US US16/363,221 patent/US11427703B2/en active Active
-
2020
- 2020-03-16 CA CA3134034A patent/CA3134034A1/en active Pending
- 2020-03-16 MX MX2021011425A patent/MX2021011425A/es unknown
- 2020-03-16 EP EP20718463.1A patent/EP3947551B1/en active Active
- 2020-03-16 CN CN202080008511.1A patent/CN113272381B/zh active Active
- 2020-03-16 WO PCT/US2020/022901 patent/WO2020197811A1/en unknown
- 2020-03-16 ES ES20718463T patent/ES2993872T3/es active Active
- 2020-03-16 BR BR112021018985A patent/BR112021018985A2/pt unknown
- 2020-04-02 US US16/838,086 patent/US11332601B2/en active Active
-
2022
- 2022-06-16 US US17/841,803 patent/US11634567B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
CA3134034A1 (en) | 2020-10-01 |
US11634567B2 (en) | 2023-04-25 |
US11427703B2 (en) | 2022-08-30 |
US20200308378A1 (en) | 2020-10-01 |
KR20210145124A (ko) | 2021-12-01 |
WO2020197811A1 (en) | 2020-10-01 |
US11332601B2 (en) | 2022-05-17 |
ES2993872T3 (en) | 2025-01-10 |
CN113272381A (zh) | 2021-08-17 |
BR112021018985A2 (pt) | 2021-11-30 |
EP3947551B1 (en) | 2024-08-21 |
US20220315744A1 (en) | 2022-10-06 |
US20200308380A1 (en) | 2020-10-01 |
CN113272381B (zh) | 2023-09-19 |
EP3947551A1 (en) | 2022-02-09 |
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